ES2373300A1 - Detergent for dishwashing machine - Google Patents
Detergent for dishwashing machine Download PDFInfo
- Publication number
- ES2373300A1 ES2373300A1 ES201132005A ES201132005A ES2373300A1 ES 2373300 A1 ES2373300 A1 ES 2373300A1 ES 201132005 A ES201132005 A ES 201132005A ES 201132005 A ES201132005 A ES 201132005A ES 2373300 A1 ES2373300 A1 ES 2373300A1
- Authority
- ES
- Spain
- Prior art keywords
- detergent
- dishwashing detergent
- phosphonates
- sodium
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 34
- 238000004851 dishwashing Methods 0.000 title claims abstract description 19
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- TTZMPOZCBFTTPR-UHFFFAOYSA-N O=P1OCO1 Chemical compound O=P1OCO1 TTZMPOZCBFTTPR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 239000003352 sequestering agent Substances 0.000 claims abstract description 6
- 150000001860 citric acid derivatives Chemical class 0.000 claims abstract description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims abstract 4
- 235000002639 sodium chloride Nutrition 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- MLFIYYDKLNZLAO-UHFFFAOYSA-N 2-aminoethane-1,1-diol Chemical compound NCC(O)O MLFIYYDKLNZLAO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 13
- 229910019142 PO4 Inorganic materials 0.000 abstract description 10
- 235000021317 phosphate Nutrition 0.000 abstract description 10
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract description 10
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 235000019832 sodium triphosphate Nutrition 0.000 abstract description 2
- -1 hydroxyethyl amine Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 238000005406 washing Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/14—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Detergente para lavavajillas.Dishwasher detergent
La presente memoria descriptiva se refiere, como su título indica, a un detergente para lavavajillas, caracterizado porque comprende una mezcla de compuestos alcalinos, sales y fosfonatos utilizados como secuestrantes, en lugar de los fosfatos usados convencionalmente, siendo los fosfonatos una combinación de tetra-hexametilendiamina (metilenfosfonato), di-hidroxietilamina (metilenfosfonato), y citratos.The present specification refers to, as its title indicates, to a dishwashing detergent, characterized because it comprises a mixture of alkaline compounds, salts and phosphonates used as sequestrants, instead of phosphates conventionally used, phosphonates being a combination of tetra-hexamethylene diamine (methylene phosphonate), di-hydroxyethylamine (methylene phosphonate), and citrates
En la actualidad son ampliamente conocidos y utilizados múltiples y variados tipos de detergentes para lavavajillas que tradicionalmente han incorporado fosfatos como parte integrante de su composición, tal y como podemos encontrar recogido por ejemplo en las Patentes Europeas 2264160 "Composición detergente" y 2217401 "Composición detergente". Estos detergentes presentan el grave inconveniente de tener un alto impacto ambiental, especialmente con los ecosistemas acuáticos, por su toxicidad para con las especies animales y vegetales acuáticas, y por la duración de los restos contaminantes en el medio acuático.At present, multiple and varied types of dishwashing detergents that have traditionally incorporated phosphates as an integral part of their composition are widely known and used, as we can find, for example, in European Patents 2264160 " Detergent composition " and 2217401 "Detergent composition ". These detergents have the serious disadvantage of having a high environmental impact, especially with aquatic ecosystems, because of their toxicity to aquatic animal and plant species, and because of the duration of the contaminant remains in the aquatic environment.
Hay algunos intentos de mejorar esta situación, como se describe en las Patentes ES 2079858 "Agente de lavado" y ES 2086236 "Coadyuvantes para agentes de lavado" que utilizan zeolitas y/o silicatos en lugar de fosfatos, lo cual, a pesar de mejorar su impacto ambiental no consigue cumplir con los parámetros establecidos en la normativa para la consideración de detergente ecológico.There are some attempts to improve this situation, as described in Patents ES 2079858 " Washing agent " and ES 2086236 " Adjuvants for washing agents " using zeolites and / or silicates instead of phosphates, which, despite improving Its environmental impact fails to comply with the parameters established in the regulations for the consideration of ecological detergent.
Se han utilizado también fosfonatos en los detergentes, como por ejemplo podemos encontrar reivindicado en la Patente Europea 2228468 "Composiciones detergentes para lavar la vajilla que contienen fosfonatos que estabilizan el color", pero su uso es complementario, como estabilizador de color, y nunca sustituyen en su totalidad a los fosfatos, con lo cual siguen sin conseguir cumplir con los parámetros establecidos en la normativa para la consideración de detergente ecológico.Phosphonates have also been used in detergents, as for example we can find claimed in European Patent 2228468 " Detergent compositions for washing dishes containing phosphonates that stabilize the color ", but their use is complementary, as a color stabilizer, and never replace in its entirety to phosphates, with which they still fail to comply with the parameters established in the regulations for the consideration of ecological detergent.
