ES2961747T3 - Producto de lavandería - Google Patents
Producto de lavandería Download PDFInfo
- Publication number
- ES2961747T3 ES2961747T3 ES18170466T ES18170466T ES2961747T3 ES 2961747 T3 ES2961747 T3 ES 2961747T3 ES 18170466 T ES18170466 T ES 18170466T ES 18170466 T ES18170466 T ES 18170466T ES 2961747 T3 ES2961747 T3 ES 2961747T3
- Authority
- ES
- Spain
- Prior art keywords
- methyl
- weight
- isopulegol
- fragrance composition
- fragrance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000003205 fragrance Substances 0.000 claims abstract description 57
- ZYTMANIQRDEHIO-KXUCPTDWSA-N isopulegol Chemical compound C[C@@H]1CC[C@@H](C(C)=C)[C@H](O)C1 ZYTMANIQRDEHIO-KXUCPTDWSA-N 0.000 claims abstract description 56
- 239000000203 mixture Substances 0.000 claims abstract description 44
- ZYTMANIQRDEHIO-UHFFFAOYSA-N neo-Isopulegol Natural products CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000001871 (1R,2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol Substances 0.000 claims abstract description 27
- 229940095045 isopulegol Drugs 0.000 claims abstract description 27
- 239000002304 perfume Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 11
- 239000002979 fabric softener Substances 0.000 claims description 8
- 125000003158 alcohol group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 150000005690 diesters Chemical class 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- LMXFTMYMHGYJEI-IWSPIJDZSA-N (1R,2R,5R)-2-(1-hydroxy-1-methylethyl)-5-methylcyclohexanol Chemical compound C[C@@H]1CC[C@@H](C(C)(C)O)[C@H](O)C1 LMXFTMYMHGYJEI-IWSPIJDZSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical group CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 claims 1
- -1 polyoxyethylene lauryl ether sulfate Polymers 0.000 description 19
- 230000004936 stimulating effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 8
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 6
- 210000004556 brain Anatomy 0.000 description 5
- 239000000284 extract Substances 0.000 description 5
- 229960001679 octinoxate Drugs 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 4
- 235000007586 terpenes Nutrition 0.000 description 4
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 description 3
- 229940022663 acetate Drugs 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- JSNRRGGBADWTMC-UHFFFAOYSA-N (6E)-7,11-dimethyl-3-methylene-1,6,10-dodecatriene Chemical compound CC(C)=CCCC(C)=CCCC(=C)C=C JSNRRGGBADWTMC-UHFFFAOYSA-N 0.000 description 2
- UFLHIIWVXFIJGU-ONEGZZNKSA-N (E)-3-Hexenol Natural products CC\C=C\CCO UFLHIIWVXFIJGU-ONEGZZNKSA-N 0.000 description 2
- YGFGZTXGYTUXBA-UHFFFAOYSA-N (±)-2,6-dimethyl-5-heptenal Chemical compound O=CC(C)CCC=C(C)C YGFGZTXGYTUXBA-UHFFFAOYSA-N 0.000 description 2
- OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- DOJDQRFOTHOBEK-UHFFFAOYSA-N 1-Octen-3-yl acetate Chemical compound CCCCCC(C=C)OC(C)=O DOJDQRFOTHOBEK-UHFFFAOYSA-N 0.000 description 2
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 2
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 description 2
- PETRWTHZSKVLRE-UHFFFAOYSA-N 2-Methoxy-4-methylphenol Chemical compound COC1=CC(C)=CC=C1O PETRWTHZSKVLRE-UHFFFAOYSA-N 0.000 description 2
- TYYHDKOVFSVWON-UHFFFAOYSA-N 2-butyl-2-methoxy-1,3-diphenylpropane-1,3-dione Chemical compound C=1C=CC=CC=1C(=O)C(OC)(CCCC)C(=O)C1=CC=CC=C1 TYYHDKOVFSVWON-UHFFFAOYSA-N 0.000 description 2
- CFAKWWQIUFSQFU-UHFFFAOYSA-N 2-hydroxy-3-methylcyclopent-2-en-1-one Chemical compound CC1=C(O)C(=O)CC1 CFAKWWQIUFSQFU-UHFFFAOYSA-N 0.000 description 2
- CQLYXIUHVFRXLT-UHFFFAOYSA-N 2-methoxyethylbenzene Chemical compound COCCC1=CC=CC=C1 CQLYXIUHVFRXLT-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- JIMGVOCOYZFDKB-UHFFFAOYSA-N 2-phenylethyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OCCC1=CC=CC=C1 JIMGVOCOYZFDKB-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- UXFSPRAGHGMRSQ-UHFFFAOYSA-N 3-isobutyl-2-methoxypyrazine Chemical compound COC1=NC=CN=C1CC(C)C UXFSPRAGHGMRSQ-UHFFFAOYSA-N 0.000 description 2
- ALHUZKCOMYUFRB-UHFFFAOYSA-N 3-methylcyclopentadecan-1-one Chemical compound CC1CCCCCCCCCCCCC(=O)C1 ALHUZKCOMYUFRB-UHFFFAOYSA-N 0.000 description 2
- RHLVCLIPMVJYKS-UHFFFAOYSA-N 3-octanone Chemical compound CCCCCC(=O)CC RHLVCLIPMVJYKS-UHFFFAOYSA-N 0.000 description 2
- YGCZTXZTJXYWCO-UHFFFAOYSA-N 3-phenylpropanal Chemical compound O=CCCC1=CC=CC=C1 YGCZTXZTJXYWCO-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- MSHFRERJPWKJFX-UHFFFAOYSA-N 4-Methoxybenzyl alcohol Chemical compound COC1=CC=C(CO)C=C1 MSHFRERJPWKJFX-UHFFFAOYSA-N 0.000 description 2
- WJPRNDJHASWDLE-UHFFFAOYSA-N 4-butyl-gamma-butyrolactone Chemical compound CCCCC1COC(=O)C1 WJPRNDJHASWDLE-UHFFFAOYSA-N 0.000 description 2
- NTPLXRHDUXRPNE-UHFFFAOYSA-N 4-methoxyacetophenone Chemical compound COC1=CC=C(C(C)=O)C=C1 NTPLXRHDUXRPNE-UHFFFAOYSA-N 0.000 description 2
- OALYTRUKMRCXNH-UHFFFAOYSA-N 5-pentyloxolan-2-one Chemical compound CCCCCC1CCC(=O)O1 OALYTRUKMRCXNH-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- SCCDQYPEOIRVGX-UHFFFAOYSA-N Acetyleugenol Chemical compound COC1=CC(CC=C)=CC=C1OC(C)=O SCCDQYPEOIRVGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HVJKZICIMIWFCP-UHFFFAOYSA-N Benzyl 3-methylbutanoate Chemical compound CC(C)CC(=O)OCC1=CC=CC=C1 HVJKZICIMIWFCP-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 description 2
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- YIKYNHJUKRTCJL-UHFFFAOYSA-N Ethyl maltol Chemical compound CCC=1OC=CC(=O)C=1O YIKYNHJUKRTCJL-UHFFFAOYSA-N 0.000 description 2
- LHXDLQBQYFFVNW-UHFFFAOYSA-N Fenchone Chemical compound C1CC2(C)C(=O)C(C)(C)C1C2 LHXDLQBQYFFVNW-UHFFFAOYSA-N 0.000 description 2
- 241000134874 Geraniales Species 0.000 description 2
- UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- CRZQGDNQQAALAY-UHFFFAOYSA-N Methyl benzeneacetate Chemical compound COC(=O)CC1=CC=CC=C1 CRZQGDNQQAALAY-UHFFFAOYSA-N 0.000 description 2
- UUQHKWMIDYRWHH-UHFFFAOYSA-N Methyl beta-orcinolcarboxylate Chemical compound COC(=O)C1=C(C)C=C(O)C(C)=C1O UUQHKWMIDYRWHH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- 229960005193 avobenzone Drugs 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 229960002903 benzyl benzoate Drugs 0.000 description 2
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzylacetone Chemical compound CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 2
- POIARNZEYGURDG-UHFFFAOYSA-N beta-damascenone Natural products CC=CC(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 description 2
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- OSOIQJGOYGSIMF-UHFFFAOYSA-N cyclopentadecanone Chemical compound O=C1CCCCCCCCCCCCCC1 OSOIQJGOYGSIMF-UHFFFAOYSA-N 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 2
- SSNZFFBDIMUILS-UHFFFAOYSA-N dodec-2-enal Chemical compound CCCCCCCCCC=CC=O SSNZFFBDIMUILS-UHFFFAOYSA-N 0.000 description 2
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 2
- 210000000624 ear auricle Anatomy 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- PPXUHEORWJQRHJ-UHFFFAOYSA-N ethyl isovalerate Chemical compound CCOC(=O)CC(C)C PPXUHEORWJQRHJ-UHFFFAOYSA-N 0.000 description 2
- YYZUSRORWSJGET-UHFFFAOYSA-N ethyl octanoate Chemical compound CCCCCCCC(=O)OCC YYZUSRORWSJGET-UHFFFAOYSA-N 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 230000004424 eye movement Effects 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 description 2
- NTOPKICPEQUPPH-UHFFFAOYSA-N isopropyl methoxy pyrazine Chemical compound COC1=NC=CN=C1C(C)C NTOPKICPEQUPPH-UHFFFAOYSA-N 0.000 description 2
- CZVXBFUKBZRMKR-UHFFFAOYSA-N lavandulol Chemical compound CC(C)=CCC(CO)C(C)=C CZVXBFUKBZRMKR-UHFFFAOYSA-N 0.000 description 2
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- GVOWHGSUZUUUDR-UHFFFAOYSA-N methyl N-methylanthranilate Chemical compound CNC1=CC=CC=C1C(=O)OC GVOWHGSUZUUUDR-UHFFFAOYSA-N 0.000 description 2
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 description 2
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 description 2
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N octan-3-ol Chemical compound CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 2
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 2
- 150000002923 oximes Chemical class 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C11B9/00—Essential oils; Perfumes
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- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
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- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/042—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of a macromolecular compound as a carrier or diluent
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
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- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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Landscapes
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Veterinary Medicine (AREA)
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Abstract
La invención se refiere a un producto para el lavado de ropa que comprende una composición de fragancia que incluye isopulegol. (Traducción automática con Google Translate, sin valor legal)
Description
DESCRIPCIÓN
Producto de lavandería
Campo de la invención
La presente invención se refiere a un producto de lavandería que comprende una composición de fragancia que comprende isopulegol.
Antecedentes de la invención
Existe una creciente demanda por parte de los consumidores de productos que eleven la moral, proporcionen un efecto relajante o ayuden a contrarrestar el efecto del estrés. El documento EP-A-2 716 303 describe una composición y agente energizante psíquico, cuyos efectos se evalúan mediante un método denominado Variación Contingente Negativa (CNV). También se describen materiales de fragancia que tienen un efecto estimulante, por ejemplo, en los documentos JP-A-63-199293 y EP-A-1 875902, la primera solicitud también describe un método de CNV para medir un efecto estimulante. La CNV es un método bien conocido para indexar cambios potenciales graduales en el cerebro humano, que se describió por primera vez en 1964 en un artículo publicado enNature.La CNV se relaciona con los cambios de los procesos mentales y los niveles de activación, tales como atención, expectativa y anticipación. Se sabe que cuando el nivel de activación es alto, un componente temprano de la CNV aumenta en comparación con el estado normal y cuando el nivel de activación es bajo, un componente temprano de la CNV disminuye. Por ejemplo, se informó que cuando los sujetos olían un aceite de jazmín, que se sabe empíricamente que tiene un efecto estimulante, un componente temprano de la CNV aumentó, mientras que cuando los sujetos olieron una fragancia tipo lavanda, que se sabe empíricamente que tiene un efecto calmante, un componente temprano de CNV disminuyó (véase, por ejemplo, Toriiet al.,19° Simposio de gusto y olfato, 11 de septiembre de 1985. Se informa sobre los efectos estimulantes y sedantes de los compuestos olorosos, tal como se determina mediante CNV, por ejemplo, por Okazakiet al.(Flavours, Fragances and Essential Oils. Actas del 13° Congreso Internacional de sabores, fragancias y aceites esenciales, Estambul, Turquía, 15-19 de octubre de 1995. Vol. 3). El documento CN 103655 243 A describe un champú que tiene los siguientes componentes: isopulegol, lauril sulfato de sodio, sulfato de polioxietileno lauril éter, dietanolamida de coco y agua.
