EP3145630A1 - Reaktor mit vertikal beweglicher gassperre - Google Patents
Reaktor mit vertikal beweglicher gassperreInfo
- Publication number
- EP3145630A1 EP3145630A1 EP15724580.4A EP15724580A EP3145630A1 EP 3145630 A1 EP3145630 A1 EP 3145630A1 EP 15724580 A EP15724580 A EP 15724580A EP 3145630 A1 EP3145630 A1 EP 3145630A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gas
- catalyst bed
- cylinder
- reactor
- lateral
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 claims abstract description 175
- 239000000203 mixture Substances 0.000 claims abstract description 87
- 239000007789 gas Substances 0.000 claims description 266
- 230000004888 barrier function Effects 0.000 claims description 61
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 56
- 229910021529 ammonia Inorganic materials 0.000 claims description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000003786 synthesis reaction Methods 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 238000004364 calculation method Methods 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007036 catalytic synthesis reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0447—Apparatus other than synthesis reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
- B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
- B01J8/0415—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
- B01J8/0407—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds
- B01J8/0419—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more cylindrical annular shaped beds the beds being placed in separate reactors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
- C01C1/0417—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst characterised by the synthesis reactor, e.g. arrangement of catalyst beds and heat exchangers in the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00194—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/00707—Fouling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Definitions
- the invention relates to a reactor for the catalytic conversion of a gas mixture, preferably for catalytic ammonia synthesis from a gas mixture comprising essentially nitrogen and hydrogen, which comprises a catalyst bed, wherein on at least a portion of the top of the catalyst bed a vertically movable gas barrier, which is lowered upon contraction of the catalyst bed and which prevents the gas mixture from flowing out of the catalyst bed via the top thereof.
- Ammonia reactors usually have catalyst beds, which are radially flowed through by a reacting gas mixture from outside to inside.
- the optimum catalyst utilization is achieved when the gas flow is uniform over the entire height of the catalyst bed and without detours.
- the catalyst beds are usually provided as a bed, with the poured catalyst particles tending to form a denser packing over time. As a result, the catalyst bed settles over time, which may be about 5% of the original bed height.
- By lowering the top of the catalyst bed arise catalyst-free zones above the catalyst bed in the form of cavities through which the gas mixture flows around the catalyst bed without reacting. As a result, the ammonia yield deteriorates.
- the invention has for its object to provide advantageous reactors.
- the reactors should ensure a high product yield even as the catalyst bed lowers over time.
- the invention relates to a reactor for the catalytic conversion of a gas mixture, preferably for the catalytic ammonia synthesis at elevated pressure and elevated temperature from a gas mixture comprising essentially nitrogen and hydrogen, wherein the reactor comprises a container in which a catalyst bed between a lateral boundary, preferably an inner boundary, and a further lateral boundary, preferably an outer boundary, is arranged; wherein the lateral boundary has a plurality of lateral gas inlets, through which the gas mixture can flow from the side into the catalyst bed through the lateral boundary in order to react there at least partially, preferably to ammonia; and wherein the further lateral boundary has a multiplicity of lateral gas outlets, via which the gas mixture can then flow out of the catalyst bed through the further lateral boundary; and wherein on the upper side of the catalyst bed a vertically movable gas barrier loads in the vertical direction.
- the gas barrier is freely movable in the vertical direction and prevents the gas mixture from flowing out of the catalyst bed via its top.
- the container of the reactor according to the invention preferably has a round cross-sectional area. It can be designed as a pressure vessel.
- the reactor according to the invention is preferably intended to be placed vertically, so that the round cross-sectional area is oriented substantially horizontally.
- the main extension plane of the gas barrier is preferably also substantially horizontally aligned, substantially parallel to the top of the Catalyst bed.
- the gas barrier rests on the top of the catalyst bed, ie it is pressed by gravity on the top of the catalyst bed.
- the gas barrier floats loosely above the catalyst bed, preferably in direct contact with the top of the catalyst bed.
- the gas barrier prevents the flow around the catalyst bed above the top, even after the catalyst bed.
- the vertical mobility of the gas barrier prevents the formation of a cavity between the bottom of the gas barrier and the top of the catalyst bed as a result of settling of the catalyst bed, through which the gas mixture could flow around the catalyst bed.
- the vertical movement of the gas barrier may be active, e.g. done by a spring.
- the gas barrier is lowered in the vertical direction solely by gravity when the catalyst bed contracts.
- the gas barrier is preferably also lifted from the catalyst bed in the vertical direction when the catalyst bed expands, but in practice this direction of movement plays a subordinate role.
- the gas barrier descends vertically as a result of settling of the catalyst bed, according to the invention above the lowered gas barrier no (open) gas outlets arranged in the further lateral boundary, otherwise the gas mixture bypassing the catalyst bed on this lying above the gas barrier gas outlets from the Catalyst bed could flow out.
