EP3052698A1 - Pvdf textile article - Google Patents
Pvdf textile articleInfo
- Publication number
- EP3052698A1 EP3052698A1 EP14787227.9A EP14787227A EP3052698A1 EP 3052698 A1 EP3052698 A1 EP 3052698A1 EP 14787227 A EP14787227 A EP 14787227A EP 3052698 A1 EP3052698 A1 EP 3052698A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coating
- layer
- article
- tetrafluoropropene
- article according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/22—Polymers or copolymers of halogenated mono-olefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/029—Fluoropolymer fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/02—Moisture-responsive characteristics
- D10B2401/021—Moisture-responsive characteristics hydrophobic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/22—Physical properties protective against sunlight or UV radiation
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/20—Industrial for civil engineering, e.g. geotextiles
- D10B2505/204—Geotextiles
Definitions
- the present invention relates to an architectural textile article or article covering polyvinylidene fluoride (PVDF), said article comprising a woven reinforcement and a coating.
- PVDF polyvinylidene fluoride
- An architectural textile or protective covering article is a fabric or a nonwoven fabric for the manufacture of various roofing or construction elements, eg shelters, mobile structures, textile buildings, partitions, tarpaulins, tents , stands, furniture, advertising screens, sun protection, ceilings and blinds.
- various roofing or construction elements eg shelters, mobile structures, textile buildings, partitions, tarpaulins, tents , stands, furniture, advertising screens, sun protection, ceilings and blinds.
- This type of textile material makes it possible to reduce the weight of the structures, to adapt to the constraints of space, brightness, climate and to meet the requirements of the current architecture in terms of freedom of shape, weather resistance and chemical resistance. , durability, fire protection and / or anti-UV.
- PVC cloths known for their low weight are known, which makes it possible to design light structures intended in particular for textile fronts and stretch ceilings.
- the PVC fabrics see a decrease in their mechanical properties over time, due to the phenomenon of exudation of the plasticizers present in the PVC-based formulations.
- ETFE Poly (ethylene-co-tetrafluoroethylene)
- a textile composite material for protecting the back of a solar cell.
- Said material comprises a textile support which may be a fabric layer, a net, a fabric made of fibers or filaments or a ribbon, based on a fluorinated polymer such as PTFE, a fluorinated thermoplastic polymer such as PFA, MF A, FEP, ETFE, PVDF, THV and combinations thereof.
- Said support is coated with a THV coating.
- Said support is connected to the back of a solar cell by means of an elastic adhesive intermediate layer consisting of a fluorinated thermoplastic polymer selected from THV and VDF-based copolymers, or silicone-based copolymers capable of being fused such as polysiloxane / polyurea / polyurethane polymers.
- a fluorinated thermoplastic polymer selected from THV and VDF-based copolymers, or silicone-based copolymers capable of being fused such as polysiloxane / polyurea / polyurethane polymers.
- the examples described in this document show composite structures containing 2 or 3 layers, in which the PTFE backing layer, is coated with THV and connected to the solar cell by an intermediate layer of THV (Example 1) or copolymer-based polysiloxane (Example 3).
- the present invention aims to overcome the disadvantages of the prior art.
- one of the objectives of the present invention is to provide an architectural textile in the form of a composite structure: woven-coating background, having a long life, combined with good UV resistance and performance mechanical support woven unaltered by the coating.
- the invention relates, according to a first aspect, to a textile article comprising a layer of PVDF homopolymer fiber fabric, said layer having a first face and a second face, said layer being coated on at least one of its faces with a coating comprising a copolymer of vinylidene fluoride (VDF) and a fluorinated comonomer.
- VDF vinylidene fluoride
- the invention relates to a method of manufacturing said textile article, said method comprising a step of applying, on at least one of the faces of said PVDF homopolymer layer, said VDF copolymer-based coating by a technique chosen from coating, spraying or soaking / impregnation.
- the invention relates to the use of said textile article as an architectural textile, especially as a stretched canvas and as a protective tarpaulin.
- the subject of the invention is a textile article comprising a layer consisting of a woven material.
- This is a woven made with PVDF homopolymer multi-filaments having a title ranging from 400 dtex (48 filaments) up to 2380 dtex (96 filaments).
- These homopolymer PVDF multi-filaments provide the textile article according to the invention with excellent mechanical strength as well as lightness compatible with its use in various architectural applications.
