ES2156948T3 - Procedimiento para la (co)polimerizacion de olefinas. - Google Patents

Procedimiento para la (co)polimerizacion de olefinas.

Info

Publication number
ES2156948T3
ES2156948T3 ES95935892T ES95935892T ES2156948T3 ES 2156948 T3 ES2156948 T3 ES 2156948T3 ES 95935892 T ES95935892 T ES 95935892T ES 95935892 T ES95935892 T ES 95935892T ES 2156948 T3 ES2156948 T3 ES 2156948T3
Authority
ES
Spain
Prior art keywords
phase
polymerization
olefins
catalyst
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95935892T
Other languages
English (en)
Inventor
Gianni Collina
Occo Tiziano Dall
Maurizio Galimberti
Enrico Albizzati
Luciano Noristi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Application granted granted Critical
Publication of ES2156948T3 publication Critical patent/ES2156948T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

EL PROCESO DE VARIAS FASES PARA LA POLIMERIZACION DE UNA O MAS OLEFINAS DE LA FORMULA CH{SUB,2}=CHR, EN LA CUAL R ES HIDROGENO O UN GRUPO ALQUILO, CICLOALQUILO O ARILO QUE TENGA DE 1 A 10 ATOMOS DE CARBONO, COMPRENDIENDO: (A) UNA PRIMERA FASE DE POLIMERIZACION, EN LA CUAL UN PRIMER POLIMERO DE OLEFINA ES PREPARADO EN PRESENCIA DE UN CATALIZADOR DE TITANIO O UN CATALIZADOR DE VANADIO; (B) UNA FASE DE TRATAMIENTO EN LA CUAL EL CATALIZADOR USADO PREVIAMENTE ES DESACTIVADO Y EN LA CUAL UN COMPUESTO DE METALOCENO ES SOPORTADO SOBRE EL POLIMERO DE OLEFINA PRODUCIDO EN LA FASE (A); Y (C) UNA SEGUNDA FASE DE POLIMERIZACION EN LA CUAL UNA O MAS OLEFINAS SON POLIMERIZADAS EN PRESENCIA DEL PRODUCTO OBTENIDO DE LA FASE (B).
ES95935892T 1994-10-05 1995-10-02 Procedimiento para la (co)polimerizacion de olefinas. Expired - Lifetime ES2156948T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI942028A IT1270125B (it) 1994-10-05 1994-10-05 Processo per la ( co) polimerizzazione di olefine

Publications (1)

Publication Number Publication Date
ES2156948T3 true ES2156948T3 (es) 2001-08-01

Family

ID=11369652

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95935892T Expired - Lifetime ES2156948T3 (es) 1994-10-05 1995-10-02 Procedimiento para la (co)polimerizacion de olefinas.

Country Status (29)

Country Link
US (2) US5648422A (es)
EP (1) EP0742801B1 (es)
JP (1) JP3897359B2 (es)
KR (1) KR100399625B1 (es)
CN (1) CN1070505C (es)
AT (1) ATE200499T1 (es)
AU (1) AU694276B2 (es)
BG (1) BG100674A (es)
BR (1) BR9506402A (es)
CA (1) CA2178077A1 (es)
CZ (1) CZ287739B6 (es)
DE (1) DE69520662T2 (es)
DK (1) DK0742801T3 (es)
ES (1) ES2156948T3 (es)
FI (1) FI962329A (es)
GR (1) GR3035745T3 (es)
HU (1) HU216285B (es)
IL (1) IL115515A (es)
IT (1) IT1270125B (es)
MY (1) MY112181A (es)
NO (1) NO311179B1 (es)
PH (1) PH31450A (es)
PL (1) PL314853A1 (es)
PT (1) PT742801E (es)
RU (1) RU2171265C2 (es)
SK (1) SK281619B6 (es)
TR (1) TR199501214A2 (es)
WO (1) WO1996011218A1 (es)
ZA (1) ZA958316B (es)

