ES2245600B1 - METHOD OF OBTAINING A MASS OF REINFORCEMENT FOR MARBLE PLATES AND PLATES AS GOT. - Google Patents
METHOD OF OBTAINING A MASS OF REINFORCEMENT FOR MARBLE PLATES AND PLATES AS GOT. Download PDFInfo
- Publication number
- ES2245600B1 ES2245600B1 ES200401488A ES200401488A ES2245600B1 ES 2245600 B1 ES2245600 B1 ES 2245600B1 ES 200401488 A ES200401488 A ES 200401488A ES 200401488 A ES200401488 A ES 200401488A ES 2245600 B1 ES2245600 B1 ES 2245600B1
- Authority
- ES
- Spain
- Prior art keywords
- marble
- mass
- obtaining
- reinforcement
- plates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000002787 reinforcement Effects 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000004579 marble Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 239000011505 plaster Substances 0.000 claims description 5
- 230000003014 reinforcing effect Effects 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000011398 Portland cement Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000004568 cement Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000035876 healing Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B11/00—Calcium sulfate cements
- C04B11/05—Calcium sulfate cements obtaining anhydrite, e.g. Keene's cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/26—Carbonates
- C04B14/28—Carbonates of calcium
- C04B14/285—Marble
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Método de obtención de una masa de refuerzo para placas de mármol y placas así obtenidas, que consiste en la mezcla de un ligante hidráulico, un aporte de carga inerte y al menos un aditivo, la masa resultante muestra un tiempo de curación muy reducido, se hace uso de esta masa de refuerzo para la obtención de placas de mármol de espesor reducido y alta resistencia mecánica.Method of obtaining a reinforcement mass for marble plates and plates thus obtained, consisting of the mixture of a hydraulic binder, an inert load contribution and at least one additive, the resulting mass shows a very reduced cure time, It makes use of this reinforcement mass to obtain marble plates of reduced thickness and high mechanical strength.
Description
Método de obtención de una masa de refuerzo para placas de mármol y placas así obtenidas.Method of obtaining a reinforcement mass for marble plates and plates thus obtained.
La presente invención consiste en un método de obtención de una masa de refuerzo para placas de mármol comprendiendo igualmente las placas de mármol obtenidas haciendo uso de tal refuerzo.The present invention consists of a method of obtaining a reinforcement mass for marble slabs also comprising the marble plates obtained by making use of such reinforcement.
El método de obtención de la masa de refuerzo consiste principalmente en una mezcla de un ligante hidráulico, un aporte de carga inerte, y al menos un aditivo elastomérico.The method of obtaining the reinforcement mass It consists mainly of a mixture of a hydraulic binder, a contribution of inert load, and at least one elastomeric additive.
La masa resultante muestra un tiempo de curación muy reducido frente a las masas de refuerzo empleadas habitualmente a base de cemento o yesos. Este tiempo de curación mucho más reducido redunda en tiempos de espera mucho más reducidos hasta la manipulación.The resulting mass shows a healing time very small compared to the reinforcement masses used usually based on cement or plasters. This healing time much smaller leads to much shorter wait times Until handling.
Se hace uso de esta masa de refuerzo para la obtención de placas de mármol por división consecutiva y refuerzo en la cara exterior permitiendo las características mecánicas de la masa obtener placas de mármol de espesores muy reducidos.This reinforcement mass is used for obtaining marble plates by consecutive division and reinforcement on the outer face allowing the mechanical characteristics of the mass get marble plates of very small thicknesses.
Son conocidas las prácticas de reforzar placas de mármol de espesor reducido mediante masas de mortero o mediante resinas epóxicas para manipular placas que de otra manera requerirían grosores mayores.The practices of reinforcing plates are known of marble of reduced thickness by mortar masses or by epoxy resins to manipulate plates that otherwise would require greater thicknesses.
Como ejemplo, la patente de invención con número de publicación español ES2172394 describe un procedimiento de fabricación de placas de mármol para la construcción que se obtienen a partir de los bloques de mármol extraídos de las canteras, sobre cuyas placas se fijan mediante resina de poliéster sendas planchas de poliuretano, efectuándose luego un corte de división por la mitad del grosor de la placa, con lo que resultan dos piezas de reducido grosor.As an example, the invention patent with number Spanish publication ES2172394 describes a procedure for manufacture of marble plates for construction that are obtained from the marble blocks extracted from the quarries, on whose plates are fixed using polyester resin of polyurethane, then making a division cut by the half the thickness of the plate, resulting in two pieces of reduced thickness
En la presenta invención se hace uso de materiales muy baratos, con capacidad de reutilización del polvo de corte de mármol y con tiempos de fraguado del orden de minutos para una rápida manipulación o segunda obtención de placas a partir de las anteriores.The present invention makes use of Very cheap materials, with dust reuse capability of marble cutting and setting times of the order of minutes for rapid handling or second obtaining of plates from previous.
