ES2216030T3 - Catalizadores para la oxicloracion de etileno, metodo para su preparacion y metodo de oxicloracion con el empleo de estos. - Google Patents

Catalizadores para la oxicloracion de etileno, metodo para su preparacion y metodo de oxicloracion con el empleo de estos.

Info

Publication number: ES2216030T3
Authority: ES; Spain
Prior art keywords: catalysts; holes; granules; catalyst; accordance
Prior art date: 1995-11-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES96118468T

Other languages

English (en)

Spanish (es)

Inventor

Luigi Cavalli

Carlo Rubini

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sued Chemie MT SRL

Original Assignee

Sued Chemie MT SRL

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-11-21

Filing date

1996-11-18

Publication date

2004-10-16

1996-11-18 Application filed by Sued Chemie MT SRL filed Critical Sued Chemie MT SRL

2004-10-16 Application granted granted Critical

2004-10-16 Publication of ES2216030T3 publication Critical patent/ES2216030T3/es

2016-11-18 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 14
239000005977 Ethylene Substances 0.000 title claims abstract description 14
238000000034 method Methods 0.000 title claims description 14
238000002360 preparation method Methods 0.000 title claims description 5
239000008187 granular material Substances 0.000 claims abstract description 42
230000015572 biosynthetic process Effects 0.000 claims abstract description 13
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims abstract description 11
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims abstract description 9
239000000314 lubricant Substances 0.000 claims abstract description 8
238000005461 lubrication Methods 0.000 claims abstract description 7
239000003054 catalyst Substances 0.000 claims description 59
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
239000011148 porous material Substances 0.000 claims description 10
239000000843 powder Substances 0.000 claims description 9
239000002245 particle Substances 0.000 claims description 7
230000006835 compression Effects 0.000 claims description 4
238000007906 compression Methods 0.000 claims description 4
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 9
239000007789 gas Substances 0.000 description 7
238000009826 distribution Methods 0.000 description 5
239000001103 potassium chloride Substances 0.000 description 4
235000011164 potassium chloride Nutrition 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
235000021355 Stearic acid Nutrition 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
238000009792 diffusion process Methods 0.000 description 3
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 description 3
229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
238000001354 calcination Methods 0.000 description 2
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
229960003750 ethyl chloride Drugs 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
239000010687 lubricating oil Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000012495 reaction gas Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000008117 stearic acid Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
238000004438 BET method Methods 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
229940063655 aluminum stearate Drugs 0.000 description 1
OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229940091250 magnesium supplement Drugs 0.000 description 1
239000000463 material Substances 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000003921 oil Substances 0.000 description 1
238000013021 overheating Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000010702 perfluoropolyether Substances 0.000 description 1
-1 polytetrafluoroethylene Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
229940114930 potassium stearate Drugs 0.000 description 1
239000000047 product Substances 0.000 description 1
230000003763 resistance to breakage Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
238000005245 sintering Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/122—Halides of copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

ES96118468T 1995-11-21 1996-11-18 Catalizadores para la oxicloracion de etileno, metodo para su preparacion y metodo de oxicloracion con el empleo de estos. Expired - Lifetime ES2216030T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT95MI002396A IT1276155B1 (it)	1995-11-21	1995-11-21	Catalizzatori per l'ossiclorurazione dell'etilene,procedimento per la loro preparazione e procedimento di ossiclorurazione impiegante gli
ITMI952396		1995-11-21

Publications (1)

Publication Number	Publication Date
ES2216030T3 true ES2216030T3 (es)	2004-10-16

Family

ID=11372559

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES96118468T Expired - Lifetime ES2216030T3 (es)	1995-11-21	1996-11-18	Catalizadores para la oxicloracion de etileno, metodo para su preparacion y metodo de oxicloracion con el empleo de estos.

Country Status (23)

