EP2830860A1 - Sandwichverbundbauteil und herstellungsverfahren dafür - Google Patents
Sandwichverbundbauteil und herstellungsverfahren dafürInfo
- Publication number
- EP2830860A1 EP2830860A1 EP12812532.5A EP12812532A EP2830860A1 EP 2830860 A1 EP2830860 A1 EP 2830860A1 EP 12812532 A EP12812532 A EP 12812532A EP 2830860 A1 EP2830860 A1 EP 2830860A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- sandwich
- thermoplastic
- foam layer
- decorative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title description 9
- 239000010410 layer Substances 0.000 claims abstract description 228
- 239000006260 foam Substances 0.000 claims abstract description 74
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 65
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 63
- 239000012792 core layer Substances 0.000 claims abstract description 22
- 239000012815 thermoplastic material Substances 0.000 claims abstract description 18
- 239000011265 semifinished product Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 239000002657 fibrous material Substances 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 239000012790 adhesive layer Substances 0.000 claims description 7
- 230000004927 fusion Effects 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000011087 paperboard Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000011111 cardboard Substances 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 230000002277 temperature effect Effects 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 239000011159 matrix material Substances 0.000 description 18
- 238000002844 melting Methods 0.000 description 13
- 230000008018 melting Effects 0.000 description 13
- 239000000835 fiber Substances 0.000 description 11
- -1 polypropylene Polymers 0.000 description 9
- 239000004743 Polypropylene Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 230000007547 defect Effects 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- 238000003825 pressing Methods 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000012783 reinforcing fiber Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 238000009966 trimming Methods 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
- B29C43/20—Making multilayered or multicoloured articles
- B29C43/203—Making multilayered articles
- B29C43/206—Making multilayered articles by pressing the material between two preformed layers, e.g. deformable layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/52—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/086—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/088—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of non-plastics material or non-specified material, e.g. supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/465—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating by melting a solid material, e.g. sheets, powders of fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/04—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/146—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers whereby one or more of the layers is a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2001/00—Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/12—Thermoplastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
- B29K2105/045—Condition, form or state of moulded material or of the material to be shaped cellular or porous with open cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
- B29K2309/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/60—Multitubular or multicompartmented articles, e.g. honeycomb
- B29L2031/608—Honeycomb structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/05—5 or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/02—Cellular or porous
- B32B2305/022—Foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/04—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the partial melting of at least one layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23—Sheet including cover or casing
- Y10T428/234—Sheet including cover or casing including elements cooperating to form cells
- Y10T428/236—Honeycomb type cells extend perpendicularly to nonthickness layer
Definitions
- the invention relates to a sandwich component with a honeycomb core and cover layers and a production method for the same.
- Fuel consumption as well as carbon dioxide emissions are increasingly being used in sandwich structure components, which have a significantly reduced weight compared to conventional components due to the low density of the material forming the core and adequate strength values by suitable means
- Cover layer material selection can offer. Further advantages of such sandwich structures are their thermal and acoustic properties.
- the sandwich component described therein comprises a honeycomb core made of a cellulose-based material such as paper and at least one fiber-reinforced
- thermoplastic cover layer The webs of the honeycomb core are at their
- thermoplastic matrix under the im
- Pressing ruling pressure is at least partially melted, so that the webs of the honeycomb core are received in the cover layer.
- EP 0 787 578 A2 likewise discloses a multilayer component which consists of a support body formed by a honeycomb arrangement, which is connected to at least one fiber-reinforced thermoplastic cover layer.
- the cover layer is applied to the support body, which is connected under the action of pressure and / or temperature under any spatial deformation with the support body to the multilayer component.
- a film and / or a nonwoven fabric made of a thermoplastic material on a cover layer belonging to the fibrous support body, after which the cover layer is heated with the thermoplastic at least until it is viscous. Thereafter, the cover layer is placed on the support body and pressed onto this for connection of the cover layer with the support body.
- the component can be removed from the mold.
- the cover layer can terminate with a cover layer or decorative layer to the outside, which forms the visible surface of the component.
- Forming zones such as the mapping of the honeycomb structure, come.
- Another object is to provide a low cost manufacturing process for such a laminated component.
