EP2571365A1 - Herbicidal agents for tolerant or resistant grain cultures - Google Patents
Herbicidal agents for tolerant or resistant grain culturesInfo
- Publication number
- EP2571365A1 EP2571365A1 EP11720486A EP11720486A EP2571365A1 EP 2571365 A1 EP2571365 A1 EP 2571365A1 EP 11720486 A EP11720486 A EP 11720486A EP 11720486 A EP11720486 A EP 11720486A EP 2571365 A1 EP2571365 A1 EP 2571365A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- chloro
- fluoro
- amino
- methoxyphenyl
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Definitions
- the invention is in the field of crop protection agents which can be used against harmful plants in tolerant or resistant crops of cereals (such as common wheat, barley, triticale, rye and oats) and contain as herbicidal active ingredients a combination of two or more herbicides.
- cereals such as common wheat, barley, triticale, rye and oats
- herbicidal active ingredients a combination of two or more herbicides.
- the conventional weed control system will be supplemented with new non-selective active ingredients per se in conventional cereals.
- the effectiveness of these herbicides against harmful plants in the tolerant crops is at a high level, but depends - similar to other herbicides - on the type of herbicide used, its application rate, the particular formulation, each to be controlled harmful plants, the climate and soil conditions , etc. from. Furthermore, the herbicides have weaknesses (gaps) against specific types of harmful plants. Another criterion is the duration of the action or the degradation rate of the herbicide. If necessary, changes in the susceptibility of harmful plants (resistance formation), which may occur with prolonged use of the herbicides or geographically limited, must also be taken into account. Losses in individual plants can be compensated only partially, if at all, by higher application rates of herbicides.
- a lower application rate not only reduces the amount of an active ingredient required for the application, but also reduces the amount as a rule on necessary formulation aids. Both reduce the economic effort and improve the environmental compatibility of the herbicide treatment.
- One way to improve the application profile of a herbicide may be to combine the active ingredient with one or more other agents that provide the desired additional properties.
- phenomena of physical, chemical and biological incompatibility often occur in the combined use of several active ingredients, eg. B. lack of stability of a coformulation, decomposition of an active ingredient or antagonism in the biological activity of the active ingredients.
- Desired, however, are combinations of active ingredients with favorable effect profile, high stability and synergistically enhanced as possible effect, which allows a reduction in the application rate compared to the single application of the active ingredients to be combined.
- the compounds (A) and (B) are known. Compounds of type (A1) are described, for example, in DE-A 271 7440.
- WO 2007/120706 A2 describes synergistic herbicide combinations (01, p. 1, line 8-1 1) which contain a pyrimidinecarboxylic acid of the formula 1 (see p. 2, lines 6-16) and a second herbicide (for example GS (Glutamine synthase) inhibitor (01, p. 2, line 25)) or herbicide safener.
- GS Glutamine synthase
- US-A-2002/094934 describes herbicide combinations containing a herbicide A (see p. 1 A. 6-14) and a herbicide B (see p. 1-2, A. 15-19).
- US-A-2007/179059 describes pyrimidinecarboxylic acids and their derivatives of the formula I (see 04, p.1-2).
- the invention thus relates to the use of herbicide combinations for combating harmful plants in cereal crops (preferably in wheat, oat or barley crops, particularly preferably in wheat crops), characterized in that the respective herbicide combination is a herbicide from the group of Compounds of the formula (A1)
- Z is hydroxy, -NHCH (CH 3 ) CONHCH (CH 3 ) COOH -NHCH (CH 3 ) CONHCH [CH 2 CH (CH 3 ) 2 ] COOH, or its ester or salts, and
- X is N or CH and R is CO 2 H or a herbicidally active derivative
- the cereal crops are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.
- Preferred as component (A) are glufosinates and their salts
- Glufosinate-ammonium (A1 .1), - L-glufosinate-ammonium (A1 .2) and
- Bialaphos sodium (A1 .3).
- a herbicidally active derivative is especially understood as meaning salts, esters, carboxamides, acylhydrazides, imidates, thioimidates, amidines, acyl halides, acyl cyanides, acid anhydrides, ethers, acetals, orthoesters, carboxaldehydes, oximes, hydrazones, thioacids, thioesters, Dithiolester, nitriles and any other carboxylic acid derivative which does not quench the herbicidal activity of the compound of general formula (B1) and in plants and / or in the soil, for example by hydrolysis, oxidation, Red u kom ! or other Meta bol is ier
- the compounds of formula (B1) may further form salts by addition of a suitable inorganic or organic acid such as HCl, HBr, H 2 SO 4 or HNO 3 , but also oxalic acid or sulfonic acids to a basic group such as amino or alkylamino , Suitable substituents which are present in deprotonated form, such as, for example, sulfonic acids or carboxylic acids, can form internal salts with groups which can themselves be protonated, such as amino groups. Salts can also be formed by reacting with appropriate substituents, such as sulfonic acids or carboxylic acids, the hydrogen by means of a cation suitable for agriculture wi rd.
- a suitable inorganic or organic acid such as HCl, HBr, H 2 SO 4 or HNO 3
- oxalic acid or sulfonic acids to a basic group such as amino or alkylamino
- Suitable substituents which are present in deprotonated form such as,
- metal salts in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts with cations of the formula [NRR'R "R"'] + in which R to R '"each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl.
- the compounds of general formula (B1) may also include N-oxides.
- Corresponding pyridine N-ox ide are via an oxidation of the corresponding pyridine ine accession I l.
- Appropriate oxidation methods are, for example, in Houben-Weyl, Methods of Organic Chemistry, Extension and following volumes to the 4th edition, Volume E 7b, p 565 f. described.
- component (B) in each case are:
- Particularly preferred components (B) are - 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and
- the synergistic effects are observed when the active ingredients (A) and (B) are applied together, but they can also be detected by splitting. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the simultaneous use of the active ingredients of the respective combination, optionally in several portions. But the time-delayed application of the individual active ingredients of a combination is possible and may be advantageous in individual cases. In this system application, other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated.
- other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated.
- the synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency against the same harmful plant species at the same rate, the control of previously unrecognized species (gaps), an extension of the period of application and / or a reduction in the number of necessary individual applications and - as a result for the Users - economically and ecologically more advantageous weed control systems.
- herbicide combinations are provided which are tolerant Grain crops can be used particularly favorably.
- the herbicides mentioned (A1 .1) to (A1 .3) are taken up via the green parts of the plants and are known as broad-spectrum herbicides or total herbicides; they are inhibitors of the enzyme glutamine synthetase in plants; See "The Pesticide Manual” 11 edition, British Crop Protection Council 1997, pp. 643-645 and 120-121, respectively.
- the combinations are suitably used in cereal crops which are tolerant to the compounds (A1).
- the tolerance may have been produced by breeding or mutation selection (for example, analogously to the commercially available Clearfield® wheat cultures from BASF, which are tolerant to imidazolinone herbicides), or else by genetic engineering methods.
- One tolerant cereal crops that have been genetically engineered are already known, cf. EP-A-0 242 246, EP-A-0 242 236, EP-A-0 257 542, EP-A-0 275 957, EP-A-0 513 054).
- the application rates of the herbicides (B) can vary widely.
- the following areas are suitable:
- the combinations according to the invention can be used together with other active ingredients, for example from the group of fungicides, insecticides and plant growth regulators or from the group of customary in plant protection additives and formulation auxiliaries.
- Additives are, for example, fertilizers, wetting agents, oils and dyes.
- those combinations according to the invention which also contain one or more further active compounds of other structure [active ingredients (C)], for example safeners, plant growth regulators or other herbicides.
- active ingredients (C) for example safeners, plant growth regulators or other herbicides.
- C active ingredients
- two combinations explained preferred conditions in the first place also, if it contains the Zweierkombinationen invention and with respect to the respective Zweierkombination.
- the active substance (C) has to be produced by mutation selection, breeding or genetically engineered in order to enable uses according to the invention or the addition of safeners becomes obligatory.
- compositions which can be used according to the invention comprise as active ingredient (C) cloquintocet (-mexyl) (C1), cyprosulfamide (C2), isoxadifen (-ethyl) (C3) or mefenpyr (-diethyl) (C4).
- compositions which can be used according to the invention contain as active ingredient (C) amidosulfuron (C5), bentazones (C6), bromoxynil (C7), carfentrazone (C8), carfentrazone-ethyl (C9), chlorosulfuron (C10), cinidon-ethyl (C1 1), clodinafop-propargyl (C12), 2,4-D (C13), dicamba (C14), diclofop (C15), diclofop-methyl (C16), diclofop-P-methyl (C17), diflufenican (C18 Ethephon (C19), ethoxysulfuron (C20), fenoxaprop (C21), fenoxaprop-P (C22), fenoxaprop-ethyl (C23), fenoxaprop-P-ethyl (C24), florasulam (C25), flucarba
- compositions which can be used according to the invention contain as active ingredient (C) amidosulfuron (C5), bromoxynil (C7), diclofop (C15), diflufenican (C18), fenoxaprop (C21), fenoxaprop-P (C22), fenoxaprop-ethyl (C23), fenoxaprop-P-ethyl (C24), flufenacet (thiafluamide) (C28), flurtamone (C32), iodosulfuron-methyl-sodium (C40), loxynil (C41), isoproturon (C42), mesosulfuron (C51), Mesosulfuron-methyl (C52), propoxycarbazone (C59), propoxycarbazone-sodium (C60), pyrasulfutole (C61) or thiencarbazone (C65).
- active ingredient C
- amidosulfuron C5
- A1.1 B1.0 (C59) A1.1 B1.1 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.4 (C2) A1.1 B1.4 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.8 (C61) A1.1 B1.9 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.12 (C2) A1.1 B1.12 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.15 (C7) A1.1 B1.15 (C62) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.19 (C61) A1.1 B1.20 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.1 B1.23 (C2) A1.1 B1.23 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.2 (C13) A1.2 B1.3 (C2) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.8 (C41) A1.2 B1.9 (C23) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.10 (C9) A1.2 B1.10 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.16 (C41) A1.2 B1.17 (C23) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.18 (C9) A1.2 B1.18 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
- A1.2 B1.22 (C62) A1.2 B1.23 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to herbicidal combinations and to the use of herbicidal combinations for combating pest plants in grain cultures, characterized in that the respective herbicide combination contains a herbicide from the group of compounds of the formula (A1), where Z is hydroxy, -NHCH(CH3)CONHCH(CH3)COOH or -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH, or the esters or salts thereof, and (B) a herbicide of the formula (B1), where X is N or CH and R is CO2H or a herbicidally active derivative, and the grain cultures are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.
Description
Herbizide Mittel für tolerante oder resistente Getreidekulturen Herbicides for tolerant or resistant cereal crops
Beschreibung description
Die Erfindung liegt auf dem Gebiet der Pflanzenschutzmittel, die gegen Schadpflanzen in toleranten oder resistenten Kulturen von Getreide (wie z.B. Weichweizen, Gerste, Triticale, Roggen und Hafer) eingesetzt werden können und als Herbizidwirkstoffe eine Kombination von zwei oder mehreren Herbiziden enthalten. The invention is in the field of crop protection agents which can be used against harmful plants in tolerant or resistant crops of cereals (such as common wheat, barley, triticale, rye and oats) and contain as herbicidal active ingredients a combination of two or more herbicides.
Mit der Einführung von toleranten oder resistenten Getreidesorten und -linien, insbesondere von transgenen Getreidesorten, -hybriden und -l inien, wird das herkömmliche Unkrautbekämpfungssystem um neue, per se in herkömmlichen Getreidesorten nicht-selektive Wirkstoffe ergänzt. Die Wirkstoffe sind beispielsweise die bekannten breitwirksamen Herbizide wie Glyphosate, Sulfosate, Glufosinate, Bilanafos (= Bialaphos) und Imidazolinon-Herbizide, die nunmehr in den jeweils für sie entwickelten toleranten Kulturen eingesetzt werden können. Die Wirksamkeit dieser Herbizide gegen Schadpflanzen in den toleranten Kulturen liegt auf einem hohen Niveau, hängt jedoch - ähnlich wie bei anderen Herbizidbehandlungen - von der Art des eingesetzten Herbizids, dessen Aufwandmenge, der jeweiligen Zubereitungsform, den jeweils zu bekämpfenden Schadpflanzen, den Klima- und Bodenverhältnissen, etc. ab. Ferner weisen die Herbizide Schwächen (Lücken) gegen spezielle Arten von Schadpflanzen auf. Ein weiteres Kriterium ist die Dauer der Wirkung bzw. die Abbaugeschwindigkeit des Herbizids. Zu berücksichtigen sind gegebenenfalls auch Veränderungen in der Empfindlichkeit von Schadpflanzen (Resistenzbildung), die bei längerer Anwendung der Herbizide oder geographisch begrenzt auftreten können. Wirkungsverluste bei einzelnen Pflanzen lassen sich nur bedingt, wenn überhaupt, durch höhere Aufwandmengen der Herbizide ausgleichen. Außerdem besteht immer Bedarf für Methoden, die Herbizidwirkung mit geringerer Aufwandmenge an Wirkstoffen zu erreichen. Eine geringere Aufwandmenge reduziert nicht nur die für die Applikation erforderliche Menge eines Wirkstoffs, sondern reduziert in der Regel auch die Menge
an nötigen Formulierungshilfsmitteln. Beides verringert den wirtschaftlichen Aufwand und verbessert die ökologische Verträglichkeit der Herbizidbehandlung. With the introduction of tolerant or resistant cereals and strains, in particular transgenic cereals, hybrids and liniments, the conventional weed control system will be supplemented with new non-selective active ingredients per se in conventional cereals. The active compounds are, for example, the known broad-spectrum herbicides such as glyphosate, sulfosate, glufosinate, bilanafos (= bialaphos) and imidazolinone herbicides, which can now be used in the tolerant cultures developed in each case. The effectiveness of these herbicides against harmful plants in the tolerant crops is at a high level, but depends - similar to other herbicides - on the type of herbicide used, its application rate, the particular formulation, each to be controlled harmful plants, the climate and soil conditions , etc. from. Furthermore, the herbicides have weaknesses (gaps) against specific types of harmful plants. Another criterion is the duration of the action or the degradation rate of the herbicide. If necessary, changes in the susceptibility of harmful plants (resistance formation), which may occur with prolonged use of the herbicides or geographically limited, must also be taken into account. Losses in individual plants can be compensated only partially, if at all, by higher application rates of herbicides. In addition, there is always a need for methods to achieve the herbicidal effect with less application rate of drugs. A lower application rate not only reduces the amount of an active ingredient required for the application, but also reduces the amount as a rule on necessary formulation aids. Both reduce the economic effort and improve the environmental compatibility of the herbicide treatment.
Eine Möglichkeit zur Verbesserung des Anwendungsprofils eines Herbizids kann in der Kombination des Wirkstoffs mit einem oder mehreren anderen Wirkstoffen bestehen, welche die gewünschten zusätzlichen Eigenschaften beisteuern. Allerdings treten bei der kombinierten Anwendung mehrerer Wirkstoffe nicht selten Phänomene der physikalischen, chemischen und biologischen Unverträglichkeit auf, z. B. mangelnde Stabilität einer Coformulierung, Zersetzung eines Wirkstoffes bzw. Antagonismus in der biologischen Wirkung der Wirkstoffe. Erwünscht dagegen sind Kombinationen von Wirkstoffen mit günstigem Wirkungsprofil, hoher Stabilität und möglichst synergistisch verstärkter Wirkung, welche eine Reduzierung der Aufwandmenge im Vergleich zur Einzelapplikation der zu kombinierenden Wirkstoffe erlaubt. Die Verbindungen (A) und (B) sind bekannt. Verbindungen vom Typ (A1 ) sind beispielsweise beschrieben in DE-A 271 7440. Verbindungen vom Typ (B1 ) sind beispielsweise beschrieben in WO 2007/082098. Mischungen dieser Verbindungen mit anderen Herbiziden sind z.B. beschrieben in WO 2009/029518. Dort werden auch synergistische Mischungen mancher der erfindungsgemäßen (B)-Komponenten mit dem Totalherbizid Glyphosate beschrieben, aber nicht deren Verwendung in toleranten Kulturen, sondern lediglich Synergismus in Bezug auf die herbizide Wirkung gegen Ungräser/Unkräuter. One way to improve the application profile of a herbicide may be to combine the active ingredient with one or more other agents that provide the desired additional properties. However, phenomena of physical, chemical and biological incompatibility often occur in the combined use of several active ingredients, eg. B. lack of stability of a coformulation, decomposition of an active ingredient or antagonism in the biological activity of the active ingredients. Desired, however, are combinations of active ingredients with favorable effect profile, high stability and synergistically enhanced as possible effect, which allows a reduction in the application rate compared to the single application of the active ingredients to be combined. The compounds (A) and (B) are known. Compounds of type (A1) are described, for example, in DE-A 271 7440. Compounds of type (B1) are described, for example, in WO 2007/082098. Mixtures of these compounds with other herbicides are e.g. described in WO 2009/029518. There are also described synergistic mixtures of some of the (B) components according to the invention with the total herbicide glyphosate, but not their use in tolerant cultures, but only synergism with respect to the herbicidal activity against weeds / weeds.
WO 2007/120706 A2 beschreibt synergistische Herbizid- Kombinationen (01 , S. 1 , Z. 8-1 1 ), die eine Pyrimidincarbonsäure der Formel 1 (siehe S. 2, Z. 6-16) und ein zweites Herbizid (beispielweise GS (Glutamine Synthase) Inhibitor (01 , S. 2, Z. 25)) oder Herbizid Safener enthalten. WO 2007/120706 A2 describes synergistic herbicide combinations (01, p. 1, line 8-1 1) which contain a pyrimidinecarboxylic acid of the formula 1 (see p. 2, lines 6-16) and a second herbicide (for example GS (Glutamine synthase) inhibitor (01, p. 2, line 25)) or herbicide safener.
US-A-2002/094934 beschreibt Herbizid-Kombinationen, die ein Herbizid A (siehe S. 1 A. 6-14) und ein Herbizid B (siehe S. 1 -2, A. 15-19) enthalten.
US-A-2007/179059 beschreibt Pyrimidincarbonsäuren und ihre Derivaten der Formel I (siehe 04, S.1-2). US-A-2002/094934 describes herbicide combinations containing a herbicide A (see p. 1 A. 6-14) and a herbicide B (see p. 1-2, A. 15-19). US-A-2007/179059 describes pyrimidinecarboxylic acids and their derivatives of the formula I (see 04, p.1-2).
Überraschenderweise wurde nun gefunden, dass bestimmte Wirkstoffe aus der Gruppe der genannten breitwirksamen Herbizide (A) in Kombination mit bestimmten Herbiziden (B) in besonders günstiger (synergistischer) Weise zusammenwirken, wenn sie in den Getreidekulturen eingesetzt werden, die für die selektive Anwendung der erstgenannten Herbizide geeignet sind. Surprisingly, it has now been found that certain active compounds from the group of said broad-spectrum herbicides (A) in combination with certain herbicides (B) interact in a particularly favorable (synergistic) manner when used in the grain crops used for the selective application of the former Herbicides are suitable.
Gegenstand der Erfindung ist somit die Verwendung von Herbizid-Kombinationen zur Bekämpfung von Schadpflanzen in Getreidekulturen (bevorzugt in Weizen-, Hafer-, oder Gerstekulturen, besonders bevorzugt in Weizenkulturen), dadurch gekennzeichnet, dass die jeweilige Herbizid-Kombination ein Herbizid aus der Gruppe der Verbindungen der Formel (A1) The invention thus relates to the use of herbicide combinations for combating harmful plants in cereal crops (preferably in wheat, oat or barley crops, particularly preferably in wheat crops), characterized in that the respective herbicide combination is a herbicide from the group of Compounds of the formula (A1)
O O O O
H3C-F CH. H 3 CF CH.
CH2 2^CH Z (A1) CH 2 2 ^ CH Z (A1)
OH NH2 OH NH 2
worin Z für Hydroxy, -NHCH(CH3)CONHCH(CH3)COOH -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH steht, oder dessen Ester oder Salze, und wherein Z is hydroxy, -NHCH (CH 3 ) CONHCH (CH 3 ) COOH -NHCH (CH 3 ) CONHCH [CH 2 CH (CH 3 ) 2 ] COOH, or its ester or salts, and
(B) ein Herbizid der Formel (B1),
(B) a herbicide of the formula (B1),
worin X für N oder CH steht und R für CO2H oder ein herbizid-aktives Derivat steht, enthält und die Getreidekulturen gegenüber den in der Kombination enthaltenen Herbiziden (A) und (B), gegebenenfalls in Gegenwart von Safenern, tolerant sind. in which X is N or CH and R is CO 2 H or a herbicidally active derivative, and the cereal crops are tolerant to the herbicides (A) and (B) contained in the combination, optionally in the presence of safeners.
Als Komponente (A) bevorzugt sind jeweils für sich genommen - Glufosinate und dessen Salze, Preferred as component (A) are glufosinates and their salts,
L-Glufosinate und dessen Salze und L-glufosinate and its salts and
Bialaphos und dessen Salze. Bialaphos and its salts.
Als Komponente (A) besonders bevorzugt sind jeweils für sich genommen As component (A), particular preference is given in each case
Glufosinate-ammonium (A1 .1 ), - L-Glufosinate-ammonium (A1 .2) und Glufosinate-ammonium (A1 .1), - L-glufosinate-ammonium (A1 .2) and
Bialaphos-natrium (A1 .3). Bialaphos sodium (A1 .3).
Verbindungen der allgemeinen Formel (B1 ), in denen der Substituent R für CO2H (also Carbonsäure-Funktion) steht, werden als diejenigen Verbindungen angenommen,
welche an die aktive Stelle eines Pflanzenenzyms oder eines Rezeptors binden und dadurch eine herbizide Wirkung an der Pflanze hervor rufen. Andere Verbindungen der allgemeinen Formel (B1 ), worin der Substituent R eine Gruppe ist, welche innerhalb von Pflanzen oder der Umwelt in eine Carbonsäurefunktion (also CO2H) umgewandelt werden kann, erzeugen einen ähnlichen herbiziden Effekt und werden von der vorliegenden Erfindung ebenfalls umfasst. Somit werden im Rahmen der vorliegenden Erfindung unter einem herbizid-aktiven Derivat insbesondere Salze, Ester, Carboxamide, Acylhydrazide, Imidate, Thioimidate, Amidine, Acylhalogenide, Acylcyanide, Säureanhydride, Ether, Acetale, Orthoester, Carboxaldehyde, Oxime, Hydrazone, Thiosäuren, Thioester, Dithiolester, Nitrile und jedes andere beliebige Carbonsäurederivat, welches die herbizide Wirkung der Verbindung der allgemeinen Formel (B1 ) nicht auslöscht und in Pflanzen und/oder im Boden beispielsweise durch Hyd rolyse , Oxidation , Red u ktion bzw. andersa rtige Meta bol is ieru ng d ie Carbonsäurefunktion bereitstellt, welche j e n ach p H-Wert in dissoziierter oder undissoziierter Form vorliegt, verstanden. Compounds of the general formula (B1) in which the substituent R is CO 2 H (ie carboxylic acid function) are assumed to be those compounds which bind to the active site of a plant enzyme or a receptor and thereby cause a herbicidal activity on the plant. Other compounds of general formula (B1) in which the substituent R is a group which can be converted into a carboxylic acid function (ie CO 2 H) within plants or the environment produce a similar herbicidal effect and are also encompassed by the present invention , Thus, in the context of the present invention, a herbicidally active derivative is especially understood as meaning salts, esters, carboxamides, acylhydrazides, imidates, thioimidates, amidines, acyl halides, acyl cyanides, acid anhydrides, ethers, acetals, orthoesters, carboxaldehydes, oximes, hydrazones, thioacids, thioesters, Dithiolester, nitriles and any other carboxylic acid derivative which does not quench the herbicidal activity of the compound of general formula (B1) and in plants and / or in the soil, for example by hydrolysis, oxidation, Red u ktion or other Meta bol is ieru ng The function of the carboxylic acid provides what is known as the p-H value in dissociated or undissociated form.
Die Verbindungen der Formel (B1 ) können ferner durch Anlagerung einer geeigneten anorganischen oder organischen Säure, wie beispielsweise HCl, HBr, H2SO4 oder HNO3, aber auch Oxalsäure oder Sulfonsäuren an eine basische Gruppe, wie z.B. Amino oder Alkylamino, Salze bilden. Geeignete Substituenten, die in deprotonierter Form, wie z.B. Sulfonsäuren oder Carbonsäuren, vorliegen, können innere Salze mit ihrerseits protonierbaren Gruppen, wie Aminogruppen bilden. Salze können ebenfalls dadurch gebildet werden, dass bei geeigneten Substituenten, wie z.B. Sulfonsäuren oder Carbonsäuren, der Wasserstoff durch ein für die Landwirtschaft geeignetes Kation e rsetzt wi rd . D i ese S a l ze s i nd beispielsweise Metallsalze, insbesondere Alkalimetallsalze oder Erdalkalimetallsalze, insbesondere Natrium- und Kaliumsalze, oder auch Ammoniumsalze, Salze mit organischen Aminen oder quartäre (quaternäre) Ammoniumsalze mit Kationen der Formel [NRR'R"R"']+, worin R bis R'" jeweils unabhängig voneinander einen organischen Rest, insbesondere Alkyl, Aryl, Aralkyl oder Alkylaryl darstellen.
Insbesondere können die Verbindungen der allgemeinen Formel (B1 ) auch N-Oxide umfassen. Entsprechende Pyridin-N-Ox i d e sind über eine Oxidation der entsprechenden Pyrid ine zugäng l ich . Geeig nete Oxidationsmethoden sind beispielsweise in Houben-Weyl, Methoden der organischen Chemie, Erweiterungs- und Folgebände zur 4. Auflage, Band E 7b, S. 565 f. beschrieben. The compounds of formula (B1) may further form salts by addition of a suitable inorganic or organic acid such as HCl, HBr, H 2 SO 4 or HNO 3 , but also oxalic acid or sulfonic acids to a basic group such as amino or alkylamino , Suitable substituents which are present in deprotonated form, such as, for example, sulfonic acids or carboxylic acids, can form internal salts with groups which can themselves be protonated, such as amino groups. Salts can also be formed by reacting with appropriate substituents, such as sulfonic acids or carboxylic acids, the hydrogen by means of a cation suitable for agriculture wi rd. For example, metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts with cations of the formula [NRR'R "R"'] + in which R to R '"each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl. In particular, the compounds of general formula (B1) may also include N-oxides. Corresponding pyridine N-ox ide are via an oxidation of the corresponding pyridine ine accession I l. Appropriate oxidation methods are, for example, in Houben-Weyl, Methods of Organic Chemistry, Extension and following volumes to the 4th edition, Volume E 7b, p 565 f. described.
Als Komponente (B) bevorzugt sind jeweils für sich genommen: Preferred as component (B) in each case are:
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ) Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure ethylester (B1 .2) Ethyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .2)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-n- propylester (B1 .3) - 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1 .4) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-propyl ester (B1 .3) - 4-Amino-3-chloro-6- (4 -chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid i-propyl ester (B1 .4)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-n- butylester (B1 .5) N-butyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .5)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-2- butylester (B1 .6) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butyl ester (B1 .6)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-tert- butylester (B1 .7)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- allylester (B1 .8) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid tert-butyl ester (B1 .7) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid allyl ester (B1 .8)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-2- butoxy-ethylester (B1 .9) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butoxyethyl ester (B1 .9)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- triethylamnnoniunnsalz (B1 .10) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid triethylammonium salt (B1 .10)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .1 1 ) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid potassium salt (B1 .1 1)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B1 .12) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1 .12)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure - methylester (B1 .13) Methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.13)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure - ethylester (B1 .14) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid ethyl ester (B1 .14)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-n propylester (B1 .15) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid n-propyl ester (B1 .15)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-i- propylester (B1 .16) I-propyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.16)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-n butylester (B1 .17) N-butyl ester of 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .17)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-2
butylester (B1 .18) 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2 butyl ester (B1 .18)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbon butylester (B1 .19) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carbon butyl ester (B1 .19)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsä allylester (B1 .20) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid allyl ester (B1 .20)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure-2- butoxy-ethylester (B1 .21 ) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1 .21)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbon triethylammoniunnsalz (B1 .22) - 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbon 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carbon triethylammonium salt (B1 .22) - 6-Amino-5-chloro-2- (4-chloro) 2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic
Kaliumsalz (B1 .23) Potassium salt (B1 .23)
Besonders bevorzugt sind als Komponenten (B) - 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) und Particularly preferred components (B) are - 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ) Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1)
In einer anderen Ausführungsform besonders bevorzugt sind als Komponenten (B) In another embodiment, particular preference is given as components (B)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B1 .12) und 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1 .12) and
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure -
methylester (B1 .13) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid methyl ester (B1 .13)
In d en erfi nd u ng sg em ä ße n H erb izid-Kombinationen können weitere Pflanzenschutzmittelwirkstoffe und im Pflanzenschutz übl iche H ilfsstoffe und Formulierungshilfsmittel verwendet werden. In the case of the herbalicide combinations according to the invention, it is possible to use further crop protection active ingredients and plant protection active ingredients and formulation auxiliaries.
Die synergistischen Wirkungen werden bei gemeinsamer Ausbringung der Wirkstoffe (A) und (B) beobachtet, können jedoch auch bei zeitlich getrennter Anwendung (Splitting) festgestellt werden. Möglich ist auch die Anwendung der Herbizide oder der Herbizid-Kombinationen in mehreren Portionen (Sequenzanwendung), z. B. nach Anwendungen im Vorauflauf, gefolgt von Nachauflauf-Applikationen oder nach frühen Nachauflaufanwendungen, gefolgt von Applikationen im mittleren oder späten Nachauflauf. Bevorzugt ist dabei die simultane Anwendung der Wirkstoffe der jeweiligen Kombination, gegebenenfalls in mehreren Portionen . Aber auch die zeitversetzte Anwendung der Einzelwirkstoffe einer Kombination ist möglich und kann im Einzelfall vorteilhaft sein . In diese Systemanwendung können auch andere Pflanzenschutzmittel wie Fungizide, Insektizide, Akarizide etc. und/oder verschiedene Hilfsstoffe, Adjuvantien und/oder Düngergaben integriert werden. Die synergistischen Effekte erlauben eine Reduktion der Aufwandmengen der Einzelwirkstoffe, eine höhere Wirkungsstärke gegenüber derselben Schadpflanzenart bei gleicher Aufwandmenge, die Kontrolle bislang nicht erfasster Arten (Lücken), eine Ausdehnung des Anwendungszeitraums und/oder eine Reduzierung der Anzahl notwendiger Einzelanwendungen und - als Resultat für den Anwender - ökonomisch und ökologisch vorteilhaftere Unkrautbekämpfungssysteme. The synergistic effects are observed when the active ingredients (A) and (B) are applied together, but they can also be detected by splitting. It is also possible to use the herbicides or herbicide combinations in several portions (sequence application), eg. After pre-emergence applications, followed by post-emergence applications or early post-emergence applications, followed by mid-late post-emergence applications. Preference is given to the simultaneous use of the active ingredients of the respective combination, optionally in several portions. But the time-delayed application of the individual active ingredients of a combination is possible and may be advantageous in individual cases. In this system application, other crop protection agents such as fungicides, insecticides, acaricides, etc. and / or various adjuvants, adjuvants and / or fertilizers can be integrated. The synergistic effects allow a reduction in the application rates of the individual active ingredients, a higher potency against the same harmful plant species at the same rate, the control of previously unrecognized species (gaps), an extension of the period of application and / or a reduction in the number of necessary individual applications and - as a result for the Users - economically and ecologically more advantageous weed control systems.
Beispielsweise werden durch die erfindungsgemäßen Kombinationen aus (A)+(B) synergistische Wirkungssteigerungen möglich, die weit und in unerwarteter Weise über die Wirkungen hinausgehen, die mit den Einzelwirkstoffen (A) und (B) erreicht werden. For example, the combinations of (A) + (B) according to the invention make possible synergistic increases in activity which go far and unexpectedly beyond the effects achieved with the individual active compounds (A) and (B).
Erfindungsgemäß werden Herbizid-Kombinationen bereitgestellt, die in toleranten
Getreidekulturen besonders günstig eingesetzt werden können. According to the invention, herbicide combinations are provided which are tolerant Grain crops can be used particularly favorably.
Die genannten Herbizide (A1 .1 ) bis (A1 .3) werden über die grünen Teile der Pflanzen aufgenommen und sind als Breitspektrum-Herbizide oder Totalherbizide bekannt; sie sind Hemmstoffe des Enzyms Glutaminsynthetase in Pflanzen; siehe "The Pesticide Manual" 1 1 th Edition, British Crop Protection Council 1997, S. 643-645 bzw. 120-121 . The herbicides mentioned (A1 .1) to (A1 .3) are taken up via the green parts of the plants and are known as broad-spectrum herbicides or total herbicides; they are inhibitors of the enzyme glutamine synthetase in plants; See "The Pesticide Manual" 11 edition, British Crop Protection Council 1997, pp. 643-645 and 120-121, respectively.
In den erfindungsgemäßen Kombinationen benötigt man in der Regel vom Wirkstoff (A) am Beispiel des Racemats von Glufosinate eine Aufwandmenge im Bereich von 2,5 bis 2500 g AS/ha (=Gramm Aktivsubstanz pro Hektar), vorzugsweise 3,0 bis 2000 g AS/ha, besonders bevorzugt 5,0 - 1 500 g AS/ha. Entsprechende in Mol pro Hektar umgerechnete Mengen gelten auch für (A1 .1 ), (A1 .2) und (A1 .3). In the combinations according to the invention, as a rule the active ingredient (A) is used on the example of the racemate of glufosinate in the range from 2.5 to 2500 g AS / ha (= grams of active substance per hectare), preferably 3.0 to 2000 g AS / ha, more preferably 5.0-1,500 g AS / ha. Corresponding amounts converted into moles per hectare also apply to (A1 .1), (A1 .2) and (A1 .3).
Die Kombinationen werden zweckmäßig in Getreidekulturen eingesetzt, die gegenüber den Verbindungen (A1 ) tolerant sind. Die Toleranz kann dabei durch Züchtung oder Mutationsselektion erzeugt worden sein (z.B. analog zu den kommerziell erhältlichen Clearfield®-Weizenkulturen der Firma BASF, welche gegen Imidazolinon-Herbizide tolerant sind), oder auch durch gentechnische Verfahren . Ein ige tolerante Getreidekulturen, die gentechnisch erzeugt wurden, sind bereits bekannt, vgl. EP-A-0 242 246, EP-A-0 242 236, EP-A-0 257 542, EP-A-0 275 957, EP-A-0 513 054). The combinations are suitably used in cereal crops which are tolerant to the compounds (A1). The tolerance may have been produced by breeding or mutation selection (for example, analogously to the commercially available Clearfield® wheat cultures from BASF, which are tolerant to imidazolinone herbicides), or else by genetic engineering methods. One tolerant cereal crops that have been genetically engineered are already known, cf. EP-A-0 242 246, EP-A-0 242 236, EP-A-0 257 542, EP-A-0 275 957, EP-A-0 513 054).
Die Aufwandmengen der Herbizide (B) können stark variieren. Zweckmäßig sind folgende Bereiche: The application rates of the herbicides (B) can vary widely. The following areas are suitable:
Im Allgemeinen 0,5 - 500 g AS/ha, bevorzugt 1 - 400 g AS/ha, besonders bevorzugt: 2 - 300 g AS/ha (vgl. die Angaben zur Gruppe der Verbindungen (A) In general, 0.5-500 g AS / ha, preferably 1 - 400 g AS / ha, more preferably: 2 - 300 g AS / ha (see the information on the group of compounds (A)
Die Mengenverhältn isse der Verbindungen (A) und (B) ergeben sich aus den genannten Aufwandmengen für die Einzelstoffe. Von besonderem Interesse ist die Verwendung jeder einzelnen der nachfolgend tabellarisch aufgeführten Kombinationen.
Tabelle 1 The Mengenverhältn isse of the compounds (A) and (B) result from the stated application rates for the individual substances. Of particular interest is the use of each of the combinations listed below in tabular form. Table 1
Nr. Wirkstoff (A) Wirkstoff (B) No. Active substance (A) Active substance (B)
1 A1.1 B1.0 1 A1.1 B1.0
2 A1.1 B1.1 2 A1.1 B1.1
3 A1.1 B1.2 3 A1.1 B1.2
4 A1.1 B1.3 4 A1.1 B1.3
5 A1.1 B1.4 5 A1.1 B1.4
6 A1.1 B1.5 6 A1.1 B1.5
7 A1.1 B1.6 7 A1.1 B1.6
8 A1.1 B1.7 8 A1.1 B1.7
9 A1.1 B1.8 9 A1.1 B1.8
10 A1.1 B1.9 10 A1.1 B1.9
11 A1.1 B1.10 11 A1.1 B1.10
12 A1.1 B1.1112 A1.1 B1.11
13 A1.1 B1.1213 A1.1 B1.12
14 A1.1 B1.1314 A1.1 B1.13
15 A1.1 B1.1415 A1.1 B1.14
16 A1.1 B1.1516 A1.1 B1.15
17 A1.1 B1.1617 A1.1 B1.16
18 A1.1 B1.1718 A1.1 B1.17
19 A1.1 B1.1819 A1.1 B1.18
20 A1.1 B1.1920 A1.1 B1.19
21 A1.1 B1.2021 A1.1 B1.20
22 A1.1 B1.2122 A1.1 B1.21
23 A1.1 B1.2223 A1.1 B1.22
24 A1.1 B1.2324 A1.1 B1.23
25 A1.2 B1.0 25 A1.2 B1.0
26 A1.2 B1.1 26 A1.2 B1.1
27 A1.2 B1.2
Nr. Wirkstoff (A) Wirkstoff (B)27 A1.2 B1.2 No. Active substance (A) Active substance (B)
28 A1.2 B1.3 28 A1.2 B1.3
29 A1.2 B1.4 29 A1.2 B1.4
30 A1.2 B1.5 30 A1.2 B1.5
31 A1.2 B1.6 31 A1.2 B1.6
32 A1.2 B1.7 32 A1.2 B1.7
33 A1.2 B1.8 33 A1.2 B1.8
34 A1.2 B1.9 34 A1.2 B1.9
35 A1.2 B1.10 35 A1.2 B1.10
36 A1.2 B1.1136 A1.2 B1.11
37 A1.2 B1.1237 A1.2 B1.12
38 A1.2 B1.1338 A1.2 B1.13
39 A1.2 B1.1439 A1.2 B1.14
40 A1.2 B1.1540 A1.2 B1.15
41 A1.2 B1.1641 A1.2 B1.16
42 A1.2 B1.1742 A1.2 B1.17
43 A1.2 B1.1843 A1.2 B1.18
44 A1.2 B1.1944 A1.2 B1.19
45 A1.2 B1.2045 A1.2 B1.20
46 A1.2 B1.2146 A1.2 B1.21
47 A1.2 B1.2247 A1.2 B1.22
48 A1.2 B1.2348 A1.2 B1.23
49 A1.3 B1.0 49 A1.3 B1.0
50 A1.3 B1.1 50 A1.3 B1.1
51 A1.3 B1.2 51 A1.3 B1.2
52 A1.3 B1.3 52 A1.3 B1.3
53 A1.3 B1.4 53 A1.3 B1.4
54 A1.3 B1.5 54 A1.3 B1.5
55 A1.3 B1.6 55 A1.3 B1.6
56 A1.3 B1.7
Nr. Wirkstoff (A) Wirkstoff (B) 56 A1.3 B1.7 No. Active substance (A) Active substance (B)
57 A1.3 B1.8 57 A1.3 B1.8
58 A1.3 B1.9 58 A1.3 B1.9
59 A1.3 B1.10 59 A1.3 B1.10
60 A1.3 B1.11 60 A1.3 B1.11
61 A1.3 B1.12 61 A1.3 B1.12
62 A1.3 B1.13 62 A1.3 B1.13
63 A1.3 B1.14 63 A1.3 B1.14
64 A1.3 B1.15 64 A1.3 B1.15
65 A1.3 B1.16 65 A1.3 B1.16
66 A1.3 B1.17 66 A1.3 B1.17
67 A1.3 B1.18 67 A1.3 B1.18
68 A1.3 B1.19 68 A1.3 B1.19
69 A1.3 B1.20 69 A1.3 B1.20
70 A1.3 B1.21 70 A1.3 B1.21
71 A1.3 B1.22 71 A1.3 B1.22
72 A1.3 B1.23 72 A1.3 B1.23
In Einzelfällen kann es sinnvoll sein, eine oder mehrere der Verbindungen (A) mit mehreren Verbindungen (B) zu kombinieren. Weiterhin können die erfindungsgemäßen Kombinationen zusammen mit anderen Wirkstoffen beispielsweise aus der Gruppe der Fungizide, Insektizide und Pflanzenwachstumsregulatoren oder aus der Gruppe der im Pflanzenschutz üblichen Zusatzstoffe und Formulierungshilfsmittel eingesetzt werden. Zusatzstoffe sind beispielsweise Düngemittel, Netzmittel, Öle und Farbstoffe. In individual cases, it may be useful to combine one or more of the compounds (A) with several compounds (B). Furthermore, the combinations according to the invention can be used together with other active ingredients, for example from the group of fungicides, insecticides and plant growth regulators or from the group of customary in plant protection additives and formulation auxiliaries. Additives are, for example, fertilizers, wetting agents, oils and dyes.