- sealed gas outlets e.g. Mesh a metal basket which is closed by suitable means (e.g., inside or outside metal sheets) so that it can no longer function as gas outlets.
- the (open) gas outlets in the further lateral boundary are spaced from the upper edge of the further lateral boundary.
- the extent of the spacing of the (opened) gas outlets from the upper edge of the further lateral boundary corresponds to the expected lowering of the gas barrier as a result of the lowering of the catalyst bed. Since a deposition of the catalyst bed in the course of time by up to about 5% of the original bed height is expected, the extent of the spacing of the (open) gas outlets from the top of the further lateral boundary is preferably at least 5% of the total vertical extension of the further lateral boundary, more preferably about 5% to about 15%, or about 5% to about 10%.
- the gas inlets in the lateral boundary are not spaced from the top of the further lateral boundary, i. they are preferably evenly or non-uniformly distributed over the entire vertical extent of the lateral boundary, in particular in its upper region.
- the main extension plane of the gas barrier is arranged substantially orthogonal to the lateral boundary and the further lateral boundary.
- the lateral boundary and the further lateral boundary are preferably arranged substantially vertically parallel to each other.
- the lateral boundary and the further lateral boundary prevent the catalyst bed from breaking out laterally during the filling and also during the operation of the reactor.
- the lateral boundary and the further lateral boundary are elements of the same component, e.g. a basket in which the catalyst bed is introduced as a bed.
- the lateral boundary and the further lateral boundary are different components, preferably cylinders of different diameters, which are arranged concentrically to each other about a common axis, so that the catalyst bed is arranged in the space between the outside of the inner cylinder and the inside of the outer cylinder.
- Below the catalyst bed is preferably loaded on a gas-impermeable plate.
- the type of catalyst depends on the gas phase reaction for which the reactor according to the invention is to be used.
- the ammonia synthesis is usually carried out on iron catalysts, which are provided as particles (pellets) of a defined size.
- the plurality of lateral gas inlets in the lateral boundary and the plurality of lateral gas outlets in the further lateral boundary of the reactor according to the invention are dimensioned so that the gas mixture can flow through controlled, wherein the catalyst granules are retained.
- the influx of the gas mixture into the catalyst bed can be influenced by the size and the number of gas inlets per area of the lateral boundary.
- the outflow of the gas mixture from the catalyst bed can be influenced by the size and the number of gas outlets per area of the further lateral boundary.
- the lateral boundary and / or the further lateral boundary is formed as a perforated plate.
- the holes in the lateral boundary form the plurality of lateral gas inlets and the holes in the further lateral boundary form the plurality of lateral gas outlets
- Differently perforated sheets for the lateral boundary and for the further lateral boundary allow a homogenization and thus improvement of the flow of the gas mixture through the catalyst bed.
- the number and / or size and / or arrangement of the gas inlets in or along the lateral boundary of number and / or size and / or arrangement of the gas outlets in or along the other lateral boundary, whereby the flow of the gas mixture through the catalyst bed uniformed and thereby the sales can be increased.
- a difference in the arrangement can be achieved, for example, by a different distribution per unit area along the lateral boundary or along the further lateral boundary.
- the gas inlets in the lateral boundary are designed such that they produce a lower flow resistance than the gas outlets in the further lateral boundary.
- This can be achieved in perforated plates, for example, by making the number of holes per area substantially equal for both lateral boundaries, the holes in the lateral boundary, i. the gas inlets, however, are larger than the holes in the further lateral boundary, i. as the gas outlets.
- this can be accomplished by making the lateral boundary per area more holes, i. has more gas inlets than the further lateral boundary has holes per area, i. Gas outlets.
- the gas inlets in the lateral boundary are designed such that they produce a greater flow resistance for the gas mixture than the gas outlets in the further lateral boundary.
- This can for perforated plates, for example, by making the number of holes per area substantially equal for both lateral boundaries, the holes in the lateral boundary, ie the gas inlets, are smaller than the holes in the further lateral boundary, ie as the gas outlets , Alternatively, this can be achieved with essentially the same hole size in that the lateral boundary has fewer holes per area, ie fewer gas inlets, than the further lateral boundary has holes per area, ie gas outlets.
- the gas inlets in the lateral boundary may differ in size and number from the gas outlets in the further lateral boundary.
- the gas inlets are unevenly distributed over the area of the lateral boundary or the gas outlets unevenly over the area of the further lateral boundary.
- the flow resistance for the gas mixture in the lower region, i. facing the ground larger or smaller than in the upper region of the lateral boundary or the further lateral boundary. In this way it can be achieved that the flow resistances along the lateral boundary or along the other lateral boundary are different.
- the gas barrier does not extend over the entire area of the top of the catalyst bed, but only rests on a portion of the top of the catalyst bed, i. on a partial surface, whereby the other part of the top of the catalyst bed, on which the gas barrier is not loaded, remains free and forms an upper gas inlet, through which the gas mixture can additionally flow from above into the catalyst bed.