Sumario de la invención
La presente invención se refiere a un producto de lavandería como se define en la reivindicación 1 y que comprende una composición de fragancia, en la que la composición de fragancia comprende desde aproximadamente el 0,2% en peso hasta menos del 10% en peso de isopulegol, basándose en el peso total de la composición de fragancia, y al menos dos ingredientes adicionales de perfume.
Breve descripción de los dibujos
La figura 1 es una representación esquemática de la técnica de CNV.
La figura 2 representa un registro de CNV típico, en el que se detectan cambios potenciales en el cerebro humano en el área de enfoque.
La figura 3 representa la diferencia entre el área bajo la curva de (fragancia A isopulegol) y el área bajo la curva de fragancia A sola, tal como se calcula a partir del registro de CNV (no mostrado).
La figura 4 representa la diferencia entre el área bajo la curva de la fragancia B y el área bajo la curva de aire tal como se calcula a partir del registro de CNV (mostrado en la figura 5).
La figura 5 es un registro de CNV de la fragancia B (línea roja) en comparación con aire (línea negra).
La figura 6 es un registro de CNV de la fragancia C (línea roja) en comparación con aire (línea negra).
La figura 7 representa la diferencia entre el área bajo la curva de la fragancia C y el área bajo la curva de aire tal como se calcula a partir del registro de CNV (mostrado en la figura 6).
El área bajo la curva se calcula para valores entre las líneas punteadas en la figuras 5 y 6.
Descripción detallada de la invención
La presente invención se refiere a un producto de lavandería como se define en la reivindicación 1 y que comprende una composición de fragancia, en la que la composición de fragancia comprende desde aproximadamente el 0,2% en peso hasta menos del 10% en peso de isopulegol, basándose en el peso total de la composición de fragancia, y al menos dos ingredientes adicionales de perfume.
El producto de lavado de ropa de la invención se imparte con un efecto estimulante.
En el contexto de la presente invención, el término “efecto estimulante” se refiere a un efecto de mejora del nivel de activación de un sujeto humano, tal como se determina mediante Variación Contingente Negativa (CNV). En el contexto de la presente invención, los términos “que estimula”, “que energiza”, “que vigoriza”, “que activa” y “que despierta” pueden usarse de manera intercambiable. Asimismo, el término “agente estimulante” debe entenderse en el contexto de la presente invención como un agente que proporciona un efecto estimulante.
El isopulegol está disponible o bien como mezcla racémica (CAS 7786-67-6) bien como (-)-isómero (CAS 89-79-2). En una realización isopulegol está disponible como Coolact® P, un producto de Takasago. El isopulegol de la invención puede tener un isómero óptico y una pureza química de más del 90%, preferiblemente más del 95%, más preferiblemente más del 97,5%, e incluso más preferiblemente más del 99%. La pureza de isopulegol se determina mediante cromatografía de gases usando el método descrito en el documento US 5.773.410 sumando el porcentaje de área de los picos de impurezas y restando estos del área total medida que se toma como del 100%.
Mientras que el isopulegol se conoce como un agente refrescante que proporciona un efecto refrescante a la piel cuando se aplica a la misma, los inventores han descubierto ahora sorprendentemente que el isopulegol también produce un efecto estimulante, en particular cuando se formula en una composición de fragancia que se distribuye y luego se evapora en el aire.
La composición de fragancia ventajosamente comprende desde aproximadamente el 0,2 hasta aproximadamente el 9% en peso, desde aproximadamente el 0,2 hasta aproximadamente el 8% en peso, desde aproximadamente el 0,2 hasta aproximadamente el 7% en peso, desde aproximadamente el 0,2 hasta aproximadamente el 6% en peso, desde aproximadamente el 0,2 hasta aproximadamente el 5% en peso, desde aproximadamente el 0,2 hasta aproximadamente el 4% en peso o desde aproximadamente el 0,2 hasta aproximadamente el 3% en peso de isopulegol, basándose en el peso total de la composición de fragancia. La composición de fragancia puede comprender desde aproximadamente el 1 hasta aproximadamente el 9% en peso, desde aproximadamente el 1 hasta aproximadamente el 8% en peso, desde aproximadamente el 1 hasta aproximadamente el 7% en peso, desde aproximadamente el 1 hasta aproximadamente el 6% en peso, desde aproximadamente el 1 hasta aproximadamente el 5% en peso, desde aproximadamente el 1 hasta aproximadamente el 4% en peso o desde aproximadamente el 1 hasta aproximadamente el 3% en peso de isopulegol, basándose en el peso total de la composición de fragancia. La composición de fragancia también puede comprender desde aproximadamente el 2 hasta aproximadamente el 9% en peso, desde aproximadamente el 2 hasta aproximadamente el 8% en peso, desde aproximadamente el 2 hasta aproximadamente el 7% en peso, desde aproximadamente el 2 hasta aproximadamente el 6% en peso, desde aproximadamente el 2 hasta aproximadamente el 5% en peso o desde aproximadamente el 2 hasta aproximadamente el 4% en peso de isopulegol, basándose en el peso total de la composición de fragancia.
La composición de fragancia no comprende un diéster como se divulga en US 2011/081393, de fórmula:
en la que A representa CH<2>o CH=CH, n representa un número entero de 0 a 4 cuando A es CH<2>o 1 cuando A es CH=c H, B es un residuo de alcohol que tiene de 10 a 18 átomos de carbono y que contiene un esqueleto de paramentano, que puede sustituirse, y C es un residuo de alcohol que tiene de 6 a 18 átomos de carbono, que puede sustituirse. En una realización, la composición de fragancia no comprende ninguno de 1-mentoxi-propanodiol, 1-mentol y p-mentano-3,8-diol. En otra realización la composición de fragancia no comprende un éster salicílico de fórmula:
en la que R representa un grupo hidrocarbonado que tiene de 1 a 18 átomos de carbono que puede sustituirse. La composición de fragancia comprende, además de isopulegol, al menos dos, tal como al menos cinco, o al menos ocho componentes de perfume distintos. Puede comprender mezclas altamente complejas de componentes de perfume, escogidas para proporcionar cualquier olor deseado. El componente de perfume normalmente es un material olfativamente activo que actúa como neutralizador del mal olor, que no proporcionan necesariamente un olor agradable. Los componentes de perfume usados normalmente en el campo de la perfumería y usados para los fines de la presente invención se describen más completamente en S. Arctander, Perfume Flavors and Chemicals 1969, vol. I y II, Montclair, N. J. y en The Merck Index, 8a edición, Merck & Co., Inc. Rahway, N. J. El término componente de perfume abarca materiales de perfume que se producen de manera natural así como sintéticos conocidos para su uso en perfumes, así como aceites de origen animal. Un componente de perfume también puede ser cualquier extracto o aceite natural, o compuesto químico usado en una composición de fragancia. Los extractos y aceites naturales se describen en The Essential Oils de E Guenther publicado en 1949 por Van Nostrand y pueden incluir extractos, prensados, recogida de exudados y destilados de cualquier parte de plantas adecuadas: raíces, rizomas, bulbos, cormos, tallos, corteza, duramen, hojas, flores, semillas y fruto. Los ejemplos de tales extractos y destilados incluyen aceites de frutos cítricos tales como aceites de naranja, mandarina, pomelo, lima o limón, aceites de árboles tales como pino, o madera de cedro, aceites herbales tales como menta piperita, tomillo, lavanda, albahaca, romero, clavo o extractos de flores tales como aceite de rosa, jazmín, lirio de los valles o geranio.
