EP2366006B1 - Fester gerüststoff - Google Patents

Fester gerüststoff Download PDF

Info

Publication number
EP2366006B1
EP2366006B1 EP09759729.8A EP09759729A EP2366006B1 EP 2366006 B1 EP2366006 B1 EP 2366006B1 EP 09759729 A EP09759729 A EP 09759729A EP 2366006 B1 EP2366006 B1 EP 2366006B1
Authority
EP
European Patent Office
Prior art keywords
soap
weight
composition
builder
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP09759729.8A
Other languages
English (en)
French (fr)
Other versions
EP2366006A1 (de
Inventor
Subir K Das
Amitava Pramanik
Arpita Sarkar
Archana Sinha
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP2366006A1 publication Critical patent/EP2366006A1/de
Application granted granted Critical
Publication of EP2366006B1 publication Critical patent/EP2366006B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1233—Carbonates, e.g. calcite or dolomite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

Definitions

  • the present invention relates to a solid builder composition and a solid detergent composition comprising the same.
  • Water hardness due to presence of calcium and magnesium ions in water, is known to cause deterioration in cleaning efficacy of fabrics.
  • Use of builders to reduce water hardness and consequently to improve cleaning efficacy is also known.
  • a builder composition comprising sodium carbonate and calcium carbonate is known to be effective in reducing water hardness and improve cleaning efficacy.
  • the kinetics of water hardness reduction is relatively slow.
  • the concentration of hardness ions that can be achieved by use of builder compositions of the prior art is relatively high. When such builder compositions are incorporated in detergent compositions, relatively higher concentration of hardness ions coupled with slower kinetics leads to depletion of soluble form of surfactant and consequent reduction in cleaning efficacy.
  • a builder composition comprising alkali metal carbonate, calcium carbonate, alkali metal silicate, and soap particles of specific size and specific composition provide relatively faster building kinetics and allow attainment of relatively low hardness ion concentration and that incorporation of the inventive builder composition in a detergent composition provides relatively higher fabric cleaning efficacy in hard water.
  • GB-1424406 describes composition comprising sodium carbonate, soap, calcium carbonate, sodium silicate, and alkyl benzene sulfonate. Soap, alkyl benzene sulfonate, sodium silicate and sodium sulfate were admixed and compacted to form granules.
  • One of the objects of the present invention is to provide a builder composition that provides relatively fast building kinetics.
  • a further object of the present invention is to provide a builder composition that allows attainment of relatively low hardness ion concentration.
  • Yet another object of the present invention is to provide a detergent composition that provides relatively higher fabric cleaning efficacy in hard water.
  • a solid detergent composition comprising the builder composition of the first aspect characterized in that the soap is in form of particles comprising at least 50% by weight soap and in that at least 80% by weight of the soap particles are retained on sieve of 80 mesh and a non-soap surfactant.
  • the alkali metal silicate is preferably sodium silicate or potassium silicate, more preferably sodium silicate.
  • Sodium silicate is a colorless compound of oxides of sodium and silica. It has a range of chemical formula varying in sodium oxide (Na 2 O) and silicon dioxide or silica (SiO 2 ) contents. It is soluble in water and it is prepared by reacting silica (sand) and sodium carbonate at a high temperature ranging from 1200 to 1400°C.
  • sodium metasilicate available sodium metasilicate is preferred. Both sodium metasilicate pentahydrate as well as sodium metasilicate nonahydrate can be used although sodium metasilicate pentahydrate is preferred as it dissolves faster.
  • the alkali metal silicate is present at a level of 1 to 40%, preferably 2 to 35% and most preferably 5 to 30% by weight of the builder composition.
  • the % by weight alkali metal silicate is on anhydrous basis.
  • Crystal form of calcium carbonate may be calcite, vaterite or aragonite, with calcite being the most preferable crystal form.
  • the calcium carbonate has a surface area greater than 18 m 2 /g, more preferably greater than 30 m 2 /g, and most preferably greater than 60 m 2 /g.
  • the soap is in form of particles comprising at least 50% by weight soap and at least 80% by weight of soap particles are retained on sieve of 80 mesh.
  • the soap particles comprise preferably at least 60%, more preferably at least 70% and most preferably at least 80% by weight soap.
