ES2627928T3 - Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos - Google Patents
Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos Download PDFInfo
- Publication number
- ES2627928T3 ES2627928T3 ES11763925.2T ES11763925T ES2627928T3 ES 2627928 T3 ES2627928 T3 ES 2627928T3 ES 11763925 T ES11763925 T ES 11763925T ES 2627928 T3 ES2627928 T3 ES 2627928T3
- Authority
- ES
- Spain
- Prior art keywords
- adducts
- alcohol
- weight
- components obtained
- catalytic components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/63—Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/632—Pretreating with metals or metal-containing compounds
- C08F4/634—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Aductos sólidos que comprenden: - MgCl2 - un alcohol ROH, donde R es un grupo hidrocarburo C1-C10, presente en una relación molar con MgCl2 comprendido entre 0,5 y 5; - un ácido carboxílico alifático que tiene de 8 a 22 átomos de carbono o su sal metálica presente en una cantidad inferior al 15% en peso, basado en el peso total del aducto.
Description
TABLA 1
- Ejemplo
- Mg % en peso Ti % en peso DIBP % en peso P50 µm Actividad kg/g Insoluble en xileno % en peso APS µm
- 10
- 18 2,9 10,6 19,1 61,1 97,3 1130
- Comp.11
- 19,4 2,9 10,8 33 60,6 97,1 1904
TABLA 2
- Ejemplo
- Preparación Características del producto
- X g
- X Tipo Mg % en peso X % en peso EtOH % en peso P50 % en peso Intervalo µm
- Comp. 12
- 10,2 57,3 69,9 1,07
- 13
- 6,05 Mg 9,8 2,37 55,2 45,5 1,20
- 14
- 6,05 Ca 9,5 2,25 56,8 63,8 1,15
- 15
- 6,05 Al3d 9,8 2,42 55,5 44,1 1,09
- 16
- 6,10 Al3t 10,2 2,18 56,0 44,2 1,28
- 17
- 6,4 Na 9,9 2,37 54,5 38,2 1,3
- 18
- 6,6 Zn 10 2,39 56,1 52,2 1,02
- 19
- 6,05 Li 9,9 2,15 57,4 49,8 0,99
- 20
- 6,7 K 10 2,77 55,9 43,1 1,14
- Mg = estearato de magnesio Ca = estearato de calcio Al3d = diestearato de monohidroxi de aluminio Al3t = estearato de aluminio Na = estearato de sodio Zn = estearato de cinc Li = estearato de litio K = estearato de potasio
TABLA 3
- Ejemplo
- Mg % en peso Ti % en peso DIBP % en peso P50 µm APS µm
- 13
- 19,8 2,7 11,3 39 1842
- 14
- 20,4 2,6 10,5 51 1865
- 15
- 19,7 3,1 11,1 41 1694
- 19
- 17,2 2,2 n/a 41 1783
- Comp. 12
- 19,2 2,5 10,2 67 2575
10
Claims (1)
-
imagen1
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10183309 | 2010-09-30 | ||
EP10183309 | 2010-09-30 | ||
US40451810P | 2010-10-05 | 2010-10-05 | |
US404518P | 2010-10-05 | ||
PCT/EP2011/066956 WO2012041944A1 (en) | 2010-09-30 | 2011-09-29 | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2627928T3 true ES2627928T3 (es) | 2017-08-01 |
Family
ID=44720890
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES11763925.2T Active ES2627928T3 (es) | 2010-09-30 | 2011-09-29 | Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos |
Country Status (9)
Country | Link |
---|---|
US (1) | US8940653B2 (es) |
EP (1) | EP2621964B1 (es) |
JP (1) | JP5745068B2 (es) |
KR (1) | KR101775317B1 (es) |
CN (1) | CN103119072B (es) |
BR (1) | BR112013006142A2 (es) |
ES (1) | ES2627928T3 (es) |
RU (1) | RU2576523C2 (es) |
WO (1) | WO2012041944A1 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2699605B1 (en) * | 2011-04-18 | 2018-05-23 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
EP2712874A1 (en) * | 2012-09-26 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
KR20170003528A (ko) | 2014-03-14 | 2017-01-09 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분들 |
WO2018161854A1 (zh) * | 2017-03-10 | 2018-09-13 | 北京利和知信科技有限公司 | 用于烯烃聚合的固体催化剂组分、催化剂及其应用 |
WO2019115610A1 (en) * | 2017-12-14 | 2019-06-20 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
IT202100029732A1 (it) * | 2021-11-24 | 2023-05-24 | Basell Poliolefine Italia Srl | Processo per la preparazione di complessi di coordinazione in forma cristallina |
