EP2414495A1 - Cleaning agent for floors - Google Patents
Cleaning agent for floorsInfo
- Publication number
- EP2414495A1 EP2414495A1 EP10707263A EP10707263A EP2414495A1 EP 2414495 A1 EP2414495 A1 EP 2414495A1 EP 10707263 A EP10707263 A EP 10707263A EP 10707263 A EP10707263 A EP 10707263A EP 2414495 A1 EP2414495 A1 EP 2414495A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning
- agent according
- cleaning agent
- acid
- agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 37
- -1 fatty alcohol sulfate Chemical class 0.000 claims abstract description 36
- 238000004140 cleaning Methods 0.000 claims abstract description 33
- 239000004094 surface-active agent Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 28
- 102000004190 Enzymes Human genes 0.000 claims description 13
- 108090000790 Enzymes Proteins 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 150000007513 acids Chemical class 0.000 claims description 10
- 239000004615 ingredient Substances 0.000 claims description 10
- 230000000845 anti-microbial effect Effects 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003599 detergent Substances 0.000 claims description 7
- 239000002585 base Substances 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000008139 complexing agent Substances 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000003082 abrasive agent Substances 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000000872 buffer Substances 0.000 claims description 2
- 239000000645 desinfectant Substances 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 239000010408 film Substances 0.000 claims description 2
- 239000003752 hydrotrope Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- 229920002125 Sokalan® Polymers 0.000 description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 235000002639 sodium chloride Nutrition 0.000 description 13
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 229940088598 enzyme Drugs 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 229960005150 glycerol Drugs 0.000 description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 10
- 239000004599 antimicrobial Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 150000004676 glycans Chemical class 0.000 description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 239000007844 bleaching agent Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 235000010338 boric acid Nutrition 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000008406 cosmetic ingredient Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- 229920000858 Cyclodextrin Polymers 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000002338 glycosides Chemical group 0.000 description 3
- 229960004592 isopropanol Drugs 0.000 description 3
- 239000004310 lactic acid Substances 0.000 description 3
- 235000014655 lactic acid Nutrition 0.000 description 3
- 229940094522 laponite Drugs 0.000 description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229920000388 Polyphosphate Polymers 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
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- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000010419 agar Nutrition 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
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- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
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- 239000002775 capsule Substances 0.000 description 2
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- 235000019820 disodium diphosphate Nutrition 0.000 description 2
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000174 gluconic acid Substances 0.000 description 2
- 235000012208 gluconic acid Nutrition 0.000 description 2
- 125000003827 glycol group Chemical group 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
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- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
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- 150000002989 phenols Chemical class 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
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- 239000001205 polyphosphate Substances 0.000 description 2
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- 230000008569 process Effects 0.000 description 2
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- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
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- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
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- 239000001488 sodium phosphate Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
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- 239000000196 tragacanth Substances 0.000 description 2
- 229940116362 tragacanth Drugs 0.000 description 2
- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
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- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- FMYOMWCQJXWGEN-WYRLRVFGSA-M sodium;(2r,3r,4s,5r,6r)-2,3,4,5,6,7-hexahydroxyheptanoate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)C([O-])=O FMYOMWCQJXWGEN-WYRLRVFGSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- FYZXEMANQYHCFX-UHFFFAOYSA-K tripotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].[K+].[K+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O FYZXEMANQYHCFX-UHFFFAOYSA-K 0.000 description 1
- 229940117565 trisodium dicarboxymethyl alaninate Drugs 0.000 description 1
- 229940048198 trisodium hedta Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- WHNXAQZPEBNFBC-UHFFFAOYSA-K trisodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O WHNXAQZPEBNFBC-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the invention relates to an aqueous surfactant-containing cleaning composition for hard surfaces, a C 6 -C 0 fatty alcohol sulfate as well as 0.5 to 10 wt .-% glycerol contains.
- the agent is especially suitable for cleaning floors.
- aqueous cleaner which is more wet than conventional floor cleaners, but which dries faster due to poorer wetting behavior, thereby sparing sensitive surfaces. Furthermore, a reduced foaming and a good residue behavior are also desirable with good cleaning performance.
- an aqueous surfactant-containing detergent with a short chain (C 6 -C 0) anionic surfactant and 0.5 to 10 wt .-% glycerol over conventional damp applicable cleaners having a significantly improved and thereby streak-free cleaning results, because it a wet application is suitable.
