EP2113036A2 - Fiber composite comprising a metallic matrix, and method for the production thereof - Google Patents
Fiber composite comprising a metallic matrix, and method for the production thereofInfo
- Publication number
- EP2113036A2 EP2113036A2 EP08706752A EP08706752A EP2113036A2 EP 2113036 A2 EP2113036 A2 EP 2113036A2 EP 08706752 A EP08706752 A EP 08706752A EP 08706752 A EP08706752 A EP 08706752A EP 2113036 A2 EP2113036 A2 EP 2113036A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- metallic
- layer
- fibers
- fiber composite
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 89
- 239000002131 composite material Substances 0.000 title claims abstract description 38
- 239000011159 matrix material Substances 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 22
- 239000010410 layer Substances 0.000 claims abstract description 111
- 239000012790 adhesive layer Substances 0.000 claims abstract description 26
- 239000002657 fibrous material Substances 0.000 claims abstract description 18
- 238000001465 metallisation Methods 0.000 claims description 54
- 239000004744 fabric Substances 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 238000007751 thermal spraying Methods 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000003365 glass fiber Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 6
- 239000004760 aramid Substances 0.000 claims description 6
- 229920006231 aramid fiber Polymers 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000004917 carbon fiber Substances 0.000 claims description 6
- 239000012811 non-conductive material Substances 0.000 claims description 5
- 238000009713 electroplating Methods 0.000 claims 2
- 238000003754 machining Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- -1 and the scrim Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000011156 metal matrix composite Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000005422 blasting Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 229920000914 Metallic fiber Polymers 0.000 description 1
- 206010041662 Splinter Diseases 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000002146 bilateral effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical class O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/04—Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/06—Pretreatment of the fibres or filaments by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element
- C22C47/062—Pretreatment of the fibres or filaments by forming the fibres or filaments into a preformed structure, e.g. using a temporary binder to form a mat-like element from wires or filaments only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/249927—Fiber embedded in a metal matrix
Definitions
- Fiber composite with metallic matrix and process for its preparation
- the invention relates to a fiber composite material with metallic matrix and a method for producing such.
- fiber composites made of plastic, in which, for example, glass, carbon or aramid fibers are embedded in a synthetic resin such as epoxy, polyester or vinyl ester resin or a similar synthetic resin.
- the synthetic resin forms a matrix which wraps and connects the fibers, which are typically arranged in the form of a fabric, fabric or braid.
- the problem with such conventional plastic fiber composites is the fact that they are flammable in the event of damage, such as vehicles, such as land, water or aircraft in particular splinter-break with sharp-edged, sharp fragments.
- Metal matrix composite materials mentioned which are, however, usually technically complex to produce, since primitive or molded body are used, which also has the disadvantage that the geometric freedom of the semifinished product or component to be produced is quite limited. Furthermore, the metal matrix composite materials used hitherto are usually heavy, which is disadvantageous in particular in the aerospace industry. In addition, they have the disadvantage that no frictional connection between fibers and metal is generated.
- PVD / CVD process for example, fibers can be coated all-encompassing, but only with relatively high expenditure on equipment at the same time long coating times.
- a layer thickness of, for example, 0.1 mm is in a PVD / CVD method depending on Material requires a period of several hours to a few days.
- the PVD / CVD process a variety of different materials can be deposited, but only with above-average process times.
- the component size to be coated is limited by the dimensioning of the required vacuum boiler.
- US 5 846 288 discloses a process for producing an electrically conductive material which can be used, for example, for the production of pressed or sintered conductive strips or rods, in which granular particles produced in a solution of silver salts of tin oxide are coated.
- the object of the invention is to provide a metal matrix fiber composite, which has a high strength, is non-combustible and insensitive to fracture, and to provide a method for producing such, which is simple and fast to perform.
- the object is achieved by a fiber composite material with the features of claim 1. Furthermore, the object is achieved by a method for producing a fiber composite material having the features of claim 14. Advantageous embodiments and further developments of the subject invention are specified in the dependent claims.
- the invention provides a fiber composite material with a metallic matrix.
- this is characterized by a fiber material consisting of individual fibers and a metallic coating which forms the metallic matrix, the metallic coating comprising a metallization layer surrounding the fibers and a metallic end layer applied in turn to the metallization layer.
