EP2468654B1 - Fermeture de récipient - Google Patents

Fermeture de récipient Download PDF

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Publication number
EP2468654B1
EP2468654B1 EP10196924.4A EP10196924A EP2468654B1 EP 2468654 B1 EP2468654 B1 EP 2468654B1 EP 10196924 A EP10196924 A EP 10196924A EP 2468654 B1 EP2468654 B1 EP 2468654B1
Authority
EP
European Patent Office
Prior art keywords
closure
seal
base
rib
outer seal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP10196924.4A
Other languages
German (de)
English (en)
Other versions
EP2468654A1 (fr
Inventor
Alexandre Rouquette
Lino Dreyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Obrist Closures Switzerland GmbH
Original Assignee
Obrist Closures Switzerland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP10196924.4A priority Critical patent/EP2468654B1/fr
Application filed by Obrist Closures Switzerland GmbH filed Critical Obrist Closures Switzerland GmbH
Priority to ES10196924.4T priority patent/ES2535320T3/es
Priority to CA2820567A priority patent/CA2820567A1/fr
Priority to MX2013005325A priority patent/MX2013005325A/es
Priority to NZ610137A priority patent/NZ610137A/en
Priority to PCT/EP2011/072039 priority patent/WO2012084514A1/fr
Priority to MA36108A priority patent/MA34825B1/fr
Priority to RU2013128775/12A priority patent/RU2013128775A/ru
Priority to AU2011347858A priority patent/AU2011347858B2/en
Priority to US13/824,972 priority patent/US20130256306A1/en
Priority to BR112013011387-1A priority patent/BR112013011387B1/pt
Priority to JP2013545167A priority patent/JP2014503434A/ja
Priority to CN201180060899.0A priority patent/CN103261044B/zh
Priority to ARP110104908A priority patent/AR084560A1/es
Publication of EP2468654A1 publication Critical patent/EP2468654A1/fr
Priority to IL226008A priority patent/IL226008A/en
Application granted granted Critical
Publication of EP2468654B1 publication Critical patent/EP2468654B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/16Closures not otherwise provided for with means for venting air or gas
    • B65D51/1633Closures not otherwise provided for with means for venting air or gas whereby venting occurs by automatic opening of the closure, container or other element
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/02Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
    • B65D41/04Threaded or like caps or cap-like covers secured by rotation
    • B65D41/0407Threaded or like caps or cap-like covers secured by rotation with integral sealing means
    • B65D41/0414Threaded or like caps or cap-like covers secured by rotation with integral sealing means formed by a plug, collar, flange, rib or the like contacting the internal surface of a container neck
    • B65D41/0421Threaded or like caps or cap-like covers secured by rotation with integral sealing means formed by a plug, collar, flange, rib or the like contacting the internal surface of a container neck and combined with integral sealing means contacting other surfaces of a container neck
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/16Closures not otherwise provided for with means for venting air or gas
    • B65D51/1633Closures not otherwise provided for with means for venting air or gas whereby venting occurs by automatic opening of the closure, container or other element
    • B65D51/1661Closures not otherwise provided for with means for venting air or gas whereby venting occurs by automatic opening of the closure, container or other element by means of a passage for the escape of gas between the closure and the lip of the container mouth