- the flow of the gas mixture into the catalyst bed can be regarded as two partial flows, wherein one partial flow flows laterally into the catalyst bed via the plurality of lateral gas inlets through the lateral boundary and the other partial flow from above into the catalyst bed via the upper gas inlet into flows. This embodiment has proved to be particularly advantageous, since in this way an improved use of the catalyst is achieved.
- the gas barrier is dimensioned and arranged so that the gas mixture may indeed flow into the catalyst bed via the upper gas inlet, but not out, because it is prevented by the gas barrier.
- the part of the upper side of the catalyst bed on which the gas barrier does not bear preferably faces the lateral boundary and thus the plurality of lateral gas inlets.
- an outer edge of the gas barrier rests flush against the further lateral boundary, so that the entire part of the top of the catalyst bed, on which the gas barrier does not load, the side boundary and thus the plurality of lateral gas inlet faces.
- the transition region, on which an outer edge of the gas barrier preferably rests flush against the further lateral boundary is not completely gastight.
- this is also not required for the gas barrier effect according to the invention. So it is sufficient if the gas barrier opposes the present in the catalyst bed gas mixture a certain flow resistance.
- the horizontal area of the gas barrier in its main plane of extension is preferably 20% to 95%, more preferably 50% to 90%, even more preferably 60 to 85% of the area of the top of the catalyst bed.
- the gas barrier may be made of a single component.
- the gas barrier preferably comprises a plurality of segments, for example at least 2, 3, 4, 5, 6, 7 or 8, preferably similar segments, wherein two laterally adjacent segments each preferably overlap horizontally.
- the segments are movably connected to each other in a manner such that when vertical movement of the gas barrier, the horizontal overlap of the segments is maintained and possibly also a tilting of the gas barrier is counteracted. This may be accomplished in a variety of ways, and appropriate measures will be known to one of ordinary skill in the art, for example glands with play, i. with a freedom of movement of two interlocking or juxtaposed segments.
- the lateral boundary forms an outer cylinder and the further lateral boundary an inner cylinder, wherein the inner cylinder is arranged concentrically within the outer cylinder about a common central axis.
- the catalyst bed according to this embodiment is disposed between the inner wall of the outer cylinder and the outer wall of the inner cylinder.
- the container has a substantially circular cross-sectional area, wherein the outer cylinder is concentrically disposed within the container about a common central axis, whereby between the inner wall of the container and the outer wall of the outer cylinder, an annular gap is formed, through which the gas mixture to the Variety of lateral gas inlets can flow in the outer cylinder.
- this annular gap has a width of at least 5 cm, more preferably at least 10 cm, particularly preferably 10 cm to 40 cm.
- the plurality of lateral gas inlets is arranged in the wall of the outer cylinder, so that the gas mixture from the annular gap on the plurality of lateral gas inlets through the wall of the outer cylinder can flow radially from the side into the catalyst bed to react there at least partially.
- the plurality of lateral gas outlets is preferably arranged in the wall of the inner cylinder, so that the gas mixture can then flow radially out of the catalyst bed into an inner cavity, which is formed by the inner cylinder, via the plurality of lateral gas outlets through the wall of the inner cylinder and over which the gas mixture can be derived.
- This cavity can be considered as a manifold.
- the plurality of lateral gas inlets and the plurality of side gas outlets allow a controlled uniform radial flow of the gas mixture from outside into the reactor bed and then inwardly out of the reactor bed into the cavity.
- the plurality of lateral gas inlets over the entire vertical extent of the wall of the outer cylinder is distributed, so that in particular in the upper region of lateral gas inlets are present. These make it possible for the gas mixture to flow laterally into the catalyst bed through the gas inlets, also in the upper region of the outer cylinder.
- the plurality of lateral (open) gas outlets are not distributed over the entire vertical extent of the wall of the inner cylinder, but spaced in the upper region of the upper edge.
- the gas barrier moves as the catalyst bed contracts.
- the gas barrier preferably has the shape of a disc ring, which is optionally divided into a plurality of overlapping segments, wherein the inner edge of the disc ring preferably rests flush on the outer wall of the inner cylinder.
- the main extension plane of the disc ring and the vertical extension axis of the inner cylinder are preferably arranged substantially orthogonal to one another, wherein the disc ring is movable in the direction of the vertical extension axis of the inner cylinder along the outer wall of the inner cylinder.
- outer cylinder, inner cylinder and disc ring are preferably arranged concentrically to each other about a common axis.
- the cavity formed by the inner cylinder preferably has internals, for example a mixing element and / or a heat exchanger and / or a further cylinder, which deflects the gas stream emerging from the reactor bed (deflecting tube). This is advantageous for the regulation of the flow and a heat exchange.