Puede preferirse que cada componente de perfume tenga un peso molecular de más de 100 g/mol, preferiblemente más del 120 g/mol y de menos de 325 g/mol, preferiblemente menos de 300 g/mol. Puede preferirse además que cada componente de perfume tenga un punto de ebullición en el intervalo 80-400°C, tal como en el intervalo 100-350°C, cuando se mide a 760 mm Hg.
Ventajosamente, el componente de perfume se selecciona de la siguiente lista:
• hidrocarburos Cs-C-is, preferiblemente delta-3-careno, alfa-pineno, beta-pineno, alfa-terpineno, gammaterpineno, p-cimeno, bisaboleno, canfeno, cariofileno, cedreno, farneseno, limoneno, longifoleno, mirceno, ocimeno, valenceno, (E,Z)-1,3,5-undecatrieno;
• alcoholes alifáticos C<2>-C<18>, preferiblemente hexanol, octanol, 3-octanol, 2,6-dimetilheptanol, 2-metilheptanol, 2-metiloctanol, (E)-3-hexenol, (E) y (Z)-3-hexenol, 1-octen-3-ol, mezclas de 3,4,5,6,6-pentametil-3/4-hepten-2-ol y 3,5,6,6-tetrametil-4-metilenoheptan-2-ol, (E,Z)-2,6-nonadienol, 3,7-dimetil-7-metoxioctan-2-ol, 9-decenol, 10-undecenol, 4-metil-3-decen-5-ol;
• aldehidos alifáticos C<2>-C<18>y sus acetales, preferiblemente hexanal, heptanal, octanal, nonanal, decanal, undecanal, dodecanal, tridecanal, 2-metiloctanal, 2-metilnonanal, (E)-2-hexenal, (Z)-4-heptenal, 2,6-dimetil-5-heptenal, 10-undecenal, (E)-4-decenal, 2-dodecenal, 2,6,10-trimetil-5,9-undecadienal, heptanal dietil acetal, 1,1-dimetoxi-2,2,5-trimetil-4-hexeno, oxiacetaldehído de citronelilo;
• cetonas alifáticas C<3>-C<18>y oximas de las mismas, preferiblemente 2-heptanona, 2-octanona, 3-octanona, 2-nonanona, 5-metil-3-heptanona, oxima de 5-metil-3-heptanona, 2,4,4,7-tetrametil-6-octen-3-ona;
• compuestos que contienen azufre alifáticos C<2>-C<18>, preferiblemente 3-metiltiohexanol, acetato de 3-metiltiohexilo, 3-mercaptohexanol, acetato de 3-mercaptohexilo, butirato de 3-mercaptohexilo, acetato de 3-acetiltiohexilo, 1-menteno-S-tiol;
• compuestos que contienen nitrilos alifáticos C<2>-C<18>, preferiblemente 2-nonenonitrilo, 2-tridecenenonitrilo, 2,12-trideceneno-nitrilo, 3,7-dimetil-2,6-octadienonitrilo, 3,7-dimetil-6-octenonitrilo;
• ácidos carboxílicos alifáticos C<2>-C<18>y ésteres de los mismos, preferiblemente formiato de (E)- y (Z)-3-hexenilo, acetoacetato de etilo, acetato de isoamilo, acetato de hexilo, acetato de 3,5,5-trimetilhexilo, acetato de 3-metil-2-butenilo, acetato de (E)-2-hexenilo, acetato de (E)- y (Z)-3-hexenilo, acetato de octilo, acetato de 3-octilo, acetato de 1-octen-3-ilo, butirato de etilo, butirato de butilo, butirato de isoamilo, butirato de hexilo, isobutirato de (E)- y (Z)-3-hexenilo, crotonato de hexilo, isovalerato de etilo, 2-metilpentanoato de etilo, hexanoato de etilo, hexanoato de alilo, heptanoato de etilo, heptanoato de alilo, octanoato de etilo, (E,Z)-2,4-decadienoato de etilo, 2-octinoato de metilo, 2-noninoato de metilo, alil-2-isoamiloxiacetato, metil-3,7-dimetil-2,6-octadienoato;
• alcoholes de terpeno acíclicos C<4>-C<18>, preferiblemente citronelol, geraniol, nerol, linalool, lavandulol, nerolidol, farnesol, tetrahidrolinalool, tetrahidrogeraniol, 2,6-dimetil-7-octen-2-ol, 2,6-dimetiloctan-2-ol, 2-metil-6-metileno-7-octen-2-ol, 2,6-dimetil-5,7-octadien-2-ol, 2,6-dimetil-3,5-octadien-2-ol, 3,7-dimetil-4,6-octadien-3-ol, 3,7-dimetil-1,5,7-octatrien-3-ol, 2,6-dimetil-2,5,7-octatrien-1-ol;
• cetonas y aldehídos de terpeno acíclicos C<4>-C<18>, preferiblemente geranial, neral, citronelal, 7-hidroxi-3,7-dimetiloctanal, 7-metoxi-3,7-dimetiloctanal, 2,6,10-trimetil-9-undecenal, geranilacetona, y los acetales de dimetilo y dietilo de geranial, neral, 7-hidroxi-3,7-dimetiloctanal;
• alcoholes de terpeno cíclicos C<4>-C<18>, preferiblemente alfa-terpineol, terpineol-4, mentan-8-ol, mentan-1-ol, mentan-7-ol, borneol, isoborneol, óxido de linalool, nopol, cedrol, ambrinol, vetiverol, guaiol;
• cetonas y aldehídos de terpeno cíclicos C<4>-C<18>, preferiblemente fenchona, alfa-ionona, beta-ionona, alfa-nmetilionona, beta-n-metilionona, alfa-isometilionona, beta-isometilionona, alfa-irona, alfa-damascona, betadamascona, beta-damascenona, delta-damascona, gamma-damascona, 1-(2,4,4-trimetil-2-ciclohexen-1-il)-2-buten-1-ona, 1,3,4,6,7,8a-hexahidro-1,1,5,5-tetrametil-2H-2,4a-metanonaftalen-8(5H)-ona, nootkatona, dihidronootkatona, alfa-sinensal, beta-sinensal, metil cedril cetona;