  • At least 80% by weight soap particles are retained on a sieve of 80 mesh, preferably on a sieve of 65 mesh, and more preferably on a sieve of 60 mesh.
  • the soap is preferably C8-C24 soap, more preferably C10-C20 soap, and most preferably C12-C18 soap.
  • the builder composition comprises calcium oxide or hydroxide, with calcium hydroxide being particularly preferred.
  • calcium oxide or hydroxide is preferably 0.1 to 15%, more preferably 0.5 to 12% and most preferably 1 to 10 % by weight of the builder composition.
  • the solid detergent composition comprises the builder composition and a non-soap surfactant.
  • the solid builder composition is preferably 5 to 90%, more preferably 10 to 80% and most preferably 15 to 70% by weight of the solid detergent composition.
  • the soap is in form of particles comprising at least 50% by weight soap and at least 80% by weight of the soap particles are retained on sieve of 80 mesh, preferably 70 mesh.
  • non-soap surfactant as used herein means any surfactant excluding soap.
  • the non-soap surfactant may be anionic, non-ionic, cationic, zwitterionic or amphoteric. More preferably the non-soap surfactant is an anionic surfactant
  • the anionic surfactant is a salt of an acid selected from a group consisting of linear alkyl benzene sulfonic acid, alpha olefin sulfonic acid and primary alkyl sulfuric acid. More preferably, the anionic surfactant is a salt of linear alkyl benzene sulfonic acid
  • the salt is an ammonium salt, an alkali metal salt or an alkaline earth metal salt. More preferably, the salt is an alkaline earth metal salt. It is particularly preferred that the alkaline earth metal is magnesium.
  • the non-soap surfactant is a magnesium salt of a linear alkyl benzene sulfonic acid
  • the non-soap surfactant is in form of particles wherein at least 50% by weight of the non-soap surfactant particles are preferably retained on a sieve of 80 mesh, preferably 70 mesh, still more preferably retained on 60 mesh, and most preferably retained on a sieve of 50 mesh.
  • a sieve of 80 mesh preferably 70 mesh, still more preferably retained on 60 mesh, and most preferably retained on a sieve of 50 mesh.
  • Soap particles may be prepared by any process.
  • a corresponding fatty acid is neutralized to form a soap which is then extruded, and extruded noodles are granulated.
  • a pan-granulator is used for granulation.
  • the soap granules may be separated according to size by any suitable method, preferably by sieving.
  • the builder composition may be prepared by a process comprising the step of mixing all the ingredients of the builder composition.
  • the builder composition is prepared by a process comprising the steps of:
  • the step (2) is carried out in a low shear mixer.
  • low shear mixer include a ribbon mixer or a blender.
  • the step (2) is not carried out in a sigma mixer.
  • the detergent composition may be prepared by mixing the non-soap detergent with the builder composition.
  • the detergent composition comprising an anionic non-soap surfactant is prepared by a process comprising the steps of:
  • the step (3) is carried out in a low shear mixer.
  • tow shear mixer include a ribbon mixer or a blender.
  • the step (3) is not carried out in a sigma mixer. In low shear mixer, breakage or deformation of soap granules is avoided thus ensuring that the size of soap particles remains unaltered such that at least 80% by weight of the soap particles are retained on a sieve of 80 mesh, preferably 70 mesh.
  • the process of preparation of the detergent composition preferably comprises the steps of:
  • the step (3) is carried out in the low shear mixer.
  • the step (3) is not carried out in a sigma mixer.
  • the granules of magnesium salt of linear alkyl benzene sulfonic acid obtained in the step (2) are sieved such that at least 50% by weight of the granules of the magnesium salt of linear alkyl benzene sulfonic acid are retained on a sieve of 70 mesh.
  • compositions comprising soap were prepared by a process comprising the steps of:
  • soap granules comprised 80% by weight of sodium laurate.
  • soap particles comprised 90% by weight soap.
  • Builder composition of Comparative Ex A and Comparative Ex D comprised 48.6% by weight sodium carbonate, 27% by weight calcium carbonate, 24.3% by weight sodium metasilicate. Comparative Ex A and Comparative Ex D did not have soap.
  • Other builder compositions in the table below comprised 45% by weight sodium carbonate, 25% by weight calcium carbonate, 22.5% by weight sodium metasilicate, and 7.5% by weight soap. Calcium carbonate with surface area of 60 m 2 /g and particle size of 2-10 microns procured from Saurashtra Solid Industries, India was used in all the experiments.