Para solventar la problemática existente en la actualidad en cuanto al uso de fosfatos y sus efectos contaminantes se ha ideado el detergente para lavavajillas objeto de la presente invención, el cual utiliza una mezcla de compuestos alcalinos, sales y fosfonatos, siendo los fosfonatos una combinación de tetra-hexametilendiamina (metilenfosfonato), di-hidroxietilamina (metilenfosfonato), y citratos. Los fosfonatos son utilizados como secuestrantes, en lugar de los fosfatos usados convencionalmente.To solve the problem in the actuality regarding the use of phosphates and their contaminating effects The dishwashing detergent object of the present has been devised invention, which uses a mixture of alkaline compounds, salts and phosphonates, phosphonates being a combination of tetra-hexamethylene diamine (methylene phosphonate), di-hydroxyethylamine (methylene phosphonate), and citrates. Phosphonates are used as sequestrants, instead of conventionally used phosphates.
Este detergente para lavavajillas que se presenta aporta múltiples ventajas sobre los sistemas disponibles en la actualidad siendo la más importante que se eliminan los fosfatos/tripolifosfatos de la composición detergente, consiguiendo un impacto ambiental muy reducido, especialmente con los ecosistemas acuáticos.This dishwashing detergent that presents brings multiple advantages over the systems available in currently being the most important that the phosphates / tripolyphosphates of the detergent composition, achieving a very low environmental impact, especially with ecosystems aquatic
Otra importante ventaja es que la composición del detergente permite cumplir con los parámetros reglamentados de total de productos químicos, sustancias o mezclas prohibidas o restringidas, toxicidad para los organismos acuáticos, volumen crítico de dilución, biodegradabilidad de los compuestos orgánicos y eficacia de lavado, consiguiendo por ello la denominación de detergente ecológico EcoLabel.Another important advantage is that the composition of the detergent allows to comply with the regulated parameters of total of banned chemicals, substances or mixtures or Restricted, toxicity to aquatic organisms, volume Critical dilution, biodegradability of organic compounds and washing efficiency, thus obtaining the denomination of EcoLabel ecological detergent.
Para comprender mejor el objeto de la presente invención, en el plano anexo se ha representado una realización práctica preferencial de la fabricación de detergente para lavavajillas. En dicho plano la figura -1- muestra un diagrama de bloques simplificado del procedimiento de fabricación del detergente para lavavajillas.To better understand the purpose of this invention, an embodiment has been shown in the attached drawing preferential practice of the manufacture of detergent for dishwasher. In that plane, figure -1- shows a diagram of Simplified blocks of the detergent manufacturing process dishwashing.
El detergente para lavavajillas objeto de la presente invención, comprende, como puede apreciarse en el plano anexo, los siguientes elementos:The dishwashing detergent subject to The present invention comprises, as can be seen in the drawing Annex, the following elements:
- \bullet?
- compuestos alcalinos (1): entre un 15% y un 60% en peso,alkaline compounds (1): between 15% and 60% by weight,
- \bullet?
- sales (2): entre un 10% y un 40% en peso,salts (2): between 10% and 40% in weigh,
- \bullet?
- fosfonatos (3): entre un 1% y un 15% en peso.phosphonates (3): between 1% and a 15% by weight.
Los fosfonatos (3) son utilizados como secuestrantes y pueden ser:Phosphonates (3) are used as kidnappers and can be:
- \bullet?
- tetra-hexametilendiamina (metilenfosfonato),tetra-hexamethylene diamine (methylene phosphonate),
- \bullet?
- di-hidroxietilamina (metilenfosfonato),di-hydroxyethylamine (methylene phosphonate),
- \bullet?
- citratos,citrates,
- \bullet?
- ó una combinación de los anteriores.or a combination of previous.
Los fosfonatos (3) sustituyen a los fosfatos utilizados convencionalmente como secuestrantes, evitan las incrustaciones calcáreas y son inhibidores de corrosión. La mezcla aumenta el poder de sinergia.Phosphonates (3) replace phosphates conventionally used as sequestrants, avoid limestone inlays and are corrosion inhibitors. Mix Increase the power of synergy.
Los compuestos alcalinos (1) pueden ser:The alkaline compounds (1) can be:
- \bullet?
- hidróxido sódico,sodium hydroxide,
- \bullet?
- hidróxido potásico,potassium hydroxide,
- \bullet?
- meta silicato sódico,sodium meta silicate,
- \bullet?
- carbonato sódico,sodium carbonate,
- \bullet?
- ó una combinación de los anteriores.or a combination of previous.
