Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
  • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
  • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
  • C08G63/16—Dicarboxylic acids and dihydroxy compounds
  • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
  • C08G63/181—Acids containing aromatic rings
  • C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
  • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/28—Nitrogen-containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

Definitions

• the present invention relates to a thermoplastic resin itself which has excellent thermal conductivity and can be injection-molded.
• thermoplastic resin composition In a case where a thermoplastic resin composition is used for various applications such as housings of a personal computer and a display device, an electronic device material, and automotive exterior and interior parts, there sometimes occurs a problem that it is difficult to release generated heat because a plastic is less thermally conductive than an inorganic substance such as a metal material.
• an attempt has been extensively made to obtain a thermally conductive filler by adding, with a thermoplastic resin, a highly thermally conductive filler in a large amount.
• thermally conductive filler In order to obtain a thermally conductive filler, it is necessary to add, to a resin, a thermally conductive filler such as graphite, carbon fiber, alumina, or boron nitride generally in an amount of not less than 30 vol%, and further in a high amount, i.e., in an amount of not less than 50 vol%.
• thermal conductivity of a resin composition is limited even if a large amount of filler is added to a resin because the resin itself has low thermal conductivity. In view of the circumstances, improvement in thermal conductivity of a resin itself is demanded.
• Patent Literature 1 discloses an epoxy resin and Patent Literature 2 discloses a bismaleimido resin as a thermosetting resin itself having excellent thermal conductivity. Each of the resins is thermally conductive to some extent, whereas it is difficult to produce the resin because the resin has a complicated molecular structure. Patent Literature 3 discloses an epoxy resin which is synthesized with relative ease, however, does not have enough thermal conductivity.
• thermoplastic resin is exemplified by a resin molded product described in Patent Literature 4.
• the resin molded product is obtained as follows: thermal liquid crystal polyester is oriented by at least one external field selected from a flow field, a shear field, a magnetic field, and an electric field, so as to cause the thermal liquid crystal polyester to be highly thermally conductive in a direction in which the thermal liquid crystal polyester is oriented.
• the resin molded product is highly thermally conductive in one axis direction but less thermally conductive in the other two axis directions.
• the magnetic field at least 3 teslas of magnetic flux density is required to obtain a desired thermal conductivity. This makes it difficult to produce the resin molded product.
• Non Patent Literatures 1 to 4 describe alternating polycondensation products, showing liquid crystal phases, which are formed from mesogenic groups and alkyl chains. However, because a ratio of carboxyl groups to ends of each resin is about 50 mol%, thermal conductivity of the resin composition is less likely to improve when another filler is added. It is deduced that this is caused by a thermal resistance generated at a contact interface between a resin and a filler. Further, each of the Non Patent Literatures 1 to 4 does not disclose thermal conductivity of a resin itself nor adding of another filler.
• Patent Literature 5 discloses, as an example of thermal liquid crystal polyester having molecular chains whose ends could be carboxyl groups, aromatic polyester having a specific component which can be obtained by carrying out polymerization by use of the excessive number of aromatic dicarboxylic acid monomers.
• each liquid crystal polyester has low crystallinity because of its molecular structure, so that a resulting resin itself has low thermal conductivity.
• An object of the present invention is to provide such a thermoplastic resin that (i) the thermoplastic resin itself is excellent in thermal conductivity and (ii) in a case where a thermally conductive filler is added to the thermoplastic resin, a resultant resin composition becomes remarkably high in thermal conductivity.
• the inventors of the present invention have been diligently examined that a thermal resistance of a contact interface between resin and a thermally conductive filler could be reduced by providing, in ends of molecular chains of the resin, carboxyl groups which combines or has affinity with a thermally conductive filler.
• a thermoplastic resin which has a specific molecular structure and in which not less than 60 mol% of ends of molecular chains are carboxyl groups could achieve the object, and the inventors achieved the present invention.
• the present invention is as follows (1) to 14)).
• thermoplastic resin of the present invention (i) is excellent in thermal conductivity, and, (ii) in a case where a thermally conductive filler is added to the thermoplastic resin, a resultant resin composition becomes remarkably high in thermal conductivity.
• the term "mainly" in the present invention means, as for an amount of the substances expressed by the general formula (1) or the general formula (3) contained in the main chain of a molecular chain, that the amount is not less than 50 mol%, preferably not less than 70 mol%, more preferably not less than 90 mol%, and most preferably substantially not less than 100 mol%, with respect to total structural units.
• the resin may be less crystalline and thus less thermally conductive.
• a ratio of carboxyl groups with respect to all ends of molecular chains is not less than 60 mol%, preferably not less than 70 mol%, and more preferably not less than 80 mol%, and most preferably not less than 90 mol%. If the ratio of carboxyl groups is less than 60 mol%, the thermal conductivity of the resin composition becomes lower than that of a resin having the ratio of carboxyl groups of not less than 60 mol% when the thermally conductive filler is added.
• characteristic signals of ends is calculated from an integrated value of the characteristic signals corresponding to respective end groups by use of FT-IR if the characteristic signals cannot be identified by use of 1H-NMR.
• FT-IR FT-IR-IR-IR-IR-IR-IR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR-NMR
• thermoplastic resin of the present invention has mainly a chain structure.
• thermophysical property of the thermoplastic resin of the present invention generally indicates, in a temperature increasing process, (A) a transition point Tm from a solid phase to a liquid crystal phase and (B) a transition point Ti from a liquid crystal phase to an isotropic phase.
• phase transition points can be found out as peaks of heat absorption in a temperature increasing process of the DSC.
• thermal conductivity of the present invention represents thermal conductivity of a molded product in which a thermoplastic resin or a thermoplastic resin composition has been molded to a form suitable for measuring the thermal conductivity.
