ES2148924T3 - Procedimiento de polimerizacion en suspension acuosa del cloruro de vinilo con ayuda de peroxidicarbonatos de dialquilo en solucion y procedimiento de fabricacion de una solucion de peroxidicarbonato de dialquilo. - Google Patents

Procedimiento de polimerizacion en suspension acuosa del cloruro de vinilo con ayuda de peroxidicarbonatos de dialquilo en solucion y procedimiento de fabricacion de una solucion de peroxidicarbonato de dialquilo.

Info

Publication number
ES2148924T3
ES2148924T3 ES97901036T ES97901036T ES2148924T3 ES 2148924 T3 ES2148924 T3 ES 2148924T3 ES 97901036 T ES97901036 T ES 97901036T ES 97901036 T ES97901036 T ES 97901036T ES 2148924 T3 ES2148924 T3 ES 2148924T3
Authority
ES
Spain
Prior art keywords
procedure
solution
vinyl chloride
dialkyl
peroxidicarbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97901036T
Other languages
English (en)
Other versions
ES2148924T5 (es
Inventor
Vincent Bodart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay SA
Original Assignee
Solvay SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3889493&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2148924(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Solvay SA filed Critical Solvay SA
Publication of ES2148924T3 publication Critical patent/ES2148924T3/es
Application granted granted Critical
Publication of ES2148924T5 publication Critical patent/ES2148924T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00Preparation of peroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00Preparation of peroxy compounds
    • C07C407/003Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00Peroxy compounds
    • C07C409/32Peroxy compounds the —O—O— group being bound between two >C=O groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

SE EMPLEAN PEROXIDICARBONATOS DE DIALQUILO DE CADENAS CORTAS ALQUILO, PREFERIBLEMENTE DE DIETIL O DIISOPROPIL, PARA LA POLIMERIZACION EN SUSPENSION ACUOSA DE CLORURO DE VINILO EN FORMA DE UNA SOLUCION EN UN ALCANODICARBOXILATO DE DIALQUILO LIQUIDO E INSOLUBLE EN AGUA. LOS DISOLVENTES PREFERIDOS SON LOS HEXANODICARBOXILATOS (ADIPATOS) DERIVADOS DE ACIDO ADIPICO Y DE ALCANOLES EN C 6 A C 10 . LA CONCENTRACION EN PEROXIDICARBONATO DE DICHAS SOLUCIONES ASCIENDE POR LO GENERAL AL 15 - 40 % EN PESO. EL PROCEDIMIENTO DE LA INVENCION PRODUCE POLIMEROS DE CLORURO DE VINILO DE CALIDAD MEJORADA QUE CONDUCEN A UNOS ARTICULOS ELABORADOS CON CLARAMENTE MENOS OJOS DE PESCADO. LA INVENCION SE REFIERE ASIMISMO A UN PROCEDIMIENTO DE FABRICACION EN DOS ETAPAS DE UNA SOLUCION DE PEROXIDICARBONATOS DE DIALQUILO DE CADENAS CORTAS ALQUILO, ESPECIALMENTE ADECUADA PARA LA POLIMERIZACION EN SUSPENSION ACUOSA DEL CLORURO DE VINILO. SEGUN ESTE PROCEDIMIENTO, SE APLICA UNA SAL INORGANICA EN LA ETAPA DE FABRICACION DELPEROXIDICARBONATO (PRIMERA ETAPA) Y A CONTINUACION SE SEPARA ESTE POR EXTRACCION MEDIANTE UN DISOLVENTE INSOLUBLE EN AGUA (SEGUNDA ETAPA).
ES97901036T 1996-01-25 1997-01-10 Procedimiento de polimerización en suspensión acuosa de cloruro de vinilo por medio de peroxidicarbonatos de dialquilo en solución y procedimiento de fabricación de una solución de peroxidicarbonato de dialquilo. Expired - Lifetime ES2148924T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BE9600070 1996-01-25
BE9600070A BE1009969A3 (fr) 1996-01-25 1996-01-25 Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle.

Publications (2)

Publication Number Publication Date
ES2148924T3 true ES2148924T3 (es) 2000-10-16
ES2148924T5 ES2148924T5 (es) 2012-01-10

Family

ID=3889493

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97901036T Expired - Lifetime ES2148924T5 (es) 1996-01-25 1997-01-10 Procedimiento de polimerización en suspensión acuosa de cloruro de vinilo por medio de peroxidicarbonatos de dialquilo en solución y procedimiento de fabricación de una solución de peroxidicarbonato de dialquilo.