- the upper edge of the further cylinder is preferably spaced from the top of the cavity closed above, so that the flowing from the plurality of lateral gas outlets into the cavity gas mixture initially flows upwards in an annular gap, which from the inside of the inner cylinder and the outside of the other cylinder is formed, is then deflected and finally along the inside of the other cylinder, if necessary, through the existing internals, preferably a heat exchanger, flows downwards, where it preferably leaves this part of the reactor.
- the reactor according to the invention are container, outer cylinder, inner cylinder, further cylinder and disc ring are preferably arranged concentrically to each other about a common axis.
- the outer edge of the disc ring at least almost describes a circle which is smaller than that circle which is described by the inner wall of the outer cylinder, whereby between the inner wall of the outer cylinder and the outer edge of the disc ring, a further annular gap is formed , which acts as an upper gas inlet, through which the gas mixture can additionally flow from above into the catalyst bed.
- this further annular gap has a width of at least 4 cm, more preferably at least 10 cm, particularly preferably 5 cm to 21 cm.
- the condition satisfies Fi> F 2 , ie the partial area of the upper side of the catalyst bed on which the disc ring acts as a gas barrier is greater than the other partial area of the upper side of the catalyst bed, which acts as the upper gas inlet.
- Fi> 1 the partial area of the upper side of the catalyst bed on which the disc ring acts as a gas barrier is greater than the other partial area of the upper side of the catalyst bed, which acts as the upper gas inlet.
- Fi> 1, 5-F 2 Fi> 2-F 2
- Fi> 2,5-F 2 Fi> 1,5-F 2 , or
- the inner cylinder in an upper region, which abuts the inner edge of the disc ring,
- closed gas outlets which are closed by a concentrically arranged closure, preferably in the form of an inner or outer short tube flush and cuff-shaped, so that they no longer act as gas outlets.
- the extent of the spacing of the (opened) gas outlets from the upper edge of the inner cylinder corresponds to the expected lowering of the gas barrier due to the lowering of the catalyst bed. Since a settling of the catalyst bed over time is expected to be up to about 5% of the original bed height, the extent of the spacing of the (open) gas outlets from the top of the inner cylinder is preferably at least 5% of the total vertical extension of the further lateral boundary , more preferably about 5% to about 15%, or about 5% to about 10%.
- the outer cylinder in a top region, which is arranged substantially parallel to the above-mentioned, upper portion of the inner cylinder, gas inlets, so that the gas mixture through these gas inlets laterally radially in the upper region of the Catalyst bed can flow into it.
- the reactors according to the invention preferably each comprise a container, an outer cylinder, an inner cylinder and a disc ring, which are each arranged concentrically about a common axis.
- the diameters of the containers and the outer cylinders are preferably substantially the same for all reactors, but the diameters of the inner cylinders of the upper reactor and the lower reactor are preferably different.
- the arrangement of the reactors is preferably provided so that the upper reactor is first flowed through by the gas mixture, followed by the lower reactor.
- the lower reactor preferably pursues the purpose of reacting educts contained in the gas mixture, which have not yet reacted in the passage of the upper reactor.
- the reaction conditions, in particular the reaction temperature can preferably be regulated independently in the reactors.
- the upper reactor is preferably configured as illustrated in Figures 5A / B and has within the inner cylinder an upwardly closed cavity in which a heat exchanger and a further cylinder are arranged, wherein the upper edge of the further cylinder from the top of the above closed cavity, so that the flowing of the plurality of lateral gas outlets into the cavity gas mixture can initially flow between the inside of the inner cylinder and the outside of the other cylinder upwards, then is deflected and finally along the inside of the other cylinder down can flow to the lower reactor.
- the lower reactor is preferably designed as illustrated in Figure 6 and also has within the inner cylinder to an upwardly closed cavity in which, in contrast to the upper reactor, however, neither a heat exchanger nor another cylinder are arranged, so that from the plurality of lateral gas outlets in the cavity flowing gas mixture can flow without deflection down; and wherein the diameter of the inner cylinder of the lower reactor is smaller than the diameter of the inner cylinder of the upper reactor, whereby the inner radial extent of the catalyst bed in the lower reactor is greater than in the upper reactor.
- the lower reactor has an upwardly closed cavity, in which another cylinder, in contrast to the upper reactor, however, no heat exchanger is arranged, so that the gas flowing from the plurality of lateral gas outlets into the cavity gas mixture initially between the inside the inner cylinder and the outside of the other cylinder upwards can flow, then is deflected and finally along the inside of the other cylinder can flow down from the lower reactor out.
- the ammonia converter according to the invention comprises three reactors according to the invention, which are arranged one above the other, the middle reactor is preferably designed according to the upper reactor, in particular in the cavity also comprises internals, namely a mixing element, a heat exchanger and a further cylinder, the upper and
- the middle reactor need not be completely identical.
- FIG. 1A shows a side view of a section through a conventional reactor in the state initially filled with catalyst.
- the flow direction of the gas mixture which essentially comprises nitrogen and hydrogen, is indicated by arrows.