- This invention is accordingly an aqueous surfactant-containing cleaning composition for hard surfaces, a C 6 -C 0 fatty alcohol sulfate as well as 0.5 to 10 wt .-% glycerol contains.
- the cleaning agent can be used for cleaning hard surfaces, especially for floor cleaning.
- Another subject of the invention is therefore the use of a cleaning agent according to the invention for cleaning hard surfaces, in particular for floor cleaning.
- the indication CAS means that the following sequence of numbers is a name of the Chemical Abstracts Service.
- the cleaning formulation according to the invention contains as surfactant a C 6 -C 10 fatty alcohol sulfate. In addition, it may contain one or more other surface-active substances. Suitable surface-active substances for the compositions according to the invention are, in particular, surfactants from the classes of anionic and nonionic surfactants.
- Suitable anionic surfactants are preferably C 8 -C 8 -alkylbenzenesulfonates, in particular having about 12 C atoms in the alkyl moiety, C 8 -C 2 0-alkanesulfonates, C 6 -C 8 -monoalkyl sulfates, C 6 -C 8 -alkyl polyglycol ether sulfates with 2 to 6 ethylene oxide units (EO) in the ether part and sulfosuccinic mono- and di-C 8 -C 18 alkyl esters.
- C 8 -C 8 -alkylbenzenesulfonates in particular having about 12 C atoms in the alkyl moiety
- C 8 -C 2 0-alkanesulfonates C 6 -C 8 -monoalkyl sulfates
- C 8 -C 18 - ⁇ - olefinsulfonates sulfonated C 8 -C 8 fatty acids, especially dodecyl benzene sulfonate, C 8 -C 22 - Carbonklareamidethersulfate, C 8 -C 8 -Alkylpolyglykolethercarboxylate, C 8 -C 8 -N-acyl taurides , C 8 - Ci 8 -N-sarcosinates and C 8 -C 8 alkyl isethionates or mixtures thereof are used.
- the anionic surfactants are preferably used as sodium salts, but may also be present as other alkali metal or alkaline earth metal salts, for example magnesium salts, and in the form of ammonium or mono-, di-, tri- or tetraalkylammonium salts, in the case of the sulfonates also in the form their corresponding acid, eg dodecylbenzenesulfonic acid.
- surfactants examples include sodium cocoalkyl sulfate, sodium sec-alkanesulfonate having about 15 carbon atoms and sodium dioctylsulfosuccinate.
- Particularly suitable nonionic surfactants are Cs-C-is-alcohol polyglycol ethers, ie ethoxylated and / or propoxylated alcohols having 8 to 18 C atoms in the alkyl moiety and 2 to 15 ethylene oxide (EO) and / or propylene oxide units (PO), Cs-C -is-carboxylic acid polyglycol esters having 2 to 15 EO, for example tallow fatty acid + 6-EO esters, ethoxylated fatty acid amides having 12 to 18 C atoms in the fatty acid moiety and 2 to 8 EO, long-chain amine oxides having 14 to 20 C atoms and long-chain alkylpolyglycosides with 8 to mention 14 carbon atoms in the alkyl moiety and 1 to 3 glycoside units.
- Cs-C-is-alcohol polyglycol ethers ie ethoxylated and / or propoxylated alcohols having 8 to 18 C
- surfactants examples include oleyl-cetyl-alcohol with 5 EO, nonylphenol with 10 EO, lauric acid diethanolamide, Kokosalkyldimethylaminoxid and Kokosalkylpolyglucosid with an average of 1, 4 glucose units.
- 8 -io alkyl polyglucosides with 1 to 2 glycoside units used fatty alcohol polyglycol ethers having, in particular 2 to 8 EO, for example C 12 fatty alcohol + 7 EO ether, and C - Surfactants are also particularly preferred here based on oleochemicals such as C i 8. 8
- the agent according to the invention may also contain cationic surfactants and / or amphoteric surfactants.
- Suitable amphoteric surfactants are, for example, betaines of the formula (R '") (R IV ) (R v ) N + CH 2 C 00 - , in which R'" is an alkyl radical optionally interrupted by hetero atoms or heteroatom groups having 8 to 25, preferably 10 to 21 carbon atoms and R IV and R V are identical or different alkyl radicals having 1 to 3 carbon atoms, in particular C 10 -C 18 -alkyl dimethylcarboxymethylbetain and C 1 -C 4 -alkylamidopropyl-dimethylcarboxymethylbetaine.
