ES2166271B1 - Catalizador de oxido de silicio con contenido en titanio. - Google Patents
Catalizador de oxido de silicio con contenido en titanio.Info
- Publication number
- ES2166271B1 ES2166271B1 ES9901743A ES9901743A ES2166271B1 ES 2166271 B1 ES2166271 B1 ES 2166271B1 ES 9901743 A ES9901743 A ES 9901743A ES 9901743 A ES9901743 A ES 9901743A ES 2166271 B1 ES2166271 B1 ES 2166271B1
- Authority
- ES
- Spain
- Prior art keywords
- sup
- silicon oxide
- catalyst
- oxide catalyst
- titanium content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052814 silicon oxide Inorganic materials 0.000 title abstract 3
- 229910052719 titanium Inorganic materials 0.000 title abstract 3
- 239000010936 titanium Substances 0.000 title abstract 3
- 239000011148 porous material Substances 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- GQNOPVSQPBUJKQ-UHFFFAOYSA-N 1-hydroperoxyethylbenzene Chemical compound OOC(C)C1=CC=CC=C1 GQNOPVSQPBUJKQ-UHFFFAOYSA-N 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/643—Pore diameter less than 2 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Catalizador de óxido de silicio con contenido en titanio. Un catalizador de óxido de silicio que contiene titanio que satisface todas las condiciones (1) a (4) que se exponen a continuación: (1) Tamaño de poro medio de 10 {angstron} o más, (2) Tamaño de poro de 90% o más del volumen de poro total de 5 a 200 {angstron}, (3) Volumen de poro específico de 0,2 cm{sup,3}/g o más, y (4) Uso de un ión de amonio cuaternario representado por la siguiente fórmula general (I) como plantilla eliminándose después dicha plantilla a través de una operación de extracción con disolvente; [NR{sup,1} R{sup,2} R{sup,3} R{sup,4}]{sup,+} (I) donde, R{sup,1} representa una cadena de hidrocarburos lineal o ramificada que tiene de 2 a 36 átomos de carbono y R{sup,2} a R{sup,4} representan un grupo alquilo que tiene de 1 a 6 átomos de carbono, un método para producir dicho catalizador y un método para producir óxido de propileno por reacción de propileno con un hidroperóxido, excepto hidroperóxido de etilbenceno, en presencia de dicho catalizador.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22066598 | 1998-08-04 | ||
JP15639399A JP3788107B2 (ja) | 1998-08-04 | 1999-06-03 | チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法 |
JP15639599A JP3731384B2 (ja) | 1998-08-04 | 1999-06-03 | チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2166271A1 ES2166271A1 (es) | 2002-04-01 |
ES2166271B1 true ES2166271B1 (es) | 2003-05-01 |
Family
ID=27320997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES9901743A Expired - Fee Related ES2166271B1 (es) | 1998-08-04 | 1999-07-30 | Catalizador de oxido de silicio con contenido en titanio. |
Country Status (5)
Country | Link |
---|---|
US (2) | US6323147B1 (es) |
CN (1) | CN1140335C (es) |
ES (1) | ES2166271B1 (es) |
NL (1) | NL1012749C2 (es) |
SG (1) | SG82626A1 (es) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1171679C (zh) * | 2000-02-02 | 2004-10-20 | 住友化学工业株式会社 | 模制催化剂、制造模制催化剂的方法及制造环氧乙烷化合物的方法 |
JP4889865B2 (ja) * | 2001-01-31 | 2012-03-07 | 住友化学株式会社 | チタン含有珪素酸化物触媒の製造方法 |
JP2002239381A (ja) * | 2001-02-22 | 2002-08-27 | Sumitomo Chem Co Ltd | チタン含有珪素酸化物触媒の製造方法及び触媒 |
US6872679B2 (en) * | 2002-09-20 | 2005-03-29 | Arco Chemical Technology, L.P. | Heterogeneous catalyst regeneration |
US6712398B1 (en) * | 2002-09-20 | 2004-03-30 | Fox Bindery, Inc. | Removable insert assemblies and methods for making |
EP1403358A1 (en) * | 2002-09-27 | 2004-03-31 | ENI S.p.A. | Process and catalysts for deep desulphurization of fuels |
JP4265212B2 (ja) * | 2002-12-19 | 2009-05-20 | 住友化学株式会社 | チタン含有珪素酸化物触媒の製造方法 |
US7270742B2 (en) * | 2003-03-13 | 2007-09-18 | Lyondell Chemical Technology, L.P. | Organosulfur oxidation process |
US7193093B2 (en) * | 2003-06-30 | 2007-03-20 | Shell Oil Company | Process for producing alkylene oxide |
US7144499B2 (en) * | 2003-11-26 | 2006-12-05 | Lyondell Chemical Technology, L.P. | Desulfurization process |
US7314545B2 (en) * | 2004-01-09 | 2008-01-01 | Lyondell Chemical Technology, L.P. | Desulfurization process |
JP4834982B2 (ja) * | 2004-12-06 | 2011-12-14 | 住友化学株式会社 | チタン含有珪素酸化物触媒の製造方法及び触媒 |
WO2006062111A1 (ja) * | 2004-12-06 | 2006-06-15 | Sumitomo Chemical Company, Limited | チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いるオレフィンオキサイド化合物の製造方法 |