• alcoholes cíclicos C<4>-C<18>, preferiblemente 4-terc-butilciclohexanol, 3,3,5-trimetilciclohexanol, 3-isocampilciclohexanol, 2,6,9-trimetil-Z2,Z5,E9-ciclododecatrien-1-ol, 2-isobutil-4-metiltetrahidro-2H-piran-4oí;
• alcoholes cicloalifáticos C<4>-C<18>, preferiblemente alfa-3,3-trimetilcidohexilmetanol, 2-metil-4-(2,2,3-trimetil-3-ciclopent-1-il)butanol, 2-metil-4-(2,2,3-trimetil-3-cidopent-1-il)-2-buten-1-ol, 2-etil-4-(2,2,3-trimetil-3-cidopent-1-il)-2-buten-1-ol, 3-metil-5-(2,2,3-trimetil-3-cidopent-1-il)-pentan-2-ol, 3-metil-5-(2,2,3-trimetil-3-ciclopent-1-il)-4-penten-2-ol, 3,3-dimetil-5-(2,2,3-trimetil-3-cidopent-1-il)-4-penten-2-ol, 1-(2,2,6-trimetilciclohexil)pentan-3-ol, 1-(2,2,6-trimetilciclohexil)hexan-3-ol;
• éteres cíclicos y cicloalifáticos C<4>-C<18>, preferiblemente cedril metil éter, ciclododecil metil éter, (etoximetoxi)ciclododecano, epóxido de alfa-cedreno, 3a,6,6,9a-tetrametil-dodecahidronafto[2,1-b]furano, 3a-etil-6,6,9a-trimetildodecahidro-nafto[2,1-b]furano, 1,5,9-trimetil-13-oxabiciclo[10.1.0]trideca-4,8-dieno, óxido de rosa, 2-(2,4-dimetil-3-ciclohexen-1-il)-5-metil-5-(1-metilpropil)-1,3-dioxano;
• cetonas cíclicas C<4>-C<18>, preferiblemente 4-terc-butilciclohexanona, 2,2,5-trimetil-5-pentilciclopentanona, 2-heptilciclopentanona, 2-pentilciclopentanona, 2-hidroxi-3-metil-2-ciclopenten-1-ona, 3-metil-cis-2-penten-1-il-2-ciclopenten-1-ona, 3-metil-2-pentil-2-ciclopenten-1-ona, 3-metil-4-ciclopentadecenona, 3-metil-5-ciclopentadecenona, 3-metilciclopentadecanona, 4-(1-etoxivinil)-3,3,5,5-tetrametilciclohexanona, 4-tercpentilciclohexanona, 5-ciclohexadecen-1-ona, 6,7-dihidro-1,1,2,3,3-pentametil-4(5H)-indanona, 9-cicloheptadecen-1-ona, ciclopentadecanona, ciclohexadecanona;
• aldehídos cicloalifáticos C<4>-C<18>, preferiblemente 2,4-dimetil-3-ciclohexenocarbaldehído, 2-metil-4-(2,2,6-trimetil-ciclohexen-1-il)-2-butenal, 4-(4-hidroxi-4-metilpentil)-3-ciclohexenocarbaldehído, 4-(4-metil-3-penten-1- il)-3-ciclohexenocarbaldehído;
• cetonas cicloalifáticas C<4>-C<18>, preferiblemente 1-(3,3-dimetilciclohexil)-4-penten-1-ona, 1-(5,5-dimetil-1-ciclohexen-1-il)-4-penten-1-ona, 2,3,8,8-tetrametil-1,2,3,4,5,6,7,8-octahidro-2-naftalenil metil cetona, metil-2,6,10-trimetil-2,5,9-ciclododecatrienil cetona, terc-butil(2,4-dimetil-3-ciclohexen-1-il)cetona;
• ésteres de alcoholes cíclicos en C<4>-C<18>, preferiblemente acetato de 2-terc-butilciclohexilo, acetato de 4-tercbutil-ciclohexilo, acetato de 2-terc-pentilciclohexilo, acetato de 4-terc-pentilciclohexilo, acetato de decahidro-2- naftilo, acetato de 3-pentiltetrahidro-2H-piran-4-ilo, acetato de decahidro-2,5,5,8a-tetrametil-2-naftilo, acetato de 4,7-metano-3a,4,5,6,7,7a-hexahidro-5 o 6-indenilo, propionato de 4,7-metano-3a,4,5,6,7,7ahexahidro-5 o 6-indenilo, isobutirato de 4,7-metano-3a,4,5,6,7,7a-hexahidro-5 o 6-indenilo, acetato de 4,7-metanooctahidro-5 o 6-indenilo;
• ésteres de ácidos carboxílicos cicloalifáticos en C<4>-C<18>, preferiblemente 3-ciclohexilpropionato de alilo, ciclohexiloxiacetato de alilo, dihidrojasmonato de metilo, jasmonato de metilo, 2-hexil-3-oxociclopentanocarboxilato de metilo, 2-etil-6,6-dimetil-2-ciclohexenocarboxilato de etilo, 2,3,6,6-tetrametil-2- ciclohexenocarboxilato de etilo, 2-metil-1,3-dioxolano-2-acetato de etilo;
• hidrocarburos aromáticos C<4>-C<18>, preferiblemente estireno y difenilmetano;
• alcoholes aralifáticos C<4>-C<18>, preferiblemente alcohol bencílico, alcohol 1 -feniletílico, alcohol 2-feniletílico, 3-fenilpropanol, 2-fenilpropanol, 2-fenoxietanol, 2,2-dimetil-3-fenilpropanol, 2,2-dimetil-3-(3-metilfenil)propanol, alcohol 1,1-dimetil-2-feniletílico, 1,1-dimetil-3-fenilpropanol, 1-etil-1-metil-3-fenilpropanol, 2-metil-5-fenilpentanol, 3-metil-5-fenilpentanol, 3-fenil-2-propen-1-ol, alcohol 4-metoxibencílico, 1-(4-isopropilfenil)etanol;
• ésteres de alcoholes aralifáticos en C<4>-C<18>y ácidos carboxílicos alifáticos en C<4>-C<18>, preferiblemente acetato de bencilo, propionato de bencilo, isobutirato de bencilo, isovalerato de bencilo, acetato de 2-feniletilo, propionato de 2-feniletilo, isobutirato de 2-feniletilo, isovalerato de 2-feniletilo, acetato de 1-feniletilo, acetato de alfa-triclorometilbencilo, acetato de alfa,alfa-dimetilfeniletilo, butirato de alfa,alfadimetilfeniletilo, acetato de cinamilo, isobutirato de 2-fenoxietilo, acetato de 4-metoxibencilo;