- Suitable cationic surfactants include the quaternary ammonium compounds of the formula (R VI ) (R V ") (R VI ") (R IX ) N + X " , in which R v ⁇ to R ⁇ x for four identical or different, in particular two long, and two short-chain, alkyl radicals and X 'are an anion, in particular a halide ion, for example, didecyl-dimethyl-ammonium chloride, alkyl-benzyl-didecyl-ammonium chloride and mixtures thereof.
- the agent according to the invention as surfactant components in addition to C 6 -- ⁇ o-fatty alcohol sulfates only one or more further anionic surfactants, preferably C 10 -C 18 - alkyl sulfates and / or C 8 -C 18 alkyl ether sulfates, and / or a or more nonionic surfactants, preferably C 8 -i 8 -Fettalkoholpolyglykolether having 2 to 8 EO and / or C 8 -io-alkylpolyglucosides having 1 to 2 glycoside units.
- further anionic surfactants preferably C 10 -C 18 - alkyl sulfates and / or C 8 -C 18 alkyl ether sulfates
- nonionic surfactants preferably C 8 -i 8 -Fettalkoholpolyglykolether having 2 to 8 EO and / or C 8 -io-alkylpolyglucosides having 1 to 2
- the agent contains as surfactant components only C 6 -io-fatty alcohol sulfates, preferably in amounts of 0.01 to 1 wt .-%, in particular 0.05 to 0.5 wt .-%.
- composition of the invention contains 0.5 to 10 wt .-% glycerol (1, 2,3-trihydroxypropane, glycerol, propane-1,2,3-triol). In a preferred embodiment, 1 to 5 wt .-% glycerol contain, for example, 2%.
- compositions according to the invention are further solvents, in particular water-soluble organic solvents.
- suitable solvents are for example, saturated or unsaturated, preferably saturated, branched or unbranched Ci -20 - hydrocarbons, preferably C 2 -i 5 hydrocarbons, with at least one hydroxy group and optionally one or more ether functions COC, ie the carbon atom chain interrupting oxygen atoms.
- Preferred solvents are the - optionally unilaterally etherified with a Ci_ 6 -alkanol - C 2 - 6 alkylene glycols and poly-C 2 .
- 3 -alkylene glycol ethers with an average of 1 to 9 identical or different, preferably identical, alkylene glycol groups per molecule as well as the C
- Exemplary solvents are the following INCI compounds: alcohol (ethanol), buteth-3, butoxy diglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, n-butyl alcohol, t-butyl alcohol, butylene glycol, butyloctanol, diethylene glycol, dimethoxy diglycol, dimethyl ether, Dipropylene glycol, ethoxydiglycol, ethoxyethanol, ethyl hexanediol, glycol, hexanediol, 1, 2,6-hexanetriol, hexyl alcohol, hexylene glycol, isobutoxypropanol, isopentyldiol, isopropyl alcohol (isopropanol), 3-methoxybutanol, methoxy diglycol, methoxyethanol, methoxyisopropanol, Methoxymethylbutanol, Methoxy PEG-10, Methylal,
- the alcohols used are in particular ethanol, isopropanol and n-propanol.
- ether alcohols are sufficiently water-soluble compounds having up to 10 carbon atoms in the molecule into consideration. Examples of such ether alcohols are ethylene glycol monobutyl ether, propylene glycol monobutyl ether, diethylene glycol monobutyl ether,
- polyether-polyester copolymers for example those based on alkoxylated terephthalic acid esters.
- a particularly preferred polymer is commercially available under the trade name Marloquest HSCB.
- the polyether-polyester copolymer is preferably contained in amounts of 0.1 to 5 wt .-%, particularly preferably 0.2 to 1 wt .-%, for example 0.25 wt .-%.
- composition according to the invention may contain other conventional ingredients of cleaning agents, for example other surfactants, acids, bases, hydrophilizing agents, disinfectants, pH adjusters, fragrances and dyes, buffers, viscosity regulators, corrosion inhibitors, complexing agents, film formers, antimicrobial agents , Builders, bleaches, enzymes, organic and inorganic salts, optical brighteners, antioxidants, opacifiers, hydrotropes, abrasives, preservatives, oxidizing agents or insecticides, and mixtures thereof.
