EP2540445B1 - Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel - Google Patents
Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel Download PDFInfo
- Publication number
- EP2540445B1 EP2540445B1 EP12167847.8A EP12167847A EP2540445B1 EP 2540445 B1 EP2540445 B1 EP 2540445B1 EP 12167847 A EP12167847 A EP 12167847A EP 2540445 B1 EP2540445 B1 EP 2540445B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- green body
- pore former
- oxalic acid
- pore
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000003082 abrasive agent Substances 0.000 title claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid group Chemical group C(C(=O)O)(=O)O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 118
- 238000000034 method Methods 0.000 claims description 38
- 235000006408 oxalic acid Nutrition 0.000 claims description 37
- 239000011148 porous material Substances 0.000 claims description 37
- 238000000354 decomposition reaction Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- 239000011230 binding agent Substances 0.000 claims description 24
- 239000001993 wax Substances 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 20
- 238000010304 firing Methods 0.000 claims description 12
- 238000003825 pressing Methods 0.000 claims description 9
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 8
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 8
- 150000001991 dicarboxylic acids Chemical group 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 150000004677 hydrates Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 238000005056 compaction Methods 0.000 claims 2
- 238000011084 recovery Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 28
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 25
- 238000000227 grinding Methods 0.000 description 20
- 230000008569 process Effects 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 229910001868 water Inorganic materials 0.000 description 11
- GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N activated carbon Substances [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 238000000859 sublimation Methods 0.000 description 5
- 230000008022 sublimation Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 206010006784 Burning sensation Diseases 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- UJBORAMHOAWXLF-UHFFFAOYSA-N 1-(aziridin-1-yl)octadecan-1-one Chemical compound CCCCCCCCCCCCCCCCCC(=O)N1CC1 UJBORAMHOAWXLF-UHFFFAOYSA-N 0.000 description 1
- 101000993093 Arabidopsis thaliana Heat stress transcription factor B-2a Proteins 0.000 description 1
- 229920001342 Bakelite® Polymers 0.000 description 1
- 241001522319 Chloris chloris Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 208000035904 Exposure to mould Diseases 0.000 description 1
- 239000008118 PEG 6000 Substances 0.000 description 1
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- 239000006061 abrasive grain Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004637 bakelite Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 244000240602 cacao Species 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000004455 differential thermal analysis Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000000622 irritating effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940068886 polyethylene glycol 300 Drugs 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/005—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used during pre- or after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/348—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties utilised as impregnating agent for porous abrasive bodies
Definitions
- the invention relates to a method for producing a bonded abrasive tool.
- Bound abrasive tools are widely used in the art for surface finishing. Such tools are, for example, grinding wheels, abrasive segments, grinding rods or honing stones.
- an abrasive for example corundum, silicon carbide, diamond or CBN of a desired grain size
- a binder in particular a ceramic binder
- This is pressed into a green body of the desired shape.
- the green body is then dried at suitable temperatures, optionally freed from pore formers and finally fired by a ceramic.
- such a tool should have a certain porosity, usually also a certain pore shape and size. It is therefore known to add to the mixture a pore-forming agent (usually naphthalene) which occupies corresponding proportions of space in the green body.
- a pore-forming agent usually naphthalene
- the pore-forming agent is removed by evaporation, sublimation or by burning. This can be done during the sintering process or in a temporally upstream process step at lower temperatures.
- naphthalene can be removed even at relatively low temperatures, namely by Sublimation at about 80 ° C.
- Other important advantages of naphthalene are the good miscibility with other formulation components and the very low springback after pressing, which prevents cracks in the green body. Finally, the removal is made possible at a relatively low temperature, in which the abrasive article is dried anyway and other components of the grinding wheel mixture, such. B. binding components, not yet activated.
