EP2091954A2 - Metallverbindungen als initiatoren - Google Patents
Metallverbindungen als initiatorenInfo
- Publication number
- EP2091954A2 EP2091954A2 EP07821523A EP07821523A EP2091954A2 EP 2091954 A2 EP2091954 A2 EP 2091954A2 EP 07821523 A EP07821523 A EP 07821523A EP 07821523 A EP07821523 A EP 07821523A EP 2091954 A2 EP2091954 A2 EP 2091954A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- sbf
- epoxy resin
- resin system
- trans
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003999 initiator Substances 0.000 title claims abstract description 88
- 150000002736 metal compounds Chemical class 0.000 title description 3
- 238000002360 preparation method Methods 0.000 claims abstract description 55
- 239000003446 ligand Substances 0.000 claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 23
- 239000004593 Epoxy Substances 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 230000000536 complexating effect Effects 0.000 claims abstract description 3
- 229910018286 SbF 6 Inorganic materials 0.000 claims description 79
- 229920000647 polyepoxide Polymers 0.000 claims description 78
- 239000003822 epoxy resin Substances 0.000 claims description 74
- 229920005989 resin Polymers 0.000 claims description 61
- 239000011347 resin Substances 0.000 claims description 61
- 239000000203 mixture Substances 0.000 claims description 50
- -1 hexafluoroantimonate Chemical compound 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 29
- 230000005855 radiation Effects 0.000 claims description 28
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 claims description 21
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 18
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 17
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 15
- 150000001768 cations Chemical class 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 14
- 238000010894 electron beam technology Methods 0.000 claims description 14
- 238000009472 formulation Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 11
- 229920003986 novolac Polymers 0.000 claims description 11
- VFTFKUDGYRBSAL-UHFFFAOYSA-N 15-crown-5 Chemical compound C1COCCOCCOCCOCCO1 VFTFKUDGYRBSAL-UHFFFAOYSA-N 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 claims description 8
- 238000005755 formation reaction Methods 0.000 claims description 8
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 claims description 7
- 239000004912 1,5-cyclooctadiene Substances 0.000 claims description 7
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 229920001971 elastomer Polymers 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 150000002170 ethers Chemical class 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 claims description 5
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims description 5
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- CHVJITGCYZJHLR-UHFFFAOYSA-N cyclohepta-1,3,5-triene Chemical compound C1C=CC=CC=C1 CHVJITGCYZJHLR-UHFFFAOYSA-N 0.000 claims description 5
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 claims description 5
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims description 5
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 229940031439 squalene Drugs 0.000 claims description 5
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 claims description 5
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- ZOLLIQAKMYWTBR-FFWAUJBHSA-N (1e,5e,9e)-cyclododeca-1,5,9-triene Chemical compound C/1C\C=C\CC\C=C\CC\C=C\1 ZOLLIQAKMYWTBR-FFWAUJBHSA-N 0.000 claims description 4
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 claims description 4
- 239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 claims description 4
- ILPBINAXDRFYPL-HWKANZROSA-N (E)-2-octene Chemical compound CCCCC\C=C\C ILPBINAXDRFYPL-HWKANZROSA-N 0.000 claims description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- XEZNGIUYQVAUSS-UHFFFAOYSA-N 18-crown-6 Chemical compound C1COCCOCCOCCOCCOCCO1 XEZNGIUYQVAUSS-UHFFFAOYSA-N 0.000 claims description 4
- XNMQEEKYCVKGBD-UHFFFAOYSA-N 2-butyne Chemical group CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims description 4
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- FYGUSUBEMUKACF-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene-5-carboxylic acid Chemical compound C1C2C(C(=O)O)CC1C=C2 FYGUSUBEMUKACF-UHFFFAOYSA-N 0.000 claims description 4
- 230000009918 complex formation Effects 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- ZOLLIQAKMYWTBR-RYMQXAEESA-N cyclododecatriene Chemical compound C/1C\C=C\CC\C=C/CC\C=C\1 ZOLLIQAKMYWTBR-RYMQXAEESA-N 0.000 claims description 4
- KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 claims description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000000565 sealant Substances 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 3
- 229910017008 AsF 6 Inorganic materials 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001345 alkine derivatives Chemical class 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000011258 core-shell material Substances 0.000 claims description 3
- 229930003836 cresol Natural products 0.000 claims description 3
- 150000003983 crown ethers Chemical class 0.000 claims description 3
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 claims description 3
- 239000004913 cyclooctene Substances 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- OZZYKXXGCOLLLO-TWTPFVCWSA-N ethyl (2e,4e)-hexa-2,4-dienoate Chemical compound CCOC(=O)\C=C\C=C\C OZZYKXXGCOLLLO-TWTPFVCWSA-N 0.000 claims description 3
- 239000002071 nanotube Substances 0.000 claims description 3
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims description 3
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 229920005992 thermoplastic resin Polymers 0.000 claims description 3
- FZERLKNAJSFDSQ-DDHJBXDOSA-N (2r,3r,11r,12r)-1,4,7,10,13,16-hexaoxacyclooctadecane-2,3,11,12-tetracarboxylic acid Chemical compound OC(=O)[C@@H]1OCCOCCO[C@@H](C(O)=O)[C@H](C(O)=O)OCCOCCO[C@H]1C(O)=O FZERLKNAJSFDSQ-DDHJBXDOSA-N 0.000 claims description 2
- WTTJVINHCBCLGX-UHFFFAOYSA-N (9trans,12cis)-methyl linoleate Natural products CCCCCC=CCC=CCCCCCCCC(=O)OC WTTJVINHCBCLGX-UHFFFAOYSA-N 0.000 claims description 2
- KEIFWROAQVVDBN-UHFFFAOYSA-N 1,2-dihydronaphthalene Chemical compound C1=CC=C2C=CCCC2=C1 KEIFWROAQVVDBN-UHFFFAOYSA-N 0.000 claims description 2
- DVWSXZIHSUZZKJ-UHFFFAOYSA-N 18:3n-3 Natural products CCC=CCC=CCC=CCCCCCCCC(=O)OC DVWSXZIHSUZZKJ-UHFFFAOYSA-N 0.000 claims description 2
- ROKSAUSPJGWCSM-UHFFFAOYSA-N 2-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol Chemical compound C1C2C(C)(C)C1CC=C2CCO ROKSAUSPJGWCSM-UHFFFAOYSA-N 0.000 claims description 2
- LJBWJFWNFUKAGS-UHFFFAOYSA-N 2-[bis(2-hydroxyphenyl)methyl]phenol Chemical compound OC1=CC=CC=C1C(C=1C(=CC=CC=1)O)C1=CC=CC=C1O LJBWJFWNFUKAGS-UHFFFAOYSA-N 0.000 claims description 2
- LNJCGNRKWOHFFV-UHFFFAOYSA-N 3-(2-hydroxyethylsulfanyl)propanenitrile Chemical compound OCCSCCC#N LNJCGNRKWOHFFV-UHFFFAOYSA-N 0.000 claims description 2
- DQQNMIPXXNPGCV-UHFFFAOYSA-N 3-hexyne Chemical compound CCC#CCC DQQNMIPXXNPGCV-UHFFFAOYSA-N 0.000 claims description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 2
