EP3303960B1 - Rohrofen und verfahren zur chemischen umsetzung - Google Patents
Rohrofen und verfahren zur chemischen umsetzung Download PDFInfo
- Publication number
- EP3303960B1 EP3303960B1 EP16731519.1A EP16731519A EP3303960B1 EP 3303960 B1 EP3303960 B1 EP 3303960B1 EP 16731519 A EP16731519 A EP 16731519A EP 3303960 B1 EP3303960 B1 EP 3303960B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluid
- tube furnace
- heat transfer
- volume
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/10—Rotary-drum furnaces, i.e. horizontal or slightly inclined internally heated, e.g. by means of passages in the wall
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F5/00—Elements specially adapted for movement
- F28F5/06—Hollow screw conveyors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/02—Rotary-drum furnaces, i.e. horizontal or slightly inclined of multiple-chamber or multiple-drum type
- F27B7/04—Rotary-drum furnaces, i.e. horizontal or slightly inclined of multiple-chamber or multiple-drum type with longitudinal divisions
- F27B2007/046—Radial partitions
- F27B2007/048—Radial partitions defining an helical chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0056—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for ovens or furnaces
- F28D2021/0057—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for ovens or furnaces for melting materials
Definitions
- the invention relates to a tube furnace with a housing which contains a heat exchanger which has a wall which separates a first volume from a second volume, wherein the second volume is adapted to receive at least one educt and the first volume is adapted to receive a heat transfer fluid , Furthermore, the invention relates to a method for the chemical reaction of educts in a second volume, in which the process space by means of at least one heat transfer medium flowing through a heat transfer fluid heat or removed. Devices and methods of the type mentioned can be used for example for pyrolysis or for the heat treatment of solids.
- a tube furnace which contains an Archimedes spiral as a heat exchanger. Heat is supplied to the reactants by hot ash is transported in countercurrent through the Archimedes spiral. As a result, the heat remaining in the ash after combustion can be used to heat the tube furnace.
- the GB 1 440 525 A describes a drying device for flowing materials, this device having, inter alia, balls.
- the invention is therefore an object of the invention to provide a tube furnace and a method for its application, in which the temperature is better controlled and reliable operation is possible.
- the invention relates to a tube furnace with a housing containing a heat exchanger.
- the heat exchanger has a wall which separates a first volume from a second volume.
- a first, self-contained volume is formed by the boundary wall of the heat exchanger and a second, self-contained volume of the wall or the housing of the tube furnace on the one hand and the outer surface of the heat exchanger on the other hand is limited.
- This allows a heat transfer between the first volume and the second volume, without the substances or the streams mix or contact each other.
- heat can be supplied to a reactant located in the tube furnace when the heat transfer fluid is at a higher temperature than the educt. If, in other embodiments of the invention, the reactant reacts exothermically in the tube furnace and thus has a higher temperature than the heat transfer fluid, heat can be removed from the educt or from the process space.
- the heat carrier fluid contains at least one spherical fluid.
- a spherical fluid consists of a plurality of balls of predeterminable size and Nature.
- all balls of the ball fluid may have an identical shape and / or size within the usual tolerances.
- the balls may have a different size or a size distribution and / or consist of different materials. Since the balls are round in the usual tolerances, they have no sharp edges, so that the abrasive wear is reduced by the heat transfer fluid in the heat exchanger. Furthermore, due to their smooth surface, the balls do not tend to catch or form agglomerates.
- the spherical fluid can flow through the heat exchanger like a liquid.
- solid-state spherical fluid can provide heat at a higher temperature level without phase transition in the heat exchanger.
- the spherical fluid may have a higher heat capacity than a liquid or gaseous heat transfer fluid, so that the mass flow may be reduced.
- the heat exchanger can be made smaller, so that the tube furnace requires less overall space.
- the ball fluid further has the advantage that it does not completely fill the heat exchanger or the flow channels.
- the heat exchanger can optionally also be flowed through by a gaseous heat carrier in order to adapt the temperature of the ball fluid to predefinable setpoint values or to keep it within predefinable setpoint values.
