EP3180134A1 - Beschichtetes substrat und verfahren zu dessen herstellung - Google Patents
Beschichtetes substrat und verfahren zu dessen herstellungInfo
- Publication number
- EP3180134A1 EP3180134A1 EP15752950.4A EP15752950A EP3180134A1 EP 3180134 A1 EP3180134 A1 EP 3180134A1 EP 15752950 A EP15752950 A EP 15752950A EP 3180134 A1 EP3180134 A1 EP 3180134A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating agent
- substrate
- coating
- applying
- wet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims description 34
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 61
- 238000000576 coating method Methods 0.000 claims abstract description 33
- 239000004743 Polypropylene Substances 0.000 claims abstract description 28
- 229920001155 polypropylene Polymers 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 26
- 229920002397 thermoplastic olefin Polymers 0.000 claims abstract description 23
- -1 polyethylene Polymers 0.000 claims abstract description 22
- 230000005855 radiation Effects 0.000 claims abstract description 20
- 239000004698 Polyethylene Substances 0.000 claims abstract description 19
- 229920003023 plastic Polymers 0.000 claims abstract description 18
- 239000004033 plastic Substances 0.000 claims abstract description 18
- 229920000573 polyethylene Polymers 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000004140 cleaning Methods 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 3
- 239000003973 paint Substances 0.000 claims description 28
- 238000010422 painting Methods 0.000 claims description 28
- 239000004417 polycarbonate Substances 0.000 claims description 19
- 229920000515 polycarbonate Polymers 0.000 claims description 18
- 239000004922 lacquer Substances 0.000 claims description 17
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 11
- 239000008199 coating composition Substances 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 9
- 230000001070 adhesive effect Effects 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- 239000003463 adsorbent Substances 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 125000001145 hydrido group Chemical group *[H] 0.000 claims 1
- 230000009977 dual effect Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 4
- 230000004913 activation Effects 0.000 description 19
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 15
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 13
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 13
- 230000000694 effects Effects 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- 210000002381 plasma Anatomy 0.000 description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 7
- 239000004926 polymethyl methacrylate Substances 0.000 description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 230000037452 priming Effects 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000002966 varnish Substances 0.000 description 4
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000007591 painting process Methods 0.000 description 3
- 238000002042 time-of-flight secondary ion mass spectrometry Methods 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000003682 fluorination reaction Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 238000012667 polymer degradation Methods 0.000 description 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- 241001482107 Alosa sapidissima Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000012443 analytical study Methods 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000001420 photoelectron spectroscopy Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005211 surface analysis Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0209—Multistage baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
- B05D3/101—Pretreatment of polymeric substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
Definitions
- the present invention relates to a process for producing a coated substrate by applying at least one coating agent to the substrate comprising a plastic selected from a group consisting of polyethylene (PE), polypropylene (PP), thermoplastic polyolefins (TPO) or mixtures from this, as well as a corresponding plastic component.
- a plastic selected from a group consisting of polyethylene (PE), polypropylene (PP), thermoplastic polyolefins (TPO) or mixtures from this, as well as a corresponding plastic component.
- the invention further relates to an apparatus for producing the coated substrate by applying at least one coating agent to the substrate.
- plastics account for between 15 and 20 percent by weight and are increasing in automotive engineering. These are often exterior and interior parts, which receive their corresponding visual, haptic and functional properties through a paint job.
- the trend towards fewer coating steps, for example with filler-less coating systems, is also very popular with plastic attachments.
- the elimination of intermediate drying reduces energy consumption and at the same time reduces material consumption and solvent emissions. In addition, less
- Corresponding paint solutions are available, inter alia, for glossy, injection-molded interior parts, for example trim strips, of an ABS-PC blend (ABS: acrylonitrile-butadiene-styrene, PC: polycarbonate).
- ABS-PC blend ABS-PC blend
- the varnish provides a noble, high-gloss surface with a single-layer varnish structure.
- solvent-based and water-based paints are used for the coating of plastics.
- Solvent-based UV dual-cure systems have also been used for several years. They allow good matting and metallic shades. However, not all metallic shades can be produced with UV varnishes.
- High-gloss surfaces are produced with solvent-based UV dual-cure clearcoats in the structure with basecoats.