- UHUUGQDYCYKQTC-UHFFFAOYSA-N 4-[2,2,2-tris(4-hydroxyphenyl)ethyl]phenol Chemical compound C1=CC(O)=CC=C1CC(C=1C=CC(O)=CC=1)(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UHUUGQDYCYKQTC-UHFFFAOYSA-N 0.000 claims description 2
- YWFPGFJLYRKYJZ-UHFFFAOYSA-N 9,9-bis(4-hydroxyphenyl)fluorene Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 YWFPGFJLYRKYJZ-UHFFFAOYSA-N 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 2
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 claims description 2
- PKIXXJPMNDDDOS-UHFFFAOYSA-N Methyl linoleate Natural products CCCCC=CCCC=CCCCCCCCC(=O)OC PKIXXJPMNDDDOS-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 2
- HFKJQIJFRMRSKM-UHFFFAOYSA-N [3,5-bis(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1 HFKJQIJFRMRSKM-UHFFFAOYSA-N 0.000 claims description 2
- JRXXLCKWQFKACW-UHFFFAOYSA-N biphenylacetylene Chemical group C1=CC=CC=C1C#CC1=CC=CC=C1 JRXXLCKWQFKACW-UHFFFAOYSA-N 0.000 claims description 2
- XFUOBHWPTSIEOV-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohexane-1,2-dicarboxylate Chemical compound C1CCCC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 XFUOBHWPTSIEOV-UHFFFAOYSA-N 0.000 claims description 2
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- WFYPICNXBKQZGB-UHFFFAOYSA-N butenyne Chemical group C=CC#C WFYPICNXBKQZGB-UHFFFAOYSA-N 0.000 claims description 2
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 150000004292 cyclic ethers Chemical class 0.000 claims description 2
- UCIYGNATMHQYCT-OWOJBTEDSA-N cyclodecene Chemical compound C1CCCC\C=C\CCC1 UCIYGNATMHQYCT-OWOJBTEDSA-N 0.000 claims description 2
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 claims description 2
- ZDSFBVVBFMKMRF-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)silane Chemical compound C=CC[Si](C)(C)CC=C ZDSFBVVBFMKMRF-UHFFFAOYSA-N 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 2
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 claims description 2
- 150000004761 hexafluorosilicates Chemical class 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- 235000001510 limonene Nutrition 0.000 claims description 2
- 229940087305 limonene Drugs 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- DVWSXZIHSUZZKJ-YSTUJMKBSA-N methyl linolenate Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(=O)OC DVWSXZIHSUZZKJ-YSTUJMKBSA-N 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- GHUURDQYRGVEHX-UHFFFAOYSA-N prop-1-ynylbenzene Chemical compound CC#CC1=CC=CC=C1 GHUURDQYRGVEHX-UHFFFAOYSA-N 0.000 claims description 2
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 claims description 2
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims description 2
- 235000021286 stilbenes Nutrition 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 claims description 2
- ANEFWEBMQHRDLH-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl) borate Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1OB(OC=1C(=C(F)C(F)=C(F)C=1F)F)OC1=C(F)C(F)=C(F)C(F)=C1F ANEFWEBMQHRDLH-UHFFFAOYSA-N 0.000 claims description 2
- HYPABJGVBDSCIT-UHFFFAOYSA-N cyclododecene Chemical compound C1CCCCCC=CCCCC1 HYPABJGVBDSCIT-UHFFFAOYSA-N 0.000 claims 1
- URYYVOIYTNXXBN-UHFFFAOYSA-N cyclooctene Chemical compound [CH]1[CH]CCCCCC1 URYYVOIYTNXXBN-UHFFFAOYSA-N 0.000 claims 1
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims 1
- 239000004848 polyfunctional curative Substances 0.000 claims 1
- 238000001723 curing Methods 0.000 description 36
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- XKGLSKVNOSHTAD-UHFFFAOYSA-N valerophenone Chemical compound CCCCC(=O)C1=CC=CC=C1 XKGLSKVNOSHTAD-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
Definitions
- the present invention relates to initiators of the general formula ⁇ [M (L) a ] X b ⁇ n , these preferably having (SbF 6 ) as counterion and being preferably obtainable by complexing reaction of a corresponding metal-SbF 6 salt with a corresponding ligand (L). Furthermore, the present invention relates to preparations and epoxy resin systems which contain such initiators and in particular are non-thermally and / or thermally curable.
- initiators that initiate the curing reactions are of particular importance.
- initiators should be usable at room temperature and cause rapid curing and yet not adversely affect the mechanical properties of the products.
- the initiators should still meet certain requirements, such as good solubility in the monomer and storage stability.
- the initiators should also have no side effects like yellowing of the
- curable resins have been hardened by radiant energy for some years.
- a polymerization (hardening) can therefore not only thermally but also by
- the radiation is attenuated upon penetration of the resin, or the radiation energy is largely attenuated or absorbed, for example, in the presence of a substance capable of absorbing a wavelength corresponding to that of the radiant energy.
- No. 5,726,216 claims a process for the preparation of non-thermally cured epoxy resins in which diaryliodonium salts are used as cationic initiators and curing is carried out by means of high-energy ionizing radiation at a dose of greater than 0.75 kilogray / sec.
- EP0843685 B1 claims a process for the preparation of a toughened, non-thermally curing epoxy resin system which also contains a cationic initiator consisting of a diaryl iodonium salt and in which the curing is carried out at a dose rate of more than 1 kilogray / sec.
- a further object of the present invention was to provide initiators which sufficiently cure a system, preferably a resin system, non-thermally and / or thermally (initiated), and which has a high degree of crosslinking after curing. Curing with the initiators according to the invention should not adversely affect in particular the thermomechanical and mechanical properties of the cured product.
- Another object of the present invention was to provide preparations as well
- Resin systems in particular epoxy resin systems containing the initiators of the invention to provide.
- a good storage stability of the formulations and preparations containing such initiators is a particularly important factor.
- the initiators according to the invention have a comparable and in part also improved crosslinking density in resins in comparison with the initiator systems of the prior art.
- the present invention therefore provides initiators of the general formula (I)
- the counterion (X) is preferably selected from hexafluoroantimonate (SbF 6 ), hexafluorophosphate (PF 6 ), boron tetrafluoride (BF 4 ), hexafluoroaluminate (AIF 6 3 ), trifluoromethanesulfonate (CF 3 SO 3 " ), nitrate (NO 3 " ) Hexafluoroarsenate (AsF 6 " ), tetrakis (pentafluorophenylborate) (B [C 6 F 5 ] 4 - ), tetrakis [3,5-bis (trifluoromethyl) phenyl] borate (B [C 6 H 3 (CF 3 ) 2 ] 4 - ), Tetraphenylborate (B [C 6 H 5 ] 4 - ), hexafluorotitanate (TiF 6 2 " ), hexafluorogermanate (GeF
- Another object of the present invention are initiators comprising at least one metal cation (M), at least one ligand (L) and at least one molecule Hexafluoroantimonat (SbF 6 " ) as a counterion, obtainable by the complex formation reaction of a corresponding metal SbF 6 salt with a corresponding ligands (L).
- the corresponding metal-SbF 6 salt is first formed before the complex formation reaction with the corresponding ligand (L).
