EP4328377A1 - Strukturierungsstoff mit unterschichtwulsten und verfahren zu dessen herstellung - Google Patents
Strukturierungsstoff mit unterschichtwulsten und verfahren zu dessen herstellung Download PDFInfo
- Publication number
- EP4328377A1 EP4328377A1 EP23166785.8A EP23166785A EP4328377A1 EP 4328377 A1 EP4328377 A1 EP 4328377A1 EP 23166785 A EP23166785 A EP 23166785A EP 4328377 A1 EP4328377 A1 EP 4328377A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- structuring
- beads
- fabric
- sublayer
- nozzle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011324 bead Substances 0.000 title claims abstract description 141
- 239000004744 fabric Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims description 13
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 12
- 230000000284 resting effect Effects 0.000 claims abstract description 5
- 238000001125 extrusion Methods 0.000 claims description 41
- 239000002759 woven fabric Substances 0.000 claims description 20
- 239000010410 layer Substances 0.000 description 14
- 239000012260 resinous material Substances 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 241000880493 Leptailurus serval Species 0.000 description 1
- ILVGMCVCQBJPSH-WDSKDSINSA-N Ser-Val Chemical compound CC(C)[C@@H](C(O)=O)NC(=O)[C@@H](N)CO ILVGMCVCQBJPSH-WDSKDSINSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- AFJYYKSVHJGXSN-KAJWKRCWSA-N selamectin Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1C(/C)=C/C[C@@H](O[C@]2(O[C@@H]([C@@H](C)CC2)C2CCCCC2)C2)C[C@@H]2OC(=O)[C@@H]([C@]23O)C=C(C)C(=N\O)/[C@H]3OC\C2=C/C=C/[C@@H]1C AFJYYKSVHJGXSN-KAJWKRCWSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/006—Making patterned paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/0027—Screen-cloths
Definitions
- the invention concerns a structuring fabric for use in a machine to produce a structured fiber web, preferably a structured tissue fiber web, the structuring fabric having a machine direction, a cross machine direction and a thickness direction, wherein the structuring fabric comprises a woven base fabric, the woven base fabric having a web facing side and a machine side, and wherein the structuring fabric further comprises a plurality of structuring-beads of polymeric material on the web facing side of the woven base fabric, the structuring-beads being suitable to provide a visible structure to the fiber web that is produced on the structuring fabric. Furthermore, the invention concerns a method of producing such a structuring fabric.
- structuring fabrics sometimes also called “structured fabrics” or “molding fabrics", are already known. They are often used in the production of bulky tissue webs.
- the structuring-beads need to be of a certain minimum dimension to be suitable of imparting a visible structure into the fiber web produced thereon.
- the structuring-beads can have a substantially square cross-section of 0.5 mm x 0.5 mm. The smallest dimension of the structuring-beads should be at least 0.25 mm.
- WO 00/75424 A1 discloses such a fabric for making strong, soft, absorbent paper products.
- the content of WO 00/75424 A1 is incorporated herein by reference.
- This document teaches to extrude a fluid resinous material onto a reinforcing element, such as a woven fabric, according to a desired predetermined pattern and then solidifying the patterned resinous material. After solidification the resinous material is attached to the reinforcing element.
- a portion of such a structuring fabric 10 known from the prior art is shown in a cross-sectional view along the machine direction MD in figure 1 .
- a problem that can be observed with such a structuring fabric 10 is that the bonding of the extruded structuring-beads 14 to the woven base fabric 12 is sometimes insufficient.
- the structuring fabric 10 is circulated at high speeds in a corresponding web making machine and/or if high forces are applied to the structuring fabric 10, such as in a press nip, it can happen that the structuring-beads 14 peel away from the woven base fabric 12.
- the extruded structuring-beads 14 have only a very limited contact area with the web facing side 16 of the woven base fabric 12. In other words, the extruded structuring-bead 14 hardly penetrates the volume of the woven base fabric 12 in thickness direction TD from its upper, web facing side 16 towards its lower, machine side 18. Instead, it has only local contact to individual yarn knuckles on the web facing side 16 of the woven fabric 12.
- the structuring-beads should have a substantially rectangular cross-section, wherein the sidewalls of the structuring-beads should be substantial perpendicular to the web facing surface of the woven fabric.
- this is difficult to achieve if the viscosity of the resinous material is reduced.
- the still soft structuring-beads are forced into the woven base fabric e.g. by a calendaring device as proposed in WO 00/75424 A1 .
- the problem is solved by the generic structuring fabric as described at the beginning wherein the structuring-beads are resting on an upper foundation surface of corresponding sublayer-beads of polymeric material, the sublayer-beads thereby providing a foundation for the structuring-beads.