  • Builder compositions comprising calcium hydroxide Ex No Soap Size of soap particles Sieve details G 0 - - 10 Sodium laurate 0.5-0.85 mm 20 + 35 - 11 Sodium laurate 0.35-0.5 mm 35 + 45 - 12 Sodium laurate 0.2-0.5 mm 45 + 70 - H Sodium laurate ⁇ 0.075 mm 200 - 13 Sodium palmitate 0.35-0.5 mm 35 + 45 - 14 Sodium palmitate 0.2-0.5 mm 45 + 70 - I Sodium palmitate ⁇ 0.075 mm 200 -
  • the builder compositions of the present invention provide relatively fast building kinetics as compared to the builder compositions outside the scope of the present invention.
  • the builder compositions of the present invention provide relatively fast building kinetics, achieve attainment of relatively low hardness ion concentration.
  • All the detergent compositions in the following table comprised 19% by weight of LAS (either magnesium or sodium salt), 67% by weight the builder composition, 3% by weight sodium carboxymethyl cellulose, 1 % by weight of sodium sulfite, 4% by weight sodium chloride, 2% by weight moisture and other minor ingredients including perfume and fluorescer.
  • LAS magnesium or sodium salt
  • step (3) Prior to step (3), the granules of the magnesium salt of linear alkyl benzene sulfonic acid obtained in the step (2) were sieved such that all the granules are retained on a sieve of mesh 35.
  • the detergent composition was sieved and the fraction retained on mesh 35 was used in the washing experiment.
  • WFK10D is a cotton fabric having composite soil
  • WFK20D is a poly-cotton fabric having composite soil
  • AS9 is a cotton fabric having other variety of composite soil. The experiments were done at a liquor to cloth ratio of 50:1.
  • the detergent compositions of the present invention provide relatively higher cleaning efficacy on cotton fabric as compared to the detergent compositions that are outside the scope of the present invention. It can also be seen that for cotton fabrics as well as polycotton fabrics, the detergent composition comprising magnesium salt of linear alkyl benzene sulfonic acid provides relatively higher cleaning efficacy as compared to the detergent composition comprising sodium salt of linear alkyl benzene sulfonic acid.
  • detergent compositions of the present invention provide relatively higher fabric cleaning efficacy in hard water.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Feste Gerüststoffzusammensetzung, die Folgendes aufweist:
    (v) 5 bis 70 Gew.-% der Gerüststoffzusammensetzung in Form von Alkalimetallcarbonat,
    (vi) 1 bis 40 Gew.-% der Gerüststoffzusammensetzung in Form von Alkalimetallsilicat,
    (vii) 3 bis 50 Gew.-% der Gerüststoffzusammensetzung in Form von Calciumcarbonat und
    (viiii) 1 bis 25 Gew.-% der Gerüststoffzusammensetzung in Form von Seife, dadurch gekennzeichnet, dass die Seife in Form von Teilchen vorliegt, die mindestens 50 Gew.-% Seife aufweisen, und dass mindestens 80 Gew.-% der Seifenteilchen auf einem Sieb mit 80 mesh zurückgehalten werden.
  2. Feste Gerüststoffzusammensetzung nach Anspruch 1,
    die 0,1 bis 15 Gew.-% Calciumoxid oder Calciumhydroxid aufweist.
  3. Feste Waschmittelzusammensetzung, die Folgendes aufweist:
    (i) eine feste Gerüststoffzusammensetzung nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, dass die Seife in Form von Teilchen vorliegt, die mindestens 50 Gew.-% Seife aufweisen, und dass mindestens 80 Gew.-% der Seifenteilchen auf einem Sieb mit 80 mesh zurückgehalten werden, und
    (ii) ein seifenfreies Tensid.
  4. Feste Waschmittelzusammensetzung nach Anspruch 3,
    wobei die Gerüststoffzusammensetzung in einer Menge von 5 bis 90 Gew.-% der Waschmittelzusammensetzung vorliegt.
  5. Feste Waschmittelzusammensetzung nach Anspruch 3 oder 4,
    wobei das seifenfreie Tensid in einer Menge von 5 bis 80 Gew.-% der Waschmittelzusammensetzung vorliegt.
  6. Feste Waschmittelzusammensetzung nach einem der vorstehenden Ansprüche 3 bis 5,
    wobei das seifenfreie Tensid ein anionisches Tensid ist.
  7. Feste Waschmittelzusammensetzung nach Anspruch 6,
    wobei das anionische Tensid ein Salz einer Säure ist, die aus der Gruppe ausgewählt ist, die aus linearer Alkylbenzolsulfonsäure, oc-Olefinsulfonsäure und primärer Alkylschwefelsäure besteht.
  8. Feste Waschmittelzusammensetzung nach Anspruch 6 oder 7,
    wobei das anionische Tensid ein Salz einer linearen Alkylbenzolsulfonsäure ist.
  9. Feste Waschmittelzusammensetzung nach einem der vorstehenden Ansprüche 7 oder 8,
    wobei das Salz ein Erdalkalimetallsalz ist.
  10. Feste Waschmittelzusammensetzung nach Anspruch 9,
    wobei das Erdalkalimetall Magnesium ist.
EP09759729.8A 2008-12-16 2009-11-24 Fester gerüststoff Not-in-force EP2366006B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN2623MU2008 2008-12-16
PCT/EP2009/065711 WO2010069718A1 (en) 2008-12-16 2009-11-24 Solid builder composition

