ES2187073T3 - Procedimiento para la preparacion de compuestos 1,3-dicarbonilicos acilados. - Google Patents

Procedimiento para la preparacion de compuestos 1,3-dicarbonilicos acilados.

Info

Publication number
ES2187073T3
ES2187073T3 ES98954618T ES98954618T ES2187073T3 ES 2187073 T3 ES2187073 T3 ES 2187073T3 ES 98954618 T ES98954618 T ES 98954618T ES 98954618 T ES98954618 T ES 98954618T ES 2187073 T3 ES2187073 T3 ES 2187073T3
Authority
ES
Spain
Prior art keywords
formula
optionally substituted
compound
dicarbonilic
acilated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98954618T
Other languages
English (en)
Inventor
Stephen Martin Brown
Thomas William Bentley
Robert Oliver Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Ltd
Original Assignee
Syngenta Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Ltd filed Critical Syngenta Ltd
Application granted granted Critical
Publication of ES2187073T3 publication Critical patent/ES2187073T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00—Preparation of sulfones; Preparation of sulfoxides
    • C07C315/04—Preparation of sulfones; Preparation of sulfoxides by reactions not involving the formation of sulfone or sulfoxide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/46—Friedel-Crafts reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/54—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of compounds containing doubly bound oxygen atoms, e.g. esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

Un procedimiento para preparar un compuesto de Fórmula (I): **fórmula** donde Q completa un anillo carbocíclico saturado de 5 ó 6 miembros, opcionalmente sustituido, y R es un fenilo opcionalmente sustituido o un cicloalquilo C3-C6 opcionalmente sustituido, procedimiento que comprende la reordenación de un compuesto de fórmula (II) **fórmula** donde Q y R son como se definieron en relación con la Fórmula (I) en un disolvente aprótico polar, aprótico dipolar o hidrocarburo aromático, en presencia de una base moderada y un compuesto de azol de fórmula (III) **fórmula** en la que A es N o CR22; B es N o CR23 y R21, R22 y R23 son, independientemente H, alquilo o arilo cuando B es CR23, R21 y R23, junto con los átomos de carbono a los que están unidos forman un anillo carbocíclico de 6 miembros y sus sales.
ES98954618T 1997-11-27 1998-11-17 Procedimiento para la preparacion de compuestos 1,3-dicarbonilicos acilados. Expired - Lifetime ES2187073T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9725135.9A GB9725135D0 (en) 1997-11-27 1997-11-27 Chemical process

Publications (1)

Publication Number Publication Date
ES2187073T3 true ES2187073T3 (es) 2003-05-16

Family

ID=10822758

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98954618T Expired - Lifetime ES2187073T3 (es) 1997-11-27 1998-11-17 Procedimiento para la preparacion de compuestos 1,3-dicarbonilicos acilados.

Country Status (19)