La presente invención consiste en un método de obtención de una masa de refuerzo para placas de mármol consistente en una mezcla que es capaz de fraguar en tiempos muy reducidos y predecibles en función de los porcentajes empleados.The present invention consists of a method of obtaining a stiffening mass for consistent marble slabs in a mixture that is able to set in very short times and predictable depending on the percentages used.
La mezcla emplea un ligante hidráulico obtenido de la calcinación a bajas temperaturas de yeso natural o industrial, seguido de un rápido enfriamiento, como el comercializado como "Gypcement", una carga que principalmente estará compuesta por el polvo de mármol obtenido en el corte y que es difícil reciclado, más un aditivo.The mixture uses a obtained hydraulic binder of low temperature calcination of natural plaster or industrial, followed by rapid cooling, such as marketed as "Gypcement", a load that mainly it will be composed of the marble dust obtained in the cut and that It is difficult to recycle, plus an additive.
El aditivo utilizado en la invención disminuye los requerimientos de agua, aumentando la velocidad de curado.The additive used in the invention decreases water requirements, increasing cure speed.
De esta forma la placa de mármol se puede manipular con rapidez ya que cura antes que con otras masas de refuerzo.In this way the marble plate can be handle quickly as it heals before other masses of reinforcement.
El aditivo elastomérico utilizado en la presente invención, no se ha utilizado hasta el momento para facilitar el fraguado de masas.The elastomeric additive used herein invention, has not been used so far to facilitate the mass setting.
La carga utilizada en la mezcla es polvo de mármol que se obtienen en el corte de otras placas. Este polvo de mármol es un material inerte que aumenta el volumen de la mezcla y la abarata, ya que de no ser utilizado en la mezcla, el polvo de mármol es un residuo difícil de reciclar.The load used in the mixture is powder marble that are obtained in the cut of other plates. This powder of Marble is an inert material that increases the volume of the mixture and the abarata, since if not used in the mixture, the powder of Marble is a difficult waste to recycle.
Igualmente se puede utilizar como carga cemento Pórtland, o yeso beta con objeto de modificar el color.It can also be used as cement load Portland, or beta plaster in order to modify the color.
El método de obtención de la masa de refuerzo consiste en llevar a cabo el fraguado de una mezcla compuesta de un ligante hidráulico obtenido de la calcinación a bajas temperaturas de yeso natural o industrial, seguido de un rápido enfriamiento, como el comercializado como "Gypcement" en un porcentaje mayor que el 40% y aditivos elatoméricos en un porcentaje menor que el 7%. Igualmente se puede incorporar una carga en un porcentaje menor que el 40%.The method of obtaining the reinforcement mass it consists in carrying out the setting of a mixture composed of a hydraulic binder obtained from low temperature calcination of natural or industrial plaster, followed by rapid cooling, as marketed as "Gypcement" in a higher percentage than 40% and elastomeric additives in a percentage lower than the 7% You can also incorporate a charge in a percentage less than 40%.
La placas de mármol con la masa de refuerzo de la presente invención presentan una cara vista de mármol y una masa de refuerzo posterior, mostrando una mayor resistencia mecánica y en un menor espacio de tiempo.Marble slabs with reinforcing dough The present invention has a marble face and a mass of subsequent reinforcement, showing greater mechanical resistance and in less time.
Se complementa la presente memoria descriptiva, con un juego de gráficos, ilustrativos del ejemplo preferente y nunca limitativos de la invención.This descriptive report is complemented, with a set of graphics, illustrative of the preferred example and never limiting the invention.
La Figura 1 muestra dos gráficos donde se representa una comparación de la resistencia mecánica que presentan en función del tiempo, distintos refuerzos de placas de mármol.Figure 1 shows two graphs where represents a comparison of the mechanical resistance that they present depending on the weather, different reinforcements of marble plates.
A la vista de lo anteriormente enunciado, la presente invención consiste en un método de refuerzo para placas de mármol y la placas así obtenidas.In view of the foregoing, the The present invention consists of a reinforcement method for plates marble and the plates thus obtained.
La mezcla que presenta unas mejores proporciones mecánicas comprende:The mixture that has better proportions Mechanical includes:
En la figura 1 se muestran dos gráficos, en ambos se representan, una comparativa en cuanto a resistencia mecánica de la masa de refuerzo de la invención, del Gypcement, y de cemento Portlan. En el gráfico superior se representa horas frente a megapascales, y en el inferior minutos frente a megapascales.Figure 1 shows two graphs, in both are represented, a comparative in terms of resistance mechanics of the reinforcement mass of the invention, of the Gypcement, and of Portlan cement. The chart above represents hours in front of megapascals, and in the lower minutes in front of megapascals
En ambos gráficos se aprecia como la resistencia de la masa de refuerzo de la invención es mayor que la resistencia del Gypcement y del cemento Pórtland, lo que permite que el espesor de la placa de mármol sea menor, alargando la vida de la cantera.In both graphs it can be seen as resistance of the reinforcement mass of the invention is greater than the resistance of the Gypcement and Portland cement, which allows the thickness of the marble plate is smaller, extending the life of the quarry.