El hidróxido sódico ó hidróxido potásico se utiliza para potenciar el efecto desengrasante de determinadas formulaciones de detergentes.Sodium hydroxide or potassium hydroxide is used to enhance the degreasing effect of certain detergent formulations
El silicato sódico se utiliza como inhibidor del hierro y sus diferentes sales ú óxidos tiene efecto de sinergia con los tensioactivos, manteniendo estable el ph de las soluciones.Sodium silicate is used as an inhibitor of iron and its different salts or oxides have a synergy effect with the surfactants, keeping the pH of the solutions stable.
El carbonato sódico se utiliza como coadyuvante en detergencia y para el control de ph.Sodium carbonate is used as an adjuvant in detergency and for the control of ph.
Las sales (2) pueden serThe salts (2) can be
- \bullet?
- sulfato sódico,sodium sulfate,
- \bullet?
- bicarbonato sódico,sodium bicarbonate,
- \bullet?
- cloruro sódico,sodium chloride,
- \bullet?
- ó una combinación de las anteriores.or a combination of previous.
El sulfato sódico se utiliza como regulador de ph y dispersante.Sodium sulfate is used as a regulator of Ph and dispersant.
El bicarbonato sódico aumenta el efecto desengrasante de los detergentes y ejerce efecto tampón de ph, además de contribuir al ablandamiento del agua.Baking soda increases the effect detergent degreaser and exerts a buffer effect of ph, In addition to contributing to water softening.
El cloruro sódico se utiliza en el proceso como conductor iónico.Sodium Chloride is used in the process as ionic conductor
El procedimiento de fabricación de un detergente para lavavajillas según esta invención comprende dos fases diferenciadas:The process of manufacturing a detergent for dishwashers according to this invention comprises two phases differentiated:
- \bullet?
- fase de mezclado (4): se realiza añadiendo en una mezcladora los compuestos alcalinos (1), las sales (2), y los fosfonatos (3), hasta conseguir un acabado homogéneo y con la viscosidad adecuada. Se utiliza preferentemente una mezcladora de acero inoxidable con palas de 35º de inclinación, sentido único de rotación y regulador de velocidad. mixing phase (4): it is carried out by adding in a mixer the alkaline compounds (1), the salts (2), and the phosphonates (3), until a homogeneous finish is obtained and with the appropriate viscosity. A stainless steel mixer with 35 ° tilt blades, single direction of rotation and speed regulator is preferably used.
- \bullet?
- fase de llenado (5): se realiza por gravedad en los envases a través de un dispositivo de llenado. filling phase (5): it is carried out by gravity in the containers through a filling device.
Claims (8)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201132005A ES2373300B1 (en) | 2011-12-14 | 2011-12-14 | DETERGENT FOR DISHWASHERS. |
| EP12001324.8A EP2604677A1 (en) | 2011-12-14 | 2012-02-28 | Detergent for dishwashing machine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES201132005A ES2373300B1 (en) | 2011-12-14 | 2011-12-14 | DETERGENT FOR DISHWASHERS. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2373300A1 true ES2373300A1 (en) | 2012-02-02 |
| ES2373300B1 ES2373300B1 (en) | 2012-12-20 |
Family
ID=45491990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES201132005A Expired - Fee Related ES2373300B1 (en) | 2011-12-14 | 2011-12-14 | DETERGENT FOR DISHWASHERS. |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP2604677A1 (en) |
| ES (1) | ES2373300B1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2060186T3 (en) * | 1989-07-13 | 1994-11-16 | Unilever Nv | LIQUID WHITENING COMPOSITION. |
| ES2228468T3 (en) * | 1999-09-16 | 2005-04-16 | THE PROCTER & GAMBLE COMPANY | DETERGENT COMPOSITIONS TO WASH THE DISH THAT CONTAIN PHOSPHONATES THAT STABILIZE THE COLOR. |
| EP2000460A1 (en) * | 2007-06-02 | 2008-12-10 | Dalli-Werke GmbH & Co. KG | New surfactants in detergent compositions |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH679311A5 (en) * | 1989-01-07 | 1992-01-31 | Sandoz Ag | |
| DE4106880A1 (en) | 1991-03-05 | 1992-09-10 | Henkel Kgaa | LAUNDRY DETERGENT |
| DE4228044A1 (en) | 1992-08-24 | 1994-03-03 | Henkel Kgaa | Builder for detergents |
| ES2120074T3 (en) * | 1993-11-03 | 1998-10-16 | Procter & Gamble | CONTROL OF THE PRECIPITATION OF CALCIUM CARBONATE IN AUTOMATIC DISHWASHERS. |