US7735998B2 (en) * | 2006-10-25 | 2010-06-15 | Volk Donald A | Multi-layered multifocal lens with blended refractive index |
JP4935604B2 (ja) * | 2006-11-27 | 2012-05-23 | 住友化学株式会社 | 担持酸化ルテニウムの製造方法 |
CN102807537B (zh) * | 2011-06-02 | 2014-08-06 | 中国石油化工股份有限公司 | 制备环氧丙烷的方法 |
CN102807538B (zh) * | 2011-06-02 | 2014-08-06 | 中国石油化工股份有限公司 | 一种制备环氧丙烷的方法 |
CN102872847B (zh) * | 2011-07-12 | 2014-11-26 | 中国石油化工股份有限公司 | 钛氧化硅材料的改性方法 |
CN103157450B (zh) * | 2013-04-08 | 2014-09-10 | 南开大学 | 一种功能性介孔硅球制备方法 |
CN105315233B (zh) * | 2014-07-03 | 2018-06-08 | 中国石油化工股份有限公司 | 环氧丁烷的生产方法 |
CN108349918A (zh) * | 2015-11-09 | 2018-07-31 | 国际壳牌研究有限公司 | 催化剂制备 |
US10011575B2 (en) | 2016-07-25 | 2018-07-03 | Oriental Union Chemical Corp. | Method for fabricating titanium-containing silicon oxide material and application of the same |
US10493430B2 (en) | 2016-11-28 | 2019-12-03 | Oriental Union Chemical Corp. | Method for fabricating a titanium-containing silicon oxide material with high thermal stability and applications of the same |
CN107930610B (zh) | 2017-11-29 | 2019-09-20 | 万华化学集团股份有限公司 | 一种烯烃环氧化催化剂的制备方法及由此制备的催化剂 |
JP7150476B2 (ja) * | 2018-05-25 | 2022-10-11 | 三井化学株式会社 | 結晶性多孔質チタノシリケート触媒及びその製造方法、並びに該触媒を用いたp-ベンゾキノン類の製造方法 |
US10780431B1 (en) | 2019-03-22 | 2020-09-22 | Oriental Union Chemical Corp. | Method of using biopolymer to synthesize titanium-containing silicon oxide material and applications thereof |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4367342A (en) * | 1969-04-02 | 1983-01-04 | Shell Oil Company | Olefin epoxidation |
JPS5440526B1 (es) * | 1970-10-01 | 1979-12-04 | ||
US3829392A (en) | 1970-10-01 | 1974-08-13 | Shell Oil Co | Heterogeneous catalysts for olefin epoxidation |
US3923843A (en) | 1972-03-13 | 1975-12-02 | Shell Oil Co | Epoxidation process with improved heterogeneous catalyst |
US5143879A (en) * | 1991-07-18 | 1992-09-01 | Mobil Oil Corporation | Method to recover organic templates from freshly synthesized molecular sieves |
ES2092428B1 (es) | 1993-06-15 | 1997-08-01 | Univ Valencia Politecnica | Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos. |
US5453511A (en) * | 1993-12-23 | 1995-09-26 | Arco Chemical Technology, L.P. | Bis-piperidinium compounds |
JPH07300312A (ja) * | 1994-03-09 | 1995-11-14 | Nippon Shokubai Co Ltd | メソポアチタノシリケートおよびその合成方法 |
US5795555A (en) | 1994-11-24 | 1998-08-18 | Alive; Keshavaraja | Micro-meso porous amorphous titanium silicates and a process for preparing the same |
JP3658790B2 (ja) | 1995-03-30 | 2005-06-08 | 住友化学株式会社 | 触媒及びオキシラン化合物の製造方法 |
US5622684A (en) * | 1995-06-06 | 1997-04-22 | Board Of Trustees Operating Michigan State University | Porous inorganic oxide materials prepared by non-ionic surfactant templating route |
US5723637A (en) * | 1995-12-06 | 1998-03-03 | Sumitomo Chemical Company, Limited | Process for producing propylene oxide |
US5688484A (en) | 1996-07-29 | 1997-11-18 | Arco Chemical Technology, L.P. | Non-hydrothermal method of making a titanium-containing zeolite |
DE19644348A1 (de) * | 1996-10-25 | 1998-04-30 | Degussa | Verfahren zur Herstellung von titanhaltigen Molekularsieben |
US6054112A (en) | 1996-10-25 | 2000-04-25 | Degussa-Huls Ag | Process for the preparation of titanium containing molecular sieves |
SG73663A1 (en) | 1998-08-04 | 2000-06-20 | Sumitomo Chemical Co | A process for producing propylene oxide |
ES2156506B1 (es) | 1998-10-14 | 2002-03-01 | Sumitomo Chemical Co | Metodo para la produccion de oxido de propileno. |
-
1999
- 1999-07-21 SG SG9903618A patent/SG82626A1/en unknown
- 1999-07-30 US US09/364,268 patent/US6323147B1/en not_active Expired - Lifetime
- 1999-07-30 NL NL1012749A patent/NL1012749C2/nl not_active IP Right Cessation
- 1999-07-30 ES ES9901743A patent/ES2166271B1/es not_active Expired - Fee Related
- 1999-08-02 CN CNB991116224A patent/CN1140335C/zh not_active Expired - Lifetime
-
2001
- 2001-10-02 US US09/967,982 patent/US6512128B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6323147B1 (en) | 2001-11-27 |
CN1140335C (zh) | 2004-03-03 |
US6512128B2 (en) | 2003-01-28 |
CN1247101A (zh) | 2000-03-15 |
NL1012749A1 (nl) | 2000-02-08 |
US20020037807A1 (en) | 2002-03-28 |
ES2166271A1 (es) | 2002-04-01 |
NL1012749C2 (nl) | 2000-06-06 |
SG82626A1 (en) | 2001-08-21 |
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