• a molded product used to evaluate thermal conductivity of resin itself or a resin composition is preferably molded at a temperature within the range from Tm or more and Ti or less. The molded product cannot be molded at a temperature of not more than Tm and the thermal conductivity of the resin itself or the resin composition sometimes decreases at a temperature of Ti or more.
• a method for molding resin is not particularly limited, however, the resin is preferably injection-molded in terms of easiness.
• Thermal conductivity of the thermoplastic resin according to the present invention is not less than 0.45 W/m ⁇ K, preferably not less than 0.6 W/m ⁇ K, more preferably not less than 0.8 W/m ⁇ K, and most preferably not less than 1.0 W/m ⁇ K.
• An upper limit of the thermal conductivity of the thermoplastic resin is not particularly limited. It is preferable that the thermoplastic resin have thermal conductivity as high as possible.
• the thermoplastic resin generally has thermal conductivity of not more than 30 W/m ⁇ K, and further, not more than 10 W/m ⁇ K provided that the thermoplastic resin (A) has a fusing point at which the thermoplastic resin is injection-molded and (B) is not subjected to physical treatments, such as magnetic field application, voltage application, rubbing, and extension, when the thermoplastic resin is formed.
• number average molecular mass of the thermoplastic resin of the present invention refers to a value obtained as follows: assuming that polystyrene is a reference material, the thermoplastic resin of the present invention is measured by GPC at 80 °C by use of a 0.25 wt% solution of the thermoplastic resin in a solvent of p-chlorophenol and o-dichlorobenzene mixed in a ratio of 1:2 (volume ratio).
• the thermoplastic resin of the present invention has a number average molecular mass preferably of 3000 to 40000. In view of an upper limit of the number average molecular mass, the thermoplastic resin has a number average molecular mass more preferably of 3000 to 30000, and particularly preferably of 3000 to 20000.
• the thermoplastic resin has a number average molecular mass preferably of 3000 to 40000, more preferably of 5000 to 40000, and particularly preferably of 7000 to 40000.
• the thermoplastic resin has a number average molecular mass more preferably of 5000 to 30000, and most preferably of 7000 to 20000.
• the thermoplastic resin which has a number average molecular mass of less than 3000 or more than 40000 may have thermal conductivity of not more than 0.45 W/(m ⁇ K) even if the tehrmoplastic resin has an identical primary structure.
• thermoplastic resin of the present invention contains lamellar crystals.
• an amount of lamellar crystals can be used as an indication of crystallinity. The greater the amount of lamellar crystals is, the higher the crystallinity is.
• lamellar crystal includes a plate crystal in which long chain molecules are folded so as to be juxtaposed to each other. It is easily determined, by means of transmission electron microscopic (TEM) observation or X-ray diffraction, whether or not such a crystal is contained in resin.
• TEM transmission electron microscopic
• a ratio of lamellar crystals having such a continuous layer structure to resin can be found by directly observing, by a transmission electron microscope (TEM), a sample dyed with RuO 4 .
• the ratio of lamellar crystals can be found by using, as a sample for TEM observation, an ultrathin slice which has a thickness of 0.1 ⁇ m and has been prepared, by a microtome, after cutting out a part of a molded sample (6 mm in thickness ⁇ 20 mm in diameter) and dying the part with RuO 4 .
• the ultrathin slice thus prepared is observed by TEM at an acceleration voltage of 100 kV, so as to obtain a photograph with a 40000 ⁇ scale (20 cm ⁇ 25 cm).
• the photograph allows determination of a lamellar crystal region.
• a boundary of the lamellar crystal region can be determined assuming that the lamellar crystal region is a region in which a periodic change occurs.
• the ratio of lamellar crystals is found as a ratio of the lamellar crystal region to a total area of the photograph.
• the ratio of lamellar crystals is preferably not less than 10 vol%.
• the ratio of lamellar crystals is more preferably not less than 20 vol%, more preferably not less than 30 vol%, and particularly preferably not less than 40 vol%.
• the thermoplastic resin of the present invention preferably contains crystals.
• the crystallinity of the thermoplastic resin is preferably not less than 7 %.
• the crystallinity of the thermoplastic resin is more preferably not less than 14 %, still more preferably not less than 21 %, and particularly preferably not less than 28 %.
• the resin itself has density preferably of not less than 1.1 g/cm 3 , more preferably of not less than 1.13 g/cm 3 , and particularly preferably of not less than 1.16 g/cm 3 .
• the resin having a high density means resin which contains a large amount of lamellar crystals, i.e., has a high crystallinity.
• the thermoplastic resin used in the present invention is preferably isotropically highly thermally conductive.
• a method for determining whether or not the thermoplastic resin is isotropically thermally conductive is exemplified by a method in which thermal conductivity in respective thickness and plane directions of a disk-shaped sample (1 mm in thickness ⁇ 25.4 mm in diameter) into which the thermoplastic resin is molded are separately measured by a Xe flash method.
• the thermoplastic resin according to the present invention is isotropically highly thermally conductive, and the thermal conductivity measured by the Xe flash method in the respective thickness and plane directions are generally 0.3 W/(m ⁇ K) or more.
• the mesogenic group M contained in the thermoplastic resin of the present invention means a substituent group which is rigid and highly-oriented.
• the mesogenic group M corresponds to a general formula (5) of the following general formula (1).
• each of A 1 and A 2 independently represents a substituent group selected from the group consisting of an aromatic group, a fused aromatic group, an alicyclic group, and an alicyclic heterocyclic group
• a 1 and A 2 are each independently selected from a hydrocarbon group having a C6 to C12 benzene ring, a hydrocarbon group having a C10 to C20 naphthalene ring, a hydrocarbon group a C12 to C24 biphenyl structure, a hydrocarbon group having three or more C12 to C36 benzene rings, a hydrocarbon group having a C12 to C36 fused aromatic group, and a C4 to C36 alicyclic heterocyclic group.