Definitions

  • the present invention relates to a closure according to the preamble of the independent claim.
  • Screw closures for containers with pressurized fluids such as carbonated beverages are widely known. If the pressure build-up in the container exceeds a desired level sufficient to overcome the thread engagement, the closure may be suddenly ejected from the container neck, an effect also called “closure missiling" which may lead to possible injury of users.
  • Closures for containers have therefore been developed, whereby excessive gas pressure in the container is decreased by automatic self-venting of the closure-container arrangement in the sense of a pressure control valve.
  • EP 0 858 416 discloses a closure with a base and a downwardly depending skirt defining the outside of the closure.
  • a bore seal downwardly depends from the base.
  • a stop also downwardly depends from the base. This stop acts to prevent over-tightening of corresponding screw threads located within the shell and on an associated container, and acts against the rim of the container.
  • the thickness of the base is thinned.
  • a rib of uniform thickness lying on the inside of the base extends from the bore seal towards the axial centre of the base and the bore seal is bulged radially outwardly by its presence in case of overpressure, whereby the container is vented.
  • the venting mechanism of EP 0 858 416 functions in that the thinned portion as described works as a hinge allowing the portion of the base, including the part which has the bore seal depending from it, to move upwards. Hence, the bore seal has to be lifted slightly from the inner side of the container neck to allow venting.
  • WO 2006/051068 discloses a closure suitable for self-venting of excessive gas by a rib which is lying on the surface of its base and in direct contact with a bore seal and transfers any movement of the centre of the base by excessive gas to that bore seal allowing venting.
  • EP1666370A1 discloses a self-venting closure cap according to the preamble of claim 1, in which excess pressure in a container can be vented as a result of movement of an inner circumferential portion of the upper part of the cap being translated to an inner seal projection, which is pulled radially inwardly to allow the venting of excess gas.
  • DE19847001A1 discloses a self-venting closure cap in which excess pressure in a container can be vented as a result of movement of an upper part of the cap being translated to a sealing lip, which is thereby translated upwards to allow the venting of excess gas via recessed portions of the lip.
  • GB932356A discloses a self-venting closure cap in which excess pressure in a container can be vented as a result of movement of a resilient flange in the form of a one-way lip valve that bears onto and seals against a closure member.
  • the invention provides a closure for a container comprising a circular base, a skirt extending from the periphery thereof, a plug seal in the form of an annulus, typically also called dive seal, and at least one rib lying on the surface of the base in a substantially radial direction.
  • the plug seal seals the closure against the inner side of the container.
  • the rib is in contact with the radially inner surface of the plug seal at one end for transferring any movement of the base, relative to the skirt, to the plug seal such that the plug seal is pulled radially inward to allow venting of excess pressure within the container.
  • An outer seal is arranged concentrically to the skirt. Such outer seal seals against an outer surface of the container and further centers the closure against the container and generates a counterforce to the plug seal supporting its sealing properties against the container neck.
  • the outer seal has at least one deformation portion which is weaker than a main fraction of the outer seal and which will interrupt partially the sealing effect of the outer seal in case overpressure occurs.
  • a deformation portion maintains the desired functionality of automatic self-venting, whereas, especially at normal gas and ambient temperature conditions in the container, the sealing effect at the position of such deformation portion is as effective as at the main fraction of the outer seal.
  • the deformation portion may be formed by locally reducing the size of the seal, e.g. its axial length and/or by its radial thickness.
  • the deformation portion might also be formed by influencing the material properties. The deformation portion may even break when extreme pressure conditions are built up inside the container.
  • the closure preferably comprises 6 main fraction and deformation portions, respectively, if the circular base has a diameter of 28mm.
  • the closure preferably comprises 8 or 9 main fractions and deformation portions, respectively, if the circular base has a diameter of 38mm.
  • the closure provides further preferably a top bulge located at the underside of the upper wall between the plug seal and the outer seal.
  • the top bulge features at least one gap whereby excessive gas can pass through. Thereby, in addition to the deformation portions, a defined route for the gas to escape strengthens the effect of self-venting.
  • the top bulge is arranged concentrically to and between the plug seal and the outer seal. There is some free radial space between the top bulge and the outer seal such that excessive gas can reach and pass the deformation portion.
  • the gap of the top bulge is circumferentially aligned with the deformation portion to guarantee a defined and direct route for excessive gas, thereby increasing the effect of the self-venting.