Country Status (32)

Country Link
US (3) US6258906B1 (es)
EP (1) EP0876410B2 (es)
JP (3) JP4889837B2 (es)
KR (2) KR100476175B1 (es)
CN (2) CN1132859C (es)
AR (2) AR006753A1 (es)
AT (1) ATE192460T1 (es)
AU (1) AU723766B2 (es)
BE (1) BE1009969A3 (es)
BG (1) BG63396B1 (es)
BR (1) BR9707080A (es)
CA (1) CA2244154C (es)
CZ (1) CZ292259B6 (es)
DE (1) DE69701855T3 (es)
DZ (1) DZ2170A1 (es)
EA (1) EA000881B1 (es)
ES (1) ES2148924T5 (es)
HR (1) HRP970047B1 (es)
HU (1) HU229149B1 (es)
IL (2) IL125396A (es)
MY (1) MY116847A (es)
NO (2) NO318952B1 (es)
PL (1) PL186797B1 (es)
PT (1) PT876410E (es)
RO (1) RO119887B1 (es)
SK (1) SK284350B6 (es)
TR (1) TR199801423T2 (es)
TW (1) TW326048B (es)
UA (1) UA63900C2 (es)
WO (1) WO1997027229A1 (es)
YU (1) YU49136B (es)
ZA (1) ZA97449B (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009969A3 (fr) * 1996-01-25 1997-11-04 Solvay Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle.
BE1011295A3 (fr) * 1997-07-22 1999-07-06 Solvay Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus.
US6995221B2 (en) * 1999-11-04 2006-02-07 Oxy Vinyls, L.P. Method for producing organic peroxides and their use in the radical polymerization of monomers
US6433208B1 (en) * 1999-11-04 2002-08-13 Oxy Vinyls Lp Method for producing stable, dilute, aqueous, emulsified peroxydicarbonates by homogenization
US6846888B2 (en) * 2001-02-01 2005-01-25 Atofina Chemicals, Inc. Stabilized organic peroxydicarbonate compositions
PL363747A1 (en) * 2001-03-23 2004-11-29 Akzo Nobel N.V. Storage stable aqueous organic peroxide emulsions
DE502004007483D1 (de) * 2004-05-05 2008-08-14 Vestolit Gmbh & Co Kg Verfahren zur Herstellung von Polymeren und Copolymeren
EP1849804A1 (en) * 2006-04-27 2007-10-31 Arkema France Process of free-radical polymerization or crosslinking in the presence of an organic peroxide by an ex situ process
EP1852418A1 (en) 2006-04-27 2007-11-07 Arkema France Process for synthesizing selected organic peroxides
CN101230770B (zh) * 2007-01-22 2010-12-01 优护国际企业股份有限公司 具寻码功能的两用号码锁
FR2968660B1 (fr) * 2010-12-14 2014-03-07 Solvay Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle
FR2984331A1 (fr) * 2011-12-15 2013-06-21 Solvay Procede de preparation d'une solution organique d'un peroxydicarbonate de dialkyle

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE118608C (es)
US2370588A (en) * 1942-10-22 1945-02-27 Pittsburgh Plate Glass Co Organic percarbonates
AT243234B (de) 1962-10-06 1965-10-25 Hoechst Ag Verfahren zur Herstellung von Lösungen von Peroxydikohlensäureestern
NL302390A (es) * 1962-12-22
DE1259325B (de) 1964-05-22 1968-01-25 Hoechst Ag Verfahren zur kontinuierlichen Herstellung von Loesungen von Peroxydikohlensaeureestern
GB1107956A (en) 1966-02-28 1968-03-27 Noury & Van Der Lande Improvements in or relating to organic peroxydicarbonates
IL29131A (en) * 1967-12-14 1971-01-28 Kreisel M Process for the polymerization of vinyl compounds
BE791488A (fr) * 1971-11-18 1973-05-16 Rhone Progil Procede de preparation en continu de peroxydes
US3799916A (en) 1972-06-19 1974-03-26 Air Prod & Chem Vinyl chloride based polymers prepared by in-situ initiators in acid medium
JPS4997882A (es) * 1973-01-08 1974-09-17
FR2241566B1 (es) 1973-04-03 1978-02-10 Rhone Progil
US3935243A (en) 1973-09-17 1976-01-27 The Dow Chemical Company Method for preparing polyperoxydicarbonate esters
FR2253760B1 (es) 1973-12-05 1976-10-08 Solvay
US3950375A (en) * 1973-12-10 1976-04-13 Pennwalt Corporation Continuous manufacture of peroxydicarbonates
DD118608A1 (es) 1975-04-14 1976-03-12
NO761321L (es) * 1975-07-30 1977-02-01 Continental Oil Co
JPS52142792A (en) 1976-05-25 1977-11-28 Kureha Chem Ind Co Ltd Suspension polymerization of vinyl chloride
JPS584933B2 (ja) * 1978-05-31 1983-01-28 呉羽化学工業株式会社 可塑化塩化ビニリデン↓−塩化ビニル系共重合体の製造法
JPS559067A (en) * 1978-06-30 1980-01-22 Ppg Industries Inc Manufacture of peroxydicarbonates
SE7907690L (sv) 1979-10-05 1981-03-18 Ceskoslovenska Akademie Ved Sett att framstella inre mjukad polyvinylklorid
JPS5887101A (ja) 1981-11-18 1983-05-24 Kayaku Nuurii Kk エチレン系不飽和単量体の重合用組成物
JPS58103357A (ja) * 1981-12-14 1983-06-20 Nippon Oil & Fats Co Ltd ジイソプロピルペルオキシジカ−ボネ−トの製造方法
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JPH07188489A (ja) * 1993-11-22 1995-07-25 Sumitomo Chem Co Ltd 粉末成形用塩化ビニル系樹脂組成物及びその製造方法
US5548046A (en) * 1994-02-16 1996-08-20 Elf Atochem North America, Inc. Stabilized dialkyl peroxydicarbonate compositions and their uses
JPH0812708A (ja) * 1994-06-29 1996-01-16 Sumitomo Chem Co Ltd 塩化ビニル系重合体の製造方法
BE1009969A3 (fr) * 1996-01-25 1997-11-04 Solvay Procede pour la polymerisation en suspension aqueuse du chlorure de vinyle a l'intervention de peroxydicarbonates de dialkyle.
BE1011294A3 (fr) * 1997-07-22 1999-07-06 Solvay Solution organique de peroxydicarbonate de dialkyle, procede pour l'obtenir, preparation de polymeres halogenes a l'intervention de celle-ci et polymeres halogenes obtenus.