- Increasingly used for KunststoffStofflacktechnik are both 100% UV clearcoats with piano lacquer optics and 2K dual-cure systems, the former having significantly higher chemical resistance properties.
- Dual-cure is the combined cure by heat and actinic radiation.
- Dual-cure coating materials and methods and devices for their curing with actinic radiation, in particular UV radiation are known from the German patent applications DE 198 18 735 AI, DE 42 15 070 AI, DE 199 30 665 AI, DE 199 30 067 AI, DE 199 30 664 AI, DE 199 24 674 AI or DE 199 20 799 AI known. They serve for the production of coatings, in particular of clearcoats and color and / or effect multicoat paint systems.
- the curing with actinic radiation is carried out mainly with UV radiation.
- the binder components contained thereby have different functional groups which under appropriate conditions i.d.R. independently network with each other.
- Conventional dual-cure systems belonging to the prior art have radiation-curable and thermally curable groups, with particularly advantageous properties being achieved when using isocyanate and hydroxyl groups as thermally crosslinking functions.
- EP 1 419 015 discloses a process for the preparation of coatings of thermally and actinic radiation curable coating materials comprising: A) the coating materials on primed or unprimed substrates or uncured, partially cured and / or fully cured coating layers thereon applied and B) the resulting layers of the coating materials cured by itself or together with the uncured and / or partially cured coating layers thermally and with actinic radiation, wherein the curing is carried out with actinic radiation under an oxygen-depleted atmosphere.
- the object of the present invention is thus to provide a simplified process for producing a coated polyethylene (PE), polypropylene (PP), or thermoplastic polyolefins (TPO)
- PE coated polyethylene
- PP polypropylene
- TPO thermoplastic polyolefins
- Another object of the invention is to provide a corresponding coating apparatus and a coated plastic component obtained by the method.
- This object is achieved according to the method by the following steps: a- wet cleaning of the untreated substrate;
- a second coating agent which is curable thermally and by actinic radiation (dual-cure); e-heating or drying the coated substrate, wherein a polyaddition occurs;
- a particular advantage of the invention is that in the proposed method, the step of activating the substrate is entirely dispensed with.
- Activation units flame treatment, plasma
- associated fire protection measures and operating costs associated fire protection measures and operating costs.
- Polyethylene (PE), polypropylene (PP), or thermoplastic polyolefin (TPO) plastic substrate may be filled or unfilled.
- thermoplastic polyolefins one-, two-, and one-half can be activated without activation
- Three-layer structures made of dual-cure, 2K or 1K systems are provided, which meet the requirements of automobile manufacturers, for example, for painted interior ⁇ KunststoffStoffbaumaschine polypropylene.
- the first coating agent in step b preferably contains at least one 1K or 2K hydroprimer or a solvent primer and / or UV-2K dual-cure primer.
- the second coating composition contains a hydrosol, preferably at least one UV-2K Dualcure hydro lacquer.
- the combination of 1K or 2K solvent and / or hydroprimer and / or UV / 2K dualcure primer with UV / 2K Dualcure hydro lacquer systems on substrates of PP and TPO can in combination with ABS, ABS mod. PC, PC ABS, PC, PMMA for painted interior components.
- An activation unit, e.g. with flame or plasma is not required.
- UV / 2K-Hydro-Dualcure clearcoats with 1K or 2K-solvent and hydroprimer and / or 2K-basecoats and / or UV / 2K-Dualcure hydro lacquer systems also enables the generation of a wide product range with matt, semi-glossy or high-gloss surfaces.
- the surface of the substrate or plastic is not activated according to the invention before the application of the first coating agent.
- Gas phase fluorination can be used primarily for the cleaning of thin organic contaminants with simultaneous activation of the surface. This dual function is based on a physical and chemical reaction of the process. As a result, in addition to a clean surface, the increase of the surface tension or surface energy is achieved in order to create optimum conditions for the subsequent painting process.
- ToF-SIMS secondary ion mass spectrometry
- the first coating agent and / or the second coating agent preferably contains at least one UV
- Coating is effectively protected against UV radiation, especially from sunlight. Sunlight-exposed varnish embrittles significantly slower and gives a longer shelf life.
- the first coating agent and / or the second coating agent preferably contains at least one adhesion additive or a binder in order to improve the adhesion of the paint to the substrate.
- the adhesive additive or binder includes, for example, pigments and resins.