- sublayer-beads below the structuring beads it is possible to significantly improve the strength of the bonding of the structuring-beads to the web facing side of the woven base fabric, without adversely affecting the cross-sectional shape of the structuring-beads.
- the sublayer-beads can protrude deeper into the volume of the woven base fabric to have a larger contact area with the yarns of the woven base fabric, while providing a good foundation for the structuring-beads that rest thereon.
- the polymeric material of the sublayer-beads could be for example silicone, in particular a two-component silicone.
- the form of the upper foundation surface of the sublayer-beads substantially corresponds to the form of a lower surface of the corresponding structuring-beads that rest thereon.
- the dimensional extensions of the sublayer-beads within the plane of the web facing side of the woven base fabric can be substantially the same as the dimensional extensions of the structuring-beads. That way, the structuring-beads can be fully supported by the sublayer-beads while at the same time the sublayer-beads do not or do hardly reduce permeability of the structuring fabric.
- the upper foundation surface of the sublayer-beads is substantially flat. At least the upper foundation surface of the sublayer-beads shall be significantly smoother compared to the web facing surface of the woven base fabric, which is characterized by a plurality of individual yarn knuckles.
- the woven base fabric can be a single layer weave or can comprise serval layers.
- the layer defining the web facing side of the woven base fabric has a plain weave pattern.
- a plain weave pattern the warp and weft yarns cross at right angles, aligned so they form a simple criss-cross pattern.
- Each weft yarns crosses the warp yarns by going over one, then under the next, and so on.
- the next weft yarn goes under the warp yarns that its neighbor went over, and vice versa.
- irregularities on the web facing side of the woven base structure can already be kept small.
- the sublayer-beads can be provided substantially within the volume of the woven base fabric. This maximizes their contact area with the yarns of the woven base fabric.
- the woven base fabric is a single-layer woven fabric or a multi-layer woven fabric, it comprises an upper layer, that defines the web facing side of the woven base fabric.
- the upper layer is formed from upper cross-machine direction yarns that are interwoven with upper machine direction yarns.
- the sublayer-beads extend so deeply into the woven base fabric that they create a form-fit connection with at least some of the upper cross-machine direction yarns at their deepest points, that is where these upper cross-machine direction yarns pass under the upper machine direction yarns.
- the sublayer beads preferably surround the upper cross-machine direction yarns at their deepest points by more than half of their diameter to create such a form-fit connection.
- the sub-layer beads do not extend deeper than the thickness of the upper layer into the woven base fabric, so as not to reduce the void volume of the woven base fabric too much.
- structuring-beads have a substantially rectangular cross-sectional shape.
- the structuring-beads may have a substantially square cross-sectional shape.
- substantially shall mean here that the sidewalls of the structuring beads do not necessarily have to be exactly flat and/or that the corners of the substantially rectangular cross-sectional shape are not allowed to be slightly rounded.
- the structuring-beads can form continuous lines on the web facing surface of the woven fabric, wherein preferably the continuous lines substantially extend in machine direction of the structuring fabric.
- substantially in machine direction means in this context that their main extension is in machine direction and not in cross machine direction of the structuring fabric.
- the structuring-beads do not have to extend precisely as straight lines in machine direction.
- the structuring beads may have a wavy configuration or may form a zig-zag pattern. They also may have in total a small inclination angle with respect to the machine direction of the structuring fabric.
- the structuring beads do not cross each other. Instead, they can extend substantially parallel to each other.
- the structuring-beads form continuous lines on the web facing surface of the woven fabric, this implies that they can not be formed by extruding the resinous material through a rotary screen. Instead, a method called "nozzle extrusion deposition" is preferably applied.
- the polymeric material for forming the sublayer-beads may have a lower viscosity than the polymeric material for forming the structuring-beads.
- a lower viscosity can be beneficial to enhance the penetration of the material into the volume of the woven base fabric.
- the polymeric material of the structuring-beads is the same as the polymeric material of the sublayer-beads. A good bonding can be achieved especially achieved if the two beads are applied in a so-called "wet-in-wet" method.
- Another aspect of the present invention refers to a method of producing a structuring fabric of the present invention as described above, comprising the following steps:
- step a) might be read as "into” since the polymeric material forming the sublayer-bead shall at least partly, preferably completely, penetrate into the woven base fabric.
- the nozzles may be stationary while the woven base fabric is moved in machine direction of the structuring fabric to be produced. This will result in a pattern of straight lines extending in machine direction. If the pattern shall be a zig-zag configuration or a wavy configuration, the nozzles may be movable in cross machine direction during the manufacturing process. An example is illustrated in figure 4 of WO 00/75424 A1 .