Dabei sind auch solche Kombinationen erfindungsgemäß, die noch ein oder mehrere weitere Wirkstoffe anderer Struktur [Wirkstoffe (C)], z.B. Safener, Pflanzenwachstumsregulatoren oder weitere Herbizide, enthalten. Für Kombinationen der letztgenannten Art mit drei oder mehr Wirkstoffen gelten die für erfindungsgemäße
Zweierkombinationen erläuterten bevorzugten Bedingungen in erster Linie ebenfalls, sofern darin die erfindungsgemäßen Zweierkombinationen enthalten sind und bezüglich der betreffenden Zweierkombination. Insofern Getreidekulturen nicht naturgemäß eine Toleranz gegen den Wirkstoff (C) aufweisen, muss eine solche durch Mutationsselektion, Züchtung oder gentechnisch erzeugt werden, um erfindungsgemäße Verwendungen zu ermöglichen bzw. wird die Zugabe von Safenern obligatorisch. In this case, those combinations according to the invention which also contain one or more further active compounds of other structure [active ingredients (C)], for example safeners, plant growth regulators or other herbicides. For combinations of the latter type with three or more active ingredients apply the invention Two combinations explained preferred conditions in the first place also, if it contains the Zweierkombinationen invention and with respect to the respective Zweierkombination. Insofar as cereal crops do not naturally have a tolerance to the active substance (C), such has to be produced by mutation selection, breeding or genetically engineered in order to enable uses according to the invention or the addition of safeners becomes obligatory.
Als Wirkstoff (C) sind z.B. die Safener Benoxacor, Cloquintocet (-mexyl), Cyometrinil, Cyprosulfamide, Dichlormid, Fenchlorazole (-ethyl), Fenclorim, Flurazole, Fluxofenim, Furilazole, Isoxadifen (-ethyl), Mefenpyr (-diethyl), Naphthalic anhydride, Oxabetrinil, "AD-67" oder "MON 4660" (= 3-Dichloracetyl-1-oxa-3-aza-spiro[4,5]decan), "ΤΊ-35" (= 1-Dichloracetyl-azepan),„Dimepiperate" oder "MY-93" (= Piperidin-1-thiocarbonsäure- S-1-methyl-1-phenylethylester), "Daimuron" oder "SK 23" (= 1 -(1 -Methyl-1 -phenylethyl)- 3-p-tolyl-harnstoff) oder "Cumyluron" = "JC-940" (= 3-(2-Chlorphenylmethyl)-1-(1- methyl-1-phenyl-ethyl)harnstoff) oder die folgenden Herbizide bzw. Pflanzenwachstumsregulatoren geeignet: As active ingredient (C) are e.g. the safeners benoxacor, cloquintocet (-mexyl), cyometrinil, cyprosulfamides, dichloromide, fenchlorazoles (-ethyl), fenclorim, flurazoles, fluxofenim, furilazoles, isoxadifen (-ethyl), mefenpyr (-diethyl), naphthalic anhydrides, oxabetrinil, "AD 67 "or" MON 4660 "(= 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane)," ΤΊ-35 "(= 1-dichloroacetyl-azepane)," dimepiperate "or" MY -93 "(= piperidine-1-thiocarboxylic acid S-1-methyl-1-phenylethyl ester)," daimurone "or" SK 23 "(= 1 - (1-methyl-1-phenylethyl) -3-p-tolyl- urea) or "cumyluron" = "JC-940" (= 3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenylethyl) urea) or the following herbicides or plant growth regulators:
Acetochlor, Acibenzolar, Acibenzolar-S-methyl, Acifluorfen, Acifluorfen-sodium, Aclonifen, Alachlor, Allidochlor, Alloxydinn, Alloxydinn-sodiunn, Ametryn, Amicarbazone, Amidochlor, Amidosulfuron, Aminocyclopyrachlor, Aminopyralid, Amitrole, Ammoniumsulfamat, Ancymidol, Anilofos, Asulam, Atrazine, Azafenidin, Azimsulfuron, Aziprotryn, Beflubutamid, Benazolin, Benazolin-ethyl, Bencarbazone, Benfluralin, Benfuresate, Bensulide, Bensulfuron, Bensulfuron-methyl, Bentazone, Benzfendizone, Benzobicyclon, Benzofenap, Benzofluor, Benzoylprop, Bicyclopyrone, Bifenox, Bispyribac, Bispyribac-natrium, Bromacil, Bromobutide, Bromofenoxim, Bromoxynil, Bromuron, Buminafos, Busoxinone, Butachlor, Butafenacil, Butamifos, Butenachlor, Butralin, Butroxydim, Butylate, Cafenstrole, Carbetamide, Carfentrazone, Carfentrazone-ethyl, Chlomethoxyfen, Chloramben, Chlorazifop, Chlorazifop-butyl, Chlorbromuron, Chlorbufam, Chlorfenac, Chlorfenac-natrium, Chlorfenprop, Chlorflurenol, Chlorflurenol-methyl, Chloridazon, Chlorimuron, Chlorimuron-ethyl, Chlormequat-chlorid, Chlornitrofen, Chlorophthalim, Chlorthal-dimethyl, Chlorotoluron,
Chlorsulfuron, Cin idon, Cin idon-ethyl , Cinmethyl in , Cinosulfuron , Clethod im , Clodinafop, Clodinafop-propargyl, Clofencet, Clonnazone, Clonneprop, Cloprop, Clopyralid, Cloransulam, Cloransulam-methyl, Cumyluron, Cyanamide, Cyanazine, Cyclanilide, Cycloate, Cyclosulfamuron, Cycloxydim, Cycluron, Cyhalofop, Cyhalofop- butyl, Cyperquat, Cyprazine, Cyprazole, 2,4-D, 2,4-DB, Dainnuron/Dynnron, Dalapon, Daminozide, Dazonnet, n-Decanol, Desmedipham, Desmetryn, Detosyl-Pyrazolate (DTP), Diallate, Dicamba, Dichlobenil, Dichlorprop, Dichlorprop-P, Diclofop, Diclofop- methyl, Diclofop-P-methyl, Diclosulam , Diethatyl, Diethatyl-ethyl, Difenoxuron, Difenzoquat, Diflufenican, Diflufenzopyr, Diflufenzopyr-natrium, Dimefuron, Dikegulac- sodium, Dimefuron, Dimepiperate, Dimethachlor, Dimethametryn, Dimethenamid, Dimethenamid-P, Dimethipin, Dimetrasulfuron, Dinitramine, Dinoseb, Dinoterb, Diphenamid, Dipropetryn, Diquat, Diquat-dibromide, Dithiopyr, Diuron, DNOC, Eglinazine-ethyl , Endothal , EPTC, Esprocarb, Ethalflu ral in , Ethametsulfuron, Ethametsulfuron-methyl, Ethephon, Ethidimuron, Ethiozin, Ethofumesate, Ethoxyfen, Ethoxyfen-ethyl, Ethoxysulfuron, Etobenzanid, F-5331 , d.h. N-[2-Chlor-4-fluor-5-[4-(3- fluorpropyl)-4,5-dihydro-5-oxo-1 H-tetrazol-1 -yl]-phenyl]-ethansulfonamid, F-7967, d. h. 3-[7-Chlor-5-fluor-2-(trifluormethyl)-1 H-benzimidazol-4-yl]-1 -methyl-6- (trifluormethyl)pyrimidin-2,4(1 H,3H)-dion, Fenoprop, Fenoxaprop, Fenoxaprop-P, Fenoxaprop-ethyl, Fenoxaprop-P-ethyl, Fenoxasulfone, Fentrazamide, Fenuron, Flamprop, Flamprop-M-isopropyl, Flamprop-M-methyl, Flazasulfuron, Florasulam, Fluazifop, Fluazifop-P, Fluazifop-butyl, Fluazifop-P-butyl, Fluazolate, Flucarbazone, Flucarbazone-sodium, Flucetosulfuron, Fluchloralin, Flufenacet (Thiafluamide), Flufenpyr, Flufenpyr-ethyl, Flumetralin, Flumetsulam, Flumiclorac, Flumiclorac-pentyl, Flumioxazin, Flumipropyn, Fluometuron, Fluorodifen, Fluoroglycofen, Fluoroglycofen- ethyl, Flupoxam, Flupropacil, Flupropanate, Flupyrsulfuron, Flupyrsulfuron-methyl- sodium, Flurenol, Flurenol-butyl, Fluridone, Flurochloridone, Fluroxypyr, Fluroxypyr- meptyl , Flurprim idol , Flurtamone, Fluthiacet, Fluth iacet-methyl, Fluthiamide, Fomesafen, Foramsulfuron, Forchlorfenuron, Fosamine, Furyloxyfen, Gibberellinsäure, Glyphosate, Glyphosate-diammonium, Glyphosate-isopropylammonium, Glyphosate- Kalium, H-9201 , d . h . O-(2,4-Dimethyl-6-nitrophenyl)-O-ethyl-isopropylphosphor- amidothioat, Halosafen, Halosulfuron, Halosulfuron-methyl, Haloxyfop, Haloxyfop-P,
Haloxyfop-ethoxyethyl, Haloxyfop-P-ethoxyethyl, Haloxyfop-methyl, Haloxyfop-P- m eth yl , H exaz i n o n e , H W-02, d. h. 1 -(Dimethoxyphosphoryl)-ethyl(2,4- dichlorphenoxy)acetat, Imazamethabenz, Imazamethabenz-nnethyl , Imazamox, Imazannox-annnnoniunn, Imazapic, Imazapyr, Imazapyr-isopropylammonium, Imazaquin, Imazaquin-a nn nnon i u nn , Imazethapyr, Imazethapyr-ammonium, Imazosulfuron, Inabenfide, Indanofan, Indaziflam, Indolessigsäure (IAA), 4-lndol-3-ylbuttersäure (IBA), lodosulfuron, lodosulfuron-methyl-natrium, loxynil, Ipfencarbazone, Isocarbamid, Isopropalin, Isoproturon, Isouron, Isoxaben, Isoxachlortole, Isoxaflutole, Isoxapyhfop, KUH-0 4 3 , d . h . 3-({[5-(Difluormethyl)-1 -methyl-3-(trifluormethyl)-1 H-pyrazol-4- yl]methyl}sulfonyl)-5,5-dinnethyl-4,5-dihydro-1 ,2-oxazol, Karbutilate, Ketospiradox, Lactofen, Lenacil, Linuron, Maleinsäurehydrazid, MCPA, MCPB, MCPB-methyl, -ethyl und -natrium, Mecoprop, Mecoprop-natrium, Mecoprop-butotyl, Mecoprop-P-butotyl, Mecoprop-P-dimethylammonium, Mecoprop-P-2-ethylhexyl, Mecoprop-P-kalium, Mefenacet, Meflu id ide, Mepiquat-chlorid, Mesosulfuron , Mesosulfuron-methyl, Mesosulfuron-methyl-Natrium, Mesotrione, Methabenzthiazuron, Metam, Metamifop, Metamitron, Metazachlor, Metazasulfuron, Methazole, Methiopyrsulfuron, Methiozolin, Methoxyphenone, Methyldym ron , 1 -Methylcyclopropen, Methyl isothiocyanat, Metobenzuron, Metobromuron, Metolachlor, S-Metolachlor, Metosulam, Metoxuron, Metribuzin, Metsulfuron, Metsulfuron-methyl, Molinate, Monalide, Monocarbamide, Monocarbamide-dihydrogensulfat, Monolinuron, Monosulfuron, Monosulfuron-ester, Mon u ron , MT-128, d. h. 6-Chlor-N-[(2E)-3-chlorprop-2-en-1 -yl]-5-methyl-N- phenylpyhdazin-3-am in , MT-5950, d. h. N-[3-Chlor-4-(1 -methylethyl)-phenyl]-2- methylpentanamid, NGGC-01 1 , Naproanilide, Napropamide, Naptalam, NC-310, d.h. 4- (2,4-Dichlorobenzoyl)-1 -methyl-5-benzyloxypyrazole, Nebu ron , N icosulfuron , Nipyraclofen, Nitralin, Nitrofen, Nitrophenolat-nat um (Isomerengemisch), Nitrofluorfen, Nonansäure, Norflurazon, Orbencarb, Orthosulfamuron, Oryzalin, Oxadiargyl, Oxadiazon, Oxasulfuron, Oxaziclomefone, Oxyfluorfen, Paclobutrazol, Paraquat, Paraquat-d ichlorid , Pelargonsäure (Nonansäure), Pend imethal in , Pendral in , Penoxsulam, Pentanochlor, Pentoxazone, Perfluidone, Pethoxamid, Phenisopham, Phenmediphann, Phenmedipham-ethyl, Pidoram, Picolinafen, Pinoxaden, Piperophos, Pirifenop, Pirifenop-butyl, Pretilachlor, Primisulfuron, Primisulfuron-methyl,
Probenazole, Profluazol , Procyazine, Prod iam ine, Prifl ural ine, Profoxyd im , Prohexadione, Prohexadione-calcium, Prohydrojasmone, Prometon, Prometryn, Propachlor, Propanil, Propaquizafop, Propazine, Propham , Propisochlor, Propoxycarbazone, Propoxycarbazone-natrium, Propyrisulfuron, Propyzamide, Prosulfalin, Prosulfocarb, Prosulfuron, Prynachlor, Pyraclonil, Pyraflufen, Pyraflufen- ethyl, Pyrasulfotole, Pyrazolynate (Pyrazolate), Pyrazosulfuron, Pyrazosulfuron-ethyl, Pyrazoxyfen, Pyribambenz, Pyribambenz-isopropyl, Pyribambenz-propyl, Pyribenzoxim, Pyributicarb, Pyridafol , Pyridate, Pyriftal id , Pyriminobac, Pyriminobac-methyl, Pyrimisulfan, Pyrithiobac, Pyrithiobac-nathum, Pyroxasulfone, Pyroxsulam, Quinclorac, Quinmerac, Quinoclamine, Quizalofop, Quizalofop-ethyl, Quizalofop-P, Quizalofop-P- ethyl, Quizalofop-P-tefuryl, Rimsulfuron, Saflufenacil, Secbumeton, Sethoxydim, Siduron , Simazine, Simetryn , SN-106279, d. h. Methyl-(2R)-2-({7-[2-chlor-4- (trifluormethyl)phenoxy]-2-naphthyl}oxy)propanoat, Sulcotrione, Sulfallate (CDEC), Sulfentrazone, Sulfonneturon, Sulfonneturon-nnethyl, Sulfosate (Glyphosate-t mesium), Sulfosulfuron, SYN-523, SYP-249, d . h . 1 -Ethoxy-3-methyl-1 -oxobut-3-en-2-yl-5-[2- chlor-4-(trifluormethyl)phenoxy]-2-nitrobenzoat, SYP-300, d . h . 1 -[7-Fluor-3-oxo-4- (prop-2-in-1 -yl)-3,4-dihydro-2H-1 ,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidin-4,5- dion, Tebutam, Tebuthiuron, Tecnazene, Tefuryltrione, Tembotrione, Tepraloxydim, Terbacil, Terbucarb, Terbuchlor, Terbumeton, Terbuthylazine, Terbutryn, Thenylchlor, Thiafluamide, Thiazafluron, Thiazopyr, Thidiazimin, Thidiazuron, Thiencarbazone, Thiencarbazone-methyl , Th ifensulfuron , Th ifensulfuron-methyl, Thiobencarb, Tiocarbazil, Topramezone, Tralkoxyd im , Trial late, Triasulfuron , Triaziflam , Triazofenamide, Tribenuron, Tribenuron-methyl, Trichloressigsäure (TCA), Triclopyr, Trid iphane, Trietazine, Trifloxysulfuron , Trifloxysulfuron-natrium, Trifluralin, Triflusulfuron, Triflusulfuron-methyl, Trimeturon, Trinexapac, Trinexapac-ethyl, Tritosulfuron, Tsitodef, Uniconazole, Uniconazole-P, Vernolate, ZJ-0862, d. h. 3,4- Dichlor-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}anilin, sowie die folgenden Verbindungen:
Acetochlor, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydine, alloxydine-sodiunn, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminopyralid, amitrole, ammonium sulfamate, ancymidol, anilofos, asulam, Atrazines, Azafenidin, Azimsulfuron, Aziprotryn, Beflubutamide, Benazoline, Benazolin-ethyl, Bencarbazone, Benfluralin, Benfuresate, Bensulide, Bensulfuron, Bensulfuron-methyl, Bentazone, Benzfendizone, Benzobicyclone, Benzofenap, Benzofluor, Benzoylprop, Bicyclopyrone, Bifenox, Bispyribac, Bispyribac sodium, bromacil, bromobutide, bromofenoxime, bromoxynil, bromuron, buminafos, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butraline, butroxydim, butylates, cafenstrols, carbamides, carfentrazone, carfentrazone-ethyl, chlomethoxyfen, chloroambrene, chloroazifop, chloroazifop-butyl, Chlorobromuron, Chlorobufam, Chlorfenac, Chlorfenac Sodium, Chlorfenprop, Chlorflurenol, Chlorflurenol-methyl, Chloridazo n, chlorimuron, chlorimuron-ethyl, chlormequat chloride, chloronitrofen, chlorophthalim, chlorothal-dimethyl, chlorotoluron, Chlorsulfuron, cin idon, cin idon-ethyl, cinmethyl in, cinosulfuron, clethodim, clodinafop, clodinafop-propargyl, clofencet, clonzone, clonneprop, cloprop, clopyralid, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cyclanilide, cycloate, Cyclosulfamuron, Cycloxydim, Cycluron, Cyhalofop, Cyhalofopbutyl, Cyperquat, Cyprazine, Cyprazole, 2,4-D, 2,4-DB, Dainnuron / Dynnron, Dalapon, Daminozide, Dazonnet, n-Decanol, Desmedipham, Desmetryn, Detosyl- Pyrazolates (DTP), dialkyls, dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofopmethyl, diclofop-P-methyl, diclosulam, diethatyl, diethylethyl, difenoxuron, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron , Dikegulac-sodium, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P, dimethipine, dimetrasulfuron, dinitramine, dinoseb, dinoterb, diphenamid, dipropetryn, diquat, diquat-dibromide, dithiopyr, diuron, DNOC, eglinazine-ethyl, endothal , EP TC, esprocarb, ethalfluorin, ethametsulfuron, ethametsulfuron-methyl, ethephon, ethidimuron, ethiozine, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanide, F-5331, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H-tetrazol-1-yl] -phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro 2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1-methyl-6- (trifluoromethyl) pyrimidine-2,4 (1H, 3H) -dione, fenoprop, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl , Fenoxaprop-P-ethyl, Fenoxasulfone, Fentrazamide, Fenuron, Flamprop, Flamprop-M-isopropyl, Flamprop-M-methyl, Flazasulfuron, Florasulam, Fluazifop, Fluazifop-P, Fluazifop-butyl, Fluazifop-P-butyl, Fluazolate, Flucarbazone , Flucarbazone-sodium, Flucetosulfuron, Fluchloralin, Flufenacet (Thiafluamide), Flufenpyr, Flufenpyr-ethyl, Flumetralin, Flumetsulam, Flumiclorac, Flumiclorac-pentyl, Flumioxazin, Flumipropyn, Fluometuron, Fluorodifen, Fluoroglycofen, Fluoroglycofenethyl, Flupoxam, Flupropacil, Flupropanate, Flupyrs ulfuron, flupyrsulfuron-methyl-sodium, flurenol, flurenol-butyl, fluridones, flurochloridones, fluroxypyr, fluroxypyrmeptyl, flurprim idol, flurtamones, fluthiacet, flut iacet-methyl, fluthiamides, fomesafen, foramsulfuron, forchlorfenuron, fosamine, furyloxyfen, gibberellin acid, Glyphosate, glyphosate-diammonium, glyphosate-isopropylammonium, glyphosate-potassium, H-9201, d. H . O- (2,4-dimethyl-6-nitrophenyl) -O-ethyl-isopropylphosphoramidothioate, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, Haloxyfopethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfopmethyl, haloxyfop-P-methyl, H exazoneone, H W-02, ie 1- (dimethoxyphosphoryl) ethyl (2,4-dichlorophenoxy) acetate, imazamethabenz, Imazamethabenz-n-ethyl, imazamox, imazannox-annnunnonium, imazapic, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-a nnnnnnn, imazethapyr, imazethapyr-ammonium, imazosulfuron, inabenfide, indanofan, indaziflam, indoleacetic acid (IAA), 4-indole 3-yl-butyric acid (IBA), iodosulfuron, iodosulfuron-methyl-sodium, loxynil, isoparbazone, isocarbamide, isopropalin, isoproturon, isourone, isoxaben, isoxachlorotole, isoxaflutole, isoxapyhfop, KUH-0 4 3, d. H . 3 - ({[5- (Difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dinethyl-4,5-dihydro-1,2 -oxazole, carbutilates, ketospiradox, lactofen, lenacil, linuron, maleic hydrazide, MCPA, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, mecoprop-butotyl, mecoprop-p-butotyl, mecoprop-P-dimethylammonium , Mecoprop-P-2-ethylhexyl, mecoprop-P-potassium, mefenacet, meflu ide ide, mepiquat chloride, mesosulfuron, mesosulfuron-methyl, mesosulfuron-methyl-sodium, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazasulfuron , Methazole, Methiopyrsulfuron, Methiozolin, Methoxyphenone, Methyldym ron, 1 -Methylcyclopropen, methyl isothiocyanate, Metobenzuron, Metobromuron, Metolachlor, S-Metolachlor, Metosulam, Metoxuron, Metribuzin, Metsulfuron, Metsulfuron-methyl, Molinate, Monalide, Monocarbamide, monocarbamide dihydrogen sulfate , Monolinuron, monosulfuron, monosulfuron ester, monuron, MT-128, ie 6-chloro-N - [(2E) -3-chloroprop-2-en-1 -yl] -5-methyl-N-phenylpyhdazin-3-one in, MT-5950, ie N- [3-chloro-4- (1-methylethyl) -phenyl] -2-methylpentanamide, NGGC-01 1, naproanilide , Napropamide, Naptalam, NC-310, ie 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazoles, Nebu ron, N icosulfuron, Nipyraclofen, Nitralin, Nitrofen, Nitrophenolat-nat um (mixture of isomers), Nitrofluorfen, Nonanoic acid, norflurazon, orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paclobutrazole, paraquat, paraquatide dichloride, pelargonic acid (nonanoic acid), pend imethalin, pendulum in, penoxsulam, pentanochlor, pentoxazone, perfluidone, pethoxamide , Phenisopham, Phenmediphan, Phenmedipham-ethyl, Pidoram, Picolinafen, Pinoxaden, Piperophos, Pirifenop, Pirifenop-butyl, Pretilachlor, Primisulfuron, Primisulfuron-methyl, Sample azoles, profluazole, procyazene, prodamine, prialuric, profoxydim, prohexadione, prohexadione-calcium, prohydrojasmone, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, prophy, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide , Prosulfine, prosulfocarb, prosulfuron, prynachlor, pyraclonil, pyraflufen, pyraflufenethyl, pyrasulfotols, pyrazolynates (pyrazolates), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxime, pyributicarb, pyridafol, pyridates, Pyridinium, Pyriminobac, Pyriminobac-methyl, Pyrimisulfan, Pyrithiobac, Pyrithiobac-nathum, Pyroxasulfone, Pyroxsulam, Quinclorac, Quinmerac, Quinoclamine, Quizalofop, Quizalofop-ethyl, Quizalofop-P, Quizalofop-P-ethyl, Quizalofop-P-tefuryl, Rimsulfuron , Saflufenacil, secbumetone, sethoxydim, siduron, simazine, simetryn, SN-106279, ie, methyl (2R) -2- ({7- [2-chloro-4- (trifluoromethyl) phenoxy] -2-naphth yl} oxy) propanoate, sulcotrione, sulfallates (CDEC), sulfentrazone, sulfonneturon, sulfonneturon-n-methyl, sulfosate (glyphosate-t mesium), sulfosulfuron, SYN-523, SYP-249, d. H . 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300, d. H . 1 - [7-Fluoro-3-oxo-4- (prop-2-yn-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl-2- thioxoimidazolidine-4,5-dione, tebutam, tebuthiuron, tecnazene, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbuchlor, terbumetone, terbuthylazine, terbutryn, thenylchloro, thiafluamides, thiazafluron, thiazopyr, thidiazimine, thidiazuron, thiencarbazone, thiencarbazone-methyl, Thifensulfuron, thifensulfuron-methyl, thiobencarb, tiocarbazil, topramezone, tralkoxydim, triallate, triasulfuron, triaziflam, triazofenamide, tribenuron, tribenuron-methyl, trichloroacetic acid (TCA), triclopyr, tridiphane, trietazine, trifloxysulfuron, trifloxysulfuron sodium, Trifluralin, triflusulfuron, triflusulfuron-methyl, trimeturon, trinexapac, trinexapac-ethyl, tritosulfuron, Tsitodef, Uniconazole, Uniconazole-P, Vernolate, ZJ-0862, ie 3,4-dichloro-N- {2 - [(4,6-) dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:
In einer bevorzugten Ausführungsform enthalten die erfindungsgemäß einsetzbaren Zusannnnensetzungen als Wirkstoff (C) Cloquintocet (-mexyl) (C1 ), Cyprosulfamide (C2), Isoxadifen(-ethyl) (C3) oder Mefenpyr (-diethyl) (C4). In a preferred embodiment, the compositions which can be used according to the invention comprise as active ingredient (C) cloquintocet (-mexyl) (C1), cyprosulfamide (C2), isoxadifen (-ethyl) (C3) or mefenpyr (-diethyl) (C4).
In einer anderen bevorzugten Ausführungsform enthalten die erfindungsgemäß einsetzbaren Zusammensetzungen als Wirkstoff (C) Amidosulfuron (C5), Bentazone (C6), Bromoxynil (C7), Carfentrazone (C8), Carfentrazone-ethyl (C9), Chlorsulfuron (C10), Cinidon-ethyl (C1 1 ), Clodinafop-propargyl (C12), 2,4-D (C13), Dicamba (C14), Diclofop (C15), Diclofop-methyl (C16), Diclofop-P-methyl (C17), Diflufenican (C18), Ethephon (C19), Ethoxysulfuron (C20), Fenoxaprop (C21 ), Fenoxaprop-P (C22), Fenoxaprop-ethyl (C23), Fenoxaprop-P-ethyl (C24), Florasulam (C25), Flucarbazone (C26), Flucarbazone-sodium (C27), Flufenacet (Thiafluamide) (C28), Fluoroglycofen (C29), Fluroxypyr (C30), Fluroxypyr-meptyl (C31 ), Flurtamone (C32), Glyphosate (C33), Glyphosate-isopropylammonium (C34), Glyphosate-diammonium (C35), Glyphosate- Kalium (C36), Imazamox (C37), Imazamox-ammonium (C38), lodosulfuron (C39), lodosulfuron-methyl-natrium (C40), loxynil (C41 ), Isoproturon (C42), MCPA (C43), Mecoprop (C44), Mecoprop-natrium (C45), Mecoprop-butotyl (C46), Mecoprop- P-butotyl (C47), Mecoprop-P-dimethylammonium (C48), Mecoprop-P-2-ethylhexyl (C49), Mecoprop-P-kalium (C50), Mesosulfuron (C51 ), Mesosulfuron-methyl-Natrium (C52), Metribuzin (C53), Metsulfuron (C54), Metsulfuron-methyl (C55), Pendimethalin (C56 ), Penoxsu la m (C57), P i noxad en (C58) , Propoxyca rbazone (C59) , Propoxycarbazone-natrium (C60), Pyrasulfutole (C61 ), Pyroxsulam (C62), Saflufenacil
(C63), Sulfosulfuron (C64), Thiencarbazone (C65), Thiencarbazone-methyl (C66), Thifensulfuron (C67), Thifensulfuron-methyl (C68), Tralkoxydim (C69), Triasulfuron (C70), Tribenuron (C71 ), Tribenuron-methyl (C72) oder Tritosulfuron (C73). In einer besonders bevorzugten Ausführungsform enthalten die erfindungsgemäß einsetzbaren Zusammensetzungen als Wirkstoff (C) Amidosulfuron (C5), Bromoxynil (C7), Diclofop (C15), Diflufenican (C18), Fenoxaprop (C21 ), Fenoxaprop-P (C22), Fenoxaprop-ethyl (C23), Fenoxaprop-P-ethyl (C24), Flufenacet (Thiafluamide) (C28), Flurtamone (C32), lodosulfuron-methyl-natrium (C40), loxynil (C41 ), Isoproturon (C42), Mesosulfuron (C51 ), Mesosulfuron-methyl (C52), Propoxycarbazone (C59), Propoxycarbazone-natrium (C60), Pyrasulfutole (C61 ) oder Thiencarbazone (C65). In another preferred embodiment, the compositions which can be used according to the invention contain as active ingredient (C) amidosulfuron (C5), bentazones (C6), bromoxynil (C7), carfentrazone (C8), carfentrazone-ethyl (C9), chlorosulfuron (C10), cinidon-ethyl (C1 1), clodinafop-propargyl (C12), 2,4-D (C13), dicamba (C14), diclofop (C15), diclofop-methyl (C16), diclofop-P-methyl (C17), diflufenican (C18 Ethephon (C19), ethoxysulfuron (C20), fenoxaprop (C21), fenoxaprop-P (C22), fenoxaprop-ethyl (C23), fenoxaprop-P-ethyl (C24), florasulam (C25), flucarbazone (C26), Flucarbazone-sodium (C27), flufenacet (thiafluamide) (C28), fluoroglycofen (C29), fluroxypyr (C30), fluroxypyr-meptyl (C31), flurtamone (C32), glyphosate (C33), glyphosate-isopropylammonium (C34), glyphosate -diammonium (C35), glyphosate potassium (C36), imazamox (C37), imazamoxammonium (C38), iodosulfuron (C39), iodosulfuron-methyl-sodium (C40), loxynil (C41), isoproturon (C42), MCPA (C43), mecoprop (C44), mecoprop-natr ium (C45), mecopropbutotyl (C46), mecoprop-p-butotyl (C47), mecoprop-P-dimethylammonium (C48), mecoprop-P-2-ethylhexyl (C49), mecoprop-P-potassium (C50), Mesosulfuron (C51), mesosulfuron-methyl-sodium (C52), metribuzin (C53), metsulfuron (C54), metsulfuron-methyl (C55), pendimethalin (C56), Penoxsu la m (C57), phenoxadene (C58) , Propoxycarbazone (C59), Propoxycarbazone Sodium (C60), Pyrasulfutole (C61), Pyroxsulam (C62), Saflufenacil (C63), sulfosulfuron (C64), thiencarbazone (C65), thiencarbazone-methyl (C66), thifensulfuron (C67), thifensulfuron-methyl (C68), tralkoxydim (C69), triasulfuron (C70), tribenuron (C71), tribenuron methyl (C72) or tritosulfuron (C73). In a particularly preferred embodiment, the compositions which can be used according to the invention contain as active ingredient (C) amidosulfuron (C5), bromoxynil (C7), diclofop (C15), diflufenican (C18), fenoxaprop (C21), fenoxaprop-P (C22), fenoxaprop-ethyl (C23), fenoxaprop-P-ethyl (C24), flufenacet (thiafluamide) (C28), flurtamone (C32), iodosulfuron-methyl-sodium (C40), loxynil (C41), isoproturon (C42), mesosulfuron (C51), Mesosulfuron-methyl (C52), propoxycarbazone (C59), propoxycarbazone-sodium (C60), pyrasulfutole (C61) or thiencarbazone (C65).
Erfindungsgemäß in hervorzuhebender Weise geeignet sind damit jeweils für sichauch die nachfolgend tabellarisch aufgeführten Dreierkombinationen von Wirkstoffen:
According to the invention, the triple combinations of active substances listed below in tabular form are thus suitable in each case for themselves.