- the spherical fluid has spheres with a diameter of about 1 mm to about 50 mm. In other embodiments of the invention, the spherical fluid may have spheres having a diameter of about 5 mm to about 50 mm. In still other embodiments of the invention, the spherical fluid may have spheres having a diameter of about 15 mm to about 30 mm.
- spheres in the stated size range can store enough heat to be able to handle technically manageable mass flows as a heat transfer fluid to be used.
- spheres in this size range may be multilayered, for example containing a core of a first material and a cladding of a second material.
- the first and second materials may each be metals or alloys. This allows, for example, to provide a core with high heat capacity and / or high melting temperature with a coating which is chemically inert and / or has catalytic properties.
- the melting temperature of the cladding may be higher than the melting temperature of the core.
- the core may be a phase change material or a latent heat storage, which can provide a comparatively large amount of heat at a constant temperature at its melting temperature.
- the balls of the spherical fluid may comprise at least one chemical element having atomic numbers from 3 to 6 or atomic numbers from 11 to 14 or atomic numbers from 19 to 34 or ordinal numbers from 37 to 52 or atomic numbers from 55 to 84 or with atomic numbers from 87 to 116 included.
- the balls of the spherical fluid may contain or consist of at least one chemical element of atomic number 13 or atomic numbers from 21 to 30 or from 39 to 48 or from 57 to 80 or from 89 to 112.
- the balls of the spherical fluid may contain or consist of at least copper and / or iron and / or aluminum and / or a ceramic.
- the spheres may contain or consist of a transition metal.
- Such balls may be characterized by high thermal conductivity and / or high heat capacity, so that a correspondingly large amount of heat can be added to the educts located in the process chamber of the tube furnace or removed from them.
- the spherical fluid through the wall of the Heat exchanger is separated from the educts, unwanted side reactions are avoided, which can occur upon contact of the balls with the starting materials.
- the housing of the tube furnace may have a substantially cylindrical cross section and the heat exchanger may include a multi-flight screw conveyor.
- the auger in this case contains a wall which separates an inner screw as the first volume of an outer screw as the second volume, wherein a screw for receiving the at least one educt is set up and the other screw for receiving the heat transfer fluid is set up.
- the screw conveyor allows the simultaneous transport of the educt or the resulting product through the tube furnace as well as the transport of the heat transfer fluid.
- the screw conveyor can also effect thorough mixing of the educts so that the reaction proceeds more uniformly.
- the educts or the heat transfer fluid can be transported in co-current through the tube furnace, ie the material flow and the heat transfer fluid enter at one end and at the other end.
- the transport can take place in countercurrent, ie, the inlet side of a material flow corresponds to the outlet side of the heat transfer fluid.
- the auger may have an axis which carries the flights and about which the auger is rotatable during operation of the kiln. This avoids that the educts or products fall through the free middle part of the screw conveyor through and thereby be transported unevenly through the tube furnace.
- drive means can be flanged particularly easily to the axis to set the screw conveyor in rotation.
- the axis may be hollow to allow for recirculation of the spherical fluid.
- the flow and the return of the heat transfer fluid can be done on one side of the tube furnace, so that the tube furnace is easier to operate.
- the multi-flight auger may be a sequential auger having a plurality of different longitudinal sections.
- a plurality of longitudinal sections may be interconnected by a single shaft.
- different longitudinal sections can have different drive means, so that the rotational speed and / or the drive torque of different longitudinal sections can be controlled independently of one another.
- different longitudinal sections of the screw conveyor may have a different pitch and / or a different cross section, so that the mass flow and / or the area available for heat transfer are different in different longitudinal sections.
- the self-adjusting temperature and / or the amount of heat transferred to the respective application can be adjusted. This also makes it possible to produce an intermediate product and an end product in different longitudinal sections of the tube furnace or the screw conveyor, if this in a first longitudinal section produced product is converted as starting material in a second longitudinal section.
- the tube furnace further includes a recuperator, in which the spherical fluid is brought into contact with a gaseous heat carrier.
- the gaseous heat carrier allows the heating of the ball fluid before it enters the supply line of the heat exchanger or screw conveyor.