- the first extrusion nozzle and the second extrusion nozzle are preferably integrally formed in one extrusion die. Furthermore, it is advantageous if the distance between the two different nozzles is kept small. With respect to the moving direction of the woven base fabric during the production process of the structured fabric, the two nozzles are preferably located one behind the other so that first the sublayer-bead is applied onto the web facing side of the woven base fabric and then, on top of the sublayer-bead, the structuring bead is applied.
- a plurality of pairs of first extrusion nozzles and second extrusion nozzles are integrally formed in one extrusion die.
- the first extrusion nozzle is formed in a first surface of an extrusion die which first surface is substantially parallel to the web facing surface of the woven fabric during the extrusion process, wherein the second extrusion nozzle is formed in a second surface of an or the extrusion die which second surface is inclined with respect to the web facing surface of the woven fabric during the extrusion process.
- the distance of the first extrusion nozzle to the web facing surface of the woven fabric is preferably larger than the distance of the second extrusion nozzle to the web facing surface of the woven fabric during the extrusion process.
- the structuring-bead can be extruded in step b) at a time when the sublayer-bead has not been cured yet, at least not completely. This is sometimes called "wet-in-wet" method.
- the two beads may be formed from the same polymeric material, such as silicone, and may be cured substantially at the same time, it is still possible to clearly recognize, at least in a laboratory, the border between the two beads in the final product.
- first nozzle is substantially rectangular shaped
- second nozzle is substantially star-shaped.
- the star-shaped nozzle can lead to a structuring-bead having a substantially rectangular, in particular substantially square, formed cross-section.
- the width of the first, substantially rectangular shaped nozzle is substantially the same as the smallest width of the second, substantially star-shaped nozzle and/or the length of the first, substantially rectangular shaped nozzle is substantially half the length of the second, substantially star-shaped nozzle.
- width refers to its extension in cross machine direction of the structuring fabric during the production process
- length refers to its extension in machine direction of the structuring fabric during the production process.
- Figure 2 shows in cross-section a portion of a structuring fabric 10 according to the present invention. This figure resembles figure 1 showing a corresponding portion of a structuring fabric known from the prior art, as described above. Therefore, the same reference signs are used for the same features, and it is referred to the description of figure 1 above regarding these features. In the following, only the differences between the embodiments of figure 1 and figure 2 will be explained.
- the structuring-bead 14 does not only have a limited local contact with the yarn knuckles that characterize the web facing side 16 of the woven base fabric 12 but the structuring-bead 14 rests with its lower surface on an upper foundation surface of a sublayer-bead 20.
- the sublayer-bead 20 is formed preferably completely within the volume of the woven base layer 12, thus having a strong bond to the woven base layer 12. Its upper foundation surface, i.e. its surface that is facing away from the machine side 18 of the woven base layer 12, is substantially flat, thereby providing a very good foundation for the structuring bead 14 resting thereon.
- the dimension of the sublayer-bead 20 may be smaller than the dimension of the structuring-bead 14.
- the woven base fabric 12 is formed as a multi-layer woven fabric but it could also be a single-layer woven fabric.
- the upper layer, that defines the web facing side 16 of the woven base fabric 12 is preferably a plain weave.
- the upper layer is formed by upper machine direction yarns 32 interwoven with upper cross-machine direction yarns 34.
- the sublayer-bead 20 extends so deep into the woven base fabric 12 as to create a form-fit connection with the upper cross-machine direction yarns 34 where these upper cross-machine direction yarns 34 pass under the machine direction yarns 34.
- the polymeric material of the sublayer-bead 20 surrounds more than half of the diameter of the upper cross-machine direction yarns 34 at their lowest points.
- the sublayer-bead 20 does not extend deeper into the woven base fabric 12 than the thickness of the upper layer. In thickness direction, the sublayer-bead 20 is almost as thick as the structuring-bead 14 resting thereon.
- the knuckles on the web facing side 16 of the woven fabric only slightly project above the substantially flat upper foundation surface of the sublayer-bead 20.
- the sublayer-bead 20 and the structuring-bead 14 are preferably formed from the same polymeric material, such as a two component silicone. This results in a strong bond between the two beads, especially if the structuring-bead 14 is applied on top of the sublayer-bead 20 at a time when the material of the sublayer-bead 20 has not been cured yet.
- Figure 3 shows an extrusion die 22 adapted to simultaneously apply several structuring-beads 14 and corresponding sublayer-beads 20 onto the web facing side 16 of the woven base fabric 12. More precisely, the extrusion die 22 comprises five pairs of first nozzles 24 and second nozzles 26, to extrude five pairs of sublayer-beads 20 and structuring-beads 14, respectively. For the sake of clarity, two pairs of first nozzles 24 and second nozzles 26 are shown in an enlarged view on the bottom of figure 3 . The first nozzles 24 for extruding the sublayer-beads 20 have a substantially rectangular form, whereas the second nozzles 26 for extruding the structuring-beads 14 have a substantially star-shaped form.