Tabelle 2 WirkWirkWirkstoff (A) stoff (B) stoff (C)Table 2 ActiveCompact Active Ingredient (A) Substance (B) Substance (C)
WirkWirkWirkA1.1 B1.0 (C60) stoff (A) stoff (B) stoff (C) A1.1 B1.0 (C61)WirkWirkWirkA1.1 B1.0 (C60) Substance (A) Substance (B) Substance (C) A1.1 B1.0 (C61)
A1.1 B1.0 (C1) A1.1 B1.0 (C62)A1.1 B1.0 (C1) A1.1 B1.0 (C62)
A1.1 B1.0 (C2) A1.1 B1.0 (C65)A1.1 B1.0 (C2) A1.1 B1.0 (C65)
A1.1 B1.0 (C3) A1.1 B1.0 (C66)A1.1 B1.0 (C3) A1.1 B1.0 (C66)
A1.1 B1.0 (C4) A1.1 B1.0 (C71)A1.1 B1.0 (C4) A1.1 B1.0 (C71)
A1.1 B1.0 (C5) A1.1 B1.0 (C74)A1.1 B1.0 (C5) A1.1 B1.0 (C74)
A1.1 B1.0 (C7) A1.1 B1.1 (C1)A1.1 B1.0 (C7) A1.1 B1.1 (C1)
A1.1 B1.0 (C9) A1.1 B1.1 (C2)A1.1 B1.0 (C9) A1.1 B1.1 (C2)
A1.1 B1.0 (C15) A1.1 B1.1 (C3)A1.1 B1.0 (C15) A1.1 B1.1 (C3)
A1.1 B1.0 (C18) A1.1 B1.1 (C4)A1.1 B1.0 (C18) A1.1 B1.1 (C4)
A1.1 B1.0 (C21) A1.1 B1.1 (C5)A1.1 B1.0 (C21) A1.1 B1.1 (C5)
A1.1 B1.0 (C22) A1.1 B1.1 (C7)A1.1 B1.0 (C22) A1.1 B1.1 (C7)
A1.1 B1.0 (C23) A1.1 B1.1 (C9)A1.1 B1.0 (C23) A1.1 B1.1 (C9)
A1.1 B1.0 (C24) A1.1 B1.1 (C15)A1.1 B1.0 (C24) A1.1 B1.1 (C15)
A1.1 B1.0 (C25) A1.1 B1.1 (C18)A1.1 B1.0 (C25) A1.1 B1.1 (C18)
A1.1 B1.0 (C28) A1.1 B1.1 (C21)A1.1 B1.0 (C28) A1.1 B1.1 (C21)
A1.1 B1.0 (C32) A1.1 B1.1 (C22)A1.1 B1.0 (C32) A1.1 B1.1 (C22)
A1.1 B1.0 (C37) A1.1 B1.1 (C23)A1.1 B1.0 (C37) A1.1 B1.1 (C23)
A1.1 B1.0 (C40) A1.1 B1.1 (C25)A1.1 B1.0 (C40) A1.1 B1.1 (C25)
A1.1 B1.0 (C41) A1.1 B1.1 (C24)A1.1 B1.0 (C41) A1.1 B1.1 (C24)
A1.1 B1.0 (C42) A1.1 B1.1 (C28)A1.1 B1.0 (C42) A1.1 B1.1 (C28)
A1.1 B1.0 (C43) A1.1 B1.1 (C32)A1.1 B1.0 (C43) A1.1 B1.1 (C32)
A1.1 B1.0 (C51) A1.1 B1.1 (C37)A1.1 B1.0 (C51) A1.1 B1.1 (C37)
A1.1 B1.0 (C52) A1.1 B1.1 (C40)A1.1 B1.0 (C52) A1.1 B1.1 (C40)
A1.1 B1.0 (C57) A1.1 B1.1 (C41)A1.1 B1.0 (C57) A1.1 B1.1 (C41)
A1.1 B1.0 (C58) A1.1 B1.1 (C42)A1.1 B1.0 (C58) A1.1 B1.1 (C42)
A1.1 B1.0 (C59) A1.1 B1.1 (C43)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.0 (C59) A1.1 B1.1 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.1 (C51) A1.1 B1.2 (C28)A1.1 B1.1 (C51) A1.1 B1.2 (C28)
A1.1 B1.1 (C52) A1.1 B1.2 (C32)A1.1 B1.1 (C52) A1.1 B1.2 (C32)
A1.1 B1.1 (C57) A1.1 B1.2 (C37)A1.1 B1.1 (C57) A1.1 B1.2 (C37)
A1.1 B1.1 (C58) A1.1 B1.2 (C40)A1.1 B1.1 (C58) A1.1 B1.2 (C40)
A1.1 B1.1 (C59) A1.1 B1.2 (C41)A1.1 B1.1 (C59) A1.1 B1.2 (C41)
A1.1 B1.1 (C60) A1.1 B1.2 (C42)A1.1 B1.1 (C60) A1.1 B1.2 (C42)
A1.1 B1.1 (C61) A1.1 B1.2 (C43)A1.1 B1.1 (C61) A1.1 B1.2 (C43)
A1.1 B1.1 (C62) A1.1 B1.2 (C51)A1.1 B1.1 (C62) A1.1 B1.2 (C51)
A1.1 B1.1 (C65) A1.1 B1.2 (C52)A1.1 B1.1 (C65) A1.1 B1.2 (C52)
A1.1 B1.1 (C66) A1.1 B1.2 (C57)A1.1 B1.1 (C66) A1.1 B1.2 (C57)
A1.1 B1.1 (C71) A1.1 B1.2 (C58)A1.1 B1.1 (C71) A1.1 B1.2 (C58)
A1.1 B1.1 (C74) A1.1 B1.2 (C59)A1.1 B1.1 (C74) A1.1 B1.2 (C59)
A1.1 B1.2 (C1) A1.1 B1.2 (C60)A1.1 B1.2 (C1) A1.1 B1.2 (C60)
A1.1 B1.2 (C2) A1.1 B1.2 (C61)A1.1 B1.2 (C2) A1.1 B1.2 (C61)
A1.1 B1.2 (C3) A1.1 B1.2 (C62)A1.1 B1.2 (C3) A1.1 B1.2 (C62)
A1.1 B1.2 (C4) A1.1 B1.2 (C65)A1.1 B1.2 (C4) A1.1 B1.2 (C65)
A1.1 B1.2 (C5) A1.1 B1.2 (C66)A1.1 B1.2 (C5) A1.1 B1.2 (C66)
A1.1 B1.2 (C7) A1.1 B1.2 (C71)A1.1 B1.2 (C7) A1.1 B1.2 (C71)
A1.1 B1.2 (C9) A1.1 B1.2 (C74)A1.1 B1.2 (C9) A1.1 B1.2 (C74)
A1.1 B1.2 (C12) A1.1 B1.3 (C1)A1.1 B1.2 (C12) A1.1 B1.3 (C1)
A1.1 B1.2 (C13) A1.1 B1.3 (C2)A1.1 B1.2 (C13) A1.1 B1.3 (C2)
A1.1 B1.2 (C15) A1.1 B1.3 (C3)A1.1 B1.2 (C15) A1.1 B1.3 (C3)
A1.1 B1.2 (C18) A1.1 B1.3 (C4)A1.1 B1.2 (C18) A1.1 B1.3 (C4)
A1.1 B1.2 (C21) A1.1 B1.3 (C5)A1.1 B1.2 (C21) A1.1 B1.3 (C5)
A1.1 B1.2 (C22) A1.1 B1.3 (C7)A1.1 B1.2 (C22) A1.1 B1.3 (C7)
A1.1 B1.2 (C23) A1.1 B1.3 (C9)A1.1 B1.2 (C23) A1.1 B1.3 (C9)
A1.1 B1.2 (C24) A1.1 B1.3 (C12)A1.1 B1.2 (C24) A1.1 B1.3 (C12)
A1.1 B1.2 (C25) A1.1 B1.3 (C13)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.2 (C25) A1.1 B1.3 (C13) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.3 (C15) A1.1 B1.4 (C3)A1.1 B1.3 (C15) A1.1 B1.4 (C3)
A1.1 B1.3 (C18) A1.1 B1.4 (C4)A1.1 B1.3 (C18) A1.1 B1.4 (C4)
A1.1 B1.3 (C21) A1.1 B1.4 (C5)A1.1 B1.3 (C21) A1.1 B1.4 (C5)
A1.1 B1.3 (C22) A1.1 B1.4 (C7)A1.1 B1.3 (C22) A1.1 B1.4 (C7)
A1.1 B1.3 (C23) A1.1 B1.4 (C9)A1.1 B1.3 (C23) A1.1 B1.4 (C9)
A1.1 B1.3 (C24) A1.1 B1.4 (C12)A1.1 B1.3 (C24) A1.1 B1.4 (C12)
A1.1 B1.3 (C25) A1.1 B1.4 (C13)A1.1 B1.3 (C25) A1.1 B1.4 (C13)
A1.1 B1.3 (C28) A1.1 B1.4 (C15)A1.1 B1.3 (C28) A1.1 B1.4 (C15)
A1.1 B1.3 (C32) A1.1 B1.4 (C18)A1.1 B1.3 (C32) A1.1 B1.4 (C18)
A1.1 B1.3 (C37) A1.1 B1.4 (C21)A1.1 B1.3 (C37) A1.1 B1.4 (C21)
A1.1 B1.3 (C40) A1.1 B1.4 (C22)A1.1 B1.3 (C40) A1.1 B1.4 (C22)
A1.1 B1.3 (C41) A1.1 B1.4 (C23)A1.1 B1.3 (C41) A1.1 B1.4 (C23)
A1.1 B1.3 (C42) A1.1 B1.4 (C24)A1.1 B1.3 (C42) A1.1 B1.4 (C24)
A1.1 B1.3 (C43) A1.1 B1.4 (C25)A1.1 B1.3 (C43) A1.1 B1.4 (C25)
A1.1 B1.3 (C51) A1.1 B1.4 (C28)A1.1 B1.3 (C51) A1.1 B1.4 (C28)
A1.1 B1.3 (C52) A1.1 B1.4 (C32)A1.1 B1.3 (C52) A1.1 B1.4 (C32)
A1.1 B1.3 (C57) A1.1 B1.4 (C37)A1.1 B1.3 (C57) A1.1 B1.4 (C37)
A1.1 B1.3 (C58) A1.1 B1.4 (C40)A1.1 B1.3 (C58) A1.1 B1.4 (C40)
A1.1 B1.3 (C59) A1.1 B1.4 (C41)A1.1 B1.3 (C59) A1.1 B1.4 (C41)
A1.1 B1.3 (C60) A1.1 B1.4 (C42)A1.1 B1.3 (C60) A1.1 B1.4 (C42)
A1.1 B1.3 (C61) A1.1 B1.4 (C43)A1.1 B1.3 (C61) A1.1 B1.4 (C43)
A1.1 B1.3 (C62) A1.1 B1.4 (C51)A1.1 B1.3 (C62) A1.1 B1.4 (C51)
A1.1 B1.3 (C65) A1.1 B1.4 (C52)A1.1 B1.3 (C65) A1.1 B1.4 (C52)
A1.1 B1.3 (C66) A1.1 B1.4 (C57)A1.1 B1.3 (C66) A1.1 B1.4 (C57)
A1.1 B1.3 (C71) A1.1 B1.4 (C58)A1.1 B1.3 (C71) A1.1 B1.4 (C58)
A1.1 B1.3 (C74) A1.1 B1.4 (C59)A1.1 B1.3 (C74) A1.1 B1.4 (C59)
A1.1 B1.4 (C1) A1.1 B1.4 (C60)A1.1 B1.4 (C1) A1.1 B1.4 (C60)
A1.1 B1.4 (C2) A1.1 B1.4 (C61)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.4 (C2) A1.1 B1.4 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.4 (C62) A1.1 B1.5 (C51)A1.1 B1.4 (C62) A1.1 B1.5 (C51)
A1.1 B1.4 (C65) A1.1 B1.5 (C52)A1.1 B1.4 (C65) A1.1 B1.5 (C52)
A1.1 B1.4 (C66) A1.1 B1.5 (C57)A1.1 B1.4 (C66) A1.1 B1.5 (C57)
A1.1 B1.4 (C71) A1.1 B1.5 (C58)A1.1 B1.4 (C71) A1.1 B1.5 (C58)
A1.1 B1.4 (C74) A1.1 B1.5 (C59)A1.1 B1.4 (C74) A1.1 B1.5 (C59)
A1.1 B1.5 (C1) A1.1 B1.5 (C60)A1.1 B1.5 (C1) A1.1 B1.5 (C60)
A1.1 B1.5 (C2) A1.1 B1.5 (C61)A1.1 B1.5 (C2) A1.1 B1.5 (C61)
A1.1 B1.5 (C3) A1.1 B1.5 (C62)A1.1 B1.5 (C3) A1.1 B1.5 (C62)
A1.1 B1.5 (C4) A1.1 B1.5 (C65)A1.1 B1.5 (C4) A1.1 B1.5 (C65)
A1.1 B1.5 (C5) A1.1 B1.5 (C66)A1.1 B1.5 (C5) A1.1 B1.5 (C66)
A1.1 B1.5 (C7) A1.1 B1.5 (C71)A1.1 B1.5 (C7) A1.1 B1.5 (C71)
A1.1 B1.5 (C9) A1.1 B1.5 (C74)A1.1 B1.5 (C9) A1.1 B1.5 (C74)
A1.1 B1.5 (C12) A1.1 B1.6 (C1)A1.1 B1.5 (C12) A1.1 B1.6 (C1)
A1.1 B1.5 (C13) A1.1 B1.6 (C2)A1.1 B1.5 (C13) A1.1 B1.6 (C2)
A1.1 B1.5 (C15) A1.1 B1.6 (C3)A1.1 B1.5 (C15) A1.1 B1.6 (C3)
A1.1 B1.5 (C18) A1.1 B1.6 (C4)A1.1 B1.5 (C18) A1.1 B1.6 (C4)
A1.1 B1.5 (C21) A1.1 B1.6 (C5)A1.1 B1.5 (C21) A1.1 B1.6 (C5)
A1.1 B1.5 (C22) A1.1 B1.6 (C7)A1.1 B1.5 (C22) A1.1 B1.6 (C7)
A1.1 B1.5 (C23) A1.1 B1.6 (C9)A1.1 B1.5 (C23) A1.1 B1.6 (C9)
A1.1 B1.5 (C24) A1.1 B1.6 (C12)A1.1 B1.5 (C24) A1.1 B1.6 (C12)
A1.1 B1.5 (C25) A1.1 B1.6 (C13)A1.1 B1.5 (C25) A1.1 B1.6 (C13)
A1.1 B1.5 (C28) A1.1 B1.6 (C15)A1.1 B1.5 (C28) A1.1 B1.6 (C15)
A1.1 B1.5 (C32) A1.1 B1.6 (C18)A1.1 B1.5 (C32) A1.1 B1.6 (C18)
A1.1 B1.5 (C37) A1.1 B1.6 (C21)A1.1 B1.5 (C37) A1.1 B1.6 (C21)
A1.1 B1.5 (C40) A1.1 B1.6 (C22)A1.1 B1.5 (C40) A1.1 B1.6 (C22)
A1.1 B1.5 (C41) A1.1 B1.6 (C23)A1.1 B1.5 (C41) A1.1 B1.6 (C23)
A1.1 B1.5 (C42) A1.1 B1.6 (C24)A1.1 B1.5 (C42) A1.1 B1.6 (C24)
A1.1 B1.5 (C43) A1.1 B1.6 (C25)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.5 (C43) A1.1 B1.6 (C25) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.6 (C28) A1.1 B1.7 (C15)A1.1 B1.6 (C28) A1.1 B1.7 (C15)
A1.1 B1.6 (C32) A1.1 B1.7 (C18)A1.1 B1.6 (C32) A1.1 B1.7 (C18)
A1.1 B1.6 (C37) A1.1 B1.7 (C21)A1.1 B1.6 (C37) A1.1 B1.7 (C21)
A1.1 B1.6 (C40) A1.1 B1.7 (C22)A1.1 B1.6 (C40) A1.1 B1.7 (C22)
A1.1 B1.6 (C41) A1.1 B1.7 (C23)A1.1 B1.6 (C41) A1.1 B1.7 (C23)
A1.1 B1.6 (C42) A1.1 B1.7 (C24)A1.1 B1.6 (C42) A1.1 B1.7 (C24)
A1.1 B1.6 (C43) A1.1 B1.7 (C25)A1.1 B1.6 (C43) A1.1 B1.7 (C25)
A1.1 B1.6 (C51) A1.1 B1.7 (C28)A1.1 B1.6 (C51) A1.1 B1.7 (C28)
A1.1 B1.6 (C52) A1.1 B1.7 (C32)A1.1 B1.6 (C52) A1.1 B1.7 (C32)
A1.1 B1.6 (C57) A1.1 B1.7 (C37)A1.1 B1.6 (C57) A1.1 B1.7 (C37)
A1.1 B1.6 (C58) A1.1 B1.7 (C40)A1.1 B1.6 (C58) A1.1 B1.7 (C40)
A1.1 B1.6 (C59) A1.1 B1.7 (C41)A1.1 B1.6 (C59) A1.1 B1.7 (C41)
A1.1 B1.6 (C60) A1.1 B1.7 (C42)A1.1 B1.6 (C60) A1.1 B1.7 (C42)
A1.1 B1.6 (C61) A1.1 B1.7 (C43)A1.1 B1.6 (C61) A1.1 B1.7 (C43)
A1.1 B1.6 (C62) A1.1 B1.7 (C51)A1.1 B1.6 (C62) A1.1 B1.7 (C51)
A1.1 B1.6 (C65) A1.1 B1.7 (C52)A1.1 B1.6 (C65) A1.1 B1.7 (C52)
A1.1 B1.6 (C66) A1.1 B1.7 (C57)A1.1 B1.6 (C66) A1.1 B1.7 (C57)
A1.1 B1.6 (C71) A1.1 B1.7 (C58)A1.1 B1.6 (C71) A1.1 B1.7 (C58)
A1.1 B1.6 (C74) A1.1 B1.7 (C59)A1.1 B1.6 (C74) A1.1 B1.7 (C59)
A1.1 B1.7 (C1) A1.1 B1.7 (C60)A1.1 B1.7 (C1) A1.1 B1.7 (C60)
A1.1 B1.7 (C2) A1.1 B1.7 (C61)A1.1 B1.7 (C2) A1.1 B1.7 (C61)
A1.1 B1.7 (C3) A1.1 B1.7 (C62)A1.1 B1.7 (C3) A1.1 B1.7 (C62)
A1.1 B1.7 (C4) A1.1 B1.7 (C65)A1.1 B1.7 (C4) A1.1 B1.7 (C65)
A1.1 B1.7 (C5) A1.1 B1.7 (C66)A1.1 B1.7 (C5) A1.1 B1.7 (C66)
A1.1 B1.7 (C7) A1.1 B1.7 (C71)A1.1 B1.7 (C7) A1.1 B1.7 (C71)
A1.1 B1.7 (C9) A1.1 B1.7 (C74)A1.1 B1.7 (C9) A1.1 B1.7 (C74)
A1.1 B1.7 (C12) A1.1 B1.8 (C1)A1.1 B1.7 (C12) A1.1 B1.8 (C1)
A1.1 B1.7 (C13) A1.1 B1.8 (C2)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.7 (C13) A1.1 B1.8 (C2) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.8 (C3) A1.1 B1.8 (C62)A1.1 B1.8 (C3) A1.1 B1.8 (C62)
A1.1 B1.8 (C4) A1.1 B1.8 (C65)A1.1 B1.8 (C4) A1.1 B1.8 (C65)
A1.1 B1.8 (C5) A1.1 B1.8 (C66)A1.1 B1.8 (C5) A1.1 B1.8 (C66)
A1.1 B1.8 (C7) A1.1 B1.8 (C71)A1.1 B1.8 (C7) A1.1 B1.8 (C71)
A1.1 B1.8 (C9) A1.1 B1.8 (C74)A1.1 B1.8 (C9) A1.1 B1.8 (C74)
A1.1 B1.8 (C12) A1.1 B1.9 (C1)A1.1 B1.8 (C12) A1.1 B1.9 (C1)
A1.1 B1.8 (C13) A1.1 B1.9 (C2)A1.1 B1.8 (C13) A1.1 B1.9 (C2)
A1.1 B1.8 (C15) A1.1 B1.9 (C3)A1.1 B1.8 (C15) A1.1 B1.9 (C3)
A1.1 B1.8 (C18) A1.1 B1.9 (C4)A1.1 B1.8 (C18) A1.1 B1.9 (C4)
A1.1 B1.8 (C21) A1.1 B1.9 (C5)A1.1 B1.8 (C21) A1.1 B1.9 (C5)
A1.1 B1.8 (C22) A1.1 B1.9 (C7)A1.1 B1.8 (C22) A1.1 B1.9 (C7)
A1.1 B1.8 (C23) A1.1 B1.9 (C9)A1.1 B1.8 (C23) A1.1 B1.9 (C9)
A1.1 B1.8 (C24) A1.1 B1.9 (C12)A1.1 B1.8 (C24) A1.1 B1.9 (C12)
A1.1 B1.8 (C25) A1.1 B1.9 (C13)A1.1 B1.8 (C25) A1.1 B1.9 (C13)
A1.1 B1.8 (C28) A1.1 B1.9 (C15)A1.1 B1.8 (C28) A1.1 B1.9 (C15)
A1.1 B1.8 (C32) A1.1 B1.9 (C18)A1.1 B1.8 (C32) A1.1 B1.9 (C18)
A1.1 B1.8 (C37) A1.1 B1.9 (C21)A1.1 B1.8 (C37) A1.1 B1.9 (C21)
A1.1 B1.8 (C40) A1.1 B1.9 (C22)A1.1 B1.8 (C40) A1.1 B1.9 (C22)
A1.1 B1.8 (C41) A1.1 B1.9 (C23)A1.1 B1.8 (C41) A1.1 B1.9 (C23)
A1.1 B1.8 (C42) A1.1 B1.9 (C24)A1.1 B1.8 (C42) A1.1 B1.9 (C24)
A1.1 B1.8 (C43) A1.1 B1.9 (C25)A1.1 B1.8 (C43) A1.1 B1.9 (C25)
A1.1 B1.8 (C51) A1.1 B1.9 (C28)A1.1 B1.8 (C51) A1.1 B1.9 (C28)
A1.1 B1.8 (C52) A1.1 B1.9 (C32)A1.1 B1.8 (C52) A1.1 B1.9 (C32)
A1.1 B1.8 (C57) A1.1 B1.9 (C37)A1.1 B1.8 (C57) A1.1 B1.9 (C37)
A1.1 B1.8 (C58) A1.1 B1.9 (C40)A1.1 B1.8 (C58) A1.1 B1.9 (C40)
A1.1 B1.8 (C59) A1.1 B1.9 (C41)A1.1 B1.8 (C59) A1.1 B1.9 (C41)
A1.1 B1.8 (C60) A1.1 B1.9 (C42)A1.1 B1.8 (C60) A1.1 B1.9 (C42)
A1.1 B1.8 (C61) A1.1 B1.9 (C43)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.8 (C61) A1.1 B1.9 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.9 (C51) A1.1 B1.10 (C28)A1.1 B1.9 (C51) A1.1 B1.10 (C28)
A1.1 B1.9 (C52) A1.1 B1.10 (C32)A1.1 B1.9 (C52) A1.1 B1.10 (C32)
A1.1 B1.9 (C57) A1.1 B1.10 (C37)A1.1 B1.9 (C57) A1.1 B1.10 (C37)
A1.1 B1.9 (C58) A1.1 B1.10 (C40)A1.1 B1.9 (C58) A1.1 B1.10 (C40)
A1.1 B1.9 (C59) A1.1 B1.10 (C41)A1.1 B1.9 (C59) A1.1 B1.10 (C41)
A1.1 B1.9 (C60) A1.1 B1.10 (C42)A1.1 B1.9 (C60) A1.1 B1.10 (C42)
A1.1 B1.9 (C61) A1.1 B1.10 (C43)A1.1 B1.9 (C61) A1.1 B1.10 (C43)
A1.1 B1.9 (C62) A1.1 B1.10 (C51)A1.1 B1.9 (C62) A1.1 B1.10 (C51)
A1.1 B1.9 (C65) A1.1 B1.10 (C52)A1.1 B1.9 (C65) A1.1 B1.10 (C52)
A1.1 B1.9 (C66) A1.1 B1.10 (C57)A1.1 B1.9 (C66) A1.1 B1.10 (C57)
A1.1 B1.9 (C71) A1.1 B1.10 (C58)A1.1 B1.9 (C71) A1.1 B1.10 (C58)
A1.1 B1.9 (C74) A1.1 B1.10 (C59)A1.1 B1.9 (C74) A1.1 B1.10 (C59)
A1.1 B1.10 (C1) A1.1 B1.10 (C60)A1.1 B1.10 (C1) A1.1 B1.10 (C60)
A1.1 B1.10 (C2) A1.1 B1.10 (C61)A1.1 B1.10 (C2) A1.1 B1.10 (C61)
A1.1 B1.10 (C3) A1.1 B1.10 (C62)A1.1 B1.10 (C3) A1.1 B1.10 (C62)
A1.1 B1.10 (C4) A1.1 B1.10 (C65)A1.1 B1.10 (C4) A1.1 B1.10 (C65)
A1.1 B1.10 (C5) A1.1 B1.10 (C66)A1.1 B1.10 (C5) A1.1 B1.10 (C66)
A1.1 B1.10 (C7) A1.1 B1.10 (C71)A1.1 B1.10 (C7) A1.1 B1.10 (C71)
A1.1 B1.10 (C9) A1.1 B1.10 (C74)A1.1 B1.10 (C9) A1.1 B1.10 (C74)
A1.1 B1.10 (C12) A1.1 B1.11 (C1)A1.1 B1.10 (C12) A1.1 B1.11 (C1)
A1.1 B1.10 (C13) A1.1 B1.11 (C2)A1.1 B1.10 (C13) A1.1 B1.11 (C2)
A1.1 B1.10 (C15) A1.1 B1.11 (C3)A1.1 B1.10 (C15) A1.1 B1.11 (C3)
A1.1 B1.10 (C18) A1.1 B1.11 (C4)A1.1 B1.10 (C18) A1.1 B1.11 (C4)
A1.1 B1.10 (C21) A1.1 B1.11 (C5)A1.1 B1.10 (C21) A1.1 B1.11 (C5)
A1.1 B1.10 (C22) A1.1 B1.11 (C7)A1.1 B1.10 (C22) A1.1 B1.11 (C7)
A1.1 B1.10 (C23) A1.1 B1.11 (C9)A1.1 B1.10 (C23) A1.1 B1.11 (C9)
A1.1 B1.10 (C24) A1.1 B1.11 (C12)A1.1 B1.10 (C24) A1.1 B1.11 (C12)
A1.1 B1.10 (C25) A1.1 B1.11 (C13)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.10 (C25) A1.1 B1.11 (C13) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.11 (C15) A1.1 B1.12 (C3)A1.1 B1.11 (C15) A1.1 B1.12 (C3)
A1.1 B1.11 (C18) A1.1 B1.12 (C4)A1.1 B1.11 (C18) A1.1 B1.12 (C4)
A1.1 B1.11 (C21) A1.1 B1.12 (C5)A1.1 B1.11 (C21) A1.1 B1.12 (C5)
A1.1 B1.11 (C22) A1.1 B1.12 (C7)A1.1 B1.11 (C22) A1.1 B1.12 (C7)
A1.1 B1.11 (C23) A1.1 B1.12 (C9)A1.1 B1.11 (C23) A1.1 B1.12 (C9)
A1.1 B1.11 (C24) A1.1 B1.12 (C12)A1.1 B1.11 (C24) A1.1 B1.12 (C12)
A1.1 B1.11 (C25) A1.1 B1.12 (C13)A1.1 B1.11 (C25) A1.1 B1.12 (C13)
A1.1 B1.11 (C28) A1.1 B1.12 (C15)A1.1 B1.11 (C28) A1.1 B1.12 (C15)
A1.1 B1.11 (C32) A1.1 B1.12 (C18)A1.1 B1.11 (C32) A1.1 B1.12 (C18)
A1.1 B1.11 (C37) A1.1 B1.12 (C21)A1.1 B1.11 (C37) A1.1 B1.12 (C21)
A1.1 B1.11 (C40) A1.1 B1.12 (C22)A1.1 B1.11 (C40) A1.1 B1.12 (C22)
A1.1 B1.11 (C41) A1.1 B1.12 (C23)A1.1 B1.11 (C41) A1.1 B1.12 (C23)
A1.1 B1.11 (C42) A1.1 B1.12 (C24)A1.1 B1.11 (C42) A1.1 B1.12 (C24)
A1.1 B1.11 (C43) A1.1 B1.12 (C25)A1.1 B1.11 (C43) A1.1 B1.12 (C25)
A1.1 B1.11 (C51) A1.1 B1.12 (C28)A1.1 B1.11 (C51) A1.1 B1.12 (C28)
A1.1 B1.11 (C52) A1.1 B1.12 (C32)A1.1 B1.11 (C52) A1.1 B1.12 (C32)
A1.1 B1.11 (C57) A1.1 B1.12 (C37)A1.1 B1.11 (C57) A1.1 B1.12 (C37)
A1.1 B1.11 (C58) A1.1 B1.12 (C40)A1.1 B1.11 (C58) A1.1 B1.12 (C40)
A1.1 B1.11 (C59) A1.1 B1.12 (C41)A1.1 B1.11 (C59) A1.1 B1.12 (C41)
A1.1 B1.11 (C60) A1.1 B1.12 (C42)A1.1 B1.11 (C60) A1.1 B1.12 (C42)
A1.1 B1.11 (C61) A1.1 B1.12 (C43)A1.1 B1.11 (C61) A1.1 B1.12 (C43)
A1.1 B1.11 (C62) A1.1 B1.12 (C51)A1.1 B1.11 (C62) A1.1 B1.12 (C51)
A1.1 B1.11 (C65) A1.1 B1.12 (C52)A1.1 B1.11 (C65) A1.1 B1.12 (C52)
A1.1 B1.11 (C66) A1.1 B1.12 (C57)A1.1 B1.11 (C66) A1.1 B1.12 (C57)
A1.1 B1.11 (C71) A1.1 B1.12 (C58)A1.1 B1.11 (C71) A1.1 B1.12 (C58)
A1.1 B1.11 (C74) A1.1 B1.12 (C59)A1.1 B1.11 (C74) A1.1 B1.12 (C59)
A1.1 B1.12 (C1) A1.1 B1.12 (C60)A1.1 B1.12 (C1) A1.1 B1.12 (C60)
A1.1 B1.12 (C2) A1.1 B1.12 (C61)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.12 (C2) A1.1 B1.12 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.12 (C62) A1.1 B1.13 (C51)A1.1 B1.12 (C62) A1.1 B1.13 (C51)
A1.1 B1.12 (C65) A1.1 B1.13 (C52)A1.1 B1.12 (C65) A1.1 B1.13 (C52)
A1.1 B1.12 (C66) A1.1 B1.13 (C57)A1.1 B1.12 (C66) A1.1 B1.13 (C57)
A1.1 B1.12 (C71) A1.1 B1.13 (C58)A1.1 B1.12 (C71) A1.1 B1.13 (C58)
A1.1 B1.12 (C74) A1.1 B1.13 (C57)A1.1 B1.12 (C74) A1.1 B1.13 (C57)
A1.1 B1.13 (C1) A1.1 B1.13 (C58)A1.1 B1.13 (C1) A1.1 B1.13 (C58)
A1.1 B1.13 (C2) A1.1 B1.13 (C59)A1.1 B1.13 (C2) A1.1 B1.13 (C59)
A1.1 B1.13 (C3) A1.1 B1.13 (C60)A1.1 B1.13 (C3) A1.1 B1.13 (C60)
A1.1 B1.13 (C4) A1.1 B1.13 (C61)A1.1 B1.13 (C4) A1.1 B1.13 (C61)
A1.1 B1.13 (C5) A1.1 B1.13 (C62)A1.1 B1.13 (C5) A1.1 B1.13 (C62)
A1.1 B1.13 (C7) A1.1 B1.13 (C65)A1.1 B1.13 (C7) A1.1 B1.13 (C65)
A1.1 B1.13 (C9) A1.1 B1.13 (C66)A1.1 B1.13 (C9) A1.1 B1.13 (C66)
A1.1 B1.13 (C12) A1.1 B1.13 (C71)A1.1 B1.13 (C12) A1.1 B1.13 (C71)
A1.1 B1.13 (C13) A1.1 B1.13 (C74)A1.1 B1.13 (C13) A1.1 B1.13 (C74)
A1.1 B1.13 (C15) A1.1 B1.14 (C1)A1.1 B1.13 (C15) A1.1 B1.14 (C1)
A1.1 B1.13 (C18) A1.1 B1.14 (C2)A1.1 B1.13 (C18) A1.1 B1.14 (C2)
A1.1 B1.13 (C21) A1.1 B1.14 (C3)A1.1 B1.13 (C21) A1.1 B1.14 (C3)
A1.1 B1.13 (C22) A1.1 B1.14 (C4)A1.1 B1.13 (C22) A1.1 B1.14 (C4)
A1.1 B1.13 (C23) A1.1 B1.14 (C5)A1.1 B1.13 (C23) A1.1 B1.14 (C5)
A1.1 B1.13 (C24) A1.1 B1.14 (C7)A1.1 B1.13 (C24) A1.1 B1.14 (C7)
A1.1 B1.13 (C25) A1.1 B1.14 (C9)A1.1 B1.13 (C25) A1.1 B1.14 (C9)
A1.1 B1.13 (C28) A1.1 B1.14 (C12)A1.1 B1.13 (C28) A1.1 B1.14 (C12)
A1.1 B1.13 (C32) A1.1 B1.14 (C13)A1.1 B1.13 (C32) A1.1 B1.14 (C13)
A1.1 B1.13 (C37) A1.1 B1.14 (C15)A1.1 B1.13 (C37) A1.1 B1.14 (C15)
A1.1 B1.13 (C40) A1.1 B1.14 (C18)A1.1 B1.13 (C40) A1.1 B1.14 (C18)
A1.1 B1.13 (C41) A1.1 B1.14 (C21)A1.1 B1.13 (C41) A1.1 B1.14 (C21)
A1.1 B1.13 (C42) A1.1 B1.14 (C22)A1.1 B1.13 (C42) A1.1 B1.14 (C22)
A1.1 B1.13 (C43) A1.1 B1.14 (C23)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.13 (C43) A1.1 B1.14 (C23) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.14 (C24) A1.1 B1.15 (C9)A1.1 B1.14 (C24) A1.1 B1.15 (C9)
A1.1 B1.14 (C25) A1.1 B1.15 (C12)A1.1 B1.14 (C25) A1.1 B1.15 (C12)
A1.1 B1.14 (C25) A1.1 B1.15 (C13)A1.1 B1.14 (C25) A1.1 B1.15 (C13)
A1.1 B1.14 (C28) A1.1 B1.15 (C15)A1.1 B1.14 (C28) A1.1 B1.15 (C15)
A1.1 B1.14 (C32) A1.1 B1.15 (C18)A1.1 B1.14 (C32) A1.1 B1.15 (C18)
A1.1 B1.14 (C37) A1.1 B1.15 (C21)A1.1 B1.14 (C37) A1.1 B1.15 (C21)
A1.1 B1.14 (C40) A1.1 B1.15 (C22)A1.1 B1.14 (C40) A1.1 B1.15 (C22)
A1.1 B1.14 (C41) A1.1 B1.15 (C23)A1.1 B1.14 (C41) A1.1 B1.15 (C23)
A1.1 B1.14 (C42) A1.1 B1.15 (C24)A1.1 B1.14 (C42) A1.1 B1.15 (C24)
A1.1 B1.14 (C43) A1.1 B1.15 (C25)A1.1 B1.14 (C43) A1.1 B1.15 (C25)
A1.1 B1.14 (C51) A1.1 B1.15 (C25)A1.1 B1.14 (C51) A1.1 B1.15 (C25)
A1.1 B1.14 (C52) A1.1 B1.15 (C28)A1.1 B1.14 (C52) A1.1 B1.15 (C28)
A1.1 B1.14 (C57) A1.1 B1.15 (C32)A1.1 B1.14 (C57) A1.1 B1.15 (C32)
A1.1 B1.14 (C58) A1.1 B1.15 (C37)A1.1 B1.14 (C58) A1.1 B1.15 (C37)
A1.1 B1.14 (C59) A1.1 B1.15 (C40)A1.1 B1.14 (C59) A1.1 B1.15 (C40)
A1.1 B1.14 (C60) A1.1 B1.15 (C41)A1.1 B1.14 (C60) A1.1 B1.15 (C41)
A1.1 B1.14 (C61) A1.1 B1.15 (C42)A1.1 B1.14 (C61) A1.1 B1.15 (C42)
A1.1 B1.14 (C62) A1.1 B1.15 (C43)A1.1 B1.14 (C62) A1.1 B1.15 (C43)
A1.1 B1.14 (C65) A1.1 B1.15 (C51)A1.1 B1.14 (C65) A1.1 B1.15 (C51)
A1.1 B1.14 (C66) A1.1 B1.15 (C52)A1.1 B1.14 (C66) A1.1 B1.15 (C52)
A1.1 B1.14 (C71) A1.1 B1.15 (C57)A1.1 B1.14 (C71) A1.1 B1.15 (C57)
A1.1 B1.14 (C74) A1.1 B1.15 (C58)A1.1 B1.14 (C74) A1.1 B1.15 (C58)
A1.1 B1.15 (C1) A1.1 B1.15 (C57)A1.1 B1.15 (C1) A1.1 B1.15 (C57)
A1.1 B1.15 (C2) A1.1 B1.15 (C58)A1.1 B1.15 (C2) A1.1 B1.15 (C58)
A1.1 B1.15 (C3) A1.1 B1.15 (C59)A1.1 B1.15 (C3) A1.1 B1.15 (C59)
A1.1 B1.15 (C4) A1.1 B1.15 (C60)A1.1 B1.15 (C4) A1.1 B1.15 (C60)
A1.1 B1.15 (C5) A1.1 B1.15 (C61)A1.1 B1.15 (C5) A1.1 B1.15 (C61)
A1.1 B1.15 (C7) A1.1 B1.15 (C62)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.15 (C7) A1.1 B1.15 (C62) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.15 (C62) A1.1 B1.16 (C51)A1.1 B1.15 (C62) A1.1 B1.16 (C51)
A1.1 B1.15 (C65) A1.1 B1.16 (C52)A1.1 B1.15 (C65) A1.1 B1.16 (C52)
A1.1 B1.15 (C66) A1.1 B1.16 (C57)A1.1 B1.15 (C66) A1.1 B1.16 (C57)
A1.1 B1.15 (C71) A1.1 B1.16 (C58)A1.1 B1.15 (C71) A1.1 B1.16 (C58)
A1.1 B1.15 (C74) A1.1 B1.16 (C59)A1.1 B1.15 (C74) A1.1 B1.16 (C59)
A1.1 B1.16 (C1) A1.1 B1.16 (C60)A1.1 B1.16 (C1) A1.1 B1.16 (C60)
A1.1 B1.16 (C2) A1.1 B1.16 (C61)A1.1 B1.16 (C2) A1.1 B1.16 (C61)
A1.1 B1.16 (C3) A1.1 B1.16 (C62)A1.1 B1.16 (C3) A1.1 B1.16 (C62)
A1.1 B1.16 (C4) A1.1 B1.16 (C65)A1.1 B1.16 (C4) A1.1 B1.16 (C65)
A1.1 B1.16 (C5) A1.1 B1.16 (C66)A1.1 B1.16 (C5) A1.1 B1.16 (C66)
A1.1 B1.16 (C7) A1.1 B1.16 (C71)A1.1 B1.16 (C7) A1.1 B1.16 (C71)
A1.1 B1.16 (C9) A1.1 B1.16 (C74)A1.1 B1.16 (C9) A1.1 B1.16 (C74)
A1.1 B1.16 (C12) A1.1 B1.17 (C1)A1.1 B1.16 (C12) A1.1 B1.17 (C1)
A1.1 B1.16 (C13) A1.1 B1.17 (C2)A1.1 B1.16 (C13) A1.1 B1.17 (C2)
A1.1 B1.16 (C15) A1.1 B1.17 (C3)A1.1 B1.16 (C15) A1.1 B1.17 (C3)
A1.1 B1.16 (C18) A1.1 B1.17 (C4)A1.1 B1.16 (C18) A1.1 B1.17 (C4)
A1.1 B1.16 (C21) A1.1 B1.17 (C5)A1.1 B1.16 (C21) A1.1 B1.17 (C5)
A1.1 B1.16 (C22) A1.1 B1.17 (C7)A1.1 B1.16 (C22) A1.1 B1.17 (C7)
A1.1 B1.16 (C23) A1.1 B1.17 (C9)A1.1 B1.16 (C23) A1.1 B1.17 (C9)
A1.1 B1.16 (C24) A1.1 B1.17 (C12)A1.1 B1.16 (C24) A1.1 B1.17 (C12)
A1.1 B1.16 (C25) A1.1 B1.17 (C13)A1.1 B1.16 (C25) A1.1 B1.17 (C13)
A1.1 B1.16 (C28) A1.1 B1.17 (C15)A1.1 B1.16 (C28) A1.1 B1.17 (C15)
A1.1 B1.16 (C32) A1.1 B1.17 (C18)A1.1 B1.16 (C32) A1.1 B1.17 (C18)
A1.1 B1.16 (C37) A1.1 B1.17 (C21)A1.1 B1.16 (C37) A1.1 B1.17 (C21)
A1.1 B1.16 (C40) A1.1 B1.17 (C22)A1.1 B1.16 (C40) A1.1 B1.17 (C22)
A1.1 B1.16 (C41) A1.1 B1.17 (C23)A1.1 B1.16 (C41) A1.1 B1.17 (C23)
A1.1 B1.16 (C42) A1.1 B1.17 (C24)A1.1 B1.16 (C42) A1.1 B1.17 (C24)
A1.1 B1.16 (C43) A1.1 B1.17 (C25)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.16 (C43) A1.1 B1.17 (C25) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.17 (C28) A1.1 B1.18 (C15)A1.1 B1.17 (C28) A1.1 B1.18 (C15)
A1.1 B1.17 (C32) A1.1 B1.18 (C18)A1.1 B1.17 (C32) A1.1 B1.18 (C18)
A1.1 B1.17 (C37) A1.1 B1.18 (C21)A1.1 B1.17 (C37) A1.1 B1.18 (C21)
A1.1 B1.17 (C40) A1.1 B1.18 (C22)A1.1 B1.17 (C40) A1.1 B1.18 (C22)
A1.1 B1.17 (C41) A1.1 B1.18 (C23)A1.1 B1.17 (C41) A1.1 B1.18 (C23)
A1.1 B1.17 (C42) A1.1 B1.18 (C24)A1.1 B1.17 (C42) A1.1 B1.18 (C24)
A1.1 B1.17 (C43) A1.1 B1.18 (C25)A1.1 B1.17 (C43) A1.1 B1.18 (C25)
A1.1 B1.17 (C51) A1.1 B1.18 (C28)A1.1 B1.17 (C51) A1.1 B1.18 (C28)
A1.1 B1.17 (C52) A1.1 B1.18 (C32)A1.1 B1.17 (C52) A1.1 B1.18 (C32)
A1.1 B1.17 (C57) A1.1 B1.18 (C37)A1.1 B1.17 (C57) A1.1 B1.18 (C37)
A1.1 B1.17 (C58) A1.1 B1.18 (C40)A1.1 B1.17 (C58) A1.1 B1.18 (C40)
A1.1 B1.17 (C59) A1.1 B1.18 (C41)A1.1 B1.17 (C59) A1.1 B1.18 (C41)
A1.1 B1.17 (C60) A1.1 B1.18 (C42)A1.1 B1.17 (C60) A1.1 B1.18 (C42)
A1.1 B1.17 (C61) A1.1 B1.18 (C43)A1.1 B1.17 (C61) A1.1 B1.18 (C43)
A1.1 B1.17 (C62) A1.1 B1.18 (C51)A1.1 B1.17 (C62) A1.1 B1.18 (C51)
A1.1 B1.17 (C65) A1.1 B1.18 (C52)A1.1 B1.17 (C65) A1.1 B1.18 (C52)
A1.1 B1.17 (C66) A1.1 B1.18 (C57)A1.1 B1.17 (C66) A1.1 B1.18 (C57)
A1.1 B1.17 (C71) A1.1 B1.18 (C58)A1.1 B1.17 (C71) A1.1 B1.18 (C58)
A1.1 B1.17 (C74) A1.1 B1.18 (C59)A1.1 B1.17 (C74) A1.1 B1.18 (C59)
A1.1 B1.18 (C1) A1.1 B1.18 (C60)A1.1 B1.18 (C1) A1.1 B1.18 (C60)
A1.1 B1.18 (C2) A1.1 B1.18 (C61)A1.1 B1.18 (C2) A1.1 B1.18 (C61)
A1.1 B1.18 (C3) A1.1 B1.18 (C62)A1.1 B1.18 (C3) A1.1 B1.18 (C62)
A1.1 B1.18 (C4) A1.1 B1.18 (C65)A1.1 B1.18 (C4) A1.1 B1.18 (C65)
A1.1 B1.18 (C5) A1.1 B1.18 (C66)A1.1 B1.18 (C5) A1.1 B1.18 (C66)
A1.1 B1.18 (C7) A1.1 B1.18 (C71)A1.1 B1.18 (C7) A1.1 B1.18 (C71)
A1.1 B1.18 (C9) A1.1 B1.18 (C74)A1.1 B1.18 (C9) A1.1 B1.18 (C74)
A1.1 B1.18 (C12) A1.1 B1.19 (C1)A1.1 B1.18 (C12) A1.1 B1.19 (C1)
A1.1 B1.18 (C13) A1.1 B1.19 (C2)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.18 (C13) A1.1 B1.19 (C2) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.19 (C3) A1.1 B1.19 (C62)A1.1 B1.19 (C3) A1.1 B1.19 (C62)