- the reactor comprises a container (1), in which a catalyst bed (2) between a lateral boundary (3) and a further lateral boundary (4) is arranged.
- the cylindrical reactor (1), the lateral boundary (3) and the further lateral boundary (4) are each cylindrical and arranged concentric with each other about a common central axis.
- the lateral boundary (3) has a multiplicity of lateral gas inlets (5).
- a first annular gap (9) is formed, through which the gas mixture from above along the outside of the lateral boundary (3) to the plurality of lateral gas inlets (5) in the lateral Limit (3) can flow, via which the gas mixture can then flow from the side into the catalyst bed (2).
- a portion of the top of the catalyst bed (2) is closed by an immovable upper limit (7 '), which is impermeable to the gas mixture.
- the other part of the upper side of the catalyst bed (2) forms an upper gas inlet (8) in the form of a second annular gap through which the gas mixture can additionally flow from above into the catalyst bed (2) in order to at least partially react there with ammonia.
- the further lateral boundary (4) has a multiplicity of lateral gas outlets (6) via which the Gas mixture then flow out of the catalyst bed (2) out into an inner cavity (10), which is formed by the further lateral boundary (4) and through which the gas mixture can be derived.
- Figure 1 B shows the same conventional ammonia reactor in a state where the catalyst bed (2) has shrunk so that the top of the catalyst bed (2) has dropped by the distance d.
- a cavity (H) has formed between the upper side of the catalyst bed (2) and the underside of the immovable upper boundary (7 '), through which a large part of the gas mixture flows without coming into contact with the catalyst bed (2).
- the result is a significant loss of revenue in ammonia synthesis.
- FIG. 2 illustrates a conventional solution to this problem illustrated in FIG. 1, wherein the reactor according to FIG. 1 has been modified so that the lateral boundary (3) in the upper region is concentrically cuff-like from a lateral closure in the form of a short tube (12 '). and the further lateral boundary (4) in the upper region is surrounded concentrically like a sleeve by a lateral closure in the form of a short tube (12 ").
- the gas mixture can not enter the catalyst bed (2) laterally in this upper region because of the short tube (12 '). do not flow out of the catalyst bed (2) in this upper area because of the short tube (12 ").
- FIG. 2A shows a side view of a section through this conventional reactor in the state initially filled with catalyst.
- Figure 2B shows the same conventional reactor in a state where the catalyst bed (2) has shrunk so that the top of the catalyst bed (2) has dropped by the distance d.
- a cavity (H) has arisen between the upper side of the catalyst bed (2) and the underside of the immovable upper boundary (7 ').
- This cavity (H) is closed off from the immovable upper boundary (7 '), the short tube (12') and the short tube (12 ") in such a way that the gas mixture is practically not bypassing the catalyst bed (2) into the cavity (H).
- Figure 3 illustrates in simplified terms the operation of a reactor according to the invention, which comprises a container (1) in which a catalyst bed (2) between a lateral boundary (3) and a further lateral boundary (4) is arranged.
- the lateral Boundary (3) has a multiplicity of lateral gas inlets (5), via which the gas mixture can flow in through the lateral boundary (3) from the side into the catalyst bed (2) in order to react there at least partly to ammonia.
- the further lateral boundary (4) has a multiplicity of lateral gas outlets (6), via which the gas mixture can then flow out of the catalyst bed (2) through the further lateral boundary (4).
- the further lateral boundary (4) has no lateral gas outlets (6).
- a vertically movable gas barrier (7) On the top of the catalyst bed (2) loads a vertically movable gas barrier (7), which preferably prevents the gas mixture from flowing out of the catalyst bed (2) on its upper side.
- the gas barrier (7) is movable in the vertical direction along the further lateral boundary (4) and thereby preferably connects flush to the further lateral boundary (4); which is preferably supported by a contact element (13).
- FIG. 3A shows a side view of a section through this reactor according to the invention in the state initially filled with catalyst.
- Figure 3B shows the same reactor according to the invention in a state in which the catalyst bed (2) has shrunk so that the top of the catalyst bed (2) has dropped by the distance d. Since the gas barrier (7) is movable in the vertical direction, it still rests on the top of the catalyst bed (2) and has thus been lowered by the distance d along the further lateral boundary (4). The gas barrier (7) continues to be flush with the further lateral boundary (4), possibly supported by the contact element (13). The formation of a cavity H below the upper boundary (7 '), as in the conventional reactors according to Figures 1A / B and 2A B, is thus prevented. Because of the gas barrier (7), the gas mixture can not escape from the catalyst bed (2) on its top and the total amount of catalyst is used for ammonia synthesis.
- Figure 4 illustrates a simplified embodiment of a preferred embodiment of the reactor according to the invention.