- the plastic-coated plastic substrate component obtained by a method described above has the first coating agent a layer thickness of 10-30 ⁇ m, preferably 15 ⁇ m, and / or the second coating composition a layer thickness of 3-20 ⁇ m, preferably 15-40 ⁇ m, particularly preferably 25 ⁇ m. 30 pm up.
- the second coating agent preferably has a layer thickness of from 3 to 20 ⁇ m Coating transparent substrates, especially in conjunction with polycarbonate, on.
- the device according to the invention for producing a coated substrate by applying at least one coating agent to the substrate which comprises a plastic which is selected from a group consisting of polyethylene (PE), polypropylene (PP), thermoplastic polyolefins (TPO) or mixtures thereof a washing device for alkaline wet cleaning of the non-activated substrate; a downstream adhesive water dryer with cooling zone; a first painting device having a region for applying a first coating agent and a downstream second coating device having a region for applying a second coating composition, which comprises at least one heat-and-actinic radiation (dual-cure) hydrostatic coating, wherein an intermediate drying and / or cooling zone is arranged between the first painting device and the second painting device; and one of the first and second painting device downstream irradiation unit with actinic radiation.
- a plastic which is selected from a group consisting of polyethylene (PE), polypropylene (PP), thermoplastic polyolefins (TPO) or mixtures thereof
- the first coating device is preferably suitable for applying a first coating composition which contains at least one 1K or 2K hydroprimer or solvent primer and / or UV-2K dual-cure hydroprimer.
- the second painting device is preferably suitable for applying a second coating composition which contains at least one UV-2K dual-cure hydro lacquer.
- the intermediate drying and / or cooling zone is designed for drying temperatures of 20-90 ° C.
- the following examples show, in tabular form, various paint vehicles consisting of hydro-primer as the first coating agent and basecoat or protective paint as the second coating agent on flamed and non-marred substrates.
- the coatings generally have a 1K Primer with UV Dualcure Topcoat or a 1K Primer with 2K Topcoat or UV Hydro-Dualcure Topcoats.
- Untreated PP as a substrate shows the sole use of 1K-, 2K-, etc. Hydro lacquers insufficient underground adhesion, whereby the coatings can be completely removed from the substrate. Solvent-based paints also adhere less well without pretreatment.
- UV / 2K-Dualcure topcoats are for decor, soft, comfort, any color tones for interior, exterior, such as black, beige, red, silver, chrome, contrast anthracite, titanium, etc., matte, semi-gloss and piano black, Pianowhite and high gloss.
- UV / 2K clearcoats are high gloss, semi-gloss and matt, common shades are possible.
- Fig. La, b is a schematic representation of two
- Lacquering devices from the prior art for interior components in the wet / wet process ( Figure la) or with intermediate drying after priming ( Figure lb).
- Fig. 2 is a schematic representation of a
- FIG. 3 is a schematic representation of a
- Fig. 4 is a schematic representation of a
- Fig. 5 is a schematic representation of a
- FIG. 1 shows two prior art coating devices for interior components of acrylonitrile-butadiene-styrene (ABS) copolymer, ABS-modified polycarbonate (PC), polycarbonate (PC), polymethylmethacrylate (PMMA) or mixtures thereof, in the wet / wet process ie without intermediate drying (FIG. 1 a) in the dryer 8, or with intermediate drying after priming in the first painting booth 6 (FIG. 1 b).
- ABS acrylonitrile-butadiene-styrene
- PC polycarbonate
- PMMA polymethylmethacrylate
- the decorative soft lacquer is applied wet in wet in two applications. There is no interim drying, but only a flash off for 7-10 min at 20 ° - 26 ° C and 55 ⁇ 5% relative humidity.
- a primer with or without intermediate drying is applied to the primer.
- the application of 2K Hydro Topcoat for interior paints, decor, soft and effect paints such as metallic, silver, chrome, etc. takes place.
- an alkaline wet cleaning 1 is equivalent to two degreasing zones in two rinse zones as well then rinse with demineralised water.
- a blowing zone 2 with an adhesive water dryer 3.
- plastic components which are not made of acrylonitrile-butadiene-styrene (ABS) copolymer, ABS-modified polycarbonate (PC), polycarbonate (PC), polymethyl methacrylate (PMMA) or mixtures thereof, after the adhesive water dryer 3 an activation device (not shown ) intended.