- star-shaped form in this context refers to a form that resembles a square, wherein the lateral edges of the square are not straight but curved toward the center of the star-shaped form.
- the smallest distance between two opposite curved lateral edges is designated here with letter "A".
- This smallest distance A is preferably between 0.3 mm and 1.0 mm, more preferably between 0,6 mm and 0,8 mm.
- the first, substantially rectangular shaped nozzle 24 has a width that substantially corresponds to the smallest distance A of the second, substantially star-shaped nozzle 26.
- the length of the first, substantially rectangular shaped nozzle 24 is significantly smaller than its width. It may be only half the width, i.e. half the smallest distance A of the second, substantially star-shaped nozzle 26.
- the pitch of two directly neighboring pairs of first nozzles 24 and second nozzles 26 is "B".
- the pitch B is measured as the distance from the center of one second nozzle 26 to the center of one of its directly neighboring second nozzles 26.
- the pitch B is preferably between 2 and 6 times the smallest distance A between two opposite curved lateral edges of the first, substantially rectangular shaped nozzle 24.
- the first nozzles 24 are provided within a first surface 28, whereas the second nozzles 26 are provided within a second surface 30.
- the first surface 28 and the second surface 30 do not lie within the same plane. In other words, the second surface 30 is inclined with respect to the first surface 28.
- the first surface 28 of the extrusion die 22 is placed close and substantially parallel to the web facing side 16 of the woven base fabric 12.
- the extrusion die 22 may be stationary while the woven base fabric 12 moves in moving direction v, so as to form a pattern of structuring-beads 14 that extend in parallel straight lines. However, if it is preferred to provide the structuring fabric 10 with another pattern of structuring-beads 14, such as a zig-zag pattern or a wavy pattern, the extrusion die 22 may be moved, e.g. back and forth, orthogonally to the moving direction v during the manufacturing process, i.e. orthogonally to the image plane of figure 4 .
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- Absorbent Articles And Supports Therefor (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP23166785.8A EP4328377A1 (de) | 2023-04-05 | 2023-04-05 | Strukturierungsstoff mit unterschichtwulsten und verfahren zu dessen herstellung |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP23166785.8A EP4328377A1 (de) | 2023-04-05 | 2023-04-05 | Strukturierungsstoff mit unterschichtwulsten und verfahren zu dessen herstellung |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4328377A1 true EP4328377A1 (de) | 2024-02-28 |
Family
ID=85979603
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP23166785.8A Pending EP4328377A1 (de) | 2023-04-05 | 2023-04-05 | Strukturierungsstoff mit unterschichtwulsten und verfahren zu dessen herstellung |
Country Status (1)
Country | Link |
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EP (1) | EP4328377A1 (de) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996000812A1 (en) * | 1994-06-29 | 1996-01-11 | The Procter & Gamble Company | Web patterning apparatus comprising a felt layer and a photosensitive resin layer |
WO2000075424A1 (en) | 1999-06-07 | 2000-12-14 | The Procter & Gamble Company | Papermaking belt |
WO2002061191A2 (en) * | 2000-10-24 | 2002-08-08 | The Procter & Gamble Company | Fibrous structure having increased surface area and process for making same |
WO2010030298A1 (en) * | 2008-09-11 | 2010-03-18 | Albany International Corp. | Permeable belt for the manufacture of tissue, towel and nonwovens |
US20180119354A1 (en) * | 2016-10-27 | 2018-05-03 | The Procter & Gamble Company | Deflecting Member for Making Fibrous Structures |
-
2023
- 2023-04-05 EP EP23166785.8A patent/EP4328377A1/de active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996000812A1 (en) * | 1994-06-29 | 1996-01-11 | The Procter & Gamble Company | Web patterning apparatus comprising a felt layer and a photosensitive resin layer |
WO2000075424A1 (en) | 1999-06-07 | 2000-12-14 | The Procter & Gamble Company | Papermaking belt |
WO2002061191A2 (en) * | 2000-10-24 | 2002-08-08 | The Procter & Gamble Company | Fibrous structure having increased surface area and process for making same |
WO2010030298A1 (en) * | 2008-09-11 | 2010-03-18 | Albany International Corp. | Permeable belt for the manufacture of tissue, towel and nonwovens |
US20180119354A1 (en) * | 2016-10-27 | 2018-05-03 | The Procter & Gamble Company | Deflecting Member for Making Fibrous Structures |
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