- naphthalene as pore formers are its toxic and environmentally hazardous properties. Through an intense and typical odor, it pollutes the production facilities and the exhaust air and the surrounding area. Expenditures for occupational health and environmental protection dominate the corresponding manufacturing steps in the manufacturing process. Furthermore, naphthalene together with air can form explosive mixtures. Accordingly, costly and expensive safety precautions are required.
- the core of the invention lies in the use of the pore-forming agent defined according to the invention, which allows the production of a defined porosity without impairing the structural integrity of the green body.
- the dicarboxylic acids used according to the invention decompose on heating in decomposition products (in particular water and / or carbon monoxide / carbon dioxide), the decomposition process is preferably endothermic and can therefore be performed controlled without it by exothermic reactions to a local overheating of the green body with a possible impairment of the structural integrity can come.
- the pore-forming agent is preferably selected from the group consisting of oxalic acid, malonic acid and mixtures and hydrates of these acids. Particularly preferred is oxalic acid.
- the decomposition temperature of the pore-forming agent is preferably between 70 and 400 ° C.
- the decomposition of the pore-forming agent as well as the removal of the preferably complete or substantially gaseous decomposition products can therefore take place before the actual sintering temperature of the green body is reached.
- pores in the tool should be distributed as homogeneously as possible.
- the density of the pore-forming agent is similar to the density of the remaining constituents of the green body.
- the density of the pore-forming agent may preferably be between 1.5 and 2 g / cm 3 .
- the fraction of the pore-forming agent in the total weight of the green body may preferably be between 2 and 35% by weight, more preferably 2 and 25% by weight, more preferably 10 and 25% by weight, according to the invention.
- the heating In the endothermic decomposition of dicarboxylic acids, significant volumes of gas may be released. In order to release them in a controlled manner and without impairing the green body, it may be preferable to carry out the heating to or above the decomposition temperature of the pore-forming agent with a defined temperature control. Preference is given here to a heating rate of 2 to 40 ° C / h, more preferably 15 to 25 ° C / h. A heating rate in the lower region may be preferred if high pore fractions, such as> 55% by volume, are to be present.
- the pore-forming agent before heating to or above the decomposition temperature of the pore-forming agent additionally heating to a temperature below the decomposition temperature of the pore-forming agent, preferably 30 to 50 ° C, takes place and the green body is held at this temperature for a period of time in particular the evaporation of volatile components such as water or solvent allowed. Preferably, this period is between 24 and 48 h.
- the individual components are preferably combined in the order of abrasive grain, optional deformation aid, binder and pore former and combined to form a homogeneous mixture.
- Decisive for the homogeneity of the distribution of the pore-forming agent and thus of the pores in the final product are not exclusively the type and duration of the mixing process. Rather, it has been found that the density of the pore-forming agent in relation to the density of the other mixture components has a significant influence on the homogeneity of the mixture.
- oxalic acid dihydrate in contrast to naphthalene (1.14 g / cm 3) or wax (0.9 g / cm 3) to 1.65 g / cm 3, a density of the order of substantially mix constituents. Accordingly, a very uniform pore distribution was found in the abrasive bodies of the invention prepared with oxalic acid.
- the density of pure oxalic acid is 1.90 g / cm 3 .
- the weight loss distilled water of crystallization
- the surface of the abrasive article obtained according to Example 1 was divided into 6 different circle segments of 60 ° each. Within these segments, an area of 7 ⁇ 7 mm was selected in each of an inner and an outer area of the circle segment and the number of pores in these areas was counted. A deviation of ⁇ 10% was determined for all 12 surfaces, based on the highest or lowest number of pores determined.
- Oxalic acid dihydrate is plastically deformable in the solid state.
- the plastic deformability largely prevents springback after the shaping of the green body by pressing.
- Conventional compression pressures in this deformation can be in the range of about 30 to 220 bar (preferably based on the side surface of the green body or abrasive body to be produced).
- Strong springback which also affects the density of the fired abrasive article, can lead, for example, to cracks in the green body weakening the strength after removal from the press or after firing
- Decomposition means that the pore-forming agent undergoes a chemical reaction under the action of temperature, whereby at least two different reaction products are formed and these predominantly escape from the green body in a gaseous state.