- cleaning agents for example other surfactants, acids, bases, hydrophilizing agents, disinfectants, pH adjusters, fragrances and dyes, buffers, viscosity regulators, corrosion inhibitors, complexing agents, film formers, antimicrobial agents , Builders, bleaches, enzymes, organic and inorganic salts, optical brighteners, antioxidants, opacifiers, hydrotropes, abrasives, preservatives, oxidizing agents or insecticides, and mixtures
- the agents according to the invention may contain volatile alkali.
- ammonia and / or alkanolamines which may contain up to 9 C atoms in the molecule, are used.
- alkanolamines the ethanolamines are preferred and of these in turn the monoethanolamine.
- the content of ammonia and / or alkanolamine is preferably 0.01 to 2 wt .-%; ammonia is particularly preferably used.
- the cleaning agents according to the invention may also contain small amounts of bases.
- Preferred bases are selected from the group of alkali metal and alkaline earth metal hydroxides and carbonates, in particular the alkali metal hydroxides, of which potassium hydroxide and especially sodium hydroxide is particularly preferred.
- Alkaline agents may additionally contain carboxylic acid in addition to the volatile alkali, the
- Equivalent ratio of amine and / or ammonia to carboxylic acid preferably between 1: 0.9 and
- Suitable carboxylic acids having up to 6 carbon atoms, which are mono-, di- or
- Polycarboxylic acids can act. Depending on the equivalent weight of amine and carboxylic acid is the
- carboxylic acid preferably between 0.01 and 2.7 wt .-%, in particular between
- carboxylic acids are acetic acid, glycolic acid, lactic acid,
- Citric acid succinic acid, adipic acid, malic acid, tartaric acid and gluconic acid, of which preferably acetic acid, citric acid and lactic acid are used. Citric acid is particularly preferably used.
- composition according to the invention may also contain agents for the hydrophilization of surfaces.
- colloidal silica sols in which the silicon dioxide is present nanoparticulate are suitable for hydrophilization.
- Colloidal nanoparticulate silica sols for the purposes of this invention are stable dispersions of amorphous particulate silicon dioxide SiO 2 having particle sizes in the range from 1 to 100 nm. The particle sizes are preferably in the range from 3 to 50 nm, more preferably from 4 to 40 nm
- a silica sol which is suitable for use in accordance with this invention is the silica sol having a particle size of 9 nm available under the trade name BindziP 30/360 from Akzo.
- silica sols are BindziP 15 / 500, 30/220, 40/200 (Akzo), NyacoP 215, 830, 1430, 2034DI and NyacoP DP5820, DP5480, DP5540 etc.
- LevasiP 100/30, 100F / 30, 100S / 30, 200 / 30, 200F / 30, 300F / 30, VP 4038, VP 4055 (HC Starck / Bayer) or CAB-O-SPERSE ® PG 001, PG 002 (aqueous dispersion of CAB-O-SIL ®, Cabot), Quartron PL -1, PL-3 (Fuso Chemical Co.), Köstrosol 0830, 1030, 1430 (Chemiewerk Bad Köstritz).
- the silica sols used may also be surface-modified silica treated with sodium aluminate (alumina-modified silica).
- hydrophilizing polymers are amphoteric polymers, for example copolymers of acrylic or methacrylic acid and MAPTAC, DADMAC or another polymerisable quaternary ammonium compound.
- copolymers with AMPS (2-acrylamido-2-methylpropanesulfonic acid).
- Polyethersiloxanes, ie Copolymers of polymethylsiloxanes with ethylene oxide or propylene oxide segments are other suitable polymers.
- acrylic polymers, maleic acid copolymers and polyurethanes with PEG (polyethylene glycol) units are also usable.
- Suitable polymers are, for example, under the trade names Mirapol Surf-S 100, 110, 200, 210, 400, 410, A 300, A 400 (Rhodia), Tegopren 5843 (Goldschmidt), Sokalan CP 9 (BASF) or Polyquart Ampho 149 (Cognis ) commercially available.
