ES2020649A6 - Procedimiento para la obtencion de acrilato de sec-butilo. - Google Patents

Procedimiento para la obtencion de acrilato de sec-butilo.

Info

Publication number
ES2020649A6
ES2020649A6 ES9000646A ES9000646A ES2020649A6 ES 2020649 A6 ES2020649 A6 ES 2020649A6 ES 9000646 A ES9000646 A ES 9000646A ES 9000646 A ES9000646 A ES 9000646A ES 2020649 A6 ES2020649 A6 ES 2020649A6
Authority
ES
Spain
Prior art keywords
acrylic acid
butyl acrylate
olefin
sec
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES9000646A
Other languages
English (en)
Inventor
Pascual Miguel A Perez
De Benito Fernando Albertos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compania Espanola de Petroleos SA CEPSA
Original Assignee
Compania Espanola de Petroleos SA CEPSA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8266240&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2020649(A6) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to ES9000646A priority Critical patent/ES2020649A6/es
Application filed by Compania Espanola de Petroleos SA CEPSA filed Critical Compania Espanola de Petroleos SA CEPSA
Priority to EP91200346A priority patent/EP0445859B1/en
Priority to DE69100955T priority patent/DE69100955T2/de
Priority to DK91200346.4T priority patent/DK0445859T3/da
Priority to AT91200346T priority patent/ATE100076T1/de
Priority to CA002036720A priority patent/CA2036720C/en
Priority to US07/659,965 priority patent/US5138092A/en
Priority to JP3038504A priority patent/JPH06104645B2/ja
Publication of ES2020649A6 publication Critical patent/ES2020649A6/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE ACRILATO DE SEC-BUTILO. COMPRENDE HACER REACCIONAR, TANTO EN FORMA CONTINUA COMO DISCONTINUA, ACIDO ACRILICO Y 1-BUTENO EN PRESENCIA DE UNA RESINA DE INTERCAMBIO IONICO QUE CONTIENE GRUPOS DE ACIDO SULFONICO, EFECTUANDOSE LA REACCION A UNA TEMPERATURA COMPRENDIDA ENTRE 50 Y 120GC, A UNA PRESION COMPRENDIDA ENTRE 10 Y 30 KG/CMBS2, DURANTE UN TIEMPO DE REACCION O DE CONTACTO COMPRENDIDO ENTRE 0,5 Y 4 HORAS Y EMPLEANDO UNA RELACION MOLAR OLEFINA/ACIDO ACRILICO COMPRENDIDA ENTRE 0,3 Y 10. EL ACRILATO DE SEC-BUTILO OBTENIDO TIENE APLICACION EN PROCESOS DE POLIMERIZACION RINDIENDO POLIMEROS DE GRAN DUREZA Y CON ELEVADA RESITENCIA TANTO TERMICA COMO FRENTE A LA HIDROLISIS. LA FIG. 1 REPRESENTA UNA GRAFICA DEL EFECTO DE LA RAZON MOLAR OLEFINA/ACIDO ACRILICO SOBRE LA CONVERSION DEL ACIDO ACRILICO.
ES9000646A 1990-03-05 1990-03-05 Procedimiento para la obtencion de acrilato de sec-butilo. Expired - Lifetime ES2020649A6 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES9000646A ES2020649A6 (es) 1990-03-05 1990-03-05 Procedimiento para la obtencion de acrilato de sec-butilo.
EP91200346A EP0445859B1 (en) 1990-03-05 1991-02-19 Process for obtaining sec-butyl acrylate
DE69100955T DE69100955T2 (de) 1990-03-05 1991-02-19 Verfahren zur Herstellung von sec-Butylacrylat.
DK91200346.4T DK0445859T3 (da) 1990-03-05 1991-02-19 Fremgangsmåde til opnåelse af sec-butylacrylat
AT91200346T ATE100076T1 (de) 1990-03-05 1991-02-19 Verfahren zur herstellung von sec-butylacrylat.
CA002036720A CA2036720C (en) 1990-03-05 1991-02-20 Process for obtaining sec-butyl acrylate
US07/659,965 US5138092A (en) 1990-03-05 1991-02-22 Process for obtaining sec-butyl acrylate
JP3038504A JPH06104645B2 (ja) 1990-03-05 1991-03-05 アクリル酸ｓ−ブチルの製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9000646A ES2020649A6 (es) 1990-03-05 1990-03-05 Procedimiento para la obtencion de acrilato de sec-butilo.

Publications (1)

Publication Number Publication Date
ES2020649A6 true ES2020649A6 (es) 1991-08-16

Family

ID=8266240

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9000646A Expired - Lifetime ES2020649A6 (es) 1990-03-05 1990-03-05 Procedimiento para la obtencion de acrilato de sec-butilo.

Country Status (8)

Country Link
US (1) US5138092A (es)
EP (1) EP0445859B1 (es)
JP (1) JPH06104645B2 (es)
AT (1) ATE100076T1 (es)
CA (1) CA2036720C (es)
DE (1) DE69100955T2 (es)
DK (1) DK0445859T3 (es)
ES (1) ES2020649A6 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5189201A (en) * 1992-03-25 1993-02-23 Showa Denko K.K. Process for preparation of lower fatty acid ester
FR2718740B1 (fr) * 1994-04-15 1996-05-31 Atochem Elf Sa Procédé de préparation de l'acrylate de butyle secondaire.
FR2734813B1 (fr) * 1995-06-02 1997-07-04 Atochem Elf Sa Procede de fabrication d'acrylate de butyle secondaire par reaction de l'acide acrylique et des isomeres de butene
EP0873985A4 (en) * 1995-12-22 1999-03-17 Idemitsu Petrochemical Co PROCESS FOR PRODUCING sec-BUTYL ACRYLATE
KR20010055010A (ko) * 1999-12-09 2001-07-02 이영일 2-하이드록시에틸 아크릴레이트의 제조방법
JP4323699B2 (ja) * 2000-08-18 2009-09-02 株式会社日本触媒 イオン交換樹脂の脱水方法およびその用途
KR101845120B1 (ko) * 2010-12-21 2018-04-03 쓰리엠 이노베이티브 프로퍼티즈 컴파니 이차 알킬 (메트)아크릴레이트로부터 유도된 중합체

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE590370A (es) * 1959-04-29 1900-01-01
DE2358625B2 (de) * 1973-11-24 1979-03-01 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Isopropylacrylat oder Isopropylmethacrylat
US4293499A (en) * 1980-02-08 1981-10-06 Celanese Corporation Process for producing a carboxylate ester using a supported acidic catalyst
JPH07116103B2 (ja) * 1986-11-27 1995-12-13 三菱レイヨン株式会社 メタクリル酸ｔ−ブチルの製造法

Also Published As

Publication number Publication date
JPH06104645B2 (ja) 1994-12-21
JPH06192176A (ja) 1994-07-12
EP0445859A1 (en) 1991-09-11
US5138092A (en) 1992-08-11
DE69100955D1 (de) 1994-02-24
CA2036720A1 (en) 1991-09-06
CA2036720C (en) 1997-03-04
EP0445859B1 (en) 1994-01-12
DK0445859T3 (da) 1994-03-07
DE69100955T2 (de) 1994-05-19
ATE100076T1 (de) 1994-01-15

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