- a disadvantage of the decomposition of oxalic acid for example compared to the sublimation of naphthalene, is the release of considerable volumes of gas. These can mechanically damage the green body, for example by microcracks, but also by large-scale cracking or structural distortions. As a result, such previously damaged grinding wheels do not have the required strength after firing and can not be used.
- the decomposition products formed in the course of the process behave inertly with respect to all customary formulation components such as abrasives and ceramic binders.
- the proportion of the pore-forming agent in the total weight of the green body is preferably between the two according to the invention 2 and 35 wt .-%, more preferably 2 and 25 wt .-%, more preferably 2 and 20 wt .-%.
- the pore volume of the abrasive article can be adjusted in the range of 30% to 80% total porosity, with the average pore size varying between 0.1 mm and 2.0 mm.
- Oxalic acid dihydrate may cause problems in industrial use. During processing, abrasion and dusts may occur which, on the one hand due to the acid content, are highly corrosive to production plants such as As mixers or molds can act and on the other hand can exert an irritant effect on mucous membranes as inhaled particulate matter. Also problematic when using oxalic acid dihydrate is the fact that when heated at a temperature of 100 ° C, crystal water is released (this temperature is well below the decomposition temperature of oxalic acid of 150 ° C). This release of water of crystallization carries the risk of volume change or cracking of the green body. The use of dried and thus free of crystallized oxalic acid in turn is problematic because on the one hand dried oxalic acid is hygroscopic and on the other hand, the problem of occupational safety (inhalation of dusts) is reinforced.
- a suitable binder can help ensure that the granules have sufficient resistance to crushing by pressure and shear stress. Further, when the granules are dried and water of crystallization of the oxalic acid is expelled, such a binder contributes to preventing or reducing the re-uptake of water.
- Suitable binders for solidifying the oxalic acid may be, for example, polyethylene glycols, polyvinylpyrrolidone or else waxes.
- examples include PEG6000 as a 40% aqueous solution or an aqueous solution of PVP (polyvinylpyrrolidone), for example, used as a 15 to 25% PVP solution.
- the oxalic acid as a whole with such a binder and solidify.
- binders can be used in the production of the green body, which make the abrasive body mass manageable and deformable as a temporary binder (also referred to as deformation aid) and give the green body sufficient strength after drying until the tool is made by burning the green body.
- PF0436SW13 from the company Momentive (temporary binder based on phenolic resin).
- waxes As non-polar substances, waxes have the advantage that they show no changes in their properties due to contact with water. Their properties thus remain unaffected by the processes of mixing, pressing and drying.
- wax is used in the context of the invention as defined in Ullmann's Encyclopedia of Industrial Chemistry, 6th edition, volume A39, page 135 et seq. Particularly suitable within the scope of the invention are waxes which are also oxidized at the decomposition temperature of oxalic acid (about 150.degree C) (the so-called debindering) still effect a sufficient solidification of the green body, so that it retains the intended shape and form during the so-called debindering.
- waxes are, for example, Zusoplast WE52 (Zschimmer & Schwarz, 56108 Lahnstein), various waxes from DEUREX GmbH, 06729 Elsteraue (for example WX9820 (polyolefin wax emulsion), MP2120 (polypropylene wax), MA7020 (ethylene stearamide wax)).
- suitable agents are the polyglycols already described above. They can be used not only for binding or inerting the oxalic acid, but also as a temporary binder in the context of the method according to the invention.
- the pasty mass was placed on sieves of mesh-size 500 microns and 1000 microns and pressed through the mesh with a brush and a soft plastic scraper.
- the mass was previously heated to 100 ° C over 4 h, in order to achieve the desired pasty consistency of the mixture with the then liquid wax.
- the green body is heated at 4 ° C./h to 90 ° C. and further from 90 ° C. to 165 ° C. at 2.5 ° C./h.