- composition according to the invention may contain one or more perfumes, preferably in an amount of from 0.01 to 1% by weight, in particular from 0.02 to 0.8% by weight, particularly preferably from 0.05 to 0.5% by weight. , most preferably 0.1 to 0.3 wt .-%, and / or one or more dyes (INCI Colorants), preferably in an amount of 0.0001 to 0.1 wt .-%, in particular 0.0005 to 0 , 05 wt .-%, particularly preferably 0.001 to 0.01 wt .-%, included.
- perfumes preferably in an amount of from 0.01 to 1% by weight, in particular from 0.02 to 0.8% by weight, particularly preferably from 0.05 to 0.5% by weight. , most preferably 0.1 to 0.3 wt .-%, and / or one or more dyes (INCI Colorants), preferably in an amount of 0.0001 to 0.1 wt .-%, in particular 0.0005 to 0 , 05 wt
- the agent according to the invention may further contain viscosity regulators.
- Suitable viscosity regulators are, for example, organic natural thickeners (agar-agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, locust bean gum, starch, dextrins, gelatin, casein), organic modified natural products (carboxymethylcellulose and other cellulose ethers, hydroxyethyl - and -propylcellulose and the like, core flour ethers), organic fully synthetic thickeners (polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides) and inorganic thickeners (polysilicic acids, clay minerals such as montmorillonites, zeolites, silicas).
- organic natural thickeners agar-agar, carrageenan, tragacanth, gum arabic, alginates, pectins,
- polyacrylic and polymethacrylic compounds include the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to the International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry, and Fragrance Association (US Pat. CTFA): carbomers), also referred to as carboxyvinyl polymers.
- polyacrylic acids are obtainable inter alia from Fa. 3V Sigma under the tradename Polygel ® such as Polygel ® DA, and by the company.
- Carbopol ® such as Carbopol ® 940 (molecular weight about 4,000,000), Carbopol ® 941 (molecular weight approximately 1,250,000) or Carbopol ® 934 (molecular weight approximately 3,000,000).
- carbopol ® 940 molecular weight about 4,000,000
- Carbopol ® 941 molecular weight approximately 1,250,000
- Carbopol ® 934 molecular weight approximately 3,000,000.
- acrylic acid copolymers are included: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C
- 4- alkanols formed esters (INCI acrylates copolymer), which include about the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS Name according to Chemical Abstracts Service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and (for example, by the company Rohm & Haas under the trade names Aculyn ® and Acusol ® and from Evonik.
- ICI acrylates copolymer which include about the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS Name according to Chemical Abstracts Service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and (for example, by the company Rohm & Haas under the trade names Aculyn ® and Acusol ® and from Evonik.
- Goldschmidt are available under the trade name Tego ® polymer, eg, the anionic non-associative polymers Aculyn ® 22, Aculyn ® 28, Aculyn ® 33 (crosslinked), Acusol ® 810, Acusol ® 823 and Acusol ® 830 (CAS 25852-37- 3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of do- 30- alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably with C
- Tego ® polymer eg, the anionic non-associative polymers Aculyn ® 22, Aculyn ® 28, Aculyn ® 33 (crosslinked), Acusol ® 810, Acusol ® 823 and Acusol ® 830 (CAS 25852-37- 3
- esters (INCI Acrylates / C 10-30 Alkyl Acrylate Crosspolymer) and which are for example available from the company.
- Carbopol ® for example hydrophobized Carbopol ® ETD 2623 and Carbopol ® 1382 (INCI Acrylates / C 10-30 alkyl acrylate Crosspolymer) and Carbopol AQUA ® 30 (formerly Carbopol ® EX 473).
- thickening agents are the polysaccharides and heteropolysaccharides, in particular the polysaccharide gums, for example gum arabic, agar, alginates, carrageenans and their salts, guar, guar gum, tragacanth, gellan, Ramzan, dextran or xanthan and their derivatives, e.g. propoxylated guar, as well as their mixtures.
- polysaccharide thickeners such as starches or cellulose derivatives, may be used alternatively, but preferably in addition to a polysaccharide gum, for example starches of various origins and starch derivatives, e.g.
- a particularly preferred polysaccharide thickener is the microbial anionic heteropolysaccharide xanthan gum, which is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2-15x10 6 and for example, by Fa. Kelco under the trade names Keltrol ® and Kelzan ® or available from Rhodia under the trade name Rhodopol ®.