- the ball fluid leaves the tube furnace via a return and is then returned to the recuperator to recover heat from a hot gas stream, such as a flue gas stream formed during combustion. If the balls are provided with a catalytically active coating, they can be used simultaneously for flue gas detoxification.
- the recuperator can be used to transfer the heat from the spherical fluid to a gaseous heat carrier and thereby dissipate it into the environment.
- the recuperator may also include a screw conveyor. This allows the simultaneous cooling or heating of the spherical fluid and its promotion by the recuperator or the promotion of the return of the heat exchanger to the flow of the heat exchanger of the tube furnace.
- the tube furnace may further include a heater, with which a heat flow through the wall of the cylindrical housing can be generated.
- a heat flow through the outer wall can be provided or a cooling, ie a heat transfer through the wall of the cylindrical housing, can be prevented or reduced. This allows on the one hand a more accurate temperature control inside the tube furnace or the supply of a higher amount of heat to bring a large mass flow of educts quickly to a predetermined target temperature or to bring the educts to a higher temperature level.
- the heat exchanger of the tube furnace in addition to the ball fluid a further gaseous heat transfer medium can be supplied.
- a further gaseous heat transfer medium can be supplied.
- This allows, for example, a post-heating of the spherical fluid when it cools on initial contact with the still cold educt. Since the supply of a gaseous heat carrier can be quickly absorbed or interrupted, this can also serve to make the control of the temperature prevailing in the tube furnace or to reduce the temperature fluctuations occurring during the control.
- a base heat flow is supplied by the spherical fluid and additional thermal energy is provided to control the temperature across the gaseous heat transfer medium. This possibility characterizes the tube furnace according to the invention, since liquid heat carriers or the ash particles known from the prior art can not be combined with an additional gas stream.
- the tube furnace 1 comprises a housing 10 with a wall 101.
- the housing 10 has at least one approximately circular inner cross section, so that the interior has the shape of a circular cylinder.
- the wall 101 of the housing 10 is uniformly thick, so that the outer shape takes the form of a circular cylinder.
- the housing 10 in the illustrated embodiment the shape of a round tube.
- the housing 10 has a first end 11 and a second end 12. At the first end 11 is the flow of heat transfer fluid and the second end 12 is the return of the heat transfer fluid. Adjacent to the first end 11, the filling opening 15 is arranged for educts to be processed. These can be supplied to the interior of the housing 10 in particular as a solid, but alternatively also in gaseous or liquid form. Adjacent to the second end 12 is an outlet 16 for gaseous reaction products and an outlet 17 for solid or liquid reaction products. Both the heat transfer fluid and the reactants to be reacted are conveyed by a screw conveyor 2 from the first end 11 to the second end 12 of the tube furnace 1. Since the screw conveyor 2 is a multi-start screw conveyor, only heat transfer takes place, but no mass transfer between the heat transfer fluid and the reactants to be reacted.
- FIG. 2 shows, it is in the screw conveyor 2 to a multi-start screw conveyor, in which a first volume 21 and a second volume 22 by a wall 23 are separated from each other.
- the second volume 22 is directly accessible via the filling opening 15.
- an inlet region 25 in which the first volume 21 is open to the outside.
- a baffle 26 In order to prevent penetration of the other medium into the opening 25 avoid this is separated with a baffle 26 from the second volume 22.
- the screw conveyor 2 rotates, wherein the educts are transported in the second volume 22 and a heat transfer fluid in the first volume 21 is transported.
- This allows a heat transfer via the wall 23, so that the educts in the second volume 22 are either heated or cooled, depending on whether the supplied via the opening 25 heat transfer fluid has a higher or lower temperature. Since the available surface of the wall 23 of the screw conveyor 2 is larger than the wall 101 of the housing 10, a significantly larger heat flow per unit time can be transmitted than would be possible with pure heating or cooling of the housing 10.
- an axis 24 is further seen, which is hollow and has an opening 241 on its front side.
- the interior of the hollow axle 24 may optionally be used to transport the heat transfer fluid, for example, to recirculate the fluid from the second end 12 to the first end 11.
- a recuperator 3 which also has an approximately tubular housing 30 with a conveyor screw 35 disposed therein.