En el gráfico inferior se representa minutos frente a Megapascales con objeto de representar que la masa de refuerzo de la invención alcanza niveles de resistencia mecánica más altos en menor espacio de tiempo, así tras 60 minutos de curado la masa de refuerzo de la invención alcanza una resistencia de 5.5 Mpa frente al Gypcementen que tan solo muestra un valor de 0.5 Mpa y el Cemento Pórtland que se mantiene en cero.The graph below shows minutes versus Megapascals in order to represent that the mass of reinforcement of the invention reaches mechanical resistance levels higher in less time, so after 60 minutes of curing The reinforcement mass of the invention reaches a resistance of 5.5 Mpa versus Gypcementen that only shows a value of 0.5 Mpa and Portland Cement that remains at zero.
Esto es gracias a que la velocidad de curado de la masa de refuerzo de la invención es mucho más rápida, además de realizarse al aire sin necesidad de horno. Por esto las placas de mármol que presentan el refuerzo de la invención se pueden manipular a los 10-30 minutos de haber añadido el refuerzo a la placa, mientras que con otros refuerzo se necesita esperar aproximadamente dos horas si el secado se lleva a cabo en un horno.This is thanks to the cure speed of The reinforcement mass of the invention is much faster, in addition to Perform in the air without the need for an oven. This is why the plates of marble presenting the reinforcement of the invention can be manipulate within 10-30 minutes of adding the plate reinforcement, while with other reinforcement you need wait approximately two hours if drying takes place in an oven.
No alteran la esencialidad de esta invención variaciones en materiales, forma, tamaño y disposición de los elementos componentes, descritos de manera no limitativa, bastando ésta para proceder a su reproducción por un experto.They do not alter the essentiality of this invention variations in materials, shape, size and arrangement of component elements, described in a non-limiting manner, sufficient this one to proceed to its reproduction by an expert.
Claims (7)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200401488A ES2245600B1 (en) | 2004-06-17 | 2004-06-17 | METHOD OF OBTAINING A MASS OF REINFORCEMENT FOR MARBLE PLATES AND PLATES AS GOT. |
| PCT/ES2005/070074 WO2006000609A2 (en) | 2004-06-17 | 2005-05-30 | Method of producing a reinforcing mass for marble slabs and slabs thus produced |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES200401488A ES2245600B1 (en) | 2004-06-17 | 2004-06-17 | METHOD OF OBTAINING A MASS OF REINFORCEMENT FOR MARBLE PLATES AND PLATES AS GOT. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2245600A1 ES2245600A1 (en) | 2006-01-01 |
| ES2245600B1 true ES2245600B1 (en) | 2007-04-01 |
Family
ID=34972107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES200401488A Expired - Fee Related ES2245600B1 (en) | 2004-06-17 | 2004-06-17 | METHOD OF OBTAINING A MASS OF REINFORCEMENT FOR MARBLE PLATES AND PLATES AS GOT. |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES2245600B1 (en) |
| WO (1) | WO2006000609A2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8113911B1 (en) | 2008-11-07 | 2012-02-14 | Expecting Support | Maternity body support |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE663363A (en) * | 1964-05-01 | |||
| GB1280472A (en) * | 1968-05-14 | 1972-07-05 | Grace W R & Co | Method of preparing plaster and concrete structures |
| DE2835924A1 (en) * | 1978-08-16 | 1980-02-28 | Pelt & Hooykaas | WALL PANELING OR FLOOR PANELING |
| FR2556395A1 (en) * | 1983-12-09 | 1985-06-14 | Gerard Rittner | Method for a floor covering, as well as product, in particular topping or slab, obtained by the implementation of this method |
| US4746365A (en) * | 1985-02-19 | 1988-05-24 | Construction Products Research, Inc. | Utilization of latexes with hydraulic cement and gypsum compositions |
| AU1471500A (en) * | 1998-11-06 | 2000-05-29 | University Of Utah, The | Process and composition for latex modified rubber crumb reinforced cement |
| ES2157157B1 (en) * | 1999-04-29 | 2002-04-16 | Uralita Productos Y Servicios | PROCEDURE FOR THE OBTAINING AND REINFORCEMENT OF NATURAL STONE SHEETS OF SMALL THICKNESS. |
| FR2807424B1 (en) * | 2000-04-05 | 2002-12-13 | Energetic Ind Internat | HYDRAULIC BINDER RESULTING FROM THE MIXTURE OF A SULFATIC BINDER AND A BINDER CONTAINING THE MINERALOGIC COMPOUND C4A3S |
-
2004
- 2004-06-17 ES ES200401488A patent/ES2245600B1/en not_active Expired - Fee Related
-
2005
- 2005-05-30 WO PCT/ES2005/070074 patent/WO2006000609A2/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006000609A3 (en) | 2006-06-01 |
| WO2006000609A2 (en) | 2006-01-05 |
| ES2245600A1 (en) | 2006-01-01 |
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