EP2920112A4 - Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins - Google Patents

Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Info

Publication number
EP2920112A4
EP2920112A4 EP13855440.7A EP13855440A EP2920112A4 EP 2920112 A4 EP2920112 A4 EP 2920112A4 EP 13855440 A EP13855440 A EP 13855440A EP 2920112 A4 EP2920112 A4 EP 2920112A4
Authority
EP
European Patent Office
Prior art keywords
oxygenates
olefins
conversion
production
zeolitic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP13855440.7A
Other languages
German (de)
French (fr)
Other versions
EP2920112A1 (en
Inventor
Manuela Gaab
Ulrich Mueller
Milan Kostur
Kirsten Braunsmann
Kerem Bay
Andrei-Nicolae Parvulescu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP13855440.7A priority Critical patent/EP2920112A4/en
Publication of EP2920112A1 publication Critical patent/EP2920112A1/en
Publication of EP2920112A4 publication Critical patent/EP2920112A4/en
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B01J35/30—
    • B01J35/40—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
    • B01J35/23—
    • B01J35/50—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
EP13855440.7A 2012-11-13 2013-11-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins Pending EP2920112A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13855440.7A EP2920112A4 (en) 2012-11-13 2013-11-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12192407 2012-11-13
PCT/IB2013/060057 WO2014076625A1 (en) 2012-11-13 2013-11-11 Production and Use of a Zeolitic Material in a Process for the Conversion of Oxygenates to Olefins
EP13855440.7A EP2920112A4 (en) 2012-11-13 2013-11-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Publications (2)

Publication Number Publication Date
EP2920112A1 EP2920112A1 (en) 2015-09-23
EP2920112A4 true EP2920112A4 (en) 2016-12-07

Family

ID=47143770

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13855440.7A Pending EP2920112A4 (en) 2012-11-13 2013-11-11 Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins

Country Status (6)

Country Link
EP (1) EP2920112A4 (en)
JP (1) JP6461807B2 (en)
KR (1) KR102171666B1 (en)
CN (1) CN104918886B (en)
WO (1) WO2014076625A1 (en)
ZA (1) ZA201504215B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102305167B1 (en) * 2013-10-23 2021-09-29 바스프 에스이 Molding for a hydrophobic zeolitic material and process for its production
JP6519943B2 (en) * 2015-03-25 2019-05-29 株式会社豊田中央研究所 Spherical silica-based mesoporous material and method for producing the same
EP3341329A1 (en) * 2015-08-27 2018-07-04 Chevron U.S.A. Inc. Molecular sieve ssz-91, methods for preparing ssz-91, and uses for ssz-91
JP2017114755A (en) * 2015-12-25 2017-06-29 ユニオン昭和株式会社 Zeolite and manufacturing method therefor
MY190500A (en) * 2016-02-19 2022-04-25 Hitachi Zosen Corp Zeolite separation membrane and production method therefor
CN106064822B (en) * 2016-05-30 2018-03-23 中国科学院大连化学物理研究所 A kind of MWW/MEL cocrystallization molecular sieve and its synthetic method
US11046587B2 (en) * 2016-06-17 2021-06-29 Basf Se Process for a continuous synthesis of zeolitic materials
EP3509991B1 (en) * 2016-09-06 2021-12-01 Basf Se Solidothermal synthesis of a boron-containing zeolite with an mww framework structure
GB2597878B (en) 2016-09-30 2022-12-07 Johnson Matthey Plc A zeolite synthesis
SG11201908901UA (en) * 2017-03-29 2019-10-30 Exxonmobil Chemical Patents Inc Catalyst compositions and their use in aromatic alkylation processes
WO2019030279A1 (en) * 2017-08-08 2019-02-14 Basf Se A composition comprising a mixed metal oxide and a molding comprising a zeolitic material having framework type cha and an alkaline earth metal
CN108751219B (en) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 Hierarchical porous EU-1 molecular sieve and synthesis method thereof
CN108946762B (en) * 2018-08-20 2020-02-14 中触媒新材料股份有限公司 Hierarchical porous EU-1 molecular sieve and preparation method thereof
CN114786809A (en) * 2019-12-11 2022-07-22 巴斯夫欧洲公司 Method for producing a molded article comprising a zeolite catalyst and method for converting an oxygenate to an olefin using the catalytic molded article
CN111573694B (en) * 2020-06-17 2021-10-15 浙江大学 Method for synthesizing aluminum-enriched MRE zeolite molecular sieve by organic template in one step