Families Citing this family (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1274469B (it) 1995-05-11 1997-07-17 Spherilene Spa Composizioni poliolefiniche vulcanizzabili dinamicamente
JP3719715B2 (ja) * 1996-06-24 2005-11-24 モンテル ノース アメリカ インコーポレーテッド 高透明性で高柔軟性の弾性プラスチックポリオレフィン組成物
DE69907785T2 (de) * 1998-03-09 2004-02-12 Basell Poliolefine Italia S.P.A. Mehrstufiges Verfahren zur Olefinpolymerisation
EP0942011B1 (en) * 1998-03-09 2003-05-14 Basell Poliolefine Italia S.p.A. Multi-stage process for the polymerization of olefins
US6268062B1 (en) 1998-04-06 2001-07-31 Applied Extrusion Technologies, Inc. Polypropylene blends and films prepared therewith
US6037417A (en) * 1998-08-18 2000-03-14 Montell Technology Company Bv Polypropylene composition useful for making solid state oriented film
IT1302029B1 (it) 1998-08-19 2000-07-20 Montech Usa Inc Processo per produrre composizioni polimeriche eterofasiche ecomposizioni cosi' ottenute
AU3960500A (en) * 1999-03-09 2000-09-28 Basell Technology Company B.V. Multi-stage process for the (co)polymerization of olefins
FI991015A0 (fi) * 1999-05-04 1999-05-04 Borealis As Menetelmä alfa-olefiinipolymeerien valmistamiseksi
JP2003518531A (ja) 1999-12-28 2003-06-10 バセル テクノロジー カンパニー ビー．ブイ． エチレンポリマーの製造方法
TR200103338T1 (tr) * 2000-03-22 2002-07-22 Basell Technology Company Bv İsotaktik propilen polimerlerin termoplastik bileşimleri.
GB0008690D0 (en) 2000-04-07 2000-05-31 Borealis Polymers Oy Process
US20020045190A1 (en) * 2000-07-11 2002-04-18 Wilson Robert B. Encoding methods using up-converting phosphors for high-throughput screening of catalysts
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
EP1355958A2 (en) * 2000-12-22 2003-10-29 Basell Poliolefine Italia S.p.A. Process for the preparation of porous polymers and polymers obtainable thereof
AU2002246517A1 (en) * 2001-01-16 2002-08-12 Exxonmobil Chemical Patents Inc. Catalysts with at least two transition metal compounds and polymerization processes using them
US7365137B2 (en) 2001-07-17 2008-04-29 Basell Polyolefine Gmbh Multistep process for the (co) polymerization of olefins
EP1448625A1 (en) * 2001-11-27 2004-08-25 Basell Poliolefine Italia S.p.A. Porous polymers of propylene
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
DE60207870T3 (de) * 2002-01-15 2011-12-15 Advanced Elastomer Systems, L.P. Thermoplastische elastomere und verfahren zu ihrer herstellung
EP1523509A1 (en) * 2002-07-24 2005-04-20 Basell Polyolefine GmbH At least two-stage process for preparing propylene polymer compositions
US6833416B2 (en) * 2003-03-21 2004-12-21 Univation Technologies, Llc Methods of polymerizing olefin monomers with mixed catalyst systems
TW200504093A (en) * 2003-05-12 2005-02-01 Dow Global Technologies Inc Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom
CN100594878C (zh) * 2004-03-31 2010-03-24 信越化学工业株式会社 含有硅氧烷聚合物的化妆品
WO2006044149A1 (en) * 2004-10-13 2006-04-27 Exxonmobil Chemical Patents Inc. Elastomeric reactor blend compositions
CN1328310C (zh) * 2004-11-05 2007-07-25 中国科学院化学研究所 聚烯烃复合材料及其制备方法
US7629422B2 (en) * 2004-12-21 2009-12-08 Univation Technologies, Llc Process for transitioning between Ziegler-Natta-based and chromium-based catalysts
WO2007035493A2 (en) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
US20080312390A1 (en) * 2007-06-14 2008-12-18 Petrochina Company Limited Process for preparation of polyolefin alloy
KR101141494B1 (ko) * 2007-09-05 2012-05-03 에스케이이노베이션 주식회사 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법
EP2315789B1 (en) * 2008-08-21 2015-09-02 W.R. Grace & CO. - CONN. Catalyst composition with mixed selectivity control agent and polymerisation method using it
US8480227B2 (en) 2010-07-30 2013-07-09 Novartis Ag Silicone hydrogel lenses with water-rich surfaces
ES2605429T3 (es) 2011-06-15 2017-03-14 Borealis Ag Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno
US8957168B1 (en) * 2013-08-09 2015-02-17 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations with an alcohol compound
US9708087B2 (en) 2013-12-17 2017-07-18 Novartis Ag Silicone hydrogel lens with a crosslinked hydrophilic coating
HUE046948T2 (hu) 2014-08-26 2020-03-30 Novartis Ag Eljárás stabil bevonat felvitelére szilikon hidrogél kontaktlencsékre
CN105622808B (zh) * 2014-10-31 2018-06-15 中国石油化工股份有限公司 一种抗冲聚丙烯的生产方法
US9920176B2 (en) 2015-06-05 2018-03-20 Exxonmobil Chemical Patents Inc. Single site catalyst supportation
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
CN107683295A (zh) * 2015-06-05 2018-02-09 埃克森美孚化学专利公司 多孔丙烯聚合物
EP3885373A1 (en) * 2015-06-05 2021-09-29 ExxonMobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