Publications (2)

Publication Number Publication Date
EP2366006A1 EP2366006A1 (de) 2011-09-21
EP2366006B1 true EP2366006B1 (de) 2013-08-14

Family

ID=41611346

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09759729.8A Not-in-force EP2366006B1 (de) 2008-12-16 2009-11-24 Fester gerüststoff

Country Status (4)

Country Link
EP (1) EP2366006B1 (de)
CN (1) CN102257113B (de)
WO (1) WO2010069718A1 (de)
ZA (1) ZA201103721B (de)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102906251B (zh) 2010-04-26 2016-11-16 诺维信公司 酶颗粒剂
MX351761B (es) 2011-06-20 2017-10-26 Novozymes As Composicion particulada.
JP6126086B2 (ja) 2011-06-24 2017-05-10 ノボザイムス アクティーゼルスカブ プロテアーゼ活性を有するポリペプチドおよびこれをコードするポリヌクレオチド
CN112662734A (zh) 2011-06-30 2021-04-16 诺维信公司 用于筛选α-淀粉酶的方法
US10711262B2 (en) 2011-07-12 2020-07-14 Novozymes A/S Storage-stable enzyme granules
MX2014001594A (es) 2011-08-15 2014-04-25 Novozymes As Polipeptidos que tienen actividad de celulasa y polinucleotidos que los codifican.
WO2013041689A1 (en) 2011-09-22 2013-03-28 Novozymes A/S Polypeptides having protease activity and polynucleotides encoding same
JP2015500006A (ja) 2011-11-25 2015-01-05 ノボザイムス アクティーゼルスカブ サブチラーゼ変異体およびこれをコードするポリヌクレオチド
CN107267489A (zh) 2011-12-20 2017-10-20 诺维信公司 枯草杆菌酶变体和编码它们的多核苷酸
ES2644007T3 (es) 2012-01-26 2017-11-27 Novozymes A/S Uso de polipéptidos con actividad de proteasa en piensos para animales y en detergentes
JP2015509364A (ja) 2012-02-17 2015-03-30 ノボザイムス アクティーゼルスカブ サブチリシン変異体およびそれをコードするポリヌクレオチド
US20150064773A1 (en) 2012-03-07 2015-03-05 Novozymes A/S Detergent Composition and Substitution of Optical Brighteners in Detergent Composition
CN117904080A (zh) 2012-05-07 2024-04-19 诺维信公司 具有黄原胶降解活性的多肽以及编码其的核苷酸
EP2863759A2 (de) 2012-06-20 2015-04-29 Novozymes Biopolymer A/S Verwendung von polypeptiden mit proteasewirkung in tierfutter und reinigungsmitteln
US9551042B2 (en) 2012-12-21 2017-01-24 Novozymes A/S Polypeptides having protease activity and polynucleotides encoding same
CN104903443A (zh) 2013-01-03 2015-09-09 诺维信公司 α-淀粉酶变体以及对其进行编码的多核苷酸
WO2014183921A1 (en) 2013-05-17 2014-11-20 Novozymes A/S Polypeptides having alpha amylase activity
US10538751B2 (en) 2013-06-06 2020-01-21 Novozymes A/S Alpha-amylase variants and polynucleotides encoding same
CN105874067A (zh) 2013-06-27 2016-08-17 诺维信公司 枯草杆菌酶变体以及编码它们的多核苷酸
WO2014207224A1 (en) 2013-06-27 2014-12-31 Novozymes A/S Subtilase variants and polynucleotides encoding same
WO2015001017A2 (en) 2013-07-04 2015-01-08 Novozymes A/S Polypeptides having anti-redeposition effect and polynucleotides encoding same
EP2832853A1 (de) 2013-07-29 2015-02-04 Henkel AG&Co. KGAA Waschmittelzusammensetzung mit Proteasevarianten
RU2670946C9 (ru) 2013-07-29 2018-11-26 Новозимс А/С Варианты протеазы и кодирующие их полинуклеотиды
EP3613853A1 (de) 2013-07-29 2020-02-26 Novozymes A/S Proteasevarianten und polynukleotide zur codierung davon
WO2015049370A1 (en) 2013-10-03 2015-04-09 Novozymes A/S Detergent composition and use of detergent composition