- At least one reaction product of the complex formation reaction comprises a complex of the general formula (II)
- M metal cation
- L ligand
- a 1 to 10, preferably 1 to 6, particularly preferably 1 to 4
- b 1 to 10, preferably 1 to 6, particularly preferably 1 to 3
- n 1 to ⁇ , wherein a, b, and n are both integers can represent as well as number ranges and a in addition also can not represent whole numbers.
- the metal cation (M) of the initiators (I) and / or (II) according to the invention may be selected from the group of the transition metals of the fourth or fifth period or the second or third main group of the periodic table.
- the metal cation (M) is selected from the group comprising Ag, Fe, Mg, Co, Cu, Al or Ti.
- the ligand (L) is a compound having at least one (C)
- the ligand (L) is an ether, in particular a cyclic ether, preferably a crown ether.
- the ligand (L) is a compound from the group of nitriles. Such a compound comprises at least one C ⁇ N group.
- Suitable preferred ligands (L) are for example selected from propene, 1-butene, 1-pentene, 1-hexene, 1-octene, 1-decene, isoprene, norbornene, cyclohexene, cyclooctene, cyclodecene, 1, 4-cyclohexadiene, 4- Vinylcyclohexene, trans-2-octene, styrene, 5-norbornene-2-carboxylic acid, butadiene, 1, 5-hexadiene, 1, 6-heptadiene, 1, 7-octadiene, 1, 9-decadiene, sorbic acid ethyl ester, 1, 3 Cyclohexadiene, 1,3-cyclooctadiene, 1,5-cyclooctadiene, norbornadiene, dicyclopentadiene, cycloheptatriene, trans, trans, trans-1, 5,9-cyclododecatrien
- a, b, and n can represent both integers and number ranges, and a can not additionally represent integers.
- n is preferably either 1 (monomeric metal complex) or is preferably in the range of 1 to ⁇ (monomeric, dimer, trimeric, oligomeric and polymeric coordination compounds or mixtures of these), for example preferably 1 to 20,000, more preferably 1 to 1000, most particularly preferably 1 to 500 or 1 to 300. Particularly preferred for n, however, is a number range between 1 to ⁇ (infinite).
- the initiators according to the invention can represent coordination polymers in the case of polyfunctional ligands L (dienes, trienes, oligoalkenes, dune, oligoalkynes), ⁇ in the present invention means that n can go to infinity.
- n 1, it means according to the invention that monomeric coordination compounds are present. If n is a numerical range from 1 to ⁇ , this means that monomeric as well as dimeric, trimeric, oligomeric and polymeric coordination compounds, so-called coordination polymers, and mixtures of these with different chain lengths are present.
- a mixture of initiators of the general formula (I) is present, particularly preferably a mixture of initiators of the general formula (II) is present.
- cyclic di-, tri- or tetraenes eg, 1, 5-cyclooctadiene, cycloheptatriene or cyclooctatetraene
- mononuclear metal complexes eg, 1, 5-cyclooctadiene, cycloheptatriene or cyclooctatetraene
- polynuclear ligand-bridged structures e.g. 1, 5-cyclooctadiene, cycloheptatriene or cyclooctatetraene
- open-chain dienes are used as ligands L, depending on the metal cation and anion, the formation of coordination polymers may also be favored.
- the ligands 1, 5-hexadiene and 1, 9-decadiene preferably give similar structures. As the number of double bonds in the ligand increases, more and more branching possibilities arise, the resulting structures preferably become more complex, and mixtures of different crosslinked oligomeric and polymeric coordination compounds are preferably obtained, such as the squalene ligand, an open-chain hexaalkene. Preferably, in addition to mononuclear compounds and polynuclear compounds are formed.
- Inventive initiators are [Ag (cyclohexene) 2 ] SbF 6 ,
- the initiators of the invention preferably initiate the polymerization by formation of
- the initiators of the invention are also
- Another object of the present invention are preparations containing at least one initiator of the invention.
- preparation in the context of the present invention for mixtures containing at least one initiator of the invention and at least one further additive, as it is either due to the nature of the preparation of the initiators of the invention (for example, solvents, catalysts) or added later (for example, plasticizer , Reactive diluents, fillers and the like).
- the preparation according to the invention preferably comprises one or more additional constituents (additives) which are selected from the group of fillers, stabilizers, hardening accelerators, antioxidants, adhesion promoters, rheological agents, thickeners, binders, solvents, free-radical scavengers, catalysts, reactive diluents, plasticizers, additive resins, flame retardant additives, impact additives such as elastomers, thermoplastics, core-shell particles, nanoparticles, block copolymers, nanotubes.
- further customary additives such as dispersants, anti-scratch agents, pigments, dyes, emulsifiers (surfactants), corrosion inhibitors may be added to the preparations according to the invention.
- the concentration of the initiators according to the invention in the preparations is preferably 0.01 to 10% by weight, preferably 0.5 to 3% by weight, and more preferably 1 to 2% by weight, based on the total composition.
- Suitable plasticizers are, for example, preferably esters such as abietic acid esters, adipic acid esters, azelaic acid esters, benzoic acid esters, butyric acid esters, acetic acid esters, phosphoric esters, phthalic acid esters; Esters of higher fatty acids having from about 8 to about 44 carbon atoms, such as dioctyl adipate, diisodecylsuccinate, dibutyl sebacate or butyl oleate, esters containing OH groups or epoxidized fatty acids, fatty acid esters and fats, glycolic esters, phosphoric esters, phthalic acid esters, linear containing from 1 to 12 carbon atoms or branched alcohols such as dioctyl phthalate, dibutyl phthalate or butyl benzyl phthalate, propionic acid esters, sebacic acid esters, sulfonic acid esters, thiobutyric
- asymmetric esters of difunctional, aliphatic dicarboxylic acids for example the esterification product of adipic acid monooctyl ester with 2-ethylhexanol (Edenol DOA, Fa. Henkel, Dusseldorf).
- plasticizers are preferably the pure or mixed ethers of monofunctional, linear or branched C 4-16 -alcohols or mixtures of two or more different ethers of such alcohols, for example dioctyl ether (obtainable as Cetiol OE, from Henkel, Dusseldorf).
- end-compounded polyethylene glycols are used as plasticizers.
- plasticizers polyethylene or polypropylene glycol di-C1-4 alkyl ethers, in particular the dimethyl or diethyl ether of diethylene glycol or dipropylene glycol, and mixtures of two or more of these.
- the preparation of the invention may contain up to about 80% by weight of fillers.
- suitable fillers are inorganic fillers, such as naturally occurring or synthetic materials such as quartz, nitrides (eg, silicon nitride), eg glasses derived from Ce, Sb, Sn, Zr, Sr, Ba and Al, colloidal silica, feldspar, borosilicate glasses, kaolin, talc, titanium dioxide and zinc glasses, as well as submicron sized silica particles ( For example, pyrogenic silicas, such as the "Aerosil” series “OX 50", "130", “150” and “200” silicas sold by Degussa, and "Cab-O-Sil M5" available from Cabot Corp.
- fillers can be used which impart thixotropy to the formulation, for example swellable plastics such as PVC.