- the multi PVDF homopolymer filaments used as woven layer using for example the product Kynar ® 705 marketed by the applicant, can be texturized and woven in all types of known technologies.
- This woven fabric is coated with a coating based on a copolymer of vinylidene fluoride and a fluorinated comonomer.
- the said fluorinated comonomer may be chosen from: vinyl fluoride; trifluoroethylene (VF3); chlorotrifluoroethylene (CTFE); bromotrifluoroethylene; 1,2-difluoroethylene; tetrafluoroethylene (TFE); hexafluoropropylene (HFP); perfluoro (alkyl vinyl) ethers such as perfluoro (methyl vinyl) ether (PMVE), perfluoro (ethyl vinyl) ether (PEVE) and perfluoro (propyl vinyl) ether (PPVE); perfluoro (1,3-dioxole); perfluoro (2,2- dimethyl-1,3-dioxole) (PDD), tetrafluoropropene, chlorotrifluoropropene; 3,3,3-
- the above-mentioned fluorinated comonomer is chosen from chlorotrifluoroethylene (CTFE), hexafluoropropylene (HFP), trifluoroethylene (VF3), tetrafluoroethylene (TFE) and mixtures thereof.
- CFE chlorotrifluoroethylene
- HFP hexafluoropropylene
- VF3 trifluoroethylene
- TFE tetrafluoroethylene
- the comonomer is advantageously the HFP.
- the copolymer comprises only VDF and HFP.
- the VDF / HFP copolymer has a level of HFP greater than 10%, preferably greater than 15%. This makes it possible to lower the bending modulus of the coating, which considerably increases the flexibility properties of the textile article according to the invention.
- VDF / HFP of this type are for example those marketed by the Applicant under the name Kynar Flex ® 2500, 2750, 2800, 2900, 2950, and under the name Kynar ULTRAFLEX.
- said copolymer is a random copolymer.
- This type of copolymer has the advantage of having a homogeneous distribution of the comonomer along the vinylidene fluoride chains, unlike the so-called "heterogeneous" copolymers, which are characterized by a non-homogeneous distribution of the comonomer along the chains of vinylidene fluoride.
- VDF due to the synthesis method described by the applicant for example in the document US 6,187,885.
- the heterogeneous VDF / HFP copolymers described in this document are obtained in two stages, initially taking place the homopolymerization of the VDF monomer, followed in a second step by the polymerization of VDF with HFP, leading to obtaining isolated domains which are richer in comonomer in the copolymer thus prepared.
- said coating is applied on a single side of said PVDF homopolymer layer.
- said coating is applied on both sides of said PVDF homopolymer layer.
- the thickness of the coating layer per face varies between 20 and 80 microns, preferably between 40 and 60 microns.
- said coating comprises at least one additive chosen from: flame retardant fillers, conductive fillers, impact modifiers, inorganic thermal stabilizers, organic and inorganic UV stabilizers.
- flame retardant fillers e.g., boron trifluoride
- conductive fillers e.g., boron nitride
- impact modifiers e.g., titanium dioxide
- inorganic thermal stabilizers e.g., titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, titanium dioxide, magnesium, magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium magnesium
- the textile article according to the invention consists of a layer of PVDF homopolymer fiber fabric, said layer being coated on at least one of its faces with a coating based on a copolymer of VDF and of a fluorinated comonomer.
- the invention relates to a method of manufacturing said textile article, said method comprising a step of applying, on at least one of the faces of said PVDF homopolymer layer, said VDF copolymer-based coating by a technique chosen from coating, spraying or soaking / impregnation. These techniques make it possible to apply the coating both to the surface of the multi-filament fibers of PVDF homopolymer, and between these fibers.
- the coating of PVDF copolymer may be applied either in aqueous or solvent route, with the known solvents of PVDF such as those of the family of ketones, of the ethyl methyl ketone (MEK) or methylisobuiyicone (MIBK) type, those of the family of sulfonates of the dimethylsulfoxide type (DMSO) or those of the family of ethyl acetate type ethers, di-ethyl glycol, di-ethyl acetate.