- the vertically movable gas barrier (7) does not bear on the entire upper side of the catalyst bed (2), but only on the part of the upper side of the catalyst bed (2), which faces the further lateral boundary (4) with the lateral gas outlets (6) ,
- the part of the top of the catalyst bed (2) which faces the lateral boundary (3) with the lateral gas inlets (5) is not closed by the gas barrier (7) and thus acts as the upper gas inlet (8) over which the Gas mixture can additionally flow into the reactor bed (2) to react there at least partially to ammonia.
- FIG. 4A shows a side view of a section through this reactor according to the invention in the state originally filled with catalyst.
- Figure 4B shows the same reactor according to the invention in a state in which the catalyst bed (2) has shrunk so that the top of the catalyst bed (2) has dropped by the distance d. Also in this state, the part of the top of the catalyst bed (2) which faces the lateral boundary (3) with the side gas inlets (5) still acts as the top gas inlet (8).
- Figure 5 illustrates in simplified form a further preferred embodiment of the reactor according to the invention, which preferably with respect to container (1), catalyst bed (2), lateral boundary (3) and further lateral boundary (4) substantially radially symmetrical about a common central axis is constructed.
- the lateral boundary (3) forms an outer cylinder (31) and the further lateral boundary (4) an inner cylinder (41), wherein the inner cylinder (41) arranged concentrically within the outer cylinder (31) about a common central axis is.
- the catalyst bed (2) is disposed between the inner wall of the outer cylinder (31) and the outer wall of the inner cylinder (41).
- the container (1) has a substantially circular cross-sectional area, wherein the outer cylinder (31) is arranged concentrically within the container (1) about a common central axis, whereby between the inner wall of the container (1) and the outer wall of the outer cylinder (31) an annular gap (9) is formed, through which the gas mixture to the plurality of lateral gas inlets (5) in the outer cylinder (31) can flow.
- the plurality of lateral gas inlets (5) in the wall of the outer cylinder (31) is arranged so that the gas mixture from the annular gap (9) via the plurality of lateral gas inlets (5) through the wall of the outer cylinder (31) from the side can flow radially into the catalyst bed (2) to react there at least partially to ammonia.
- the plurality of lateral gas outlets (6) in the wall of the inner cylinder (41) is arranged so that the gas mixture then through the plurality of lateral gas outlets (6) through the wall of the inner cylinder (41) radially out of the catalyst bed (2) out into an inner cavity (10), which is formed by the inner cylinder (41) and over which the gas mixture can be derived.
- the gas barrier (7) preferably has the shape of a disc ring (1 1), which is optionally divided into a plurality of overlapping segments, wherein the inner edge (1 1 1) of the disc ring (1 1) preferably on the outer wall of the inner cylinder ( 41) is flush.
- the outer edge (1 12) of the disc ring (1 1) preferably describes at least almost a circle which is smaller than the circle which is described by the inner wall of the outer cylinder (31), whereby between the inner wall of the outer cylinder (31) and the outer edge (1 12) of the disc ring (1 1) an annular gap (81) is formed, which acts as the upper gas inlet (8) through which the gas mixture can additionally flow from above into the catalyst bed (2).
- the inner cylinder (41) has a vertical overall extension (412) and is flanked in its upper region (410) by a lateral closure (12) which is in the form of a short tube (12) which is located inside the inner cylinder (41 ) and flush with the inside of the inner cylinder (41), so that over the entire vertical extent (41 1) of the upper portion (410) of the inner cylinder (41) no gas mixture from the catalyst bed into the cavity (10) can.
- a flow of the gas mixture from the catalyst bed (2) into the cavity (10) is made possible only by the plurality of lateral gas outlets (6) which are arranged in the wall of the inner cylinder (41) below its upper portion (410).
- the vertical extent (41 1) of the upper portion (410) of the inner cylinder (41) is preferably at least 5%, more preferably about 5% to about 15%, or about 5% to about 10% of the total vertical extent (412) of the inner Cylinder (41).
- the cavity (10) preferably has internals, preferably a mixer and a further cylinder (14), which deflects the gas stream leaving the reactor bed (deflection tube), which is advantageous for the regulation of the flow and a heat exchange.
- the upper edge of the further cylinder (14) is preferably at a distance from the upper side of the cavity (10) closed above, so that the gas mixture flowing from the plurality of lateral gas outlets (6) into the cavity (10) initially flows upwards in an annular gap which is formed from the inside of the inner cylinder (41) and the outer side of the further cylinder (14), is then deflected and finally flows downwards along the inside of the further cylinder (14).
- FIG. 5A shows a side view of a section through this reactor according to the invention in the state originally filled with catalyst.
- FIG. 5B shows the same reactor according to the invention in a state in which the catalyst bed (2) has shrunk so that the top of the catalyst bed (2) has dropped by the distance d.
- FIG. 6 illustrates a simplified variant of the reactor according to the invention, here already in the state in which the catalyst bed (2) has shrunk, so that the top of the catalyst bed (2) has lowered by the distance d.