Country Link
US (1) US6218579B1 (es)
EP (1) EP1034159B1 (es)
JP (1) JP4384353B2 (es)
KR (1) KR100558626B1 (es)
CN (1) CN1116266C (es)
AT (1) ATE231483T1 (es)
AU (1) AU1167199A (es)
BR (1) BR9815026B1 (es)
CA (1) CA2295892C (es)
DE (1) DE69810962T2 (es)
DK (1) DK1034159T3 (es)
ES (1) ES2187073T3 (es)
GB (1) GB9725135D0 (es)
HU (1) HUP0004664A3 (es)
IL (1) IL134635A (es)
IN (1) IN191500B (es)
PT (1) PT1034159E (es)
TW (1) TW528747B (es)
WO (1) WO1999028282A1 (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6809206B2 (en) 1999-02-12 2004-10-26 E. I. Du Pont De Nemours And Company Method for acylating cyclic compounds
ATE268116T1 (de) * 2000-09-08 2004-06-15 Syngenta Participations Ag Mesotrion-formulierungen
US7285678B2 (en) * 2001-03-26 2007-10-23 Syngenta Limited Purification of 2-nitro-4-methylsulphonylbenzoic acid
AUPR484201A0 (en) * 2001-05-08 2001-05-31 Bioprospect Limited Pesticidal compositions
DE10209645A1 (de) * 2002-03-05 2003-09-18 Bayer Cropscience Ag Substituierte Arylketone
TWI348999B (en) 2003-10-02 2011-09-21 Syngenta Participations Ag Process
GB0323090D0 (en) * 2003-10-02 2003-11-05 Syngenta Participations Ag Novel process
GB0406894D0 (en) * 2004-03-26 2004-04-28 Syngenta Participations Ag Process
GB0419075D0 (en) 2004-08-26 2004-09-29 Syngenta Participations Ag Process
EP1795674A1 (en) * 2004-12-08 2007-06-13 Matsushita Electric Industrial Co., Ltd. Door handle device, door member with the door handle device, and smart entry system with the door member
US7856033B2 (en) * 2006-11-14 2010-12-21 Lantiq Deutschland Gmbh Methods and systems for adaptive communication
CN100537530C (zh) * 2007-06-08 2009-09-09 浙江工业大学 一种磺草酮的合成方法
CN103965084A (zh) * 2014-05-14 2014-08-06 江苏常隆农化有限公司 硝草酮的生产方法
WO2015194424A1 (ja) * 2014-06-16 2015-12-23 イハラケミカル工業株式会社 トリケトン化合物の製造方法
GB2530838B (en) 2015-06-08 2020-01-22 Rotam Agrochem Int Co Ltd Process for purifying mesotrione
US20170327454A1 (en) * 2016-05-13 2017-11-16 Sirrus, Inc. High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
CN106748919A (zh) * 2016-11-11 2017-05-31 湖北广富林生物制剂有限公司 一种硝磺草酮的合成工艺
CN106565557A (zh) * 2016-11-11 2017-04-19 湖北广富林生物制剂有限公司 一种2‑硝基‑4‑甲磺酰基苯甲酰氯的合成工艺
CN106565561A (zh) * 2016-11-11 2017-04-19 湖北广富林生物制剂有限公司 一种2‑硝基‑4‑甲磺酰基苯甲酰氯的合成工艺
CN106565560A (zh) * 2016-11-11 2017-04-19 湖北广富林生物制剂有限公司 一种硝磺草酮的合成工艺
CN106565558A (zh) * 2016-11-11 2017-04-19 湖北广富林生物制剂有限公司 一种2‑硝基‑4‑甲磺酰基苯甲酰氯的合成工艺
CN108440352B (zh) * 2018-03-30 2020-04-14 江苏丰山集团股份有限公司 一种硝磺草酮的制备方法
CN113845450A (zh) * 2020-06-28 2021-12-28 沈阳中化农药化工研发有限公司 一种硝磺草酮及其同系物的合成方法
CN113943235B (zh) * 2020-07-17 2022-06-14 沈阳中化农药化工研发有限公司 一种制备硝磺草酮除草剂的方法
CN115784949A (zh) * 2022-12-08 2023-03-14 江苏扬农化工股份有限公司 一种三酮类化合物的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3025219A1 (de) * 1980-07-03 1982-01-28 Bayer Ag, 5090 Leverkusen Benzoyl-azole, verfahren zu ihrer herstellung sowie ihre verwendung als fungizide
US4780127A (en) * 1982-03-25 1988-10-25 Stauffer Chemical Company Certain 2-(substituted benzoyl)-1,3-cyclohexanediones and their use as herbicides
US4806146A (en) * 1984-12-20 1989-02-21 Stauffer Chemical Company Certain 2-(2-substituted benzoyl)-1,3-cyclohexanediones
US4695673A (en) * 1985-11-20 1987-09-22 Stauffer Chemical Company Process for the production of acylated 1,3-dicarbonyl compounds
JPS62185034A (ja) * 1986-02-12 1987-08-13 Nippon Soda Co Ltd 固定化触媒によるシクロヘキサンジオン誘導体の製造方法
DE3604871A1 (de) * 1986-02-15 1987-08-20 Basf Ag Cyclohexenonderivate, verfahren zu ihrer herstellung und ihre verwendung als mittel zur regulierung des pflanzenwachstums
US6096930A (en) * 1994-08-18 2000-08-01 Korea Research Institute Of Chemical Technology Herbicidal cyclohexane-1,3-dione derivatives and their preparation process
GB9501433D0 (en) 1995-01-25 1995-03-15 Zeneca Ltd Chemical process
GB9501434D0 (en) * 1995-01-25 1995-03-15 Zeneca Ltd Chemical process

