ES2085688T3 - Mezclas casi-azeotropicas para uso como refrigerantes. - Google Patents
Mezclas casi-azeotropicas para uso como refrigerantes.Info
- Publication number
- ES2085688T3 ES2085688T3 ES93111181T ES93111181T ES2085688T3 ES 2085688 T3 ES2085688 T3 ES 2085688T3 ES 93111181 T ES93111181 T ES 93111181T ES 93111181 T ES93111181 T ES 93111181T ES 2085688 T3 ES2085688 T3 ES 2085688T3
- Authority
- ES
- Spain
- Prior art keywords
- mixtures
- propane
- percentage
- refrigerants
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/11—Ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/124—Fluorinated cyclic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/128—Perfluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/32—The mixture being azeotropic
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Lubricants (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
SE PRESENTAN MEZCLAS CUASI-ACEOTROPICAS QUE CONTIENEN HIDROCARBONOS FLUORADOS Y PROPANO. LAS MEZCLAS SON MEZCLAS DE CLORODIFLUOROETANO (HCFC-22), PROPANO Y PENTAFLUOROETANO (HFCV-125) EN LAS PROPORCIONES DE 1.98.9 EN PORCENTAJE DE PESO DE HCFC-22, 0.1-15 EN PORCENTAJE DE PESO DE PROPANO Y 1.98.9 EN PORCENTAJE DE PESO HFC-125. TALES MEZCLAS TIENEN UN BAJO POTENCIAL DE DEGRADACION DEL OZONO Y PUEDEN USARSE COMO REEMPLAZAMIENTO DEL REFRIGERANTE R-502.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US55834690A | 1990-07-26 | 1990-07-26 | |
US68156591A | 1991-04-05 | 1991-04-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2085688T3 true ES2085688T3 (es) | 1996-06-01 |
Family
ID=27071713
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91912138T Expired - Lifetime ES2066453T5 (es) | 1990-07-26 | 1991-06-17 | Mezclas casi azeotropicas para su uso como refrigerantes. |
ES93111181T Expired - Lifetime ES2085688T3 (es) | 1990-07-26 | 1991-06-17 | Mezclas casi-azeotropicas para uso como refrigerantes. |
ES94200518T Expired - Lifetime ES2102759T3 (es) | 1990-07-26 | 1991-06-17 | Mezclas casi azeotropicas para uso como refrigerantes. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91912138T Expired - Lifetime ES2066453T5 (es) | 1990-07-26 | 1991-06-17 | Mezclas casi azeotropicas para su uso como refrigerantes. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94200518T Expired - Lifetime ES2102759T3 (es) | 1990-07-26 | 1991-06-17 | Mezclas casi azeotropicas para uso como refrigerantes. |
Country Status (14)
Country | Link |
---|---|
US (3) | US5616276A (es) |
EP (3) | EP0568115B1 (es) |
JP (4) | JP2561988B2 (es) |
KR (1) | KR0130833B1 (es) |
AR (1) | AR248158A1 (es) |
AT (3) | ATE115994T1 (es) |
BR (1) | BR9106694A (es) |
CA (3) | CA2413038C (es) |
DE (3) | DE69118208T2 (es) |
DK (3) | DK0545942T4 (es) |
ES (3) | ES2066453T5 (es) |
GR (2) | GR3019604T3 (es) |
HK (1) | HK109995A (es) |
WO (1) | WO1992001762A1 (es) |
Families Citing this family (85)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2244492B (en) | 1989-09-12 | 1993-08-04 | Star Refrigeration | Three-component refrigerant mixture |
US5370811A (en) * | 1989-11-30 | 1994-12-06 | Matsushita Electric Industrial Co., Ltd. | Working fluid containing tetrafluoroethane |