• éteres aralifáticos C<2>-C<18>, preferiblemente 2-feniletil metil éter, 2-feniletil isoamil éter, 2-feniletil 1-etoxietil éter, dimetil acetal de fenilacetaldehído, dietil acetal de fenilacetaldehído, dimetil acetal de hidratropaldehído, glicerol acetal de fenilacetaldehído, 2,4,6-trimetil-4-fenil-1,3-dioxano, 4,4a,5,9btetrahidroindeno[1,2-d]-m-dioxina, 4,4a,5,9b-tetrahidro-2,4-dimetilindeno[1,2-d]-m-dioxina;
• aldehídos aromáticos y aralifáticos C<4>-C<18>, preferiblemente benzaldehído, fenilacetaldehído, 3-fenilpropanal, hidratropaldehído, 4-metilbenzaldehído, 4-metilfenilacetaldehído, 3-(4-etilfenil)-2,2-dimetilpropanal, 2-metil-3- (4-isopropilfenil)propanal, 2-metil-3-(4-terc-butilfenil)propanal, 3-(4-terc-butilfenil)propanal, cinamaldehído, alfa-butilcinamaldehído, alfa-amilcinamaldehído, alfa-hexilcinamaldehído, 3-metil-5-fenilpentanal, 4-metoxibenzaldehído, 4-hidroxi-3-metoxibenzaldehído, 4-hidroxi-3-etoxibenzaldehído, 3,4-metilenodioxibenzaldehído, 3,4-dimetoxibenzaldehído, 2-metil-3-(4-metoxifenil)propanal, 2-metil-3-(4-metilenodioxifenil)propanal;
• cetonas aromáticas y aralifáticas C<4>-C<18>, preferiblemente acetofenona, 4-metilacetofenona, 4-metoxiacetofenona, 4-terc-butil-2,6-dimetilacetofenona, 4-fenil-2-butanona, 4-(4-hidroxifenil)-2-butanona, 1-(2-naftalenil)etanona, benzofenona, 1,1,2,3,3,6-hexametil-5-indanil metil cetona, 6-terc-butil-1,1-dimetil-4-indanil metil cetona, 1-[2,3-dihidro-1,1,2,6-tetrametil-3-(1-metiletil)-1H-5-indenil]etanona, 5',6',7',8'-tetrahidro-3',5',5',6',8',8'-hexametil-2-acetonaftona;
• ácidos caboxílicos aromáticos y aralifáticos C<4>-C<18>y ésteres de los mismos, preferiblemente ácido fenilacético, benzoato de metilo, benzoato de etilo, benzoato de hexilo, benzoato de bencilo, fenilacetato de metilo, fenilacetato de etilo, fenilacetato de geranilo, fenilacetato de feniletilo, cinamato de metilo, cinamato de etilo, cinamato de bencilo, cinamato de feniletilo, cinamato de cinamilo, fenoxiacetato de alilo, salicilato de metilo, salicilato de isoamilo, salicilato de hexilo, salicilato de ciclohexilo, salicilato de cis-3-hexenilo, salicilato de bencilo, salicilato de feniletilo, 2,4-dihidroxi-3,6-dimetilbenzoato de metilo, 3-fenilglicidato de etilo, 3-metil-3-fenilglicidato de etilo;
• compuestos aromáticos que contienen nitrógeno en C<4>-C<18>, preferiblemente 2,4,6-trinitro- 1,3-dimetil-5-tercbutilbenceno, 3,5-dinitro-2,6-dimetil-4-terc-butilacetofenona, cinamonitrilo, 5-fenil-3-metil-2-pentenonitrilo, 5-fenil-3-metilpentanonitrilo, antranilato de metilo, N-metilantranilato de metilo, bases de Schiff de antranilato de metilo con 7-hidroxi-3,7-dimetiloctanal, 2-metil-3-(4-terc-butilfenil)propanal, 2,4-dimetil-3-ciclohexenocarbaldehído, 6-isopropilquinolina, 6-isobutilquinolina, 6-sec-butilquinolina, indol, escatol, 2-metoxi-3-isopropilpirazina, 2-isobutil-3-metoxipirazina;
• fenoles, fenil éteres y ésteres fenílicos, preferiblemente estragol, anetol, eugenol, eugenil metil éter, isoeugenol, isoeugenil metil éter, timol, carvacrol, difenil éter, beta-naftil metil éter, beta-naftil etil éter, betanaftil isobutil éter, 1,4-dimetoxibenceno, acetato de eugenilo, 2-metoxi-4-metilfenol, 2-etoxi-5-(1-propenil)fenol, fenilacetato de p-cresilo;
• compuestos heterocíclicos en C<4>-C<12>, preferiblemente 2,5-dimetil-4-hidroxi-2H-furan-3-ona, 2-etil-4-hidroxi-5-metil-2H-furan-3-ona, 3-hidroxi-2-metil-4H-piran-4-ona, 2-etil-3-hidroxi-4H-piran-4-ona;
• lactonas en C<4>-C<18>, preferiblemente 1,4-octanolida, 3-metil-1,4-octanolida, 1,4-nonanolida, 1,4-decanolida, 8-decen-1,4-olida, 1,4-undecanolida, 1,4-dodecanolida, 1,5-decanolida, 1,5-dodecanolida, 1,15-pentadecanolida, cis y trans-11-pentadecen-1,15-olida, cis- y trans-12-pentadecen-1,15-olida, 1,16-hexadecanolida, 9-hexadecen-1,16-olida, 10-oxa-1,16-hexadecanolida, 11-oxa-1,16-hexadecanolida, 12-oxa-1,16-hexadecanolida, 1,12-dodecanedioato de etileno, 1,13-tridecanedioato de etileno, cumarina, 2,3-dihidrocumarina, octahidrocumarina.