- Suitable additive resins are all natural and synthetic resins, such as rosin derivatives (for example, by disproportionation, hydrogenation or esterification derived derivatives), coumarone-indene and polyterpene resins, aliphatic or aromatic hydrocarbon resins (C-5-, C -9-, (C-5) 2-resins), mixed C-5 / C-9 resins, hydrogenated and partially hydrogenated derivatives of the types mentioned, resins of styrene or ⁇ -methylstyrene and terpene-phenolic resins and others as listed in Ullmanns Encyclopedia of Industrial Chemistry (4th ed.), Volume 12, pp. 525-555, Weinheim.
- rosin derivatives for example, by disproportionation, hydrogenation or esterification derived derivatives
- coumarone-indene and polyterpene resins aliphatic or aromatic hydrocarbon resins (C-5-, C -9-, (C-5) 2-resins), mixed C-5 / C-9 resins
- Suitable solvents are water, ketones, lower alcohols, lower carboxylic acids, ethers and esters such as (meth) acrylic acid (ester), acetone, acetylacetone, acetoacetic ester, methyl ethyl ketone, methyl isobutyl ketone, cyclopentanone, cyclohexanone, N-methylpyrrolidone, dioxane, tetrahydrofuran, 2-methoxyethanol , 2-ethoxyethanol, 1-methoxy-2-propanol, 1, 2-dimethoxyethane, ethyl acetate, n-butyl acetate, ethyl 3-ethoxypropionate, methanol, ethanol, iso-propanol, n-propanol, n-butanol, iso-butanol , sec-butanol, tert-butanol, diacetone alcohol, 2-ethylhexyl
- adhesion promoters and / or reactive diluents ⁇ -silanes are advantageously selected from the group consisting of -, ⁇ -methacrylic, ⁇ -carbamatosilanes and ⁇ -alkoxysilanes. Suitable examples are (methacryloxymethyl) methyldiethoxysilane and methacryloxymethyltriethoxysilane, N- (triethoxysilylmethyl) -O-methyl-carbannate and N- (methyldiethoxysilylmethyl) -O-methyl-carbannate.
- Morpholine, N-methylmorpholine, 1, 3-diazabicyclo [5.4.6] undecene-7 (DBU) are particularly suitable catalysts for promoting crosslinking.
- Suitable catalysts are those based on organic or inorganic heavy metal compounds, such as, for example, cobalt naphthenate, dibutyltin dilaurate, tin mercaptides, tin dichloride, zirconium tetraoctoate, tin naphthenate, tin stearate, antimony octoate, lead octoate, metal acetoacetate, especially iron acetylacetonate.
- organic or inorganic heavy metal compounds such as, for example, cobalt naphthenate, dibutyltin dilaurate, tin mercaptides, tin dichloride, zirconium tetraoctoate, tin naphthenate, tin stearate, antimony octoate, lead octoate, metal acetoacetate, especially iron acetylacetonate.
- Examples of such compounds are dibutyltin dilaurate, dibutyltin dimaleate, tin octoate, isopropyltriisostearoyl titanate, isopropyltris (dioctylpyrophosphate) titanate,
- Dibutyltin alkyl esters such as dibutyltin alkyl maleates or dibutyltin laurates are particularly suitable, especially dibutyltin bisethyl maleate, dibutyltin bisbutyl maleate, dibutyltin bisoctyl maleate, dibutyltin bisoleyl maleate, dibutyltin bisacetylacetate, dibutyltin diacetate, dibutyltin dioctoate, dibutyltin oxide, dibutyltin bis-triethoxysilicate and their catalytically active derivatives.
- the catalysts mentioned can be used alone or as a mixture of two or more of the catalysts mentioned.
- the preparations according to the invention may contain up to 5% by weight of such catalysts in the overall composition.
- the preparations according to the invention may further contain up to about 7% by weight, in particular about 3 to about 5% by weight, of antioxidants in the overall composition.
- the stabilizers or antioxidants which can be used as additives in the invention include hindered phenols of high molecular weight (M w ), polyfunctional phenols and sulfur and phosphorus-containing phenols.
- phenols are, for example, 1, 3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene; Pentaerythritol tetrakis-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate; n-octa-decyl-3,5-di-tert-butyl-4-hydroxyphenyl) propionate; 4,4-methylenebis (2,6-di-tert-butyl-phenol); 4,4-thiobis (6-tert-butyl-o-cresol); 2,6-di-tert-butylphenol; 2,4-dimethyl-6-tert-buty
- Suitable photostabilizers are, for example, those sold under the name Thinuvin®
- Suitable stabilizers may also be included, preferably selected from the groups of the oxanilides, triazines and benzotriazole (the latter available as Tinuvin ® grades from Ciba-Spezialitatenchemie) and benzophenones or combinations thereof. It may be advantageous to add light stabilizers that do not absorb UV light.
- a selection of suitable preferred UV absorbers and light stabilizers which may be included in the preparations according to the invention are:
- 2-hydroxybenzophenones for example the 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, A-
- Esters of substituted and unsubstituted benzoic acids such as 4-tert-butylphenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoylresorcinol, bis (4-tert-butylbenzoyl) resorcinol, benzoylresorcinol, 2,4-di-tert-butylphenyl-3,5-di- tert-butyl-4-hydroxybenzoate, hexadecyl-3,5-di-tert-butyl-4-hydroxybenzoate, octadecyl-3,5-di-tert-butyl-4-hydroxybenzoate, 2-methyl-4,6-di-benzoate, tert-butylphenyl-3,5-di-tert-butyl-4-hydroxybenzoate.
- the formulations according to the invention may contain up to about 2% by weight, preferably about 1% by weight, of such UV stabilizers in the overall composition.
- the preparations according to the invention can furthermore contain impact-resistant additives (impact modifiers).
- Suitable impact modifiers are, for example, end-functionalized or non-end-functionalized thermoplastics such as polysulfones, polyphenylsulfones, polyethersulfones (for example Radel and Udel from Solvay, or Ultrason from BASF), polyetheretherketones, polyetherketones,
- Polybutylene terephthalates polycarbonates, polyetherimides, polyethylene, nylon, polyamide-imides,
- Suitable elastomers which also act as impact modifiers are, for example, EPDM or EPM rubber, polyisobutylene, butyl rubber, ethylene-vinyl acetate, hydrogenated
- Block copolymers of dienes for example by hydrogenation of SBR, cSBR, SBS, SIS or IR, such polymers are known, for example, as SEPS and SEBS), copolymers of styrene,
- butadiene and ethylene, or styrene, butylenes, ethylene, butadiene, butyl rubber, neoprene
- Rubber and poly (siloxanes).
- Suitable nanoparticles which can also be used as impact modifiers are, in particular, those based on silica (for example nanopox of nanoresins), aluminum oxide, zirconium oxide and barium sulfate. They preferably have a particle size of less than 50 nm.
- suitable nanoparticles based on silica are pyrogenic silicas which are sold under the trade name Aerosil® VP8200, VP721 or R972 by Degussa or the trade names Cab 0 Sil® TS 610, CT 1110F or CT 1 110G by CABOT. "Multiwall" and "single-wall” nanotubes with a modified or unmodified surface can also be used.
- nanoparticles which are in the form of dispersions for example the dispersion which is sold under the trade name High Link® OG 103-31 by the company Clariant Hoechst.
- Suitable core-shell particles e.g. have a crosslinked silica core and a functionalized shell (e.g., Genioperl from Wacker, Albidur from Nanoresins) or the e.g. having a rubber core (e.g., Zeon, Kaneka) as well as suitable highly functionalized polymers e.g. Polyols, dendritic polymers (e.g., Perstorp's Boltorn) and polyester can also be used.