| US6156715A (en) * | 1997-01-13 | 2000-12-05 | Ecolab Inc. | Stable solid block metal protecting warewashing detergent composition |
| US7498158B2 (en) | 2001-05-15 | 2009-03-03 | Novozymes A/S | Alpha-amylase variant with altered properties |
| DE102005004761B4 (en) * | 2005-02-01 | 2009-04-02 | Witty Chemie Gmbh & Co. Kg | Cleaning agent for basic cleaning of items to be washed in a dishwasher and method for controlling the cleaning cycles in a dishwasher |
| US20090122389A1 (en) | 2007-11-14 | 2009-05-14 | E Ink Corporation | Electro-optic assemblies, and adhesives and binders for use therein |
| JP5032523B2 (en) | 2009-03-09 | 2012-09-26 | ジャパンスーパークォーツ株式会社 | Quartz glass crucible stopper, quartz glass crucible and method of handling the same |
| DE102009027162A1 (en) * | 2009-06-24 | 2010-12-30 | Henkel Ag & Co. Kgaa | Machine dishwashing detergent |
-
2011
- 2011-12-14 ES ES201132005A patent/ES2373300B1/en not_active Expired - Fee Related
-
2012
- 2012-02-28 EP EP12001324.8A patent/EP2604677A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2060186T3 (en) * | 1989-07-13 | 1994-11-16 | Unilever Nv | LIQUID WHITENING COMPOSITION. |
| ES2228468T3 (en) * | 1999-09-16 | 2005-04-16 | THE PROCTER & GAMBLE COMPANY | DETERGENT COMPOSITIONS TO WASH THE DISH THAT CONTAIN PHOSPHONATES THAT STABILIZE THE COLOR. |
| EP2000460A1 (en) * | 2007-06-02 | 2008-12-10 | Dalli-Werke GmbH & Co. KG | New surfactants in detergent compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2373300B1 (en) | 2012-12-20 |
| EP2604677A1 (en) | 2013-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2564231T3 (en) | Formulations, their use as or for the preparation of dishwashing agents and their preparation | |
| ES2759535T3 (en) | Hard surface cleaning composition | |
| ES2757677T3 (en) | Hard surface cleaning composition for personal contact areas | |
| ES2386637T3 (en) | Alkaline cleaner for cleaning aluminum surfaces | |
| ES2612352T3 (en) | Formulations, their use as or for the preparation of dishwashing detergents and their preparation | |
| JP2013502966A (en) | Method for removing / preventing redeposits of protein soil | |
| ZA200706561B (en) | Anti-corrosion detergent compositions and use of same in cleaning dental and medical instruments | |
| ES2612342T3 (en) | Formulations, their use as or for the preparation of dishwashing detergents and their preparation | |
| KR20040002848A (en) | Surface-active compositions | |
| ES2795108T3 (en) | Caustic-free low-temperature dishwashing detergent to reduce scale build-up | |
| US9580671B2 (en) | Intercalated bleach compositions, related methods of manufacture and use | |
| JP2023121851A (en) | Liquid detergent composition for dishwasher, and method for cleaning tableware using the same | |
| ES2795009T3 (en) | Method for treating stains on textiles | |
| ES2627545T3 (en) | Laundry detergent composition for low temperature washing | |
| ES2373300A1 (en) | Detergent for dishwashing machine | |
| WO2001065939A1 (en) | Bactericidal compositions comprising a quaternary ammonium salt | |
| JP5336160B2 (en) | Antibacterial composition | |
| US9040475B2 (en) | Intercalated bleach compositions, related methods of manufacture and use | |
| WO2013056901A1 (en) | Cleansing composition | |
| JP2016108552A (en) | Liquid detergent composition and cleaning method using the same | |
| ES2575999B1 (en) | Multifunctional solid dishwashing detergent | |
| ES2353976T3 (en) | IMPROVEMENT OF STABILITY OF WASHING AGENTS AND CLEANING LIQUIDS CONTAINING HYPOCLORITE. | |
| CN105555933B (en) | Intercalation bleach compositions, manufacture and the correlation technique used | |
| KR102046690B1 (en) | Intercalated bleach compositions, related methods of manufacture and use | |
| BR112019003193B1 (en) | COMPOSITION FOR TREATMENT OF A SURFACE, AND METHODS FOR CLEANING A SURFACE, A HARD SURFACE, A FLOOR SURFACE AND FOR DEGREASING A SURFACE |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
Ref document number: 2373300 Country of ref document: ES Kind code of ref document: B1 Effective date: 20121220 |
|
| PC2A | Transfer of patent |
Owner name: SORO GLOBAL S.A. Effective date: 20170220 |
|
| PC2A | Transfer of patent |
Owner name: ELISA SORO LEFEBVRE Effective date: 20170407 |
|
| GD2A | Contractual licences |
Effective date: 20180125 |
|
| FD2A | Announcement of lapse in spain |
Effective date: 20220426 |