ES2627928T3 - Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos - Google Patents

Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos Download PDF

Info

Publication number
ES2627928T3
ES2627928T3 ES11763925.2T ES11763925T ES2627928T3 ES 2627928 T3 ES2627928 T3 ES 2627928T3 ES 11763925 T ES11763925 T ES 11763925T ES 2627928 T3 ES2627928 T3 ES 2627928T3
Authority
ES
Spain
Prior art keywords
adducts
alcohol
weight
components obtained
catalytic components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES11763925.2T
Other languages
English (en)
Inventor
Gianni Collina
Daniele Evangelisti
Benedetta Gaddi
Anna Fait
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia SRL filed Critical Basell Poliolefine Italia SRL
Application granted granted Critical
Publication of ES2627928T3 publication Critical patent/ES2627928T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/63—Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/632—Pretreating with metals or metal-containing compounds
    • C08F4/634—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00—Compounds of magnesium
    • C01F5/26—Magnesium halides
    • C01F5/30—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Aductos sólidos que comprenden: - MgCl2 - un alcohol ROH, donde R es un grupo hidrocarburo C1-C10, presente en una relación molar con MgCl2 comprendido entre 0,5 y 5; - un ácido carboxílico alifático que tiene de 8 a 22 átomos de carbono o su sal metálica presente en una cantidad inferior al 15% en peso, basado en el peso total del aducto.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
TABLA 1
Ejemplo
Mg % en peso Ti % en peso DIBP % en peso P50 µm Actividad kg/g Insoluble en xileno % en peso APS µm
10
18 2,9 10,6 19,1 61,1 97,3 1130
Comp.11
19,4 2,9 10,8 33 60,6 97,1 1904
TABLA 2
Ejemplo
Preparación Características del producto
X g
X Tipo Mg % en peso X % en peso EtOH % en peso P50 % en peso Intervalo µm
Comp. 12
10,2 57,3 69,9 1,07
13
6,05 Mg 9,8 2,37 55,2 45,5 1,20
14
6,05 Ca 9,5 2,25 56,8 63,8 1,15
15
6,05 Al3d 9,8 2,42 55,5 44,1 1,09
16
6,10 Al3t 10,2 2,18 56,0 44,2 1,28
17
6,4 Na 9,9 2,37 54,5 38,2 1,3
18
6,6 Zn 10 2,39 56,1 52,2 1,02
19
6,05 Li 9,9 2,15 57,4 49,8 0,99
20
6,7 K 10 2,77 55,9 43,1 1,14
Mg = estearato de magnesio Ca = estearato de calcio Al3d = diestearato de monohidroxi de aluminio Al3t = estearato de aluminio Na = estearato de sodio Zn = estearato de cinc Li = estearato de litio K = estearato de potasio
TABLA 3
Ejemplo
Mg % en peso Ti % en peso DIBP % en peso P50 µm APS µm
13
19,8 2,7 11,3 39 1842
14
20,4 2,6 10,5 51 1865
15
19,7 3,1 11,1 41 1694
19
17,2 2,2 n/a 41 1783
Comp. 12
19,2 2,5 10,2 67 2575
10

Claims (1)

  1. imagen1
ES11763925.2T 2010-09-30 2011-09-29 Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos Active ES2627928T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10183309 2010-09-30
EP10183309 2010-09-30
US40451810P 2010-10-05 2010-10-05
US404518P 2010-10-05
PCT/EP2011/066956 WO2012041944A1 (en) 2010-09-30 2011-09-29 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom

Publications (1)

Publication Number Publication Date
ES2627928T3 true ES2627928T3 (es) 2017-08-01

Family

ID=44720890

Family Applications (1)

Application Number Title Priority Date Filing Date
ES11763925.2T Active ES2627928T3 (es) 2010-09-30 2011-09-29 Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos

Country Status (9)