- a functionalized shell e.g., Genioperl from Wacker, Albidur from Nanoresins
- a rubber core e.g., Zeon, Kaneka
- suitable highly functionalized polymers e.g. Polyols, dendritic polymers (e.g., Perstorp's Boltorn) and polyester can also be used.
- the preparations according to the invention may contain up to 90% by weight, preferably up to 80% by weight, particularly preferably up to 50% by weight, of impact-strength additives in the overall composition.
- preparations of the invention may contain thermal inhibitors, which are intended to prevent premature polymerization.
- Suitable inhibitors are, for example, hydroquinone, hydroquinone derivatives, p-methoxyphenol, ⁇ -naphthol or sterically hindered phenols such as 2,6-di (tert-butyl) -p-cresol.
- Suitable dispersants are water-soluble high molecular weight organic compounds bearing polar groups, for example polyvinyl alcohols, polyethers, polyvinylpyrrolidone or cellulose ethers.
- Suitable emulsifiers may be nonionic emulsifiers and, in some cases, ionic emulsifiers may also be used.
- thermally activatable initiators may be added selected from organic azo compounds, organic peroxides, C-C cleaving initiators such as benzpinacol silyl ethers, hydroxy imides such as e.g. N-hydroxyphthalimide or N-hydroxysuccinimide.
- Suitable thermally activatable peroxo compounds which are suitable as initiators include representatives of the various peroxidic compounds, such as disuccinoyl peroxide, potassium peroxodisulfate, cyclohexylsulfonyl acetyl peroxide, dibenzoyl peroxide, cyclohexanone peroxide, di-tert-butyl peroxide, dialkyl peroxides, diacyl peroxides, peroxydicarbonates, perketals, peroxycarboxylic acids and their esters, Ketone peroxides and / or hydroperoxides.
- peroxidic compounds such as disuccinoyl peroxide, potassium peroxodisulfate, cyclohexylsulfonyl acetyl peroxide, dibenzoyl peroxide, cyclohexanone peroxide, di-tert-butyl peroxide, dialkyl peroxides, diacyl peroxide
- di (3,5,5-trimethylhexanoyl) peroxide didecanoyl peroxide, dilauroyl peroxide, dibenzoyl peroxide, di (2-ethylhexyl) peroxydicarbonate, dicyclohexyl peroxydicarbonate, di (4-tert-butylcyclohexyl) peroxydicarbonate, dimyristyl peroxydicarbonate, diacetyl peroxydicarbonate, di-tert-butyl peroxy oxalate and peroxycarboxylic acid esters from the reaction products between pivalic acid, neodecanoic acid or 2-ethylhexanoic acid and tert-butyl hydroperoxide, tert-amyl hydroperoxide, cumyl hydroperoxide, 2,5-dimethyl-2,5-dihydroperoxy-hexane, 1,3-di (2-hydroxyperoxy
- the initiators according to the invention can be used in the preparation with other initiators. These may be, for example, photoinitiators known to the person skilled in the art.
- Suitable preferred photoinitiators are, for example, benzophenone, acetophenone, acetonaphthoquinone, methyl ethyl ketone, valerophenone, hexanophenone, ⁇ -phenylbutyrophenone, p-morpholinopropiophenone, dibenzosuberone, 4-morpholinobenzophenone, A-morpholinodeoxybenzoin, p-diacetylbenzene, 4-aminobenzophenone, 4'-methoxyacetophenone, Methylanthraquinone, tert-butylanthraquinone, anthraquinonecarboxylic acid esters, benzaldehyde, ⁇ -tetralone, 9-acetylphenanthrene, 2-acetylphenanthrene, 10-thioxanthenone, 3-acetylphenanthrene, 3-acetylindole, 9-fluoren
- thermal post-curing accelerator it is preferable to use e.g. Zinnoctoat, zinc octoate, dibutyltin laureate or Diaza [2.2.2] bicyclooctane be used in the inventive preparations.
- the preparation according to the invention is preferably a resin system selected from the group of epoxy resin systems, benzoxazine systems, polyurethane systems, acrylate resin systems, epoxyacrylate resin systems, cyanoacrylate resin systems, triazine resin systems, polyimide resin systems, ester acrylate resin systems or thermoplastic resin systems.
- the preparation is preferably an epoxy resin system.
- a mixture of said resin systems may also be a mixture of said resin systems.
- a mixture of an epoxy resin system and a benzoxazine system and / or polyurethane system and / or acrylate resin system and / or an epoxy acrylate resin system is preferably present.
- Particularly preferred is the combination of an epoxy resin system and an acrylate resin system.
- an "epoxy resin system” is understood as meaning a resin composition which is formed on the basis of epoxide compounds or epoxide-containing compounds.
- Such epoxide compounds or epoxide-containing compounds can comprise both oligomeric and monomeric epoxide compounds, as well as epoxides of the polymeric type and can be aliphatic, cycloaliphatic, aromatic or heterocyclic compounds.
- the epoxy compounds or epoxide-containing compounds of the epoxy resin system generally have on average at least one polymerizable epoxide group per molecule, preferably at least about 1.5 polymerizable epoxide groups per molecule.
- the polymeric epoxies include linear polymers having terminal epoxide groups (eg, a diglycidyl ether of a polyoxyalkylene glycol), polymers having oxirane units in the molecular skeleton (eg, polybutadiene polyepoxide), and polymers having pendant epoxy groups (eg, a glycidyl methacrylate polymer or copolymer).
- These epoxies may be pure compounds or mixtures containing one, two or more epoxide groups per molecule.
- the "average" number of epoxide groups per molecule is determined by dividing the total number of epoxide groups in the epoxide-containing material by the total number of epoxide molecules present.
- the molecular weight of the epoxy compounds or epoxide-containing compounds of the epoxy resin system varies from 100 g / mol up to a maximum of 10,000 g / mol for polymeric epoxy resins.
- the epoxide compounds or epoxide-containing compounds are likewise no limits.
- the backbone may be of any type and the substituent groups thereon may represent all groups that do not substantially interfere with cure.
- the substituent groups include halogens, ester groups, ethers, sulfonate groups, siloxane groups, nitro groups, phosphate groups, and the like.
- Suitable epoxy resin systems in the context of the present invention are, for example, preferably selected from bisphenol A type epoxy resins, bisphenol S type epoxy resins, bisphenol F type epoxy resins, phenol novolak type epoxy resins, cresol novolak epoxy resins.
- Type, epoxidized products of numerous dicyclopentadiene-modified phenolic resins obtainable by reaction of dicyclopentadiene with numerous phenols, epoxidized products of 2,2 ', 6,6'-tetramethylbiphenol, aromatic epoxy resins such as naphthalene-based epoxy resins and fluorene-based epoxy resins, aliphatic Epoxy resins such as neopentyl glycol diglycidyl ether and 1,6-hexanediol diglycidyl ether, alicyclic epoxy resins such as 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate and bis (3,4-epoxycyclohexyl) adipate, and epoxy resins having a hetero ring such as triglycidyl isocyanurate.