- a sandwich component according to the invention which has a honeycomb core layer and at least one fiber-reinforced thermoplastic cover layer on both sides, which is connected to the honeycomb core layer by means of a thermoplastic material, which may be the thermoplastic of the cover layer or an additionally introduced thermoplastic material, has at least one Side on a decorated layer on the decorative layer.
- the sandwich component comprises at least on the visible side of the
- Sandwich component between the cover layer and the decorative layer a foam layer which is connected to the cover layer and the decorative layer.
- the foam layer is particularly preferably directly and cohesively connected to the cover layer and the decorative layer.
- the sandwich component can be provided on one side only, namely on the visible side or A side of the component with a decorative layer and the underlying foam layer, but it can also be equipped on both sides with decorative layers, one of which (the visible side) or both are separated by a foam layer from the cover layer.
- the foam layer can be about the connection with the fiber reinforced
- thermoplastic cover layer consist of a foamed thermoplastic.
- Low cost polyolefins such as polypropylene and polyethylene are proposed for use.
- Plastics have the advantage that a fusion and fusion of the foam can take place with the cover layer. This is especially important in the area of the edges.
- a fusion of cover layers and foam layer, or their thermoplastic components is carried out, so that a sealing of the edges is achieved. This is achieved, for example, by an increased pressure in the press in the edge region.
- the cover layer of polypropylene is formed with a fiber reinforcement of glass fiber fleece and the foam layer of foamed polypropylene or polyethylene terephthalate (PET).
- a polyester is preferably selected.
- the polyester of the decorative layer has at least on the surface, or visible surface no recognizable Merger on.
- the foam layer reduces or conceals the markings on the decorative surface.
- the decorative surface also retains the same visual appearance in the edge area and in the forming zones as on the rest of the surface.
- the density of the foam is above 45 kg / m 3 .
- the preferred thickness is above 1 mm, preferably in the range of 1 to 5 mm. For larger errors or irregularities, the volume weight and the foam thickness is up
- foams with a high recovery behavior ie with a low compression set, are to be selected.
- the foam layer may be bonded to the cover layer by means of a thermoplastic material already present in the cover layer or the foam layer or both.
- the composite of the foam layer with the decorative layer can be done by means of the thermoplastic material of the foam layer or carried out by an additional adhesive layer.
- the foam layer can also with the cover layer by means of a
- the sandwich component between the honeycomb core layer and the cover layer may have an additional thermoplastic intermediate layer. It may be beneficial if the physico-chemical properties such as the melting or glass transition temperature of the thermoplastics of the cover layer are similar or equivalent.
- the honeycomb core layer can cost-effectively consist of a cellulose-based material, preferably of paper or cardboard.
- the production of a sandwich component according to the invention comprises, after a sandwich arrangement has been formed, the at least the honeycomb core layer and on both sides of the honeycomb core layer a thermoplastic fiber material layer for forming the cover layer comprising, (a) heating the sandwich assembly until at least the thermoplastic material of the fibrous material layer begins to flow, thereby obtaining a sandwich semi-finished product. Then (b) a decorative layer on at least one side of the heated sandwich semi-finished product and a foam layer are arranged at least between one of the decorative layers, which is provided to form an A-side of the sandwich component, and the sandwich semi-finished product.
- the heated sandwich semifinished product is (c) transferred into an optionally preheated molding press whose temperature is significantly below the melting temperature of the thermoplastic matrix and inserted into the mold cavity such that the side of the sandwich semifinished product with the foam layer and the decorative layer is the A side / visible side the sandwich component is formed.
- the foam and decorative layer is placed on the still hot Sandwichalbzeug only in the cold mold cavity. It follows (d) the compression molding of the heated sandwich semi-finished product with the foam and decorative layers to the sandwich component with simultaneous cooling and thus
- thermoplastic material Consolidation of the thermoplastic material and production of the composite.
- the finished, cut sandwich component can then be removed from the mold.
- the production method enables the cost-effective in-situ lamination of the sand wiping component in order to prevent the marking of surface defects on the decorative layer.
- the heating is preferably carried out in a heating tool, in particular in a hot press, so that the pressing pressure generated thereby causes the thermoplastic fiber material layers to adhere to the honeycomb core.