- the inner cavity (10) which is formed by the inner cylinder (41) is designed to be space-saving without internals, in particular even without additional cylinders (14).
- This embodiment is particularly preferred if in the inner cavity (10) no heat exchanger is provided to dissipate the resulting heat of reaction.
- the diameter of the inner cylinder (41) is smaller, whereby the catalyst bed (2) can be increased accordingly (shown in Figure 6 as a hatched area).
- Figure 7 illustrates in simplified form a variant of the preferred embodiment of the reactor according to the invention according to FIG 6.
- Figure 7A is a side view in section through the reactor according to the invention already in the state in which the catalyst bed (2) has shrunk, so that the Top of the catalyst bed (2) has lowered by the distance d.
- FIG. 7B is a plan view in section through the reactor according to the invention.
- the inner cylinder (41) is flanked in its upper region (410) by a lateral closure (12) which is in the form of a short tube (12) which is arranged inside the inner cylinder (41) and flush with the inner side of the inner cylinder (41) connects, so that over the entire vertical extent (41 1) of the upper portion (410) of the inner cylinder (41) no gas mixture from the catalyst bed into the cavity (10) can pass.
- a lateral closure (12) which is in the form of a short tube (12) which is arranged inside the inner cylinder (41) and flush with the inner side of the inner cylinder (41) connects, so that over the entire vertical extent (41 1) of the upper portion (410) of the inner cylinder (41) no gas mixture from the catalyst bed into the cavity (10) can pass.
- Such a flow of the gas mixture from the catalyst bed (2) into the cavity (10) is made possible only by the plurality of lateral gas outlets (6) which are arranged in the wall of the inner cylinder (41) below its upper portion (410).
- the gas barrier (7) which presses on top of the catalyst bed (2) is designed as a disk ring (11) which has an inner edge (11) and an outer edge (112) and of several (eight shown here) segments (71) is constructed, which preferably overlap.
- the inner edge (1 1 1) of the disc ring (1 1) is preferably flush with the outer wall of the inner cylinder (41).
- the outer edge (1 12) of the disc ring (1 1) preferably describes at least almost a circle which is smaller than the circle which is described by the inner wall of the outer cylinder (31), whereby between the inner wall of the outer cylinder (31) and the outer edge (1 12) of the disc ring (1 1) an annular gap (81) is formed, which acts as the upper gas inlet (8) through which the gas mixture can additionally flow from above into the catalyst bed (2).
- the Disk ring (1 1) is movable in the vertical direction along the outer wall of the outer cylinder (41) and thereby preferably connects flush with it.
- Figure 8 illustrates in simplified form a preferred embodiment of the disc ring (1 1) of a plurality of overlapping segments (71), wherein the segments (71) are movably connected to each other in a manner such that upon vertical movement of the gas barrier (7) the horizontal Overlapping the segments (71) is maintained.
- the connection can be realized, for example, by screws, rivets, wire and the like.
- Figure 9 illustrates a simplified arrangement of a total of three reactors according to the invention in a common pressure vessel (15), which form an ammonia converter.
- the two upper reactors are reactors according to the invention, as they are also e.g. in FIGS. 5A / B.
- the cavity (10) which is formed by the inner cylinder (41), in addition to a further cylinder (14) each have a heat exchanger (16) is arranged.
- the lower reactor is also a reactor according to the invention, as e.g. Also shown in Figure 6.
- the inner cavity (10 ') which is formed by the inner cylinder (41') is designed to be space-saving in the lower reactor, but without internals, in particular without additional cylinders and without a heat exchanger.
- the diameter of the inner cylinder (41 ') is smaller, whereby the catalyst bed (2) is enlarged correspondingly radially inward.
- the lower reactor is carried out with the further cylinder (14).
- the inner cavity (10 ') in the lower reactor analogously to the two upper reactors, i. also with internals, in particular with a further cylinder (14 ') (not shown in Figure 9), but preferably without a heat exchanger.
- Another aspect of the invention relates to a process for the catalytic synthesis of ammonia, wherein a gas mixture comprising substantially nitrogen and hydrogen at elevated pressure and elevated temperature in a reactor according to the invention described above or in an ammonia converter described above for the reaction.
- a conventional ammonia converter with a capacity of 1200 t NH 3 / d was used.
- This reference converter comprised three superimposed reactors, each with a catalyst bed, the upper reactor (reactor 1) and the middle reactor (reactor 2) having a heat exchanger and all three reactors in the cavity, which was formed by the inner cylinder, another cylinder as a deflection tube (For the deflection tube, see Figures 5 and 9, reference numeral (14)).
- reactor 1 and reactor 2 no separate FLUENT calculations were performed.
- the amount of gas entering the catalyst bed of reactor 1 was 596149 Nm 3 / h.
- the inlet and outlet conditions for the three catalyst beds of this reference converter are summarized in the following table:
- the ammonia converter according to the invention was structurally changed by individual measures (cf., FIG. 9).