DK0545942T4 (da) * | 1990-07-26 | 2004-04-13 | Du Pont | Næsten-azeotrope blandinger til anvendelse som kølemidler |
US5182040A (en) * | 1991-03-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of 1,1,2,2-tetrafluoroethane |
GB9108527D0 (en) * | 1991-04-18 | 1991-06-05 | Ici Plc | Refrigerant compositions |
JPH06281272A (ja) * | 1991-07-08 | 1994-10-07 | Daikin Ind Ltd | 最高共沸混合物および共沸様混合物 |
FR2682395B1 (fr) * | 1991-10-09 | 1993-12-10 | Atochem | Melanges de 1,1,1-trifluoroethane, de perfluoropropane et de propane, et leurs applications comme fluides frigorigenes, comme propulseurs d'aerosols ou comme agents d'expansion des mousses plastiques. |
JP2568774B2 (ja) * | 1991-10-28 | 1997-01-08 | 松下電器産業株式会社 | 作動流体 |
US5290466A (en) * | 1991-10-31 | 1994-03-01 | E. I. Du Pont De Nemours And Company | Compositions of difluoromethane and tetrafluoroethane |
JPH07504889A (ja) * | 1991-12-03 | 1995-06-01 | ユナイテッド ステーツ インバイオロンメンタル プロテクション エイジェンシー | 冷媒組成物およびその使用方法 |
AU3615193A (en) * | 1992-02-12 | 1993-09-03 | Allied-Signal Inc. | Refrigerant compositions of monochlorodifluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane |
EP0565265B1 (en) * | 1992-04-04 | 1995-12-13 | Star Refrigeration Ltd. | Refrigerant composition |
US5248433A (en) * | 1992-04-30 | 1993-09-28 | E. I. Du Pont De Nemours And Company | Binary azeotropic mixtures of octafluoropropane and fluoroethane |
JPH07508519A (ja) * | 1992-06-29 | 1995-09-21 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | ペンタフルオロエタン及びトリフルオロエタンの混合物 |
US5762818A (en) * | 1992-07-15 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Compositions which include 1,1,2,2- tetrafluoroethane and fluoroethane |
EP0668897A1 (en) * | 1992-11-10 | 1995-08-30 | AlliedSignal Inc. | Azeotrope-like compositions of difluoromethane, pentafluoroethane and 1,1,1-trifluoroethane |
AU5548494A (en) * | 1992-11-19 | 1994-06-08 | E.I. Du Pont De Nemours And Company | Refrigerant compositions including 1,1,2-trifluoroethane |
AU686129B2 (en) * | 1993-01-20 | 1998-02-05 | Imperial Chemical Industries Plc | Refrigerant compositions |
DE69430662T2 (de) * | 1993-02-05 | 2002-12-05 | E.I. Du Pont De Nemours And Co., Wilmington | Zusammensetzungen von fluorkohlenwasserstoffen und kohlenwasserstoffen |
US5458798A (en) * | 1993-02-05 | 1995-10-17 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of a hydrofluorocarbon and a hydrocarbon |
IT1264126B1 (it) * | 1993-04-05 | 1996-09-16 | Ausimont Spa | Composizioni a base di fluorocarburi idrogenati |
NL9300834A (nl) * | 1993-05-14 | 1994-12-01 | Bernardina Carolina Maria Enge | Koelinrichting. |
WO1995004787A1 (en) * | 1993-08-10 | 1995-02-16 | Intermagnetics General Corporation | Mixture refrigerants |
IT1270960B (it) * | 1993-08-13 | 1997-05-26 | Ausimont Spa | Miscele ternarie quasi azeotropiche con fluidi refrigeranti |
US5736062A (en) * | 1993-08-13 | 1998-04-07 | Ausimont S.P.A. | Azeotrope-like mixtures utilizable as refrigerating fluids |
US5723429A (en) * | 1994-03-11 | 1998-03-03 | E. I. Du Pont De Nemours And Company | Azeotropic or azeotrope-like compositions of tetrafluoroethane and chlorotetrafluoroethane |