- phyllosilicates include, for example, available under the trade name Laponite ® magnesium or sodium magnesium phyllosilicates from Solvay Alkali, in particular the Laponite ® RD or Laponite ® RDS, and the magnesium silicates Süd-Chemie, especially the Optigel ® SH.
- the cleaning agent according to the invention contains from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight, of a thickener, preferably a polysaccharide thickener, for example xanthan gum.
- a thickener preferably a polysaccharide thickener, for example xanthan gum.
- Suitable corrosion inhibitors are, for example, the following named according to INCI: Cyclohexylamine, Diammonium Phosphate, Dilithium Oxalate, Dimethylamino Methylpropanol, Dipotassium Oxalate, Dipotassium Phosphate, Disodium Phosphate, Disodium Pyrophosphate, Disodium Tetrapropenyl Succinate, Hexoxyethyl Diethylammonium, Phosphates, Nitromethanes, Potassium Silicate, Sodium Aluminate, Sodium Hexametaphosphate, Sodium Metasilicate, Sodium Molybdate, Sodium Nitrites, Sodium Oxalate, Sodium Silicate, Stearamidopropyl Dimethicone, Tetrapotassium Pyrophosphate, Tetrasodium Pyrophosphate, Triisopropanolamine.
- INCI chelating agents also called sequestrants, are ingredients that are capable of complexing and inactivating metal ions to prevent their detrimental effects on the stability or appearance of the agents, such as clouding. On the one hand, it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness. On the other hand, the complexation of the ions of heavy metals such as iron or copper delays the oxidative decomposition of the finished agents. In addition, the complexing agents support the cleaning effect.
- Suitable examples are the following according to INCI called complexing agents: Aminotri- methylene phosphonic acid, beta-alanines diacetic acid, calcium disodium EDTA, citric acid, cyclodextrin, cyclohexanediamines tetraacetic acid, diammonium citrate, diammonium EDTA, diethylenetriamine pentamethylene phosphonic acid, dipotassium EDTA, disodium Azacycloheptane Diphosphonates, Disodium EDTA, Disodium Pyrophosphates, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphates, Pentasodium Aminotrimethylene Phosphonates, Pentasodium Ethylenediamine Tetramethylene Phosphonates, Pentasodium Pentetate
- a preferred component of the cleaning agent according to the invention is a film former which contributes to better wetting and surface modification.
- All the film-forming polymers used in detergents and cleaners in the prior art can be used for this purpose, but the film former is preferably selected from the group comprising polyethylene glycol, polyethylene glycol derivatives and mixtures thereof, preferably having a molecular weight between 200 and 20,000,000 between 5,000 and 200,000.
- the film former is advantageously used in amounts of from 0.01 to 30% by weight, in particular from 0.2 to 15% by weight.
- the cleaning agent therefore contains one or more antimicrobial agents, preferably in an amount of 0.01 to 1% by weight, preferably 0.02 to 0.8 wt .-%, in particular 0.05 to 0.5 wt .-%, particularly preferably 0.1 to 0.3 wt .-%, most preferably 0.2 wt .-%.
- disinfection, sanitation, antimicrobial action and antimicrobial agent have the usual meaning within the scope of the teaching according to the invention. While disinfection in the narrower sense of the medical practice means the killing of - in theory all - infectious germs, sanitation is to be understood as the greatest possible elimination of all - including the saprophytic - normally harmless to humans saprophytic - germs. Here, the extent of disinfection or sanitation depends on the antimicrobial effect of the applied agent, which decreases with decreasing content of antimicrobial agent or increasing dilution of the agent for use.
- antimicrobial agents from the groups of alcohols, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazoles and their suitable Derivatives such as isothiazolines and isothiazolinones, phthalimide derivatives, pyridine derivatives, antimicrobial surface active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carbamate, iodine, iodophores and peroxides.
- Preferred antimicrobial agents are preferably selected from the group comprising ethanol, n-propanol, i-propanol, 1, 3-butanediol, phenoxyethanol, 1, 2-propylene glycol, glycerol, undecylenic acid, citric acid, lactic acid, benzoic acid, salicylic acid, thymol, 2- Benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 2,4,4'-trichloro-2'-hydroxydiphenyl ether, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octanamine) dihydrochloride, N , N'-bis (4-chlorophenyl) -3,12-diimino-2,4,11,
- Preferred antimicrobial surface-active quaternary compounds contain an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Furthermore, it is also possible to use antimicrobial-effective essential oils which at the same time ensure scenting of the cleansing agent.
