ES2186267T3 - Procedimiento para la hidrogenacion en fase liquida selectiva de compuestos de carbonilo alfa,beta-insaturados. - Google Patents

Procedimiento para la hidrogenacion en fase liquida selectiva de compuestos de carbonilo alfa,beta-insaturados.

Info

Publication number
ES2186267T3
ES2186267T3 ES99105126T ES99105126T ES2186267T3 ES 2186267 T3 ES2186267 T3 ES 2186267T3 ES 99105126 T ES99105126 T ES 99105126T ES 99105126 T ES99105126 T ES 99105126T ES 2186267 T3 ES2186267 T3 ES 2186267T3
Authority
ES
Spain
Prior art keywords
procedure
compounds
hydrogen
liquid phase
hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99105126T
Other languages
English (en)
Inventor
Franz Josef Dr Brocker
Gerd Dr Kaibel
Werner Dr Aquila
Hartwig Fuchs
Gunter Dr Wegner
Manfred Stroezel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2186267T3 publication Critical patent/ES2186267T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2495—Net-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO PARA LA HIDROGENACION SELECTIVA EN FASE LIQUIDA DE COMPUESTOS DE CARBONILO DE AL , BE I NSATURADOS DE FORMULA GENERAL I, EN LA QUE R 1 ES HIDROGENO O UN RADICAL ORGANICO, R 2 , R 3 Y R 4 SON IN DEPENDIENTEMENTE UNO DEL OTRO HIDROGENO O UN GRUPO ALQUILO DE C 1 HASTA C 4 , PARA DAR COMPUESTOS SATURADOS DE CARBONILO II CON HIDROGENO EN PRESENCIA DE UN CATALIZADOR EN POLVO DE PALADIO Y/O RODIO Y DE UNA BASE ORGANICA. EL PROCEDIMIENTO SE LLEVA A CABO EN UN REACTOR EMPAQUETADO DE COLUMNAS AIREADAS (1, 2) CON RECICLADO DEL PRODUCTO (11, 17) Y GAS DE CIRCULACION QUE ES HIDROGENO (4, 15, 16). ES ESPECIALMENTE APROPIADO PARA LA HIDROGENACION SELECTIVA DEL CITRAL PARA DAR ACEITE DE CITRONELA.
ES99105126T 1998-04-02 1999-03-26 Procedimiento para la hidrogenacion en fase liquida selectiva de compuestos de carbonilo alfa,beta-insaturados. Expired - Lifetime ES2186267T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19814879A DE19814879A1 (de) 1998-04-02 1998-04-02 Verfahren zur selektiven Flüssigphasenhydrierung von alpha,beta-ungesättigten Carbonylverbindungen

Publications (1)

Publication Number Publication Date
ES2186267T3 true ES2186267T3 (es) 2003-05-01

Family

ID=7863426

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99105126T Expired - Lifetime ES2186267T3 (es) 1998-04-02 1999-03-26 Procedimiento para la hidrogenacion en fase liquida selectiva de compuestos de carbonilo alfa,beta-insaturados.

Country Status (12)