  • the outer seal of the closure is preferably arranged vertically to the circular base or may be inclined slightly radially inwardly or outwardly. Such inclination of the outer seal will reduce the surface contact and thereby reduce friction, in order to keep removal torques low.
  • the end of the rib in contact with the radially inner surface of the plug seal is preferably thinner, in a plane parallel to the base, than in a region spaced from the end of the rib in contact with the radially inner surface, in particular thinner than the other end of the rib.
  • a relatively thin contact to the plug seal brings several advantages such as a minimized reduction of the flexibility of the plug seal. Such an arrangement is described in WO 2006/051068 .
  • the deformation portion may be formed by reduction of the radial thickness of the outer seal.
  • the rib is aligned to a deformation portion in order to shorten the way of excessive gas when venting.
  • the deformation portions are preferably located in a constant circumferential distance to each other.
  • the radial angle included between the deformation portions is preferably between neighbourly internal sides of 34° to 50°, more preferably between 34° to 45°, most preferably 34° to 40°.
  • a constant distance between the deformation portion leads to a homogeneous force allocation and centering when the closure is applied to the container. Furthermore, self-venting is effected homogeneously over the whole circumference of the outer seal.
  • the thickness of those deformations portions is preferably between 0.3 to 0.5 mm, more preferably between 0.3 to 0.4 mm, as compared to a thickness of 0.7mm of the outer seal.
  • the circumferential length of the deformation portion is determined by a radial angle from the centre of the circular base including preferably between 6° to 30°, more preferably between 6° to 20° , most preferably between 6° to 15°.
  • FIG.1 shows an external view on a closure 10.
  • a base 20 is comprised as a circular upper fundament and depending downwardly from its periphery is a skirt 30.
  • FIG.2 shows approximately half of the closure shell 10 in cross-section.
  • the base 20 may be seen here and depending downwardly from its periphery is the skirt 30.
  • screw threads 40 Located at the inner surface of this skirt 30 are screw threads 40. These screw threads 40 cooperate with corresponding container screw threads 45 located on a radially outer surface of a container.
  • an olive type plug seal 50 is depending downwardly from the base 20 extending in a complete annulus as shown in FIG.3 and which seals with a radially projecting rib 51 against an inner side of a neck of a container.
  • a top bulge 70 acts as a limitation for the container progressing towards the base 20.
  • the top bulge 70 is interrupted with at least one gap 75 constituting a passage for excessive gas P and the gap of the top bulge 70 is aligned with the deformation portion as also shown in FIG.3 .
  • an outer seal 60 Concentrically to and as a next inner annulus to the skirt 30 is an outer seal 60 depending vertically from the base 20.
  • the outer seal 60 may also be slightly inclined radially inwardly or outwardly.
  • the outer seal 60 is provided with at least one deformation portion 65 which is relatively thinner than a main fraction 61 of the outer seal 60.
  • a rib 80 extends radially between a position of the base 20 and the inner surface of the plug seal 50.
  • FIG.3 shows a plan view of a part of the base of the closure.
  • FIG. 3 shows a base 20 which is substantially circular.
  • the plug seal 50 Depending downwardly from the base 20 and extending as a complete annulus from the centre of the base 20 is the plug seal 50, thereby providing a seal with an inside of a neck of a container as can be seen in FIG.1 .
  • the outer seal 60 is arranged concentrically to the skirt 30. At least one deformation portion 65 is shown as part of the outer seal 60 which is relatively thinner than the main fraction 61 of the outer seal 60.
  • the thickness of those deformation portions 65 is between 0.3 to 0.4 mm.
  • the radial angle between lateral sides of the deformation portions 65 is between 34° to 40° and includes a constant circumferential length between the deformation portions 65.
  • the circumferential length of the deformation portion 65 is determined by a radial angle of the circular base 20 including 6° to 15°.
  • Such closures comprise 8 or 9 deformation portions 65 and main fractions 61, respectively and their circular base 20 has a diameter of 38mm.
  • the closure with 8 deformation portions 65 and main fractions 61, respectively, comprises a thread 40 which is two-start.
  • the closure with 9 deformation portions 65 and main fractions 61, respectively, comprises a thread 40 which is three-start.
  • the top bulge 70 is located radially outwardly to the plug seal 50.
  • the top bulge 70 is placed between the plug seal 50 and the outer seal 60.
  • the top bulge 70 is thereby interrupted by at least one gap 75 defining a passage for excessive gas P during self-venting.
  • the rib 80 extends radially between a position of the base 20 and the inner surface of the plug seal 50. It may been seen in FIG.2 that the end 81 of the rib 80 contacting the inner surface of the plug seal 50 is thinner compared with the opposite end 84. It may be seen that the rib 80 has a first part 83 and a second part, the second part terminating at an end 81 in contact with the plug seal 50 and the first part 83 extending radially inwards from the other end of the second part. In a preferred embodiment, the first part 81 of the rib 80 is substantially stiffer than the second part 82.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)
  • Gasket Seals (AREA)