• a 1 and A 2 include: phenylene, biphenylene, naphthylene, anthracenylene, cyclohexyl, pyridyl, pyrimidyl, and thiophenylene.
• a 1 and A 2 can be non-substituent or a derivative which contains a substituent group such as an aliphatic hydrocarbon group, a halogen group, a cyano group, or a nitro group.
• a bivalent substituent group whose x, corresponding to the connector has a main chain length of even-numbered atoms is preferable.
• thermoplastic resin is more flexible due to an increase in molecular width of the mesogenic group and an increase in degree of freedom of bond rotation. This urges a decrease in crystallinity and would cause a decrease in thermal conductivity of resin itself.
• a preferable mesogenic group encompass: biphenyl, terphenyl, quarterphenyl, stilbene, diphenyl ether, 1,2-diphenylethylene, diphenylacetylene, benzophenone, phenylbenzoate, phenylbenzamide, azobenzene, azoxybenzene, 2-naphtoate, phenyl-2-naphtoate, and bivalent groups which have a structure in which two hydrogens are removed from a derivative or the like of such a mesogenic group as mentioned above.
• a preferable mesogenic group is not limited to those.
• a more preferable mesogenic group is a mesogenic group represented by the general formula (2).
• This mesogenic group is rigid and highly-oriented due to its structure, and can also be easily available or synthesized.
• X independently represents an aliphatic hydrocarbon group, F, Cl, Br, I, CN, or NO 2 ;
• n represents an integer from 0 to 4; and
• m represents an integer from 2 to 4.
• thermoplastic resin composition which has an excellent moldability
• a mesogenic group contained in a thermoplastic resin does not contain cross-linking substituent group.
• a spacer Sp contained in the thermoplastic resin means a flexible molecular chain, and contains a connector with the mesogenic group.
• the main chain length of the spacer of the thermoplastic resin is preferably from 4 to 28, more preferably 6 to 24, and still more preferably 8 to 20. If the main chain length of the spacer is less than 4, the thermoplastic resin may not have a satisfactorily flexible molecular structure. This sometimes reduces crystallinity and thermal conductivity. Meanwhile, if the main chain length is not less than 29, the crystallinity may decrease. This reduces the thermal conductivity.
• Kinds of atoms constituting the main chain of the spacer are not particularly limited, so that any atom can be used. However, the atom is preferably at least one kind of atoms selected from the group of C, H, O, S, and N.
• the spacer Sp corresponds to general formula (6) of the following general formula (1).
• R is preferably selected from a C2 to C20 chain saturated hydrocarbon group, a C2 to C20 saturated hydrocarbon group containing 1 to 3 ring structure(s), a C2 to C20 hydrocarbon group containing 1 to 5 unsaturated group(s), a C2 to C20 hydrocarbon group containing 1 to 3 aromatic ring(s), and a C2 to C20 polyether group containing 1 to 5 oxygen atom(s).
• R is preferably a linear aliphatic hydrocarbon chain which is not branched. R which is branched may urge the thermoplastic resin to be less crystalline and cause a decrease in thermal conductivity of resin itself.
• R may be saturated or unsaturated, but is preferably a saturated aliphatic hydrocarbon chain.
• R which contains an unsaturated bond may be insufficiently flexible and cause the thermoplastic resin to be less thermally conductive.
• R is preferably a linear saturated aliphatic hydrocarbon chain which has C2 to C20, more preferably a linear saturated aliphatic hydrocarbon chain which has C4 to C18, still more preferably a linear saturated aliphatic hydrocarbon chain which has C6 to C16, and particular preferably a linear saturated aliphatic hydrocarbon chain which has C8 to C 14.
• R preferably has a main chain length of even-numbered carbon atoms.
• R which has a main chain length of odd-numbered carbon atoms causes the mesogenic group to be tilted. This would cause the thermoplastic resin to be less crystalline and less thermally conductive.
• R is preferably at least one kind selected from -(CH 2 ) 8 -, -(CH 2 ) 10 -, and -(CH 2 ) 12 -.
• y and z are groups for bonding a substituent group R with the mesogenic group.
• spacers containing such groups -CO-OR-O-CO- and -O-CO-R-CO-O- are preferable, and -O-CO-R-CO-O- is particularly preferable for the sake of obtaining resin with an excellent thermal conductivity.
• thermoplastic resin according to the present invention can be produced by any publicly-known method.
• the thermoplastic resin is preferably produced by reacting (i) a compound in which the mesogenic group has reactive functional groups at its both ends and (ii) a compound in which the substituent group R has reactive functional groups at its both ends.
• a reactive functional group include publicly-known groups such as a hydroxyl group, a carboxyl group, an alkoxy group, an amino group, a vinyl group, an epoxy group, and a cyano group.
• a requirement under which such groups react with each other is not particularly limited.
• the thermoplastic resin is preferably produced by reacting (i) a compound in which the mesogenic group has hydroxyl groups at its both ends with (ii) a compound in which the substituent group R has carboxyl groups at its both ends.
• the thermoplastic resin is preferably produced by reacting (i) a compound in which the mesogenic group has carboxyl groups at its both ends with (ii) a compound in which the substituent group R has hydroxyl groups at its both ends, and is particularly preferably produced by excessively using a compound in which the substituent group R has carboxyl groups at its both ends.
• thermoplastic resin which contains (i) the compound in which the mesogenic group has hydroxyl groups at its both ends and (ii) the compound in which the substituent group R has carboxyl groups at its both ends.
• the mesogenic group which has hydroxyl groups at its both ends is reacted with a lower fatty acid such as acetic anhydride, so that the hydroxyl groups are converted to acetic ester individually or at one time. Thereafter, the resultant is subjected to a polycondensation reaction, in one reaction vessel or in different reaction vessels, for acetic acid elimination with the compound in which the substituent group R has carboxyl groups at its both ends.