A1.1 B1.19 (C4) A1.1 B1.19 (C65)A1.1 B1.19 (C4) A1.1 B1.19 (C65)
A1.1 B1.19 (C5) A1.1 B1.19 (C66)A1.1 B1.19 (C5) A1.1 B1.19 (C66)
A1.1 B1.19 (C7) A1.1 B1.19 (C71)A1.1 B1.19 (C7) A1.1 B1.19 (C71)
A1.1 B1.19 (C9) A1.1 B1.19 (C74)A1.1 B1.19 (C9) A1.1 B1.19 (C74)
A1.1 B1.19 (C12) A1.1 B1.20 (C1)A1.1 B1.19 (C12) A1.1 B1.20 (C1)
A1.1 B1.19 (C13) A1.1 B1.20 (C2)A1.1 B1.19 (C13) A1.1 B1.20 (C2)
A1.1 B1.19 (C15) A1.1 B1.20 (C3)A1.1 B1.19 (C15) A1.1 B1.20 (C3)
A1.1 B1.19 (C18) A1.1 B1.20 (C4)A1.1 B1.19 (C18) A1.1 B1.20 (C4)
A1.1 B1.19 (C21) A1.1 B1.20 (C5)A1.1 B1.19 (C21) A1.1 B1.20 (C5)
A1.1 B1.19 (C22) A1.1 B1.20 (C7)A1.1 B1.19 (C22) A1.1 B1.20 (C7)
A1.1 B1.19 (C23) A1.1 B1.20 (C9)A1.1 B1.19 (C23) A1.1 B1.20 (C9)
A1.1 B1.19 (C24) A1.1 B1.20 (C12)A1.1 B1.19 (C24) A1.1 B1.20 (C12)
A1.1 B1.19 (C25) A1.1 B1.20 (C13)A1.1 B1.19 (C25) A1.1 B1.20 (C13)
A1.1 B1.19 (C28) A1.1 B1.20 (C15)A1.1 B1.19 (C28) A1.1 B1.20 (C15)
A1.1 B1.19 (C32) A1.1 B1.20 (C18)A1.1 B1.19 (C32) A1.1 B1.20 (C18)
A1.1 B1.19 (C37) A1.1 B1.20 (C21)A1.1 B1.19 (C37) A1.1 B1.20 (C21)
A1.1 B1.19 (C40) A1.1 B1.20 (C22)A1.1 B1.19 (C40) A1.1 B1.20 (C22)
A1.1 B1.19 (C41) A1.1 B1.20 (C23)A1.1 B1.19 (C41) A1.1 B1.20 (C23)
A1.1 B1.19 (C42) A1.1 B1.20 (C24)A1.1 B1.19 (C42) A1.1 B1.20 (C24)
A1.1 B1.19 (C43) A1.1 B1.20 (C25)A1.1 B1.19 (C43) A1.1 B1.20 (C25)
A1.1 B1.19 (C51) A1.1 B1.20 (C28)A1.1 B1.19 (C51) A1.1 B1.20 (C28)
A1.1 B1.19 (C52) A1.1 B1.20 (C32)A1.1 B1.19 (C52) A1.1 B1.20 (C32)
A1.1 B1.19 (C57) A1.1 B1.20 (C37)A1.1 B1.19 (C57) A1.1 B1.20 (C37)
A1.1 B1.19 (C58) A1.1 B1.20 (C40)A1.1 B1.19 (C58) A1.1 B1.20 (C40)
A1.1 B1.19 (C59) A1.1 B1.20 (C41)A1.1 B1.19 (C59) A1.1 B1.20 (C41)
A1.1 B1.19 (C60) A1.1 B1.20 (C42)A1.1 B1.19 (C60) A1.1 B1.20 (C42)
A1.1 B1.19 (C61) A1.1 B1.20 (C43)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.19 (C61) A1.1 B1.20 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.20 (C51) A1.1 B1.21 (C28)A1.1 B1.20 (C51) A1.1 B1.21 (C28)
A1.1 B1.20 (C52) A1.1 B1.21 (C32)A1.1 B1.20 (C52) A1.1 B1.21 (C32)
A1.1 B1.20 (C57) A1.1 B1.21 (C37)A1.1 B1.20 (C57) A1.1 B1.21 (C37)
A1.1 B1.20 (C58) A1.1 B1.21 (C40)A1.1 B1.20 (C58) A1.1 B1.21 (C40)
A1.1 B1.20 (C59) A1.1 B1.21 (C41)A1.1 B1.20 (C59) A1.1 B1.21 (C41)
A1.1 B1.20 (C60) A1.1 B1.21 (C42)A1.1 B1.20 (C60) A1.1 B1.21 (C42)
A1.1 B1.20 (C61) A1.1 B1.21 (C43)A1.1 B1.20 (C61) A1.1 B1.21 (C43)
A1.1 B1.20 (C62) A1.1 B1.21 (C51)A1.1 B1.20 (C62) A1.1 B1.21 (C51)
A1.1 B1.20 (C65) A1.1 B1.21 (C52)A1.1 B1.20 (C65) A1.1 B1.21 (C52)
A1.1 B1.20 (C66) A1.1 B1.21 (C57)A1.1 B1.20 (C66) A1.1 B1.21 (C57)
A1.1 B1.20 (C71) A1.1 B1.21 (C58)A1.1 B1.20 (C71) A1.1 B1.21 (C58)
A1.1 B1.20 (C74) A1.1 B1.21 (C59)A1.1 B1.20 (C74) A1.1 B1.21 (C59)
A1.1 B1.21 (C1) A1.1 B1.21 (C60)A1.1 B1.21 (C1) A1.1 B1.21 (C60)
A1.1 B1.21 (C2) A1.1 B1.21 (C61)A1.1 B1.21 (C2) A1.1 B1.21 (C61)
A1.1 B1.21 (C3) A1.1 B1.21 (C62)A1.1 B1.21 (C3) A1.1 B1.21 (C62)
A1.1 B1.21 (C4) A1.1 B1.21 (C65)A1.1 B1.21 (C4) A1.1 B1.21 (C65)
A1.1 B1.21 (C5) A1.1 B1.21 (C66)A1.1 B1.21 (C5) A1.1 B1.21 (C66)
A1.1 B1.21 (C7) A1.1 B1.21 (C71)A1.1 B1.21 (C7) A1.1 B1.21 (C71)
A1.1 B1.21 (C9) A1.1 B1.21 (C74)A1.1 B1.21 (C9) A1.1 B1.21 (C74)
A1.1 B1.21 (C12) A1.1 B1.22 (C1)A1.1 B1.21 (C12) A1.1 B1.22 (C1)
A1.1 B1.21 (C13) A1.1 B1.22 (C2)A1.1 B1.21 (C13) A1.1 B1.22 (C2)
A1.1 B1.21 (C15) A1.1 B1.22 (C3)A1.1 B1.21 (C15) A1.1 B1.22 (C3)
A1.1 B1.21 (C18) A1.1 B1.22 (C4)A1.1 B1.21 (C18) A1.1 B1.22 (C4)
A1.1 B1.21 (C21) A1.1 B1.22 (C5)A1.1 B1.21 (C21) A1.1 B1.22 (C5)
A1.1 B1.21 (C22) A1.1 B1.22 (C7)A1.1 B1.21 (C22) A1.1 B1.22 (C7)
A1.1 B1.21 (C23) A1.1 B1.22 (C9)A1.1 B1.21 (C23) A1.1 B1.22 (C9)
A1.1 B1.21 (C24) A1.1 B1.22 (C12)A1.1 B1.21 (C24) A1.1 B1.22 (C12)
A1.1 B1.21 (C25) A1.1 B1.22 (C13)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.21 (C25) A1.1 B1.22 (C13) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.22 (C15) A1.1 B1.23 (C3)A1.1 B1.22 (C15) A1.1 B1.23 (C3)
A1.1 B1.22 (C18) A1.1 B1.23 (C4)A1.1 B1.22 (C18) A1.1 B1.23 (C4)
A1.1 B1.22 (C21) A1.1 B1.23 (C5)A1.1 B1.22 (C21) A1.1 B1.23 (C5)
A1.1 B1.22 (C22) A1.1 B1.23 (C7)A1.1 B1.22 (C22) A1.1 B1.23 (C7)
A1.1 B1.22 (C23) A1.1 B1.23 (C9)A1.1 B1.22 (C23) A1.1 B1.23 (C9)
A1.1 B1.22 (C24) A1.1 B1.23 (C12)A1.1 B1.22 (C24) A1.1 B1.23 (C12)
A1.1 B1.22 (C25) A1.1 B1.23 (C13)A1.1 B1.22 (C25) A1.1 B1.23 (C13)
A1.1 B1.22 (C28) A1.1 B1.23 (C15)A1.1 B1.22 (C28) A1.1 B1.23 (C15)
A1.1 B1.22 (C32) A1.1 B1.23 (C18)A1.1 B1.22 (C32) A1.1 B1.23 (C18)
A1.1 B1.22 (C37) A1.1 B1.23 (C21)A1.1 B1.22 (C37) A1.1 B1.23 (C21)
A1.1 B1.22 (C40) A1.1 B1.23 (C22)A1.1 B1.22 (C40) A1.1 B1.23 (C22)
A1.1 B1.22 (C41) A1.1 B1.23 (C23)A1.1 B1.22 (C41) A1.1 B1.23 (C23)
A1.1 B1.22 (C42) A1.1 B1.23 (C24)A1.1 B1.22 (C42) A1.1 B1.23 (C24)
A1.1 B1.22 (C43) A1.1 B1.23 (C25)A1.1 B1.22 (C43) A1.1 B1.23 (C25)
A1.1 B1.22 (C51) A1.1 B1.23 (C28)A1.1 B1.22 (C51) A1.1 B1.23 (C28)
A1.1 B1.22 (C52) A1.1 B1.23 (C32)A1.1 B1.22 (C52) A1.1 B1.23 (C32)
A1.1 B1.22 (C57) A1.1 B1.23 (C37)A1.1 B1.22 (C57) A1.1 B1.23 (C37)
A1.1 B1.22 (C58) A1.1 B1.23 (C40)A1.1 B1.22 (C58) A1.1 B1.23 (C40)
A1.1 B1.22 (C59) A1.1 B1.23 (C41)A1.1 B1.22 (C59) A1.1 B1.23 (C41)
A1.1 B1.22 (C60) A1.1 B1.23 (C42)A1.1 B1.22 (C60) A1.1 B1.23 (C42)
A1.1 B1.22 (C61) A1.1 B1.23 (C43)A1.1 B1.22 (C61) A1.1 B1.23 (C43)
A1.1 B1.22 (C62) A1.1 B1.23 (C51)A1.1 B1.22 (C62) A1.1 B1.23 (C51)
A1.1 B1.22 (C65) A1.1 B1.23 (C52)A1.1 B1.22 (C65) A1.1 B1.23 (C52)
A1.1 B1.22 (C66) A1.1 B1.23 (C57)A1.1 B1.22 (C66) A1.1 B1.23 (C57)
A1.1 B1.22 (C71) A1.1 B1.23 (C58)A1.1 B1.22 (C71) A1.1 B1.23 (C58)
A1.1 B1.22 (C74) A1.1 B1.23 (C59)A1.1 B1.22 (C74) A1.1 B1.23 (C59)
A1.1 B1.23 (C1) A1.1 B1.23 (C60)A1.1 B1.23 (C1) A1.1 B1.23 (C60)
A1.1 B1.23 (C2) A1.1 B1.23 (C61)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.1 B1.23 (C2) A1.1 B1.23 (C61) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.1 B1.23 (C62) A1.2 B1.0 (C51)A1.1 B1.23 (C62) A1.2 B1.0 (C51)
A1.1 B1.23 (C65) A1.2 B1.0 (C52)A1.1 B1.23 (C65) A1.2 B1.0 (C52)
A1.1 B1.23 (C66) A1.2 B1.0 (C57)A1.1 B1.23 (C66) A1.2 B1.0 (C57)
A1.1 B1.23 (C71) A1.2 B1.0 (C58)A1.1 B1.23 (C71) A1.2 B1.0 (C58)
A1.1 B1.23 (C74) A1.2 B1.0 (C59)A1.1 B1.23 (C74) A1.2 B1.0 (C59)
A1.2 B1.0 (C1) A1.2 B1.0 (C60)A1.2 B1.0 (C1) A1.2 B1.0 (C60)
A1.2 B1.0 (C2) A1.2 B1.0 (C61)A1.2 B1.0 (C2) A1.2 B1.0 (C61)
A1.2 B1.0 (C3) A1.2 B1.0 (C62)A1.2 B1.0 (C3) A1.2 B1.0 (C62)
A1.2 B1.0 (C4) A1.2 B1.0 (C65)A1.2 B1.0 (C4) A1.2 B1.0 (C65)
A1.2 B1.0 (C5) A1.2 B1.0 (C66)A1.2 B1.0 (C5) A1.2 B1.0 (C66)
A1.2 B1.0 (C7) A1.2 B1.0 (C71)A1.2 B1.0 (C7) A1.2 B1.0 (C71)
A1.2 B1.0 (C9) A1.2 B1.0 (C74)A1.2 B1.0 (C9) A1.2 B1.0 (C74)
A1.2 B1.0 (C12) A1.2 B1.1 (C1)A1.2 B1.0 (C12) A1.2 B1.1 (C1)
A1.2 B1.0 (C13) A1.2 B1.1 (C2)A1.2 B1.0 (C13) A1.2 B1.1 (C2)
A1.2 B1.0 (C15) A1.2 B1.1 (C3)A1.2 B1.0 (C15) A1.2 B1.1 (C3)
A1.2 B1.0 (C18) A1.2 B1.1 (C4)A1.2 B1.0 (C18) A1.2 B1.1 (C4)
A1.2 B1.0 (C21) A1.2 B1.1 (C5)A1.2 B1.0 (C21) A1.2 B1.1 (C5)
A1.2 B1.0 (C22) A1.2 B1.1 (C7)A1.2 B1.0 (C22) A1.2 B1.1 (C7)
A1.2 B1.0 (C23) A1.2 B1.1 (C9)A1.2 B1.0 (C23) A1.2 B1.1 (C9)
A1.2 B1.0 (C24) A1.2 B1.1 (C12)A1.2 B1.0 (C24) A1.2 B1.1 (C12)
A1.2 B1.0 (C25) A1.2 B1.1 (C13)A1.2 B1.0 (C25) A1.2 B1.1 (C13)
A1.2 B1.0 (C28) A1.2 B1.1 (C15)A1.2 B1.0 (C28) A1.2 B1.1 (C15)
A1.2 B1.0 (C32) A1.2 B1.1 (C18)A1.2 B1.0 (C32) A1.2 B1.1 (C18)
A1.2 B1.0 (C37) A1.2 B1.1 (C21)A1.2 B1.0 (C37) A1.2 B1.1 (C21)
A1.2 B1.0 (C40) A1.2 B1.1 (C22)A1.2 B1.0 (C40) A1.2 B1.1 (C22)
A1.2 B1.0 (C41) A1.2 B1.1 (C23)A1.2 B1.0 (C41) A1.2 B1.1 (C23)
A1.2 B1.0 (C42) A1.2 B1.1 (C24)A1.2 B1.0 (C42) A1.2 B1.1 (C24)
A1.2 B1.0 (C43) A1.2 B1.1 (C25)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.0 (C43) A1.2 B1.1 (C25) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.1 (C28) A1.2 B1.2 (C15)A1.2 B1.1 (C28) A1.2 B1.2 (C15)
A1.2 B1.1 (C32) A1.2 B1.2 (C18)A1.2 B1.1 (C32) A1.2 B1.2 (C18)
A1.2 B1.1 (C37) A1.2 B1.2 (C21)A1.2 B1.1 (C37) A1.2 B1.2 (C21)
A1.2 B1.1 (C40) A1.2 B1.2 (C22)A1.2 B1.1 (C40) A1.2 B1.2 (C22)
A1.2 B1.1 (C41) A1.2 B1.2 (C23)A1.2 B1.1 (C41) A1.2 B1.2 (C23)
A1.2 B1.1 (C42) A1.2 B1.2 (C24)A1.2 B1.1 (C42) A1.2 B1.2 (C24)
A1.2 B1.1 (C43) A1.2 B1.2 (C25)A1.2 B1.1 (C43) A1.2 B1.2 (C25)
A1.2 B1.1 (C51) A1.2 B1.2 (C28)A1.2 B1.1 (C51) A1.2 B1.2 (C28)
A1.2 B1.1 (C52) A1.2 B1.2 (C32)A1.2 B1.1 (C52) A1.2 B1.2 (C32)
A1.2 B1.1 (C57) A1.2 B1.2 (C37)A1.2 B1.1 (C57) A1.2 B1.2 (C37)
A1.2 B1.1 (C58) A1.2 B1.2 (C40)A1.2 B1.1 (C58) A1.2 B1.2 (C40)
A1.2 B1.1 (C59) A1.2 B1.2 (C41)A1.2 B1.1 (C59) A1.2 B1.2 (C41)
A1.2 B1.1 (C60) A1.2 B1.2 (C42)A1.2 B1.1 (C60) A1.2 B1.2 (C42)
A1.2 B1.1 (C61) A1.2 B1.2 (C43)A1.2 B1.1 (C61) A1.2 B1.2 (C43)
A1.2 B1.1 (C62) A1.2 B1.2 (C51)A1.2 B1.1 (C62) A1.2 B1.2 (C51)
A1.2 B1.1 (C65) A1.2 B1.2 (C52)A1.2 B1.1 (C65) A1.2 B1.2 (C52)
A1.2 B1.1 (C66) A1.2 B1.2 (C57)A1.2 B1.1 (C66) A1.2 B1.2 (C57)
A1.2 B1.1 (C71) A1.2 B1.2 (C58)A1.2 B1.1 (C71) A1.2 B1.2 (C58)
A1.2 B1.1 (C74) A1.2 B1.2 (C59)A1.2 B1.1 (C74) A1.2 B1.2 (C59)
A1.2 B1.2 (C1) A1.2 B1.2 (C60)A1.2 B1.2 (C1) A1.2 B1.2 (C60)
A1.2 B1.2 (C2) A1.2 B1.2 (C61)A1.2 B1.2 (C2) A1.2 B1.2 (C61)
A1.2 B1.2 (C3) A1.2 B1.2 (C62)A1.2 B1.2 (C3) A1.2 B1.2 (C62)
A1.2 B1.2 (C4) A1.2 B1.2 (C65)A1.2 B1.2 (C4) A1.2 B1.2 (C65)
A1.2 B1.2 (C5) A1.2 B1.2 (C66)A1.2 B1.2 (C5) A1.2 B1.2 (C66)
A1.2 B1.2 (C7) A1.2 B1.2 (C71)A1.2 B1.2 (C7) A1.2 B1.2 (C71)
A1.2 B1.2 (C9) A1.2 B1.2 (C74)A1.2 B1.2 (C9) A1.2 B1.2 (C74)
A1.2 B1.2 (C12) A1.2 B1.3 (C1)A1.2 B1.2 (C12) A1.2 B1.3 (C1)
A1.2 B1.2 (C13) A1.2 B1.3 (C2)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.2 (C13) A1.2 B1.3 (C2) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.3 (C3) A1.2 B1.3 (C62)A1.2 B1.3 (C3) A1.2 B1.3 (C62)
A1.2 B1.3 (C4) A1.2 B1.3 (C65)A1.2 B1.3 (C4) A1.2 B1.3 (C65)
A1.2 B1.3 (C5) A1.2 B1.3 (C66)A1.2 B1.3 (C5) A1.2 B1.3 (C66)
A1.2 B1.3 (C7) A1.2 B1.3 (C71)A1.2 B1.3 (C7) A1.2 B1.3 (C71)
A1.2 B1.3 (C9) A1.2 B1.3 (C74)A1.2 B1.3 (C9) A1.2 B1.3 (C74)
A1.2 B1.3 (C12) A1.2 B1.4 (C1)A1.2 B1.3 (C12) A1.2 B1.4 (C1)
A1.2 B1.3 (C13) A1.2 B1.4 (C2)A1.2 B1.3 (C13) A1.2 B1.4 (C2)
A1.2 B1.3 (C15) A1.2 B1.4 (C3)A1.2 B1.3 (C15) A1.2 B1.4 (C3)
A1.2 B1.3 (C18) A1.2 B1.4 (C4)A1.2 B1.3 (C18) A1.2 B1.4 (C4)
A1.2 B1.3 (C21) A1.2 B1.4 (C5)A1.2 B1.3 (C21) A1.2 B1.4 (C5)
A1.2 B1.3 (C22) A1.2 B1.4 (C7)A1.2 B1.3 (C22) A1.2 B1.4 (C7)
A1.2 B1.3 (C23) A1.2 B1.4 (C9)A1.2 B1.3 (C23) A1.2 B1.4 (C9)
A1.2 B1.3 (C24) A1.2 B1.4 (C12)A1.2 B1.3 (C24) A1.2 B1.4 (C12)
A1.2 B1.3 (C25) A1.2 B1.4 (C13)A1.2 B1.3 (C25) A1.2 B1.4 (C13)
A1.2 B1.3 (C28) A1.2 B1.4 (C15)A1.2 B1.3 (C28) A1.2 B1.4 (C15)
A1.2 B1.3 (C32) A1.2 B1.4 (C18)A1.2 B1.3 (C32) A1.2 B1.4 (C18)
A1.2 B1.3 (C37) A1.2 B1.4 (C21)A1.2 B1.3 (C37) A1.2 B1.4 (C21)
A1.2 B1.3 (C40) A1.2 B1.4 (C22)A1.2 B1.3 (C40) A1.2 B1.4 (C22)
A1.2 B1.3 (C41) A1.2 B1.4 (C23)A1.2 B1.3 (C41) A1.2 B1.4 (C23)
A1.2 B1.3 (C42) A1.2 B1.4 (C24)A1.2 B1.3 (C42) A1.2 B1.4 (C24)
A1.2 B1.3 (C43) A1.2 B1.4 (C25)A1.2 B1.3 (C43) A1.2 B1.4 (C25)
A1.2 B1.3 (C51) A1.2 B1.4 (C28)A1.2 B1.3 (C51) A1.2 B1.4 (C28)
A1.2 B1.3 (C52) A1.2 B1.4 (C32)A1.2 B1.3 (C52) A1.2 B1.4 (C32)
A1.2 B1.3 (C57) A1.2 B1.4 (C37)A1.2 B1.3 (C57) A1.2 B1.4 (C37)
A1.2 B1.3 (C58) A1.2 B1.4 (C40)A1.2 B1.3 (C58) A1.2 B1.4 (C40)
A1.2 B1.3 (C59) A1.2 B1.4 (C41)A1.2 B1.3 (C59) A1.2 B1.4 (C41)
A1.2 B1.3 (C60) A1.2 B1.4 (C42)A1.2 B1.3 (C60) A1.2 B1.4 (C42)
A1.2 B1.3 (C61) A1.2 B1.4 (C43)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.3 (C61) A1.2 B1.4 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.4 (C51) A1.2 B1.5 (C24)A1.2 B1.4 (C51) A1.2 B1.5 (C24)
A1.2 B1.4 (C52) A1.2 B1.5 (C25)A1.2 B1.4 (C52) A1.2 B1.5 (C25)
A1.2 B1.4 (C57) A1.2 B1.5 (C28)A1.2 B1.4 (C57) A1.2 B1.5 (C28)
A1.2 B1.4 (C58) A1.2 B1.5 (C32)A1.2 B1.4 (C58) A1.2 B1.5 (C32)
A1.2 B1.4 (C57) A1.2 B1.5 (C37)A1.2 B1.4 (C57) A1.2 B1.5 (C37)
A1.2 B1.4 (C58) A1.2 B1.5 (C40)A1.2 B1.4 (C58) A1.2 B1.5 (C40)
A1.2 B1.4 (C59) A1.2 B1.5 (C41)A1.2 B1.4 (C59) A1.2 B1.5 (C41)
A1.2 B1.4 (C60) A1.2 B1.5 (C42)A1.2 B1.4 (C60) A1.2 B1.5 (C42)
A1.2 B1.4 (C61) A1.2 B1.5 (C43)A1.2 B1.4 (C61) A1.2 B1.5 (C43)
A1.2 B1.4 (C62) A1.2 B1.5 (C51)A1.2 B1.4 (C62) A1.2 B1.5 (C51)
A1.2 B1.4 (C65) A1.2 B1.5 (C52)A1.2 B1.4 (C65) A1.2 B1.5 (C52)
A1.2 B1.4 (C66) A1.2 B1.5 (C57)A1.2 B1.4 (C66) A1.2 B1.5 (C57)
A1.2 B1.4 (C71) A1.2 B1.5 (C58)A1.2 B1.4 (C71) A1.2 B1.5 (C58)
A1.2 B1.4 (C74) A1.2 B1.5 (C59)A1.2 B1.4 (C74) A1.2 B1.5 (C59)
A1.2 B1.5 (C1) A1.2 B1.5 (C60)A1.2 B1.5 (C1) A1.2 B1.5 (C60)
A1.2 B1.5 (C2) A1.2 B1.5 (C61)A1.2 B1.5 (C2) A1.2 B1.5 (C61)
A1.2 B1.5 (C3) A1.2 B1.5 (C62)A1.2 B1.5 (C3) A1.2 B1.5 (C62)
A1.2 B1.5 (C4) A1.2 B1.5 (C65)A1.2 B1.5 (C4) A1.2 B1.5 (C65)
A1.2 B1.5 (C5) A1.2 B1.5 (C66)A1.2 B1.5 (C5) A1.2 B1.5 (C66)
A1.2 B1.5 (C7) A1.2 B1.5 (C71)A1.2 B1.5 (C7) A1.2 B1.5 (C71)
A1.2 B1.5 (C9) A1.2 B1.5 (C74)A1.2 B1.5 (C9) A1.2 B1.5 (C74)
A1.2 B1.5 (C12) A1.2 B1.6 (C1)A1.2 B1.5 (C12) A1.2 B1.6 (C1)
A1.2 B1.5 (C13) A1.2 B1.6 (C2)A1.2 B1.5 (C13) A1.2 B1.6 (C2)
A1.2 B1.5 (C15) A1.2 B1.6 (C3)A1.2 B1.5 (C15) A1.2 B1.6 (C3)
A1.2 B1.5 (C18) A1.2 B1.6 (C4)A1.2 B1.5 (C18) A1.2 B1.6 (C4)
A1.2 B1.5 (C21) A1.2 B1.6 (C5)A1.2 B1.5 (C21) A1.2 B1.6 (C5)
A1.2 B1.5 (C22) A1.2 B1.6 (C7)A1.2 B1.5 (C22) A1.2 B1.6 (C7)
A1.2 B1.5 (C23) A1.2 B1.6 (C9)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.5 (C23) A1.2 B1.6 (C9) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.6 (C12) A1.2 B1.7 (C1)A1.2 B1.6 (C12) A1.2 B1.7 (C1)
A1.2 B1.6 (C13) A1.2 B1.7 (C2)A1.2 B1.6 (C13) A1.2 B1.7 (C2)
A1.2 B1.6 (C15) A1.2 B1.7 (C3)A1.2 B1.6 (C15) A1.2 B1.7 (C3)
A1.2 B1.6 (C18) A1.2 B1.7 (C4)A1.2 B1.6 (C18) A1.2 B1.7 (C4)
A1.2 B1.6 (C21) A1.2 B1.7 (C5)A1.2 B1.6 (C21) A1.2 B1.7 (C5)
A1.2 B1.6 (C22) A1.2 B1.7 (C7)A1.2 B1.6 (C22) A1.2 B1.7 (C7)
A1.2 B1.6 (C23) A1.2 B1.7 (C9)A1.2 B1.6 (C23) A1.2 B1.7 (C9)
A1.2 B1.6 (C24) A1.2 B1.7 (C12)A1.2 B1.6 (C24) A1.2 B1.7 (C12)
A1.2 B1.6 (C25) A1.2 B1.7 (C13)A1.2 B1.6 (C25) A1.2 B1.7 (C13)
A1.2 B1.6 (C28) A1.2 B1.7 (C15)A1.2 B1.6 (C28) A1.2 B1.7 (C15)
A1.2 B1.6 (C32) A1.2 B1.7 (C18)A1.2 B1.6 (C32) A1.2 B1.7 (C18)
A1.2 B1.6 (C37) A1.2 B1.7 (C21)A1.2 B1.6 (C37) A1.2 B1.7 (C21)
A1.2 B1.6 (C40) A1.2 B1.7 (C22)A1.2 B1.6 (C40) A1.2 B1.7 (C22)
A1.2 B1.6 (C41) A1.2 B1.7 (C23)A1.2 B1.6 (C41) A1.2 B1.7 (C23)
A1.2 B1.6 (C42) A1.2 B1.7 (C24)A1.2 B1.6 (C42) A1.2 B1.7 (C24)
A1.2 B1.6 (C43) A1.2 B1.7 (C25)A1.2 B1.6 (C43) A1.2 B1.7 (C25)
A1.2 B1.6 (C51) A1.2 B1.7 (C28)A1.2 B1.6 (C51) A1.2 B1.7 (C28)
A1.2 B1.6 (C52) A1.2 B1.7 (C32)A1.2 B1.6 (C52) A1.2 B1.7 (C32)
A1.2 B1.6 (C57) A1.2 B1.7 (C37)A1.2 B1.6 (C57) A1.2 B1.7 (C37)
A1.2 B1.6 (C58) A1.2 B1.7 (C40)A1.2 B1.6 (C58) A1.2 B1.7 (C40)
A1.2 B1.6 (C59) A1.2 B1.7 (C41)A1.2 B1.6 (C59) A1.2 B1.7 (C41)
A1.2 B1.6 (C60) A1.2 B1.7 (C42)A1.2 B1.6 (C60) A1.2 B1.7 (C42)
A1.2 B1.6 (C61) A1.2 B1.7 (C43)A1.2 B1.6 (C61) A1.2 B1.7 (C43)
A1.2 B1.6 (C62) A1.2 B1.7 (C51)A1.2 B1.6 (C62) A1.2 B1.7 (C51)
A1.2 B1.6 (C65) A1.2 B1.7 (C52)A1.2 B1.6 (C65) A1.2 B1.7 (C52)
A1.2 B1.6 (C66) A1.2 B1.7 (C57)A1.2 B1.6 (C66) A1.2 B1.7 (C57)
A1.2 B1.6 (C71) A1.2 B1.7 (C58)A1.2 B1.6 (C71) A1.2 B1.7 (C58)
A1.2 B1.6 (C74) A1.2 B1.7 (C59)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.6 (C74) A1.2 B1.7 (C59) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.7 (C60) A1.2 B1.8 (C42)A1.2 B1.7 (C60) A1.2 B1.8 (C42)
A1.2 B1.7 (C61) A1.2 B1.8 (C43)A1.2 B1.7 (C61) A1.2 B1.8 (C43)
A1.2 B1.7 (C62) A1.2 B1.8 (C51)A1.2 B1.7 (C62) A1.2 B1.8 (C51)
A1.2 B1.7 (C65) A1.2 B1.8 (C52)A1.2 B1.7 (C65) A1.2 B1.8 (C52)
A1.2 B1.7 (C66) A1.2 B1.8 (C57)A1.2 B1.7 (C66) A1.2 B1.8 (C57)
A1.2 B1.7 (C71) A1.2 B1.8 (C58)A1.2 B1.7 (C71) A1.2 B1.8 (C58)
A1.2 B1.7 (C74) A1.2 B1.8 (C59)A1.2 B1.7 (C74) A1.2 B1.8 (C59)
A1.2 B1.8 (C1) A1.2 B1.8 (C60)A1.2 B1.8 (C1) A1.2 B1.8 (C60)
A1.2 B1.8 (C2) A1.2 B1.8 (C61)A1.2 B1.8 (C2) A1.2 B1.8 (C61)
A1.2 B1.8 (C3) A1.2 B1.8 (C62)A1.2 B1.8 (C3) A1.2 B1.8 (C62)
A1.2 B1.8 (C4) A1.2 B1.8 (C65)A1.2 B1.8 (C4) A1.2 B1.8 (C65)
A1.2 B1.8 (C5) A1.2 B1.8 (C66)A1.2 B1.8 (C5) A1.2 B1.8 (C66)
A1.2 B1.8 (C7) A1.2 B1.8 (C71)A1.2 B1.8 (C7) A1.2 B1.8 (C71)
A1.2 B1.8 (C9) A1.2 B1.8 (C74)A1.2 B1.8 (C9) A1.2 B1.8 (C74)
A1.2 B1.8 (C12) A1.2 B1.9 (C1)A1.2 B1.8 (C12) A1.2 B1.9 (C1)
A1.2 B1.8 (C13) A1.2 B1.9 (C2)A1.2 B1.8 (C13) A1.2 B1.9 (C2)
A1.2 B1.8 (C15) A1.2 B1.9 (C3)A1.2 B1.8 (C15) A1.2 B1.9 (C3)
A1.2 B1.8 (C18) A1.2 B1.9 (C4)A1.2 B1.8 (C18) A1.2 B1.9 (C4)
A1.2 B1.8 (C21) A1.2 B1.9 (C5)A1.2 B1.8 (C21) A1.2 B1.9 (C5)
A1.2 B1.8 (C22) A1.2 B1.9 (C7)A1.2 B1.8 (C22) A1.2 B1.9 (C7)
A1.2 B1.8 (C23) A1.2 B1.9 (C9)A1.2 B1.8 (C23) A1.2 B1.9 (C9)
A1.2 B1.8 (C24) A1.2 B1.9 (C12)A1.2 B1.8 (C24) A1.2 B1.9 (C12)
A1.2 B1.8 (C25) A1.2 B1.9 (C13)A1.2 B1.8 (C25) A1.2 B1.9 (C13)
A1.2 B1.8 (C28) A1.2 B1.9 (C15)A1.2 B1.8 (C28) A1.2 B1.9 (C15)
A1.2 B1.8 (C32) A1.2 B1.9 (C18)A1.2 B1.8 (C32) A1.2 B1.9 (C18)
A1.2 B1.8 (C37) A1.2 B1.9 (C21)A1.2 B1.8 (C37) A1.2 B1.9 (C21)
A1.2 B1.8 (C40) A1.2 B1.9 (C22)A1.2 B1.8 (C40) A1.2 B1.9 (C22)
A1.2 B1.8 (C41) A1.2 B1.9 (C23)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.8 (C41) A1.2 B1.9 (C23) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.9 (C24) A1.2 B1.10 (C12)A1.2 B1.9 (C24) A1.2 B1.10 (C12)
A1.2 B1.9 (C25) A1.2 B1.10 (C13)A1.2 B1.9 (C25) A1.2 B1.10 (C13)
A1.2 B1.9 (C28) A1.2 B1.10 (C15)A1.2 B1.9 (C28) A1.2 B1.10 (C15)
A1.2 B1.9 (C32) A1.2 B1.10 (C18)A1.2 B1.9 (C32) A1.2 B1.10 (C18)
A1.2 B1.9 (C37) A1.2 B1.10 (C21)A1.2 B1.9 (C37) A1.2 B1.10 (C21)
A1.2 B1.9 (C40) A1.2 B1.10 (C22)A1.2 B1.9 (C40) A1.2 B1.10 (C22)
A1.2 B1.9 (C41) A1.2 B1.10 (C23)A1.2 B1.9 (C41) A1.2 B1.10 (C23)
A1.2 B1.9 (C42) A1.2 B1.10 (C24)A1.2 B1.9 (C42) A1.2 B1.10 (C24)
A1.2 B1.9 (C43) A1.2 B1.10 (C25)A1.2 B1.9 (C43) A1.2 B1.10 (C25)
A1.2 B1.9 (C51) A1.2 B1.10 (C28)A1.2 B1.9 (C51) A1.2 B1.10 (C28)
A1.2 B1.9 (C52) A1.2 B1.10 (C32)A1.2 B1.9 (C52) A1.2 B1.10 (C32)
A1.2 B1.9 (C57) A1.2 B1.10 A1.2 B1.9 (C57) A1.2 B1.10
A1.2 B1.9 (C58) A1.2 B1.10 (C40) A1.2 B1.9 (C58) A1.2 B1.10 (C40)
A1.2 B1.9 (C59) A1.2 B1.10 (C41)A1.2 B1.9 (C59) A1.2 B1.10 (C41)
A1.2 B1.9 (C60) A1.2 B1.10 (C42)A1.2 B1.9 (C60) A1.2 B1.10 (C42)
A1.2 B1.9 (C61) A1.2 B1.10 (C43)A1.2 B1.9 (C61) A1.2 B1.10 (C43)
A1.2 B1.9 (C62) A1.2 B1.10 (C51)A1.2 B1.9 (C62) A1.2 B1.10 (C51)
A1.2 B1.9 (C65) A1.2 B1.10 (C52)A1.2 B1.9 (C65) A1.2 B1.10 (C52)
A1.2 B1.9 (C66) A1.2 B1.10 (C57)A1.2 B1.9 (C66) A1.2 B1.10 (C57)
A1.2 B1.9 (C71) A1.2 B1.10 (C58)A1.2 B1.9 (C71) A1.2 B1.10 (C58)
A1.2 B1.9 (C74) A1.2 B1.10 (C59)A1.2 B1.9 (C74) A1.2 B1.10 (C59)
A1.2 B1.10 (C1) A1.2 B1.10 (C60)A1.2 B1.10 (C1) A1.2 B1.10 (C60)
A1.2 B1.10 (C2) A1.2 B1.10 (C61)A1.2 B1.10 (C2) A1.2 B1.10 (C61)
A1.2 B1.10 (C3) A1.2 B1.10 (C62)A1.2 B1.10 (C3) A1.2 B1.10 (C62)
A1.2 B1.10 (C4) A1.2 B1.10 (C65)A1.2 B1.10 (C4) A1.2 B1.10 (C65)
A1.2 B1.10 (C5) A1.2 B1.10 (C66)A1.2 B1.10 (C5) A1.2 B1.10 (C66)
A1.2 B1.10 (C7) A1.2 B1.10 (C71)A1.2 B1.10 (C7) A1.2 B1.10 (C71)
A1.2 B1.10 (C9) A1.2 B1.10 (C74)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.10 (C9) A1.2 B1.10 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.11 (C1) A1.2 B1.11 (C61)A1.2 B1.11 (C1) A1.2 B1.11 (C61)
A1.2 B1.11 (C2) A1.2 B1.11 (C62)A1.2 B1.11 (C2) A1.2 B1.11 (C62)
A1.2 B1.11 (C3) A1.2 B1.11 (C65)A1.2 B1.11 (C3) A1.2 B1.11 (C65)
A1.2 B1.11 (C4) A1.2 B1.11 (C66)A1.2 B1.11 (C4) A1.2 B1.11 (C66)
A1.2 B1.11 (C5) A1.2 B1.11 (C71)A1.2 B1.11 (C5) A1.2 B1.11 (C71)
A1.2 B1.11 (C7) A1.2 B1.11 (C74)A1.2 B1.11 (C7) A1.2 B1.11 (C74)
A1.2 B1.11 (C9) A1.2 B1.12 (C1)A1.2 B1.11 (C9) A1.2 B1.12 (C1)
A1.2 B1.11 (C12) A1.2 B1.12 (C2)A1.2 B1.11 (C12) A1.2 B1.12 (C2)
A1.2 B1.11 (C13) A1.2 B1.12 (C3)A1.2 B1.11 (C13) A1.2 B1.12 (C3)
A1.2 B1.11 (C15) A1.2 B1.12 (C4)A1.2 B1.11 (C15) A1.2 B1.12 (C4)
A1.2 B1.11 (C18) A1.2 B1.12 (C5)A1.2 B1.11 (C18) A1.2 B1.12 (C5)
A1.2 B1.11 (C21) A1.2 B1.12 (C7)A1.2 B1.11 (C21) A1.2 B1.12 (C7)
A1.2 B1.11 (C22) A1.2 B1.12 (C9)A1.2 B1.11 (C22) A1.2 B1.12 (C9)
A1.2 B1.11 (C23) A1.2 B1.12 (C12)A1.2 B1.11 (C23) A1.2 B1.12 (C12)
A1.2 B1.11 (C24) A1.2 B1.12 (C13)A1.2 B1.11 (C24) A1.2 B1.12 (C13)
A1.2 B1.11 (C28) A1.2 B1.12 (C15)A1.2 B1.11 (C28) A1.2 B1.12 (C15)
A1.2 B1.11 (C32) A1.2 B1.12 (C18)A1.2 B1.11 (C32) A1.2 B1.12 (C18)
A1.2 B1.11 (C37) A1.2 B1.12 (C21)A1.2 B1.11 (C37) A1.2 B1.12 (C21)
A1.2 B1.11 (C40) A1.2 B1.12 (C22)A1.2 B1.11 (C40) A1.2 B1.12 (C22)
A1.2 B1.11 (C41) A1.2 B1.12 (C23)A1.2 B1.11 (C41) A1.2 B1.12 (C23)
A1.2 B1.11 (C42) A1.2 B1.12 (C24)A1.2 B1.11 (C42) A1.2 B1.12 (C24)
A1.2 B1.11 (C43) A1.2 B1.12 (C25)A1.2 B1.11 (C43) A1.2 B1.12 (C25)
A1.2 B1.11 (C51) A1.2 B1.12 (C28)A1.2 B1.11 (C51) A1.2 B1.12 (C28)
A1.2 B1.11 (C52) A1.2 B1.12 (C32)A1.2 B1.11 (C52) A1.2 B1.12 (C32)
A1.2 B1.11 (C57) A1.2 B1.12 (C37)A1.2 B1.11 (C57) A1.2 B1.12 (C37)
A1.2 B1.11 (C58) A1.2 B1.12 (C40)A1.2 B1.11 (C58) A1.2 B1.12 (C40)
A1.2 B1.11 (C59) A1.2 B1.12 (C41)A1.2 B1.11 (C59) A1.2 B1.12 (C41)
A1.2 B1.11 (C60) A1.2 B1.12 (C42)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.11 (C60) A1.2 B1.12 (C42) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.12 (C43) A1.2 B1.13 (C24)A1.2 B1.12 (C43) A1.2 B1.13 (C24)
A1.2 B1.12 (C51) A1.2 B1.13 (C25)A1.2 B1.12 (C51) A1.2 B1.13 (C25)
A1.2 B1.12 (C52) A1.2 B1.13 (C28)A1.2 B1.12 (C52) A1.2 B1.13 (C28)
A1.2 B1.12 (C57) A1.2 B1.13 (C32)A1.2 B1.12 (C57) A1.2 B1.13 (C32)
A1.2 B1.12 (C58) A1.2 B1.13 (C37)A1.2 B1.12 (C58) A1.2 B1.13 (C37)
A1.2 B1.12 (C59) A1.2 B1.13 (C40)A1.2 B1.12 (C59) A1.2 B1.13 (C40)
A1.2 B1.12 (C60) A1.2 B1.13 (C41)A1.2 B1.12 (C60) A1.2 B1.13 (C41)
A1.2 B1.12 (C61) A1.2 B1.13 (C42)A1.2 B1.12 (C61) A1.2 B1.13 (C42)
A1.2 B1.12 (C62) A1.2 B1.13 (C43)A1.2 B1.12 (C62) A1.2 B1.13 (C43)
A1.2 B1.12 (C62) A1.2 B1.13 (C51)A1.2 B1.12 (C62) A1.2 B1.13 (C51)
A1.2 B1.12 (C65) A1.2 B1.13 (C52)A1.2 B1.12 (C65) A1.2 B1.13 (C52)
A1.2 B1.12 (C66) A1.2 B1.13 (C57)A1.2 B1.12 (C66) A1.2 B1.13 (C57)
A1.2 B1.12 (C71) A1.2 B1.13 (C58)A1.2 B1.12 (C71) A1.2 B1.13 (C58)
A1.2 B1.12 (C74) A1.2 B1.13 (C59)A1.2 B1.12 (C74) A1.2 B1.13 (C59)
A1.2 B1.13 (C1) A1.2 B1.13 (C60)A1.2 B1.13 (C1) A1.2 B1.13 (C60)
A1.2 B1.13 (C2) A1.2 B1.13 (C61)A1.2 B1.13 (C2) A1.2 B1.13 (C61)
A1.2 B1.13 (C3) A1.2 B1.13 (C62)A1.2 B1.13 (C3) A1.2 B1.13 (C62)
A1.2 B1.13 (C4) A1.2 B1.13 (C65)A1.2 B1.13 (C4) A1.2 B1.13 (C65)
A1.2 B1.13 (C5) A1.2 B1.13 (C66)A1.2 B1.13 (C5) A1.2 B1.13 (C66)
A1.2 B1.13 (C7) A1.2 B1.13 (C71)A1.2 B1.13 (C7) A1.2 B1.13 (C71)
A1.2 B1.13 (C9) A1.2 B1.13 (C74)A1.2 B1.13 (C9) A1.2 B1.13 (C74)
A1.2 B1.13 (C12) A1.2 B1.14 (C1)A1.2 B1.13 (C12) A1.2 B1.14 (C1)
A1.2 B1.13 (C13) A1.2 B1.14 (C2)A1.2 B1.13 (C13) A1.2 B1.14 (C2)
A1.2 B1.13 (C15) A1.2 B1.14 (C3)A1.2 B1.13 (C15) A1.2 B1.14 (C3)
A1.2 B1.13 (C18) A1.2 B1.14 (C4)A1.2 B1.13 (C18) A1.2 B1.14 (C4)
A1.2 B1.13 (C21) A1.2 B1.14 (C5)A1.2 B1.13 (C21) A1.2 B1.14 (C5)
A1.2 B1.13 (C22) A1.2 B1.14 (C7)A1.2 B1.13 (C22) A1.2 B1.14 (C7)
A1.2 B1.13 (C23) A1.2 B1.14 (C9)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.13 (C23) A1.2 B1.14 (C9) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.14 (C12) A1.2 B1.15 (C1)A1.2 B1.14 (C12) A1.2 B1.15 (C1)
A1.2 B1.14 (C13) A1.2 B1.15 (C2)A1.2 B1.14 (C13) A1.2 B1.15 (C2)