- the metallic coating may comprise an additional metallic adhesive layer located between the metallization layer and the metallic end layer, which is advantageous in particular for thermally sprayed end layers for improving the adhesion.
- the metallization layer may have a thickness of 0.5 ⁇ m to 0.5 mm.
- the metallic end layer can have a thickness of 2 ⁇ m to 20 mm or preferably 20 ⁇ m to 2 mm.
- the additional metallic adhesive layer may have a thickness of 2 ⁇ m to 1 mm or 20 ⁇ m to 200 ⁇ m.
- the fibers may be glass, carbon and / or aramid fibers. Particular preference is given to using fibers of electrically non-conductive material.
- the metallization layer and / or the additional metallic adhesion layer may contain copper and / or nickel.
- the final metal layer is typically a light metal (e.g., aluminum), which is particularly advantageous for weight reasons. However, it is also possible to use copper base materials or heavy metals.
- the fibrous material may be formed by a scrim (e.g., fiber nonwoven), woven or braided fiber.
- the fibers of the fabric, fabric or braid as such are coated with the metallization layer or with the metallization layer and the additional metallic adhesion layer, and the scrim, fabric or braid as a whole is coated with the final layer.
- the fibers of the fabric, fabric or braid as such are coated with the metallization layer or with the metallization layer and the additional metallic adhesion layer, and the scrim, fabric or braid as a whole is coated with the final layer.
- the metal matrix fiber composite according to the invention can in
- Aircraft construction e.g., wings, rudders, etc.
- automotive racing e.g., spoilers, fairing, underbody, etc.
- missiles sports equipment, and more.
- the invention provides a method for producing a
- Fiber composite material with metallic matrix created.
- a metallic coating which forms the metallic matrix to be applied to a fiber material consisting of individual fibers, the metallic coating being formed by a metallization layer surrounding the fibers and, in turn, on the
- Metallization layer applied metallic final layer is formed.
- the metallic coating may include a metallic adhesive layer applied between the metallization layer and the final metallic layer, which is particularly advantageous when the final layer is applied by thermal spraying.
- the metallization layer can be applied chemically / reactively or by thermal spraying.
- the metallic end layer can be applied galvanically or by thermal spraying.
- Application by thermal spraying is particularly simple, fast and inexpensive, and allows a high degree of flexibility with regard to the desired geometry.
- the additional metallic adhesive layer can also be applied galvanically or by thermal spraying.
- the fibers forming the fiber material are, for example, glass, carbon and / or aramid fibers. However, there are particular advantages in using fibers of electrically nonconductive material which are rendered conductive by the metallization layer described above.
- the metallization layer and / or the additional metallic adhesion layer can be formed by copper and / or nickel.
- the metallic end layer is typically made of a light metal (e.g., aluminum), but it may be formed of a copper-based alloy or a heavy metal.
- the fiber material can be formed by a scrim, fabric or mesh of the fibers.
- the fibers of the fabric, fabric or braid may be coated with the metallization layer or with the metallization layer and the additional metallic adhesion layer, and the scrim, fabric or braid as a whole may be coated with the final layer. It is likewise possible for the fabric layer, woven fabric or braid in its entirety to be coated with the metallization layer and, if appropriate, the adhesion layer in such a way that the fibers are completely coated, and then the final layer is applied, preferably by thermal spraying.
- Fiber composite material is provided with metallic matrix, in which the fibers with the metallic matrix, in particular the metallization, are positively connected. This is not the case with previous methods and metal-matrix composites.
- the fiber composite material shown in the figure which is generally designated by the reference numeral 10, comprises a metallic matrix, which binds and surrounds a fiber material.
- the fiber material consists of the fibers 1 shown very diagrammatically in the figure, which may for example be formed by electrically non-conductive glass fibers, or e.g. also by carbon or aramid fibers.
- a metallic conductive layer On the fibers 1 is a metallic conductive layer, which is also referred to below as the metallization layer 2, on which in turn a metallic adhesive layer 3 may be applied.
- the metallization layer 2 and the metallic adhesion layer 3 are each applied to the individual fibers 1, which are processed in the illustrated embodiment to a mesh fabric.
- the metallic end layer 4 is applied to the fiber fabric as a whole.
