EP3209385A1 - Produit et procédés de mise en en forme temporaire de fibres kératiniques - Google Patents

Produit et procédés de mise en en forme temporaire de fibres kératiniques

Info

Publication number
EP3209385A1
EP3209385A1 EP15766426.9A EP15766426A EP3209385A1 EP 3209385 A1 EP3209385 A1 EP 3209385A1 EP 15766426 A EP15766426 A EP 15766426A EP 3209385 A1 EP3209385 A1 EP 3209385A1
Authority
EP
European Patent Office
Prior art keywords
copolymer
composition according
alkyl
group
vinylpyrrolidone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15766426.9A
Other languages
German (de)
English (en)
Inventor
Julia Bibiane Lange
Anna Henschel
Cyrielle Martinez
Bernd Richters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3209385A1 publication Critical patent/EP3209385A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the present invention relates to a cosmetic composition for hair setting or for the temporary reshaping of keratinic fibers, in particular human hair, wherein the agent contains a combination of two polymers.
  • the temporary design of hairstyles for a longer period of time to several days usually requires the application of firming agents. Therefore, hair treatment agents which serve a temporary shaping of the hair, play an important role.
  • Corresponding temporary deformation agents usually contain synthetic polymers and / or waxes as the setting agent.
  • Means for supporting the temporary shaping keratin braver fibers can be formulated for example as a hair spray, hair wax, hair gel, hair foam.
  • a hair temporary deformation agent hereafter called a styling agent
  • a styling agent The most important property of a hair temporary deformation agent, hereafter called a styling agent, is to treat the treated fibers in the newly modeled form - i. a form imprinted on the hair - to give as strong a hold as possible.
  • the hairstyle hold is essentially determined by the type and amount of setting agents used, but also an influence of the other ingredients of the styling agent may be given.
  • styling agents In addition to a high degree of hold, styling agents must meet a whole range of other requirements. These may be broad in properties on the hair, properties of the particular formulation, e.g. Properties of the foam, the gel or the sprayed aerosol, and properties that affect the handling of the styling agent, are subdivided, with the properties of the hair is of particular importance. Particularly noteworthy are moisture resistance, strength, low tack and a balanced conditioning effect. Furthermore, a styling agent should be universally applicable for all hair types and mild to hair and skin.
  • Hair cosmetics suitable for temporary hair styling which also contain at least one polymeric quaternary ammonium compound from the group of the vinylpyrrolidone copolymers in addition to other constituents, are described in the German patent application DE 10 201 1 089 170 A1.
  • An object of the present invention was to provide further suitable polymer combinations which are distinguished by good film-forming and / or setting properties, have a very high degree of retention, without sacrificing flexibility and good moisture resistance, in particular perspiration and water resistance would and should also be suitable for the production of stable viscous and preferably stable transparent cosmetic compositions.
  • currently available styling agents can still be improved to the extent that a good combination of stiffness (stiffness) and long-term maintenance is not always adequately guaranteed. It is therefore an object of the present invention to provide such styling agents which, in addition to the abovementioned properties, result in particular both good rigidity and good long-term maintenance.
  • a first subject of the present application is therefore a cosmetic agent for the temporary deformation of keratinous fibers, containing, based on its total weight
  • a first essential constituent of cosmetic agents according to the invention is the hydrophobically modified (meth) acrylic acid copolymer a).
  • Preferred copolymers a) have a thickening effect.
  • a proportion by weight of the copolymer a) of the total weight of the cosmetic composition of 0.2 to 1, 5 wt .-%, preferably 0.3 to 1, 0 wt .-% and in particular 0.4 to 0.6 wt .-% has proved to be advantageous for the cosmetic effect.
  • hydrophobically modified (meth) acrylic acid copolymers a) it is preferred to use copolymers which are based on
  • At least one monomer (a2) from the group of unsaturated hydrophobically modified monomers at least one monomer (a2) from the group of unsaturated hydrophobically modified monomers
  • Preferred copolymers a) are based on at least one monomer (a1) from the group consisting of acrylic acid, methacrylic acid, C 1 -C 6 -alkylacrylic acid esters, C 1 -C 6 -alkyl methacrylic acid esters.
  • the acrylic acid esters and methacrylic acid esters are preferably esters of the respective acids with non-tertiary alkyl alcohols having alkyl radicals of 1 to 12 carbon atoms, in particular 2 to 4 carbon atoms.
  • Suitable monomers are ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, 2-methylbutyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, isooctyl acrylate, isooctyl methacrylate, isononyl acrylate and isodecyl acrylate.
  • the group of hydrophobically modified monomers (a2) refers to monomers which have a hydrophobic substructure.