• the polycondensation reaction is carried out, generally at a temperature in the range of 250 °C to 350 °C, and preferably at a temperature in the range of 270 °C to 330 °C, in the presence of substantially no solvent and in the presence of an inert gas such as nitrogen, under an ordinary pressure or under a reduced pressure, for 0.5 hour to 5 hours.
• the polycondensation reaction progresses slowly at a reaction temperature lower than 230 °C, whereas a side reaction such as degradation is likely to occur at a reaction temperature higher than 350 °C. In a case where the polycondensation reaction is carried out under a reduced pressure, it is preferable to gradually increase a decompression degree.
• Ultimate vacuum is preferably not more than 50 torr, more preferably not more than 30 torr, and particularly preferably not more than 10 torr. If the ultimate vacuum is more than 50 torr, it takes a long time to carry out the polycondensation reaction. Many phases of reaction temperature can be employed. Alternatively, a reaction product may be immediately taken out and collected in its molten state while the reaction temperature is increasing or when the reaction temperature reaches its maximum. The thermoplastic resin thus obtained may be used as it is.
• thermoplastic resin thus obtained may be used after an unreacted material is removed from the thermoplastic resin or the thermoplastic resin is subjected to solid phase polymerization so that the thermoplastic resin has a better physical property.
• the solid phase polymerization may be carried out as follows: The thermoplastic resin thus obtained is mechanically crushed into particles whose size is not more than 3 mm, and preferably not more than 1 mm. Then, the particles are preferably treated in a solid-phase state at a temperature in the range of 100 °C to 350 °C in an atmosphere of an inert gas such as nitrogen or under a reduced pressure for 1 hour to 20 hours.
• Examples of an acid anhydride of a lower fatty acid which acid anhydride is used to produce the thermoplastic resin of the present invention, encompass: acid anhydrides of lower fatty acids having a chain length of C2 to C5 such as acetic anhydride, propionic acid anhydride, monochloroacetic acid anhydride, dichloroacetic acid anhydride, trichloroacetic acid anhydride, monobromoacetic acid anhydride, dibromoacetic acid anhydride, tribromoacetic acid anhydride, monofluoroacetic acid anhydride, difluoroacetic acid anhydride, trifluoroacetic acid anhydride, butyric anhydride, isobutyric acid anhydride, valeric acid anhydride, and pivalic acid anhydride.
• acid anhydrides of lower fatty acids having a chain length of C2 to C5 such as acetic anhydride, propionic acid anhydride, monochloroacetic acid anhydride,
• acetic anhydride, propionic acid anhydride, and trichloroacetic acid anhydride are suitably used in particular.
• An acid anhydride of a lower fatty acid is used in an equivalent weight of 1.01 time to 1.50 time, and preferably of 1.02 time to 1.20 time with respect to a total amount of hydroxyl groups contained in the mesogenic group to be used.
• a method for producing a thermoplastic resin containing a compound having a carboxyl group at its both ends and a compound having a hydroxyl group at its both ends can be exemplified by a method for producing a thermoplastic resin, in which method transesterification is carried out by mixing a melted thermoplastic resin material in the presence of an appropriate catalyst.
• Examples of the catalyst encompass: germanium compounds such as germanium oxide; tin compounds such as stannous oxalate, stannous acetate, alkyl tin oxide, and diaryl tin oxide; titanium compounds such as titanium dioxide, titanalkoxides, and alkoxy titanium silicate; metallic salts of organic acid, such as sodium acetate, potassium acetate, calcium acetate, zinc acetate, and ferrous acetate; Lewis acids such as BF3 and AlCl3; inorganic acids such as amines, amides, hydrochloric acid, and sulfuric acid.
• germanium compounds such as germanium oxide
• tin compounds such as stannous oxalate, stannous acetate, alkyl tin oxide, and diaryl tin oxide
• titanium compounds such as titanium dioxide, titanalkoxides, and alkoxy titanium silicate
• metallic salts of organic acid such as sodium acetate, potassium acetate, calcium acetate, zinc acetate, and ferrous
• thermoplastic resin of the present invention may be copolymerized with another monomer, provided that the thermoplastic resin still can yield its effect.
• the another monomer encompass: aromatic hydroxycarboxylic acid, aromatic dicarboxylic acid, aromatic diol, aromatic hydroxylamine, aromatic diamine, aromatic aminocarboxylic acid, caprolactams, caprolactones, aliphatic dicarboxylic acid, aliphatic diol, aliphatic diamine, alicyclic dicarboxylic acid, alicyclic diol, aromatic mercaptocarboxylic acid, aromatic dithiol, and aromatic mercaptophenol.
• aromatic hydroxycarboxylic acid encompass: 4-hydroxybenzoic acid, 3-hydroxybenzoic acid, 2-hydroxybenzoic acid, 2-hydroxy-6-naphthoic acid, 2-hydroxy-5-naphthoic acid, 2-hydroxy-7-naphthoic acid, 2-hydroxy-3-naphthoic acid, 4'-hydroxyphenyl-4-benzoic acid, 3'-hydroxyphenyl-4-benzoic acid, and 4'-hydroxyphenyl-3-benzoic acid, each of which may or may not be substituted with an alkyl, alkoxy, or halogen.
• aromatic dicarboxylic acid encompass: terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, 1,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 4,4'-dicarboxybiphenyl, 3,4'-dicarboxybiphenyl, 4,4"-dicarboxyterphenyl, bis(4-carboxyphenyl)ether, bis(4-carboxyphenoxy)butane, bis(4-carboxyphenyl)ethane, bis(3-carboxyphenyl)ether, bis(3-carboxyphenyl)ethane, and the like, each of which may or may not be substituted with an alkyl, alkoxy, or halogen.