EP3303419A4 (en) * 2015-06-05 2018-06-20 ExxonMobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
US9725537B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. High activity catalyst supportation
US9725569B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. Porous propylene polymers
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10077325B2 (en) 2015-06-05 2018-09-18 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
EP3303418A4 (en) * 2015-06-05 2018-06-20 ExxonMobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US9738779B2 (en) 2015-06-05 2017-08-22 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
CN105254808A (zh) * 2015-09-30 2016-01-20 宁波职业技术学院 一种改性石油树脂的制备方法
MY184638A (en) 2015-12-15 2021-04-13 Alcon Inc Method for applying stable coating on silicone hydrogel contact lenses
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
EP3724698B1 (en) 2017-12-13 2021-12-15 Alcon Inc. Method for producing mps-compatible water gradient contact lenses
CN110551242B (zh) * 2018-05-31 2022-03-29 中国石油天然气股份有限公司 一种抗冲共聚聚丙烯及其制备方法
WO2022106710A1 (en) 2020-11-23 2022-05-27 Borealis Ag In-situ reactor blend of ziegler-natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK133012C (da) * 1968-11-21 1976-08-09 Montedison Spa Katalysator til polymerisation af alkener
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
IT1140221B (it) * 1981-10-14 1986-09-24 Montedison Spa Composizioni polipropileniche aventi migliorate caratteristiche di resistenza all'urto alle basse temperature e procedimento di preparazione
US4431571A (en) * 1982-05-14 1984-02-14 Standard Oil Company (Indiana) Retreating comminuted olefin polymerization catalyst with a titanium(IV) compound, a haloalkylchlorosilane and an ester
IT1206128B (it) * 1984-07-30 1989-04-14 Himont Inc Composizioni polipropileniche resistenti all'urto aventi migliorata resistenza allo sbiancamento.
CA1235543A (en) * 1984-09-12 1988-04-19 Norio Kashiwa Process for producing propylene block copolymer
KR920000173B1 (ko) * 1986-10-09 1992-01-09 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체
IT1227259B (it) * 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
IT1227260B (it) * 1988-09-30 1991-03-28 Himont Inc Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta
IT1227258B (it) * 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1230134B (it) * 1989-04-28 1991-10-14 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine.
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
DE3942363A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
US5280074A (en) * 1989-12-21 1994-01-18 Hoechst Ag Process for the preparation of a polypropylene molding composition
DE4005947A1 (de) * 1990-02-26 1991-08-29 Basf Ag Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
IT1241093B (it) * 1990-03-30 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
DE59109217D1 (de) * 1990-11-12 2001-09-20 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers
ES2091273T3 (es) * 1990-11-12 1996-11-01 Hoechst Ag Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
FR2669915B1 (fr) * 1990-11-29 1993-01-29 Atochem Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.
DE69225749T2 (de) * 1991-08-08 1998-10-01 Ube Rexene Corp Harzzusammensetzung aus amorphem Polyolefin und crystallinem Polypropylen
DE4130429A1 (de) * 1991-09-13 1993-03-18 Basf Ag Verfahren zur herstellung von mehrphasigen blockcopolymerisaten auf der basis von alk-1-enen
DE59206948D1 (de) * 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
DE4206367A1 (de) * 1992-02-29 1993-09-02 Basf Ag Verfahren zur herstellung von propylen-ethylen-copolymerisaten
IT1254547B (it) * 1992-03-23 1995-09-25 Montecatini Tecnologie Srl Copolimeri elastomerici dell'etilene con alfa-olefine.
IT1264406B1 (it) * 1993-05-11 1996-09-23 Spherilene Srl Copolimeri amorfi dell'etilene con alfa-olefine e procedimento per la loro preparazione
DE69307472T2 (de) * 1992-11-10 1997-05-15 Mitsubishi Chem Corp Verfahren zur Herstellung von Alpha-Olefinpolymeren
IT1256260B (it) * 1992-12-30 1995-11-29 Montecatini Tecnologie Srl Polipropilene atattico
DE69433347T2 (de) * 1993-01-29 2004-04-15 Dow Global Technologies, Inc., Midland Ethylen Copolymerisation
IT1264483B1 (it) * 1993-06-30 1996-09-23 Spherilene Srl Copolimeri elastomerici dell'etilene con propilene
IT1264482B1 (it) * 1993-06-30 1996-09-23 Spherilene Srl Copolimeri amorfi dell'etilene con propilene e procedimento per la loro preparazione
IT1271406B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti
IT1271407B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti
US5397843A (en) * 1993-11-22 1995-03-14 Igi Baychem, Inc. Polymer compositions comprising amorphous propylene polymer