  • preferred monomers (a2) can be attributed to the two following structural units:
  • an unsaturated acid preferably acrylic acid, methacrylic acid or itaconic acid
  • a Cs-4oalkyl chain preferably a Cio-3oAlkyl chain
  • These two partial structures may optionally be supplemented by a third structural unit from the group of the polyoxyalkylene groups, preferably the polyethylene glycol groups, the polypropylene glycol groups or the polyethylene glycol / polypropylene glycol groups.
  • monomer (a2) for example, Cio-3oAlkyl acrylates, Cio-3oAlkyl PEG acrylates, Cio-3oAlkyl PEG methacrylates or Cio soAlkyl PEG itaconates are used.
  • Preferred monomers (a2) are selected from the Cio-soAlkyl acrylates, Cio-soAlkyl PEG 20-25 acrylates, Cio-soAlkyl PEG 20-25 methacrylates or Cio soAlkyl PEG 20-25 itaconates.
  • Particularly preferred monomers (a2) are selected from the group of C 10 -alkyl acrylates, steareth-20-methacrylates, beheneth-25-methacrylates, steareth-20-itaconates, ceteth-20-itaconates, palmeth-25-acrylates or C 10 -alkyl-PEG-20-itaconates.
  • copolymers a) are preferred which consist of at least one monomer (a1) from the group of acrylic acid, methacrylic acid, C 1 -C 6 -alkylacrylic acid ester, C 1 -C 6 -alkyl methacrylic acid ester,
  • hydrophobically modified (meth) acrylic acid copolymers a) are formed, apart from the previously described monomers (a1) and (a2), from at least one monomer (a3) from the group of the unsaturated amine-containing monomers.
  • Monomers (a3) are preferably monomers from the group of acrylamide, methacrylamide, mono- (C 1 -C 4) -alkylamino (C 1 -C 4) -alkyl acrylate, di (C 1 -C 4) -alkylamino (C 1 -C 4) -alkyl acrylate, mono - (Ci-C4) - alkylamino (Ci-C4) -alkylmethacrylat, di- (Ci-C4) -alkylamino (Ci-C4) -alkylmethacrylat used.
  • Exemplary and preferred monomers (A2) are 2- (N, N-dimethylamino) ethyl acrylate, 2- (N, N-dimethylamino) ethyl methacrylate, 2- (N, N-diethylamino) ethyl acrylate, 2- (N, N Diethylamino) ethyl methacrylate, 3- (N, N-dimethylamino) propyl acrylate, 3- (N, N-dimethylamino) propyl methacrylate, 2- (N, N-dimethylamino) neopentyl acrylate, N '- (3 N, N-dimethylamino) propyl acrylamide, N '- (3-N, N-dimethylamino) propyl methacrylamide.
  • Preferably used copolymers a) are crosslinked.
  • preferred cosmetic agents according to the invention are characterized in that the copolymer a) is selected from the group of compounds with the INCI designations Acrylates / Cio-3o-Alkyl Methacrylate Copolymer, Acrylates / Cio-30-Alkyl Acrylate Crosspolymer, Acrylates / Steareth-20 Methacrylate Crosspolymer, Acrylates / Steareth-20 Methacrylate Copolymer, Acrylates / Beheneth-25 Methacrylate Copolymer, Acrylates / Steareth-20 Itaconate Copolymer, Acrylates / Ceteth-20 Itaconate Copolymer, Acrylates / Palmeth-25 Acrylate Copolymer, Acrylates / Aminoacrylates / Cio-3oalkyl PEG-20 itaconate copolymer.
  • the copolymer a) is selected from the group of compounds with the INCI name Acrylates / Cio-3o-alkyl methacrylate crosspolymer.
  • compositions according to the invention containing as the second essential constituent a polymeric quaternary ammonium compound from the group of the vinylpyrrolidone copolymers b).
  • Cosmetic compositions containing, based on the total weight of the cosmetic agent, by weight of the copolymer b) from 0.5 to 10% by weight, preferably from 1.0 to 6.0% by weight and in particular from 1.5 to 4.0% by weight % are characterized by particularly advantageous cosmetic properties.
  • Suitable copolymers b) are, for example
  • quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer such as the copolymers with the trade names Gafquat ® 755 N and Gafquat ® 734 (Gaf Co., USA) and Luviquat PQ 1 1 PN (BASF);
  • Vinylpyrrolidone / imidazolimine copolymer (INCI name Polyquaternium-16), for example the copolymer Luviquat ® HM 552 (BASF);
  • Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer for example the copolymer Gafquat ® HS 100 (ISP); Methylvinylimidazolium chloride / vinylpyrrolidone copolymers (INCI designation Polyquaternium-44), for example Luviquat ® Ultra Care (BASF);
  • the agents according to the invention contain at least one copolymer selected from
  • Methacrylamidopropyltrimethylammonium chloride and / or b2
  • copolymers of vinylpyrrolidone with dimethylaminoethyl methacrylate and / or b3 copolymers of vinylpyrrolidone with dimethylaminopropylmethacrylamide
  • a particularly suitable copolymer b) is obtained by reacting vinylpyrrolidone with methacrylamidopropyltrimethylammonium chloride.
  • indices m and n vary depending on the molecular weight of the polymer and should not mean that they are block copolymers. Rather, structural units can be present in the molecule in a statistically distributed manner.
  • Particularly preferred cosmetic agents are characterized in that they contain as the cationic polymer b) copolymers of methacrylamidopropyltrimethylammonium chloride (MAPTAC) with vinylpyrrolidone, which contains 40 to 95 mol%, preferably 42.5 to 90 mol%, more preferably 45 to 85 Mol .-% and in particular 50 to 80 mol .-% vinylpyrrolidone.
  • Particularly preferred cosmetic agents are further characterized in that the copolymers b) have molecular weights of from 10 to 1000 kDa, preferably from 25 to 900 kDa, more preferably from 50 to 800 kDa and in particular from 100 to 750 kDa.
  • a very particularly preferred copolymer b) is referred to as Polyquaternium 28 according to the INCI nomenclature.