• aromatic diol encompass: hydroquinone, resorcin, 2,6-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 3,3'-dihydroxybiphenyl, 3,4'-dihydroxybiphenyl, 4,4'-dihydroxybiphenyl, 4,4'-dihydroxybiphenol ester, bis(4-hydroxyphenyl)ethane, 2,2'-dihydroxybinaphthyl, and the like, each of which may or may not be substituted with an alkyl, alkoxy, or halogen.
• aromatic hydroxylamine encompass: 4-aminophenol, N-methyl-4-aminophenol, 3-aminophenol, 3-methyl-4-aminophenol, 4-amino-1-naphthol, 4-amino-4'-hydroxybiphenyl, 4-amino-4'-hydroxybiphenyl ether, 4-amino-4'-hydroxybiphenyl methane, 4-amino-4'-hydroxybiphenyl sulfide, and 2,2'-diaminobinaphthyl, each of which may or may not be substituted with an alkyl, alkoxy, or halogen.
• aromatic diamine and the aromatic aminocarboxylic acid encompass: 1,4-phenylenediamine, 1,3-phenylenediamine, N-methyl-1,4-phenylenediamine, N,N'-dimethyl-1,4-phenylenediamine, 4,4'-diaminophenyl sulfide (thiodianiline), 4,4'-diaminobiphenyl sulfone, 2,5-diaminotoluene, 4,4'-ethylenedianiline, 4,4'-diaminobiphenoxyethane, 4,4'-diaminobiphenyl methane (methylenedianiline), 4,4'-diaminobiphenyl ether (oxydianiline), 4-aminobenzoic acid, 3-aminobenzoic acid, 6-amino-2-naphthoic acid, and 7-amino-2-naphthoic acid, each of which may or may not be substituted with an al
• aliphatic dicarboxylic acid encompass: oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, tetradecanedioic acid, fumaric acid, and maleic acid.
• aliphatic diamine encompass: 1,2-ethylenediamine, 1,3-trimethylenediamine, 1,4-tetramethylenediamine, 1,6-hexamethylenediamine, 1,8-octanediamine, 1,9-nonanediamine, 1,10-decanediamine, and 1,12-dodecanediamine.
• alicyclic dicarboxylic acid encompasses: linear or branched aliphatic diols such as hexahydroterephthalic acid, trans-1,4-cyclohexanediol, cis-1,4-cyclohexanediol, trans-1,4-cyclohexanedimethanol, cis-1,4-cyclohexanedimethanol, trans-1,3-cyclohexanediol, cis-1,2-cyclohexanediol, trans-1,3-cyclohexanedimethanol, ethylene glycol, propylene glycol, butylene glycol, 1,3-propanediol, 1,2-propanediol, 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, 1,10-decan
• aromatic mercaptocarboxylic acid encompasses: 4-mercaptobenzoic acid, 2-mercapto-6-naphthoic acid, 2-mercapto-7-naphthoic acid, benzene-1,4-dithiol, benzene-1,3-dithiol, 2,6-naphthalene-dithiol, 2,7-naphthalene-dithiol, 4-mercaptophenol, 3-mercaptophenol, 6-mercapto-2-hydroxynaphthalene, 7-mercapto-2-hydroxynaphthalene, and the like, and reactive derivatives thereof.
• a resin composition is prepared by adding a thermally conductive filler into the thermoplastic resin of the present invention. This can further improve thermal conductivity of the resin composition.
• the thermal conductivity of the resin composition is preferably not less than 0.4 W/(m ⁇ K), more preferably not less than 1.0 W/(m ⁇ K), and still more preferably not less than 5.0 W/(m ⁇ K), and particularly preferably not less than 10 W/(m ⁇ K). If the thermal conductivity is less than 0.4 W/(m ⁇ K), it is difficult to effectively conduct, to the outside, heat generated from an electric component.
• An upper limit of the thermal conductivity of the thermoplastic resin is not particularly limited.
• thermoplastic resin has thermal conductivity as high as possible, however, a thermoplastic resin whose thermal conductivity is not more than 100 W/(m ⁇ K), and further, not more than 80 W/(m ⁇ K) is generally used. Since the thermoplastic resin of the present invention has excellent thermal conductivity, it is easily possible to obtain a highly thermally conductive thermoplastic resin composition having thermal conductivity which falls within the above range.
• the usage amount of the thermally conductive filler contained in the thermoplastic resin of the present invention is preferably 90:10 to 30:70, more preferably 80:20 to 40:60, and particularly preferably 70:30 to 50:50 at a volume ratio of the thermoplastic resin to the thermally conductive filler. If the volume ratio of the thermoplastic resin to the thermally conductive filler is 100:0 to 90:10, satisfactory thermal conductivity cannot be obtained in some cases. If the volume ratio of the thermoplastic resin to the thermally conductive filler is 30:70 to 0:100, a mechanical property may decreases.
• thermoplastic resin of the present invention Since the thermoplastic resin of the present invention has excellent thermal conductivity, the usage amount of the thermally conductive filler is low (90:10 to 70:30) at the volume ratio of the thermoplastic resin to the thermally conductive filler, the resin composition exhibits excellent thermal conductivity, and in addition, can be less dence because the usage amount of thermally conductive filler is small.
• the resin composition which has excellent thermal conductivity and is less dense, is advantageous for use as a heat radiating or heat transmitting resin material for various fields such as electric, electronic, and automotive industries.
• thermally conductive filler can be extensively used as the thermally conductive filler.
• Thermal conductivity of the thermally conductive filler itself is preferably not less than 10 W/(m ⁇ K), more preferably not less than 15 W/(m ⁇ K), most preferably not less than 20 W/(m ⁇ K), and particularly preferably not less than 30 W/(m ⁇ K) is used.