Claims (12)

  1. Fermeture (10) pour un récipient comprenant une base circulaire (20), une jupe (30) s'étendant à partir de la périphérie de celle-ci, un anneau d'étanchéité de bouchon (50) sous la forme d'un anneau et au moins une nervure (80) reposant sur la surface de la base (20) dans une direction sensiblement radiale et en contact avec la surface radialement intérieure de l'anneau d'étanchéité de bouchon (50) à une extrémité pour transférer tout mouvement de la base (20), par rapport à la jupe (30), à l'anneau d'étanchéité de bouchon (50) de sorte que l'anneau d'étanchéité de bouchon (50) soit tiré radialement vers l'intérieur pour permettre la mise à l'évent de la pression en excès dans le récipient, caractérisée en ce que la fermeture (10) est dotée d'un joint extérieur (60) ayant au moins une partie de déformation (65) pour déformer localement le joint extérieur (60) dans le cas d'une surpression pour partiellement interrompre sur la circonférence l'effet d'étanchéité du joint extérieur.
  2. Fermeture (10) selon la revendication 1 caractérisée en ce qu'une bosse supérieure (70) est située du côté inférieur de la base (20) et de façon concentrique et entre l'anneau d'étanchéité de bouchon (50) et le joint extérieur (60) et interrompue p au moins un intervalle (75).
  3. Fermeture (10) selon la revendication 2 caractérisée en ce que l'intervalle (75) de la bosse supérieure (70) est aligné avec la partie de déformation (65).
  4. Fermeture (10) selon l'une des revendications 1 à 3 caractérisée en ce que le joint extérieur (60) est incliné radialement vers l'intérieur.
  5. Fermeture (10) selon l'une des revendications 1 à 3 caractérisée en ce que le joint extérieur (60) est incliné radialement vers l'extérieur.
  6. Fermeture (10) selon l'une des revendications 1 à 5 caractérisée en ce qu'une extrémité (81) de la nervure (80) en contact avec la surface radialement intérieure de l'anneau d'étanchéité de bouchon (60) est plus mince, dans un plan parallèle à la base (20), que dans une zone de la nervure (80) disposée à l'écart rapport à la surface intérieure de l'anneau d'étanchéité de bouchon (50).
  7. Fermeture (10) selon l'une des revendications 1 à 6 caractérisée en ce que la nervure (80) possède une première partie (83) et une deuxième partie (82), la deuxième partie (82) se terminant à une extrémité (81) en contact avec l'anneau d'étanchéité de bouchon (50) et la première partie (83) s'étendant radialement vers l'intérieur à partir de l'autre extrémité de la deuxième partie (82).
  8. Fermeture (10) selon la revendication 7, dans laquelle la première partie (83) de la nervure (80) est globalement plus rigide que la deuxième partie (82).
  9. Fermeture (10) selon l'une des revendications 1 à 8 caractérisée en ce que la nervure (80) est alignée avec une partie de déformation (65).
  10. Fermeture (10) selon l'une des revendications 1 à 9 caractérisée en ce que les parties de déformation (65) sont écartées de manière constante et l'angle inclus entre les côtés latéraux des parties de déformation (65) est de préférence entre 34° et 50°, davantage de préférence entre 34° et 45°, de la façon la plus préférée entre 34° et 40°.
  11. Fermeture (10) selon l'une des revendications 1 à 10 caractérisée en ce que l'épaisseur des parties de déformation (65) est de préférence entre 0,3 et 0,5 mm, davantage de préférence entre 0,3 et 0,4 mm par comparaison avec une épaisseur de 0,7 mm du joint extérieur.
  12. Fermeture (10) selon l'une des revendications 1 à 11 caractérisée en ce qu'une longueur circonférentielle de la partie de déformation (65) est déterminée par un angle radial par rapport au centre de la base circulaire incluant de préférence entre 6° et 30°, davantage de préférence entre 6° et 20°, de la façon la plus préférée entre 6° et 15°.
EP10196924.4A 2010-12-23 2010-12-23 Fermeture de récipient Active EP2468654B1 (fr)

Priority Applications (15)

Application Number Priority Date Filing Date Title
ES10196924.4T ES2535320T3 (es) 2010-12-23 2010-12-23 Cierre para un envase
EP10196924.4A EP2468654B1 (fr) 2010-12-23 2010-12-23 Fermeture de récipient
JP2013545167A JP2014503434A (ja) 2010-12-23 2011-12-07 容器用クロージャ
NZ610137A NZ610137A (en) 2010-12-23 2011-12-07 Closure for a container
PCT/EP2011/072039 WO2012084514A1 (fr) 2010-12-23 2011-12-07 Dispositif de fermeture pour contenant
MA36108A MA34825B1 (fr) 2010-12-23 2011-12-07 Dispositif de fermeture pour contenant
RU2013128775/12A RU2013128775A (ru) 2010-12-23 2011-12-07 Крышка для контейнера
AU2011347858A AU2011347858B2 (en) 2010-12-23 2011-12-07 Closure for a container
CA2820567A CA2820567A1 (fr) 2010-12-23 2011-12-07 Dispositif de fermeture pour contenant
BR112013011387-1A BR112013011387B1 (pt) 2010-12-23 2011-12-07 Fechamento para um recipiente
MX2013005325A MX2013005325A (es) 2010-12-23 2011-12-07 Cierre para contenedor.
CN201180060899.0A CN103261044B (zh) 2010-12-23 2011-12-07 用于容器的闭合件
US13/824,972 US20130256306A1 (en) 2010-12-23 2011-12-07 Closure for a Container
ARP110104908A AR084560A1 (es) 2010-12-23 2011-12-22 Cierre para un recipiente
IL226008A IL226008A (en) 2010-12-23 2013-04-28 Lid for container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP10196924.4A EP2468654B1 (fr) 2010-12-23 2010-12-23 Fermeture de récipient