  • Such a polymer is available for example under the trade name Gafquat ® HS 100 (ISP).
  • compositions according to the invention are distinguished by cosmetic agents with alternative vinylpyrrolidone copolymers b) in addition to the abovementioned advantages, in particular also by improved retention and high stiffness.
  • a weight ratio of the polymers a) and b) in the cosmetic has proved to be 5: 1 to 1: 5, preferably 3: 1 to 1: 3 and in particular 2: 1 to 1: 2 ,
  • the copolymer a) is preferably used in the cosmetic compositions in partially neutralized or neutralized form.
  • at least one alkanolamine is preferably used.
  • the alkanolamines which can be used as alkalizing agents according to the invention are preferably selected from primary amines having a C 2 -C 6 -alkyl basic body which carries at least one hydroxyl group.
  • alkanolamines are selected from the group formed from 2-aminoethane-1-ol (monoethanolamine), tris (2-hydroxyethyl) amine (triethanolamine), 3-aminopropan-1-ol, 4-aminobutane-1 -ol, 5-aminopentan-1-ol, 1-aminopropan-2-ol, 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol , 3-Amino-2-methylpropan-1-ol, 1-amino-2-methylpropan-2-ol, 3-aminopropane-1, 2-diol, 2-amino-2-methylpropane-1,3-diol.
  • Very particularly preferred alkanolamines according to the invention are selected from the group consisting of 2-aminoethane-1-ol, 2-amino-2-methylpropan-1-ol and 2-amino-2-methylpropane-1,3-diol.
  • 2-amino-2-methylpropanol has proven to be a particularly suitable neutralizing agent.
  • Cosmetic agents preferred according to the invention comprise at least one alkanolamine, preferably 2-amino-2-methylpropanol.
  • the 2-amino-2-methylpropanol is preferably used in the compositions according to the invention in an amount which does not exceed the amount needed to neutralize the copolymer a).
  • the amounts of 2-amino-2-methylpropanol used in the agents according to the invention are preferably 80 to 100%, particularly preferably 90 to 100% and in particular 95 to 100% of the amount required for complete neutralization of the copolymer a).
  • the proportion by weight of 2-amino-2-methylpropanol in the total weight of the cosmetic agent is from 0.01 to 2.0% by weight, preferably from 0.01 to 1.0% by weight and in particular from 0.02 to 0 , 5 wt .-%.
  • proportions by weight of the aminoalcohol preferably of the 2- Amino-2-methylpropanols from 0.01 to 0.2 wt .-%, preferably 0.01 to 0.1 wt .-% and in particular 0.02 to 0.6 wt .-%.
  • the cosmetic compositions of the invention may contain other active ingredients, auxiliaries and care substances.
  • a first group of preferred agents are the film-forming polymers. These film-forming polymers are not identical to the previously described hydrophobically modified (meth) acrylic acid copolymer a) or the vinylpyrrolidone copolymer b).
  • the proportion by weight of the film-forming polymer in the total weight of the cosmetic compositions is preferably 0.1 to 8.0 wt .-%, preferably 0.5 to 6.0 wt .-% and in particular 1, 0 to 4.0 wt .-%.
  • Non-ionic polymers are used with particular preference as film-forming polymers. Suitable nonionic polymers are, for example:
  • Vinylpyrrolidone / vinyl ester copolymers as sold, for example, under the trademark Luviskol ® (BASF).
  • Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are preferred non-ionic polymers.
  • Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropylcellulose, as sold for example under the trademark Culminal® ® and Benecel ® (AQUALON).
  • Siloxanes These siloxanes can be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ° C. under normal pressure.
  • Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, for example polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
  • preferred film-forming polymers according to the invention are in particular the polyvinylpyrrolidone (INCI name: PVP) and vinylpyrrolidone vinyl acetate copolymers (INCI name VP VA copolymer), wherein the weight fraction of these polymers preferably on Amounts between 1, 0 and 10 wt .-% is limited.
  • Particularly preferred cosmetic according to the invention are therefore characterized in that, based on their total weight, they furthermore contain 1.0 to 10% by weight of polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer, preferably polyvinylpyrrolidone.
  • Particularly preferred cosmetic agents have a weight fraction of the polyvinylpyrrolidone and / or vinylpyrrolidone vinyl acetate copolymer c) in the total weight of the cosmetic composition of 2.0 to 8.5 wt .-%, preferably from 3.0 to 7.0 wt .-% to ,
  • particularly preferred cosmetic agents comprising the copolymers a) and b) and the film-forming polymer c) comprise three polymers which are different from one another.
  • the cosmetic agents contain based on their total weight
  • At least one monomer (A1) from the group acrylic acid, methacrylic acid, C1-C6-alkylacrylic acid ester, Ci-C6-Alkylmethacryl Acidester, with
  • At least one monomer (A2) selected from the group consisting of C 1 -C 5 -alkyl acrylates, C 10 -C 30 -alkyl methacrylates, Cio-3Oalkyl PEG-acrylates, Cio-3Oalkyl PEG-methacrylates or Ciosoalkyl PEG-itaconates;
  • cosmetic agents which, based on their total weight
  • protein hydrolysates and / or their derivatives can be used as a care substance.
  • Protein hydrolysates are product mixtures obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).