• An upper limit of the thermal conductivity of the thermally conductive filler itself is not particularly limited. It is preferable that the highly thermally conductive compound has thermal conductivity as high as possible.
• the thermally conductive compound whose thermal conductivity is preferably not more than 3000 W/(m ⁇ K), and more preferably not more than 2500 W/(m ⁇ K) is generally used.
• thermally conductive filler In a case where the thermally conductive filler is used for an application in which an electric insulation property is not particularly required as a composition, a metal compound, a conductive carbon compound, or the like is preferably used.
• thermally conductive fillers such as: conductive carbon materials such as graphite and carbon fiber; conductive metal powder obtained by microparticulating various metals; conductive metal fiber obtained by fibrously processing various metals; and metal oxides such as ferrites including a soft magnetic ferrite and zinc oxide are preferably usable, in terms of excellent thermal conductivity.
• a compound which has an electric insulation property is preferably used.
• having an electric insulation property specifically means having an electric resistance of not less than 1 ⁇ cm. It is advantageous to use a compound which has an electric resistance preferably of not less than 10 ⁇ cm, more preferably of not less than 10 5 ⁇ cm, still more preferably of not less than 10 10 ⁇ cm, and most preferably of not less than 10 13 ⁇ cm.
• An upper limit of the electric resistance is not particularly limited.
• a compound which has an electric resistance of not more than 10 18 ⁇ cm is generally used. It is preferable that a molded product obtained from the highly thermally conductive thermoplastic resin composition of the present invention also has an electric insulation property falling within the above range.
• thermally conductive filler having electric insulation property encompass: metal oxides such as aluminum oxide, magnesium oxide, silicon oxide, beryllium oxide, copper oxide, and cuprous oxide; metal nitrides such as boron nitride, aluminum nitride, and silicon nitride; metal carbides such as silicon carbide; metal carbonates such as magnesium carbonate; insulating carbon materials such as diamond; and metal hydroxides such as aluminum hydroxide and magnesium hydrate. These compounds can be used solely or in combination of two or more kinds.
• the thermally conductive fillers can have various shapes. Examples of the various shapes encompass: particles, fine particles, nanoparticles, agglomerated particles, a tubular shape, a nanotubular shape, a wire shape, a rod shape, a needle shape, a plate shape, an amorphous shape, a rugby ball shape, a hexahedral shape, composite particles in which large particles and microparticles are mixed with each other, and a liquid.
• the thermally conductive fillers may be natural products or synthetic products. In the case of natural products, where they are come from is not particularly limited and they can be appropriately selected.
• the thermally conductive fillers can be used solely or in combination of two or more kinds which are different in shape, average particle size, kind, surface treatment agent, and the like.
• the thermally conductive fillers which increase adhesiveness at an interface between a resin and an inorganic compound and facilitate processability, can be subjected to a surface treatment carried out by use of various surface treatment agents such as a silane treatment agent.
• a surface treatment agent is not particularly limited, and conventionally publicly known surface treatment agents such as a silane coupling agent and a titanate coupling agent are usable.
• a silane coupling agent containing an epoxy group such as epoxy silane a silane coupling agent containing an amino group such as aminosilane, and a polyoxyethylene silane coupling agent are preferable because they are less likely to cause deterioration in properties of resin.
• a method for carrying out a surface treatment with respect to an inorganic compound is not particularly limited, and a general surface treatment method can be employed.
• Examples of a filler other than the thermally conductive fillers encompass: diatomite powder; basic magnesium silicate; calcined clay; micronized silica; quartz powder; crystalline silica; kaolin; talc; antimony trioxide; micronized mica; molybdenum disulfide; rock wool; ceramic fiber; inorganic fiber such as asbestos; and glass fillers such as glass fiber, glass powder, glass cloth, and molten silica.
• an organic filler such as: paper, pulp, and wood material; synthetic fibers including polyamide fiber, aramid fiber, and boron fiber; and resin powder including polyolefin powder can be blended in combination.
• the thermoplastic resin of the present invention can contain any publicly-known resin such as epoxy resin, polyolefin resin, bismaleimide resin, polyimide resin, polyether resin, phenol resin, silicone resin, polycarbonate resin, polyamide resin, polyester resin, fluororesin, acrylic resin, melamine resin, urea resin, and urethane resin, provided that the thermoplastic resin continues to yield an effect of the present invention.
• a preferable resin encompass: polycarbonate, polyethylene terephthalate, polybutylene terephthalate, a liquid crystal polymer, nylon 6, and nylon 6,6.
• a usage amount of each of the resins is 0 part by weight to 10000 parts by weight with respect to 100 parts by weight of the thermoplastic resin of the present invention contained in a resin composition.
• any other component such as a reinforcer, a thickner, a mold release agent, a coupling agent, a flame retarder, a flame-resistant agent, a pigment, a coloring agent, and other auxiliary agents can be added, as an additive other than the resins and the fillers mentioned above, to the thermoplastic resin of the present invention, provided that the thermoplastic resin continues to yield an effect of the present invention.
• a usage amount of additive is preferably 0 part by weight to 20 parts by weight in total with respect to 100 parts by weight of the thermoplastic resin.
• thermoplastic resin composition can be produced as follows: components, an additive, and/or the like mentioned above are dried, so as to be subjected to melt-kneading by use of a melt-kneading machine such as a single screw extruder or a double screw extruder.
• a melt-kneading machine such as a single screw extruder or a double screw extruder.
• a blended component is a liquid
• it is also possible to produce the thermoplastic resin composition by adding, in the middle of the melt-kneading, the liquid into the melt-kneading machine by use of a liquid supply pump or the like.
• thermoplastic resin of the present invention it is possible to extensively use for various applications such as an electronic material, a magnetic material, a catalytic material, a structure material, an optical material, a medical material, an automotive material, and an architectural material.