- ABS-modified polycarbonate PC
- PC polycarbonate
- PMMA polymethyl methacrylate
- a drive-through area 5 in front of the first 6 and second 11 spray booth. Before the drive-through area 5 to the first painting booth 6 is a first cooling zone. 4
- the second paint booth is a Abdunstzone 12 arranged with the final paint drier 13, in which the fully coated substrate is dried at 80 ° C for 30 min.
- the now painted component arrives in the extension area 15 and also in the parts removal control 17, as well as the parts task 18 and the placement area 19.
- the decorative soft lacquer is intermediately dried in two jobs in the primer dryer 8, which is preceded by an evaporation zone 7, after priming in the first painting booth 6 (FIG. 1 b).
- a control zone 10 is arranged between the paint booths, in which the flash-off takes place.
- the second spray booth is a Abdunstzone 12 with the final Paint drier 13 downstream, in which the fully coated substrate is dried at 80 ° C for 30 min.
- the now painted component arrives in the extension area 15 and also in the parts removal control 17, as well as the parts task 18 and the placement area 19.
- FIG. 2 shows a schematic representation of a coating device according to the invention for plastic components, in particular interior components containing polyethylene (PE), polypropylene (PP), thermoplastic polyolefins (TPO) or mixtures thereof in the wet / wet process.
- PE polyethylene
- PP polypropylene
- TPO thermoplastic polyolefins
- the substrates used are PP, TPO without activation, optionally in combination with ABS, ABS mod., PC ABS, PC or PMMA.
- the combination of 1K or 2K solvent and / or hydroprimer and / or UV / 2K dualcure primer with UV / 2K Dualcure hydro lacquer systems on substrates of PP and TPO can, also in combination with ABS, ABS mod. PC, PC ABS, PC, PMMA for all painted interior components.
- a complex and expensive activation unit, eg with flame or plasma is not required. This not only eliminates Investment costs for the activation units when retrofitting or upgrading existing paint shops, but also the fire protection measures and operating costs associated with the activation units (flame treatment, plasma).
- the lacquering process can in principle also be carried out "wet on wet” (FIG. 2) or with intermediate drying in the primer dryer 8 (FIG. 3) of the adhesion-promoting layer.
- the UV / 2K Dualcure - Hydrobase paints are applied for interior paints, decor, soft and effect paints such as metallic, silver, chrome, etc.
- the devices according to the invention additionally have a UV radiator unit 16 compared to the prior art, which is preferably arranged in the system area between the final cooling zone 14 and the extension area 15.
- the coating device according to the invention for producing a coated substrate is thus characterized in particular by the combination of a washing device for alkaline wet cleaning 1 of the non-activated substrate, a downstream adhesive water dryer 3 with cooling zone 4, a first coating device 6 for applying a first coating agent and a downstream second Painting device 11 for applying a second coating agent, which has at least one cured by dual-cure hydro paint from.
- a washing device for alkaline wet cleaning 1 of the non-activated substrate a downstream adhesive water dryer 3 with cooling zone 4
- a first coating device 6 for applying a first coating agent
- a downstream second Painting device 11 for applying a second coating agent, which has at least one cured by dual-cure hydro paint from.
- an intermediate drying and / or evaporation zone 7, 8 is arranged between the first painting device and the second painting device and one of the second painting device 11 downstream irradiation unit 16 with actinic radiation.
- FIG. 4 shows, analogously to FIG. 2, a schematic representation of a coating device in the wet / wet process for clearcoats.
- the painting process can basically also be carried out "wet on wet” (FIG. 4) or as a two-layer structure with intermediate drying 8 (FIG. 5) of the adhesion-promoting layer.
- intermediate drying 8 a flash-off is likewise carried out for 7-10 minutes at 24 ° -26 ° C. and 55 ⁇ 5% relative humidity.
- UV-Hydro clearcoat e.g. matt, semi-gloss or high gloss.