El componente de perfume presente en la composición de fragancia no contiene preferiblemente grupos funcionales ionizantes, tales como sulfonatos, sulfatos, fosfatos o iones de amonio cuaternario.
La composición de fragancia de la invención puede incluir uno o más materiales de apoyo, tales como disolventes o estabilizadores UV. Los ejemplos de disolventes adecuados incluyen hidrocarburos tales como aquellos comercializados con el nombre comercial Isopar®; éteres tales como aquellos comercializados con el nombre comercial Dowanol®; benzoato de bencilo; miristato de isopropilo; adipatos de dialquilo; succinatos de dialquilo; glutaratos de dialquilo tales como los ésteres dimetílicos comercializados con el nombre comercial Flexisolv®; ésteres de citrato, tales como citrato de trietilo y citrato de acetilo-tributilo; éster metílico de soja tal como ME-S1885 (comercializado por Peter Cremer NA); ftalato de dietilo; monoetil éter de dietilenglicol; 3-metoxi-3-metil-1-butanol; dipropilenglicol; e isopropilidenglicerol comercializados con el nombre de marca Augeo® Clean Multi. Los ejemplos de estabilizadores UV incluyen butilmetoxidibenzoilmetano; bisetilhexiloxifenolmetoxifeniltriazina; aquellos comercializados con el nombre comercial Uvinol® tales como Uvinul D50 [bis(2,4-dihidroxifenil)-metanona], Uvinul MC80 (metoxicinamato de etilhexilo) y Uvinul M40 (benzofenona-3); aquellos comercializados con el nombre comercial Parsol®, tales como Parsol® MCX (mismo producto que Uvinul MC80) y Parsol® 1789 (butilmetoxidibenzoilmetano); y aquellos comercializados con el nombre comercial Tinogard®, tales como Tinogard® TT (hidroxihidrocinamato de pentaeritritilo de tetra di-t-butilo). Cuando la composición de fragancia está contenida en un producto doméstico, la cantidad de disolvente(s) puede representar hasta el 60% en peso, tal como hasta el 50% en peso, tal como hasta el 40% en peso, del peso total del producto doméstico.
La composición de fragancia que contiene un componente de perfume además de isopulegol presenta un efecto estimulante potenciado cuando se distribuye en el aire, mediante un dispositivo dispensador de ambientador, y se inhala.
Las composiciones de fragancias de la presente invención imparten un efecto estimulante a los productos de consumo no comestibles en los que se incorporan.
En el contexto de la presente invención, un producto de consumo no comestible es un producto o dispositivo para uso doméstico generalmente en la forma en que se vende pero que excluye los productos que pueden ser ingeridos, ya sean los que se ingieren deliberadamente, como los alimentos, los aperitivos y los productos farmacéuticos y los que pueden ser ingeridos accidentalmente porque se usan en la boca, como dentífricos y colutorios.
Según la invención, el producto de consumo no comestible no comestible es un producto de lavandería. Ejemplos no limitativos de productos de lavandería incluyen detergentes para ropa líquidos y en polvo, detergentes en pastillas y barras y suavizantes para tejidos. En una realización, el producto de lavandería es un suavizante para tejidos, un acondicionador de tejidos o un detergente para ropa.
Los suavizantes y acondicionadores de tejidos incluyen específicamente tantos suavizantes líquidos convencionales de concentración activa diluidos (por ejemplo, del 2% al 8% en peso) y suavizantes líquidos de concentración activa concentrados (por ejemplo, del 10% al 40% en peso) de concentración activa líquida así como acondicionadores de tejidos que pueden contener ingredientes para proteger los colores o la forma y el aspecto de la prenda (puede hacerse referencia, por 30 ejemplo a los documentos US 6.335.315, US 5.674.832, US 5.759.990, US 5.877.145, US 5.574.179).Los detergentes para ropa, en particular los detergentes líquidos, incluyen específicamente los detergentes líquidos ligeros y detergentes líquidos de gran potencia que pueden ser líquidos multifásicos estructurados o líquidos isótropos y que pueden ser líquidos acuosos o no acuosos. Estos líquidos pueden presentarse en 35 frascos o sobres de dosis unitaria y pueden contener opcionalmente agentes blanqueadores o enzimas (puede hacerse referencia, por ejemplo, a los documentos US 5.929.022, US 5.916.862, US 5.731.278, US 5.470.507, US 5.466.802, US 5.460.752 y US 5.458.810).
El efecto estimulante del isopulegol se determinó mediante el método de CNV (Variación Contingente Negativa) tal como se describe a continuación y se resume brevemente en las figuras 1 y 2.
Se midió la CNV usando un electroencefalograma digital BIOSEMi®. Los electrodos para la medición de CNV se colocaron en Fp1, Fp2, F4, Fz, F3, T7, C3, Cz, C4, T8, P4, Pz, P3, O1, Oz, O2 según el sistema internacional 10-20, los electrodos para los lóbulos de las orejas se fijaron en electrodos indiferentes y las ondas cerebrales se registraron a una constante de tiempo de 5,0 segundos con referencia a los lóbulos de las orejas enlazados. Con el fin de comprobar los artefactos del movimiento del ojo en una onda cerebral, también se registraron los movimientos verticales y horizontales del ojo izquierdo.
La confirmación de un efecto estimulante de una muestra se llevó a cabo mediante las etapas de suministrar un estímulo de advertencia S1 (tono de 60-65 dB), seguido 2300 ms más tarde por un segundo estímulo S2 (fuente de luz). Las composiciones de fragancia de prueba se inhalaron de frascos dispuestos a unos pocos centímetros (por ejemplo, 15-20) de la nariz de los sujetos durante cada periodo de adquisición. El potencial evocado promedio se obtuvo añadiendo 20 veces o más ensayos después de restar cualquier artefacto, tal como el movimiento de los ojos, usando el software Matlab® con Toolbox EEGlab y ERPlab de código abierto. Se determinó el nivel inicial a partir de un voltaje promedio de una onda cerebral en un periodo de tiempo de 500 ms antes de S1. La evaluación de la forma de onda de la CNV se llevó a cabo según el método de Toriiet al. (op. cit.),en el que la CNV se evaluó por el área (unidad: ms x mH) de un componente temprano entre 400 ms y 1000 ms después del estímulo sonoro de advertencia (S1).