- aromatic epoxy resins such as naphthalene-based epoxy resins and fluorene-based epoxy resin
- the epoxy resins include, for example, the reaction product of bisphenol A and epichlorohydrin, the reaction product of phenol and formaldehyde (novolak resins) and epichlorohydrin, glycidyl esters, and the reaction product of epichlorohydrin and p-aminophenol.
- epoxy resins that are commercially available include, in particular, octadecylene oxide, epichlorohydrin, styrene oxide, vinylcyclohexene oxide, glycidol, glycidyl methacrylate, diglycidyl ethers of bisphenol A (eg, those sold under the trade designations "Epon 828”, “Epon 825”, “Epon 1004" and “Epon 1010" from Hexion Specialty Chemicals Inc., "DER-331”, “DER-332”, “DER-334”, “DER-732", and “DER736” from the Dow
- reactive resins and terpene phenolic resins such as. B. NIREZ TM 2019 of
- reactive resins and phenolic resins such as YP 50 from Toto Kasei, PKHC from Dow Chemical Co. and BKR 2620 from Showa Union Gosei Corp. deploy.
- reactive resins and polyisocyanates such as. For example, use Coronate TM L from Nippon Polyurethane Ind., Desmodur TM N3300, or Mondur TM 489 from Bayer.
- epoxy resins may preferably include copolymers of acrylic acid esters with glycidol, e.g.
- epoxy resins are well known and include epoxides such as e.g.
- epichlorohydrin Alkylene oxides, e.g. Propylene oxide, styrene oxide; Alkenyloxides, e.g. butadiene oxide;
- Glycidyl esters e.g. Ethylglycidat.
- Cyclohexylepoxid groups especially those with a silicone backbone. Examples are UV
- the preparations according to the invention comprise a mixture of a plurality of said epoxy resin systems.
- Examples of such mixtures may be two or more molecular weight distributions of epoxide containing compounds, such as e.g. a low molecular weight (below 200), an average molecular weight (about 200 to 10,000), and a higher molecular weight (above about 10,000).
- the epoxy resin may contain a mixture of epoxy-containing materials of different chemical nature (e.g., aliphatic or aromatic) or functionality (e.g., polar or nonpolar).
- a "polyurethane resin system” is understood as meaning a resin composition which is formed on the basis of polyurethanes.
- a "benzoxazine resin system” is understood to mean a resin composition which is formed on the basis of benzoxazines.
- an "acrylate resin system, cyanoacrylate resin system, triazine resin system, polyimide resin system, ester acrylate resin system” is understood to mean a resin composition which is formed on the basis of acrylates, cyanoacrylates, triazines, polyimides and / or ester acrylates.
- Another object of the present invention are preparations containing
- thermoplastic 0% to 50% by weight
- compositions according to the invention which comprise at least one initiator according to the invention are curable thermally and / or non-thermally.
- the preparation according to the invention is an epoxy resin system which is non-thermally curable.
- thermo is to be understood as meaning a hardening initiated by external heat supply, wherein non-thermal initiation brought about by targeted and actively supplied non-thermal energy is not included.
- This heat supply can be carried out for example by means of a convection oven or equipped with infrared radiators as a heat source or microwave radiators oven.
- the curing using thermal heat is preferably carried out at 20 to 35O 0 C, preferably at 50 to 25O 0 C for 10 seconds to 24 hours, preferably 30 minutes to 12 hours.
- non-thermal is understood as radiation-initiated curing, wherein thermal initiation brought about by targeted and actively supplied thermal energy is not included (Polymerization) lead or contribute (so-called post-curing).
- the curing of the formulations or resin systems or mixtures of the resin systems according to the invention preferably takes place by blasting with at least one wavelength of 1 mm, preferably at least 780 nm, preferably at least 1 nm, very particularly preferably at least 10 ⁇ m.
- the preparations according to the invention are preferably curable by radiation selected from x-ray, gamma, electron, UV and / or microwave radiation.
- a source of UV rays a mercury lamp, a halogen lamp, but also monochromatic radiation in the form of lasers can be used.
- UV crosslinking preferably takes place by means of short-term ultraviolet irradiation in a wavelength range of 200 to 450 nm, in particular using mercury high pressure or medium pressure lamps at a power of 80 to 240 W / cm.
- thermoelectrons produced by commercially available tungsten filament, a cold cathode method, which electron beams by passing a high Voltage pulse generated by a metal, and a secondary electron method, the secondary electrons, which are generated by the collision of ionized gas molecules, and a metal electrode uses are used.
- a source of ⁇ -rays ⁇ -rays and V-rays
- fissile substances such as Co 60 can be used.
- ⁇ -rays a vacuum tube that causes the collision of an accelerated electron with an anode can be used.
- the radiation can be used either singly or in combination of two or more types of radiation. In the latter case, two or more types of radiation may be used either simultaneously or at certain time intervals.
- the curing using radiation is preferably at 20 to 25O 0 C, preferably at 80 to 100 0 C in a period of 5 seconds to 12 hours, preferably 8 seconds to 4 hours, most preferably 10 seconds to 1 Hour, performed.
- the radiation used for curing the preparations according to the invention or one of the abovementioned resin systems is an ionizing radiation, preferably X-ray and / or electron radiation.
- Preparations or resin systems by cationic polymerization wherein the polymerization is preferably initiated by the action of electron beams.
- the curing or polymerization by means of electron beams has the advantage that the rays, in
- the material to be cured penetrate almost completely and so a homogeneous and complete curing can be better achieved.
- Another object of the present invention relates to epoxy resin systems containing at least one initiator of the invention.
- Such an epoxy resin system is preferably curable thermally and / or non-thermally, wherein the radiation used for curing the epoxy resin system is preferably selected from X-rays, gamma rays, electron beams, UV rays and / or
- a curable preparation preferably selected from an epoxy resin system containing at least one initiator of the invention at 3 eV to 25 MeV, in particular at
- the epoxy resin system is provided with a freely selectable
- the system is curable in 4 steps of about 33 kGy.
- a combination of thermal and / or non-thermal curing can also be carried out.
- a thermal hardening step can be carried out and thereafter a non-thermal or conversely first a non-thermal, then a thermal hardening step.
- the hardening can also take place under protective gas.
- any gas which is inert with respect to the chemicals used is suitable as protective gas.
- gases such as N 2 , CO 2 or Ar come into question.
- inexpensive gases such as CO 2 and N 2 .
- CO 2 has the advantage that it collects at the bottom of vessels and thus is easy to handle.
- Suitable shielding gases are, in particular, non-toxic and nonflammable.
- Another object of the present invention relates to the use of the initiators of the invention in said preparations or epoxy resin systems as adhesives, composite materials, sealants, materials and for the coating of surfaces.
- such a preparation according to the invention can be applied as a coating composition to a surface and then cured.
- Particularly preferred substrates are wood, paper, textile, leather, fleece, plastics (polycarbonate, polymethacrylate, polystyrene, polyester, polyolefin, epoxy resins, melamine resins, triacetylcellulose resins, ABS resins, AS resins, norbornene resins, etc.), glass, ceramics, Paper, mineral building materials, such as cement blocks and fiber cement boards, metals or coated metals suitable.
- the substrate may also be a plate, a film or a three-dimensionally shaped body.
- composition in this case as a coating composition
- various application methods can be used, such as spraying, flow coating, knife coating, brushing, pouring, dipping, soaking, trickling, rolling, shatter coating or dip coating.