EP3083954B1 (de) 2013-12-20 2018-09-26 Novozymes A/S Polypeptide mit proteaseaktivität und polynukleotide, die für diese kodieren
EP3114219A1 (de) 2014-03-05 2017-01-11 Novozymes A/S Zusammensetzungen und verfahren zur verbesserung der eigenschaften von nichtcellulosischen textilmaterialien mit xyloglucan-endotransglycosylase
CN106062271A (zh) 2014-03-05 2016-10-26 诺维信公司 用于改进具有木葡聚糖内糖基转移酶的纤维素纺织材料的性质的组合物和方法
US20170015950A1 (en) 2014-04-01 2017-01-19 Novozymes A/S Polypeptides having alpha amylase activity
US20170121695A1 (en) 2014-06-12 2017-05-04 Novozymes A/S Alpha-amylase variants and polynucleotides encoding same
EP3739029A1 (de) 2014-07-04 2020-11-18 Novozymes A/S Subtilasevarianten und polynukleotide zur codierung davon
WO2016001449A1 (en) 2014-07-04 2016-01-07 Novozymes A/S Subtilase variants and polynucleotides encoding same
US10287562B2 (en) 2014-11-20 2019-05-14 Novoszymes A/S Alicyclobacillus variants and polynucleotides encoding same
US10683491B2 (en) 2014-12-04 2020-06-16 Novozymes A/S Subtilase variants and polynucleotides encoding same
WO2016096714A1 (en) 2014-12-15 2016-06-23 Henkel Ag & Co. Kgaa Detergent composition comprising subtilase variants
EP3106508B1 (de) 2015-06-18 2019-11-20 Henkel AG & Co. KGaA Reinigungsmittelzusammensetzung mit subtilasevarianten
EP3310912B1 (de) 2015-06-18 2021-01-27 Novozymes A/S Subtilasevarianten und polynukleotide zur codierung davon
EP3362556B1 (de) 2015-10-14 2024-07-10 Novozymes A/S Polypeptidvarianten
CN108291215A (zh) 2015-10-14 2018-07-17 诺维信公司 具有蛋白酶活性的多肽以及编码它们的多核苷酸
WO2017207762A1 (en) 2016-06-03 2017-12-07 Novozymes A/S Subtilase variants and polynucleotides encoding same
CN109642222A (zh) 2016-07-13 2019-04-16 诺维信公司 食物芽孢杆菌dna酶变体
CN106479689A (zh) * 2016-09-09 2017-03-08 北京神雾环境能源科技集团股份有限公司 一种电石渣基污渍去除剂及其应用
CN111386340B (zh) 2017-10-27 2024-05-24 宝洁公司 包含多肽变体的洗涤剂组合物
EP3701017A1 (de) 2017-10-27 2020-09-02 Novozymes A/S Dnase-varianten
WO2019201793A1 (en) 2018-04-17 2019-10-24 Novozymes A/S Polypeptides comprising carbohydrate binding activity in detergent compositions and their use in reducing wrinkles in textile or fabric.
BR112021018731A2 (pt) 2019-03-21 2021-12-21 Novozymes As Variantes de alfa-amilase e polinucleotídeos codificando as mesmas
WO2020207944A1 (en) 2019-04-10 2020-10-15 Novozymes A/S Polypeptide variants
US20220325204A1 (en) 2019-08-27 2022-10-13 Novozymes A/S Detergent composition
US20220315866A1 (en) 2019-09-19 2022-10-06 Novozymes A/S Detergent Composition
WO2021064068A1 (en) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprising at least two carbohydrate binding domains
EP3892708A1 (de) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Reinigungszusammensetzungen mit dispersinvarianten
WO2022074037A2 (en) 2020-10-07 2022-04-14 Novozymes A/S Alpha-amylase variants
WO2022171780A2 (en) 2021-02-12 2022-08-18 Novozymes A/S Alpha-amylase variants
EP4359518A1 (de) 2021-06-23 2024-05-01 Novozymes A/S Alpha-amylase-polypeptide
WO2024131880A2 (en) 2022-12-23 2024-06-27 Novozymes A/S Detergent composition comprising catalase and amylase