- the holding time at 165 ° C is 4 h.
- test abrasives correspond to Examples 3 and 4, Example 3 being an abrasive article of the invention and Example 4 being a prior art abrasive article EP 2 251143 A1 is.
- the modulus of elasticity and the density differ only slightly. The differences are within the usual manufacturing tolerances.
- the grinding wheels were subjected to a grinding test with the following test parameters: grinding machine Blohm HSF 6 with integrated force measuring unit Workpiece surface (width x length)] mm] 10x100 Workpiece material 100Cr6 Workpiece hardness [HRC] 60 +/- 1 Grinding speed [m / s] 33 Workpiece speed [m / min] 20 Delivery per stroke [ ⁇ m] 20 coolant Unimet AS 220 R5% dressing tool CVD Blattabrichter Measurement of tangential and normal forces continuous
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polishing Bodies And Polishing Tools (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12167847.8A EP2540445B1 (de) | 2011-06-29 | 2012-05-14 | Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel |
PL12167847T PL2540445T3 (pl) | 2011-06-29 | 2012-05-14 | Sposób wytwarzania narzędzia ze związanego materiału ściernego |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11171918 | 2011-06-29 | ||
EP12167847.8A EP2540445B1 (de) | 2011-06-29 | 2012-05-14 | Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2540445A1 EP2540445A1 (de) | 2013-01-02 |
EP2540445B1 true EP2540445B1 (de) | 2013-09-18 |
Family
ID=46044582
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12167847.8A Active EP2540445B1 (de) | 2011-06-29 | 2012-05-14 | Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2540445B1 (pl) |
PL (1) | PL2540445T3 (pl) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3231558A1 (en) | 2016-04-11 | 2017-10-18 | 3M Innovative Properties Company | A green body, a grinding wheel and a method for manufacturing at least a green body |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH710934A1 (de) | 2015-04-01 | 2016-10-14 | Reishauer Ag | Offenporiges, keramisch gebundenes Schleifwerkzeug, Verfahren zu seiner Herstellung sowie für seine Herstellung verwendete Porenbildnermischungen. |
WO2017050755A1 (de) | 2015-09-22 | 2017-03-30 | Reishauer Ag | Verfahren zur herstellung offenporiger, keramisch gebundener schleifwerkzeuge |
EP3205450A1 (de) * | 2016-02-09 | 2017-08-16 | Hermes Schleifkörper GmbH | Verfahren zur herstellung eines keramischen formkörpers |
EP3205449A1 (de) | 2016-02-09 | 2017-08-16 | Hermes Schleifkörper GmbH | Verfahren zur herstellung eines keramischen formkörpers |
CN106041767B (zh) * | 2016-07-12 | 2018-07-27 | 广东工业大学 | 一种带有内冷却微结构的树脂结合剂超硬磨具及其制造方法和应用 |
WO2021152456A1 (en) * | 2020-01-31 | 2021-08-05 | 3M Innovative Properties Company | Bonded abrasive articles and methods of manufacture |
CN114180923B (zh) * | 2021-12-29 | 2023-05-16 | 贺州学院 | 一种具有分层分级孔结构的免烧多孔陶粒及其制备方法 |
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AT389883B (de) * | 1986-08-21 | 1990-02-12 | Igel Schleifmittel | Schleifmittelzusammensetzung bzw. schleifmittel und verfahren zu deren herstellung |
DE4133191A1 (de) * | 1991-10-07 | 1993-04-08 | Basf Ag | Schleifmittel |
EP2251143B1 (de) | 2009-05-15 | 2011-11-23 | Hermes Schleifkörper GmbH | Verfahren zur Herstellung eines Werkzeugs aus gebundenem Schleifmittel |
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EP3231558A1 (en) | 2016-04-11 | 2017-10-18 | 3M Innovative Properties Company | A green body, a grinding wheel and a method for manufacturing at least a green body |
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