- the metallic end layer 4 can also be applied directly to the metallization layer 2; in this case, on the individual fibers 1, only the metallization layer 2, which is subsequently connected e.g. are processed into a fiber fabric, on which then the total metallic end layer 4 is applied.
- a finished fiber material for example in the form of a fiber mesh semifinished product or a mesh fabric
- an adhesive layer 3 may optionally be applied to the metallization layer 2 to subsequently coat the final layer 4, e.g. apply by thermal spraying.
- the fibers 1 must first be pretreated in order to be able to coat them adherently, in particular if they consist of electrically non-conductive material (eg glass fibers).
- the application of metallic Final layer 4 can be carried out galvanically or by thermal spraying according to the embodiment described here.
- the surface of the fibers 1 must be conductive.
- the fibers 1 are therefore provided in a first step with said metallic conductive layer or metallization layer 2.
- the metallization layer 2 can be applied, for example, reductive / chemical or by thermal spraying.
- the metallic end layer 4 may be applied by thermal spraying, for example. Also in this case is a previous one
- the additional metallic adhesive layer 3 can be applied, for example, galvanically or by thermal spraying.
- the metallization layer 2 or the metallization layer 2 and the metallic adhesion layer 3 thus form the basis for the thermally sprayed metallic final layer 4.
- the metallization layer 2 can also be applied to the individual fibers 1, while the additional metallic adhesive layer 3 is applied to the fiber material formed by the fibers 1, whereupon in turn the metallic end layer 4 is applied.
- a prefabricated (for example commercially available) fiber material can be assumed, which is provided with the metallization layer 2 in a first step. In this case, care must be taken that the individual fibers 1 are each enclosed by the metallization layer 2.
- the metallization layer 2 may typically have a thickness of 0.5 ⁇ m to 0.5 mm, but the thickness is not limited to this range.
- the additional metallic adhesive layer 3 may have a thickness of 2 microns to 1 mm, in particular from 20 microns to 200 microns, but without this Area to be limited.
- the metallic end layer 4 can have a very different thickness, depending on the field of application between 2 ⁇ m and 20 mm, preferably between 20 ⁇ m and 2 mm.
- the metallic conductive layer or metallization layer 2 may contain or may be formed by any metals suitable for the purpose (e.g., copper and / or nickel).
- the metallic end layer 4 may also contain or be formed by any suitable metals.
- the final layer 4 is made of light metals (e.g., aluminum), copper base materials, or heavy metals.
- the additional electroplated or by thermal spraying adhesive layer 3 may also contain or be formed by copper and / or nickel and / or aluminum or another suitable metal.
- Arc wire spraying with a light metal e.g., aluminum
- the arc wire spraying can be carried out until the gaps of the original glass fiber grid are closed and a compact, continuous layer (composite) is created.
- This composite is characterized by high strength and low weight at the same time.
- mechanical processing methods such as drilling, milling, grinding, polishing or the like of this composite are possible.
- the described fiber matrix composite with metallic matrix forms a highly solid, non-flammable, unbreakable material without fragmentation behavior with an optimum ratio of strength to weight.
- the matrix materials are not limited to light metals, e.g. Aluminum, any other suitable metals can be used, which can be applied in a suitable form as a layer on the prepared fiber material.
- the actual matrix is formed essentially only by this coating, and a non-positive connection between the fibers and the metallic matrix is produced.
- a particular advantage over, for example PVD / CVD method consists firstly that the order speed is much greater, that the fibers can be coated from all sides, and that in terms of the size of the components are not the limits as in the said vacuum process, at where the dimension is limited by the size of the surrounding vacuum vessel.