Country Link
US (1) US8940653B2 (es)
EP (1) EP2621964B1 (es)
JP (1) JP5745068B2 (es)
KR (1) KR101775317B1 (es)
CN (1) CN103119072B (es)
BR (1) BR112013006142A2 (es)
ES (1) ES2627928T3 (es)
RU (1) RU2576523C2 (es)
WO (1) WO2012041944A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2699605B1 (en) * 2011-04-18 2018-05-23 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2712874A1 (en) * 2012-09-26 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
KR20170003528A (ko) 2014-03-14 2017-01-09 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분들
WO2018161854A1 (zh) * 2017-03-10 2018-09-13 北京利和知信科技有限公司 用于烯烃聚合的固体催化剂组分、催化剂及其应用
WO2019115610A1 (en) * 2017-12-14 2019-06-20 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
IT202100029732A1 (it) * 2021-11-24 2023-05-24 Basell Poliolefine Italia Srl Processo per la preparazione di complessi di coordinazione in forma cristallina
CN114316102B (zh) * 2022-01-18 2023-12-22 北京吉海川科技发展有限公司 一种烷氧基镁载体、聚乙烯催化剂及其制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5425517B2 (es) * 1972-12-27 1979-08-28
DE3273399D1 (en) 1982-02-12 1986-10-30 Mitsui Petrochemical Ind Process for producing olefin polymers
US4612299A (en) 1984-07-09 1986-09-16 Amoco Corporation Magnesium carboxylate supports
JPS6162505A (ja) * 1984-07-09 1986-03-31 アモコ・コ−ポレ−シヨン マグネシウムカルボキシレ−ト担体
JPS61195102A (ja) * 1985-02-25 1986-08-29 Idemitsu Kosan Co Ltd エチレン系重合体の製造方法
IT1230134B (it) 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
US6730627B1 (en) 1991-07-12 2004-05-04 Ecp Enichem Polimeri S.R.L. Solid component of catalyst for the (co) polymerization of ethylene and α-olefins
IT1251462B (it) * 1991-07-12 1995-05-15 Enichem Polimeri Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene e delle alfa olefine.
ID20547A (id) * 1997-03-29 1999-01-14 Montell Technology Company Bv Hasil adisi magnesium diklorida-alkohol, proses untuk penyediaannya dan komponen katalis yang dihasilkannya
CN1131246C (zh) * 2000-12-14 2003-12-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
EP1490416B1 (en) * 2002-03-29 2009-01-07 Basell Poliolefine Italia S.r.l. Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom
JP2005529225A (ja) * 2002-06-13 2005-09-29 バセル　ポリオレフィン　イタリア　エス．ピー．エー． エチレンコポリマー類の製造方法
BR0306437A (pt) * 2002-09-17 2005-01-11 Basell Poliolefine Spa Adutos de dicloreto de magnésio-etanol e componentes catalìticos obtidos a partir deles
US7427653B2 (en) * 2002-12-18 2008-09-23 Basell Poliolefine Italia S.P.A Catalyst components for the polymerization of olefins
CA2510254A1 (en) * 2002-12-18 2004-07-01 Basell Poliolefine Italia S.P.A. Magnesium dichloride-based adducts and catalyst components obtained therefrom
EP1673157B1 (en) 2003-10-16 2008-05-28 Basell Poliolefine Italia S.P.A. Process for the continuous production of emulsions
JP4733053B2 (ja) * 2003-12-23 2011-07-27 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ マグネシウムジクロライド−エタノール付加物およびそれから得られる触媒成分
CN1289542C (zh) * 2004-07-05 2006-12-13 中国石油化工股份有限公司 用于烯烃聚合反应的球形催化剂组分及其催化剂
DE102005038282A1 (de) * 2005-08-12 2007-02-22 Basf Ag Verfahren zur Herstellung von Copolymeren aus Isobuten und wenigstens einer vinylaromatischen Verbindung

Also Published As

Publication number Publication date
EP2621964B1 (en) 2017-05-17
CN103119072B (zh) 2016-03-30
KR20130114644A (ko) 2013-10-17
WO2012041944A1 (en) 2012-04-05
JP5745068B2 (ja) 2015-07-08
US20130197172A1 (en) 2013-08-01
RU2013120068A (ru) 2014-11-10
US8940653B2 (en) 2015-01-27
EP2621964A1 (en) 2013-08-07
KR101775317B1 (ko) 2017-09-19
RU2576523C2 (ru) 2016-03-10
CN103119072A (zh) 2013-05-22
BR112013006142A2 (pt) 2017-11-07
JP2013542278A (ja) 2013-11-21

Similar Documents

Publication Publication Date Title
ES2627928T3 (es) Aductos de dicloruro de magnesio-alcohol y componentes catalíticos obtenidos
BR112014020044A8 (pt) Unidade de iluminação; método de preparação de um material luminescente particulado; e material luminescente particulado
WO2012161990A3 (en) Catalyst with an ion-modified binder
MX340553B (es) Composicion de resina de poliamida.
ES2570170T3 (es) Películas de poliéster resistentes a la hidrólisis
RU2013109393A (ru) Безилатная соль ингибитора втк
JP2016536458A5 (es)
JP2012149068A5 (es)
WO2013151593A3 (en) Post-treated sulfurized salt of an alkyl-substituted hydroxyaromatic composition
ES2532451T3 (es) Composición herbicida
MY170245A (en) Diesel fuel compositions
GB201307692D0 (en) Acid and Alkali Resistant Nickel-Chromium-Molybdenum-Copper Alloys
JP2017039858A5 (es)
BR112014031358A2 (pt) precursor para preparar um óxido de metal de transição de compósito de lítio, método para preparar o precursor, e óxido de metal de transição de compósito de lítio
MX347432B (es) Composiciones activas de antitranspirante y fabricacion de las mismas.
EA201291066A1 (ru) Композиции, поглощающие кислород
AR083880A1 (es) Aleacion de niquel-cromo-hierro-molibdeno, producto y articulo que comprenden dicha aleacion, y su uso
RU2012145084A (ru) Адъюванты-разбавители для живых вакцин от болезней свиней
MX342428B (es) Componente de catalizador solido, catalizador que comprende dicho componente solido y proceso para la (co)polimerizacion de a-olefinas.
RU2010150939A (ru) Ингибитор коррозии
EP2540693A4 (en) PARTICLE MIXED MAGNESIUM DIALCOXIDE, METHOD FOR SYNTHESIZING THE SAME, AND METHOD FOR THE USE THEREOF
JP2012062421A5 (es)
BR112012017021A2 (pt) sistemas catalisadores ziegler-natta e polímeros formados a partir destes
BR112015015083A2 (pt) método para produzir olefina
MY193114A (en) Use of a mixture of a complex ester with a monocarboxylic acid to reduce friction