EP2978867A1 - Alloy for the production of jewels - Google Patents
Alloy for the production of jewelsInfo
- Publication number
- EP2978867A1 EP2978867A1 EP14720688.2A EP14720688A EP2978867A1 EP 2978867 A1 EP2978867 A1 EP 2978867A1 EP 14720688 A EP14720688 A EP 14720688A EP 2978867 A1 EP2978867 A1 EP 2978867A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- alloy
- gold
- alloy according
- jewels
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 73
- 239000000956 alloy Substances 0.000 title claims abstract description 73
- 239000010437 gem Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 36
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000010931 gold Substances 0.000 claims abstract description 20
- 229910052737 gold Inorganic materials 0.000 claims abstract description 20
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052802 copper Inorganic materials 0.000 claims abstract description 9
- 239000010949 copper Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 150000002739 metals Chemical class 0.000 claims abstract description 9
- 229910052738 indium Inorganic materials 0.000 claims abstract description 8
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052709 silver Inorganic materials 0.000 claims abstract description 8
- 239000004332 silver Substances 0.000 claims abstract description 8
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 7
- 239000010948 rhodium Substances 0.000 claims abstract description 7
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 4
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 4
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052762 osmium Inorganic materials 0.000 claims abstract description 4
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 239000010703 silicon Substances 0.000 claims abstract description 4
- 229910052718 tin Inorganic materials 0.000 claims abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
- 229910001751 gemstone Inorganic materials 0.000 claims description 2
- 239000010938 white gold Substances 0.000 description 10
- 229910000832 white gold Inorganic materials 0.000 description 10
- 239000010970 precious metal Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 229910001020 Au alloy Inorganic materials 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 239000003353 gold alloy Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- QHSFHBRFVUUBJK-UHFFFAOYSA-N [Cu].[Zn].[In] Chemical compound [Cu].[Zn].[In] QHSFHBRFVUUBJK-UHFFFAOYSA-N 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- JRTYPQGPARWINR-UHFFFAOYSA-N palladium platinum Chemical compound [Pd].[Pt] JRTYPQGPARWINR-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/06—Alloys based on silver
Definitions
- the invention concerns an alloy for the production of jewels, in particular trinkets.
- the invention concerns also objects, in particular jewels and trinkets produced with this alloy, as well as the use of the alloy for the production»of jewels.
- Gold and platinum are metals that do not oxidize easily but they are very expensive.
- the weight of gold and platinum is relatively high, which limits the size that can be reasonably obtained for the jewels, in particular in the case of earrings.
- the market of costume jewellery has developed several alloys with a low gold and platinum content that are less expensive than gold alloys but pose several drawbacks.
- it is necessary to coat the item for example by means of a plating process carried out using galvanising methods. This layer, however, is subject to wear.
- the alloys that replace the traditional gold alloys do not maintain their gilded/platinum plated appearance over time and need to be frequently cleaned. Moreover, often these alloys do not imitate the precious metal and its alloys perfectly in terms of external appearance, that is, in terms of colour and degree of brightness. In particular, the market offers only a few alloys with a low content of precious metals that look like white gold.
- the object of the present invention is to propose an improved alloy that overcomes the drawbacks listed above.
- the object of the present invention is mainly to propose an alloy with a low precious metal carat rating that, in addition to not oxidizing easily and having good workability for the needs of the jewellery sector, imitates the aspect and the brightness of white gold.
- an alloy for the production of jewels that is constituted by: 4 - 10%, preferably 5 - 10%, more preferably 6 - 10% zinc by weight; 0.1 - 4.3% gold by weight; 8 - 20% copper by weight; 1 - 6% indium by weight; 0 - 4.3% platinum by weight; 0 - 4.3% palladium by weight; 0 - 10%, preferably 0 - 1.5% by weight of a combination of nickel and rhodium preferably with a weight ratio of 1 :1 ; 0 - 0.5% by weight of auxiliary elements, in particular one or more metals selected among iridium, germanium, silicon, osmium, tin and gallium, wherein the rest is constituted by silver.
- alloys described herein can always contain other elements, meaning elements that are not listed as components that make up the alloy, in the form of traces in overall quantities up to 0.2% by weight, preferably up to 0.1 % by weight. These traces derive from impurities present in the raw materials or are residues of auxiliary materials used during the production or processing of the alloy.
- the alloy according to the invention is advantageously in the colour of white gold.
- the variation in the content of metals or combinations of metals that are yellow/red compared to metals with a silvery colouring makes it possible to obtain different hues within the colour that in the sector of jewellery is considered as white gold colour.
- alloys according to the invention that contain nickel there is rhodium in a weight ratio of 1 :1 with respect to nickel, in order to bind nickel and prevent it from detaching from the alloy and therefore to reduce the allergenic nature of the alloy itself.
- the alloy is very sturdy, elastic, easy to clean, polish and machine and has good lapping values, partly better than those of other alloys with higher carat rating.
- the alloy does not contain iridium, germanium, silicon, osmium, tin and gallium as elements that make up the alloy.
- the alloy in any case, can contain these elements within the group consisting of traces of other elements.