- particularly preferred antimicrobial agents are selected from the group comprising salicylic acid, quaternary surfactants, in particular benzalkonium chloride, peroxo compounds, in particular hydrogen peroxide, alkali metal hypochlorite and mixtures thereof.
- water-soluble and / or water-insoluble builders may be used in the cleaning agents according to the invention.
- Water-soluble builders are preferred because they tend to be less likely to leave insoluble residues on hard surfaces.
- Typical builders which may be present in the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and its salts, the carbonates, phosphates and silicates.
- Water-insoluble builders include the zeolites, which may also be used, as well as mixtures of the aforementioned builders.
- bleaching agents can be added to the cleaning agent.
- Suitable bleaching agents include peroxides, peracids and / or perborates, particularly preferred is hydrogen peroxide.
- a bleach activator may be required in addition to the bleaching agent.
- the agent may also contain enzymes, preferably proteases, lipases, amylases, hydrolases and / or cellulases. They can be added to the composition according to the invention in any form established according to the prior art. In the case of liquid or gel-containing compositions, these include, in particular, solutions of the enzymes, advantageously as concentrated as possible, sparing in water and / or added with stabilizers. Alternatively, the enzymes can be encapsulated, for example by spray drying or extrusion of the enzyme solution together with a, preferably natural, polymer or in the form of capsules, for example those in which the enzymes are entrapped as in a solidified gel or in core-shelled form.
- enzymes preferably proteases, lipases, amylases, hydrolases and / or cellulases.
- further active ingredients for example stabilizers, emulsifiers, pigments, bleaches or dyes, may additionally be applied.
- Such capsules are applied by methods known per se, for example by shaking or rolling granulation or in fluid-bed processes.
- such granules for example by applying polymeric film-forming agent, low in dust and storage stable due to the coating.
- enzyme-stabilizing agents may be present in enzyme-containing agents to protect an enzyme contained in an agent according to the invention from damage such as inactivation, denaturation or disintegration, for example by physical influences, oxidation or proteolytic cleavage.
- Suitable enzyme stabilizers in each case depending on the enzyme used, are in particular: benzamidine hydrochloride, borax, boric acids, boronic acids or their salts or esters, especially derivatives with aromatic groups, for example substituted phenylboronic acids or their salts or esters; Peptide aldehydes (oligopeptides with reduced C-terminus), amino alcohols such as mono-, di-, triethanol- and -propanolamine and mixtures thereof, aliphatic carboxylic acids up to C 2 , such as succinic acid, other dicarboxylic acids or salts of said acids; end-capped fatty acid amide alkoxylates; lower aliphatic alcohols and especially polyols, for example glycerol,
- stabilizers for example the combination of polyols, boric acid and / or borax, the combination of boric acid or borate, reducing salts and succinic acid or other dicarboxylic acids or the combination of boric acid or borate with polyols or polyamino compounds and with reducing salts.
- Preservatives may also be included in compositions of the invention. As such, essentially the substances mentioned in the antimicrobial agents can be used.
- compositions according to the invention are preferably formulated as concentrate to be diluted before use. They can be prepared by mixing directly from their raw materials, then mixing and final standing of the agent to freedom from bubbles.
- the agents according to the invention are preferably used for cleaning hard surfaces.
- Hard surfaces in the context of this application are windows, mirrors and other glass surfaces, surfaces made of ceramic, plastic, metal or wood and painted Wood, which can be found in household and commercial, such as bathroom ceramics, kitchen surfaces or floors.
- the compositions according to the invention are suitable for floor cleaning.
- the cleaning agent is preferably diluted with water before use.
- Another subject of the invention is therefore the use of a cleaning agent according to the invention for cleaning hard surfaces, in particular for floor cleaning.
- the cleaning agent according to the invention is first diluted with water, the resulting cleaning liquor is applied to the surface to be cleaned, then the agent with the aid of a cloth, a sponge or a other suitable substrate is spread on the surface and finally dried.