- UV lamps for UV / 2K Dualcure Hydrobasislacke are preferably iron-doped emitters, for clearcoat systems mercury-doped UV emitters in question.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102014111415.9A DE102014111415A1 (de) | 2014-08-11 | 2014-08-11 | Beschichtetes substrat und verfahren zu dessen herstellung |
PCT/EP2015/067480 WO2016023760A1 (de) | 2014-08-11 | 2015-07-30 | Beschichtetes substrat und verfahren zu dessen herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3180134A1 true EP3180134A1 (de) | 2017-06-21 |
EP3180134B1 EP3180134B1 (de) | 2020-09-02 |
Family
ID=53887079
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15752950.4A Active EP3180134B1 (de) | 2014-08-11 | 2015-07-30 | Verfahren zur herstellung eines beschichteten substrats |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3180134B1 (de) |
CN (1) | CN106660070B (de) |
DE (1) | DE102014111415A1 (de) |
MY (1) | MY180617A (de) |
WO (1) | WO2016023760A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115318582A (zh) * | 2022-09-19 | 2022-11-11 | 安徽铂优新材料有限公司 | 一种铜线光固化自动涂覆生产线设备 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1391881A (fr) * | 1961-11-24 | 1965-03-12 | Dow Chemical Co | Procédé perfectionné de revêtement d'articles en résine synthétique |
DE1228398B (de) * | 1963-09-18 | 1966-11-10 | Union Verpackungs G M B H | Verfahren und Vorrichtung zur Herstellung einer aus einer Polypropylen-Schicht und einer Polyaethylen-Schicht bestehenden heisssiegelfaehigen Verbundfolie |
US4634602A (en) * | 1986-01-02 | 1987-01-06 | Ppg Industries, Inc. | Primer composition |
US5102699A (en) * | 1990-08-10 | 1992-04-07 | E. I. Du Pont De Nemours And Company | Solvent blockers and multilayer barrier coatings for thin films |
DE4215070A1 (de) | 1992-05-07 | 1993-11-11 | Herberts Gmbh | Verfahren zur Herstellung von Mehrschichtlackierungen |
DE19818735A1 (de) | 1998-04-27 | 1999-10-28 | Herberts Gmbh | Strahlungshärtbare Beschichtungsmittel und deren Verwendung |
DE19920799A1 (de) | 1999-05-06 | 2000-11-16 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung |
DE19924674C2 (de) | 1999-05-29 | 2001-06-28 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung |
DE19930067A1 (de) | 1999-06-30 | 2001-01-11 | Basf Coatings Ag | Beschichtungsstoff und seine Verwendung zur Herstellung von Füllerschichten und Steinschlagschutzgrundierungen |
DE19930665A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Basislack und seine Verwendung zur Herstellung von farb- und/oder effektgebenden Basislackierungen und Mehrschichtlackierung |
DE19930664A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Klarlack und seine Verwendung zur Herstellung von Klarlackierungen und farb- und/oder effektgebenden Mehrschichtlackierungen |
DE19945291B4 (de) * | 1999-09-22 | 2006-07-20 | Eisenmann Maschinenbau Gmbh & Co. Kg | Lackieranlage zum Lackieren von Kunststoff-Gegenständen |
WO2001089712A1 (en) * | 2000-05-24 | 2001-11-29 | Shubho Bhattacharya | Adhesion promoter application system and process |
DE10130972C1 (de) | 2001-06-27 | 2002-11-07 | Basf Coatings Ag | Verfahren zur Herstellung von Beschichtungen aus thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen und mit dem Verfahren herstellbare Lackierungen |
US20060257671A1 (en) * | 2003-03-07 | 2006-11-16 | Yahkind Alexander L | Method and primer composition for coating a non-polar substrate |
US7576139B2 (en) * | 2003-09-30 | 2009-08-18 | Kansai Paint Co., Ltd. | Coating composition and method of forming coating film |
WO2006046117A1 (en) * | 2004-10-28 | 2006-05-04 | Basf Coatings Japan Ltd. | White basecoat coating composition, method for forming coating film and coated article |
-
2014
- 2014-08-11 DE DE102014111415.9A patent/DE102014111415A1/de not_active Ceased
-
2015
- 2015-07-30 WO PCT/EP2015/067480 patent/WO2016023760A1/de active Application Filing
- 2015-07-30 CN CN201580043462.4A patent/CN106660070B/zh active Active
- 2015-07-30 MY MYPI2017000184A patent/MY180617A/en unknown
- 2015-07-30 EP EP15752950.4A patent/EP3180134B1/de active Active
Also Published As
Publication number | Publication date |
---|---|
WO2016023760A1 (de) | 2016-02-18 |
DE102014111415A1 (de) | 2016-02-11 |
MY180617A (en) | 2020-12-03 |
CN106660070A (zh) | 2017-05-10 |
EP3180134B1 (de) | 2020-09-02 |
CN106660070B (zh) | 2021-07-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2773693B1 (de) | Verfahren zur beschichtung von kunststoffsubstraten | |