- the second end 32 of the recuperator 3 is arranged lower than the second end 12 of the housing 10. Accordingly, the first end 31 of the recuperator 3 is arranged higher than the first end 11 of the housing 10.
- the recuperator is not only the supply or discharge thermal energy in the heat transfer fluid, but also the transport of the heat transfer fluid from the return to the flow of the tube furnace first
- FIG. 3 Exemplary is in FIG. 3 the transition region at the first end 11 of the housing 10 is shown. This has a reservoir or a template for the heat transfer fluid.
- the the Recuperator 3 leaving the first end 1 balls of the spherical fluid fall from the first end 31 of the recuperator 3 down and are collected by the reservoir at the first end 11 of the housing 10.
- the opening 25 is periodically immersed in the template and takes on a plurality of balls of the spherical fluid. These are subsequently conveyed through the first volume 21 of the screw conveyor 2 to the second end 12 of the tube furnace 1.
- the balls of the spherical fluid leave the conveyor screw and are supplied in an analogous manner to the recuperator 3 via its second end 32. This allows a cyclic circulation of the ball fluid used as heat transfer fluid.
- the spherical fluid can be heated or cooled, so that it passes with a predeterminable temperature in the flow at the first end 11 of the tube furnace 1.
- the required amount of heat can be introduced specifically into the reactant educts.
- the degree of filling of the first volume 21 can be matched to the degree of filling of the second volume 22.
- Balls of at least one metal, a ceramic or a salt may also be solid at higher temperatures, for example 150 to 900 ° C or between about 250 and 700 ° C. As a result, heat can be provided at a higher temperature level than, for example, with water or oil as a heat transfer fluid.
- FIG. 4 shows an alternative embodiment for supplying the heat transfer fluid. How FIG. 4 shows, this embodiment also uses within the tube furnace 1, a multi-speed screw conveyor, in which a first volume 21 and a second volume 22 by a wall 23 are separated from each other. The first volume 21 is above the hollow axis 24 accessible. In order to allow the heat transfer fluid access to the first volume 21, located at the end of the axis 24, which is hollow, an opening. In extension of the axis 24 is a catchy in the example shown feed screws 45 with a shaft 451 as part of a feed conveyor 4, which is the ball fluid from a heater, such as a recuperator 3, via a template 47 in the interior of the hollow shaft 24 of the multi-speed auger 2 promotes.
- the feed conveyor 4 may be provided with a housing 48 which may include optional cooling fins 485.
- baffle plate 245 Inside the hollow axis 24 of the multi-start screw conveyor 2 is a baffle plate 245, which deflects the ball fluid and into the first volume 21 of the screw conveyor 2 passes.
- first volume 21 in this embodiment has no immediate opening, such as the opening 25 in the embodiments described above, both the gas-tight separation of the tube furnace to the outside and the gas-tight separation of the first volume 21 and the second volume 22 is ensured.
- a pipe 46 which surrounds the feed screw 45 serves.
- This can be made of a material of low thermal conductivity, for example a ceramic.
- the tube can be provided with a heat-insulating coating, for example an oxide ceramic or vermiculite. As a result, heat losses can be reduced.
- the axis 24 of the screw conveyor 2 can be extended into the feed conveyor 4.
- the tube 46 may be omitted in this case or be replaced by a heat-insulating coating of the longitudinal section of the axis 24 located in the feed conveyor 4.
- a pyrolysis of halogen-containing plastics is to be performed.
- Such processes can be used for example for the pyrolysis of phenol-formaldehyde resins, which are often used for the production of printed circuit boards.
- the printed circuit boards contain significant amounts of recyclable aluminum and copper.
- the pyrolysis temperature for such circuit boards or a granulate produced therefrom should be above 580 ° C. However, in order to recover aluminum as easily as possible, the temperature should be below 660 ° C.
- the tube furnace according to the invention solves this problem, since the spherical fluid, for example, when using balls of copper or iron, can provide heat at the desired high temperature level.
- a large thermal power can be delivered to the reactants.
- the formation of highly toxic, persistent polybrominated dioxin and furan compounds is prevented by the catalytic action of the copper surface, since the copper of the spherical fluid through the wall 23 is separated from the educts.