A1.2 B1.14 (C15) A1.2 B1.15 (C3)A1.2 B1.14 (C15) A1.2 B1.15 (C3)
A1.2 B1.14 (C18) A1.2 B1.15 (C4)A1.2 B1.14 (C18) A1.2 B1.15 (C4)
A1.2 B1.14 (C21) A1.2 B1.15 (C5)A1.2 B1.14 (C21) A1.2 B1.15 (C5)
A1.2 B1.14 (C22) A1.2 B1.15 (C7)A1.2 B1.14 (C22) A1.2 B1.15 (C7)
A1.2 B1.14 (C23) A1.2 B1.15 (C9)A1.2 B1.14 (C23) A1.2 B1.15 (C9)
A1.2 B1.14 (C24) A1.2 B1.15 (C12)A1.2 B1.14 (C24) A1.2 B1.15 (C12)
A1.2 B1.14 (C25) A1.2 B1.15 (C13)A1.2 B1.14 (C25) A1.2 B1.15 (C13)
A1.2 B1.14 (C28) A1.2 B1.15 (C15)A1.2 B1.14 (C28) A1.2 B1.15 (C15)
A1.2 B1.14 (C32) A1.2 B1.15 (C18)A1.2 B1.14 (C32) A1.2 B1.15 (C18)
A1.2 B1.14 (C37) A1.2 B1.15 (C21)A1.2 B1.14 (C37) A1.2 B1.15 (C21)
A1.2 B1.14 (C40) A1.2 B1.15 (C22)A1.2 B1.14 (C40) A1.2 B1.15 (C22)
A1.2 B1.14 (C41) A1.2 B1.15 (C23)A1.2 B1.14 (C41) A1.2 B1.15 (C23)
A1.2 B1.14 (C42) A1.2 B1.15 (C24)A1.2 B1.14 (C42) A1.2 B1.15 (C24)
A1.2 B1.14 (C43) A1.2 B1.15 (C25)A1.2 B1.14 (C43) A1.2 B1.15 (C25)
A1.2 B1.14 (C51) A1.2 B1.15 (C28)A1.2 B1.14 (C51) A1.2 B1.15 (C28)
A1.2 B1.14 (C52) A1.2 B1.15 (C32)A1.2 B1.14 (C52) A1.2 B1.15 (C32)
A1.2 B1.14 (C57) A1.2 B1.15 (C37)A1.2 B1.14 (C57) A1.2 B1.15 (C37)
A1.2 B1.14 (C58) A1.2 B1.15 (C40)A1.2 B1.14 (C58) A1.2 B1.15 (C40)
A1.2 B1.14 (C59) A1.2 B1.15 (C41)A1.2 B1.14 (C59) A1.2 B1.15 (C41)
A1.2 B1.14 (C60) A1.2 B1.15 (C42)A1.2 B1.14 (C60) A1.2 B1.15 (C42)
A1.2 B1.14 (C61) A1.2 B1.15 (C43)A1.2 B1.14 (C61) A1.2 B1.15 (C43)
A1.2 B1.14 (C62) A1.2 B1.15 (C51)A1.2 B1.14 (C62) A1.2 B1.15 (C51)
A1.2 B1.14 (C65) A1.2 B1.15 (C52)A1.2 B1.14 (C65) A1.2 B1.15 (C52)
A1.2 B1.14 (C66) A1.2 B1.15 (C57)A1.2 B1.14 (C66) A1.2 B1.15 (C57)
A1.2 B1.14 (C71) A1.2 B1.15 (C58)A1.2 B1.14 (C71) A1.2 B1.15 (C58)
A1.2 B1.14 (C74) A1.2 B1.15 (C59)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.14 (C74) A1.2 B1.15 (C59) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.15 (C60) A1.2 B1.16 (C42)A1.2 B1.15 (C60) A1.2 B1.16 (C42)
A1.2 B1.15 (C61) A1.2 B1.16 (C43)A1.2 B1.15 (C61) A1.2 B1.16 (C43)
A1.2 B1.15 (C62) A1.2 B1.16 (C51)A1.2 B1.15 (C62) A1.2 B1.16 (C51)
A1.2 B1.15 (C65) A1.2 B1.16 (C52)A1.2 B1.15 (C65) A1.2 B1.16 (C52)
A1.2 B1.15 (C66) A1.2 B1.16 (C57)A1.2 B1.15 (C66) A1.2 B1.16 (C57)
A1.2 B1.15 (C71) A1.2 B1.16 (C58)A1.2 B1.15 (C71) A1.2 B1.16 (C58)
A1.2 B1.15 (C74) A1.2 B1.16 (C59)A1.2 B1.15 (C74) A1.2 B1.16 (C59)
A1.2 B1.16 (C1) A1.2 B1.16 (C60)A1.2 B1.16 (C1) A1.2 B1.16 (C60)
A1.2 B1.16 (C2) A1.2 B1.16 (C61)A1.2 B1.16 (C2) A1.2 B1.16 (C61)
A1.2 B1.16 (C3) A1.2 B1.16 (C62)A1.2 B1.16 (C3) A1.2 B1.16 (C62)
A1.2 B1.16 (C4) A1.2 B1.16 (C65)A1.2 B1.16 (C4) A1.2 B1.16 (C65)
A1.2 B1.16 (C5) A1.2 B1.16 (C66)A1.2 B1.16 (C5) A1.2 B1.16 (C66)
A1.2 B1.16 (C7) A1.2 B1.16 (C71)A1.2 B1.16 (C7) A1.2 B1.16 (C71)
A1.2 B1.16 (C9) A1.2 B1.16 (C74)A1.2 B1.16 (C9) A1.2 B1.16 (C74)
A1.2 B1.16 (C12) A1.2 B1.17 (C1)A1.2 B1.16 (C12) A1.2 B1.17 (C1)
A1.2 B1.16 (C13) A1.2 B1.17 (C2)A1.2 B1.16 (C13) A1.2 B1.17 (C2)
A1.2 B1.16 (C15) A1.2 B1.17 (C3)A1.2 B1.16 (C15) A1.2 B1.17 (C3)
A1.2 B1.16 (C18) A1.2 B1.17 (C4)A1.2 B1.16 (C18) A1.2 B1.17 (C4)
A1.2 B1.16 (C21) A1.2 B1.17 (C5)A1.2 B1.16 (C21) A1.2 B1.17 (C5)
A1.2 B1.16 (C22) A1.2 B1.17 (C7)A1.2 B1.16 (C22) A1.2 B1.17 (C7)
A1.2 B1.16 (C23) A1.2 B1.17 (C9)A1.2 B1.16 (C23) A1.2 B1.17 (C9)
A1.2 B1.16 (C24) A1.2 B1.17 (C12)A1.2 B1.16 (C24) A1.2 B1.17 (C12)
A1.2 B1.16 (C25) A1.2 B1.17 (C13)A1.2 B1.16 (C25) A1.2 B1.17 (C13)
A1.2 B1.16 (C28) A1.2 B1.17 (C15)A1.2 B1.16 (C28) A1.2 B1.17 (C15)
A1.2 B1.16 (C32) A1.2 B1.17 (C18)A1.2 B1.16 (C32) A1.2 B1.17 (C18)
A1.2 B1.16 (C37) A1.2 B1.17 (C21)A1.2 B1.16 (C37) A1.2 B1.17 (C21)
A1.2 B1.16 (C40) A1.2 B1.17 (C22)A1.2 B1.16 (C40) A1.2 B1.17 (C22)
A1.2 B1.16 (C41) A1.2 B1.17 (C23)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.16 (C41) A1.2 B1.17 (C23) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.17 (C24) A1.2 B1.18 (C12)A1.2 B1.17 (C24) A1.2 B1.18 (C12)
A1.2 B1.17 (C25) A1.2 B1.18 (C13)A1.2 B1.17 (C25) A1.2 B1.18 (C13)
A1.2 B1.17 (C28) A1.2 B1.18 (C15)A1.2 B1.17 (C28) A1.2 B1.18 (C15)
A1.2 B1.17 (C32) A1.2 B1.18 (C18)A1.2 B1.17 (C32) A1.2 B1.18 (C18)
A1.2 B1.17 (C37) A1.2 B1.18 (C21)A1.2 B1.17 (C37) A1.2 B1.18 (C21)
A1.2 B1.17 (C40) A1.2 B1.18 (C22)A1.2 B1.17 (C40) A1.2 B1.18 (C22)
A1.2 B1.17 (C41) A1.2 B1.18 (C23)A1.2 B1.17 (C41) A1.2 B1.18 (C23)
A1.2 B1.17 (C42) A1.2 B1.18 (C24)A1.2 B1.17 (C42) A1.2 B1.18 (C24)
A1.2 B1.17 (C43) A1.2 B1.18 (C25)A1.2 B1.17 (C43) A1.2 B1.18 (C25)
A1.2 B1.17 (C51) A1.2 B1.18 (C28)A1.2 B1.17 (C51) A1.2 B1.18 (C28)
A1.2 B1.17 (C52) A1.2 B1.18 (C32)A1.2 B1.17 (C52) A1.2 B1.18 (C32)
A1.2 B1.17 (C57) A1.2 B1.18 (C37)A1.2 B1.17 (C57) A1.2 B1.18 (C37)
A1.2 B1.17 (C58) A1.2 B1.18 (C40)A1.2 B1.17 (C58) A1.2 B1.18 (C40)
A1.2 B1.17 (C59) A1.2 B1.18 (C41)A1.2 B1.17 (C59) A1.2 B1.18 (C41)
A1.2 B1.17 (C60) A1.2 B1.18 (C42)A1.2 B1.17 (C60) A1.2 B1.18 (C42)
A1.2 B1.17 (C61) A1.2 B1.18 (C43)A1.2 B1.17 (C61) A1.2 B1.18 (C43)
A1.2 B1.17 (C62) A1.2 B1.18 (C51)A1.2 B1.17 (C62) A1.2 B1.18 (C51)
A1.2 B1.17 (C65) A1.2 B1.18 (C52)A1.2 B1.17 (C65) A1.2 B1.18 (C52)
A1.2 B1.17 (C66) A1.2 B1.18 (C57)A1.2 B1.17 (C66) A1.2 B1.18 (C57)
A1.2 B1.17 (C71) A1.2 B1.18 (C58)A1.2 B1.17 (C71) A1.2 B1.18 (C58)
A1.2 B1.17 (C74) A1.2 B1.18 (C59)A1.2 B1.17 (C74) A1.2 B1.18 (C59)
A1.2 B1.18 (C1) A1.2 B1.18 (C60)A1.2 B1.18 (C1) A1.2 B1.18 (C60)
A1.2 B1.18 (C2) A1.2 B1.18 (C61)A1.2 B1.18 (C2) A1.2 B1.18 (C61)
A1.2 B1.18 (C3) A1.2 B1.18 (C62)A1.2 B1.18 (C3) A1.2 B1.18 (C62)
A1.2 B1.18 (C4) A1.2 B1.18 (C65)A1.2 B1.18 (C4) A1.2 B1.18 (C65)
A1.2 B1.18 (C5) A1.2 B1.18 (C66)A1.2 B1.18 (C5) A1.2 B1.18 (C66)
A1.2 B1.18 (C7) A1.2 B1.18 (C71)A1.2 B1.18 (C7) A1.2 B1.18 (C71)
A1.2 B1.18 (C9) A1.2 B1.18 (C74)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.18 (C9) A1.2 B1.18 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.19 (C1) A1.2 B1.19 (C59)A1.2 B1.19 (C1) A1.2 B1.19 (C59)
A1.2 B1.19 (C2) A1.2 B1.19 (C60)A1.2 B1.19 (C2) A1.2 B1.19 (C60)
A1.2 B1.19 (C3) A1.2 B1.19 (C61)A1.2 B1.19 (C3) A1.2 B1.19 (C61)
A1.2 B1.19 (C4) A1.2 B1.19 (C62)A1.2 B1.19 (C4) A1.2 B1.19 (C62)
A1.2 B1.19 (C5) A1.2 B1.19 (C65)A1.2 B1.19 (C5) A1.2 B1.19 (C65)
A1.2 B1.19 (C7) A1.2 B1.19 (C66)A1.2 B1.19 (C7) A1.2 B1.19 (C66)
A1.2 B1.19 (C9) A1.2 B1.19 (C71)A1.2 B1.19 (C9) A1.2 B1.19 (C71)
A1.2 B1.19 (C12) A1.2 B1.19 (C74)A1.2 B1.19 (C12) A1.2 B1.19 (C74)
A1.2 B1.19 (C13) A1.2 B1.20 (C1)A1.2 B1.19 (C13) A1.2 B1.20 (C1)
A1.2 B1.19 (C15) A1.2 B1.20 (C2)A1.2 B1.19 (C15) A1.2 B1.20 (C2)
A1.2 B1.19 (C18) A1.2 B1.20 (C3)A1.2 B1.19 (C18) A1.2 B1.20 (C3)
A1.2 B1.19 (C21) A1.2 B1.20 (C4)A1.2 B1.19 (C21) A1.2 B1.20 (C4)
A1.2 B1.19 (C22) A1.2 B1.20 (C5)A1.2 B1.19 (C22) A1.2 B1.20 (C5)
A1.2 B1.19 (C23) A1.2 B1.20 (C7)A1.2 B1.19 (C23) A1.2 B1.20 (C7)
A1.2 B1.19 (C24) A1.2 B1.20 (C9)A1.2 B1.19 (C24) A1.2 B1.20 (C9)
A1.2 B1.19 (C25) A1.2 B1.20 (C12)A1.2 B1.19 (C25) A1.2 B1.20 (C12)
A1.2 B1.19 (C25) A1.2 B1.20 (C13)A1.2 B1.19 (C25) A1.2 B1.20 (C13)
A1.2 B1.19 (C28) A1.2 B1.20 (C15)A1.2 B1.19 (C28) A1.2 B1.20 (C15)
A1.2 B1.19 (C32) A1.2 B1.20 (C18)A1.2 B1.19 (C32) A1.2 B1.20 (C18)
A1.2 B1.19 (C37) A1.2 B1.20 (C21)A1.2 B1.19 (C37) A1.2 B1.20 (C21)
A1.2 B1.19 (C40) A1.2 B1.20 (C22)A1.2 B1.19 (C40) A1.2 B1.20 (C22)
A1.2 B1.19 (C41) A1.2 B1.20 (C23)A1.2 B1.19 (C41) A1.2 B1.20 (C23)
A1.2 B1.19 (C42) A1.2 B1.20 (C24)A1.2 B1.19 (C42) A1.2 B1.20 (C24)
A1.2 B1.19 (C43) A1.2 B1.20 (C25)A1.2 B1.19 (C43) A1.2 B1.20 (C25)
A1.2 B1.19 (C51) A1.2 B1.20 (C25)A1.2 B1.19 (C51) A1.2 B1.20 (C25)
A1.2 B1.19 (C52) A1.2 B1.20 (C28)A1.2 B1.19 (C52) A1.2 B1.20 (C28)
A1.2 B1.19 (C57) A1.2 B1.20 (C32)A1.2 B1.19 (C57) A1.2 B1.20 (C32)
A1.2 B1.19 (C58) A1.2 B1.20 (C37)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.19 (C58) A1.2 B1.20 (C37) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.20 (C40) A1.2 B1.21 (C22)A1.2 B1.20 (C40) A1.2 B1.21 (C22)
A1.2 B1.20 (C41) A1.2 B1.21 (C23)A1.2 B1.20 (C41) A1.2 B1.21 (C23)
A1.2 B1.20 (C42) A1.2 B1.21 (C24)A1.2 B1.20 (C42) A1.2 B1.21 (C24)
A1.2 B1.20 (C43) A1.2 B1.21 (C25)A1.2 B1.20 (C43) A1.2 B1.21 (C25)
A1.2 B1.20 (C51) A1.2 B1.21 (C25)A1.2 B1.20 (C51) A1.2 B1.21 (C25)
A1.2 B1.20 (C52) A1.2 B1.21 (C28)A1.2 B1.20 (C52) A1.2 B1.21 (C28)
A1.2 B1.20 (C57) A1.2 B1.21 (C32)A1.2 B1.20 (C57) A1.2 B1.21 (C32)
A1.2 B1.20 (C58) A1.2 B1.21 (C37)A1.2 B1.20 (C58) A1.2 B1.21 (C37)
A1.2 B1.20 (C59) A1.2 B1.21 (C40)A1.2 B1.20 (C59) A1.2 B1.21 (C40)
A1.2 B1.20 (C60) A1.2 B1.21 (C41)A1.2 B1.20 (C60) A1.2 B1.21 (C41)
A1.2 B1.20 (C61) A1.2 B1.21 (C42)A1.2 B1.20 (C61) A1.2 B1.21 (C42)
A1.2 B1.20 (C62) A1.2 B1.21 (C43)A1.2 B1.20 (C62) A1.2 B1.21 (C43)
A1.2 B1.20 (C65) A1.2 B1.21 (C51)A1.2 B1.20 (C65) A1.2 B1.21 (C51)
A1.2 B1.20 (C66) A1.2 B1.21 (C52)A1.2 B1.20 (C66) A1.2 B1.21 (C52)
A1.2 B1.20 (C71) A1.2 B1.21 (C57)A1.2 B1.20 (C71) A1.2 B1.21 (C57)
A1.2 B1.20 (C74) A1.2 B1.21 (C58)A1.2 B1.20 (C74) A1.2 B1.21 (C58)
A1.2 B1.21 (C1) A1.2 B1.21 (C59)A1.2 B1.21 (C1) A1.2 B1.21 (C59)
A1.2 B1.21 (C2) A1.2 B1.21 (C60)A1.2 B1.21 (C2) A1.2 B1.21 (C60)
A1.2 B1.21 (C3) A1.2 B1.21 (C61)A1.2 B1.21 (C3) A1.2 B1.21 (C61)
A1.2 B1.21 (C4) A1.2 B1.21 (C62)A1.2 B1.21 (C4) A1.2 B1.21 (C62)
A1.2 B1.21 (C5) A1.2 B1.21 (C65)A1.2 B1.21 (C5) A1.2 B1.21 (C65)
A1.2 B1.21 (C7) A1.2 B1.21 (C66)A1.2 B1.21 (C7) A1.2 B1.21 (C66)
A1.2 B1.21 (C9) A1.2 B1.21 (C71)A1.2 B1.21 (C9) A1.2 B1.21 (C71)
A1.2 B1.21 (C12) A1.2 B1.21 (C74)A1.2 B1.21 (C12) A1.2 B1.21 (C74)
A1.2 B1.21 (C13) A1.2 B1.22 (C1)A1.2 B1.21 (C13) A1.2 B1.22 (C1)
A1.2 B1.21 (C15) A1.2 B1.22 (C2)A1.2 B1.21 (C15) A1.2 B1.22 (C2)
A1.2 B1.21 (C18) A1.2 B1.22 (C3)A1.2 B1.21 (C18) A1.2 B1.22 (C3)
A1.2 B1.21 (C21) A1.2 B1.22 (C4)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.21 (C21) A1.2 B1.22 (C4) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.22 (C5) A1.2 B1.22 (C65)A1.2 B1.22 (C5) A1.2 B1.22 (C65)
A1.2 B1.22 (C7) A1.2 B1.22 (C66)A1.2 B1.22 (C7) A1.2 B1.22 (C66)
A1.2 B1.22 (C9) A1.2 B1.22 (C71)A1.2 B1.22 (C9) A1.2 B1.22 (C71)
A1.2 B1.22 (C12) A1.2 B1.22 (C74)A1.2 B1.22 (C12) A1.2 B1.22 (C74)
A1.2 B1.22 (C13) A1.2 B1.23 (C1)A1.2 B1.22 (C13) A1.2 B1.23 (C1)
A1.2 B1.22 (C15) A1.2 B1.23 (C2)A1.2 B1.22 (C15) A1.2 B1.23 (C2)
A1.2 B1.22 (C18) A1.2 B1.23 (C3)A1.2 B1.22 (C18) A1.2 B1.23 (C3)
A1.2 B1.22 (C21) A1.2 B1.23 (C4)A1.2 B1.22 (C21) A1.2 B1.23 (C4)
A1.2 B1.22 (C22) A1.2 B1.23 (C5)A1.2 B1.22 (C22) A1.2 B1.23 (C5)
A1.2 B1.22 (C23) A1.2 B1.23 (C7)A1.2 B1.22 (C23) A1.2 B1.23 (C7)
A1.2 B1.22 (C24) A1.2 B1.23 (C9)A1.2 B1.22 (C24) A1.2 B1.23 (C9)
A1.2 B1.22 (C25) A1.2 B1.23 (C12)A1.2 B1.22 (C25) A1.2 B1.23 (C12)
A1.2 B1.22 (C25) A1.2 B1.23 (C13)A1.2 B1.22 (C25) A1.2 B1.23 (C13)
A1.2 B1.22 (C28) A1.2 B1.23 (C15)A1.2 B1.22 (C28) A1.2 B1.23 (C15)
A1.2 B1.22 (C32) A1.2 B1.23 (C18)A1.2 B1.22 (C32) A1.2 B1.23 (C18)
A1.2 B1.22 (C37) A1.2 B1.23 (C21)A1.2 B1.22 (C37) A1.2 B1.23 (C21)
A1.2 B1.22 (C40) A1.2 B1.23 (C22)A1.2 B1.22 (C40) A1.2 B1.23 (C22)
A1.2 B1.22 (C41) A1.2 B1.23 (C23)A1.2 B1.22 (C41) A1.2 B1.23 (C23)
A1.2 B1.22 (C42) A1.2 B1.23 (C24)A1.2 B1.22 (C42) A1.2 B1.23 (C24)
A1.2 B1.22 (C43) A1.2 B1.23 (C25)A1.2 B1.22 (C43) A1.2 B1.23 (C25)
A1.2 B1.22 (C51) A1.2 B1.23 (C25)A1.2 B1.22 (C51) A1.2 B1.23 (C25)
A1.2 B1.22 (C52) A1.2 B1.23 (C28)A1.2 B1.22 (C52) A1.2 B1.23 (C28)
A1.2 B1.22 (C57) A1.2 B1.23 (C32)A1.2 B1.22 (C57) A1.2 B1.23 (C32)
A1.2 B1.22 (C58) A1.2 B1.23 (C37)A1.2 B1.22 (C58) A1.2 B1.23 (C37)
A1.2 B1.22 (C59) A1.2 B1.23 (C40)A1.2 B1.22 (C59) A1.2 B1.23 (C40)
A1.2 B1.22 (C60) A1.2 B1.23 (C41)A1.2 B1.22 (C60) A1.2 B1.23 (C41)
A1.2 B1.22 (C61) A1.2 B1.23 (C42)A1.2 B1.22 (C61) A1.2 B1.23 (C42)
A1.2 B1.22 (C62) A1.2 B1.23 (C43)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.2 B1.22 (C62) A1.2 B1.23 (C43) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.2 B1.23 (C51) A1.3 B1.0 (C25)A1.2 B1.23 (C51) A1.3 B1.0 (C25)
A1.2 B1.23 (C52) A1.3 B1.0 (C28)A1.2 B1.23 (C52) A1.3 B1.0 (C28)
A1.2 B1.23 (C57) A1.3 B1.0 (C32)A1.2 B1.23 (C57) A1.3 B1.0 (C32)
A1.2 B1.23 (C58) A1.3 B1.0 (C37)A1.2 B1.23 (C58) A1.3 B1.0 (C37)
A1.2 B1.23 (C59) A1.3 B1.0 (C40)A1.2 B1.23 (C59) A1.3 B1.0 (C40)
A1.2 B1.23 (C60) A1.3 B1.0 (C41)A1.2 B1.23 (C60) A1.3 B1.0 (C41)
A1.2 B1.23 (C61) A1.3 B1.0 (C42)A1.2 B1.23 (C61) A1.3 B1.0 (C42)
A1.2 B1.23 (C62) A1.3 B1.0 (C43)A1.2 B1.23 (C62) A1.3 B1.0 (C43)
A1.2 B1.23 (C65) A1.3 B1.0 (C51)A1.2 B1.23 (C65) A1.3 B1.0 (C51)
A1.2 B1.23 (C66) A1.3 B1.0 (C52)A1.2 B1.23 (C66) A1.3 B1.0 (C52)
A1.2 B1.23 (C71) A1.3 B1.0 (C57)A1.2 B1.23 (C71) A1.3 B1.0 (C57)
A1.2 B1.23 (C74) A1.3 B1.0 (C58)A1.2 B1.23 (C74) A1.3 B1.0 (C58)
A1.3 B1.0 (C1) A1.3 B1.0 (C59)A1.3 B1.0 (C1) A1.3 B1.0 (C59)
A1.3 B1.0 (C2) A1.3 B1.0 (C60)A1.3 B1.0 (C2) A1.3 B1.0 (C60)
A1.3 B1.0 (C3) A1.3 B1.0 (C61)A1.3 B1.0 (C3) A1.3 B1.0 (C61)
A1.3 B1.0 (C4) A1.3 B1.0 (C62)A1.3 B1.0 (C4) A1.3 B1.0 (C62)
A1.3 B1.0 (C5) A1.3 B1.0 (C65)A1.3 B1.0 (C5) A1.3 B1.0 (C65)
A1.3 B1.0 (C7) A1.3 B1.0 (C66)A1.3 B1.0 (C7) A1.3 B1.0 (C66)
A1.3 B1.0 (C9) A1.3 B1.0 (C71)A1.3 B1.0 (C9) A1.3 B1.0 (C71)
A1.3 B1.0 (C12) A1.3 B1.0 (C74)A1.3 B1.0 (C12) A1.3 B1.0 (C74)
A1.3 B1.0 (C13) A1.3 B1.1 (C1)A1.3 B1.0 (C13) A1.3 B1.1 (C1)
A1.3 B1.0 (C15) A1.3 B1.1 (C2)A1.3 B1.0 (C15) A1.3 B1.1 (C2)
A1.3 B1.0 (C18) A1.3 B1.1 (C3)A1.3 B1.0 (C18) A1.3 B1.1 (C3)
A1.3 B1.0 (C21) A1.3 B1.1 (C4)A1.3 B1.0 (C21) A1.3 B1.1 (C4)
A1.3 B1.0 (C22) A1.3 B1.1 (C5)A1.3 B1.0 (C22) A1.3 B1.1 (C5)
A1.3 B1.0 (C23) A1.3 B1.1 (C7)A1.3 B1.0 (C23) A1.3 B1.1 (C7)
A1.3 B1.0 (C24) A1.3 B1.1 (C9)A1.3 B1.0 (C24) A1.3 B1.1 (C9)
A1.3 B1.0 (C25) A1.3 B1.1 (C12)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.0 (C25) A1.3 B1.1 (C12) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.1 (C13) A1.3 B1.2 (C2)A1.3 B1.1 (C13) A1.3 B1.2 (C2)
A1.3 B1.1 (C15) A1.3 B1.2 (C3)A1.3 B1.1 (C15) A1.3 B1.2 (C3)
A1.3 B1.1 (C18) A1.3 B1.2 (C4)A1.3 B1.1 (C18) A1.3 B1.2 (C4)
A1.3 B1.1 (C21) A1.3 B1.2 (C5)A1.3 B1.1 (C21) A1.3 B1.2 (C5)
A1.3 B1.1 (C22) A1.3 B1.2 (C7)A1.3 B1.1 (C22) A1.3 B1.2 (C7)
A1.3 B1.1 (C23) A1.3 B1.2 (C9)A1.3 B1.1 (C23) A1.3 B1.2 (C9)
A1.3 B1.1 (C24) A1.3 B1.2 (C12)A1.3 B1.1 (C24) A1.3 B1.2 (C12)
A1.3 B1.1 (C25) A1.3 B1.2 (C13)A1.3 B1.1 (C25) A1.3 B1.2 (C13)
A1.3 B1.1 (C28) A1.3 B1.2 (C15)A1.3 B1.1 (C28) A1.3 B1.2 (C15)
A1.3 B1.1 (C32) A1.3 B1.2 (C18)A1.3 B1.1 (C32) A1.3 B1.2 (C18)
A1.3 B1.1 (C37) A1.3 B1.2 (C21)A1.3 B1.1 (C37) A1.3 B1.2 (C21)
A1.3 B1.1 (C40) A1.3 B1.2 (C22)A1.3 B1.1 (C40) A1.3 B1.2 (C22)
A1.3 B1.1 (C41) A1.3 B1.2 (C23)A1.3 B1.1 (C41) A1.3 B1.2 (C23)
A1.3 B1.1 (C42) A1.3 B1.2 (C24)A1.3 B1.1 (C42) A1.3 B1.2 (C24)
A1.3 B1.1 (C43) A1.3 B1.2 (C25)A1.3 B1.1 (C43) A1.3 B1.2 (C25)
A1.3 B1.1 (C51) A1.3 B1.2 (C28)A1.3 B1.1 (C51) A1.3 B1.2 (C28)
A1.3 B1.1 (C52) A1.3 B1.2 (C32)A1.3 B1.1 (C52) A1.3 B1.2 (C32)
A1.3 B1.1 (C57) A1.3 B1.2 (C37)A1.3 B1.1 (C57) A1.3 B1.2 (C37)
A1.3 B1.1 (C58) A1.3 B1.2 (C40)A1.3 B1.1 (C58) A1.3 B1.2 (C40)
A1.3 B1.1 (C59) A1.3 B1.2 (C41)A1.3 B1.1 (C59) A1.3 B1.2 (C41)
A1.3 B1.1 (C60) A1.3 B1.2 (C42)A1.3 B1.1 (C60) A1.3 B1.2 (C42)
A1.3 B1.1 (C61) A1.3 B1.2 (C43)A1.3 B1.1 (C61) A1.3 B1.2 (C43)
A1.3 B1.1 (C62) A1.3 B1.2 (C51)A1.3 B1.1 (C62) A1.3 B1.2 (C51)
A1.3 B1.1 (C65) A1.3 B1.2 (C52)A1.3 B1.1 (C65) A1.3 B1.2 (C52)
A1.3 B1.1 (C66) A1.3 B1.2 (C57)A1.3 B1.1 (C66) A1.3 B1.2 (C57)
A1.3 B1.1 (C71) A1.3 B1.2 (C58)A1.3 B1.1 (C71) A1.3 B1.2 (C58)
A1.3 B1.1 (C74) A1.3 B1.2 (C59)A1.3 B1.1 (C74) A1.3 B1.2 (C59)
A1.3 B1.2 (C1) A1.3 B1.2 (C60)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.2 (C1) A1.3 B1.2 (C60) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.2 (C61) A1.3 B1.3 (C43)A1.3 B1.2 (C61) A1.3 B1.3 (C43)
A1.3 B1.2 (C62) A1.3 B1.3 (C51)A1.3 B1.2 (C62) A1.3 B1.3 (C51)
A1.3 B1.2 (C65) A1.3 B1.3 (C52)A1.3 B1.2 (C65) A1.3 B1.3 (C52)
A1.3 B1.2 (C66) A1.3 B1.3 (C57)A1.3 B1.2 (C66) A1.3 B1.3 (C57)
A1.3 B1.2 (C71) A1.3 B1.3 (C58)A1.3 B1.2 (C71) A1.3 B1.3 (C58)
A1.3 B1.2 (C74) A1.3 B1.3 (C59)A1.3 B1.2 (C74) A1.3 B1.3 (C59)
A1.3 B1.3 (C1) A1.3 B1.3 (C60)A1.3 B1.3 (C1) A1.3 B1.3 (C60)
A1.3 B1.3 (C2) A1.3 B1.3 (C61)A1.3 B1.3 (C2) A1.3 B1.3 (C61)
A1.3 B1.3 (C3) A1.3 B1.3 (C62)A1.3 B1.3 (C3) A1.3 B1.3 (C62)
A1.3 B1.3 (C4) A1.3 B1.3 (C65)A1.3 B1.3 (C4) A1.3 B1.3 (C65)
A1.3 B1.3 (C5) A1.3 B1.3 (C66)A1.3 B1.3 (C5) A1.3 B1.3 (C66)
A1.3 B1.3 (C7) A1.3 B1.3 (C71)A1.3 B1.3 (C7) A1.3 B1.3 (C71)
A1.3 B1.3 (C9) A1.3 B1.3 (C74)A1.3 B1.3 (C9) A1.3 B1.3 (C74)
A1.3 B1.3 (C12) A1.3 B1.4 (C1)A1.3 B1.3 (C12) A1.3 B1.4 (C1)
A1.3 B1.3 (C13) A1.3 B1.4 (C2)A1.3 B1.3 (C13) A1.3 B1.4 (C2)
A1.3 B1.3 (C15) A1.3 B1.4 (C3)A1.3 B1.3 (C15) A1.3 B1.4 (C3)
A1.3 B1.3 (C18) A1.3 B1.4 (C4)A1.3 B1.3 (C18) A1.3 B1.4 (C4)
A1.3 B1.3 (C21) A1.3 B1.4 (C5)A1.3 B1.3 (C21) A1.3 B1.4 (C5)
A1.3 B1.3 (C22) A1.3 B1.4 (C7)A1.3 B1.3 (C22) A1.3 B1.4 (C7)
A1.3 B1.3 (C23) A1.3 B1.4 (C9)A1.3 B1.3 (C23) A1.3 B1.4 (C9)
A1.3 B1.3 (C24) A1.3 B1.4 (C12)A1.3 B1.3 (C24) A1.3 B1.4 (C12)
A1.3 B1.3 (C25) A1.3 B1.4 (C13)A1.3 B1.3 (C25) A1.3 B1.4 (C13)
A1.3 B1.3 (C28) A1.3 B1.4 (C15)A1.3 B1.3 (C28) A1.3 B1.4 (C15)
A1.3 B1.3 (C32) A1.3 B1.4 (C18)A1.3 B1.3 (C32) A1.3 B1.4 (C18)
A1.3 B1.3 (C37) A1.3 B1.4 (C21)A1.3 B1.3 (C37) A1.3 B1.4 (C21)
A1.3 B1.3 (C40) A1.3 B1.4 (C22)A1.3 B1.3 (C40) A1.3 B1.4 (C22)
A1.3 B1.3 (C41) A1.3 B1.4 (C23)A1.3 B1.3 (C41) A1.3 B1.4 (C23)
A1.3 B1.3 (C42) A1.3 B1.4 (C24)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.3 (C42) A1.3 B1.4 (C24) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.4 (C25) A1.3 B1.5 (C13)A1.3 B1.4 (C25) A1.3 B1.5 (C13)
A1.3 B1.4 (C28) A1.3 B1.5 (C15)A1.3 B1.4 (C28) A1.3 B1.5 (C15)
A1.3 B1.4 (C32) A1.3 B1.5 (C18)A1.3 B1.4 (C32) A1.3 B1.5 (C18)
A1.3 B1.4 (C37) A1.3 B1.5 (C21)A1.3 B1.4 (C37) A1.3 B1.5 (C21)
A1.3 B1.4 (C40) A1.3 B1.5 (C22)A1.3 B1.4 (C40) A1.3 B1.5 (C22)
A1.3 B1.4 (C41) A1.3 B1.5 (C23)A1.3 B1.4 (C41) A1.3 B1.5 (C23)
A1.3 B1.4 (C42) A1.3 B1.5 (C24)A1.3 B1.4 (C42) A1.3 B1.5 (C24)
A1.3 B1.4 (C43) A1.3 B1.5 (C25)A1.3 B1.4 (C43) A1.3 B1.5 (C25)
A1.3 B1.4 (C51) A1.3 B1.5 (C28)A1.3 B1.4 (C51) A1.3 B1.5 (C28)
A1.3 B1.4 (C52) A1.3 B1.5 (C32)A1.3 B1.4 (C52) A1.3 B1.5 (C32)
A1.3 B1.4 (C57) A1.3 B1.5 (C37)A1.3 B1.4 (C57) A1.3 B1.5 (C37)
A1.3 B1.4 (C58) A1.3 B1.5 (C40)A1.3 B1.4 (C58) A1.3 B1.5 (C40)
A1.3 B1.4 (C59) A1.3 B1.5 (C41)A1.3 B1.4 (C59) A1.3 B1.5 (C41)
A1.3 B1.4 (C60) A1.3 B1.5 (C42)A1.3 B1.4 (C60) A1.3 B1.5 (C42)
A1.3 B1.4 (C61) A1.3 B1.5 (C43)A1.3 B1.4 (C61) A1.3 B1.5 (C43)
A1.3 B1.4 (C62) A1.3 B1.5 (C51)A1.3 B1.4 (C62) A1.3 B1.5 (C51)
A1.3 B1.4 (C65) A1.3 B1.5 (C52)A1.3 B1.4 (C65) A1.3 B1.5 (C52)
A1.3 B1.4 (C66) A1.3 B1.5 (C57)A1.3 B1.4 (C66) A1.3 B1.5 (C57)
A1.3 B1.4 (C71) A1.3 B1.5 (C58)A1.3 B1.4 (C71) A1.3 B1.5 (C58)
A1.3 B1.4 (C74) A1.3 B1.5 (C59)A1.3 B1.4 (C74) A1.3 B1.5 (C59)
A1.3 B1.5 (C1) A1.3 B1.5 (C60)A1.3 B1.5 (C1) A1.3 B1.5 (C60)
A1.3 B1.5 (C2) A1.3 B1.5 (C61)A1.3 B1.5 (C2) A1.3 B1.5 (C61)
A1.3 B1.5 (C3) A1.3 B1.5 (C62)A1.3 B1.5 (C3) A1.3 B1.5 (C62)
A1.3 B1.5 (C4) A1.3 B1.5 (C62)A1.3 B1.5 (C4) A1.3 B1.5 (C62)
A1.3 B1.5 (C5) A1.3 B1.5 (C65)A1.3 B1.5 (C5) A1.3 B1.5 (C65)
A1.3 B1.5 (C7) A1.3 B1.5 (C66)A1.3 B1.5 (C7) A1.3 B1.5 (C66)
A1.3 B1.5 (C9) A1.3 B1.5 (C71)A1.3 B1.5 (C9) A1.3 B1.5 (C71)
A1.3 B1.5 (C12) A1.3 B1.5 (C74)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.5 (C12) A1.3 B1.5 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.6 (C1) A1.3 B1.6 (C58)A1.3 B1.6 (C1) A1.3 B1.6 (C58)
A1.3 B1.6 (C2) A1.3 B1.6 (C59)A1.3 B1.6 (C2) A1.3 B1.6 (C59)
A1.3 B1.6 (C3) A1.3 B1.6 (C60)A1.3 B1.6 (C3) A1.3 B1.6 (C60)
A1.3 B1.6 (C4) A1.3 B1.6 (C61)A1.3 B1.6 (C4) A1.3 B1.6 (C61)
A1.3 B1.6 (C5) A1.3 B1.6 (C62)A1.3 B1.6 (C5) A1.3 B1.6 (C62)
A1.3 B1.6 (C7) A1.3 B1.6 (C62)A1.3 B1.6 (C7) A1.3 B1.6 (C62)
A1.3 B1.6 (C9) A1.3 B1.6 (C65)A1.3 B1.6 (C9) A1.3 B1.6 (C65)
A1.3 B1.6 (C12) A1.3 B1.6 (C66)A1.3 B1.6 (C12) A1.3 B1.6 (C66)
A1.3 B1.6 (C13) A1.3 B1.6 (C71)A1.3 B1.6 (C13) A1.3 B1.6 (C71)
A1.3 B1.6 (C15) A1.3 B1.6 (C74)A1.3 B1.6 (C15) A1.3 B1.6 (C74)
A1.3 B1.6 (C18) A1.3 B1.7 (C1)A1.3 B1.6 (C18) A1.3 B1.7 (C1)
A1.3 B1.6 (C21) A1.3 B1.7 (C2)A1.3 B1.6 (C21) A1.3 B1.7 (C2)
A1.3 B1.6 (C22) A1.3 B1.7 (C3)A1.3 B1.6 (C22) A1.3 B1.7 (C3)
A1.3 B1.6 (C23) A1.3 B1.7 (C4)A1.3 B1.6 (C23) A1.3 B1.7 (C4)
A1.3 B1.6 (C24) A1.3 B1.7 (C5)A1.3 B1.6 (C24) A1.3 B1.7 (C5)
A1.3 B1.6 (C25) A1.3 B1.7 (C7)A1.3 B1.6 (C25) A1.3 B1.7 (C7)
A1.3 B1.6 (C28) A1.3 B1.7 (C9)A1.3 B1.6 (C28) A1.3 B1.7 (C9)
A1.3 B1.6 (C32) A1.3 B1.7 (C12)A1.3 B1.6 (C32) A1.3 B1.7 (C12)
A1.3 B1.6 (C37) A1.3 B1.7 (C13)A1.3 B1.6 (C37) A1.3 B1.7 (C13)
A1.3 B1.6 (C40) A1.3 B1.7 (C15)A1.3 B1.6 (C40) A1.3 B1.7 (C15)
A1.3 B1.6 (C41) A1.3 B1.7 (C18)A1.3 B1.6 (C41) A1.3 B1.7 (C18)
A1.3 B1.6 (C42) A1.3 B1.7 (C21)A1.3 B1.6 (C42) A1.3 B1.7 (C21)
A1.3 B1.6 (C43) A1.3 B1.7 (C22)A1.3 B1.6 (C43) A1.3 B1.7 (C22)
A1.3 B1.6 (C51) A1.3 B1.7 (C23)A1.3 B1.6 (C51) A1.3 B1.7 (C23)
A1.3 B1.6 (C52) A1.3 B1.7 (C24)A1.3 B1.6 (C52) A1.3 B1.7 (C24)
A1.3 B1.6 (C57) A1.3 B1.7 (C25)A1.3 B1.6 (C57) A1.3 B1.7 (C25)
A1.3 B1.6 (C58) A1.3 B1.7 (C28)A1.3 B1.6 (C58) A1.3 B1.7 (C28)
A1.3 B1.6 (C57) A1.3 B1.7 (C32)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.6 (C57) A1.3 B1.7 (C32) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.7 (C37) A1.3 B1.8 (C21)A1.3 B1.7 (C37) A1.3 B1.8 (C21)
A1.3 B1.7 (C40) A1.3 B1.8 (C22)A1.3 B1.7 (C40) A1.3 B1.8 (C22)
A1.3 B1.7 (C41) A1.3 B1.8 (C23)A1.3 B1.7 (C41) A1.3 B1.8 (C23)
A1.3 B1.7 (C42) A1.3 B1.8 (C24)A1.3 B1.7 (C42) A1.3 B1.8 (C24)
A1.3 B1.7 (C43) A1.3 B1.8 (C25)A1.3 B1.7 (C43) A1.3 B1.8 (C25)
A1.3 B1.7 (C51) A1.3 B1.8 (C28)A1.3 B1.7 (C51) A1.3 B1.8 (C28)
A1.3 B1.7 (C52) A1.3 B1.8 (C32)A1.3 B1.7 (C52) A1.3 B1.8 (C32)
A1.3 B1.7 (C57) A1.3 B1.8 (C37)A1.3 B1.7 (C57) A1.3 B1.8 (C37)
A1.3 B1.7 (C58) A1.3 B1.8 (C40)A1.3 B1.7 (C58) A1.3 B1.8 (C40)
A1.3 B1.7 (C59) A1.3 B1.8 (C41)A1.3 B1.7 (C59) A1.3 B1.8 (C41)
A1.3 B1.7 (C60) A1.3 B1.8 (C42)A1.3 B1.7 (C60) A1.3 B1.8 (C42)
A1.3 B1.7 (C61) A1.3 B1.8 (C43)A1.3 B1.7 (C61) A1.3 B1.8 (C43)
A1.3 B1.7 (C62) A1.3 B1.8 (C43)A1.3 B1.7 (C62) A1.3 B1.8 (C43)
A1.3 B1.7 (C65) A1.3 B1.8 (C51)A1.3 B1.7 (C65) A1.3 B1.8 (C51)
A1.3 B1.7 (C66) A1.3 B1.8 (C52)A1.3 B1.7 (C66) A1.3 B1.8 (C52)
A1.3 B1.7 (C71) A1.3 B1.8 (C57)A1.3 B1.7 (C71) A1.3 B1.8 (C57)
A1.3 B1.7 (C74) A1.3 B1.8 (C58)A1.3 B1.7 (C74) A1.3 B1.8 (C58)
A1.3 B1.8 (C1) A1.3 B1.8 (C59)A1.3 B1.8 (C1) A1.3 B1.8 (C59)
A1.3 B1.8 (C2) A1.3 B1.8 (C60)A1.3 B1.8 (C2) A1.3 B1.8 (C60)
A1.3 B1.8 (C3) A1.3 B1.8 (C61)A1.3 B1.8 (C3) A1.3 B1.8 (C61)
A1.3 B1.8 (C4) A1.3 B1.8 (C62)A1.3 B1.8 (C4) A1.3 B1.8 (C62)
A1.3 B1.8 (C5) A1.3 B1.8 (C65)A1.3 B1.8 (C5) A1.3 B1.8 (C65)
A1.3 B1.8 (C7) A1.3 B1.8 (C66)A1.3 B1.8 (C7) A1.3 B1.8 (C66)
A1.3 B1.8 (C9) A1.3 B1.8 (C71)A1.3 B1.8 (C9) A1.3 B1.8 (C71)
A1.3 B1.8 (C12) A1.3 B1.8 (C74)A1.3 B1.8 (C12) A1.3 B1.8 (C74)
A1.3 B1.8 (C13) A1.3 B1.9 (C1)A1.3 B1.8 (C13) A1.3 B1.9 (C1)
A1.3 B1.8 (C15) A1.3 B1.9 (C2)A1.3 B1.8 (C15) A1.3 B1.9 (C2)
A1.3 B1.8 (C18) A1.3 B1.9 (C3)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.8 (C18) A1.3 B1.9 (C3) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.9 (C4) A1.3 B1.9 (C65)A1.3 B1.9 (C4) A1.3 B1.9 (C65)
A1.3 B1.9 (C5) A1.3 B1.9 (C66)A1.3 B1.9 (C5) A1.3 B1.9 (C66)
A1.3 B1.9 (C7) A1.3 B1.9 (C71)A1.3 B1.9 (C7) A1.3 B1.9 (C71)