WO2000058026A1 (de) | Verfahren zur mehrschichtlackierung | |
DE19913442C2 (de) | Verfahren zur Lackierung von Fahrzeugkarossen oder deren Teilen | |
EP0729390B1 (de) | Verfahren zur herstellung einer mehrschichtigen reparaturlackierung | |
DE69307182T3 (de) | Verfahren zur Herstellung von knitterfreien Beschichtungen unter Verwendung eines lösungsmittelhaltigen Klarlackes auf einer wässrigen Basisschichtzusammensetzung | |
DE10220414B4 (de) | Verfahren zum Überlackieren farb- und/oder effektgebender Mehrschichtlackierungen | |
WO2014180537A1 (de) | Glanzgradeinstellung von kunststoffsubstraten mit metallischem finish | |
EP0830219A1 (de) | Mit mehreren schichten beschichtete folien und deren verwendung im automobilbau | |
WO2016005094A1 (de) | Verfahren zur beschichtung von kunststoffsubstraten | |
EP0719185B1 (de) | Verfahren zur herstellung einer mehrschichtigen reparaturlackierung | |
EP3180134B1 (de) | Verfahren zur herstellung eines beschichteten substrats | |
EP2552603A1 (de) | Substrate mit mehrfarbiger lackierung und ihre herstellung | |
EP0828569A1 (de) | Mit mehreren schichten beschichtete folien und deren verwendung im automobilbau | |
EP1289679B1 (de) | Verfahren zur haftfesten beschichtung von substraten mit korrosiven optischen schichten | |
DE102009032117B3 (de) | Verfahren zum Herstellen einer Mattlackierung | |
EP0764475B1 (de) | Verfahren zur Effektlackierung genarbter Kunststoffteile | |
WO1996003221A1 (de) | Verfahren zur herstellung und ausbesserung von mehrschichtigen effektlackierungen | |
DE60300050T2 (de) | Verfahren zur Reparaturlackierung | |
DE60110492T2 (de) | Verfahren zur Reparaturbeschichtung von Mehrschichtüberzügen auf Substraten | |
DE102010025769A1 (de) | Verfahren zur Herstellung einer farb- und/oder effektgebenden mehrschichtigen Lackierung | |
DE102011115342A1 (de) | Verfahren zur Herstellung einer Mattlackierung auf einer Substratoberfläche | |
DE102010051677A1 (de) | Verfahren zur Härtung und Aktivierung von strahlungshärtbaren Basislacken | |
DE102012209486A1 (de) | Verfahren zur Herstellung einer farb- und/oder effektgebenden mehrschichtigen Lackierung | |
DE102005022858A1 (de) | Lackierverfahren zum Erzeugen einer Lederimitatoberfläche | |
DE10153010A1 (de) | Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20170210 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20180919 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: B05D 3/02 20060101ALI20200225BHEP Ipc: B05D 3/10 20060101ALN20200225BHEP Ipc: B05D 7/02 20060101AFI20200225BHEP Ipc: B05D 3/06 20060101ALN20200225BHEP Ipc: B05D 7/00 20060101ALI20200225BHEP |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: B05D 7/00 20060101ALI20200302BHEP Ipc: B05D 3/10 20060101ALN20200302BHEP Ipc: B05D 7/02 20060101AFI20200302BHEP Ipc: B05D 3/06 20060101ALN20200302BHEP Ipc: B05D 3/02 20060101ALI20200302BHEP |
|
INTG | Intention to grant announced |
Effective date: 20200317 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1308229 Country of ref document: AT Kind code of ref document: T Effective date: 20200915 Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502015013391 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201202 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201203 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201202 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20200902 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210104 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210102 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502015013391 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20210603 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20210731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210731 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210730 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210731 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 1308229 Country of ref document: AT Kind code of ref document: T Effective date: 20210730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20150730 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200923 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230620 Year of fee payment: 9 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20231017 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20230731 Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200902 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240606 Year of fee payment: 10 |