- the substrate to be coated can rest as such, wherein the application device or -anläge is moved.
- the initiators according to the invention are used for the curing of materials, in particular shaped bodies.
- materials moldings which are produced using the initiators according to the invention preferably have a high mechanical stability and resistance.
- Another object of the present invention is the use of the initiators according to the invention in curable systems for a thermal (initiated) and / or non-thermal (initiated) curing, wherein a non-thermal (initiated) curing is preferred.
- Such curable systems are preferably resin systems, for example epoxy resin systems, benzoxazine systems, polyurethane systems, acrylate resin systems, epoxyacrylate resin systems, cyanoacrylate resin systems, triazine resin systems, polyimide resin systems, ester acrylate resin systems or thermoplastic resin systems or other resin systems known to those skilled in the art.
- resin systems for example epoxy resin systems, benzoxazine systems, polyurethane systems, acrylate resin systems, epoxyacrylate resin systems, cyanoacrylate resin systems, triazine resin systems, polyimide resin systems, ester acrylate resin systems or thermoplastic resin systems or other resin systems known to those skilled in the art.
- epoxy resin systems for example epoxy resin systems, benzoxazine systems, polyurethane systems, acrylate resin systems, epoxyacrylate resin systems, cyanoacrylate resin systems, triazine resin systems, polyimide resin systems, ester acrylate resin systems or thermoplastic resin systems or other resin systems known to those skilled in the art.
- the use of the initiators of the invention in curable systems that are non-thermally curable are preferably curable with high-energy radiation, such as electron radiation.
- the initiators according to the invention are generally readily soluble in the epoxy resin system. After curing, it also shows a high degree of crosslinking.
- Another object of the present invention relates to a
- a method of curing a composition comprising the steps of:
- the heat supply can be effected for example thermally or non-thermally, preferably the heat supply is non-thermal.
- Another object of the present invention relates to a
- a method of curing a composition comprising the steps of:
- the epoxy resin of said epoxy resin system is particularly preferably selected from the group consisting of: glycidyl ether of bisphenol A, epoxy novolaks, epoxy cresol novolaks, epoxy compounds with bisphenol F, tetraglycidyl ether of tetrakis (4-hydroxyphenyl) ethane, diglycidyl ether of 9, 9-bis (4-hydroxyphenyl) fluorene, glycidyl ether of the condensation product of dicyclopentadiene and phenol, triglycidyl ether of tris (hydroxyphenyl) methane, 3 ', 4'-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, diglycidyl ester of hexahydrophthalic acid, bis (3,4- epoxycyclohexylmethyl) adipate, high molecular weight Diglycidyl ether of bisphenol A or bisphenol F condensed with bisphenol
- the present invention also relates to the cured product prepared by curing the composition of the invention or the epoxy resin system of the present invention.
- the cured product may preferably be non-thermally and / or thermally cured, and is preferably obtainable by any of the curing methods described above.
- the curing was carried out according to one of the aforementioned curing methods, in which a preparation of the invention or an epoxy resin system according to the invention is provided and then curing of said preparation or said epoxy resin system by heat, in particular by irradiation, which is sufficient to the said preparation or the said Cure epoxy resin system.
- the cured product is preferably a coating, a film, a material, a composite material, an adhesive or a sealant.
- the starting material for the silver-alkene complexes was the commercially available AgSbF 6 (Aldrich, 98% or Chempur, 95 +%).
- the complexes were synthesized by methods known from the literature (HW Qinn, RL Van Gilder, Can J. Chem., 1970, 48, 2435, A. Albinati, SV MeNIE, G. Carturan, J. Organomet. Chem., 1979, 182 , 269, H. Masuda, M. Munakata, S. Kitagawa, J. Organomet Chem 1990, 391, 131, AJ Canty, R. Colton, Inorg, Chim Ada 1994, 220, 99).
- the respective metal chloride was first reacted with AgSbF 6 in a suitable solvent such as methanol, the precipitated AgCl was separated by filtration and the resulting solution of the metal hexafluoroantimonate was reacted with the respective ligand. Thereafter, the solvent was removed and the compound was dried under high vacuum.
- a suitable solvent such as methanol
- the degree of crosslinking of the (epoxy) resin was determined by FT-IR from the decrease in the area below the epoxide band (915 cm -1 ) .
- the decrease in the epoxide band correlates with the degree of crosslinking Epoxide groups in the material and thus also the area under the epoxide band determined by means of FT-IR
- the reference band used was the benzene ring band (1505 cm -1 ).
- A1 area under the epoxy band (915 cm “1 ) - hardened
- A2 Area under the reference band, benzene ring band (1505 cm -1 ) -hardened
- A4 area under the reference band, benzene ring band (1505 cm “1 ) -ughened
- the static fracture toughness of the pure resin systems was determined under Mode I load according to ISO 13586.
- To carry out the fracture mechanical tests was a universal testing machine (UPM) from Zwick (type Z020).
- the specimens used were CT specimens with a sample width W of 33 mm.
- the test speed was 10 mm / min. All measurements were carried out at 23 0 C and 50% humidity.
- Example 4 Thermal Curing and Electron Beam Curing (EB) of a Resin Composition Containing an Initiator of the Invention
- the resin formulation is first at max. Degassed 8O 0 C in a vacuum drying oven, poured into molds (about 20cm x 20cm x 4mm) and the surface smoothed by means of a wooden stick. It is important to ensure complete freedom from bubbles.
- the specimens are then driven through the electron beam system (10 MeV), the cure being carried out in four steps, each introducing a dose of 33 kGy (a total of 132 kGy).
- the 8O 0 C hot resin mixture is poured into likewise heated to 8O 0 C aluminum molds, then the surface by means of
- Table 1 shows that the silver salt according to the invention in the resin initiates a cationic polymerization both by electron radiation and by thermal energy and a high degree of crosslinking is achieved.
- the resins after curing have high moduli of elasticity and fracture toughness.
- Example 5 UV curing of a resin composition containing an initiator according to the invention
- a DGEBA resin (DER 331 P from DOW Chemicals Co.) was mixed with 1 wt% ⁇ [Ag (1, 7-octadiene) - ⁇ 5] SbF 6 ⁇ "and with max. Homogenize 8O 0 C with stirring.
- the resulting composition was at about 3O 0 C in about 1 mm layer thickness on aluminum plates (AI2024 sheets), which were previously cleaned with acetone, geräkelt and then by means of UV radiation (H emitters of the Fusion system / 100% power / Distance 30 cm) hardened.
- the silver salt according to the invention is likewise UV-active and initiates a cationic polymerization of epoxy resins.
- the silver salts also lead to high degrees of crosslinking on the surface of the resin formulations by means of UV irradiation.
- the degree of crosslinking of the surface increases with the irradiation time.
- the glass transition temperatures (Tg) of the formulations also increase with irradiation time.
- the degrees of crosslinking at the bottom of the samples are lower compared to the surface data, which were determined at the side facing the radiation source, which can be explained by the low penetration depth of the radiation (caused by low irradiation energy) generally during UV curing.