Country	Link
US (1)	US5905054A (it)
EP (1)	EP0775522B1 (it)
JP (1)	JPH09173851A (it)
KR (1)	KR100451661B1 (it)
AR (1)	AR004622A1 (it)
AT (1)	ATE262377T1 (it)
AU (1)	AU707979B2 (it)
BR (1)	BR9605653A (it)
CA (1)	CA2190704C (it)
CZ (1)	CZ290522B6 (it)
DE (1)	DE69631937T2 (it)
DK (1)	DK0775522T3 (it)
ES (1)	ES2216030T3 (it)
HR (1)	HRP960543B1 (it)
IL (1)	IL119631A (it)
IT (1)	IT1276155B1 (it)
MA (1)	MA24010A1 (it)
MX (1)	MX9605742A (it)
NO (1)	NO314293B1 (it)
PL (1)	PL317089A1 (it)
TR (1)	TR199600926A2 (it)
YU (1)	YU62296A (it)
ZA (1)	ZA969660B (it)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1282267B1 (it) *	1995-03-14	1998-03-16	Montecatini Tecnologie Srl	Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura
EP0931587A1 (en) *	1998-01-08	1999-07-28	Evc Technology Ag	Catalyst, process for its preparation, and its use in the synthesis of 1,2-dichloroethane
GB9807131D0 (en) *	1998-04-03	1998-06-03	Ici Plc	Copper-containing materials
IT1306194B1 (it) *	1999-01-08	2001-05-30	Sued Chemie Mt Srl	Catalizzatori per reazioni esotermiche su letto fisso.
DE69918672T2 (de) *	1999-05-21	2005-07-21	Evc Technology Ag	Katalysator und Oxychlorinierungsverfahren unter Verwendung derselben
DE10003510A1 (de) *	2000-01-27	2001-08-02	Basf Ag	Verfahren zur Herstellung von 1,2-Dichlorethan
DE10009017A1 (de) *	2000-02-25	2001-09-06	Basf Ag	Geformte Katalysatoren
EA015014B1 (ru) *	2005-05-12	2011-04-29	Солвей (Сосьете Аноним)	Катализатор оксихлорирования и способ, использующий такой катализатор
TW200719968A (en)	2005-10-31	2007-06-01	Sued Chemie Ag	Catalyst molding for partial oxidation reactions
JP4943307B2 (ja) *	2007-11-27	2012-05-30	日揮触媒化成株式会社	オキシクロリネーション用触媒の製造方法
ITMI20082333A1 (it) *	2008-12-29	2010-06-30	Sud Chemie Catalysts Italia S R L	Precursori di catalizzatori di ossiclorurazione dell'etilene a dicloroetano.
TWI642481B (zh) *	2013-07-17	2018-12-01	東楚股份有限公司	Catalyst system for the production of heterogeneous catalysts and 1,2-dichloroethane
JP2015098443A (ja) *	2013-11-18	2015-05-28	東ソー株式会社	１，２−ジクロロエタンの製造用触媒システム及びそれを用いた１，２−ジクロロエタンの製造方法
RU2722157C1 (ru)	2015-07-22	2020-05-27	Басф Корпорейшн	Катализаторы с высокой геометрической площадью поверхности для получения винилацетатного мономера
RU2677875C1 (ru) *	2017-12-18	2019-01-22	Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН)	Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира и воздуха

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH628572A5 (de) *	1977-04-20	1982-03-15	Thomae Gmbh Dr K	Verfahren zum bespruehen der verdichtungswerkzeuge von maschinen zur herstellung von formlingen.
DE2932069A1 (de) *	1979-08-08	1981-03-26	Dr. Karl Thomae Gmbh, 88400 Biberach	Verfahren zum beschichten von formwerkzeugen mittels diskreter troepfchen fluessiger oder suspendierter schmiermittel bei der herstelllung von formlingen im pharma-, lebensmittel- oder katalysatorenbereich
US4441990A (en) *	1982-05-28	1984-04-10	Mobil Oil Corporation	Hollow shaped catalytic extrudates
US4460699A (en) *	1982-08-04	1984-07-17	Conoco Inc.	Fixed bed catalyst for oxychlorination
DE3607449A1 (de) *	1986-03-07	1987-09-10	Basf Ag	Geformter traegerkatalysator und dessen verwendung bei der oxichlorierung von ethylen
US4738934A (en) *	1986-05-16	1988-04-19	American Telephone And Telegraph Company, At&T Bell Laboratories	Method of making indium phosphide devices
DE4018512A1 (de) *	1990-06-09	1991-12-12	Wacker Chemie Gmbh	Zylindrisch geformter katalysator und dessen verwendung bei der oxichlorierung von ethylen
US5292703A (en) *	1992-07-28	1994-03-08	The Geon Company	Catalyst and process for oxychlorination of ethylene to EDC
IT1256156B (it) *	1992-10-06	1995-11-29	Montecatini Tecnologie Srl	Catalizzatore in granuli particolarmente per la deidrogenazione ossidativa di metanolo a formaldeide
IT1274033B (it) *	1994-04-05	1997-07-14	Montecatini Tecnologie Srl	Catalizzatore in granuli per la sintesi di 1-2 dicloroetano e preprocedimento di ossiclorurazione a letto fisso dell'etilene che utilizza tale catalizzatore.
IT1282267B1 (it) *	1995-03-14	1998-03-16	Montecatini Tecnologie Srl	Catalizzatori e supporti per catalizzatori ottenuti per pastigliatura