A1.3 B1.9 (C9) A1.3 B1.9 (C74)A1.3 B1.9 (C9) A1.3 B1.9 (C74)
A1.3 B1.9 (C12) A1.3 B1.10 (C1)A1.3 B1.9 (C12) A1.3 B1.10 (C1)
A1.3 B1.9 (C13) A1.3 B1.10 (C2)A1.3 B1.9 (C13) A1.3 B1.10 (C2)
A1.3 B1.9 (C15) A1.3 B1.10 (C3)A1.3 B1.9 (C15) A1.3 B1.10 (C3)
A1.3 B1.9 (C18) A1.3 B1.10 (C4)A1.3 B1.9 (C18) A1.3 B1.10 (C4)
A1.3 B1.9 (C21) A1.3 B1.10 (C5)A1.3 B1.9 (C21) A1.3 B1.10 (C5)
A1.3 B1.9 (C22) A1.3 B1.10 (C7)A1.3 B1.9 (C22) A1.3 B1.10 (C7)
A1.3 B1.9 (C23) A1.3 B1.10 (C9)A1.3 B1.9 (C23) A1.3 B1.10 (C9)
A1.3 B1.9 (C24) A1.3 B1.10 (C12)A1.3 B1.9 (C24) A1.3 B1.10 (C12)
A1.3 B1.9 (C25) A1.3 B1.10 (C13)A1.3 B1.9 (C25) A1.3 B1.10 (C13)
A1.3 B1.9 (C28) A1.3 B1.10 (C15)A1.3 B1.9 (C28) A1.3 B1.10 (C15)
A1.3 B1.9 (C32) A1.3 B1.10 (C18)A1.3 B1.9 (C32) A1.3 B1.10 (C18)
A1.3 B1.9 (C37) A1.3 B1.10 (C21)A1.3 B1.9 (C37) A1.3 B1.10 (C21)
A1.3 B1.9 (C40) A1.3 B1.10 (C22)A1.3 B1.9 (C40) A1.3 B1.10 (C22)
A1.3 B1.9 (C41) A1.3 B1.10 (C23)A1.3 B1.9 (C41) A1.3 B1.10 (C23)
A1.3 B1.9 (C42) A1.3 B1.10 (C24)A1.3 B1.9 (C42) A1.3 B1.10 (C24)
A1.3 B1.9 (C43) A1.3 B1.10 (C25)A1.3 B1.9 (C43) A1.3 B1.10 (C25)
A1.3 B1.9 (C51) A1.3 B1.10 (C28)A1.3 B1.9 (C51) A1.3 B1.10 (C28)
A1.3 B1.9 (C52) A1.3 B1.10 (C32)A1.3 B1.9 (C52) A1.3 B1.10 (C32)
A1.3 B1.9 (C57) A1.3 B1.10 (C37)A1.3 B1.9 (C57) A1.3 B1.10 (C37)
A1.3 B1.9 (C58) A1.3 B1.10 (C40)A1.3 B1.9 (C58) A1.3 B1.10 (C40)
A1.3 B1.9 (C59) A1.3 B1.10 (C41)A1.3 B1.9 (C59) A1.3 B1.10 (C41)
A1.3 B1.9 (C60) A1.3 B1.10 (C42)A1.3 B1.9 (C60) A1.3 B1.10 (C42)
A1.3 B1.9 (C61) A1.3 B1.10 (C43)A1.3 B1.9 (C61) A1.3 B1.10 (C43)
A1.3 B1.9 (C62) A1.3 B1.10 (C51)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.9 (C62) A1.3 B1.10 (C51) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.10 (C52) A1.3 B1.11 (C32)A1.3 B1.10 (C52) A1.3 B1.11 (C32)
A1.3 B1.10 (C57) A1.3 B1.11 (C37)A1.3 B1.10 (C57) A1.3 B1.11 (C37)
A1.3 B1.10 (C58) A1.3 B1.11 (C40)A1.3 B1.10 (C58) A1.3 B1.11 (C40)
A1.3 B1.10 (C59) A1.3 B1.11 (C41)A1.3 B1.10 (C59) A1.3 B1.11 (C41)
A1.3 B1.10 (C60) A1.3 B1.11 (C42)A1.3 B1.10 (C60) A1.3 B1.11 (C42)
A1.3 B1.10 (C61) A1.3 B1.11 (C43)A1.3 B1.10 (C61) A1.3 B1.11 (C43)
A1.3 B1.10 (C62) A1.3 B1.11 (C51)A1.3 B1.10 (C62) A1.3 B1.11 (C51)
A1.3 B1.10 (C65) A1.3 B1.11 (C52)A1.3 B1.10 (C65) A1.3 B1.11 (C52)
A1.3 B1.10 (C66) A1.3 B1.11 (C57)A1.3 B1.10 (C66) A1.3 B1.11 (C57)
A1.3 B1.10 (C71) A1.3 B1.11 (C58)A1.3 B1.10 (C71) A1.3 B1.11 (C58)
A1.3 B1.10 (C74) A1.3 B1.11 (C59)A1.3 B1.10 (C74) A1.3 B1.11 (C59)
A1.3 B1.11 (C1) A1.3 B1.11 (C60)A1.3 B1.11 (C1) A1.3 B1.11 (C60)
A1.3 B1.11 (C2) A1.3 B1.11 (C61)A1.3 B1.11 (C2) A1.3 B1.11 (C61)
A1.3 B1.11 (C3) A1.3 B1.11 (C62)A1.3 B1.11 (C3) A1.3 B1.11 (C62)
A1.3 B1.11 (C4) A1.3 B1.11 (C65)A1.3 B1.11 (C4) A1.3 B1.11 (C65)
A1.3 B1.11 (C5) A1.3 B1.11 (C66)A1.3 B1.11 (C5) A1.3 B1.11 (C66)
A1.3 B1.11 (C7) A1.3 B1.11 (C71)A1.3 B1.11 (C7) A1.3 B1.11 (C71)
A1.3 B1.11 (C9) A1.3 B1.11 (C74)A1.3 B1.11 (C9) A1.3 B1.11 (C74)
A1.3 B1.11 (C12) A1.3 B1.12 (C1)A1.3 B1.11 (C12) A1.3 B1.12 (C1)
A1.3 B1.11 (C13) A1.3 B1.12 (C2)A1.3 B1.11 (C13) A1.3 B1.12 (C2)
A1.3 B1.11 (C15) A1.3 B1.12 (C3)A1.3 B1.11 (C15) A1.3 B1.12 (C3)
A1.3 B1.11 (C18) A1.3 B1.12 (C4)A1.3 B1.11 (C18) A1.3 B1.12 (C4)
A1.3 B1.11 (C21) A1.3 B1.12 (C5)A1.3 B1.11 (C21) A1.3 B1.12 (C5)
A1.3 B1.11 (C22) A1.3 B1.12 (C7)A1.3 B1.11 (C22) A1.3 B1.12 (C7)
A1.3 B1.11 (C23) A1.3 B1.12 (C9)A1.3 B1.11 (C23) A1.3 B1.12 (C9)
A1.3 B1.11 (C24) A1.3 B1.12 (C12)A1.3 B1.11 (C24) A1.3 B1.12 (C12)
A1.3 B1.11 (C25) A1.3 B1.12 (C13)A1.3 B1.11 (C25) A1.3 B1.12 (C13)
A1.3 B1.11 (C28) A1.3 B1.12 (C15)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.11 (C28) A1.3 B1.12 (C15) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.12 (C18) A1.3 B1.13 (C4)A1.3 B1.12 (C18) A1.3 B1.13 (C4)
A1.3 B1.12 (C21) A1.3 B1.13 (C5)A1.3 B1.12 (C21) A1.3 B1.13 (C5)
A1.3 B1.12 (C22) A1.3 B1.13 (C7)A1.3 B1.12 (C22) A1.3 B1.13 (C7)
A1.3 B1.12 (C23) A1.3 B1.13 (C9)A1.3 B1.12 (C23) A1.3 B1.13 (C9)
A1.3 B1.12 (C24) A1.3 B1.13 (C12)A1.3 B1.12 (C24) A1.3 B1.13 (C12)
A1.3 B1.12 (C25) A1.3 B1.13 (C13)A1.3 B1.12 (C25) A1.3 B1.13 (C13)
A1.3 B1.12 (C28) A1.3 B1.13 (C15)A1.3 B1.12 (C28) A1.3 B1.13 (C15)
A1.3 B1.12 (C32) A1.3 B1.13 (C18)A1.3 B1.12 (C32) A1.3 B1.13 (C18)
A1.3 B1.12 (C37) A1.3 B1.13 (C21)A1.3 B1.12 (C37) A1.3 B1.13 (C21)
A1.3 B1.12 (C40) A1.3 B1.13 (C22)A1.3 B1.12 (C40) A1.3 B1.13 (C22)
A1.3 B1.12 (C41) A1.3 B1.13 (C23)A1.3 B1.12 (C41) A1.3 B1.13 (C23)
A1.3 B1.12 (C42) A1.3 B1.13 (C24)A1.3 B1.12 (C42) A1.3 B1.13 (C24)
A1.3 B1.12 (C43) A1.3 B1.13 (C25)A1.3 B1.12 (C43) A1.3 B1.13 (C25)
A1.3 B1.12 (C51) A1.3 B1.13 (C28)A1.3 B1.12 (C51) A1.3 B1.13 (C28)
A1.3 B1.12 (C52) A1.3 B1.13 (C32)A1.3 B1.12 (C52) A1.3 B1.13 (C32)
A1.3 B1.12 (C57) A1.3 B1.13 (C37)A1.3 B1.12 (C57) A1.3 B1.13 (C37)
A1.3 B1.12 (C58) A1.3 B1.13 (C40)A1.3 B1.12 (C58) A1.3 B1.13 (C40)
A1.3 B1.12 (C59) A1.3 B1.13 (C41)A1.3 B1.12 (C59) A1.3 B1.13 (C41)
A1.3 B1.12 (C60) A1.3 B1.13 (C42)A1.3 B1.12 (C60) A1.3 B1.13 (C42)
A1.3 B1.12 (C61) A1.3 B1.13 (C43)A1.3 B1.12 (C61) A1.3 B1.13 (C43)
A1.3 B1.12 (C62) A1.3 B1.13 (C51)A1.3 B1.12 (C62) A1.3 B1.13 (C51)
A1.3 B1.12 (C65) A1.3 B1.13 (C52)A1.3 B1.12 (C65) A1.3 B1.13 (C52)
A1.3 B1.12 (C66) A1.3 B1.13 (C57)A1.3 B1.12 (C66) A1.3 B1.13 (C57)
A1.3 B1.12 (C71) A1.3 B1.13 (C58)A1.3 B1.12 (C71) A1.3 B1.13 (C58)
A1.3 B1.12 (C74) A1.3 B1.13 (C59)A1.3 B1.12 (C74) A1.3 B1.13 (C59)
A1.3 B1.13 (C1) A1.3 B1.13 (C60)A1.3 B1.13 (C1) A1.3 B1.13 (C60)
A1.3 B1.13 (C2) A1.3 B1.13 (C61)A1.3 B1.13 (C2) A1.3 B1.13 (C61)
A1.3 B1.13 (C3) A1.3 B1.13 (C62)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.13 (C3) A1.3 B1.13 (C62) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.13 (C62) A1.3 B1.14 (C43)A1.3 B1.13 (C62) A1.3 B1.14 (C43)
A1.3 B1.13 (C65) A1.3 B1.14 (C51)A1.3 B1.13 (C65) A1.3 B1.14 (C51)
A1.3 B1.13 (C66) A1.3 B1.14 (C52)A1.3 B1.13 (C66) A1.3 B1.14 (C52)
A1.3 B1.13 (C71) A1.3 B1.14 (C57)A1.3 B1.13 (C71) A1.3 B1.14 (C57)
A1.3 B1.13 (C74) A1.3 B1.14 (C58)A1.3 B1.13 (C74) A1.3 B1.14 (C58)
A1.3 B1.14 (C1) A1.3 B1.14 (C59)A1.3 B1.14 (C1) A1.3 B1.14 (C59)
A1.3 B1.14 (C2) A1.3 B1.14 (C60)A1.3 B1.14 (C2) A1.3 B1.14 (C60)
A1.3 B1.14 (C3) A1.3 B1.14 (C61)A1.3 B1.14 (C3) A1.3 B1.14 (C61)
A1.3 B1.14 (C4) A1.3 B1.14 (C62)A1.3 B1.14 (C4) A1.3 B1.14 (C62)
A1.3 B1.14 (C5) A1.3 B1.14 (C65)A1.3 B1.14 (C5) A1.3 B1.14 (C65)
A1.3 B1.14 (C7) A1.3 B1.14 (C66)A1.3 B1.14 (C7) A1.3 B1.14 (C66)
A1.3 B1.14 (C9) A1.3 B1.14 (C71)A1.3 B1.14 (C9) A1.3 B1.14 (C71)
A1.3 B1.14 (C12) A1.3 B1.14 (C74)A1.3 B1.14 (C12) A1.3 B1.14 (C74)
A1.3 B1.14 (C13) A1.3 B1.15 (C1)A1.3 B1.14 (C13) A1.3 B1.15 (C1)
A1.3 B1.14 (C15) A1.3 B1.15 (C2)A1.3 B1.14 (C15) A1.3 B1.15 (C2)
A1.3 B1.14 (C18) A1.3 B1.15 (C3)A1.3 B1.14 (C18) A1.3 B1.15 (C3)
A1.3 B1.14 (C21) A1.3 B1.15 (C4)A1.3 B1.14 (C21) A1.3 B1.15 (C4)
A1.3 B1.14 (C22) A1.3 B1.15 (C5)A1.3 B1.14 (C22) A1.3 B1.15 (C5)
A1.3 B1.14 (C23) A1.3 B1.15 (C7)A1.3 B1.14 (C23) A1.3 B1.15 (C7)
A1.3 B1.14 (C24) A1.3 B1.15 (C9)A1.3 B1.14 (C24) A1.3 B1.15 (C9)
A1.3 B1.14 (C25) A1.3 B1.15 (C12)A1.3 B1.14 (C25) A1.3 B1.15 (C12)
A1.3 B1.14 (C28) A1.3 B1.15 (C13)A1.3 B1.14 (C28) A1.3 B1.15 (C13)
A1.3 B1.14 (C32) A1.3 B1.15 (C15)A1.3 B1.14 (C32) A1.3 B1.15 (C15)
A1.3 B1.14 (C37) A1.3 B1.15 (C18)A1.3 B1.14 (C37) A1.3 B1.15 (C18)
A1.3 B1.14 (C37) A1.3 B1.15 (C21)A1.3 B1.14 (C37) A1.3 B1.15 (C21)
A1.3 B1.14 (C40) A1.3 B1.15 (C22)A1.3 B1.14 (C40) A1.3 B1.15 (C22)
A1.3 B1.14 (C41) A1.3 B1.15 (C23)A1.3 B1.14 (C41) A1.3 B1.15 (C23)
A1.3 B1.14 (C42) A1.3 B1.15 (C24)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.14 (C42) A1.3 B1.15 (C24) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.15 (C25) A1.3 B1.16 (C13)A1.3 B1.15 (C25) A1.3 B1.16 (C13)
A1.3 B1.15 (C28) A1.3 B1.16 (C15)A1.3 B1.15 (C28) A1.3 B1.16 (C15)
A1.3 B1.15 (C32) A1.3 B1.16 (C18)A1.3 B1.15 (C32) A1.3 B1.16 (C18)
A1.3 B1.15 (C37) A1.3 B1.16 (C21)A1.3 B1.15 (C37) A1.3 B1.16 (C21)
A1.3 B1.15 (C40) A1.3 B1.16 (C22)A1.3 B1.15 (C40) A1.3 B1.16 (C22)
A1.3 B1.15 (C41) A1.3 B1.16 (C23)A1.3 B1.15 (C41) A1.3 B1.16 (C23)
A1.3 B1.15 (C42) A1.3 B1.16 (C24)A1.3 B1.15 (C42) A1.3 B1.16 (C24)
A1.3 B1.15 (C43) A1.3 B1.16 (C25)A1.3 B1.15 (C43) A1.3 B1.16 (C25)
A1.3 B1.15 (C51) A1.3 B1.16 (C28)A1.3 B1.15 (C51) A1.3 B1.16 (C28)
A1.3 B1.15 (C52) A1.3 B1.16 (C32)A1.3 B1.15 (C52) A1.3 B1.16 (C32)
A1.3 B1.15 (C57) A1.3 B1.16 (C37)A1.3 B1.15 (C57) A1.3 B1.16 (C37)
A1.3 B1.15 (C58) A1.3 B1.16 (C37)A1.3 B1.15 (C58) A1.3 B1.16 (C37)
A1.3 B1.15 (C59) A1.3 B1.16 (C40)A1.3 B1.15 (C59) A1.3 B1.16 (C40)
A1.3 B1.15 (C60) A1.3 B1.16 (C41)A1.3 B1.15 (C60) A1.3 B1.16 (C41)
A1.3 B1.15 (C61) A1.3 B1.16 (C42)A1.3 B1.15 (C61) A1.3 B1.16 (C42)
A1.3 B1.15 (C62) A1.3 B1.16 (C43)A1.3 B1.15 (C62) A1.3 B1.16 (C43)
A1.3 B1.15 (C65) A1.3 B1.16 (C51)A1.3 B1.15 (C65) A1.3 B1.16 (C51)
A1.3 B1.15 (C66) A1.3 B1.16 (C52)A1.3 B1.15 (C66) A1.3 B1.16 (C52)
A1.3 B1.15 (C71) A1.3 B1.16 (C57)A1.3 B1.15 (C71) A1.3 B1.16 (C57)
A1.3 B1.15 (C74) A1.3 B1.16 (C58)A1.3 B1.15 (C74) A1.3 B1.16 (C58)
A1.3 B1.16 (C1) A1.3 B1.16 (C59)A1.3 B1.16 (C1) A1.3 B1.16 (C59)
A1.3 B1.16 (C2) A1.3 B1.16 (C60)A1.3 B1.16 (C2) A1.3 B1.16 (C60)
A1.3 B1.16 (C3) A1.3 B1.16 (C61)A1.3 B1.16 (C3) A1.3 B1.16 (C61)
A1.3 B1.16 (C4) A1.3 B1.16 (C62)A1.3 B1.16 (C4) A1.3 B1.16 (C62)
A1.3 B1.16 (C5) A1.3 B1.16 (C65)A1.3 B1.16 (C5) A1.3 B1.16 (C65)
A1.3 B1.16 (C7) A1.3 B1.16 (C66)A1.3 B1.16 (C7) A1.3 B1.16 (C66)
A1.3 B1.16 (C9) A1.3 B1.16 (C71)A1.3 B1.16 (C9) A1.3 B1.16 (C71)
A1.3 B1.16 (C12) A1.3 B1.16 (C74)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.16 (C12) A1.3 B1.16 (C74) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.17 (C1) A1.3 B1.17 (C60)A1.3 B1.17 (C1) A1.3 B1.17 (C60)
A1.3 B1.17 (C2) A1.3 B1.17 (C61)A1.3 B1.17 (C2) A1.3 B1.17 (C61)
A1.3 B1.17 (C3) A1.3 B1.17 (C62)A1.3 B1.17 (C3) A1.3 B1.17 (C62)
A1.3 B1.17 (C4) A1.3 B1.17 (C65)A1.3 B1.17 (C4) A1.3 B1.17 (C65)
A1.3 B1.17 (C5) A1.3 B1.17 (C66)A1.3 B1.17 (C5) A1.3 B1.17 (C66)
A1.3 B1.17 (C7) A1.3 B1.17 (C71)A1.3 B1.17 (C7) A1.3 B1.17 (C71)
A1.3 B1.17 (C9) A1.3 B1.17 (C74)A1.3 B1.17 (C9) A1.3 B1.17 (C74)
A1.3 B1.17 (C12) A1.3 B1.18 (C1)A1.3 B1.17 (C12) A1.3 B1.18 (C1)
A1.3 B1.17 (C13) A1.3 B1.18 (C2)A1.3 B1.17 (C13) A1.3 B1.18 (C2)
A1.3 B1.17 (C15) A1.3 B1.18 (C3)A1.3 B1.17 (C15) A1.3 B1.18 (C3)
A1.3 B1.17 (C18) A1.3 B1.18 (C4)A1.3 B1.17 (C18) A1.3 B1.18 (C4)
A1.3 B1.17 (C21) A1.3 B1.18 (C5)A1.3 B1.17 (C21) A1.3 B1.18 (C5)
A1.3 B1.17 (C22) A1.3 B1.18 (C7)A1.3 B1.17 (C22) A1.3 B1.18 (C7)
A1.3 B1.17 (C23) A1.3 B1.18 (C9)A1.3 B1.17 (C23) A1.3 B1.18 (C9)
A1.3 B1.17 (C24) A1.3 B1.18 (C12)A1.3 B1.17 (C24) A1.3 B1.18 (C12)
A1.3 B1.17 (C25) A1.3 B1.18 (C13)A1.3 B1.17 (C25) A1.3 B1.18 (C13)
A1.3 B1.17 (C28) A1.3 B1.18 (C15)A1.3 B1.17 (C28) A1.3 B1.18 (C15)
A1.3 B1.17 (C32) A1.3 B1.18 (C18)A1.3 B1.17 (C32) A1.3 B1.18 (C18)
A1.3 B1.17 (C37) A1.3 B1.18 (C21)A1.3 B1.17 (C37) A1.3 B1.18 (C21)
A1.3 B1.17 (C40) A1.3 B1.18 (C22)A1.3 B1.17 (C40) A1.3 B1.18 (C22)
A1.3 B1.17 (C41) A1.3 B1.18 (C23)A1.3 B1.17 (C41) A1.3 B1.18 (C23)
A1.3 B1.17 (C42) A1.3 B1.18 (C24)A1.3 B1.17 (C42) A1.3 B1.18 (C24)
A1.3 B1.17 (C43) A1.3 B1.18 (C25)A1.3 B1.17 (C43) A1.3 B1.18 (C25)
A1.3 B1.17 (C51) A1.3 B1.18 (C28)A1.3 B1.17 (C51) A1.3 B1.18 (C28)
A1.3 B1.17 (C52) A1.3 B1.18 (C32)A1.3 B1.17 (C52) A1.3 B1.18 (C32)
A1.3 B1.17 (C57) A1.3 B1.18 (C37)A1.3 B1.17 (C57) A1.3 B1.18 (C37)
A1.3 B1.17 (C58) A1.3 B1.18 (C40)A1.3 B1.17 (C58) A1.3 B1.18 (C40)
A1.3 B1.17 (C59) A1.3 B1.18 (C41)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.17 (C59) A1.3 B1.18 (C41) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.18 (C42) A1.3 B1.19 (C25)A1.3 B1.18 (C42) A1.3 B1.19 (C25)
A1.3 B1.18 (C51) A1.3 B1.19 (C28)A1.3 B1.18 (C51) A1.3 B1.19 (C28)
A1.3 B1.18 (C52) A1.3 B1.19 (C32)A1.3 B1.18 (C52) A1.3 B1.19 (C32)
A1.3 B1.18 (C57) A1.3 B1.19 (C37)A1.3 B1.18 (C57) A1.3 B1.19 (C37)
A1.3 B1.18 (C58) A1.3 B1.19 (C40)A1.3 B1.18 (C58) A1.3 B1.19 (C40)
A1.3 B1.18 (C59) A1.3 B1.19 (C41)A1.3 B1.18 (C59) A1.3 B1.19 (C41)
A1.3 B1.18 (C60) A1.3 B1.19 (C42)A1.3 B1.18 (C60) A1.3 B1.19 (C42)
A1.3 B1.18 (C61) A1.3 B1.19 (C43)A1.3 B1.18 (C61) A1.3 B1.19 (C43)
A1.3 B1.18 (C62) A1.3 B1.19 (C51)A1.3 B1.18 (C62) A1.3 B1.19 (C51)
A1.3 B1.18 (C65) A1.3 B1.19 (C52)A1.3 B1.18 (C65) A1.3 B1.19 (C52)
A1.3 B1.18 (C66) A1.3 B1.19 (C57)A1.3 B1.18 (C66) A1.3 B1.19 (C57)
A1.3 B1.18 (C71) A1.3 B1.19 (C58)A1.3 B1.18 (C71) A1.3 B1.19 (C58)
A1.3 B1.18 (C74) A1.3 B1.19 (C59)A1.3 B1.18 (C74) A1.3 B1.19 (C59)
A1.3 B1.19 (C1) A1.3 B1.19 (C60)A1.3 B1.19 (C1) A1.3 B1.19 (C60)
A1.3 B1.19 (C2) A1.3 B1.19 (C61)A1.3 B1.19 (C2) A1.3 B1.19 (C61)
A1.3 B1.19 (C3) A1.3 B1.19 (C62)A1.3 B1.19 (C3) A1.3 B1.19 (C62)
A1.3 B1.19 (C4) A1.3 B1.19 (C65)A1.3 B1.19 (C4) A1.3 B1.19 (C65)
A1.3 B1.19 (C5) A1.3 B1.19 (C66)A1.3 B1.19 (C5) A1.3 B1.19 (C66)
A1.3 B1.19 (C7) A1.3 B1.19 (C71)A1.3 B1.19 (C7) A1.3 B1.19 (C71)
A1.3 B1.19 (C9) A1.3 B1.19 (C74)A1.3 B1.19 (C9) A1.3 B1.19 (C74)
A1.3 B1.19 (C12) A1.3 B1.20 (C1)A1.3 B1.19 (C12) A1.3 B1.20 (C1)
A1.3 B1.19 (C13) A1.3 B1.20 (C2)A1.3 B1.19 (C13) A1.3 B1.20 (C2)
A1.3 B1.19 (C15) A1.3 B1.20 (C3)A1.3 B1.19 (C15) A1.3 B1.20 (C3)
A1.3 B1.19 (C18) A1.3 B1.20 (C4)A1.3 B1.19 (C18) A1.3 B1.20 (C4)
A1.3 B1.19 (C21) A1.3 B1.20 (C5)A1.3 B1.19 (C21) A1.3 B1.20 (C5)
A1.3 B1.19 (C22) A1.3 B1.20 (C7)A1.3 B1.19 (C22) A1.3 B1.20 (C7)
A1.3 B1.19 (C23) A1.3 B1.20 (C9)A1.3 B1.19 (C23) A1.3 B1.20 (C9)
A1.3 B1.19 (C24) A1.3 B1.20 (C12)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.19 (C24) A1.3 B1.20 (C12) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.20 (C13) A1.3 B1.21 (C2)A1.3 B1.20 (C13) A1.3 B1.21 (C2)
A1.3 B1.20 (C15) A1.3 B1.21 (C3)A1.3 B1.20 (C15) A1.3 B1.21 (C3)
A1.3 B1.20 (C18) A1.3 B1.21 (C4)A1.3 B1.20 (C18) A1.3 B1.21 (C4)
A1.3 B1.20 (C21) A1.3 B1.21 (C5)A1.3 B1.20 (C21) A1.3 B1.21 (C5)
A1.3 B1.20 (C22) A1.3 B1.21 (C7)A1.3 B1.20 (C22) A1.3 B1.21 (C7)
A1.3 B1.20 (C23) A1.3 B1.21 (C9)A1.3 B1.20 (C23) A1.3 B1.21 (C9)
A1.3 B1.20 (C24) A1.3 B1.21 (C12)A1.3 B1.20 (C24) A1.3 B1.21 (C12)
A1.3 B1.20 (C25) A1.3 B1.21 (C13)A1.3 B1.20 (C25) A1.3 B1.21 (C13)
A1.3 B1.20 (C28) A1.3 B1.21 (C15)A1.3 B1.20 (C28) A1.3 B1.21 (C15)
A1.3 B1.20 (C32) A1.3 B1.21 (C18)A1.3 B1.20 (C32) A1.3 B1.21 (C18)
A1.3 B1.20 (C37) A1.3 B1.21 (C21)A1.3 B1.20 (C37) A1.3 B1.21 (C21)
A1.3 B1.20 (C40) A1.3 B1.21 (C22)A1.3 B1.20 (C40) A1.3 B1.21 (C22)
A1.3 B1.20 (C41) A1.3 B1.21 (C23)A1.3 B1.20 (C41) A1.3 B1.21 (C23)
A1.3 B1.20 (C42) A1.3 B1.21 (C24)A1.3 B1.20 (C42) A1.3 B1.21 (C24)
A1.3 B1.20 (C43) A1.3 B1.21 (C25)A1.3 B1.20 (C43) A1.3 B1.21 (C25)
A1.3 B1.20 (C51) A1.3 B1.21 (C28)A1.3 B1.20 (C51) A1.3 B1.21 (C28)
A1.3 B1.20 (C52) A1.3 B1.21 (C32)A1.3 B1.20 (C52) A1.3 B1.21 (C32)
A1.3 B1.20 (C57) A1.3 B1.21 (C37)A1.3 B1.20 (C57) A1.3 B1.21 (C37)
A1.3 B1.20 (C58) A1.3 B1.21 (C40)A1.3 B1.20 (C58) A1.3 B1.21 (C40)
A1.3 B1.20 (C59) A1.3 B1.21 (C41)A1.3 B1.20 (C59) A1.3 B1.21 (C41)
A1.3 B1.20 (C60) A1.3 B1.21 (C42)A1.3 B1.20 (C60) A1.3 B1.21 (C42)
A1.3 B1.20 (C61) A1.3 B1.21 (C43)A1.3 B1.20 (C61) A1.3 B1.21 (C43)
A1.3 B1.20 (C62) A1.3 B1.21 (C51)A1.3 B1.20 (C62) A1.3 B1.21 (C51)
A1.3 B1.20 (C65) A1.3 B1.21 (C52)A1.3 B1.20 (C65) A1.3 B1.21 (C52)
A1.3 B1.20 (C66) A1.3 B1.21 (C57)A1.3 B1.20 (C66) A1.3 B1.21 (C57)
A1.3 B1.20 (C71) A1.3 B1.21 (C58)A1.3 B1.20 (C71) A1.3 B1.21 (C58)
A1.3 B1.20 (C74) A1.3 B1.21 (C59)A1.3 B1.20 (C74) A1.3 B1.21 (C59)
A1.3 B1.21 (C1) A1.3 B1.21 (C60)
WirkWirkWirkWirkWirkWirkstoff (A) stoff (B) stoff (C) stoff (A) stoff (B) stoff (C)A1.3 B1.21 (C1) A1.3 B1.21 (C60) WirkWirkWirkWirkWirkAbjective (A) fabric (B) fabric (C) fabric (A) fabric (B) fabric (C)
A1.3 B1.21 (C61) A1.3 B1.22 (C43)A1.3 B1.21 (C61) A1.3 B1.22 (C43)
A1.3 B1.21 (C62) A1.3 B1.22 (C51)A1.3 B1.21 (C62) A1.3 B1.22 (C51)
A1.3 B1.21 (C65) A1.3 B1.22 (C52)A1.3 B1.21 (C65) A1.3 B1.22 (C52)
A1.3 B1.21 (C66) A1.3 B1.22 (C57)A1.3 B1.21 (C66) A1.3 B1.22 (C57)
A1.3 B1.21 (C71) A1.3 B1.22 (C58)A1.3 B1.21 (C71) A1.3 B1.22 (C58)
A1.3 B1.21 (C74) A1.3 B1.22 (C59)A1.3 B1.21 (C74) A1.3 B1.22 (C59)
A1.3 B1.22 (C1) A1.3 B1.22 (C60)A1.3 B1.22 (C1) A1.3 B1.22 (C60)
A1.3 B1.22 (C2) A1.3 B1.22 (C61)A1.3 B1.22 (C2) A1.3 B1.22 (C61)
A1.3 B1.22 (C3) A1.3 B1.22 (C62)A1.3 B1.22 (C3) A1.3 B1.22 (C62)
A1.3 B1.22 (C4) A1.3 B1.22 (C62)A1.3 B1.22 (C4) A1.3 B1.22 (C62)
A1.3 B1.22 (C5) A1.3 B1.22 (C65)A1.3 B1.22 (C5) A1.3 B1.22 (C65)
A1.3 B1.22 (C7) A1.3 B1.22 (C66)A1.3 B1.22 (C7) A1.3 B1.22 (C66)
A1.3 B1.22 (C9) A1.3 B1.22 (C71)A1.3 B1.22 (C9) A1.3 B1.22 (C71)
A1.3 B1.22 (C12) A1.3 B1.22 (C74)A1.3 B1.22 (C12) A1.3 B1.22 (C74)
A1.3 B1.22 (C13) A1.3 B1.23 (C1)A1.3 B1.22 (C13) A1.3 B1.23 (C1)
A1.3 B1.22 (C15) A1.3 B1.23 (C2)A1.3 B1.22 (C15) A1.3 B1.23 (C2)
A1.3 B1.22 (C18) A1.3 B1.23 (C3)A1.3 B1.22 (C18) A1.3 B1.23 (C3)
A1.3 B1.22 (C21) A1.3 B1.23 (C4)A1.3 B1.22 (C21) A1.3 B1.23 (C4)
A1.3 B1.22 (C22) A1.3 B1.23 (C5)A1.3 B1.22 (C22) A1.3 B1.23 (C5)
A1.3 B1.22 (C23) A1.3 B1.23 (C7)A1.3 B1.22 (C23) A1.3 B1.23 (C7)
A1.3 B1.22 (C24) A1.3 B1.23 (C9)A1.3 B1.22 (C24) A1.3 B1.23 (C9)
A1.3 B1.22 (C25) A1.3 B1.23 (C12)A1.3 B1.22 (C25) A1.3 B1.23 (C12)
A1.3 B1.22 (C28) A1.3 B1.23 (C13)A1.3 B1.22 (C28) A1.3 B1.23 (C13)
A1.3 B1.22 (C32) A1.3 B1.23 (C15)A1.3 B1.22 (C32) A1.3 B1.23 (C15)
A1.3 B1.22 (C37) A1.3 B1.23 (C18)A1.3 B1.22 (C37) A1.3 B1.23 (C18)
A1.3 B1.22 (C40) A1.3 B1.23 (C21)A1.3 B1.22 (C40) A1.3 B1.23 (C21)
A1.3 B1.22 (C41) A1.3 B1.23 (C22)A1.3 B1.22 (C41) A1.3 B1.23 (C22)
A1.3 B1.22 (C42) A1.3 B1.23 (C23)
WirkWirkWirkstoff (A) stoff (B) stoff (C)A1.3 B1.22 (C42) A1.3 B1.23 (C23) WirkWirkActive agent (A) substance (B) substance (C)
A1.3 B1.23 (C24)A1.3 B1.23 (C24)
A1.3 B1.23 (C25)A1.3 B1.23 (C25)
A1.3 B1.23 (C28)A1.3 B1.23 (C28)
A1.3 B1.23 (C32)A1.3 B1.23 (C32)
A1.3 B1.23 (C37)A1.3 B1.23 (C37)
A1.3 B1.23 (C40)A1.3 B1.23 (C40)
A1.3 B1.23 (C41)A1.3 B1.23 (C41)
A1.3 B1.23 (C42)A1.3 B1.23 (C42)
A1.3 B1.23 (C43)A1.3 B1.23 (C43)
A1.3 B1.23 (C51)A1.3 B1.23 (C51)
A1.3 B1.23 (C52)A1.3 B1.23 (C52)
A1.3 B1.23 (C57)A1.3 B1.23 (C57)
A1.3 B1.23 (C58)A1.3 B1.23 (C58)
A1.3 B1.23 (C59)A1.3 B1.23 (C59)
A1.3 B1.23 (C60)A1.3 B1.23 (C60)
A1.3 B1.23 (C61)A1.3 B1.23 (C61)
A1.3 B1.23 (C62)A1.3 B1.23 (C62)
A1.3 B1.23 (C65)A1.3 B1.23 (C65)
A1.3 B1.23 (C66)A1.3 B1.23 (C66)
A1.3 B1.23 (C71)A1.3 B1.23 (C71)
A1.3 B1.23 (C74)
A1.3 B1.23 (C74)
Die Aufwandmengen der Wirkstoffe (C) können stark variieren. Als grobe Richtgröße für herbizide Wirkstoffe (C) können folgende Bereiche gelten: The application rates of the active ingredients (C) can vary widely. As a rough guide value for herbicidal active ingredients (C), the following ranges apply:
Im Allgemeinen 0,5 - 5000 g AS/ha, bevorzugt 1 bis 3000 g AS/ha, besonders bevorzugt 2 - 2000 g AS/ha. In general, 0.5-5000 g AS / ha, preferably 1 to 3000 g AS / ha, more preferably 2 - 2000 g AS / ha.
Im Fall von Safenern als Wirkstoff (C) werden diese bevorzugt im Gewichtsverhältnis 1 :10 bis 10:1 relativ zum Wirkstoff (B) eingesetzt. Einige der genannten Kombinationen sind neu und als solche auch Gegenstand der Erfindung. In the case of safeners as active ingredient (C), these are preferably used in a weight ratio of 1:10 to 10: 1 relative to the active ingredient (B). Some of the combinations mentioned are new and, as such, also the subject of the invention.
Die erfind ungsgemä ßen Kom binationen (= herbiziden M ittel ) weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger mono- und dikotyler Schadpflanzen auf. Auch schwer bekämpfbare perenn ierende U n kräuter, d ie aus Rh izomen , Wurzelstöcken oder anderen Dauerorganen austreiben, werden durch die Wirkstoffe gut erfasst. Dabei ist es gleichgültig, ob die Substanzen im Vorsaat-, Vorauflauf- oder Nachauflaufverfahren ausgebracht werden. Bevorzugt ist die Anwendung im Nachauflaufverfahren oder im frühen Nachsaat-Vorauflaufverfahren. The com binations according to the invention (= herbicidal agent) have an excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous harmful plants. Hard-to-combinate perennial herbs, which sprout out of rhizomes, rhizomes or other endemic organs, are also well recognized by the active ingredients. It does not matter whether the substances are applied in the pre-sowing, pre-emergence or postemergence process. Preferably, the application is postemergence or early seed seeding pre-emergence.
Im einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen Unkrautflora genannt, die durch die erfindungsgemäßen Mittel kontrolliert werden können, ohne dass durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll. Specifically, by way of example, some representatives of the monocotyledonous and dicotyledonous weed flora may be mentioned, which can be controlled by the agents according to the invention, without the intention of limiting them to certain species.
Monokotyle Schadpflanzen der Gattungen: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyl- octenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum.
Dikotyle Unkräuter der Gattungen: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium , Emex, Erysimum , Euphorbia, Galeopsis, Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. Monocotyledonous weeds of the genera: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyl octenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera , Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum. Dicotyledonous weeds of the genera: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erysimum, Euphorbia, Galeopsis Galinsoga Galium Hibiscus Ipomoea Kochia Lamium Lepidium Lindernia Matricaria Mentha Mercurialis Mullugo Myosotis Papaver Pharbitis Plantago Polygonum Portulaca Ranunculus Raphanus Rorippa Rotala Rumex , Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium.
Werden die erfindungsgemäßen Mittel vor dem Keimen auf d ie Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schl ießl ich nach Ablauf von drei bis vier Wochen vollkommen ab. If the agents according to the invention are applied to the surface of the earth before germination, either the weed seedlings are completely prevented or the weeds grow up to the cotyledon stage, but then cease their growth and die completely after three to four weeks from.
Bei Applikation der Mittel auf die grünen Pflanzenteile im Nachauflaufverfahren tritt ebenfalls sehr rasch nach der Behandlung ein drastischer Wachstumsstop (mit Wachstumsdeformationen, Chlorosen und Nekrosen) ein und die Unkrautpflanzen bleiben in dem zum Applikationszeitpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so dass auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird. Upon application of the agents to the green parts of the plants postemergence also occurs very quickly after treatment, a drastic halt in growth (with growth deformations, chlorosis and necrosis) and the weed plants remain in the growth stage present at the time of application or die after a certain time completely, so that in this way a harmful weed competition for the crops is eliminated very early and sustainably.