• thermoplastic resin has excellent properties of both remarkable molding workability and a high thermal conductivity, the thermoplastic resin is extremely useful as a heat-radiating/heat-conduvtive resin.
• thermoplastic resin of the present invention is suitably used for injection-molded products and extrusion-molded products of electric appliances, OA equipment parts, AV equipment parts, automotive exterior and interior parts, and the like.
• the thermoplastic resin of the present invention is particularly suitable used as a heat sink, a heat-radiation spacer, and an exterior part in electric appliances and in OA equipment which generates a large amount of heat.
• the thermally conductive resin composition of the present invention is preferably usable as an exterior part of such an electronic device so that heat generated inside the electronic device is radiated to outside the electronic device.
• thermoplastic resin of the present invention can be extremely preferably used for: (A) heat sinks, cases, housings, or external materials preferably of a portable computer such as a laptop personal computer and small-sized or portable electronic devices such as a PDA, a mobile phone, a portable game machine, a portable music player, a portable TV/video device, and a portable video camera; (B) a heat sink, a case, a housing, a lens holder, and the like of a projector; (C) cases for batteries and peripheral equipment of an automobile, an electric train, and the like; (D) cases and peripheral equipment for portable batteries of electric appliances; (E) power distribution parts such as various electric breakers, connectors, covers of the connectors; (F) a coil bobbin, a sealing material, a case for a motor, and the like; (G) heat sinks, cases, substrates, interior parts, and peripheral equipment of an LED bulb, an LED straight pipe bulb, organic EL illumination, and the like; (H) module members of a portable computer
• thermoplastic resin of the present invention can be more highly thermally conductive than conventionally-known resins, and has satisfactory molding workability. Therefore, the thermoplastic resin is useful for components or housings of the above-mentioned applications.
• thermoplastic resin of the present invention with reference to Examples and Comparative Examples.
• the present invention is not limited only to the Examples. Note that reagents produced by Wako Pure Chemical Industries, Ltd. were used as reagents described below if not otherwise specified.
• test piece obtained samples were dried and melted at a temperature 10 °C higher than a transition point Tm which is a point from a solid phase to a liquid crystal phase (specifically, by setting a cylinder temperature), and were molded into disc samples (6mm in thickness ⁇ 20 mm in diameter) by use of an injection-molding device.
• Thermal conductivities the disc samples (6 mm in thickness ⁇ 20 mm in diameter) were measured by use of a sensor of 4 in diameter in a hot disk method thermal conductivity measuring device produced by KYOTO ELECTRONICS MANUFACTURING CO., LTD.
• a sample solution was prepared by dissolving the thermoplastic resin of the present invention in a mixed solvent (1:2 volume ratio) of p-chlorophenol and o-dichlorobenzene so that the sample solution has a concentration of 0.25 wt%.
• Polystyrene [sold by Chemco Scientific Co., Ltd.; molecular weight (Mw/Mn): 390,000(1.06), 200,000(1.06), 65,000(1.06), 30,000(1.06), 3,350(1.10), 1,241(1.07)] was used as a reference material, so as to prepare a similar sample solution.
• thermoplastic resin A number average molecular mass of the thermoplastic resin was measured by high-temperature GPC (150-CV, produced by Waters Corporation) under the conditions of INJECTOR COMP: 80 °C, COLUMN COMP: 80 °C, PUMP/SOLVENT COMP: 60 °C, Injection Volume: 200 ⁇ l, flow rate: 0.7 ml/min.
• a differential refractometer (RI) was used as a detector.
• a mixture of 4,4'-dihydroxybiphenyl, dodecanedioic acid, and acetic anhydride at a molar ratio of 1.03:1:2.1 in which dodecanedioic acid was excess by 3 mol% was prepared in a reactor vessel. Further, sodium acetate (0.02 mol% with respect to 4,4'-dihydroxybiphenyl) was added as a catalyst. An acetylated reaction was carried out under an ordinary pressure in an atmosphere of nitrogen gas at 150 °C for an hour, and polycondensation was conducted in the reactor vessel heated to 260 °C at a rate of temperature increase of 1°C /min.
• thermoplastic resin and boron nitride powders (PT110, produced by Momentive Performance Materials Inc.; thermal conductivity itself: 60 W/(m ⁇ K); a volume average particle size: 45 ⁇ m; electrically insulative, a volume resistivity: 10 14 ⁇ cm) serving as a thermally conductive filler are mixed at a ratio of 50:50 Vol%.
• AO-60 produced by ADEKA CORPORATION which is a phenolic stabilizer was added to the mixture in 0.2 part by weight with respect to 100 parts by weight of thermoplastic resin.
• the mixtures were melt-mixed by use of Labo-plastomill (30C150, produced by TOYO SEIKI SEISAKU-SHO, LTD) at 210 °C for 7 minutes, so as to obtain resin compositions to be evaluated.
• the resin compositions were molded into disk-shaped samples (6 mm in thickness ⁇ 20 mm in diameter) by an injection molding machine, so as to measure thermal conductivity of the respective disk-shaped samples. Table 4 shows a result of the measurement.
• Example 2 Polymerization was carried out in the same way as that in Example 1, except that an excessive preparation amount of dodecanedioic acid of Example 1 was changed to 5 mol%, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Example 4 Polymerization was carried out in the same way as that in Example 2, except that dodecanedioic acid of Example 2 was changed to sebacic acid in Example 3 and was changed to tetradenanedioic acid in Example 4, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Example 2 Polymerization was carried out in the same way as that in Example 1, except that 4,4'-dihydroxybiphenyl and dodecanedioic acid of Example 1 were mixed in a ratio of 1:1 in Comparative Example 1 and in a ratio of 1.03:1 in Comparative Example 2, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• 4,4'-biphenyldicarboxylic acid and 1,10-decanediol were prepared in a molar ratio of 1.05:1 in a reactor vessel, and 5 ⁇ 10 -4 mol of TBT (tetrabutyl titanate) with respect to 1 mol of a constituent unit of polyester was added as a catalyst. Transesterification is carried out with respect to the mixture at a temperature of 280 °C, and water was distilled. Then, twenty minuites were spent to reduce the pressure inside the reactor vessel to 50 torr, and the resultant substance was subjected to polycondensation at 280 °C for 1.5 hours.