Country Link
US (1) US6150564A (es)
EP (1) EP0947493B1 (es)
JP (1) JPH11349517A (es)
KR (1) KR19990082817A (es)
CN (1) CN1234385A (es)
AT (1) ATE226930T1 (es)
DE (2) DE19814879A1 (es)
DK (1) DK0947493T3 (es)
ES (1) ES2186267T3 (es)
IL (1) IL129146A (es)
PT (1) PT947493E (es)
SI (1) SI0947493T1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10044400A1 (de) 2000-09-08 2002-04-04 Haarmann & Reimer Gmbh Verfahren zur Herstellung von Benzylaceton
US20110065129A1 (en) * 2001-07-27 2011-03-17 Lowe Derek B Indane acetic acid derivatives and their use as pharmaceutical agents, intermediates, and method of preparation
ITMI20012267A1 (it) * 2001-10-29 2003-04-29 Chemi Spa Preparazione ed uso di un catalizzatore eterogeneo per l'idrogenerazione di un doppio legame di un composto carbonilico b-insaturo
ATE378107T1 (de) * 2001-12-07 2007-11-15 Basf Ag Verfahren zur herstellung von ruthenium/eisen/kohlenstoffträger-katalysatoren
DE10160141A1 (de) 2001-12-07 2003-06-18 Basf Ag Verfahren zur selektiven Flüssiphasenhydrierung von alpha,beta-ungesättigren Carbonylverbindungen zu ungesättigten Alkoholen in Gegenwart eines Pt/ZnO-Katalysators
DE10231944A1 (de) * 2002-07-15 2004-01-29 Basf Ag Verfahren zur kontinuierlichen Hydrierung von Citral zu Citronellal
DE10231945A1 (de) * 2002-07-15 2004-01-29 Basf Ag Verfahren zur Herstellung von Tetrahydrogeranylaceton
DE10248159A1 (de) * 2002-10-16 2004-04-29 Degussa Ag Verfahren zur kontinuierlichen Hydrierung
DE10359026A1 (de) * 2003-12-15 2005-07-21 Basf Ag Verfahren zur Herstellung von Tetrahydrogeranylaceton
DE102005049568A1 (de) * 2005-10-17 2007-04-19 Basf Ag Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung
TW200802544A (en) * 2006-04-25 2008-01-01 Osram Opto Semiconductors Gmbh Composite substrate and method for making the same
DE102006061167A1 (de) * 2006-04-25 2007-12-20 Osram Opto Semiconductors Gmbh Optoelektronisches Halbleiterbauelement
CN108136386B (zh) 2015-10-05 2024-01-30 巴斯夫欧洲公司 制备钌/铁/碳载体催化剂的方法
CN108794314A (zh) * 2017-04-28 2018-11-13 山东新和成药业有限公司 一种柠檬醛加氢合成香茅醛的方法
EP3556451B1 (de) * 2018-04-20 2020-06-03 Siemens Aktiengesellschaft Verfahren zum betreiben einer reaktoranlage

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE226872C (es) *
FR2247445A1 (en) * 1973-10-12 1975-05-09 Anvar Reduction of alpha beta ethylenic ketones - by hydrogenation with a rhodium catalyst
DE2839474A1 (de) * 1978-09-11 1980-03-27 Basf Ag Verfahren zur herstellung von carbonylverbindungen
DE2934250A1 (de) * 1979-08-24 1981-03-19 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von olefinisch ungesaettigten carbonylverbindungen und alkoholen
DE2936362A1 (de) * 1979-09-08 1981-04-02 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von palladium-kohle-katalysatoren
DD226872A1 (de) * 1984-07-27 1985-09-04 Bitterfeld Chemie Verfahren zur katalytischen hydrierung in der fluessigphase
DE3602525A1 (de) * 1986-01-29 1987-07-30 Henkel Kgaa Verfahren zur kontinuierlichen heterogenkatalytischen hydrierung von fetten, fettsaeuren und fettsaeurederivaten
DE19530329A1 (de) * 1995-08-17 1997-02-20 Basf Ag Packungsmaterial für Stoffaustausch-Kolonnen und Verfahren zu dessen Herstellung
DE19611976A1 (de) * 1996-03-26 1997-10-02 Basf Ag Verfahren und Reaktor zur Durchführung von Stoffumwandlungen mit in Flüssigkeiten suspendierten Katalysatoren
DE19641707A1 (de) * 1996-10-10 1998-04-16 Basf Ag Verfahren zur Herstellung von 1,4-Butandiol durch katalytische Hydrierung von 1,4-Butindiol

Also Published As

Publication number Publication date
CN1234385A (zh) 1999-11-10
EP0947493A1 (de) 1999-10-06
JPH11349517A (ja) 1999-12-21
DE59903222D1 (de) 2002-12-05
DE19814879A1 (de) 1999-10-07
KR19990082817A (ko) 1999-11-25
SI0947493T1 (en) 2003-04-30
IL129146A (en) 2003-09-17
ATE226930T1 (de) 2002-11-15
PT947493E (pt) 2003-03-31
DK0947493T3 (da) 2002-12-30
US6150564A (en) 2000-11-21
EP0947493B1 (de) 2002-10-30
IL129146A0 (en) 2000-02-17

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