Die erfindungsgemäßen herbiziden Mittel zeichnen sich im Vergleich zu den Einzelpräparaten durch eine schneller einsetzende und länger andauernde herbizide Wirkung aus. Die Regenfestig keit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, dass die in den Kombinationen verwendeten und wirksamen Dosierungen von Verbindungen (A) und (B) so gering eingestellt werden können, dass ihre Bodenwirkung optimal ist. Somit wird deren Einsatz nicht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser-Kontaminationen werden praktisch vermieden. Durch die
erfindungsgemäßen Kombination von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht. Compared to the individual preparations, the herbicidal compositions according to the invention are characterized by a more rapid onset and longer-lasting herbicidal action. The Regenfestig speed of the active ingredients in the combinations of the invention is generally favorable. A particular advantage is the fact that the effective and used in the combinations dosages of compounds (A) and (B) can be set so low that their soil effect is optimal. Thus, their use is not only possible in sensitive cultures, but groundwater contamination is virtually avoided. By the inventive combination of drugs is a significant reduction in the required application rate of the drugs allows.
Bei der gemeinsamer Anwendung von Herbiziden des Typs (A)+(B) treten überadditive (= synergistische) Effekte auf. Dabei ist die Wirkung in den Kombinationen stärker als die zu erwartende Summe der Wirkungen der eingesetzten Einzelherbizide. Die synerg istischen Effekte erlauben eine Reduzierung der Aufwandmenge, d ie Bekämpfung eines breiteren Spektrums von Unkräutern und Ungräsern, einen schnelleren Eintritt der herbiziden Wirkung, eine längere Dauerwirkung, eine bessere Kontrolle der Schadpflanzen mit nur einer bzw. wenigen Applikationen sowie eine Ausweitung des möglichen Anwendungszeitraums. Teilweise wird durch den Einsatz der Mittel auch die Menge an schädlichen Inhaltsstoffen in der Kulturpflanze, wie Stickstoff oder Ölsäure, reduziert. Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung gefordert, um landwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen. Der technische Standard wird durch diese neuen Kombinationen hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen. When herbicides of the type (A) + (B) are used together, superadditive (= synergistic) effects occur. The effect in the combinations is stronger than the expected sum of the effects of the individual herbicides used. The synergistic effects allow a reduction in the application rate, ie the control of a broader spectrum of weeds and weeds, a faster onset of herbicidal activity, a longer lasting effect, a better control of harmful plants with only one or a few applications and an extension of the possible period of application , Partly by the use of funds and the amount of harmful ingredients in the crop, such as nitrogen or oleic acid, reduced. The said properties and advantages are required in practical weed control in order to keep agricultural crops free of undesired competing plants and thus to secure and / or increase yields qualitatively and quantitatively. The technical standard is significantly exceeded by these new combinations in terms of the properties described.
Obgleich die erfindungsgemäßen Mittel eine ausgezeichnete herbizide Aktivität gegenüber mono- und dikotylen Unkräutern aufweisen, werden die toleranten bzw. kreuztoleranten Getreidepflanzen nur unwesentlich oder gar nicht geschädigt. Darüber hinaus weisen d ie erfindungsgemäßen Mittel teilweise hervorragende wachstumsregulatorische Eigenschaften bei den Getreidepflanzen auf. Sie greifen regulierend in den pflanzeneigenen Stoffwechsel ein und können damit zur gezielten Beeinflussung von Pflanzen inhaltsstoffen eingesetzt werden. Des Weiteren eignen sie sich auch zur generellen Steuerung und Hemmung von unerwünschtem vegetativen Wachstum, ohne dabei die Pflanzen abzutöten . Eine Hemmung des vegetativen Wachstums spielt bei vielen mono- und dikotylen Kulturen eine große Rolle, da das
Lagern durch verbesserte Standfestigkeit verringert oder völlig verhindert werden kann. Although the compositions according to the invention have excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, the tolerant or cross-tolerant cereal plants are damaged only insignificantly or not at all. In addition, the agents according to the invention sometimes have excellent growth-regulatory properties in cereal plants. They regulate the plant's metabolism and can thus be used to specifically influence plant ingredients. Furthermore, they are also suitable for the general control and inhibition of undesirable vegetative growth, without killing the plants. Inhibition of vegetative growth plays an important role in many mono- and dicotyledonous cultures, as the Storage can be reduced by improved stability or completely prevented.
Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die Mittel zur Bekämpfung von Schadpflanzen in bekannten toleranten oder kreuztoleranten Getreidekulturen oder noch zu entwickelnden toleranten oder gentechnisch veränderten Getreidekulturen eingesetzt werden . Die transgenen Pflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, neben den Resistenzen gegenüber den erfindungsgemäßen Mitteln beispielsweise d u rch Res istenzen g egen ü ber Pfl a nzen kra n kh e iten od er Erreg ern von Pflanzenkrankheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit und Zusammensetzung spezieller Inhaltsstoffe. So sind transgene Pflanzen mit erhöhtem Ölgehalt oder veränderter Qualität, z. B. anderer Fettsäurezusammensetzung des Ernteguts bekannt. Because of their herbicidal and plant growth regulatory properties, the weed control agents can be used in known tolerant or cross-tolerant crops or tolerant or genetically engineered crops to be developed. The transgenic plants are generally distinguished by particular advantageous properties, in addition to the resistances to the agents according to the invention, for example by rescuing plants via plant creeping or the excitation of plant diseases such as certain insects or microorganisms, such as Fungi, bacteria or viruses. Other special properties relate to z. B. the crop in terms of quantity, quality, shelf life and composition of specific ingredients. Thus, transgenic plants with increased oil content or altered quality, eg. B. other fatty acid composition of the crop known.
Herkömmliche Wege zur Herstellung neuer Pflanzen, die im Vergleich zu bisher vorkommenden Pflanzen mod ifizierte Eigenschaften aufweisen , bestehen beispielsweise in klassischen Züchtungsverfahren und der Erzeugung von Mutanten. Alternativ können neue Pflanzen m it veränderten Eigenschaften m it H ilfe gentechnischer Verfahren erzeugt werden (siehe z.B. EP-A 0 221 044, EP-A 0 131 624). Beschrieben wurden beispielsweise in mehreren Fällen gentechnische Veränderungen von Kulturpflanzen zwecks Modifikation der in den Pflanzen synthetisierten Stärke (z.B. WO 92/01 1376 A, WO 92/014827 A, WO 91/019806 A), Conventional ways for the production of new plants, which exhibit modi fi ed properties in comparison to previously occurring plants, consist, for example, in classical breeding methods and the generation of mutants. Alternatively, new plants with altered properties can be generated by genetic engineering techniques (see, e.g., EP-A-0 221 044, EP-A-0 131 624). For example, genetic modifications of crops have been described in several cases for the purpose of modifying the starch synthesized in the plants (for example WO 92/01 1376 A, WO 92/014827 A, WO 91/019806 A),
transgene Kulturpflanzen, welche gegen bestimmte Herbizide vom Typ Glyphosate (WO 92/000377 A) oder der Sulfonylharnstoffe (EP 0 257 993 A, US 5,013,659) oder gegen Kombinationen oder Mischungen dieser Herbizide durch „gene stacking" resistent sind, wie transgene Kulturpflanzen z. B. Getreide oder Soja mit dem Handelsnamen oder der Bezeichnung Optimum™ GAT™ (Glyphosate ALS transgenic crop plants which are resistant to certain herbicides of the glyphosate type (WO 92/000377 A) or the sulfonylureas (EP 0 257 993 A, US Pat. No. 5,013,659) or to combinations or mixtures of these herbicides by gene stacking, such as transgenic crop plants, e.g. Cereals or soya with the trade name or the name Optimum ™ GAT ™ (Glyphosate ALS
Tolerant).
transgene Kulturpflanzen, beispielsweise Baumwolle, mit der Fähigkeit Bacillus thuringiensis-Toxine (Bt-Toxine) zu produzieren, welche die Pflanzen gegen bestimmte Schädlinge resistent machen (EP-A 0 142 924, EP-A 0 193 259). transgene Kulturpflanzen mit modifizierter Fettsäurezusammensetzung (WO 91/013972 A). Tolerant). Transgenic crops, such as cotton, with the ability to produce Bacillus thuringiensis toxins (Bt toxins), which make the plants resistant to certain pests (EP-A 0 142 924, EP-A 0 193 259). Transgenic crops with modified fatty acid composition (WO 91/013972 A).
gentechnisch veränderte Kulturpflanzen mit neuen Inhalts- oder Sekundärstoffen z.B. neuen Phytoalexinen, die eine erhöhte Krankheitsresistenz verursachen (EP O 309 862 A, EP 0 464 461 A) genetically engineered crops with new content or secondary substances, e.g. new phytoalexins which cause increased disease resistance (EP 0 309 862 A, EP 0 464 461 A)
gentechnisch veränderte Pflanzen mit reduzierter Photorespiration, die höhere Erträge und höhere Stresstoleranz aufweisen (EP 0 305 398 A) genetically modified plants with reduced photorespiration, which have higher yields and higher stress tolerance (EP 0 305 398 A)
transgene Kulturpflanzen, die pharmazeutisch oder diagnostisch wichtige Proteine produzieren („molecular pharming") transgenic crops that produce pharmaceutically or diagnostically important proteins ("molecular pharming")
transgene Kulturpflanzen, die sich durch höhere Erträge oder bessere Qualität auszeichnen Transgenic crops that are characterized by higher yields or better quality
- transgene Kulturpflanzen die sich durch eine Kombinationen z.B. der o. g. neuen Eigenschaften auszeichnen („gene stacking") transgenic crops characterized by a combination of e.g. the o. g. characterize new properties ("gene stacking")
Zahlreiche molekularbiologische Techniken, mit denen neue transgene Pflanzen mit veränderten Eigenschaften hergestellt werden können, sind im Prinzip bekannt; siehe z.B. I. Potrykus und G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, oder Christou, "Trends in Plant Science" 1 (1996) 423-431 ). Numerous molecular biology techniques that can be used to produce novel transgenic plants with altered properties are known in principle; see, e.g. I. Potrykus and G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Trends in Plant Science" 1 (1996) 423-431).
Für derartige gentechnische Manipulationen können Nucleinsäuremoleküle in Plasmide eingebracht werden, die eine Mutagenese oder eine Sequenzveränderung durch Rekombination von DNA-Sequenzen erlauben. Mit Hilfe von Standardverfahren können z.B. Basenaustausche vorgenommen, Teilsequenzen entfernt oder natürliche oder synthetische Sequenzen hinzugefügt werden. Für die Verbindung der DNA-Fragmente untereinander können an die Fragmente Adaptoren oder Linker angesetzt werden, siehe z.B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Aufl. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; oder Winnacker "Gene
und Klone", VCH Weinheim 2. Auflage 1996 For such genetic engineering, nucleic acid molecules can be introduced into plasmids that allow mutagenesis or sequence alteration by recombination of DNA sequences. By means of standard methods, for example, base exchanges can be made, partial sequences removed or natural or synthetic sequences added. For the connection of the DNA fragments with one another adapters or linkers can be attached to the fragments, see eg Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd Ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Gene and Clones ", VCH Weinheim 2nd edition 1996
Die Herstellung von Pflanzenzellen mit einer verringerten Aktivität eines Genprodukts kann beispielsweise erzielt werden durch d ie Expression m indestens einer entsprechenden antisense-R N A , e i n e r s e n s e-RNA zur Erzielung eines Cosuppressionseffektes oder die Expression mindestens eines entsprechend konstruierten Ribozyms, das spezifisch Transkripte des obengenannten Genprodukts spaltet. H ierzu können zum einen DNA-Moleküle verwendet werden, die die gesamte codierende Sequenz eines Genprodukts einschließlich eventuell vorhandener flankierender Sequenzen umfassen, als auch DNA-Moleküle, die nur Teile der codierenden Sequenz umfassen, wobei diese Teile lang genug sein müssen, um in den Zellen einen antisense-Effekt zu bewirken. Möglich ist auch die Verwendung von DNA- Sequenzen, die einen hohen Grad an Homologie zu den codiereden Sequenzen eines Genprodukts aufweisen, aber nicht vollkommen identisch sind. The production of plant cells having reduced activity of a gene product can be achieved, for example, by expression of at least one corresponding antisense RNA, one e-RNA to obtain a cosuppression effect, or expression of at least one correspondingly engineered ribozyme which specifically transcribes the above gene product splits. Here, on the one hand, DNA molecules can be used which comprise the entire coding sequence of a gene product, including any flanking sequences which may be present, as well as DNA molecules which comprise only parts of the coding sequence, which parts have to be long enough to be inserted into the Cells cause an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical.
Bei der Expression von Nucleinsäuremolekülen in Pflanzen kann das synthetisierte Protein in jedem beliebigen Kompartiment der pflanzlichen Zelle lokalisiert sein. Um aber die Lokalisation in einem bestimmten Kompartiment zu erreichen, kann z.B. die codierende Region mit DNA-Sequenzen verknüpft werden, die die Lokalisierung in einem bestimmten Kompartiment gewährleisten . Derartige Sequenzen sind dem Fachmann bekannt (siehe beispielsweise Braun et al., EMBO J. 1 1 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sei. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1 991 ), 95-106). Die Expression der Nukleinsäuremoleküle kann auch in den Organellen der Pflanzenzellen stattfinden. In the expression of nucleic acid molecules in plants, the synthesized protein may be located in any compartment of the plant cell. However, to achieve localization in a particular compartment, e.g. the coding region is linked to DNA sequences which ensure localization in a particular compartment. Such sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad., U.S.A. 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1 991), 95-106). The expression of the nucleic acid molecules can also take place in the organelles of the plant cells.
Die transgenen Pflanzenzellen können nach bekannten Techniken zu ganzen Pflanzen regeneriert werden. Bei den transgenen Pflanzen kann es sich prinzipiell um Pflanzen jeder beliebigen Pflanzenspezies handeln, d.h., sowohl monokotyle als auch dikotyle Pflanzen.
So sind transgene Pflanzen erhältl ich , d ie veränderte Eigenschaften durch Überexpression, Suppression oder Inhibierung homologer (= natürlicher) Gene oder Gensequenzen oder Expression heterologer (= fremder) Gene oder Gensequenzen aufweisen. The transgenic plant cells can be regenerated to whole plants by known techniques. The transgenic plants may in principle be plants of any plant species, ie both monocotyledonous and dicotyledonous plants. Thus, transgenic plants are obtained which have altered properties through overexpression, suppression or inhibition of homologous (= natural) genes or gene sequences or expression of heterologous (= foreign) genes or gene sequences.
Vorzugsweise können die erfindungsgemäßen Mittel in transgenen Getreidekulturen eingesetzt werden, welche nicht nur gegen die Komponente (A), sondern auch gegen Herbizide, die essentielle Pflanzenenzyme, z.B. Acetolactatsynthasen (ALS), EPSP Synthasen oder Hydoxyphenylpyruvat Dioxygenasen (HPPD) hemmen, respektive gegen Herbizide aus der Gruppe der Sulfonylharnstoffe, der Glyphosate oder Benzoylisoxazole und analogen Wirkstoffe, oder gegen beliebige Kombinationen dieser Wirkstoffe, tolerant sind. Besonders bevorzugt kön nen d ie erfindu ngsgemäßen M ittel in transgenen Getreidekulturen eingesetzt werden, die gegen eine Kombination von Glyphosaten und Glufosinaten oder gegen eine Kombination von Glufosinaten und Sulfonylharnstoffen oder Imidazolinonen tolerant sind. Preferably, the agents of the invention may be employed in transgenic crop cultures which not only target component (A) but also herbicides containing essential plant enzymes, e.g. Acetolactate synthases (ALS), EPSP synthases or Hydoxyphenylpyruvat dioxygenases (HPPD) inhibit, respectively, are tolerant to herbicides from the group of sulfonylureas, glyphosate or Benzoylisoxazole and analogues, or against any combination of these agents. Particularly preferably, the compositions according to the invention can be used in transgenic cereal cultures which are tolerant to a combination of glyphosates and glufosinates or to a combination of glufosinates and sulfonylureas or imidazolinones.
Gegenstand der Erfindung ist deshalb auch ein Verfahren zur Bekämpfung von u nerwü nschtem Pflanzenwuchs in toleranten Getreidekulturen, dadurch gekennzeichnet, dass man ein oder mehrere Herbizide des Typs (A) mit einem oder mehreren Herbiziden des Typs (B) auf die Schadpflanzen, Pflanzenteile davon oder die Anbaufläche appliziert. Gegenstand der Erfindung sind auch die neuen Kombinationen aus Verbindungen (A)+(B) und diese enthaltende herbizide Mittel. The invention therefore also provides a method for controlling undesired plant growth in tolerant cereal crops, which comprises applying one or more herbicides of the type (A) with one or more herbicides of the type (B) to the harmful plants, plant parts thereof or applied the acreage. The invention also relates to the novel combinations of compounds (A) + (B) and herbicidal compositions containing them.
Die erfindungsgemäßen Wirkstoffkombinationen können sowohl a l s M i s c hformulierungen der zwei Komponenten, gegebenenfalls mit weiteren Wirkstoffen, Zusatzstoffen und/oder üblichen Formulierungshilfsmitteln vorliegen, die dann in üblicher Weise mit Wasser verdünnt zur Anwendung gebracht werden, oder als
sogenannte Tankmischungen durch gemeinsame Verdünnung der getrennt formulierten oder partiell getrennt formulierten Komponenten mit Wasser hergestellt werden. The active compound combinations according to the invention can be present either as formulations of the two components, if appropriate with further active ingredients, additives and / or customary formulation auxiliaries, which are then diluted with water in the customary manner, or as so-called tank mixes by common dilution of the separately formulated or partially separately formulated components are prepared with water.
Die erfindungsgemäßen Mittel können in Form von Spritzpulvern, emulgierbaren Konzentraten, versprühbaren Lösungen, Stäubemitteln oder Granulaten in den üblichen Zubereitungen angewendet werden. Gegenstand der Erfindung sind deshalb a uch h erbizid e u nd pfl a nzenwach stu m sreg u l ierend e M ittel , wel che d ie erfindungsgemäßen Mittel enthalten. Die erfindungsgemäßen Mittel können auf verschiedene Art formuliert werden, je nachdem welche biolog ischen und/oder chem isch-physikalischen Parameter vorgegeben sind. Als Formulierungsmöglichkeiten kommen beispielsweise in Frage: Spritzpulver (WP), wasserlösl iche Pulver (SP), wasserlösliche Konzentrate, emu lg ierbare Konzentrate (EC), Emu lsionen (EW), wie Öl-in-Wasser- und Wasser-in-ÖI-Emulsionen, versprühbare Lösungen, Suspensionskonzentrate (SC), Dispersionen auf Öl- oder Wasserbasis, ölmischbare Lösungen, Kapselsuspensionen (CS), Stäubemittel (DP), Beizmittel, Granulate für die Streu- und Bodenapplikation, Granulate (GR) in Form von Mikro-, Sprüh-, Aufzugs- und Adsorptionsgranulaten, wasserdispergierbare Granulate (WG), wasserlösliche Granulate (SG), ULV-Formulierungen, Mikrokapseln und Wachse. The compositions of the invention can be used in the form of wettable powders, emulsifiable concentrates, sprayable solutions, dusts or granules in the usual preparations. The invention therefore also relates to heritable and plant-growth-stimulating agents which contain the agents according to the invention. The agents according to the invention can be formulated in various ways, depending on which biological and / or chemical and physical parameters are prescribed. Possible formulation options are, for example, wettable powder (WP), water-soluble powder (SP), water-soluble concentrates, emulsifiable concentrates (EC), emulsions (EW), such as oil-in-water and water-in-oil. Emulsions, sprayable solutions, suspension concentrates (SC), oil or water based dispersions, oil miscible solutions, capsule suspensions (CS), dusts (DP), mordants, granules for litter and soil application, granules (GR) in the form of micro, Spray, elevator and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules and waxes.
Diese einzel nen Formu l ierungstypen sind im Prinzip bekan nt u nd werden beispielsweise beschrieben in: Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl. 1986; Wade van Valkenburg, "Pesticide Formulations", Marcel Dekker, N.Y., 1973; K. Martens, "Spray Drying" Handbook, 3rd Ed. 1979, G. Goodwin Ltd. London. These individual types of formulation are in principle known and are described, for example, in: Winnacker-Kuchler, "Chemische Technologie", Volume 7, C. Hanser Verlag, Munich, 4th edition, 1986; Wade van Valkenburg, "Pesticide Formulations", Marcel Dekker, N.Y., 1973; K. Martens, "Spray Drying" Handbook, 3rd ed. 1979, G. Goodwin Ltd. London.
Die notwendigen Formulierungshilfsmittel wie Inertmaterialien, Tenside, Lösungsmittel und weitere Zusatzstoffe sind ebenfal ls bekannt und werden beispielsweise beschrieben in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell N.J., H.v. Olphen, "Introduction to Clay Colloid
Chemistry"; 2nd Ed., J. Wiley & Sons, N.Y.; C. Marsden, "Solvents Guide"; 2nd Ed., Interscience, N.Y. 1963; McCutcheon's "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of The necessary formulation auxiliaries such as inert materials, surfactants, solvents and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticides Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell NJ, Hv Olphen, "Introduction to Clay Colloid Chemistry, 2nd Ed., J. Wiley & Sons, NY; C. Marsden, "Solvents Guide"; 2nd Ed., Interscience, NY 1963; McCutcheon's "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood NJ; Sisley and Wood, "Encyclopedia of
S u rface Act ive Ag ents" , Ch em . P u bl . Co . I n c . , N .Y. 1 964 ; Schönfel dt, "Grenzflächenaktive Äthylenoxidaddukte", Wiss. Verlagsgesell ., Stuttgart 1 976; Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl. 1986. Surface Act ive Ag ents, Ch em P u bl Co, I nc., N, Y 1 964; Schoenfelt, "Border-Active Ethylene Oxide Adducts", Wiss. Verlagsgesell., Stuttgart 1 976; Winnacker-Kuchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th ed. 1986.
Auf der Basis dieser Formulierungen lassen sich auch Kombinationen mit anderen pestizid wirksamen Stoffen, wie z.B. Insektiziden, Akariziden, Herbiziden, Fungiziden, sowie mit Safenern, Düngemitteln und/oder Wachstumsregulatoren herstellen, z.B. in Form einer Fertigformulierung oder als Tankmix. On the basis of these formulations, combinations with other pesticidally active substances, e.g. Insecticides, acaricides, herbicides, fungicides, as well as with safeners, fertilizers and / or growth regulators, e.g. in the form of a ready-made formulation or as a tank mix.
Spritzpulver sind in Wasser gleichmäßig dispergierbare Präparate, die neben dem Wirkstoff außer einem Verdünnungs- oder Inertstoff noch Tenside ionischer und/oder nichtionischer Art (Netzmittel, Dispergiermittel), z.B. polyoxyethylierte Alkylphenole, polyoxethyl ierte Fetta l kohol e , polyoxethyl ierte Fetta m i ne , Fetta l kohol- polyglykolethersulfate, Alkansulfonate, Alkylbenzolsulfonate, ligninsulfonsaures Natri u m , 2 , 2'-dinaphthylmethan-6,6'-d isu lfonsau res Natriu m , d ibutylnaphtha- lin-sulfonsaures Natrium oder auch oleoylmethyltaurinsaures Natrium enthalten. Zur Herstellung der Spritzpulver werden die herbiziden Wirkstoffe beispielsweise in üblichen Apparaturen wie Hammermühlen, Gebläsemühlen und Luftstrahlmühlen feingemahlen und gleichzeitig oder anschließend mit den Formulierungshilfsmitteln vermischt. Injectable powders are preparations which are uniformly dispersible in water and contain surfactants of the ionic and / or nonionic type (wetting agents, dispersants) in addition to the active ingredient except a diluent or inert substance. polyoxyethylated alkylphenols, polyoxethylated fatty alcohols, polyoxyethylated fatty alcohols, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignosulfonate, 2,2'-dinaphthylmethane-6,6'-d-isocyanuric acid, d ibutylnaphthalin-sulfonic acid sodium or oleoylmethyltaurine acid. To prepare the wettable powders, the herbicidal active compounds are finely ground, for example, in customary apparatus such as hammer mills, blower mills and air-jet mills and mixed simultaneously or subsequently with the formulation auxiliaries.
Emulgierbare Konzentrate werden durch Auflösen des Wirkstoffes in einem organischen Lösungsmittel z.B. Butanol, Cyclohexanon, Dimethylformamid, Xylol oder auch höhersiedenden Aromaten oder Kohlenwasserstoffen oder Mischungen der organischen Lösungsmittel unter Zusatz von einem oder mehreren Tensiden ionischer und/oder nichtionischer Art (Emulgatoren) hergestellt. Als Emulgatoren können beispielsweise verwendet werden: Alkylarylsulfonsaure Calzium-Salze wie
Ca-Dodecylbenzolsulfonat oder nichtionische Emulgatoren wie Fettsäurepolyglykolester, Alkylarylpolyglykolether, Fettal koholpolyglykolether, Propylenoxid-Ethylenoxid-Kondensationsprodukte, Alkylpolyether, Sorbitanester wie z.B. Sorbitanfettsäureester oder Polyoxethylensorbitanester wie z.B. Polyoxyethylen- sorbitanfettsäureester. Emulsifiable concentrates are prepared by dissolving the active ingredient in an organic solvent such as butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons or mixtures of organic solvents with the addition of one or more ionic and / or nonionic surfactants (emulsifiers). Examples of emulsifiers which may be used are: alkylarylsulfonic acid calcium salts, such as Ca-dodecylbenzenesulfonate or nonionic emulsifiers such as fatty acid polyglycol, Alkylarylpolyglykolether, Fettal koholpolyglykolether, propylene oxide-ethylene oxide condensation products, alkyl polyethers, sorbitan esters such as sorbitan or polyoxethylenesorbitanester such as polyoxyethylene sorbitanfettsäureester.
Stäubemittel erhält man durch Vermählen des Wirkstoffes mit fein verteilten festen Stoffen, z.B. Talkum, natürlichen Tonen, wie Kaolin, Bentonit und Pyrophyllit, oder Diatomeenerde. Dusts are obtained by milling the active ingredient with finely divided solids, e.g. Talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.
Suspensionskonzentrate können auf Wasser- oder Ölbasis sein. Sie können beispielsweise durch Naß-Vermahlung mittels handelsüblicher Perlmühlen und gegebenenfalls Zusatz von Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, hergestellt werden. Suspension concentrates may be water or oil based. They can be prepared, for example, by wet grinding using commercially available bead mills and, if appropriate, addition of surfactants, as described, for example, in US Pat. are already listed above for the other formulation types.
Emulsionen, z.B. ÖI-in-Wasser-Emulsionen (EW), lassen sich beispielsweise mittels Rührern, Kolloidmühlen und/oder statischen Mischern unter Verwendung von wässrigen organischen Lösungsmitteln und gegebenenfalls Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, herstellen. Emulsions, e.g. Oil-in-water emulsions (EW) can be prepared, for example, by means of stirrers, colloid mills and / or static mixers using aqueous organic solvents and optionally surfactants, as described, for example, in US Pat. listed above for the other formulation types.
Granulate können entweder durch Verdüsen des Wirkstoffes auf adsorptionsfähiges, granuliertes Inertmaterial hergestellt werden oder durch Aufbringen von Wirkstoffkonzentraten mittels Klebemitteln, z.B. Polyvinylalkohol, polyacrylsaurem Natrium oder auch Mineralölen, auf die Oberfläche von Trägerstoffen wie Sand, Kaolinite oder von granuliertem Inertmaterial. Auch können geeignete Wirkstoffe in der für die Herstellung von Düngemittelgranulaten üblichen Weise - gewünschtenfalls in Mischung mit Düngemitteln - granuliert werden. Granules can either be prepared by atomizing the active ingredient on adsorptive, granulated inert material or by applying active substance concentrates by means of adhesives, e.g. Polyvinyl alcohol, polyacrylic acid sodium or mineral oils, on the surface of carriers such as sand, kaolinites or granulated inert material. It is also possible to granulate suitable active ingredients in the manner customary for the production of fertilizer granules, if desired in admixture with fertilizers.
Wasserdispergierbare Granulate werden in der Regel nach den üblichen Verfahren wie Sprühtrocknung, Wirbelbett-Granulierung, Teller-Granulierung, Mischung mit Hochgeschwindigkeitsmischern und Extrusion ohne festes Inertmaterial hergestellt.
Zur Herstellung von Teller-, Fließbett-, Extruder- und Sprühgranulate siehe z.B. Verfahren in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; J.E. Browning, "Agglomeration", Chemical and Engineering 1967, Seiten 147 ff; "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York 1973, S. 8-57. Water-dispersible granules are generally prepared by the usual methods such as spray drying, fluidized bed granulation, plate granulation, mixing with high-speed mixers and extrusion without solid inert material. For the preparation of plate, fluidized bed, extruder and spray granules, see for example methods in "Spray-Drying Handbook" 3rd ed. 1979, G. Goodwin Ltd., London; JE Browning, "Agglomeration", Chemical and Engineering 1967, pages 147 ff .; Perry's Chemical Engineer's Handbook, 5th Ed., McGraw-Hill, New York 1973, pp. 8-57.
Für weitere Einzelheiten zur Formulierung von Pflanzenschutzmitteln siehe z.B. G.C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961 , Seiten 81 -96 und J . D. Freyer, S.A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, Seiten 101 -103. For further details on the formulation of crop protection agents see, e.g. G.C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96 and J. D. Freyer, S.A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.
Die agrochemischen Zubereitungen enthalten in der Regel 0, 1 bis 99 Gew.-%, insbesondere 0,1 bis 95 Gew.-%, erfindungsgemäße Mittel. The agrochemical preparations generally contain 0, 1 to 99 wt .-%, in particular 0.1 to 95 wt .-%, inventive compositions.
In Spritzpulvern beträgt die Wirkstoffkonzentration z.B. etwa 10 bis 90 Gew.-%, der Rest zu 1 00 G ew.-% besteht aus übl ichen Formul ierungsbestandteilen . Bei emulg ierbaren Konzentraten kann d ie Wirkstoffkonzentration etwa 1 bis 90, vorzugsweise 5 bis 80 Gew.-% betragen. Staubförmige Formulierungen enthalten 1 bis 30 Gew.-% Wirkstoff, vorzugsweise meistens 5 bis 20 Gew.-% an Wirkstoff, versprühbare Lösungen enthalten etwa 0,05 bis 80, vorzugsweise 2 bis 50 Gew.-% Wirkstoff. Bei wasserdispergierbaren Granulaten hängt der Wirkstoffgehalt zum Teil davon ab, ob die wirksame Verbindung flüssig oder fest vorl iegt und welche Gran ul ierh ilfsm ittel , Fül lstoffe usw. verwendet werden . Bei den in Wasser dispergierbaren Granulaten liegt der Gehalt an Wirkstoff beispielsweise zwischen 1 und 95 Gew.-%, vorzugsweise zwischen 10 und 80 Gew.-%. In wettable powders, the drug concentration is e.g. about 10 to 90 wt .-%, the remainder to 1 00 G ew .-% consists of übler formulation ingredients. In the case of emulsifiable concentrates, the active ingredient concentration may be about 1 to 90, preferably 5 to 80,% by weight. Dusty formulations contain 1 to 30 wt .-% of active ingredient, preferably usually 5 to 20 wt .-% of active ingredient, sprayable solutions contain about 0.05 to 80, preferably 2 to 50 wt .-% of active ingredient. In the case of water-dispersible granules, the active ingredient content depends, in part, on whether the active compound is liquid or solid and which granules, fillers, etc. are used. In the case of the water-dispersible granules, the content of active ingredient is, for example, between 1 and 95% by weight, preferably between 10 and 80% by weight.
Daneben enthalten die genannten Wirkstoffformulierungen gegebenenfalls die jeweils üblichen Haft-, Netz-, Dispergier-, Emulg ier-, Penetrations-, Konservierungs-, Frostschutz- und Lösungsmittel, Füll-, Träger- und Farbstoffe, Entschäumer, Verdunstungshemmer und den pH-Wert und die Viskosität beeinflussende Mittel. In addition, the active substance formulations mentioned optionally contain the customary adhesion, wetting, dispersing, emulsifying, penetrating, preserving, antifreezing and solvent, fillers, carriers and dyes, antifoams, evaporation inhibitors and the pH and the viscosity-influencing agent.
Beispielsweise ist bekannt, dass die Wirkung von Glufosinate-ammonium (A1 .2)
ebenso wie die seines L-Enantiomeren durch oberflächenaktive Substanzen verbessert werd en ka n n , vorzug swe ise d u rch N etzm ittel a u s d er Re i h e d er Al kyl- polyglykolethersulfate, die beispielsweise 10 bis 18 C-Atomen enthalten und in Form ihrer Alkali- oder Ammoniumsalze, aber auch als Magnesiumsalz verwendet werden, wie Ci2/Ci4-Fettalkohol-diglykolethersulfat-Natrium (®Genapol LRO, Hoechst); siehe EP-A-0 476 555, EP-A-0 048 436, EP-A-0 336 151 oder US 4,400,196 sowie Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227 - 232 (1988). Weiterhin ist bekannt, dass Alkyl-polyglykolethersulfate auch als Penetrationshilfsmittel und Wirkungsverstärker für eine Reihe anderer Herbizide, unter anderem auch für Herbizide aus der Reihe der Imidazolinone geeignet ist; siehe EP-A-0 502 014. For example, it is known that the effect of glufosinate-ammonium (A1 .2) as well as those of its L-enantiomer are improved by surface-active substances, preferably, sweetener Netzm ittel he re heed he Al kyl- polyglykolethersulfate containing, for example, 10 to 18 carbon atoms and in the form of their alkali or Ammonium salts, but also be used as magnesium salt, such as Ci 2 / Ci 4 fatty alcohol diglycol ether sulfate sodium (®Genapol LRO, Hoechst); see EP-A-0 476 555, EP-A-0 048 436, EP-A-0 336 151 or US 4,400,196 and Proc. EWRS Symp. "Factors Affecting Herbicidal Activity and Selectivity", 227-232 (1988). Furthermore, it is known that alkyl polyglycol ether sulfates is also suitable as a penetration aid and enhancer for a number of other herbicides, including for herbicides from the series of imidazolinones; see EP-A-0 502 014.
Zur Anwendung werden die in handelsüblicher Form vorliegenden Formulierungen gegebenenfalls in üblicher weise verdünnt, z.B. bei Spritzpulvern, emulgierbaren Konzentraten, Dispersionen und wasserdispergierbaren Granulaten mittels Wasser. Staubförmige Zubereitungen, Boden- bzw. Streugranulate, sowie versprühbare Lösungen werden vor der Anwendung üblicherweise nicht mehr mit weiteren inerten Stoffen verdünnt. For use, the formulations present in commercial form are optionally diluted in the customary manner, e.g. for wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules by means of water. Dust-like preparations, soil or scattering granules, as well as sprayable solutions are usually no longer diluted with other inert substances before use.
Die Wirkstoffe können auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche (Ackerboden) ausgebracht werden, vorzugsweise auf die grünen Pflanzen und Pflanzenteile und gegebenenfalls zusätzlich auf den Ackerboden. The active substances can be applied to the plants, plant parts, plant seeds or the acreage (field soil), preferably to the green plants and plant parts and optionally additionally to the field soil.
Eine Möglichkeit der Anwendung ist die gemeinsame Ausbringung der Wirkstoffe in Form von Tan km isch u ngen , wobei d ie optimal formu l ierten konzentrierten Formulierungen der Einzelwirkstoffe gemeinsam im Tank mit Wasser gemischt und die erhaltene Spritzbrühe ausgebracht wird. One possibility of the application is the joint application of the active ingredients in the form of tannic acids, in which the optimally formulated concentrated formulations of the individual active ingredients are mixed together in the tank with water and the spray mixture obtained is applied.
Eine gemeinsame herbizide Formulierung der erfindungsgemäßen Kombination an Wirkstoffen (A) und (B) hat den Vorteil der leichteren Anwendbarkeit, weil die Mengen der Komponenten bereits im richtigen Verhältnis zueinander eingestellt sind. Außerdem können die Hilfsmittel in der Formulierung aufeinander optimal abgestimmt werden,
wäh rend ei n Ta n k-mix von unterschiedlichen Formulierungen unerwünschte Kombinationen von Hilfstoffen ergeben kann. A common herbicidal formulation of the combination of active ingredients (A) and (B) according to the invention has the advantage of easier applicability because the amounts of the components are already set in the correct ratio to each other. In addition, the adjuvants in the formulation can be optimally matched to one another, while a combination of different formulations may produce undesirable combinations of excipients.
Formulierungsbeispiele formulation Examples
E i n Stä u be m itte l wi rd e rh a l te n , i n d e m m a n 1 0 G ew .-Teile einer erfindungsgemäßen Wirkstoffkombination und 90 Gew.-Teile Talkum als Inertstoff mischt und in einer Schlagmühle zerkleinert. In a controlled manner, 10 parts by weight of a combination of active ingredients according to the invention and 90 parts by weight of talc are mixed as inert material and comminuted in a hammer mill.
Ein in Wasser leicht dispergierbares, benetzbares Pulver wird erhalten, indem man 25 Gewichtsteile einer erfindungsgemäßen Wirkstoffkombination, 64 Gew.-Teile kaolinhaltigen Quarz als Inertstoff, 10 Gewichtsteile ligninsulfonsaures Kalium und 1 Gew.-Teil oleoylmethyltaunnsaures Natrium als Netz- und Dispergiermittel mischt und in einer Stiftmühle mahlt. A wettable powder which is readily dispersible in water is obtained by mixing 25 parts by weight of a combination of active ingredients according to the invention, 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of oleoylmethyltaunanoic acid as wetting and dispersing agent Pin mill grinds.
Ein in Wasser leicht dispergierbares Dispersionskonzentrat wird erhalten, indem man 20 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination mit 6 Gew.-Teilen Alkylphenolpolyglykolether (©Triton X 207), 3 Gew.-Teilen Isotridecanolpolyglykolether (8 EO) und 71 Gew.-Teilen paraffinischem Mineralöl (Siedebereich z.B. ca. 255 bis über 277 C) mischt und in einer Reibkugelmühle auf eine Feinheit von unter 5 Mikron vermahlt. A dispersion concentrate readily dispersible in water is obtained by mixing 20 parts by weight of a combination of active substances according to the invention with 6 parts by weight of alkylphenol polyglycol ether (© Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic Mineral oil (boiling range, for example, about 255 to about 277 C) mixed and ground in a ball mill to a fineness of less than 5 microns.
Ein emulgierbares Konzentrat wird erhalten aus 15 Gew.-Teilen einer erfindungsgemäßen Wirkstoffkombination, 75 Gew.-Teilen Cyclohexanon als Lösungsmittel und 10 Gew.-Teilen oxethyliertes Nonylphenol als Emulgator. An emulsifiable concentrate is obtained from 15 parts by weight of a combination of active substances according to the invention, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.
Ein in Wasser dispergierbares Granulat wird erhalten indem man A water-dispersible granules are obtained by
75 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination, 75 parts by weight of a combination of active substances according to the invention,
10 Gew.-Teile ligninsulfonsaures Calcium, 10 parts by weight of lignosulfonic acid calcium,
5 Gew.-Teile Natriumlaurylsulfat,
3 Gew.-Teile Polyvinylalkohol und 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and
7 Gew.-Teile Kaolin 7 parts by weight kaolin
mischt, auf einer Stiftmühle mahlt und das Pulver in einem Wirbelbett durch Aufsprühen von Wasser als Granulierflüssigkeit granuliert. f) Ein in Wasser dispergierbares Granulat wird auch erhalten, indem man milled, ground on a pin mill and granulated the powder in a fluidized bed by spraying water as Granulierflüssigkeit. f) A water-dispersible granules are also obtained by
25 Gew.-Teile einer erfindungsgemäßen Wirkstoffkombination, 25 parts by weight of a combination of active substances according to the invention,
5 Gew.-Teile 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonate sodium
2 Gew.-Teile oleoylmethyltaurinsaures Natrium, 2 parts by weight oleoylmethyltaurine acid sodium,
1 Gew.-Teil Polyvinylalkohol, 1 part by weight of polyvinyl alcohol,
17 Gew.-Teile Calciumcarbonat und 17 parts by weight of calcium carbonate and
50 Gew.-Teile Wasser 50 parts by weight of water
auf einer Kolloidmühle homogenisiert und vorzerkleinert, anschließend auf einer Perlmühle mahlt und die so erhaltene Suspension in einem Sprühturm mittels einer Einstoffdüse zerstäubt und trocknet. Homogenized on a colloid mill and pre-crushed, then grinded on a bead mill and the resulting suspension in a spray tower by means of a Einstoffdüse atomized and dried.