Also Published As

Publication number Publication date
YU49136B (sh) 2004-03-12
US6258906B1 (en) 2001-07-10
NO983430L (no) 1998-09-24
JP2007262080A (ja) 2007-10-11
PT876410E (pt) 2000-10-31
TR199801423T2 (xx) 1998-10-21
IL125396A0 (en) 1999-03-12
PL328268A1 (en) 1999-01-18
BE1009969A3 (fr) 1997-11-04
CA2244154C (fr) 2007-01-09
EP0876410B2 (fr) 2011-08-17
ZA97449B (en) 1998-07-21
BG102649A (en) 1999-03-31
KR100476175B1 (ko) 2005-07-07
DE69701855D1 (de) 2000-06-08
DE69701855T3 (de) 2012-04-19
UA63900C2 (uk) 2004-02-16
ATE192460T1 (de) 2000-05-15
HUP9900981A2 (hu) 1999-07-28
AU1442497A (en) 1997-08-20
IL125396A (en) 2003-05-29
NO20035017L (no) 1998-09-24
CN1214703A (zh) 1999-04-21
JP2009287029A (ja) 2009-12-10
NO328156B1 (no) 2009-12-21
DZ2170A1 (fr) 2002-12-01
IL137055A0 (en) 2001-06-14
AR006753A1 (es) 1999-09-29
WO1997027229A1 (fr) 1997-07-31
HU229149B1 (en) 2013-09-30
EA000881B1 (ru) 2000-06-26
CN1267459C (zh) 2006-08-02
US20040048995A1 (en) 2004-03-11
BG63396B1 (bg) 2001-12-29
RO119887B1 (ro) 2005-05-30
JP4291378B2 (ja) 2009-07-08
MY116847A (en) 2004-04-30
US6617408B2 (en) 2003-09-09
CN1132859C (zh) 2003-12-31
JP2000504365A (ja) 2000-04-11
NO983430D0 (no) 1998-07-24
CZ292259B6 (cs) 2003-08-13
HRP970047B1 (en) 2002-02-28
CZ237098A3 (cs) 1998-12-16
US20010031846A1 (en) 2001-10-18
AU723766B2 (en) 2000-09-07
US6878840B2 (en) 2005-04-12
EA199800653A1 (ru) 1999-02-25
CN1515595A (zh) 2004-07-28
EP0876410A1 (fr) 1998-11-11
HRP970047A2 (en) 1998-04-30
IL137055A (en) 2004-07-25
SK98898A3 (en) 2000-02-14
YU2297A (sh) 1999-06-15
KR20040091624A (ko) 2004-10-28
KR19990082020A (ko) 1999-11-15
NO20035017D0 (no) 2003-11-12
BR9707080A (pt) 1999-03-23
EP0876410B1 (fr) 2000-05-03
AR017595A2 (es) 2001-09-12
JP4889837B2 (ja) 2012-03-07
TW326048B (en) 1998-02-01
DE69701855T2 (de) 2000-11-30
PL186797B1 (pl) 2004-02-27
NO318952B1 (no) 2005-05-30
HUP9900981A3 (en) 2003-12-29
SK284350B6 (sk) 2005-02-04
ES2148924T5 (es) 2012-01-10
CA2244154A1 (fr) 1997-07-31

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