- the sandwich assembly is heated to a temperature which is in a range above the melting temperature of the thermoplastic matrix plastic of the cover layer, so that this at least at the points where the
- Fibrous material layers rests on the webs of the honeycomb core, melts under the pressure in the hot press.
- the entire matrix plastic can be converted into a flowable state or melting state.
- the heating temperature of the Edelpresswerkmaschines lies at least in the
- thermoplastic polymer matrix By the at least partial melting of the thermoplastic polymer matrix, a good bond between honeycomb core and cover layer is achieved by the end edges of the honeycomb webs of the thermoplastic matrix material of the cover layer
- Adhesive layer between the foam layer and the decorative layer include.
- the foam layer can also be laminated in advance on the decorative layer, so that there is a foam-decor laminate for placement on the heated sandwich semi-finished product.
- an adhesive layer may also be provided between the foam layer and the cover layer, but the bond between the foam layer and the cover layer may preferably be provided by the matrix thermoplasts of the cover layer of the heated sandwich semi-finished product. Furthermore, it can be provided that the foam layer is heated before (b) until the softening of the thermoplastic material of the foam layer, so that the thermoplastic material of the foam layer becomes adhesive and can form the composite with the decorative layer and the cover layer.
- thermoplastic intermediate layer which may preferably be a thermoplastic film, is disposed between the honeycomb core layer and the thermoplastic fiber material layer forming the cover layer prior to step a).
- a good bond between honeycomb core and cover layer is achieved by the at least partial melting of the thermoplastic resin matrix, in which case the end edges of the honeycomb webs are taken up by the thermoplastic matrix material of the intermediate layer, which mediates the connection between honeycomb core and cover layer and at the same time the penetration of fiber material in the
- Honeycomb cavities and thus prevents the reduction of fiber content in the top layer.
- honeycomb core layer made of a cellulose-based material, for example paper, it may also be provided that, especially if higher
- the honeycomb core layer according to the component shape under pressure and temperature before (a) is preformed after it has been moistened to improve the formability of the cellulose-based material.
- the moistening may preferably be done with water by spraying or steaming, while preforming may take place in a compression mold under pressure and heat (in a range of 40 ° C to 200 ° C).
- preforming may take place in a compression mold under pressure and heat (in a range of 40 ° C to 200 ° C).
- Fig. 1 is a schematic sectional views of the tools shown
- Fig. 2 is a diagram of a sectional view of an inventive
- a sandwich component according to the invention comprises, in addition to the honeycomb core and the fiber-reinforced thermoplastic cover layers, at least one decorative layer on the visible side of the component, wherein the use of a foam layer as interlayer between the decorative layer (which may, for example, be a textile product) and the sandwich cover layer for laminating surface defects.
- step a) a multi-layer arrangement of fiber-reinforced thermoplastic layers 3 for forming the cover layers and the interposed honeycomb core layer 4 in a heating tool 30, for. B. heated a hot press.
- a fiber-reinforced thermoplastic layers 3 come z.
- honeycomb is intended to describe the structure of the
- honeycomb core not denote honeycomb core, but means a built up of webs structure with low density and high rigidity.
- Suitable honeycomb core structures include the hexagonal typical "honeycomb” structures as well Wavy, circular, rhombic or rectangular fold structures, as well as irregularly shaped, "organically” appearing structures.As cellulose-based material for the honeycomb core, among other paper and paperboard in question.
- Covering layers may be in the form of nonwoven, random woven or fiber mats with directional fibers, woven, knitted, laid, both unidirectional and multi-directional.
- the reinforcing fibers may be pre-consolidated plate-like in a thermoplastic matrix, in this semifinished product is also called organo sheets.
- a hybrid yarn or hybrid textiis is conceivable, so that a semi-finished fiber product is used which contains thermoplastic fibers which form the matrix, and reinforcing fibers.
- the reinforcing fibers are natural fibers, glass fibers, carbon fibers, polymer, in particular aramid fibers, but it is also possible to use combinations of different fibers.
- the multi-layer arrangement may further comprise a thermoplastic film as intermediate layer between the fiber-reinforced thermoplastic layers 3 and the honeycomb core 4 for improving the cover layer connection.
- a thermoplastic film as intermediate layer between the fiber-reinforced thermoplastic layers 3 and the honeycomb core 4 for improving the cover layer connection.