- Resin type 1 P novolac DEN431 from Dow (EEW: 176 ⁇ 3, viscosity 1400 ⁇ 300 mPa ⁇ s, 52 0 C)
- Resin type 2 novolac DEN438 from Dow (EEW: 179 ⁇ 3, viscosity 35500 ⁇ 3100 mPa-s, 52 0 C)
- Example 7 Storage stability
- the storage stability was determined by measuring the relative viscosity by means of a pot-timer at 80 0 C.
- Rhodorsil 2074 [Ag (1 7-octadiene) - ⁇ 5 ] SbF ⁇
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
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DE102006057142A DE102006057142A1 (de) | 2006-12-01 | 2006-12-01 | Metallverbindungen als Initiatoren |
PCT/EP2007/061158 WO2008064959A2 (de) | 2006-12-01 | 2007-10-18 | Metallverbindungen als initiatoren |
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EP07821523A Withdrawn EP2091954A2 (de) | 2006-12-01 | 2007-10-18 | Metallverbindungen als initiatoren |
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US (1) | US8426483B2 (de) |
EP (2) | EP2537873A1 (de) |
JP (1) | JP2010511083A (de) |
CN (1) | CN101578288A (de) |
BR (1) | BRPI0718930A2 (de) |
CA (1) | CA2671073A1 (de) |
DE (1) | DE102006057142A1 (de) |
WO (1) | WO2008064959A2 (de) |
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DE102007041988A1 (de) * | 2007-09-05 | 2009-03-12 | Forschungszentrum Karlsruhe Gmbh | Flammhemmende Additive |
US8399099B1 (en) | 2008-05-23 | 2013-03-19 | Henkel Ireland Limited | Coating compositions |
US20090288771A1 (en) * | 2008-05-23 | 2009-11-26 | Loctite (R&D) Limited | Surface-promoted cure of one-part radically curable compositions |
DE102008031555A1 (de) * | 2008-07-07 | 2010-01-14 | Henkel Ag & Co. Kgaa | Polymerisierbare Zusammensetzung enthaltend anorganische Partikel mit organischer Hülle |
CN102119184A (zh) * | 2008-08-12 | 2011-07-06 | 亨斯迈先进材料(瑞士)有限公司 | 热固性组合物 |
CA2752717A1 (en) | 2009-02-17 | 2010-08-26 | Henkel Ag & Co. Kgaa | Metal-to-polymer bonding using an adhesive based on epoxides |
WO2010094634A1 (en) | 2009-02-17 | 2010-08-26 | Loctite (R & D) Limited | Cationically curable compositions and a primer therefor |
DE102009001855A1 (de) * | 2009-03-25 | 2010-09-30 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung eines faserhaltigen Verbundwerkstoffs |
JP5907027B2 (ja) * | 2012-09-26 | 2016-04-20 | ニプロ株式会社 | カテーテル |
KR102171397B1 (ko) | 2013-12-30 | 2020-10-29 | 엘지디스플레이 주식회사 | 터치장치의 제조방법 및 그 수지 조성물 |
WO2016014287A1 (en) * | 2014-07-21 | 2016-01-28 | Elevance Renewable Sciences, Inc. | Conjugated diene acids and derivatives thereof |
PL3093305T3 (pl) * | 2015-05-12 | 2018-01-31 | Refractory Intellectual Property Gmbh & Co Kg | Zestaw do wytwarzania surowej kształtki do wytwarzania wiązanego poprzez węgiel wyrobu ogniotrwałego, sposób wytwarzania takiej surowej kształtki jak również surowa kształtka wytworzona tym sposobem |
CN107651722A (zh) * | 2016-07-24 | 2018-02-02 | 天津师范大学 | 基于3‑(5‑甲基‑1,3,4‑噁二唑)吡啶的三氟甲磺酸‑Ag(I)配合物在吸附染料中的应用 |
CN110511353A (zh) * | 2019-08-07 | 2019-11-29 | 周小三 | 一种可交联的tpu组合物及其制备方法 |
CN117229697A (zh) * | 2023-10-25 | 2023-12-15 | 江苏泰特尔新材料科技股份有限公司 | 一种无溶剂金属包装涂料组合物及其制备方法 |
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US3824220A (en) * | 1963-06-24 | 1974-07-16 | Minnesota Mining & Mfg | Polycationically active polymers |
NO134211C (de) | 1974-05-28 | 1976-09-01 | Dale Johannes | |
EP0148274B1 (de) | 1983-06-07 | 1989-01-11 | Nippon Kokan Kabushiki Kaisha | Zusammensetzung zur verwendung bei der metallbearbeitung |
EP0153904B1 (de) * | 1984-02-10 | 1988-09-14 | Ciba-Geigy Ag | Verfahren zur Herstellung einer Schutzschicht oder einer Reliefabbildung |
EP0182744B1 (de) * | 1984-11-14 | 1992-08-12 | Ciba-Geigy Ag | Photohärtbare gefüllte Expoxidharz-Zusammensetzungen und deren Verwendung |
US5130406A (en) * | 1989-03-21 | 1992-07-14 | Ciba-Geigy Corporation | Initiators for materials which can be polymerized cationically |
EP0526463B1 (de) * | 1990-04-23 | 1996-05-22 | Minnesota Mining And Manufacturing Company | Energiehärtbare, kationisch oder radikalisch polymerisierbare druckempfindliche zusammensetzungen |
DE59209346D1 (de) * | 1991-10-28 | 1998-07-02 | Ciba Geigy Ag | Lösungsmittelfreie härtbare Harzzusammensetzung, insbesondere für die Herstellung von Prepregs |
US5514728A (en) * | 1993-07-23 | 1996-05-07 | Minnesota Mining And Manufacturing Company | Catalysts and initiators for polymerization |
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EP0920482A1 (de) * | 1996-08-26 | 1999-06-09 | Minnesota Mining And Manufacturing Company | Halb-unterpenetrierende polymernetzweke aus epoxy-und fluorpolymeren |
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2006
- 2006-12-01 DE DE102006057142A patent/DE102006057142A1/de not_active Withdrawn
-
2007
- 2007-10-18 EP EP12185359A patent/EP2537873A1/de not_active Withdrawn
- 2007-10-18 CN CNA2007800442768A patent/CN101578288A/zh active Pending
- 2007-10-18 CA CA002671073A patent/CA2671073A1/en not_active Abandoned
- 2007-10-18 US US12/515,763 patent/US8426483B2/en not_active Expired - Fee Related
- 2007-10-18 BR BRPI0718930-3A patent/BRPI0718930A2/pt not_active IP Right Cessation
- 2007-10-18 EP EP07821523A patent/EP2091954A2/de not_active Withdrawn
- 2007-10-18 WO PCT/EP2007/061158 patent/WO2008064959A2/de active Application Filing
- 2007-10-18 JP JP2009538662A patent/JP2010511083A/ja active Pending
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US20100113639A1 (en) | 2010-05-06 |
BRPI0718930A2 (pt) | 2013-12-03 |
CN101578288A (zh) | 2009-11-11 |
DE102006057142A1 (de) | 2008-06-05 |
WO2008064959B1 (de) | 2008-12-11 |
US8426483B2 (en) | 2013-04-23 |
JP2010511083A (ja) | 2010-04-08 |
WO2008064959A2 (de) | 2008-06-05 |
CA2671073A1 (en) | 2008-06-05 |
WO2008064959A3 (de) | 2008-10-16 |
EP2537873A1 (de) | 2012-12-26 |
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