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200710004531 DE102007004531A1 (en) | 2007-01-24 | 2007-01-24 | Fiber composite with metallic matrix and process for its preparation |
PCT/DE2008/000055 WO2008089722A2 (en) | 2007-01-24 | 2008-01-12 | Fiber composite comprising a metallic matrix, and method for the production thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2113036A2 true EP2113036A2 (en) | 2009-11-04 |
EP2113036B1 EP2113036B1 (en) | 2014-10-08 |
Family
ID=39563927
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08706752.6A Active EP2113036B1 (en) | 2007-01-24 | 2008-01-12 | Method for the production of a fiber composite comprising a metallic matrix |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100092751A1 (en) |
EP (1) | EP2113036B1 (en) |
JP (1) | JP5535649B2 (en) |
CN (1) | CN101636516B (en) |
BR (1) | BRPI0807808A2 (en) |
CA (1) | CA2676731C (en) |
DE (1) | DE102007004531A1 (en) |
RU (1) | RU2465364C2 (en) |
WO (1) | WO2008089722A2 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2975317B1 (en) * | 2011-05-18 | 2013-05-31 | Snecma | METHOD FOR MANUFACTURING BY DIFFUSION WELDING OF A MONOBLOC PIECE FOR A TURBOMACHINE |
DE102012011264A1 (en) * | 2012-06-07 | 2013-12-12 | Technische Universität Dresden | Metal casting composite component has component main portion with which textile fiber reinforcement formed from fibers, threads, fiber bundles or metallic wires is embedded |
DE102013016854A1 (en) * | 2013-10-10 | 2015-04-16 | Airbus Defence and Space GmbH | Composite fiber semifinished product and method for producing semifinished fiber composite products |
RU2568407C1 (en) * | 2014-07-01 | 2015-11-20 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Fibrous composite material with matrix based on niobium |
US10883177B2 (en) | 2016-03-25 | 2021-01-05 | Mitsubishi Heavy Industries Engine & Turbocharger, Ltd. | Plated fiber-reinforced member and plating method for fiber-reinforced member |
US11306384B2 (en) | 2017-07-10 | 2022-04-19 | ResOps, LLC | Strengthening mechanism for thermally sprayed deposits |
DE102017120270B4 (en) | 2017-09-04 | 2024-03-28 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Vehicle and method for producing an inspection hatch |
RU2726422C1 (en) * | 2019-06-17 | 2020-07-14 | Общество с ограниченной ответственностью "ЭЛКАД" | Hybrid pipe |
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US3807996A (en) * | 1972-07-10 | 1974-04-30 | Union Carbide Corp | Carbon fiber reinforced nickel matrix composite having an intermediate layer of metal carbide |
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SU531645A1 (en) * | 1975-03-07 | 1976-10-15 | Физико-технический институт АН Белорусской ССР | A method of manufacturing a fibrous composite material |
JPS6041136B2 (en) * | 1976-09-01 | 1985-09-14 | 財団法人特殊無機材料研究所 | Method for manufacturing silicon carbide fiber reinforced light metal composite material |
JPS589822B2 (en) * | 1976-11-26 | 1983-02-23 | 東邦ベスロン株式会社 | Carbon fiber reinforced metal composite prepreg |
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-
2007
- 2007-01-24 DE DE200710004531 patent/DE102007004531A1/en not_active Ceased
-
2008
- 2008-01-12 EP EP08706752.6A patent/EP2113036B1/en active Active
- 2008-01-12 JP JP2009546643A patent/JP5535649B2/en not_active Expired - Fee Related
- 2008-01-12 US US12/524,408 patent/US20100092751A1/en not_active Abandoned
- 2008-01-12 WO PCT/DE2008/000055 patent/WO2008089722A2/en active Application Filing
- 2008-01-12 CN CN2008800030014A patent/CN101636516B/en active Active
- 2008-01-12 RU RU2009131843/02A patent/RU2465364C2/en not_active IP Right Cessation
- 2008-01-12 CA CA2676731A patent/CA2676731C/en not_active Expired - Fee Related
- 2008-01-12 BR BRPI0807808 patent/BRPI0807808A2/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO2008089722A2 * |
Also Published As
Publication number | Publication date |
---|---|
CA2676731A1 (en) | 2008-07-31 |
EP2113036B1 (en) | 2014-10-08 |
JP5535649B2 (en) | 2014-07-02 |
WO2008089722A3 (en) | 2008-12-04 |
RU2465364C2 (en) | 2012-10-27 |
CN101636516B (en) | 2011-12-14 |
WO2008089722A2 (en) | 2008-07-31 |
RU2009131843A (en) | 2011-02-27 |
US20100092751A1 (en) | 2010-04-15 |
CN101636516A (en) | 2010-01-27 |
JP2010516504A (en) | 2010-05-20 |
BRPI0807808A2 (en) | 2014-06-17 |
CA2676731C (en) | 2013-08-13 |
DE102007004531A1 (en) | 2008-07-31 |
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