- the known solvents of PVDF such as those of the family of ketones, of the ethyl methyl ketone (MEK) or methylisobuiyicone (MIBK) type, those of the family of sulfonates of the dimethylsulfoxide type (DMSO) or those of the family of ethyl acetate type ethers, di-ethyl glycol, di-ethyl acetate.
- the application of the coating by means of the abovementioned techniques has the advantage of making it possible to easily adjust the thicknesses of the coating and to ensure better compatibility between the PVDF fibers and the coating layer (s) due to the chemical nature of the polymers.
- the invention relates to the use of said textile article as an architectural textile, particularly as a stretched canvas. Such an article is particularly suitable for various applications in this field, and has one or more of the following properties:
- Example 1 according to the invention
- a textile article according to the invention was prepared from a layer of woven multifilament homopolymer PVDF (KYNAR ® PVDF 705) having a titre of 550 dtex (96filaments). This nonwoven layer was coated by a coating comprising a VDF / HFP copolymer (Kynar Flex ® 2500-20) previously dissolved in a mixture of MEK and ethyl acetate.
- the coating formulation contains the following components (per 100 g):
- solvent MEK
- This formulation is deposited in liquid on both sides of the fabric using a device type coating. After evaporation of the solvent (air drying or a few minutes at 60 ° C), the coating on each side is about 15 microns and is present between the fibers that make up the fabric. The final thickness of 50 microns was obtained after three successive sprays.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1359652A FR3011504B1 (en) | 2013-10-04 | 2013-10-04 | TEXTILE ARTICLE IN PVDF |
PCT/FR2014/052466 WO2015049456A1 (en) | 2013-10-04 | 2014-09-30 | Pvdf textile article |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3052698A1 true EP3052698A1 (en) | 2016-08-10 |
Family
ID=49998401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14787227.9A Withdrawn EP3052698A1 (en) | 2013-10-04 | 2014-09-30 | Pvdf textile article |
Country Status (7)
Country | Link |
---|---|
US (1) | US20160244910A1 (en) |
EP (1) | EP3052698A1 (en) |
JP (1) | JP6470742B2 (en) |
KR (1) | KR20160065161A (en) |
CN (1) | CN105593433A (en) |
FR (1) | FR3011504B1 (en) |
WO (1) | WO2015049456A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017537208A (en) | 2014-12-09 | 2017-12-14 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | Copolymer of 1,3,3,3-tetrafluoropropene |
WO2018051787A1 (en) * | 2016-09-14 | 2018-03-22 | 株式会社クレハ | Vinylidene fluoride resin fibers and sheet-like structure |
CN109563645B (en) * | 2016-09-14 | 2020-02-11 | 株式会社吴羽 | Vinylidene fluoride resin fiber and sheet-like structure |
US20180142379A1 (en) * | 2016-11-18 | 2018-05-24 | Honeywell International Inc. | Electrospinning of fluoropolymers |
EP3727836A1 (en) * | 2017-12-21 | 2020-10-28 | Beaulieu International Group NV | Biodegradable fabric and use of such fabric |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0174792A3 (en) * | 1984-09-07 | 1987-07-01 | Teijin Limited | Waterproof composite sheet material |
JPS6166646A (en) * | 1984-09-10 | 1986-04-05 | 帝人株式会社 | Laminate for sail |
JPS6164447A (en) * | 1984-09-07 | 1986-04-02 | 帝人株式会社 | Laminate |
JPS6170072A (en) * | 1984-09-07 | 1986-04-10 | 呉羽化学工業株式会社 | Production of fluorocarbon resin fiber structure |
FR2632654B1 (en) * | 1988-06-09 | 1994-05-06 | Atochem | VINYLIDENE POLYFLUORIDE MATERIAL WITH A SURFACE SUITABLE FOR ADHERING TO A NON-COMPATIBLE POLYMER, METHOD OF SURFACE TREATMENT OF A VINYLIDENE POLYFLUORIDE MATERIAL TO ENABLE ADHERENCE TO A NON-COMPATIBLE POLYMER |