US6001273A (en) * | 1994-03-11 | 1999-12-14 | Minor; Barbara Haviland | Binary azeotropes of difluoromethane and hydrocarbons |
US5417871A (en) * | 1994-03-11 | 1995-05-23 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon compositions |
GB9415140D0 (en) * | 1994-07-27 | 1994-09-14 | Ici Plc | Refrigerant compositions |
WO1996015205A1 (en) * | 1994-11-16 | 1996-05-23 | E.I. Du Pont De Nemours And Company | Compositions that include a cyclic fluorocarbon |
CA2181387A1 (en) * | 1994-11-17 | 1996-05-18 | Martin Anthony Krevalis | Refrigeration working fluid compositions for use in recompression type cooling systems |
US6146544A (en) * | 1994-11-18 | 2000-11-14 | Lacovia N.V. | Environmentally benign non-toxic fire flooding agents |
US6402975B1 (en) | 1994-11-18 | 2002-06-11 | Lacovia N.V. | Environmentally benign non-toxic fire flooding agents |
FR2725200B1 (fr) * | 1995-02-17 | 1996-10-31 | Atochem Elf Sa | Melange pseudo-azeotropique de chlorodifluoromethane, de 1,1,1-trifluoroethane et de pentafluoroethane, et son application comme fluide frigorigene en refrigeration basse temperature |
GB9504955D0 (en) * | 1995-03-11 | 1995-04-26 | Star Refrigeration | High efficiency refrigerant |
ATE194422T1 (de) * | 1995-04-18 | 2000-07-15 | Daikin Ind Ltd | Kältemittelmischungsfüllverfahren |
FR2733243B1 (fr) * | 1995-04-20 | 1997-06-13 | Atochem Elf Sa | Melanges non azeotropiques de 1,1,1,2-tetrafluoroethane, 1,1,1-trifluoroethane et pentafluoroethane, et leur application comme fluides frigorigenes |
FR2733992B1 (fr) * | 1995-05-12 | 1997-06-20 | Atochem Elf Sa | Melanges non azeotropiques de 1,1,1,2-tetrafluoroethane, difluoromethane et pentafluoroethane, et leur application comme fluides frigorigenes |
GB9516919D0 (en) * | 1995-08-18 | 1995-10-18 | Ici Plc | Refrigerant compositions |
WO1997015637A1 (fr) * | 1995-10-20 | 1997-05-01 | Tsinghua University | Refrigerant |
US6173577B1 (en) | 1996-08-16 | 2001-01-16 | American Superconductor Corporation | Methods and apparatus for cooling systems for cryogenic power conversion electronics |
US6023934A (en) * | 1996-08-16 | 2000-02-15 | American Superconductor Corp. | Methods and apparatus for cooling systems for cryogenic power conversion electronics |
US5801937A (en) * | 1996-10-16 | 1998-09-01 | American Superconductor Corporation | Uninterruptible power supplies having cooled components |
US6261472B1 (en) | 1996-11-04 | 2001-07-17 | E. I. Du Pont De Nemours And Company | Azeotrope-like compositions containing fluoroethane |
AU774247B2 (en) * | 1996-11-04 | 2004-06-24 | E.I. Du Pont De Nemours And Company | Hydrofluorocarbon compositions |
KR100261459B1 (ko) * | 1997-12-24 | 2000-07-01 | 박대치 | 냉동/공기조화기용 혼합냉매 조성물 |
KR100255477B1 (ko) * | 1998-02-13 | 2000-05-01 | 박왕근 | 냉매 조성물 |
KR100305079B1 (ko) * | 1998-12-23 | 2001-09-12 | 박호군 | 클로로디플루오로메탄(hcfc-22)대체용냉매혼합물 |
US6783691B1 (en) | 1999-03-22 | 2004-08-31 | E.I. Du Pont De Nemours And Company | Compositions of difluoromethane, pentafluoroethane, 1,1,1,2-tetrafluoroethane and hydrocarbons |