Also Published As

Publication number Publication date
US6218579B1 (en) 2001-04-17
IL134635A0 (en) 2001-04-30
JP4384353B2 (ja) 2009-12-16
PT1034159E (pt) 2003-06-30
EP1034159A1 (en) 2000-09-13
DK1034159T3 (da) 2003-05-05
CA2295892A1 (en) 1999-06-10
CA2295892C (en) 2008-02-05
KR100558626B1 (ko) 2006-03-13
AU1167199A (en) 1999-06-16
EP1034159B1 (en) 2003-01-22
IN191500B (es) 2003-12-06
TW528747B (en) 2003-04-21
WO1999028282A1 (en) 1999-06-10
HUP0004664A2 (hu) 2001-05-28
IL134635A (en) 2005-08-31
DE69810962D1 (de) 2003-02-27
DE69810962T2 (de) 2004-01-08
GB9725135D0 (en) 1998-01-28
KR20010032495A (ko) 2001-04-25
ATE231483T1 (de) 2003-02-15
HUP0004664A3 (en) 2002-02-28
CN1116266C (zh) 2003-07-30
BR9815026A (pt) 2000-10-03
BR9815026B1 (pt) 2009-12-01
JP2001524539A (ja) 2001-12-04
CN1272837A (zh) 2000-11-08

Similar Documents

Publication Publication Date Title
ES2187073T3 (es) Procedimiento para la preparacion de compuestos 1,3-dicarbonilicos acilados.
ES2188016T3 (es) Derivaqdo de benzamidoxima, productos intermedios y procedimiento para su obtencion y su empleo como fungicidas.
ES537677A0 (es) Procedimiento para preparar una 1h-imidazo (4, 5-c) quinolin-4-amina
AR004180A1 (es) Nuevos derivados de pirimidona con actividad antifungica y procedimiento para preparar los mismos.
SE8302464L (sv) Aromatiskt alkanderivat samt sett for framstellning derav
ES2154470T3 (es) Derivados de tetrahidroisoquinolina y su uso farmaceutico.
ES2078267T3 (es) H-heteroaril-purin-6-aminas, un procedimiento para su preparacion y su uso como medicamentos.
ES520526A0 (es) Procedimiento para la obtencion de derivados de piridina.
CO4520306A1 (es) Nuevos pirimido (1,2-a) indoles
AR245699A1 (es) Compuestos derivados de n'-alquil-n,n'-diacilhidrazinas insecticidamente activos y composicion que los comprende.
CO4771143A1 (es) Agentes insecticidas y acaricidas de 1,4-diaril-2-fluoro-2- buteno y proceso para su preparacion
ES2174034T3 (es) Naftilglioxamidas como inhibidores de spla2
ES2055804T3 (es) Procedimiento de preparacion de nuevas meta-fenilendiaminas sustituidas con trialcoxi.
ES498960A0 (es) Procedimiento para preparar esteres de 2-nitro-5-fenoxi sustituido)benzoato de alfa-hidroxialcanoatos
ES455909A1 (es) Procedimiento para preparar derivados de piperacina.
ES490652A0 (es) Procedimiento de preparacion de esteres de derivados de la aletrolona y de acidos ciclopropeno-carboxilicos
ES454824A1 (es) Procedimiento para la preparacion de derivados de imidazo (1,2-a) piridina.
DK392579A (da) Fremgangsmaade til fremstilling af 4,5-methano-bufadienolid-rhamnosider
AR006675A1 (es) 4-benzoilisotiazoles herbicidas, procedimiento para obtenerlas, las composiciones herbicidas que las contienen y el procedimiento de aplicacionde dichos compuestos.
WO2002072540A3 (en) Improved methods of ortho alkylation
ES531619A0 (es) Procedimiento para la obtencion de fenetil-sulfenamidas n-sulfeniladas
ES2062223T3 (es) Derivados de imidazol, procedimiento para la preparacion de los mismos y agentes antiulcera que los contienen.
ATE27955T1 (de) Verfahren und zwischenprodukte zur herstellung von 2-substituierten 4-acetyl-imidazolen.
ES551489A0 (es) Procedimiento para la obtencion de 5-sulfonamido-1-aril-pirazoles.
MX9203518A (es) 9-amino-2-fenilbiciclo [3.3.1] nonanos y 9-amino-2-fenilbiciclo [3.3.1] non-2-enos y drogas que los contienen.