  • the term protein hydrolyzates also means total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids.
  • the molecular weight of the invention usable protein hydrolysates is between 75, the molecular weight of glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and most preferably 75 to 20,000 daltons.
  • vitamins, provitamins, vitamin precursors and / or their derivatives are preferred, which are usually assigned to groups A, B, C, E, F and H.
  • Further care substances are glycerol, propylene glycol, panthenol, caffeine, nicotinamide and sorbitol.
  • Preferred cosmetic agents are based on an aqueous or aqueous / alcoholic carrier.
  • the proportion of water in the total weight of cosmetic agents according to the invention is preferably at least 10% by weight, in particular at least 20.0% by weight, more preferably at least 40% by weight, especially preferably at least 70% by weight.
  • the water content of cosmetic products according to the invention is preferably 10 to 98% by weight, preferably 30 to 98% by weight, particularly preferably 50 to 98% by weight and in particular 70 to 97% by weight.
  • composition of some cosmetic products used can be found in the following tables (data in% by weight based on the total weight of the cosmetic product, unless stated otherwise).
  • Formula 41 Formula 42
  • Formula 43 Formula 44
  • Polyquaternium-28 0.2 to 12 0.5 to 10 0.5 to 10 1.0 to 6.0 1.5 to 4.0
  • Copolymer b which is obtained by reacting vinylpyrrolidone with methacrylamidopropyltrimethylammonium chloride
  • Preferred cosmetic agents are present as hair gel, hair spray, hair foam or hair wax.
  • the cosmetic agents described above are distinguished by particular hair cosmetic properties, in particular advantageous properties in the case of temporary hair deformation.
  • a second subject of the present application is therefore the use of an agent according to the invention for the temporary deformation of keratin-containing fibers, in particular human hair.
  • a third subject of the present application is a method for the temporary deformation of keratin-containing fibers, in particular human hair, in which the keratinic fibers are acted upon by a cosmetic agent according to the invention and temporarily fixed in their form.
  • Cosmetic agent for temporary deformation of keratinous fibers containing, based on its total weight
  • composition according to item 1 characterized in that the proportion by weight of Copolmyers a) in the total weight of the cosmetic composition 0.2 to 1, 5 wt .-%, preferably 0.3 to 1, 0 wt .-% and in particular 0, 4 to 0.6 wt .-% is.
  • composition according to one of the preceding points characterized in that is selected as the copolymer a) from the group of compounds with the INCI name Acrylates / Cio-30-alkyl methacrylate crosspolymer.
  • composition according to one of the preceding points characterized in that the proportion by weight of the copolymer b) in the total weight of the cosmetic agent 0.5 to 10 wt .-%, preferably 1, 0 to 6.0 wt .-% and in particular 1, 5 to 4.0 wt .-% is.
  • composition according to one of the preceding points characterized in that the copolymer b) is obtained by reacting vinylpyrrolidone with methacrylamidopropyltrimethylammonium chloride.
  • composition according to one of the preceding points characterized in that as copolymer b) from the group of compounds with the INCI name Polyquaternium-28 is selected.
  • composition according to one of the preceding points characterized in that the weight ratio of copolymer a) to copolymer b) is 5: 1 to 1: 5, preferably 3: 1 to 1: 3 and in particular 2: 1 to 1: 2.
  • composition according to item 9 characterized in that the weight fraction of the polyvinylpyrrolidone and / or vinylpyrrolidone / vinyl acetate copolymer c) in the total weight of the cosmetic composition 2.0 to 8.5 wt .-%, preferably 3.0 to 7.0 Wt .-% is.
  • composition according to one of the preceding points characterized in that the cosmetic agent, based on its total weight, 0.01 to 0.2 wt .-%, preferably 0.01 to 0.1 wt .-% and in particular 0 , 02 to 0.6 wt .-% of an aminoalcohol, preferably 2-amino-2-methylpropanol.
  • composition according to one of the preceding points, characterized in that the cosmetic agent, calculated on the total weight of the agent, at least 10 wt .-%, in particular at least 20.0 wt .-%, more preferably at least 40 wt .-%, also preferably at least 70 wt .-%, water.
  • Cosmetic composition according to one of the preceding points characterized in that the agent is present as a hair gel, hair spray, hair foam or hair wax.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit cosmétique de mise en forme temporaire de fibres kératiniques, contenant, par rapport à son poids total, a) 0,1 à 2,0 % en poids d'au moins un copolymère d'acide (méth)acrylique modifié hydrophobe ; b) 0,2 à 12 % en poids d'au moins un composé d'ammonium quaternaire polymère du groupe des copolymères de vinylpyrrolidone, leur utilisation et les procédés mettant en oeuvre ces produits.
EP15766426.9A 2014-10-21 2015-09-08 Produit et procédés de mise en en forme temporaire de fibres kératiniques Withdrawn EP3209385A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014221375.4A DE102014221375A1 (de) 2014-10-21 2014-10-21 Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
PCT/EP2015/070437 WO2016062447A1 (fr) 2014-10-21 2015-09-08 Produit et procédés de mise en en forme temporaire de fibres kératiniques