KR100340186B1 (ko) * | 1999-11-10 | 2002-06-12 | 박호군 | 디플루오로메탄, 펜타플루오로에탄 및1,1,1-트리플루오로에탄을 포함하는 냉매 혼합물 |
FR2813610B1 (fr) * | 2000-09-04 | 2002-10-18 | Atofina | Composition utilisable comme fluide frigorifique |
DE10056606A1 (de) * | 2000-11-15 | 2002-05-23 | Solvay Fluor & Derivate | Verwendung von Gemischen,die 1,1,1,3,3-Pentafluorbutan enthalten, als Kältemittel oder Wärmerträger |
ES2185494B1 (es) * | 2001-07-11 | 2004-08-16 | Dinagas, S.A. | Mezcla refrigerante sustituta del diclorodifluorometano. |
US6863840B2 (en) * | 2002-06-27 | 2005-03-08 | George H. Goble | Nonflammable, nonozone depleting, refrigerant mixtures suitable for use in mineral oil |
AU2003273365A1 (en) * | 2002-10-01 | 2004-04-23 | James B. Tieken | Refrigerant blend |
US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US20040089839A1 (en) * | 2002-10-25 | 2004-05-13 | Honeywell International, Inc. | Fluorinated alkene refrigerant compositions |
US8033120B2 (en) * | 2002-10-25 | 2011-10-11 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
PT1572829E (pt) * | 2002-11-29 | 2012-01-11 | Du Pont | Refrigerantes para refrigeração |
JP3789898B2 (ja) * | 2003-03-17 | 2006-06-28 | 東芝キヤリア株式会社 | 冷媒、冷媒圧縮機および冷凍装置 |
US7655610B2 (en) * | 2004-04-29 | 2010-02-02 | Honeywell International Inc. | Blowing agent compositions comprising fluorinated olefins and carbon dioxide |
CN1233781C (zh) | 2003-11-12 | 2005-12-28 | 浙江蓝天环保高科技股份有限公司 | 一种替代r502的环保型制冷剂 |
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JP2007107858A (ja) * | 2005-10-17 | 2007-04-26 | Sanyo Electric Co Ltd | 冷凍装置 |
EP2013309B1 (en) | 2006-03-03 | 2014-09-03 | Rpl Holdings Limited | Refrigerant composition |
EP2380942B1 (en) | 2006-03-03 | 2016-10-19 | Rpl Holdings Limited | Refrigerant composition |
KR100805663B1 (ko) * | 2006-04-07 | 2008-02-21 | 주식회사 아로켐 | 혼합냉매 조성물 |
CN100460479C (zh) * | 2006-07-10 | 2009-02-11 | 浙江蓝天环保高科技股份有限公司 | 一种环保型热泵混合工质 |
KR100735715B1 (ko) * | 2006-09-29 | 2007-07-06 | 인하대학교 산학협력단 | 알22와 알290으로 구성된 2원 혼합냉매 |
KR100735716B1 (ko) * | 2006-09-29 | 2007-07-06 | 인하대학교 산학협력단 | 알22와 알1270으로 구성된 2원 혼합냉매 |
GB2447629A (en) * | 2007-03-19 | 2008-09-24 | Rpl Holdings Ltd | Refrigerant composition comprising three hydrofluorocarbon components |
US8820079B2 (en) * | 2008-12-05 | 2014-09-02 | Honeywell International Inc. | Chloro- and bromo-fluoro olefin compounds useful as organic rankine cycle working fluids |
US8444873B2 (en) | 2009-06-12 | 2013-05-21 | Solvay Fluor Gmbh | Refrigerant composition |
US8097182B2 (en) | 2009-06-17 | 2012-01-17 | A.S. Trust & Holdings, Inc. | Hydrocarbon refrigerant and detergent composition |
GB0922288D0 (en) | 2009-12-21 | 2010-02-03 | Rpl Holdings Ltd | Non ozone depleting and low global warming potential refrigerants for refrigeration |
TW201412966A (zh) * | 2012-08-30 | 2014-04-01 | Du Pont | 為二氟氯甲烷設計之設備的再充填方法 |
US8999191B2 (en) | 2013-03-15 | 2015-04-07 | National Refrigerants, Inc. | R22 replacement refrigerant |
GB201505230D0 (en) | 2015-03-27 | 2015-05-13 | Rpl Holdings Ltd | Non ozone depleting and low global warming refrigerant blends |
CN105925248A (zh) * | 2016-04-29 | 2016-09-07 | 成都蓉阳科技有限公司 | 一种用于替代二氟一氯甲烷的环保混合制冷剂 |