- a further subject of the invention is accordingly a process for cleaning hard surfaces, comprising the steps of a) preparing a cleaning liquor by diluting a cleaning agent according to the invention with water, b) applying the diluted cleaning agent to the surface to be cleaned, c) wiping with a cloth, a Sponge, a leather or other suitable substrate for this purpose to distribute the agent on the entire surface, d) allow to dry.
- Detergents E1 to E4 according to the invention were prepared and investigated for their cleaning performance.
- comparative formulations V1 to V4 were prepared.
- the compositions can be taken from the table below. All quantities are in wt .-%, based on the active substance.
- the cleaning performance of the compositions was determined in accordance with the quality standards for floor care and cleaning products issued by the Industrial Association for Cleaning and Care Products (IPP), each in dilute solution (12 g / l).
- IPP Industrial Association for Cleaning and Care Products
- the agents E1 to E4 according to the invention had a good cleaning performance (40-42%) according to IPP 83/21, while V2 to V4 only reached values of 27 to 29%. On the other hand, the cleaning performance of the glycerol-free agent V1 was also good.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10707263T PL2414495T3 (en) | 2009-03-31 | 2010-03-01 | Cleaning agent for floors |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009002020A DE102009002020A1 (en) | 2009-03-31 | 2009-03-31 | Cleaning agent for floors |
PCT/EP2010/052557 WO2010112283A1 (en) | 2009-03-31 | 2010-03-01 | Cleaning agent for floors |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2414495A1 true EP2414495A1 (en) | 2012-02-08 |
EP2414495B1 EP2414495B1 (en) | 2016-02-10 |
Family
ID=42102253
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP10707263.9A Active EP2414495B1 (en) | 2009-03-31 | 2010-03-01 | Cleaning agent for floors |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2414495B1 (en) |
DE (1) | DE102009002020A1 (en) |
ES (1) | ES2564206T3 (en) |
PL (1) | PL2414495T3 (en) |
WO (1) | WO2010112283A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN117050817A (en) | 2019-04-12 | 2023-11-14 | 埃科莱布美国股份有限公司 | Antimicrobial multipurpose cleaners and methods of making and using the same |
EP4034623A1 (en) | 2019-09-26 | 2022-08-03 | Ecolab USA Inc. | High alkaline solvent-based degreaser and cleaner with diutan gum as a primary thickening system |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB872181A (en) * | 1959-03-24 | 1961-07-05 | Watco Ltd | Improvements to floor sweeping compositions |
EP0007737A1 (en) * | 1978-07-31 | 1980-02-06 | Atlas Chemical Industries (U.K.) Ltd | An aqueous solution containing a surfactant and its uses in emulsification |
US5672580A (en) * | 1990-04-25 | 1997-09-30 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid detergent compositions |
JPH0633098A (en) * | 1992-07-20 | 1994-02-08 | Shiseido Co Ltd | Liquid cleaning agent for clothes |
EP0805197A1 (en) * | 1996-05-03 | 1997-11-05 | The Procter & Gamble Company | Cleaning compositions |
EP0916718A1 (en) * | 1997-10-14 | 1999-05-19 | The Procter & Gamble Company | Cleaning and disinfecting compositions |
EP1080169A1 (en) * | 1998-05-22 | 2001-03-07 | The Procter & Gamble Company | Acidic cleaning compositions with c10 alkyl sulfate detergent surfactant |
DE102005027604A1 (en) * | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Cleaning agent for hard surfaces |
US20080299491A1 (en) * | 2007-05-31 | 2008-12-04 | Miller Gary R | Highly alkaline developer composition and methods of use |
-
2009
- 2009-03-31 DE DE102009002020A patent/DE102009002020A1/en not_active Withdrawn
-
2010
- 2010-03-01 EP EP10707263.9A patent/EP2414495B1/en active Active
- 2010-03-01 WO PCT/EP2010/052557 patent/WO2010112283A1/en active Application Filing
- 2010-03-01 ES ES10707263.9T patent/ES2564206T3/en active Active
- 2010-03-01 PL PL10707263T patent/PL2414495T3/en unknown
Non-Patent Citations (1)
Title |
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See references of WO2010112283A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2010112283A1 (en) | 2010-10-07 |
PL2414495T3 (en) | 2016-08-31 |
DE102009002020A1 (en) | 2010-10-07 |
EP2414495B1 (en) | 2016-02-10 |
ES2564206T3 (en) | 2016-03-18 |
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