La invención se entenderá mejor a la luz de los siguientes ejemplos dados a modo de ilustración únicamente.
Ejemplo 1
Se preparó una composición de fragancia que tenía la siguiente composición.
Fragancia A
El efecto de la fragancia A, a la que se añadió isopulegol al 2% en peso, se determinó mediante el método de CNV tal como se describió anteriormente, usando un panel de 7 sujetos. Se usó la fragancia A como control. Puede observarse a partir de la figura 3 que el isopulegol potencia la actividad de CNV de la fragancia A; este potenciamiento es característico de un efecto estimulante impartido por la inclusión de isopulegol.
Ejemplo 2
Se preparó una composición de fragancia que tenía la siguiente composición.
Fragancia B
El efecto de la fragancia B se determinó mediante el método de CNV tal como se describió anteriormente, usando un panel de 17 sujetos. Se usó aire como control. Puede observarse a partir de la figura 4 que la actividad de CNV de la fragancia B es significativamente mayor que la del aire (razón media de 21%; prueba de la t p<0,05). Este efecto es característico de un efecto estimulante impartido por la inclusión de isopulegol.
Ejemplo 3
Se preparó una composición de fragancia que tenía la siguiente composición.
Fragancia C
El efecto de la fragancia C se determinó mediante el método de CNV tal como se describió anteriormente, usando un panel de 8 sujetos. Puede observarse a partir de la figura 7 que la actividad de CNV de la fragancia C es significativamente mayor que la del aire (razón media 31,9%). Este efecto es característico de un efecto estimulante impartido por la inclusión de isopulegol.
Ejemplo 4
Puede usarse la siguiente formulación de agua de colonia en el contexto de la invención (las cantidades están en porcentaje en peso).
Etanol 96 77,51%
Fragancia C 10,00%
Parsol 1789* 0,20%
EDTA 2Na** 0,001%
Agua csp
desmineralizada 100%
* Parsol® 1789 es
un absorbente UV
** Se usa EDTA
como secuestrante
Claims (9)
- REIVINDICACIONES 1. Un producto de lavandería que comprende una composición de fragancia, en la que la composición de fragancia comprende de aproximadamente 0,2%en peso a menos del 10%en peso de isopulegol, basado en el peso total de la composición de fragancia; en donde la composición de fragancia comprende, además de isopulegol, al menos dos ingredientes de perfume distintos; en donde la composición de fragancia no comprende un diéster de fórmula:donde A representa CH<2>o CH=CH, n representa un número entero de 0 a 4 cuando A es CH<2>o 1 cuando A es CH=CH, B es un residuo de alcohol que tiene de 10 a 18 átomos de carbono y que contiene un esqueleto de para-mentano, que puede sustituirse, y C es un residuo de alcohol que tiene de 6 a 18 átomos de carbono, que puede sustituirse.
- 2. El producto de lavandería según la reivindicación 1, en el que la composición de fragancia comprende desde aproximadamente el 0,2 hasta aproximadamente el 5% en peso de isopulegol, basándose en el peso total de la composición de fragancia.
- 3. El producto de lavandería según la reivindicación 1 o la reivindicación 2, en el que isopulegol es (-) isopulegol.
- 4. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es un detergente para ropa en polvo.
- 5. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es un detergente para ropa líquido.
- 6. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es una pastilla detergente.
- 7. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es una barra de detergente.
- 8. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es un suavizante para tejidos.
- 9. El producto de lavandería según cualquiera de las reivindicaciones de 1 a 3, que es un acondicionador de tejidos.
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US20070141127A1 (en) | 2005-12-15 | 2007-06-21 | The Procter & Gamble Company | Wet wipes with natural antimicrobial agents |
WO2008134212A1 (en) * | 2007-04-27 | 2008-11-06 | The Dial Company | Methods for treating fabric in a dryer |
JP5680291B2 (ja) * | 2009-10-07 | 2015-03-04 | 高砂香料工業株式会社 | 冷感剤組成物、感覚刺激剤組成物およびその使用 |
JP2012246278A (ja) | 2011-05-31 | 2012-12-13 | Takasago Internatl Corp | 精神高揚剤および精神高揚用組成物 |
US8658588B2 (en) | 2012-01-09 | 2014-02-25 | S.C. Johnson & Son, Inc. | Self-adhesive high viscosity cleaning composition |
BR112014025932A2 (pt) * | 2012-04-17 | 2017-06-20 | Unilever Nv | Composição aquosa de condicionador de tecido, método de preparação de água de enxágüe e uso de água de enxágüe preparada |
CN103655243B (zh) * | 2013-07-03 | 2017-04-05 | 广州腾康医药科技有限公司 | 清爽洗发露 |
-
2017
- 2017-02-23 EP EP18170466.9A patent/EP3388508B1/en active Active
- 2017-02-23 EP EP18171658.0A patent/EP3395933A1/en not_active Withdrawn
- 2017-02-23 ES ES17157673T patent/ES2851677T3/es active Active
- 2017-02-23 ES ES18170466T patent/ES2961747T3/es active Active
- 2017-02-23 WO PCT/JP2017/006961 patent/WO2017146183A1/en active Application Filing
- 2017-02-23 US US16/078,228 patent/US20190048285A1/en not_active Abandoned
- 2017-02-23 EP EP17157673.9A patent/EP3211064B1/en active Active
- 2017-02-23 JP JP2018532334A patent/JP2019506469A/ja active Pending
-
2021
- 2021-05-27 US US17/331,803 patent/US20210301219A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
ES2851677T3 (es) | 2021-09-08 |
EP3395933A1 (en) | 2018-10-31 |
JP2019506469A (ja) | 2019-03-07 |
EP3211064A1 (en) | 2017-08-30 |
US20190048285A1 (en) | 2019-02-14 |
EP3388508B1 (en) | 2023-08-02 |
US20210301219A1 (en) | 2021-09-30 |
WO2017146183A1 (en) | 2017-08-31 |
EP3388508A1 (en) | 2018-10-17 |
EP3211064B1 (en) | 2020-11-11 |
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