CN114316102B (zh) * | 2022-01-18 | 2023-12-22 | 北京吉海川科技发展有限公司 | 一种烷氧基镁载体、聚乙烯催化剂及其制备方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5425517B2 (es) * | 1972-12-27 | 1979-08-28 | ||
DE3273399D1 (en) | 1982-02-12 | 1986-10-30 | Mitsui Petrochemical Ind | Process for producing olefin polymers |
US4612299A (en) | 1984-07-09 | 1986-09-16 | Amoco Corporation | Magnesium carboxylate supports |
JPS6162505A (ja) * | 1984-07-09 | 1986-03-31 | アモコ・コ−ポレ−シヨン | マグネシウムカルボキシレ−ト担体 |
JPS61195102A (ja) * | 1985-02-25 | 1986-08-29 | Idemitsu Kosan Co Ltd | エチレン系重合体の製造方法 |
IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
US6730627B1 (en) | 1991-07-12 | 2004-05-04 | Ecp Enichem Polimeri S.R.L. | Solid component of catalyst for the (co) polymerization of ethylene and α-olefins |
IT1251462B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine. |
ID20547A (id) * | 1997-03-29 | 1999-01-14 | Montell Technology Company Bv | Hasil adisi magnesium diklorida-alkohol, proses untuk penyediaannya dan komponen katalis yang dihasilkannya |
CN1131246C (zh) * | 2000-12-14 | 2003-12-17 | 中国石油化工股份有限公司 | 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用 |
CN1169845C (zh) | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
EP1490416B1 (en) * | 2002-03-29 | 2009-01-07 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom |
JP2005529225A (ja) * | 2002-06-13 | 2005-09-29 | バセル ポリオレフィン イタリア エス.ピー.エー. | エチレンコポリマー類の製造方法 |
BR0306437A (pt) * | 2002-09-17 | 2005-01-11 | Basell Poliolefine Spa | Adutos de dicloreto de magnésio-etanol e componentes catalìticos obtidos a partir deles |
US7427653B2 (en) * | 2002-12-18 | 2008-09-23 | Basell Poliolefine Italia S.P.A | Catalyst components for the polymerization of olefins |
CA2510254A1 (en) * | 2002-12-18 | 2004-07-01 | Basell Poliolefine Italia S.P.A. | Magnesium dichloride-based adducts and catalyst components obtained therefrom |
EP1673157B1 (en) | 2003-10-16 | 2008-05-28 | Basell Poliolefine Italia S.P.A. | Process for the continuous production of emulsions |
JP4733053B2 (ja) * | 2003-12-23 | 2011-07-27 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | マグネシウムジクロライド−エタノール付加物およびそれから得られる触媒成分 |
CN1289542C (zh) * | 2004-07-05 | 2006-12-13 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的球形催化剂组分及其催化剂 |
DE102005038282A1 (de) * | 2005-08-12 | 2007-02-22 | Basf Ag | Verfahren zur Herstellung von Copolymeren aus Isobuten und wenigstens einer vinylaromatischen Verbindung |
-
2011
- 2011-09-29 JP JP2013530726A patent/JP5745068B2/ja not_active Expired - Fee Related
- 2011-09-29 ES ES11763925.2T patent/ES2627928T3/es active Active
- 2011-09-29 US US13/876,806 patent/US8940653B2/en not_active Expired - Fee Related
- 2011-09-29 BR BR112013006142A patent/BR112013006142A2/pt not_active Application Discontinuation
- 2011-09-29 EP EP11763925.2A patent/EP2621964B1/en not_active Not-in-force
- 2011-09-29 RU RU2013120068/04A patent/RU2576523C2/ru not_active IP Right Cessation
- 2011-09-29 CN CN201180047701.5A patent/CN103119072B/zh not_active Expired - Fee Related
- 2011-09-29 WO PCT/EP2011/066956 patent/WO2012041944A1/en active Application Filing
- 2011-09-29 KR KR1020137006204A patent/KR101775317B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP2621964B1 (en) | 2017-05-17 |
CN103119072B (zh) | 2016-03-30 |
KR20130114644A (ko) | 2013-10-17 |
WO2012041944A1 (en) | 2012-04-05 |
JP5745068B2 (ja) | 2015-07-08 |
US20130197172A1 (en) | 2013-08-01 |
RU2013120068A (ru) | 2014-11-10 |
US8940653B2 (en) | 2015-01-27 |
EP2621964A1 (en) | 2013-08-07 |
KR101775317B1 (ko) | 2017-09-19 |
RU2576523C2 (ru) | 2016-03-10 |
CN103119072A (zh) | 2013-05-22 |
BR112013006142A2 (pt) | 2017-11-07 |
JP2013542278A (ja) | 2013-11-21 |
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