- Particularly suitable in this case are films
- thermoplastics whose melting properties are those of the thermoplastic
- the film thermoplastic and the thermoplastic matrix of the cover layer may be the same thermoplastic material.
- thermoplastics such as polyamides, acrylonitrile-butadiene-styrene, polypropylene or other polyolefins in question.
- the temperature is applied, which depends on the type of thermoplastic or thermoplastics used and in which it is at least softened, preferably fused, so that the cover layer-forming fiber layers 3 by means of the Matrixthermoplasten or the thermoplastic of the intermediate layer on the
- Cover layers 3 can be removed after opening of the heating tool 30 in step b) and transferred to the forming press tool 20, the arrangement of the decorative layers 1, 1 'on the corresponding sides of the heated sandwich semi-finished 3.4 in Relation to the Part form takes place (step c). Optionally, it may be provided to conceal only the visible side (A-side) of the component with a decorative layer 1.
- a foam layer 2 is integrated at least between the decorative layer 1 forming the visible side of the component and the cover layer 3 in order to obtain a good surface quality of the A side.
- This foam layer 2 may already be laminated with the decorative layer 1.
- the foam layer 2 can also be supplied separately.
- the foam layer 2 adheres to the cover layer 3 by the matrix plastic flowable as a result of the heating.
- the foam layer 2 which may consist of a foamed thermoplastic, can also be heated. If appropriate, this can be carried out together with the sandwich semi-finished product 3, 4 or separately in order not only to allow the material connection to the thermoplastic matrix of the cover layer 3 but also to the decorative layer 1.
- the foam layer should only soften and become adhesive, but not melt, so as not to damage the foam layer
- the foam layer 2 can be connected by an additional adhesive layer, in particular with the decorative layer 1, but optionally also with the cover layer 3.
- materials other than thermoplastics for the foam layer may be used.
- a foam layer 2 made of a thermoplastic can according to the
- thermoplastic intermediate film can be chosen a thermoplastic whose
- the foam layer can be made of a thermoplastic such as polyamides, acrylonitrile-butadiene-styrene, polypropylene, polyethylene or other polyolefins.
- the thermoplastic for forming the foam layer may also be in terms of its
- Melting properties are chosen so that it has a higher melting or glass transition temperature compared to the thermoplastic of the cover layer, to avoid that the foam layer loses its foam structure in contact with the heated sandwich semi-finished product.
- the press tool 20 has a temperature well below the melting temperature of the thermoplastic cover layer, so that when closing the tool 20 not only the shaping takes place to the component 10, but at the same time by the cooling of the thermoplastic material, the composite production takes place between the material layers (step d).
- the foam layer 2 is possible, in particular in the
- Forming of the honeycomb core 4 are conditional. For example, marks made by cell wall cracks of the honeycomb core can be laminated on the surface. After opening the press tool 20, the finished component 10 can be removed from the mold.
- Fig. 2 shows the sandwich construction in a photographic image of a section through a sandwich material constructed according to the invention.
- the visible side of the component (A side) is here formed by a textile decorative fabric 1, under which the laminating foam layer 2 is present, which is separated by a thermoplastic nonwoven cover layer 3, here glass fibers in polypropylene, from the paper honeycomb 4.
- a thermoplastic nonwoven fabric as a cover layer 3 and a textile decorative fabric 1 ', which forms the B side are arranged on the paper honeycomb 4.
- cover layer 3 and the B-side decorative layer 1 'no foam layer before In general, however, it is possible to provide both sides of the sandwich with a laminating foam layer under the decorative layer.