• TBT tetrabutyl titanate
• Example 5 Polymerization was carried out in the same way as that in Example 5, except that 1,10-decanediol was changed to triethylene glycol.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• thermoplastic resin Polymerization was carried out in the same way as that in Example 2, except that 4,4'-dihydroxybiphenyl was changed to 4-acetoxybenzoic acid-4-acetoxyphenyl, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Example 2 Polymerization was carried out in the same way as that in Example 2, except that 4,4'-dihydroxybiphenyl was changed to 4,4'-diacetoxyazoxybenzene, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Example 4 Polymerization was carried out in the same way as that in Example 1, except that a time period for polymerization under a reduced pressure of Example 1 was changed to 0 hour in Comparative Example 3and 6 hours in Comparative Example 4, thereby producing a resin having a different number average molecular mass.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Example 1 Polymerization was carried out in the same way as that in Example 1, except that (A) preparation materials of Example 1 were changed to 4,4'-dihydroxybiphenyl, dodecanedioic acid, 4-hydroxybenzoic acid, and acetic anhydride and (B) a mixture of 4,4'-dihydroxybiphenyl, dodecanedioic acid, 4-hydroxybenzoic acid, and acetic anhydride at a molar ratio of 1:1.05:2:3.1 in which dodecanedioic acid was excess by 5 mol% in a reactor vessel.
• a thermoplastic resin in which the resin of Example 1 is co-polymerized with 4-hydroxybenzoic acid was produced.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• GC plate-like graphite powder
• AO-60 produced by ADEKA CORPORATION
• AO-60 which is a phenolic stabilizer was added to the mixture in 0.2 parts by weight with respect to 100 parts by weight of thermoplastic resin.
• the mixture was melt-mixed by use of Labo-plastomill (30C150, produced by TOYO SEIKI SEISAKU-SHO, LTD) at 210 °C for 7 minutes, so as to obtain a resin composition to be evaluated.
• the resin composition was molded into a disk-shaped sample (6 mm in thickness ⁇ 20 mm in diameter) by an injection molding machine, so as to measure a thermal conductivity of the disc sample. Table 5 shows a result of the measurement.
• a mixture of 4,4'-dihydroxyphenyl, dodecanedioic acid, and acetic anhydride at a molar ratio of 1:1.1:2.1 in which dodecanedioic acid was excess by 10 mol% was prepared in a sealed reactor vessel provided with a reflux condenser, a thermometer, a nitrogen introduction tube, and a stirring rod. Further, sodium acetate (0.02 mol% with respect to 4,4'-dihydroxybiphenyl) was added as a catalyst. The mixture was reacted under an ordinary pressure in an atmosphere of nitrogen gas at 145 °C, thereby producing a uniform solvent.
• a temperature of the uniform solvent was increased to 260 °C at a rate of temperature increase of 2 °C/min while acetic acid was distilled, and was agitated for an hour at 260 °C. Forty minutes were spent to reduce the pressure inside the sealed reactor vessel to 10 torr with the temperature maintained at 260 °C. Then a decompression state was kept. After two hours from a start of reducing of the pressure, the pressure inside the reactor vessel was brought back to an ordinary pressure with nitrogen gas, and then a generated polymer was collected.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3.
• thermoplastic resin and boron nitride powders (h-BN) (PT110, produced by Momentive Performance Materials Inc.; thermal conductivity itself: 60 W/(m ⁇ K); a volume average particle size: 45 ⁇ m; electrically insulative, a volume resistivity: 10 14 ⁇ cm) serving as a thermally conductive filler are mixed at a ratio of 50:50 Vol%.
• AO-60 produced by ADEKA CORPORATION
• AO-60 which is a phenolic stabilizer was added to the mixture in 0.2 parts by weight with respect to 100 parts by weight of thermoplastic resin.
• the mixture was melt-mixed by use of Labo-plastomill (30C150, produced by TOYO SEIKI SEISAKU-SHO, LTD) at 210 °C for 7 minutes, so as to obtain a resin composition to be evaluated.
• the resin composition was molded into a disk-shaped sample (6 mm in thickness ⁇ 20 mm in diameter) by an injection molding machine, so as to measure a thermal conductivity of the disc sample. Table 4 shows a result of the measurement.
• Example 12 Polymerization was carried out in the same way as that in Example 12, except that dodecanedioic acid of Example 12 was changed to sebacic acid in Example 13 and was changed to tetradenanedioic acid in Example 14, thereby producing a thermoplastic resin.
• a molecular structure is shown in Table 2, and a ratio of carboxyl groups of ends, a number average molecular mass, and thermal conductivity of a resin itself are shown in Table 3. Further, a measurement result of thermal conductivity of a resin composition containing boron nitride powders is shown in Table 4, which is the same as Example 1.
• Table 2 Mesogenic group M Spacer Sp other than -M-Sp-[%] A 1 x A 2 y R z Ex.
• thermoplastic resin of the present invention has excellent thermal conductivity, and, in a case where thermally conductive filler was added to the thermoplastic resin, the resultant thermoplastic resin composition becomes remarkably high in thermal conductivity. Further, the thermoplastic resin can be injection-molded even by use of a general injection mold. Such composition is advantageous for use as a heat radiating or heat transmitting resin material in various fields such as electric, electronic, and automotive industries.

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