Publications (2)

Publication Number Publication Date
EP2468654A1 EP2468654A1 (fr) 2012-06-27
EP2468654B1 true EP2468654B1 (fr) 2015-03-04

Family

ID=43567958

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10196924.4A Active EP2468654B1 (fr) 2010-12-23 2010-12-23 Fermeture de récipient

Country Status (15)

Country Link
US (1) US20130256306A1 (fr)
EP (1) EP2468654B1 (fr)
JP (1) JP2014503434A (fr)
CN (1) CN103261044B (fr)
AR (1) AR084560A1 (fr)
AU (1) AU2011347858B2 (fr)
BR (1) BR112013011387B1 (fr)
CA (1) CA2820567A1 (fr)
ES (1) ES2535320T3 (fr)
IL (1) IL226008A (fr)
MA (1) MA34825B1 (fr)
MX (1) MX2013005325A (fr)
NZ (1) NZ610137A (fr)
RU (1) RU2013128775A (fr)
WO (1) WO2012084514A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10472134B1 (en) * 2013-01-07 2019-11-12 Celebrate Everywhere, LLC Container cap securing and venting
WO2017066868A1 (fr) 2015-10-23 2017-04-27 Husky Injection Molding Systems Ltd. Récipients et fermetures
GB2546518A (en) 2016-01-21 2017-07-26 Schlumberger Holdings Rotary cutting tools
GB201613126D0 (en) 2016-07-29 2016-09-14 Obrist Closures Switzerland A closure
US10407225B2 (en) * 2017-11-07 2019-09-10 Closure Systems International Inc. Closure and package that vents at high pressure
DE102018116295A1 (de) 2018-07-05 2020-01-30 Bericap Gmbh & Co. Kg Schraubverschluss mit kontrollierter Dichtung
CN112770978B (zh) * 2018-11-30 2022-12-16 京洛株式会社 带盖容器

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB932356A (en) * 1960-10-07 1963-07-24 Domestos Ltd Container and closure therefor
GB935574A (en) * 1961-09-30 1963-08-28 John Peter Hindley Improvements in or relating to closures for fluid containers
GB958417A (en) * 1961-11-08 1964-05-21 Metal Box Co Ltd Improvements in or relating to cap closures for containers
DE29623290U1 (de) 1995-10-31 1998-02-19 Safety Cap System AG, Steinhausen Verschluß für eine Flasche o.dgl.
TR200001076T2 (tr) * 1997-10-25 2000-08-21 Safety Cap System Ag Şişe ve benzerlerinin ağzını kapamaya yarayan plastik burma kapak.
EP0987190A1 (fr) * 1998-09-14 2000-03-22 Crown Cork & Seal Technologies Corporation Capuchon de fermeture
US6202870B1 (en) * 1999-03-29 2001-03-20 Woodrow W. Pearce Venting cap
EP1092638A1 (fr) * 1999-10-14 2001-04-18 Crown Cork & Seal Technologies Corporation Capsule en matière plastique
EP1097877A1 (fr) * 1999-11-08 2001-05-09 Crown Cork & Seal Technologies Corporation Capuchon de fermeture
JP3639285B2 (ja) * 2003-09-19 2005-04-20 株式会社アルコア・クロージャー・システムズ 合成樹脂製キャップ、閉止装置、および容器詰め飲料
EP1657177A1 (fr) 2004-11-11 2006-05-17 Crown Packaging Technology, Inc Bouchon avec évent automatique
EP1679267B1 (fr) * 2004-12-16 2011-03-30 Japan Crown Cork Co. Ltd. Bouchon en plastique ayant d'excellentes propriétés d'étanchéite et de ventilation

Also Published As

Publication number Publication date
CA2820567A1 (fr) 2012-06-28
AU2011347858A1 (en) 2013-06-06
MX2013005325A (es) 2013-09-18
IL226008A0 (en) 2013-06-27
CN103261044A (zh) 2013-08-21
US20130256306A1 (en) 2013-10-03
AR084560A1 (es) 2013-05-22
CN103261044B (zh) 2015-04-22
NZ610137A (en) 2014-06-27
BR112013011387A2 (pt) 2020-08-04
ES2535320T3 (es) 2015-05-08
IL226008A (en) 2016-08-31
AU2011347858B2 (en) 2015-10-29
EP2468654A1 (fr) 2012-06-27
JP2014503434A (ja) 2014-02-13
BR112013011387B1 (pt) 2021-06-22
WO2012084514A1 (fr) 2012-06-28
RU2013128775A (ru) 2015-01-27
MA34825B1 (fr) 2014-01-02

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