- exemplary operating parameters for a tube furnace 1 with an inner diameter of 340 mm, a heated length of 4000 mm and a pitch of the screw from 110 to 150 mm are specified.
- a pyrolysis temperature of 450 ° C is to be provided at a total heat output of 3.0 kW.
- the screw conveyor 2 used for this purpose has a pitch of 150 mm.
- steel balls are used with an inlet temperature at the flow of 500 ° C.
- an average speed of the screw conveyor 2 of 27 h -1 and a drive power of 0.6 W results in a mass flow of the spherical fluid of 450 kg / h and an outlet temperature of the spherical fluid of 464 ° C. , The heat output is thus 2.6 kW.
- the remaining heat output of 400 W is provided via an additional heat exchanger to the housing 10 of the tube furnace 1. This transfers heat directly through the wall 101 of the housing 10 into the interior of the tube furnace 1.
- This additional heat exchanger a mass flow of 100 kg / h of moist flue gas is fed with an inlet temperature of 500 ° C.
- the outlet temperature is then 487 ° C, so that the total heat output of the process is 3.0 kW.
- a pyrolysis temperature of 600 ° C is to be provided at a total heat output of 3.5 kW.
- the screw conveyor 2 used for this purpose has a pitch of 150 mm.
- steel balls are used with an inlet temperature at the flow of 650 ° C.
- an average speed of the screw conveyor 2 of 27 h -1 and a drive power of 0.6 W results in a mass flow of the spherical fluid of 450 kg / h and an outlet temperature of the spherical fluid of 609 ° C.
- the heat output is thus 2.9 kW.
- the remaining heat output of 600 W is provided via an additional heat exchanger on the housing 10 of the tube furnace 1. This transfers heat directly through the wall 101 of the housing 10 into the interior of the tube furnace 1.
- This additional heat exchanger a mass flow of 100 kg / h of moist flue gas is fed with an inlet temperature of 650 ° C.
- the outlet temperature is then 635 ° C, so that the total heat output of the process is 3.5 kW.
- the screw conveyor 2 used for this purpose has a pitch of 130 mm.
- steel balls are used with an inlet temperature at the flow of 500 ° C.
- an average speed of the screw conveyor 2 of 31 h -1 and a drive power of 0.6 W results in a mass flow of the spherical fluid of 450 kg / h and an outlet temperature of the spherical fluid of 460 ° C. , The heat output is thus 2.9 kW.
- the remaining heat output of 400 W is provided via an additional heat exchanger to the housing 10 of the tube furnace 1. This transfers heat directly through the wall 101 of the housing 10 into the interior of the tube furnace 1.
- This additional heat exchanger a mass flow of 100 kg / h of moist flue gas is fed with an inlet temperature of 500 ° C.
- the outlet temperature is then 487 ° C, so that the total heat output of the process is 3.3 kW.
- a pyrolysis temperature of 450 ° C with a heat output of 4.0 kW to be provided.
- the screw conveyor 2 used for this purpose has a pitch of 150 mm.
- steel balls are used with an inlet temperature at the flow of 500 ° C.
- an average speed of the screw conveyor 2 of 27 h -1 and a drive power of 0.6 W results in a mass flow of the spherical fluid of 450 kg / h and an outlet temperature of the spherical fluid of 483 ° C. , The heat output is thus 3.4 kW.
- the remaining heat output of 600 W is provided via an additional heat exchanger on the housing 10 of the tube furnace 1. This transfers heat directly through the wall 101 of the housing 10 in the interior of the tube furnace 1.
- This additional heat exchanger a mass flow of 100 kg / h of moist flue gas is fed with an inlet temperature of 550 ° C.
- the outlet temperature is then 535 ° C, so that the total heat output of the process is 3.5 kW.
- the screw conveyor 2 used for this purpose has a pitch of 110 mm.
- steel balls are used with an inlet temperature at the flow of 530 ° C.
- an average speed of the screw conveyor 2 of 37 h -1 and a drive power of 0.6 W results in a mass flow of the spherical fluid of 450 kg / h and an outlet temperature of the spherical fluid of 468 ° C. , The heat output is thus 4.5 kW.