1995
- 1995-11-21 IT IT95MI002396A patent/IT1276155B1/it active IP Right Grant
1996
- 1996-11-12 CZ CZ19963323A patent/CZ290522B6/cs not_active IP Right Cessation
- 1996-11-15 JP JP8305233A patent/JPH09173851A/ja active Pending
- 1996-11-15 MA MA24396A patent/MA24010A1/fr unknown
- 1996-11-15 HR HR960543A patent/HRP960543B1/xx not_active IP Right Cessation
- 1996-11-18 EP EP96118468A patent/EP0775522B1/en not_active Expired - Lifetime
- 1996-11-18 IL IL11963196A patent/IL119631A/xx not_active IP Right Cessation
- 1996-11-18 ES ES96118468T patent/ES2216030T3/es not_active Expired - Lifetime
- 1996-11-18 AT AT96118468T patent/ATE262377T1/de not_active IP Right Cessation
- 1996-11-18 DK DK96118468T patent/DK0775522T3/da active
- 1996-11-18 DE DE69631937T patent/DE69631937T2/de not_active Expired - Fee Related
- 1996-11-19 CA CA002190704A patent/CA2190704C/en not_active Expired - Fee Related
- 1996-11-19 US US08/751,812 patent/US5905054A/en not_active Expired - Lifetime
- 1996-11-19 ZA ZA969660A patent/ZA969660B/xx unknown
- 1996-11-19 KR KR1019960055426A patent/KR100451661B1/ko not_active IP Right Cessation
- 1996-11-20 AU AU71894/96A patent/AU707979B2/en not_active Ceased
- 1996-11-20 AR ARP960105251A patent/AR004622A1/es active IP Right Grant
- 1996-11-20 PL PL96317089A patent/PL317089A1/xx unknown
- 1996-11-20 NO NO19964933A patent/NO314293B1/no not_active IP Right Cessation
- 1996-11-21 YU YU62296A patent/YU62296A/sh unknown
- 1996-11-21 BR BR9605653A patent/BR9605653A/pt not_active Application Discontinuation
- 1996-11-21 TR TR96/00926A patent/TR199600926A2/xx unknown
- 1996-11-21 MX MX9605742A patent/MX9605742A/es unknown

Also Published As

Publication number	Publication date
AU707979B2 (en)	1999-07-22
DK0775522T3 (da)	2004-05-10
CZ332396A3 (en)	1997-06-11
YU62296A (sh)	1998-12-23
ATE262377T1 (de)	2004-04-15
HRP960543B1 (en)	2002-02-28
CA2190704C (en)	2002-03-19
AU7189496A (en)	1997-05-29
ITMI952396A1 (it)	1997-05-21
HRP960543A2 (en)	1997-12-31
CZ290522B6 (cs)	2002-08-14
TR199600926A2 (xx)	1998-03-21
NO314293B1 (no)	2003-03-03
CA2190704A1 (en)	1997-05-22
KR100451661B1 (ko)	2004-11-20
IL119631A (en)	2000-06-29
BR9605653A (pt)	1998-08-18
DE69631937D1 (de)	2004-04-29
AR004622A1 (es)	1998-12-16
KR970025710A (ko)	1997-06-24
MX9605742A (es)	1997-05-31
US5905054A (en)	1999-05-18
IT1276155B1 (it)	1997-10-27
JPH09173851A (ja)	1997-07-08
MA24010A1 (fr)	1997-07-01
NO964933L (no)	1997-05-22
DE69631937T2 (de)	2005-02-03
EP0775522A1 (en)	1997-05-28
EP0775522B1 (en)	2004-03-24
ZA969660B (en)	1997-06-10
ITMI952396A0 (it)	1995-11-21
PL317089A1 (en)	1997-05-26
IL119631A0 (en)	1997-02-18
NO964933D0 (no)	1996-11-20

Publication	Publication Date	Title
ES2216030T3 (es)	2004-10-16	Catalizadores para la oxicloracion de etileno, metodo para su preparacion y metodo de oxicloracion con el empleo de estos.
ES2200091T3 (es)	2004-03-01	Catalizadores para la deshidrogenacion del etilbenceno en estireno.
US6518220B2 (en)	2003-02-11	Shaped catalysts
ES2259441T3 (es)	2006-10-01	Catalizadores obtenidos en forma de comprimidos.
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