Also Published As

Publication number Publication date
FI962329A0 (fi) 1996-06-04
MY112181A (en) 2001-04-30
WO1996011218A1 (en) 1996-04-18
FI962329A (fi) 1996-06-04
IL115515A0 (en) 1996-01-19
IL115515A (en) 2000-07-26
EP0742801B1 (en) 2001-04-11
BR9506402A (pt) 1997-09-09
TR199501214A2 (tr) 1996-06-21
DE69520662T2 (de) 2001-10-18
SK281619B6 (sk) 2001-05-10
NO311179B1 (no) 2001-10-22
SK87296A3 (en) 1997-04-09
PT742801E (pt) 2001-08-30
DK0742801T3 (da) 2001-05-21
AU3803395A (en) 1996-05-02
US6028140A (en) 2000-02-22
ITMI942028A0 (it) 1994-10-05
JP3897359B2 (ja) 2007-03-22
NO962298D0 (no) 1996-06-04
HUT75175A (en) 1997-04-28
ZA958316B (en) 1996-04-26
BG100674A (bg) 1997-03-31
KR960706512A (ko) 1996-12-09
NO962298L (no) 1996-06-04
AU694276B2 (en) 1998-07-16
PL314853A1 (en) 1996-09-30
RU2171265C2 (ru) 2001-07-27
ATE200499T1 (de) 2001-04-15
CA2178077A1 (en) 1996-04-18
JPH09506391A (ja) 1997-06-24
CZ287739B6 (en) 2001-01-17
KR100399625B1 (ko) 2003-12-24
PH31450A (en) 1998-11-03
EP0742801A1 (en) 1996-11-20
IT1270125B (it) 1997-04-28
DE69520662D1 (de) 2001-05-17
GR3035745T3 (en) 2001-07-31
ITMI942028A1 (it) 1996-04-05
CN1070505C (zh) 2001-09-05
HU216285B (hu) 1999-06-28
CN1139934A (zh) 1997-01-08
US5648422A (en) 1997-07-15
CZ199496A3 (en) 1996-12-11
HU9601834D0 (en) 1996-09-30

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