- the remaining heat output of 500 W is provided via an additional heat exchanger on the housing 10 of the tube furnace 1. This transfers heat directly through the wall 101 of the housing 10 in the interior of the tube furnace 1.
- This additional heat exchanger a mass flow of 100 kg / h of moist flue gas is fed with an inlet temperature of 550 ° C.
- the outlet temperature is then 532 ° C, so that the total heat output of the process is 5.0 kW.
- the heat supplied to the spherical fluid can be obtained from a combustion process.
- the hot flue gas can be introduced directly into the recuperator 3 together with the spherical fluid. Since sufficient free spaces remain between the balls of the spherical fluid, the flue gases can flow through the ball fluid and in this way give off heat to the individual balls. If the individual balls of the spherical fluid have a catalytic coating on their outer side, they can be used simultaneously for flue gas cleaning. Due to the spatial separation of the spherical fluid from the educts to be processed in the tube furnace 1 through the wall 23, this catalytic coating does not have any negative effect on the process taking place in the tube furnace 1.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Furnace Charging Or Discharging (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL16731519T PL3303960T3 (pl) | 2015-05-27 | 2016-05-27 | Piec rurowy i sposób przemiany chemicznej |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102015209742.0A DE102015209742B4 (de) | 2015-05-27 | 2015-05-27 | Rohrofen und Verfahren zur chemischen Umsetzung |
PCT/EP2016/062014 WO2016189138A1 (de) | 2015-05-27 | 2016-05-27 | Rohrofen und verfahren zur chemischen umsetzung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3303960A1 EP3303960A1 (de) | 2018-04-11 |
EP3303960B1 true EP3303960B1 (de) | 2019-11-27 |
Family
ID=56194428
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP16731519.1A Active EP3303960B1 (de) | 2015-05-27 | 2016-05-27 | Rohrofen und verfahren zur chemischen umsetzung |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3303960B1 (es) |
DE (1) | DE102015209742B4 (es) |
ES (1) | ES2769725T3 (es) |
PL (1) | PL3303960T3 (es) |
WO (1) | WO2016189138A1 (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2019552B1 (en) | 2017-09-14 | 2019-03-27 | Torrgas Tech B V | Process to prepare a char product and a syngas mixture |
NL2019553B1 (en) | 2017-09-14 | 2019-03-27 | Torrgas Tech B V | Process to prepare an activated carbon product and a syngas mixture |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE534988C (de) * | 1929-06-23 | 1931-10-05 | Otto Hardung | Umlaufender Waermeaustauscher mit in einem Gehaeuse angeordneter doppelwandiger Hohlschnecke |
GB1440525A (en) * | 1973-08-31 | 1976-06-23 | Buttner H J | Method and apparatus for drying and heating fluent materials |
US4639217A (en) * | 1985-01-14 | 1987-01-27 | Adams D Carlos | Countercurrent heat transfer device for solid particle streams |
EP1217318A1 (en) * | 2000-12-19 | 2002-06-26 | Sea Marconi Technologies Di Wander Tumiatti S.A.S. | Plant for the thermal treatment of material and operation process thereof |
-
2015
- 2015-05-27 DE DE102015209742.0A patent/DE102015209742B4/de active Active
-
2016
- 2016-05-27 PL PL16731519T patent/PL3303960T3/pl unknown
- 2016-05-27 EP EP16731519.1A patent/EP3303960B1/de active Active
- 2016-05-27 WO PCT/EP2016/062014 patent/WO2016189138A1/de active Application Filing
- 2016-05-27 ES ES16731519T patent/ES2769725T3/es active Active
Non-Patent Citations (1)
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Also Published As
Publication number | Publication date |
---|---|
EP3303960A1 (de) | 2018-04-11 |
DE102015209742A1 (de) | 2016-12-01 |
PL3303960T3 (pl) | 2020-04-30 |
DE102015209742B4 (de) | 2017-09-21 |
ES2769725T3 (es) | 2020-06-29 |
WO2016189138A1 (de) | 2016-12-01 |
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