EP3371142A4 - Processes and systems for converting hydrocarbons to cyclopentadiene - Google Patents

Processes and systems for converting hydrocarbons to cyclopentadiene Download PDF

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Publication number
EP3371142A4
EP3371142A4 EP16862675.2A EP16862675A EP3371142A4 EP 3371142 A4 EP3371142 A4 EP 3371142A4 EP 16862675 A EP16862675 A EP 16862675A EP 3371142 A4 EP3371142 A4 EP 3371142A4
Authority
EP
European Patent Office
Prior art keywords
cyclopentadiene
processes
systems
converting hydrocarbons
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16862675.2A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP3371142A1 (en
Inventor
Larry L. Iaccino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3371142A1 publication Critical patent/EP3371142A1/en
Publication of EP3371142A4 publication Critical patent/EP3371142A4/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B01J29/61—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789 containing iron group metals, noble metals or copper
    • B01J29/62—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP16862675.2A 2015-11-04 2016-10-07 Processes and systems for converting hydrocarbons to cyclopentadiene Withdrawn EP3371142A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562250697P 2015-11-04 2015-11-04
EP16153727 2016-02-02
PCT/US2016/056048 WO2017078905A1 (en) 2015-11-04 2016-10-07 Processes and systems for converting hydrocarbons to cyclopentadiene

Publications (2)

Publication Number Publication Date
EP3371142A1 EP3371142A1 (en) 2018-09-12
EP3371142A4 true EP3371142A4 (en) 2018-10-24

Family

ID=55304867

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16862675.2A Withdrawn EP3371142A4 (en) 2015-11-04 2016-10-07 Processes and systems for converting hydrocarbons to cyclopentadiene

Country Status (5)

Country Link
EP (1) EP3371142A4 (ja)
JP (1) JP6640365B2 (ja)
CN (1) CN108349839B (ja)
CA (1) CA3004332C (ja)
WO (1) WO2017078905A1 (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3371138A4 (en) 2015-11-04 2018-12-05 ExxonMobil Chemical Patents Inc. Process for conversion of acyclic c5 compounds to cyclic c5 compounds and catalyst composition for use therein
US10364200B2 (en) 2017-05-03 2019-07-30 Exxonmobil Chemical Patents Inc. Processes and systems for the conversion of acyclic hydrocarbons
CN110961127A (zh) * 2019-12-09 2020-04-07 大连理工大学 一种以类水滑石为前驱体制备负载型dcpd树脂加氢催化剂的方法
CN113083360B (zh) * 2019-12-23 2023-07-25 中国石油化工股份有限公司 一种纳米碳纤维为载体的钛硅分子筛催化剂的制备方法

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US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
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US4886926A (en) * 1988-06-24 1989-12-12 Mobil Oil Corporation Catalytic dehydrogenation of hydrocarbons over tin-containing crystalline microporous materials
US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
WO2013176712A1 (en) * 2012-05-25 2013-11-28 Exxonmobil Chemical Patents Inc. Dicyclopentadiene based resin compositions and articles manufactured therefrom

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US2438400A (en) * 1945-11-24 1948-03-23 Sun Oil Co Preparation of cyclopentadiene
US2438404A (en) * 1948-01-20 1948-03-23 Sun Oil Co Treatment of hydrocarbons
DE2535809A1 (de) * 1974-08-13 1976-03-04 Shell Int Research Verfahren zur herstellung von cyclischen c tief 5-kohlenwasserstoffen
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US20090062446A1 (en) * 2007-09-04 2009-03-05 General Electric Company Composition and associated method
US20130153456A1 (en) * 2011-12-15 2013-06-20 General Electric Company Containment case and method of manufacture
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JESPER J. H. B. SATTLER ET AL: "Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides", CHEMICAL REVIEWS, vol. 114, no. 20, 22 October 2014 (2014-10-22), US, pages 10613 - 10653, XP055237672, ISSN: 0009-2665, DOI: 10.1021/cr5002436 *
See also references of WO2017078905A1 *
V. SH. FEL'DBLYUM ET AL: "Cyclization and dehydrocyclization of C5 hydrocarbons over platinum nanocatalysts and in the presence of hydrogen sulfide", DOKLADY. CHEMISTRY, vol. 424, no. 2, February 2009 (2009-02-01), RU, pages 27 - 30, XP055267350, ISSN: 0012-5008, DOI: 10.1134/S0012500809020025 *
ZEESHAN NAWAZ: "Light alkane dehydrogenation to light olefin technologies: a comprehensive review", REVIEWS IN CHEMICAL ENGINEERING, vol. 31, no. 5, 31 August 2015 (2015-08-31), NL, pages 413 - 436, XP055273805, ISSN: 0167-8299, DOI: 10.1515/revce-2015-0012 *

Also Published As

Publication number Publication date
JP6640365B2 (ja) 2020-02-05
WO2017078905A1 (en) 2017-05-11
EP3371142A1 (en) 2018-09-12
CA3004332C (en) 2019-12-31
CN108349839A (zh) 2018-07-31
CA3004332A1 (en) 2017-05-11
JP2018532794A (ja) 2018-11-08
CN108349839B (zh) 2021-04-09
WO2017078905A8 (en) 2017-08-10

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