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0178687A2 (en) * 1984-07-13 1986-04-23 Exxon Research And Engineering Company Zeolite catalyst preparation
US20070135637A1 (en) * 2003-12-02 2007-06-14 Basf Aktiengesellschaft Pentasil-structuer zeolithic material the production and use thereof
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

Family Cites Families (4)

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Publication number Priority date Publication date Assignee Title
DE4131448A1 (en) * 1991-09-21 1993-03-25 Basf Ag METHOD FOR THE PRODUCTION OF ESSENTIALLY ALKALIFE BORSILICATE CRYSTALS WITH ZEOLITE STRUCTURE
JP2005138000A (en) * 2003-11-05 2005-06-02 Jgc Corp Catalyst, method for preparing catalyst and method for producing lower hydrocarbon using the same catalyst
CN101945823B (en) * 2008-02-22 2013-07-03 埃克森美孚化学专利公司 Large crystal molecular sieves and their manufacture
PL2454007T3 (en) * 2009-07-13 2018-01-31 Lhoist Rech Et Developpement Sa Solid inorganic composition, method for preparing same, and use thereof for reducing dioxins and heavy metals in flue gases

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0178687A2 (en) * 1984-07-13 1986-04-23 Exxon Research And Engineering Company Zeolite catalyst preparation
US20070135637A1 (en) * 2003-12-02 2007-06-14 Basf Aktiengesellschaft Pentasil-structuer zeolithic material the production and use thereof
WO2011089263A1 (en) * 2010-01-25 2011-07-28 Total Petrochemicals Research Feluy Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
ALI A ROWNAGHI ET AL: "Yield of gasoline-range hydrocarbons as a function of uniform ZSM-5 crystal size", CATALYSIS COMMUNICATIONS, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 14, no. 1, 12 July 2011 (2011-07-12), pages 37 - 41, XP028286827, ISSN: 1566-7367, [retrieved on 20110723], DOI: 10.1016/J.CATCOM.2011.07.015 *
AOKI K ET AL: "Gas permeation properties of ion-exchanged ZSM-5 zeolite membranes", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 39, no. 3, 1 October 2000 (2000-10-01), pages 485 - 492, XP004217701, ISSN: 1387-1811, DOI: 10.1016/S1387-1811(00)00224-9 *
MCINTOSH R J ET AL: "THE PROPERTIES OF MAGNESIUM AND ZINC-OXIDE TREATED ZSM-5 CATALYSTS FOR CONVERSION OF METHANOL INTO OLEFIN-RICH PRODUCTS", APPLIED CATALYSIS, AMSTERDAM, NL, vol. 6, no. 3, 1 January 1983 (1983-01-01), pages 307 - 314, XP002717328, ISSN: 0166-9834 *
RAYMOND LE VAN MAO ET AL: "Composite ZSM-5 zeolite/asbestos catalysts", CANADIAN JOURNAL OF CHEMISTRY, vol. 63, no. 12, 1 December 1985 (1985-12-01), pages 3464 - 3470, XP055112794, ISSN: 0008-4042, DOI: 10.1139/v85-568 *
See also references of WO2014076625A1 *

Also Published As

Publication number Publication date
JP2016502487A (en) 2016-01-28
WO2014076625A1 (en) 2014-05-22
KR102171666B1 (en) 2020-10-29
ZA201504215B (en) 2017-11-29
EP2920112A1 (en) 2015-09-23
CN104918886B (en) 2018-08-10
JP6461807B2 (en) 2019-01-30
KR20150086300A (en) 2015-07-27
CN104918886A (en) 2015-09-16

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