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012006609.0A DE102012006609B4 (de) | 2012-03-30 | 2012-03-30 | Verfahren zur Herstellung eines Sandwichverbundbauteils |
PCT/EP2012/005342 WO2013143569A1 (de) | 2012-03-30 | 2012-12-21 | Sandwichverbundbauteil und herstellungsverfahren dafür |
Publications (2)
Publication Number | Publication Date |
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EP2830860A1 true EP2830860A1 (de) | 2015-02-04 |
EP2830860B1 EP2830860B1 (de) | 2019-09-04 |
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EP12812532.5A Active EP2830860B1 (de) | 2012-03-30 | 2012-12-21 | Sandwichverbundbauteil und herstellungsverfahren dafür |
Country Status (5)
Country | Link |
---|---|
US (1) | US9662854B2 (de) |
EP (1) | EP2830860B1 (de) |
CN (1) | CN104220242B (de) |
DE (1) | DE102012006609B4 (de) |
WO (1) | WO2013143569A1 (de) |
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DE102014006133A1 (de) | 2014-04-26 | 2015-10-29 | Daimler Ag | Verfahren zum Herstellen wenigstens eines Kunststoffbauteils |
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WO2015192948A1 (en) * | 2014-06-19 | 2015-12-23 | Imballaggi Protettivi S.R.L. | Honeycomb sandwich sheet or panel, based on thermoplastic polypropylene |
CN104175569A (zh) * | 2014-07-21 | 2014-12-03 | 青岛顺益新材料科技有限公司 | 一种纤维增强热塑性复合材料的制备方法 |
EP3037264B1 (de) * | 2014-12-22 | 2018-02-07 | Magna Steyr Fahrzeugtechnik AG & Co KG | Wabenkern-Halbzeug und Sandwichbauteil |
PL3037247T3 (pl) | 2014-12-22 | 2018-07-31 | Magna Steyr Fahrzeugtechnik Ag & Co Kg | Sposób wytwarzania elementu sandwiczowego |
DE102015007921A1 (de) * | 2015-06-20 | 2016-12-22 | Daimler Ag | Verbundbauteil für ein Fahrzeug, insbesondere einen Kraftwagen, sowie Verfahren zum Herstellen eines Verbundbauteils |
DE102015111537A1 (de) * | 2015-07-16 | 2017-01-19 | Fvv Gmbh & Co. Kg | Bauteil aus einem Verbundmaterial sowie Verfahren zu dessen Herstellung |
CN105818453B (zh) * | 2016-03-22 | 2017-09-12 | 北京环境特性研究所 | 一种蜂窝结构雷达吸波材料及其制备方法 |
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DE102017218489A1 (de) * | 2017-10-17 | 2019-04-18 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Herstellung eines Sandwichbauteils und Sandwichbauteil |
DE102017011819A1 (de) | 2017-12-20 | 2019-06-27 | Daimler Ag | Verbundelement, insbesondere für ein Fahrzeug |
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DE102019204460A1 (de) * | 2019-03-29 | 2020-10-01 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung eines Sandwichverbund-Bauteils mit eingepresster zwei- oder dreidimensionaler Form sowie ein derartiges Sandwichverbund-Bauteil |
DE102019124642A1 (de) * | 2019-09-13 | 2021-03-18 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | Verkleidungsbauteil für ein Kraftfahrzeug und Verfahren zur Herstellung eines Verkleidungsbauteils sowie Sandwichwerkstoff für ein Verkleidungsbauteil |
DE102019218775A1 (de) * | 2019-12-03 | 2021-06-10 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung einer formbaren thermoplastischen, endlosfaserverstärkten Verbundstruktur, formbare Verbundstruktur sowie Vorrichtung zu deren Herstellung |
DE102020003819B4 (de) | 2020-06-25 | 2022-12-22 | Mercedes-Benz Group AG | Unterbodenverkleidungsteil für ein Fahrzeug und Verfahren zu dessen Herstellung |
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2012
- 2012-03-30 DE DE102012006609.0A patent/DE102012006609B4/de not_active Expired - Fee Related
- 2012-12-21 EP EP12812532.5A patent/EP2830860B1/de active Active
- 2012-12-21 CN CN201280072045.9A patent/CN104220242B/zh active Active
- 2012-12-21 US US14/388,304 patent/US9662854B2/en active Active
- 2012-12-21 WO PCT/EP2012/005342 patent/WO2013143569A1/de active Application Filing
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Also Published As
Publication number | Publication date |
---|---|
DE102012006609B4 (de) | 2017-11-16 |
WO2013143569A1 (de) | 2013-10-03 |
CN104220242A (zh) | 2014-12-17 |
CN104220242B (zh) | 2017-03-15 |
US20150050446A1 (en) | 2015-02-19 |
US9662854B2 (en) | 2017-05-30 |
EP2830860B1 (de) | 2019-09-04 |
DE102012006609A1 (de) | 2013-10-02 |
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