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3703772A (en) * 1971-07-27 1972-11-28 Colgate Palmolive Co Drying of detergents
CA992832A (en) * 1972-04-28 1976-07-13 The Procter And Gamble Company Crystallization seed-containing composition
US3992314A (en) * 1974-09-27 1976-11-16 The Procter & Gamble Company Process for the preparation of spray-dried calcium carbonate-containing granules
GB8603667D0 (en) * 1986-02-14 1986-03-19 Unilever Plc Detergent composition
MY102396A (en) * 1986-11-07 1992-06-17 Unilever Plc Detergent granules and a process for their preparation
GB8711423D0 (en) * 1987-05-14 1987-06-17 Unilever Plc Detergent composition

Also Published As

Publication number Publication date
EP2366006A1 (de) 2011-09-21
ZA201103721B (en) 2012-09-26
CN102257113A (zh) 2011-11-23
WO2010069718A1 (en) 2010-06-24
CN102257113B (zh) 2013-05-08

Similar Documents

Publication Publication Date Title
EP2366006B1 (de) Fester gerüststoff
EP2154233B1 (de) Bauzusammensetzung
EP2167624B1 (de) Festes waschmittel
EP0609273B1 (de) Wasch- und reinigungsmittel mit ausgewählten builder-systemen
US3741911A (en) Phosphate-free detergent composition
JPH0637636B2 (ja) 洗剤粒子
DE2501696A1 (de) Reinigungsmittelmischungen
CH639690A5 (de) Verfahren zur herstellung von waschmittelpulver.
JPH11166197A (ja) 抗菌性洗剤添加物
DE3879870T2 (de) Zeolithe in fluessigen reinigungsmitteln.
KR20090104136A (ko) 세제 조성물
EP0626996A1 (de) Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat-, und phosphatfreier maschinengeschirrspülmittel in form von schwergranulaten
EP1967575A1 (de) Weichspülerzusammensetzung
EP0794998B1 (de) Waschmittelzusammensetzungen
JP2002502457A (ja) 粒状洗剤
DE4139551A1 (de) Pulverfoermige tensidmischung
EP2231531B1 (de) Buildersystem für Waschmittel
EP1416039B1 (de) Verwendung wasserlöslicher Builder von bestimmter Korngrösse in bleichefreien Waschmitteln
US6448218B2 (en) Modified aluminosilicate
EP0569365A1 (de) Phosphatfreies reinigungsmittel.
EP2139980B1 (de) Buildersystem für eine waschmittelzusammensetzung
CN101503647B (zh) 粉末洗涤剂组合物
EP1416040B1 (de) Wasserlösliche Builder von bestimmter Korngrösse in Wasch-und Reinigungsmitteln
US10287531B2 (en) Free-flowing, solid, high active alkyl ether sulfates
JP2020097664A (ja) 粉末洗剤の製造方法

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20110517

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20130425

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 626886

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130815

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602009018016

Country of ref document: DE

Effective date: 20131010

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20130814

Ref country code: AT

Ref legal event code: MK05

Ref document number: 626886

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130814

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131114

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130619

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131214

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131216

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131115

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

26N No opposition filed

Effective date: 20140515

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20131124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131130

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131130

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602009018016

Country of ref document: DE

Effective date: 20140603

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20140731

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602009018016

Country of ref document: DE

Effective date: 20140515

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140603

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131124

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131124

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20091124

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814