US10816320B2 (en) * | 2016-10-05 | 2020-10-27 | Sumitomo Mitsui Construction Co., Ltd. | Sleeve position inspecting device and sleeve position inspecting method |
CN111492030A (zh) | 2017-11-27 | 2020-08-04 | Rpl控股有限公司 | 低gwp之冷冻剂共混物 |
US11286409B2 (en) | 2017-12-07 | 2022-03-29 | Daikin Industries, Ltd. | Composition containing refrigerant including R32, R125, R143a and R134a, and refrigeration method using said composition, method for operating refrigerator, and refrigerator |
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1991
- 1991-06-17 DK DK91912138T patent/DK0545942T4/da active
- 1991-06-17 DE DE69118208T patent/DE69118208T2/de not_active Revoked
- 1991-06-17 JP JP3511259A patent/JP2561988B2/ja not_active Expired - Lifetime
- 1991-06-17 EP EP93111181A patent/EP0568115B1/en not_active Revoked
- 1991-06-17 WO PCT/US1991/004100 patent/WO1992001762A1/en active IP Right Grant
- 1991-06-17 CA CA002413038A patent/CA2413038C/en not_active Expired - Lifetime
- 1991-06-17 DK DK93111181.9T patent/DK0568115T3/da active
- 1991-06-17 AT AT91912138T patent/ATE115994T1/de not_active IP Right Cessation
- 1991-06-17 ES ES91912138T patent/ES2066453T5/es not_active Expired - Lifetime
- 1991-06-17 AT AT94200518T patent/ATE153367T1/de not_active IP Right Cessation
- 1991-06-17 CA CA002148854A patent/CA2148854C/en not_active Expired - Lifetime
- 1991-06-17 DE DE69126219T patent/DE69126219T2/de not_active Expired - Lifetime
- 1991-06-17 CA CA002086841A patent/CA2086841C/en not_active Expired - Lifetime
- 1991-06-17 BR BR919106694A patent/BR9106694A/pt not_active IP Right Cessation
- 1991-06-17 ES ES93111181T patent/ES2085688T3/es not_active Expired - Lifetime
- 1991-06-17 EP EP91912138A patent/EP0545942B2/en not_active Expired - Lifetime
- 1991-06-17 DE DE69106135T patent/DE69106135T3/de not_active Expired - Lifetime
- 1991-06-17 EP EP94200518A patent/EP0602022B1/en not_active Expired - Lifetime
- 1991-06-17 AT AT93111181T patent/ATE135733T1/de active
- 1991-06-17 DK DK94200518.2T patent/DK0602022T3/da active
- 1991-06-17 ES ES94200518T patent/ES2102759T3/es not_active Expired - Lifetime
- 1991-06-21 AR AR91320008A patent/AR248158A1/es active
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1993
- 1993-01-26 KR KR1019930700222A patent/KR0130833B1/ko not_active IP Right Cessation
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1994
- 1994-09-21 JP JP6226187A patent/JP2554455B2/ja not_active Expired - Lifetime
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1995
- 1995-02-24 JP JP7036497A patent/JP2993390B2/ja not_active Expired - Lifetime
- 1995-06-07 US US08/484,419 patent/US5616276A/en not_active Expired - Lifetime
- 1995-06-07 US US08/478,146 patent/US5635099A/en not_active Expired - Lifetime
- 1995-07-06 HK HK109995A patent/HK109995A/xx not_active IP Right Cessation
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1996
- 1996-04-09 GR GR960400999T patent/GR3019604T3/el unknown
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1997
- 1997-01-13 US US08/782,136 patent/US5800730A/en not_active Expired - Lifetime
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