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102014209636.7A DE102014209636A1 (de) | 2014-05-21 | 2014-05-21 | Reaktor mit vertikal beweglicher Gassperre |
PCT/EP2015/060748 WO2015177050A1 (de) | 2014-05-21 | 2015-05-15 | Reaktor mit vertikal beweglicher gassperre |
Publications (1)
Publication Number | Publication Date |
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EP3145630A1 true EP3145630A1 (de) | 2017-03-29 |
Family
ID=53267327
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15724580.4A Withdrawn EP3145630A1 (de) | 2014-05-21 | 2015-05-15 | Reaktor mit vertikal beweglicher gassperre |
Country Status (4)
Country | Link |
---|---|
US (1) | US20170073242A1 (de) |
EP (1) | EP3145630A1 (de) |
DE (1) | DE102014209636A1 (de) |
WO (1) | WO2015177050A1 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR113648A1 (es) | 2017-12-20 | 2020-05-27 | Haldor Topsoe As | Convertidor de flujo axial adiabático |
EP3599075A1 (de) * | 2018-07-27 | 2020-01-29 | Siemens Aktiengesellschaft | Reaktor zur durchführung einer chemischen gleichgewichtsreaktion |
EP3983118B1 (de) * | 2019-06-13 | 2023-10-11 | Duke Technologies, LLC | Hydroverarbeitungsreaktor zur verringerung des druckabfalls und zur verlängerung der katalysatorlebensdauer |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2634194A (en) * | 1951-10-31 | 1953-04-07 | Universal Oil Prod Co | Lined reactor |
US3195988A (en) | 1962-05-11 | 1965-07-20 | Pullman Inc | Catalyst holder |
US3560167A (en) | 1968-12-18 | 1971-02-02 | Air Prod & Chem | Upflow catalytic reactor for fluid hydrocarbons |
FR2460707B1 (fr) | 1979-07-13 | 1986-09-05 | Ammonia Casale Sa | Reacteur de synthese, notamment pour la synthese catalytique d'ammoniac et de methanol |
CH646618A5 (it) * | 1981-03-26 | 1984-12-14 | Ammonia Casale Sa | Reattore per sintesi eterogenee catalitiche. |
US4374095A (en) * | 1981-10-29 | 1983-02-15 | Chevron Research Company | Method and apparatus for restraining radial flow catalytic reactor centerpipes |
DE3643726A1 (de) | 1986-12-20 | 1988-06-30 | Uhde Gmbh | Vorrichtung als nh(pfeil abwaerts)3(pfeil abwaerts)-reaktor |
DE68906006T2 (de) | 1988-12-21 | 1993-08-12 | Ammonia Casale Sa | Reaktoren fuer heterogene synthesen. |
EP0461988B1 (de) * | 1990-06-15 | 1994-01-05 | Institut Francais Du Petrole | Reaktor mit einer unteren und/oder oberen Wand, die eine Schicht aus flexiblem feuerfestem Material enthält und seine Verwendung |
DE4031514A1 (de) | 1990-10-05 | 1992-04-09 | Uhde Gmbh | Reaktor zur durchfuehrung katalytischer prozesse mit in rohren untergebrachtem katalysatormaterial |
FR2679787B1 (fr) * | 1991-07-31 | 1994-04-15 | Air Liquide | Adsorbeur a lits d'adsorbants annulaires superposes. |
DE4216661C2 (de) | 1992-05-20 | 1995-03-30 | Uhde Gmbh | Reaktor zur Durchführung exothermer, katalytischer Gasreaktionen |
FR2737975B1 (fr) * | 1995-08-21 | 1997-10-03 | Air Liquide | Appareil de separation de gaz par adsorption |
FR2767716B1 (fr) * | 1997-08-26 | 1999-10-01 | Air Liquide | Appareil de separation de gaz par adsorption et utilisation pour le traitement de flux d'air |
DE20118741U1 (de) * | 2001-11-17 | 2002-02-21 | Linde Ag, 65189 Wiesbaden | Reaktor |
WO2012173731A2 (en) * | 2011-06-15 | 2012-12-20 | Exxonmobil Chemical Patents Inc. | Retrofitting radial flow reactors |
-
2014
- 2014-05-21 DE DE102014209636.7A patent/DE102014209636A1/de not_active Withdrawn
-
2015
- 2015-05-15 WO PCT/EP2015/060748 patent/WO2015177050A1/de active Application Filing
- 2015-05-15 US US15/311,141 patent/US20170073242A1/en not_active Abandoned
- 2015-05-15 EP EP15724580.4A patent/EP3145630A1/de not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO2015177050A1 * |
Also Published As
Publication number | Publication date |
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US20170073242A1 (en) | 2017-03-16 |
WO2015177050A1 (de) | 2015-11-26 |
DE102014209636A1 (de) | 2015-11-26 |
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