- compositions that in the search for economic alloys with low precious metal carat rating have proved to be particularly suited to be used to make trinkets, because they do not oxidize easily, are easy to machine and shiny, and imitate the shades of the alloys known as white gold.
- a preferred variant embodiment of the invention concerns an alloy whose silver content corresponds to 55 - 75% by weight. Obviously, the sum of the weights of the components of the alloy as indicated above makes up a total of 100% by weight.
- the alloy according to the invention comprises 8 - 15% copper by weight, preferably 14 - 15% copper by weight. Contrary to expectations, this percentage represents a good compromise between a reduction of yellow in the alloy and a satisfactory structure in terms of sturdiness and workability of the alloy.
- the content of indium in the alloy according to the invention corresponds to 1 - 2% by weight. Even relatively small quantities of indium produce a considerable whitening effect.
- the alloy according to the invention comprises approximately 4.17% gold by weight.
- the alloy also comprises approximately 4.17% platinum or palladium by weight or approximately 4.17% platinum by weight and approximately 4.17% palladium by weight.
- the alloy according to the invention comprises 4.17% by weight of one or more precious metals selected among gold, palladium and platinum.
- the alloy according to the invention comprises 8.34% by weight or 12.51 % by weight of one or more precious metals selected among gold, palladium and platinum, wherein gold is preferably present in concentrations of 4.17% by weight.
- These alloys correspond to alloys with low precious metal carat ratings: for example, 1 carat gold and alternatively 1 carat gold plus 1 or 2 carats platinum and/or palladium. Even with maximum 3 carats of precious metals (gold, platinum and palladium) it has been possible to obtain an alloy that does not oxidize easily, is sufficiently hard and elastic, suited to be worked with the techniques in use in the jewellery sector, very bright and in the colour of white gold.
- the same comprises 1 - 1.5% nickel by weight and, due to the reasons explained above, also 1 - 1.5% rhodium by weight.
- a much preferred alloy according to the invention is constituted by 19 - 20% copper by weight, 4 - 5% zinc by weight, approximately 4.17% gold by weight, 1 - 2%, preferably approximately 2% indium by weight, and the remaining percentage needed to reach 100% by weight is silver.
- the alloy is characterized by optimal workability for the jewellery sector, considerable brightness and a white gold colour thanks to which it can be mistaken for real white gold.
- the invention furthermore concerns the use of the alloy according to the invention for the production of jewels, in particular trinkets.
- a third aspect of the invention concerns an item, preferably a jewel or a trinket, produced with an alloy according to the invention.
- the alloy according to the invention is suited to be used in the processing cycles that are typical of the jewellery sector.
- the invention achieves the object to provide an economic alloy with low carat rating of gold, platinum and palladium that, in addition to not oxidizing easily and having good workability, imitates the appearance of white gold and is considerably bright.
- the production of the alloy follows the methods known in the art and the general knowledge of the expert in the art for producing alloys containing gold, silver, brass, etc.
- the components of the alloy can be combined together starting from the pure metals and/or corresponding alloys, like for example brass, for example brass containing 70% copper by weight and 30% zinc by weight. These methods are not described herein for the sake of brevity.
- w% 100% by weight
- w% known in the sector, means “% by weight”.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
- Medicinal Preparation (AREA)
- Saccharide Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Eyeglasses (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL14720688T PL2978867T3 (en) | 2013-03-26 | 2014-03-20 | Alloy for the production of jewels |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000084A ITVI20130084A1 (en) | 2013-03-26 | 2013-03-26 | LEAGUE FOR THE PRODUCTION OF JEWELRY |
PCT/IB2014/000408 WO2014155178A1 (en) | 2013-03-26 | 2014-03-20 | Alloy for the production of jewels |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2978867A1 true EP2978867A1 (en) | 2016-02-03 |
EP2978867B1 EP2978867B1 (en) | 2017-04-19 |
Family
ID=48366497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14720688.2A Active EP2978867B1 (en) | 2013-03-26 | 2014-03-20 | Alloy for the production of jewels |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2978867B1 (en) |
ES (1) | ES2629909T3 (en) |
IT (1) | ITVI20130084A1 (en) |
PL (1) | PL2978867T3 (en) |
WO (1) | WO2014155178A1 (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4396578A (en) * | 1982-01-27 | 1983-08-02 | Bales Randy L | White gold jewelry alloy |
US7959855B2 (en) * | 2006-10-19 | 2011-06-14 | Heru Budihartono | White precious metal alloy |
-
2013
- 2013-03-26 IT IT000084A patent/ITVI20130084A1/en unknown
-
2014
- 2014-03-20 PL PL14720688T patent/PL2978867T3/en unknown
- 2014-03-20 ES ES14720688.2T patent/ES2629909T3/en active Active
- 2014-03-20 WO PCT/IB2014/000408 patent/WO2014155178A1/en active Application Filing
- 2014-03-20 EP EP14720688.2A patent/EP2978867B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
WO2014155178A1 (en) | 2014-10-02 |
ITVI20130084A1 (en) | 2014-09-27 |
PL2978867T3 (en) | 2017-10-31 |
ES2629909T3 (en) | 2017-08-16 |
EP2978867B1 (en) | 2017-04-19 |
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