US5093427A (en) | 1990-05-10 | 1992-03-03 | Atochem North America, Inc. | Copolymers of vinylidene fluoride and hexafluoropropylene and process for preparing the same |
JPH0976420A (en) * | 1995-09-18 | 1997-03-25 | Toray Ind Inc | Film material and production thereof |
JP3682601B2 (en) * | 2001-01-15 | 2005-08-10 | 平岡織染株式会社 | Waterproof composite membrane material fusion bonded body with excellent flame resistance and heat-resistant creep resistance at fusion bonded portion |
US7081216B2 (en) * | 2001-02-15 | 2006-07-25 | Arkema Inc. | Foams and coatings |
JP3741201B2 (en) * | 2001-02-22 | 2006-02-01 | 平岡織染株式会社 | Translucent film material for fluorescent lamp illumination with excellent stretch fixation and shape stability |
JP4177590B2 (en) * | 2002-02-27 | 2008-11-05 | 株式会社 デンギケン | Electrical / electronic insulation sheet |
JP3916622B2 (en) * | 2004-06-02 | 2007-05-16 | 平岡織染株式会社 | Waterproof and durable roofing sheet |
DE202004020048U1 (en) * | 2004-12-22 | 2005-03-17 | Fitz Johannes | Textile composites of fluoropolymers |
US8349747B2 (en) * | 2005-08-02 | 2013-01-08 | W. L. Gore & Associates, Inc. | High seam strength architectural fabric |
US7501356B2 (en) * | 2005-08-02 | 2009-03-10 | Gore Enterprise Holdings, Inc. | Architectural fabric |
FR2896445B1 (en) * | 2006-01-25 | 2010-08-20 | Arkema | FLEXIBLE FILM BASED ON FLUORINATED POLYMER |
US20070207364A1 (en) * | 2006-03-03 | 2007-09-06 | Abd Elhamid Mahmoud H | Fuel cells comprising moldable gaskets, and methods of making |
FR2918082B1 (en) * | 2007-06-27 | 2011-07-01 | Arkema France | PROCESS FOR IMPREGNATING FIBERS CONTINUOUS BY A COMPOSITE POLYMERIC MATRIX COMPRISING A FLUORINATED GRAFT POLYMER |
JP2009203558A (en) * | 2008-02-26 | 2009-09-10 | Toray Ind Inc | Fabric |
WO2010010600A1 (en) * | 2008-07-24 | 2010-01-28 | 株式会社ピアレックス・テクノロジーズ | Photocatalyst coating composition |
DE202008013246U1 (en) * | 2008-10-08 | 2009-01-02 | Fitz, Johannes | Textile fluorothermoplastic composite |
JP6057708B2 (en) * | 2009-06-10 | 2017-01-11 | アーケマ・インコーポレイテッド | Weatherproof substrate coated with polyvinylidene fluoride |
CN101709574B (en) * | 2009-11-10 | 2011-02-02 | 南京工业大学 | Self-floating type composite material bridge pressurized-water anti-collision device |
DE202010009801U1 (en) * | 2010-07-02 | 2010-10-14 | Fitz, Johannes | Finish for finishing textile structures made of fluoropolymers |
EP2527507B1 (en) * | 2011-05-23 | 2013-12-11 | Ettlin Aktiengesellschaft | Weather protection device |
DE202011109461U1 (en) * | 2011-12-22 | 2012-02-15 | Aeronautec Gmbh | Textile solar cell composites of high flexibility |
-
2013
- 2013-10-04 FR FR1359652A patent/FR3011504B1/en active Active
-
2014
- 2014-09-30 EP EP14787227.9A patent/EP3052698A1/en not_active Withdrawn
- 2014-09-30 WO PCT/FR2014/052466 patent/WO2015049456A1/en active Application Filing
- 2014-09-30 JP JP2016519737A patent/JP6470742B2/en active Active
- 2014-09-30 CN CN201480054543.XA patent/CN105593433A/en active Pending
- 2014-09-30 US US15/026,289 patent/US20160244910A1/en not_active Abandoned
- 2014-09-30 KR KR1020167011343A patent/KR20160065161A/en not_active Application Discontinuation
Non-Patent Citations (2)
Title |
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None * |
See also references of WO2015049456A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP6470742B2 (en) | 2019-02-13 |
FR3011504B1 (en) | 2015-10-23 |
CN105593433A (en) | 2016-05-18 |
FR3011504A1 (en) | 2015-04-10 |
US20160244910A1 (en) | 2016-08-25 |
WO2015049456A1 (en) | 2015-04-09 |
JP2016533280A (en) | 2016-10-27 |
KR20160065161A (en) | 2016-06-08 |
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