Publications (1)

Publication Number Publication Date
EP3209385A1 true EP3209385A1 (fr) 2017-08-30

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EP15766426.9A Withdrawn EP3209385A1 (fr) 2014-10-21 2015-09-08 Produit et procédés de mise en en forme temporaire de fibres kératiniques

Country Status (4)

Country Link
US (1) US20170216186A1 (fr)
EP (1) EP3209385A1 (fr)
DE (1) DE102014221375A1 (fr)
WO (1) WO2016062447A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006005451A1 (de) * 2006-02-01 2007-08-02 Beiersdorf Ag Kosmetische Haargele mit hoher Fadenabrisszeit
EP2090281A1 (fr) * 2008-02-07 2009-08-19 Wella Aktiengesellschaft Composition de coiffage
US20100275943A1 (en) * 2009-05-04 2010-11-04 Robert Salem Formulations for maintaining the form of a specific haircut
WO2012030750A2 (fr) * 2010-09-02 2012-03-08 Lubrizol Advanced Materials, Inc. Polymères et compositions
DE102011089170A1 (de) 2011-12-20 2013-06-20 Henkel Ag & Co. Kgaa Mittel zur temporären Verformung keratinischer Fasern auf Grundlage einer Kombination spezifischer filmbildender Polymere
DE102012214380A1 (de) 2012-08-13 2014-02-13 Henkel Ag & Co. Kgaa Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern

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Publication number Publication date
US20170216186A1 (en) 2017-08-03
WO2016062447A1 (fr) 2016-04-28
DE102014221375A1 (de) 2016-04-21

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