B. Biologische Beispiele B. Biological Examples
1 . Unkrautwirkung im Vorauflauf 1 . Weed effect in pre-emergence
Samen bzw. Rhizomstücke von mono- und dikotylen Unkrautpflanzen werden in Plastik- oder Papptöpfen in sandiger Lehmerde ausgelegt und mit Erde abgedeckt. Die in Form von konzentrierten wäßrigen Lösungen , benetzbaren Pulvern oder Emulsionskonzentraten formulierten Mittel werden dann als wäßrige Lösung, Suspension bzw. Emulsion mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha in unterschiedlichen Dosierungen auf die Oberfläche der Abdeckerde appliziert. Nach der Behandlung werden die Töpfe im Gewächshaus aufgestellt und unter guten Wachstumsbedingungen für die Unkräuter gehalten. Die optische Bonitur der Pflanzen- bzw. Auflaufschäden erfolgt nach dem Auflaufen der Versuchspflanzen nach einer Versuchszeit von 3 bis 4 Wochen im Vergleich zu unbehandelten Kontrollen. Wie die Testergebnisse zeigen, weisen die erfindungsgemäßen Mittel eine
gute herbizide Vorauflaufwirksamkeit gegen ein breites Spektrum von Ungräsern und Unkräutern auf. Seeds or rhizome pieces of monocotyledonous and dicotyledonous weed plants are placed in sandy clay soil in plastic or cardboard pots and covered with soil. The formulated in the form of concentrated aqueous solutions, wettable powders or emulsion concentrates are then applied as an aqueous solution, suspension or emulsion with a water application rate of 100 to 800 l / ha in different dosages on the surface of the cover soil. After treatment, the pots are placed in the greenhouse and kept under good growth conditions for the weeds. The visual assessment of plant damage or run-on damage occurs after emergence of the test plants after a test period of 3 to 4 weeks in comparison to untreated controls. As the test results show, the agents according to the invention have a good herbicidal pre-emergence activity against a broad spectrum of grass weeds and weeds.
Dabei werden häufig Wirkungen der erfindungsgemäßen Kombinationen beobachtet, die die formale Summe der Wirkungen bei Einzelapplikation der Herbizide übertreffen (= synergistische Wirkung). Frequently, effects of the combinations according to the invention are observed which exceed the formal sum of the effects in single application of the herbicides (= synergistic effect).
Wenn die beobachteten Wirkungswerte (= E) bereits die formale Summe (= EA= A+B) der Werte zu den Versuchen mit Einzelwirkstoffen übertreffen, dann übertreffen sie den Erwartungswert nach Colby (= Ec) ebenfalls, der sich nach folgender Formel errechnet und dessen Übertreffen ebenfalls als (Hinweis auf) Synergismus angesehen wird (vgl. S. R. Colby; in Weeds 15 (1967) S. 20 bis 22): If the observed effect values (= E) already exceed the formal sum (= E A = A + B) of the values for the tests with single active substances, then they exceed the expected value according to Colby (= E c ), which is calculated according to the following formula and whose surpassing is also regarded as (pointing to) synergism (see SR Colby, in Weeds 15 (1967) pp. 20 to 22):
Ec = Α+Β-(Α·Β/100) E c = Α + Β- (Α · Β / 100)
Dabei bedeuten: A, B = Wirkung der Wirkstoffe A bzw. B in % bei a bzw. b g AS/ha; Ec = Erwartungswert in % bei a+b g AS/ha. In this case: A, B = effect of the active compounds A or B in% at a or bg AS / ha; E c = expected value in% at a + bg AS / ha.
Die beobachteten Werte der Versuche zeigen bei geeigneten niedrigen Dosierungen eine Wirkung der Kombinationen, die über den Erwartungswerten nach Colby liegen. The observed values of the experiments show, at suitable low dosages, an effect of the combinations that are above the Colby Expected Values.
2. Unkrautwirkung im Nachauflauf 2. weed effect postemergence
Samen bzw. Rhizomstücke von mono- und dikotylen Unkräutern werden in Papptöpfen in sandigem Lehmboden ausgelegt, mit Erde abgedeckt und im Gewächshaus unter guten Wachstumsbedingungen angezogen. Drei Wochen nach der Aussaat werden die Versuchspflanzen im Zwei- bis Vierblattstadium mit den erfindungsgemäßen Mitteln behandelt. Die als Spritzpulver bzw. als Emulsionskonzentrate formul ierten erfindungsgemäßen Mittel werden in verschiedenen Dosierungen mit einer Wasseraufwandmenge von umgerechnet 100 bis 800 l/ha auf die grünen Pflanzenteile gesprüht. Nach ca. 3 bis 4 Wochen Standzeit der Versuchspflanzen im Gewächshaus
unter optimalen Wachstumsbedingungen wird die Wirkung der Präparate optisch im Vergleich zu unbehandelten Kontrollen bonitiert. Die erfindungsgemäßen Mittel weisen auch im Nachauflauf eine gute herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger Ungräser und Unkräuter auf. Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds are placed in sandy loam soil in cardboard pots, covered with soil and grown in the greenhouse under good growth conditions. Three weeks after sowing, the test plants are treated in the two- to four-leaf stage with the agents according to the invention. The formulations formulated as wettable powders or as emulsion concentrates inventive agents are sprayed in various dosages with a water application rate of 100 to 800 l / ha to the green parts of the plant. After about 3 to 4 weeks life of the test plants in the greenhouse Under optimal growth conditions, the effect of the preparations is scored visually in comparison to untreated controls. The compositions according to the invention also have a good herbicidal activity against a broad spectrum of economically important weed grasses and weeds in postemergence.
Dabei werden häufig Wirkungen der erfindungsgemäßen Kombinationen beobachtet, die die formale Summe der Wirkungen bei Einzelapplikation der Herbizide übertreffen. Die beobachteten Werte der Versuche zeigen bei geeigneten niedrigen Dosierungen eine Wirkung der Kombinationen, die über den Erwartungswerten nach Colby (vgl. Bonitur in Beispiel 1 ) liegen. Frequently, effects of the combinations according to the invention are observed which exceed the formal sum of the effects of single application of the herbicides. The observed values of the experiments show, at suitable low dosages, an effect of the combinations which are above the Colby expectation values (see rating in Example 1).
3. Herbizide Wirkung und Kulturpflanzenverträglichkeit (Feldversuch) 3. Herbicidal action and crop plant compatibility (field trial)
Pflanzen von transgenem Getreide mit einer Resistenz gegen ein oder mehrere Herbizide (A) werden zusammen mit typischen Unkrautpflanzen im Freiland auf Parzellen der Größe 2 x 5 m unter natürlichen Freilandbedingungen herangezogen; zusätzlich stellt sich beim Heranziehen der Getreidepflanzen noch eine Verunkrautung natürlich ein. Die Behandlung mit den erfindungsgemäßen Mitteln und zur Kontrolle separat m it allein iger Appl i kation der Komponentenwirkstoffe erfolgt unter Standardbedingungen mit einem Parzellen-Spritzgerät bei einer Wasseraufwandmenge von 100-400 Liter Wasser je Hektar in Parallelversuchen gemäß dem Schema aus Tabelle 1 , d. h. im Vorsaat-Vorauflauf, im Nachsaat-Vorauflauf oder im Nachauflauf im frühen, mittleren oder späten Stadium. Tabelle 3: Anwendungsschema - Beispiele Plants of transgenic cereals having resistance to one or more herbicides (A) are grown in open field on 2 x 5 m parcels under natural field conditions together with typical weed plants; In addition, when we take on the cereal plants, a weed infection naturally occurs. The treatment with the agents according to the invention and for the control with separate appli cation alone of the component active ingredients under standard conditions with a plot sprayer at a water application rate of 100-400 liters of water per hectare in parallel experiments according to the scheme of Table 1, d. H. in pre-sowing pre-emergence, after-sowing pre-emergence or post-emergence early, middle or late stages. Table 3: Application scheme - examples
Applikation Vorsaat Vorauflauf Nachauflauf Nachauflauf Nachauflauf der Wirkstoffe nach Saat 1 -2-Blatt 2-4-Blatt 6-Blatt kombiniert (A)+(B)
Applikation Vorsaat Vorauflauf Nachauflauf Nachauflauf Nachauflauf der Wirkstoffe nach Saat 1 -2-Blatt 2-4-Blatt 6-Blatt Application Pre-sowing Pre-emergence Post-emergence Post-emergence of active ingredients after sowing 1 -2-sheet 2-4-sheet 6-sheet combined (A) + (B) Application Pre-sowing Pre-emergence Post-emergence Post-emergence of active ingredients after sowing 1 -2-sheet 2-4-sheet 6-sheet
(A)+(B) (A) + (B)
(A)+(B) (A) + (B)
(A)+(B) (A) + (B)
(A)+(B) sequentiell (A) (B) (A) + (B) sequentially (A) (B)
(A) (B) (A) (B)
(A) (B) (A) (B)
(A) (A) (B) (A) (A) (B)
(A) (B) (B) (A) (B) (B)
(A) (A)+(B) (A) (A) + (B)
(B) (A) (B) (A)
(B) (A)+(B)
Applikation Vorsaat Vorauflauf Nachauflauf Nachauflauf Nachauflauf der Wirkstoffe nach Saat 1 -2-Blatt 2-4-Blatt 6-Blatt (B) (A) + (B) Application Pre-sowing Pre-emergence Post-emergence Post-emergence of active ingredients after sowing 1 -2-sheet 2-4-sheet 6-sheet
(A)+(B) (A)+(B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A)+(B) (A) + (B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A)+(B) (A) + (B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A)+(B) (A)+(B) (A) + (B) (A) + (B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A)+(B) (A) + (B) (A) + (B) (A) + (B)
(A)+(B) (A)+(B) (A) + (B) (A) + (B)
Im Abstand von 2 bis 8 Wochen nach Applikation wird die herbizide Wirksamkeit der Wirkstoffe bzw. Wirkstoffmischungen anhand der behandelten Parzellen im Vergleich zu unbehandelten Kontroll-Parzellen visuell bonitiert. Dabei wird Schädigung und Entwicklung aller oberirdischen Pflanzenteile erfaßt. Die Bonitierung erfolgte nach einer Prozentskala (100% Wirkung = alle Plfanzen abgestorben; 50 % Wirkung = 50% der Pflanzen und grünen Pflanzenteile abgestorben; 0 % Wirkung = keine erkennbare Wirkung = wie Kontrollparzelle. Die Boniturwerte von jeweils 2 - 4 Parzellen werden gemittelt.
Der Vergleich zeigte, dass die erfindungsgemäßen Kombinationen meist mehr, teilweise erheblich mehr herbizide Wirkung aufweisen als die Summe der Wirkungen der Einzelherbizide. Die Wirkungen liegen in wesentl ichen Abschn itten des Boniturzeitraums über den Erwartungswerten nach Colby (vgl. Bonitur in Beispiel 1 ) und weisen deshalb auf einen Synergismus hin. Die Getreidepflanzen dagegen wurden infolge der Behandlungen mit den herbiziden Mitteln nicht oder nur unwesentlich geschädigt. At intervals of 2 to 8 weeks after application, the herbicidal activity of the active compounds or active substance mixtures is scored visually on the basis of the treated parcels in comparison with untreated control parcels. Damage and development of all above-ground parts of plants are detected. The rating was based on a percentage scale (100% effect = all plants died, 50% effect = 50% of the plants and green parts of the plant died, 0% effect = no discernible effect = like control plot.) The rating values of 2 - 4 plots are averaged. The comparison showed that the combinations according to the invention usually more, sometimes considerably more herbicidal activity than the sum of the effects of the individual herbicides. The effects lie in much of the credit period over the expected values according to Colby (see rating in Example 1) and therefore point to a synergism. The cereal plants, however, were not or only slightly damaged as a result of the treatments with the herbicidal agents.
In den Tabellen allgemein verwendete Abkürzungen: g AS/ha = Gramm Aktivsubstanz (100 % Wirkstoff) pro Hektar Abbreviations generally used in the tables: g AS / ha = grams of active ingredient (100% active ingredient) per hectare
EA = Summe der herbiziden Wirkungen der Einzelapplikationen E A = sum of the herbicidal effects of the individual applications
(= Erwartungswert nach der Additionsmethode) (= Expected value after the addition method)
Ec = Erwartungswert nach Colby (vgl. Bonitur zu Tabelle 1 ) E c = expected value according to Colby (see rating to table 1)
"Getreide LL" = ®Liberty-Link-Getreide, das gegen Glufosinate-ammonium tolerant oder resistent ist, "Cereal LL" = ® Liberty Link corn which is tolerant or resistant to glufosinate-ammonium,
4. Herbizide Wirkung und Kulturpflanzenverträglichkeit (Gewächshausversuch) 4.1 Verwendete Materialien und Methoden 4. Herbicidal action and crop plant compatibility (greenhouse experiment) 4.1 Materials and methods used
Die Versuche wurden unter Gewächshausbedingungen durchgeführt (Versuchstöpfe, 8 cm Duchmesser, Sprühapplikation unter Verwendung von 300 I/Wasser pro Hektar, 2 Widerholungen, 6 bis 8 Pflanzen pro Topf). The experiments were carried out under greenhouse conditions (experimental pots, 8 cm diameter, spray application using 300 l / water per hectare, 2 repetitions, 6 to 8 plants per pot).
Die Applikation erfolgte als Nachauflauf Behandlung der Schadpflanzen und der Weizenpflanzen, wie in den Tabellen wiedergegeben. Zum Applikationszeitpunkt befa nd e n s ich d ie Sch ad pfl a nzen i m 2-4 Blatt Wachstumsstadium. Die Aufwandmengen der herbiziden Wirkstoffe, die alleine oder in Kombinationen angewendet wurden, werden in den einzelnen Ergebnistabellen angegeben.
Die Bonitur erfolgte durch visuellen Vergleich der behandelten mit den unbehandelten Kontrollen (0-100 %-Skala, 14 Tage nach der Applikation. Die Ergebnisse (Mittelwerte über alle Pflanzen pro Topf und Mittelwerte zweier Widerholungen pro Topf und Behandlung) werden in den folgenden Tabellen 4 bis 8 wiedergegeben. The application was carried out postemergence treatment of harmful plants and wheat plants, as shown in the tables. At the time of application, I found the plants in the 2-4 leaf stage of growth. The application rates of the herbicidal active compounds, which were used alone or in combinations, are given in the individual results tables. The scoring was done by visual comparison of the treated and untreated controls (0-100% scale, 14 days after application) The results (averages over all plants per pot and averages of two repetitions per pot and treatment) are shown in the following tables 4 to 8 reproduced.
4.2 Abkürzungen in den Tabellen 4 bis 6 4.2 Abbreviations in Tables 4 to 6
Aufwandmenge g /ai = Aufwandmenge in Gramm Wirkstoff pro Hektar Application rate g / ai = application rate in grams of active ingredient per hectare
ai = Wirkstoff (ausgehend von 100% Wirkstoffgehalt ) ai = active ingredient (based on 100% active ingredient content)
GA = Glufosinat-Ammonium GA = glufosinate-ammonium
Wheat tolerant Wheat tolerant
to GA = Weizen, der gegen GA tolerant ist (GMO) to GA = wheat tolerant to GA (GMO)
Ec = Erwartungswert nach Colby , (Ec =A+B - AxB/100) E c = expected value according to Colby, (E c = A + B - AxB / 100)
= für ternäre Kombinationen: (A+B) + C - (A+B) x C / 100 = for ternary combinations: (A + B) + C - (A + B) x C / 100
EA = Erwartungswert nach Additionsmethode (EA =A+B) E A = expected value according to addition method (E A = A + B)
Δ = Differenz (%) von beobachtetem Wert -%- vs. Erwartungswert (%) Δ = difference (%) of observed value -% - vs. Expected value (%)
(beobachtetem Wert minus Erwartungswert) (observed value minus expected value)
Untersuchung: - Beobachtete Werte für (A), (B) and (A) + (B) in % Examination: - Observed values for (A), (B) and (A) + (B) in%
Bewertung : - Beobachteter Wert (%) größer > als EC / EA : -> Synergismus (+Δ) Rating: - Observed value (%) greater> than E C / E A : -> Synergism (+ Δ)
- Beobachteter Wert (%) gleich = Ec / EA -> Additive Wirkung (+-0Δ )- Observed value (%) equals = E c / E A -> additive effect (+ -0Δ)
- Beobachteter Wert (%) kleiner < als EA / Ec -> Antagonismus (-Δ ) - Observed value (%) less <than E A / E c -> antagonism (-Δ)
4.3 Ergebnisse der Gewächshausversuche mit Kombinationen von Glufosinat- Ammonium (GA) A1 .1 mit B1 .1 und weiteren Partnern (C) auf Weizen (GA- tolerant) und Schadpflanzen 4.3 Results of greenhouse experiments with combinations of glufosinate-ammonium (GA) A1 .1 with B1 .1 and other partners (C) on wheat (GA tolerant) and harmful plants
Tabe l l e 4: Nutzpflanzenvertäglichkeit in Weizen (GA-tolerant) und herbizide Table 4: Crop tolerance to wheat (GA tolerant) and herbicides
Wirksamkeit gegenüber Matricaria chamomilla
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide Efficacy against Matricaria chamomilla Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit (%) gai/ha damage (%) effectiveness (%) gai / ha
Weizen (GA- Matricaria tolerant) chamomilla Wheat (GA-Matricaria tolerant) chamomilla
(A1.1) GA 100 10 50 (A1.1) GA 100 10 50
(B1.1) 5 0 20 (B1.1) 5 0 20
(A1.1) + (B1.1) 100 + 5 10 30 (A1.1) + (B1.1) 100 + 5 10 30
(Εε = 60;Δ-30)(Ε ε = 60, Δ-30)
(C5) Amidosulfuron 1,25 0 45 (C5) amidosulfuron 1.25 0 45
(A1.1 +B1.1) + C5 (100+5) +1,25 10 85 (A1.1 + B1.1) + C5 (100 + 5) +1.25 10 85
(Ec = 61;A+24)(E c = 61, A + 24)
(C 24) Fenoxaprop-p-et. 12,5 0 0 (C24) fenoxaprop-p-et. 12.5 0 0
(A1.1 + B1.1) + C24 (100+5)+ 12,5 0 50 (A1.1 + B1.1) + C24 (100 + 5) + 12.5 0 50
(Ec = 30; Δ +20)(E c = 30, Δ + 20)
(C9) Carfentrazone 7,5 10 0 (C9) Carfentrazone 7.5 10 0
(A1.1 +B1.1) + C9 (100 + 5) + 7,5 5 90 (A1.1 + B1.1) + C9 (100 + 5) + 7.5 5 90
(Εε = 30;Δ+60)(Ε ε = 30, Δ + 60)
( C32) Flurtamone 62,5 15 25 (C32) Flurtamone 62.5 15 25
(A1.1 +B1.1) + C32 (100 + 5) + 62,5 15 80 (A1.1 + B1.1) + C32 (100 + 5) + 62.5 15 80
(Ec = 48; Δ +32)(E c = 48, Δ + 32)
(C 37) Imazamox 5 15 0 (C 37) Imazamox 5 15 0
(A1.1 +B1.1) + C37 (100 + 5) + 5 15 85 (A1.1 + B1.1) + C37 (100 + 5) + 5 15 85
(Εε = 30;Δ+55)(Ε ε = 30, Δ + 55)
(C 58) Pinoxaden 5 0 0 (C 58) Pinoxaden 5 0 0
(A1.1 +B1.1) + C58 (100 + 5) + 5 5 70 (A1.1 + B1.1) + C58 (100 + 5) + 5 5 70
(Ec = 30; Δ +40)(E c = 30, Δ + 40)
(C60) Propoxycarbazone-Na 10 10 10 (C60) Propoxycarbazone-Na 10 10 10
(A1.1 + B1.1) + C60 (100 + 5) + 10 10 80 (A1.1 + B1.1) + C60 (100 + 5) + 10 10 80
(Ec = 37; Δ +43)(E c = 37, Δ +43)
(C61) Pyrasulfutole 25 0 50 (C61) Pyrasulfutole 25 0 50
(A1.1 + B1.1) + C61 (100+5) + 25 0 95 (A1.1 + B1.1) + C61 (100 + 5) + 25 0 95
(Εε = 65;Δ+30)(Ε ε = 65, Δ + 30)
(C 66) Thiencarbazone-me 0,375 5 10 (C 66) thiencarbazone-me 0.375 5 10
(A1.1 + B1.1) + C66 (100+5) + 0,375 10 80 (A1.1 + B1.1) + C66 (100 + 5) + 0.375 10 80
(Ec = 37; Δ +43)(E c = 37, Δ +43)
(C 71 )Tribenuron 0,5 0 0
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide (C 71) tribenuron 0.5 0 0 Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit (%) gai/ha damage (%) effectiveness (%) gai / ha
Weizen (GA- Matricaria tolerant) chamomilla Wheat (GA-Matricaria tolerant) chamomilla
(A1.1 +B1.1) + C71 (100+5) + 0,5 10 80 (A1.1 + B1.1) + C71 (100 + 5) + 0.5 10 80
(Εε = 30;Δ+50)(Ε ε = 30, Δ + 50)
(C 74) Metsulfuron 0,375 0 0 (C 74) Metsulfuron 0.375 0 0
(A1.1 +B1.1) + C74 (100+5) + 0,375 10 90 (A1.1 + B1.1) + C74 (100 + 5) + 0.375 10 90
(Εε = 30;Δ+60)(Ε ε = 30, Δ + 60)
(C42) Isoproturon 125 0 15 (C42) isoproturon 125 0 15
(A1.1 + B1.1) + C42 (100+5) + 125 0 90 (A1.1 + B1.1) + C42 (100 + 5) + 125 0 90
(Εε = 40;Δ+50) (Ε ε = 40, Δ + 50)
Tabelle 5: Nutzpflanzenvertäglichkeit in Weizen (GA-tolerant) und herbizide Table 5: Crop tolerance in wheat (GA tolerant) and herbicides
Wirksamkeit gegenüber Viola arvensis Efficacy against Viola arvensis
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit gai/ha damage (%) effectiveness gai / ha
Weizen (GA- (%) Wheat (GA- (%)
tolerant) Viola arvensis tolerant) Viola arvensis
(A1.1) GA 100 10 50 (A1.1) GA 100 10 50
(B1.1) 5 0 50 (B1.1) 5 0 50
(A1.1) + (B1.1) 100 + 5 10 30 (A1.1) + (B1.1) 100 + 5 10 30
(Εε = 75;Δ-45)(Ε ε = 75, Δ-45)
(C7) Bromoxynil 100 0 20 (C7) Bromoxynil 100 0 20
(A1.1 +B1.1) + C7 (100 + 5) + 100 0 50 (A1.1 + B1.1) + C7 (100 + 5) + 100 0 50
(Ec = 44; Δ +6)(E c = 44, Δ + 6)
(C 25) Florasulam 1,25 0 20 (C 25) Florasulam 1.25 0 20
(A1.1 + B1.1) + C25 (100+5) +1,25 10 60 (A1.1 + B1.1) + C25 (100 + 5) +1.25 10 60
(Εε = 44;Δ+16)(Ε ε = 44, Δ + 16)
(C 52) Mesosulfuron-me 2,5 0 0 (C 52) mesosulfuron-me 2.5 0 0
(A1.1 +B1.1) + C52 (100+5) + 2,5 15 60 (A1.1 + B1.1) + C52 (100 + 5) + 2.5 15 60
(Εε = 30;Δ+30)(Ε ε = 30, Δ + 30)
(C 43) MCPA 100 0 10 (C 43) MCPA 100 0 10
(A1.1 + B1.1) + C43 (100 + 5) + 100 0 50 (A1.1 + B1.1) + C43 (100 + 5) + 100 0 50
(Εε = 37;Δ+13)
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide (Ε ε = 37, Δ + 13) Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit gai/ha damage (%) effectiveness gai / ha
Weizen (GA- (%) Wheat (GA- (%)
tolerant) Viola arvensis tolerant) Viola arvensis
(C 57) Penoxulam 5 0 5 (C 57) Penoxulam 5 0 5
(A1.1 +B1.1) + C57 (100 + 5) + 5 0 50 (A1.1 + B1.1) + C57 (100 + 5) + 5 0 50
(Εε = 33;Δ+17) (Ε ε = 33, Δ + 17)
Tabelle 6: Nutzpflanzenvertaglichkeit in Weizen (GA-tolerant) und herbizide Table 6: Crop sustenance in wheat (GA tolerant) and herbicides
Wirksamkeit gegenüber Brassica napus (volunteer weed) Efficacy against Brassica napus (volunteer weed)
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit gai/ha damage (%) effectiveness gai / ha
Weizen (GA- (%) Wheat (GA- (%)
tolerant) Brassica tolerant) Brassica
napus napus
(A1.1) GA 100 10 15 (A1.1) GA 100 10 15
(B1.1) 5 0 60 (B1.1) 5 0 60
(A1.1) + (B1.1) (100 + 5) 0 30 (A1.1) + (B1.1) (100 + 5) 0 30
(Εε = 66;Δ-36)(Ε ε = 66, Δ-36)
(C12) Clodinafop 12,5 0 0 (C12) Clodinafop 12.5 0 0
(A1.1 + B1.1) + C 12 (100 + 5) + 12,5 10 65 (A1.1 + B1.1) + C 12 (100 + 5) + 12.5 10 65
(Εε = 30;Δ+35)(Ε ε = 30, Δ + 35)
(C 18) Diflufenican 50 10 30 (C18) diflufenican 50 10 30
(A1.1 + B1.1) + C 18 (100+5) + 50 10 70 (A1.1 + B1.1) + C18 (100 + 5) + 50 10 70
(Εε = 51;Δ+19)
(Ε ε = 51, Δ + 19)
Tabelle 7: Nutzpflanzenvertaglichkeit in Weizen (GA-tolerant) und herbizide Wirksamkeit gegenüber Setaria viridis Table 7: Crop sustenance in wheat (GA tolerant) and herbicidal activity against Setaria viridis
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide Active substance (ai) Application rate of crops Herbicides
gai/ha schädigung (%) Wirksamkeit gai / ha damage (%) effectiveness
(%) (%)
Weizen (GA- tolerant) Setaria viridis Wheat (GA tolerant) Setaria viridis
(A1.1) GA 100 10 90 (A1.1) GA 100 10 90
(A1.1) + (B1.1) 5 0 20 (A1.1) + (B1.1) 5 0 20
(A1.1) + B 1.1 (100 + 5) 10 ZQ (A1.1) + B 1.1 (100 + 5) 10 ZQ
(Εε = 92;Δ-22)(Ε ε = 92, Δ-22)
(C 28) Flufenacet 50 0 20 (C28) Flufenacet 50 0 20
(A 1.1) + (B 1.1) + C28 (100 + 5) + 50 10 97 (A 1.1) + (B 1.1) + C28 (100 + 5) + 50 10 97
(Εε = 76;Δ+21)(Ε ε = 76, Δ + 21)
(C 40) lodosulfuron-me-Na 1 0 10 (C 40) Iodosulfuron-Me-Na 1 0 10
(A 1.1 + B 1.1) + C40 (100+5) + 1 10 85 (A 1.1 + B 1.1) + C40 (100 + 5) + 1 10 85
(Εε = 72;Δ+13)(Ε ε = 72, Δ + 13)
(C 43) MCPA 100 0 0 (C 43) MCPA 100 0 0
(A 1.1 + B 1.1) + C43 (100 + 5) + 100 0 85 (A 1.1 + B 1.1) + C43 (100 + 5) + 100 0 85
(Εε = 70;Δ+15)(Ε ε = 70, Δ + 15)
(C 13) 2,4- D 50 0 0 (C 13) 2,4-D 50 0 0
(A 1.1 + B 1.1) + C 13 (100 + 5) + 50 0 90 (A 1.1 + B 1.1) + C 13 (100 + 5) + 50 0 90
(Ec = 70; Δ +20)
(E c = 70, Δ + 20)
Tabelle 8: Nutzpflanzenvertaglichkeit in Weizen (GA-tolerant) und herbizide Wirksamkeit gegenüber Lolium multiflorum Table 8: Crop sustenance in wheat (GA tolerant) and herbicidal activity against Lolium multiflorum
Wirkstoff (ai) Aufwandmenge NutzpflanzenHerbizide Active substance (ai) Application rate of crops Herbicides
schädigung (%) Wirksamkeit gai/ha damage (%) effectiveness gai / ha
Weizen (GA- (%) Wheat (GA- (%)
tolerant) Lolium tolerant) Lolium
multiflorum multiflorum
(A1.1) GA 100 10 15 (A1.1) GA 100 10 15
(B1.1) 5 0 0 (B1.1) 5 0 0
(A 1.1) + (B 1.1) (100 + 5) 10 15 (A 1.1) + (B 1.1) (100 + 5) 10 15
(Ec = 15;Δ+-0)(E c = 15, Δ + -0)
(C 62) Pyroxulam 1, 25 10 40 (C 62) Pyroxulam 1, 25 10 40
(A 1.1 + B 1.1) + C62 (100 + 5) + 1,25 15 70 (A 1.1 + B 1.1) + C62 (100 + 5) + 1.25 15 70
(Ec = 19; Δ- 4) (Εε = 49;Δ+21)(E c = 19, Δ- 4) (Ε ε = 49, Δ + 21)
(C 4) Mefenpyr-di-et 60 0 0 (C 4) Mefenpyr-di-et 60 0 0
(A 1.1 + B 1.1 + C62 + C4 (100 + 5) + 1,25 )+ 5 80 (A 1.1 + B 1.1 + C62 + C4 (100 + 5) + 1.25) + 5 80
C4 (Ec = 15; Δ - 10) (Ec = 15;Δ+65) safening
C4 (E c = 15; Δ-10) (E c = 15; Δ + 65) safening
Claims
1. Verwendung von Herbizid-Kombinationen zur Bekämpfung von Schadpflanzen in Getreidekulturen, dadurch gekennzeichnet, dass die jeweil ige Herbizid- Kombination ein Herbizid aus der Gruppe der Verbindungen der Formel (A1 ), 1. Use of herbicide combinations for combating harmful plants in cereal crops, characterized in that the respective herbicidal combination is a herbicide from the group of compounds of the formula (A1),
worin Z für Hydroxy, -NHCH(CH3)CONHCH(CH3)COOH -NHCH(CH3)CONHCH[CH2CH(CH3)2]COOH steht, oder dessen Ester oder Salze, und ein Herbizid der Formel (B1 ), wherein Z is hydroxy, -NHCH (CH 3 ) CONHCH (CH 3 ) COOH -NHCH (CH 3 ) CONHCH [CH 2 CH (CH 3 ) 2 ] COOH, or its ester or salts, and a herbicide of the formula (B1 )
worin X für N oder CH steht und R für C02H oder ein herbizid-aktives Derivat steht, enthält und die Getreidekulturen gegenüber den in der Kombination enthaltenen
Herbiziden (A) und (B) tolerant sind. wherein X is N or CH and R is C0 2 H or a herbicidally active derivative contains, and the cereal cultures over those contained in the combination Herbicides (A) and (B) are tolerant.
2. Verwendung gemäß Anspruch 1 , dadurch gekennzeichnet, dass die Herbizid- Kombination neben den Komponenten (A) und (B) wenigstens einen weiteren Wirkstoff aus der Gruppe der Safener, Pflanzenwachstumsregulatoren, Herbizide,2. Use according to claim 1, characterized in that the herbicide combination in addition to the components (A) and (B) at least one further active ingredient from the group of safeners, plant growth regulators, herbicides,
Fungizide oder Insektizide enthält. Contains fungicides or insecticides.
3. Verwendung gemäß Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Getreidekultur in Gegenwart eines Safeners gegen die Herbizid-Kombination tolerant ist. 3. Use according to claim 1 or 2, characterized in that the grain culture in the presence of a safener against the herbicide combination is tolerant.
4. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Herbizid-Kombination weiterhin Cloquintocet (-mexyl) (C1 ), Cyprosulfamide (C2), Isoxadifen(-ethyl) (C3) oder Mefenpyr (-diethyl) (C4) enthält. 4. Use according to one or more of claims 1 to 3, characterized in that the herbicide combination further Cloquintocet (-mexyl) (C1), Cyprosulfamide (C2), Isoxadifen (-ethyl) (C3) or Mefenpyr (-diethyl) (C4) contains.
5. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Herbizid-Kombination weiterhin Cyprosulfamide (C2), enthält. 5. Use according to one or more of claims 1 to 3, characterized in that the herbicide combination further Cyprosulfamide (C2), contains.
6. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass als Komponente (A) Glufosinate-Ammonium enthalten ist. 6. Use according to one or more of claims 1 to 4, characterized in that as component (A) glufosinate ammonium is contained.
7. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass das Getreide Weizen ist. 7. Use according to one or more of claims 1 to 6, characterized in that the grain is wheat.
8. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass die Getreidekultur weiterhin tolerant ist gegen Herbizide, die Acetolactatsynthase (ALS), EPSP Synthase oder Hydoxyphenylpyruvat Dioxygenase (HPPD) hemmen.
Verwendung gemäß Anspruch 8, dadurch gekennzeichnet, dass die Getreidekultur tolerant ist gegen wenigstens ein Sulfonylharnstoff-Herbizid, wenigstens ein Sulfonannid-Herbizid, Glyphosate, Mesotrione, Tembotrione, Topramezone, Bicyclopyrone oder Isoxaflutole. 8. Use according to one or more of claims 1 to 7, characterized in that the grain culture is further tolerant to herbicides which inhibit acetolactate synthase (ALS), EPSP synthase or Hydoxyphenylpyruvat Dioxygenase (HPPD). Use according to claim 8, characterized in that the grain culture is tolerant to at least one sulfonylurea herbicide, at least one sulfonanide herbicide, glyphosate, mesotrione, tembotrione, torame zone, bicyclopyrone or isoxaflutole.
0. Verwendung gemäß einem oder mehreren der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass die Komponente (B) ausgewählt ist aus 0. Use according to one or more of claims 1 to 9, characterized in that the component (B) is selected from
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0), 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure methylester (B1 .1 ), Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure ethylester (B1 .2), Ethyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .2),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-propylester (B1 .3), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-propyl ester (B1 .3),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1 .4), I-propyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1.4),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-butylester (B1 .5), 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-butyl ester (B1 .5),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butylester (B1 .6), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butyl ester (B1.6),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- tert-butylester (B1 .7),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- allylester (B1 .8), 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid tert-butyl ester (B1.7), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid allyl ester (B1 .8),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-nnethoxyphenyl)pyndin-2-carbonsäure- 2-butoxy-ethylester (B1 .9), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-n-ethoxyphenyl) pyndin-2-carboxylic acid 2-butoxyethyl ester (B1.9),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- triethylamnnoniunnsalz (B1 .10) und 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid triethylammonium salt (B1.10) and
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .1 1 ) 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid potassium salt (B1 .1 1)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure (B1 .12) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1 .12)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .13) Methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.13)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-ethylester (B1 .14) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid ethyl ester (B1 .14)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-propylester (B1 .15) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid n-propyl ester (B1 .15)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-i-propylester (B1 .16) I-propyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .16)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-butylester (B1 .17)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butylester (B1.18) N-butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .17) 2-Butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.18)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-tert-butylester (B1.19) Tert-butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.19)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-allylester (B1.20) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid allyl ester (B1.20)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butoxy-ethylester (B1.21 ) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1.21)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsaure-triethylamnnoniunnsalz (B1.22) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid triethylammonium salt (B1.22)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-Kaliumsalz (B1.23) 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid potassium salt (B1.23)
1. Verwendung gemäß Anspruch 10, dadurch gekennzeichnet, dass der Wirkstoff ( B ) a u s g ew ä h l t i s t a u s 4-Amino-3-chlor-6-(4-chlor-2-fluor-3- methoxyphenyl)pyridin-2-carbonsäure (B1.0) und 4-Amino-3-chlor-6-(4-chlor-2- fluor-3-methoxy-phenyl)pyridin-2-carbonsäure-methylester (B1.1 ) 1. Use according to claim 10, characterized in that the active ingredient (B) comprises more than 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxy-phenyl) -pyridine-2-carboxylate (B1.1)
2. Verwendung gemäß Anspruch 10, dadurch gekennzeichnet, dass der Wirkstoff (B) ausgewählt ist aus 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxy- phenyl)pyrimidin-4-carbonsäure (B1.12) und 6-Amino-5-chlor-2-(4-chlor-2-fluor-3- methoxyphenyl)pyrimidin-4-carbonsäure-methylester (B1.13) 2. Use according to claim 10, characterized in that the active ingredient (B) is selected from 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid ( B1.12) and methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.13)
3. Herbizides Mittel enthaltend Glufosinate-Ammonium und als Wirkstoff (B) eine Verbindung ausgewählt aus
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0), 3. A herbicidal composition containing glufosinate ammonium and as active ingredient (B) a compound selected from 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure - methylester (B1 .1 ), Methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure - ethylester (B1 .2), Ethyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .2),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-propylester (B1 .3), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-propyl ester (B1 .3),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure-i- propylester (B1 .4), I-propyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1.4),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- n-butylester (B1 .5), 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid n-butyl ester (B1 .5),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butylester (B1 .6), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butyl ester (B1.6),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- tert-butylester (B1 .7), 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid tert-butyl ester (B1.7),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-nnethoxyphenyl)pyndin-2-carbonsäure- allylester (B1 .8), 4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-n-ethoxyphenyl) pyndin-2-carboxylic acid allyl ester (B1 .8),
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- 2-butoxy-ethylester (B1 .4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid 2-butoxyethyl ester (B1.
9), 9)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-nnethoxyphenyl)pyndin-2-carbonsäure-
triethylammoniumsalz (B1 .4-amino-3-chloro-6- (4-chloro-2-fluoro-3-nnethoxyphenyl) pyridin-2-carboxylic acid triethylammonium salt (B1.
10), 10)
4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- Kaliumsalz (B1 .4-Amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid potassium salt (B1.
1 1 ), 1 1),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure (B1 .6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B1.
12), 12)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .Methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1.
13), 13)
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-ethylester (B1 .14), Ethyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .14),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-propylester (B1 .15), 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid n-propyl ester (B1 .15),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-i-propylester (B1 .16), I-propyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .16),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-n-butylester (B1 .17), N-butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .17),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butylester (B1 .18), 2-Butyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .18),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-tert-butylester (B1 .19), 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid tert-butyl ester (B1 .19),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-allylester (B1 .20),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-2-butoxy-ethylester (B1 .21 ), 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid allyl ester (B1 .20), 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid 2-butoxyethyl ester (B1 .21),
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsaure-triethylamnnoniunnsalz (B1 .22) und 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid triethylammonium salt (B1 .22) and
6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrinriidin-4- carbonsäure-Kaliumsalz (B1 .23). 6-Amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrinidine-4-carboxylic acid potassium salt (B1 .23).
14. Herbizides Mittel gemäß Anspruch 13, wobei der Wirkstoff (B) ausgewählt ist aus 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure (B1 .0) und 4-Amino-3-chlor-6-(4-chlor-2-fluor-3-methoxyphenyl)pyridin-2-carbonsäure- methylester (B1 .1 ). 14. A herbicidal composition according to claim 13, wherein the active ingredient (B) is selected from 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid (B1 .0) and methyl 4-amino-3-chloro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylate (B1 .1).
15. Herbizides Mittel gemäß Anspruch 13, wobei der Wirkstoff (B) ausgewählt ist aus 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4-carbonsäure (B 1 . 1 2 ) u nd 6-Amino-5-chlor-2-(4-chlor-2-fluor-3-methoxyphenyl)pyrimidin-4- carbonsäure-methylester (B1 .13). A herbicidal composition according to claim 13, wherein the active ingredient (B) is selected from 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylic acid (B 1 2) and methyl 6-amino-5-chloro-2- (4-chloro-2-fluoro-3-methoxyphenyl) pyrimidine-4-carboxylate (B1 .13).
16. Herbizides Mittel gemäß einem oder mehreren der Ansprüche 13 bis 15, enthaltend außerdem einen Safener und/oder ein weiteres Herbizid. 16. A herbicidal composition according to one or more of claims 13 to 15, further comprising a safener and / or another herbicide.
17. Herbizides Mittel gemäß einem oder mehreren der Ansprüche 1 3 bis 1 5, enthaltend au ßerdem Cloqu intocet(-mexyl) (C1 ), Cyprosulfamide (C2),17. A herbicidal composition according to one or more of claims 1 3 to 1 5, comprising, in addition, Cloqu intocet (-mexyl) (C1), cyprosulfamide (C2),
Isoxadifen(-ethyl) (C3) oder Mefenpyr(-diethyl) (C4). Isoxadifen (-ethyl) (C3) or Mefenpyr (-diethyl) (C4).
18. Herbizides Mittel gemäß einem oder mehreren der Ansprüche 1 3 bis 1 5, enthaltend außerdem Cyprosulfamide (C2).
18. A herbicidal composition according to one or more of claims 1 3 to 1 5, also containing Cyprosulfamide (C2).
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US8859465B2 (en) * | 2011-11-30 | 2014-10-14 | Dow Agrosciences, Llc. | Synergistic herbicidal composition containing penoxsulam and glufosinate-ammonium |
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NZ705215A (en) | 2012-09-04 | 2018-06-29 | Dow Agrosciences Llc | Synergistic weed control from applications of aminocyclopyrachlor and clopyralid |
BR102013024986B1 (en) | 2012-09-28 | 2022-03-03 | Dow Agrosciences Llc | Method for controlling undesirable vegetation |
BR102013025041B1 (en) | 2012-09-28 | 2022-11-08 | Dow Agrosciences Llc | HERBICIDIAL COMPOSITION, AND METHOD TO CONTROL UNDESIRABLE VEGETATION |
US9426991B2 (en) | 2012-12-12 | 2016-08-30 | Dow Agrosciences Llc | Synergistic weed control from applications of aminocyclopyrachlor and picloram |
US9149037B2 (en) | 2012-12-12 | 2015-10-06 | Dow Agrosciences Llc | Synergistic weed control from applications of aminocyclopyrachlor and 2,4 dichlorophenoxyacetic acid (2,4-D) |
KR20150097595A (en) | 2012-12-14 | 2015-08-26 | 다우 아그로사이언시즈 엘엘씨 | Synergistic weed control from applications of aminopyralid and clopyralid |
US10412964B2 (en) | 2012-12-14 | 2019-09-17 | Dow Agrosciences Llc | Synergistic weed control from applications of aminopyralid and clopyralid |
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- 2011-05-19 BR BR112012029616A patent/BR112012029616A2/en not_active IP Right Cessation
- 2011-05-19 CN CN201180036188XA patent/CN103025166A/en active Pending
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US20110287932A1 (en) | 2011-11-24 |
AU2011254591A1 (en) | 2012-12-06 |
US9253985B2 (en) | 2016-02-09 |
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