EP1986600A2 - Creme de coloration capillaire a base de polymeres - Google Patents

Creme de coloration capillaire a base de polymeres

Info

Publication number
EP1986600A2
EP1986600A2 EP07722776A EP07722776A EP1986600A2 EP 1986600 A2 EP1986600 A2 EP 1986600A2 EP 07722776 A EP07722776 A EP 07722776A EP 07722776 A EP07722776 A EP 07722776A EP 1986600 A2 EP1986600 A2 EP 1986600A2
Authority
EP
European Patent Office
Prior art keywords
hair
amino
cream according
acid
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP07722776A
Other languages
German (de)
English (en)
Inventor
Matthias Hloucha
Martina Seiler
Thomas Döring
Gert-Lothar Striepling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to EP10171543A priority Critical patent/EP2332615A1/fr
Publication of EP1986600A2 publication Critical patent/EP1986600A2/fr
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/33—Free of surfactant

Definitions

  • the present invention relates to hair colorants creams with amphiphilic polymers and low emulsifier content and their use for dyeing hair
  • Hair coloration creams usually contain large amounts of short-chain emulsifiers. As a result, these agents irritate the skin and have poor sensory properties
  • the object of the present invention was therefore to provide hair colorants creams which have good compatibility with the skin, lead to reduced skin irritation and have good sensory properties
  • EP1023891 discloses water-free compositions for bleaching keratin fibers which comprise, in a medium suitable for bleaching, at least one base, at least one peroxide salt, at least one anionic and / or nonionic amphiphilic polymer which has at least one fatty chain, and at least one cationic and / or containing amphoteric substantive polymer
  • EP1031343 discloses an aqueous composition for bleaching keratin fibers comprising, in a medium suitable for bleaching, at least one base, at least one peroxide salt, hydrogen peroxide, at least one water-soluble solvent and at least one nonionic and / or anionic amphiphilic polymer having at least one fatty chain; contains
  • EP11142555 discloses a composition for the oxidative dyeing of keratinic fibers which contains in a suitable medium for colorants at least one oxidation colorant, at least one thickening polymer having at least one fatty chain, and at least one fatty alcohol having at least 20 C atoms
  • EP11142556 discloses a composition for the oxidative dyeing of keratinic fibers which contains in a dyeing medium at least one oxidation dyeing agent, at least one thickening polymer having at least one fatty chain, and at least one mono- or polyglycene-modified fatty alcohol
  • EP0861065 discloses a composition for the oxidative dyeing of keratinic fibers which contains in a suitable medium at least one dye precursor of an oxidation dye, optionally one or more couplers and at least one amphiphilic nonionic polymer having at least one fatty chain and at least one hydrophilic group
  • amphiphilic polymers in hair coloration creams, a particular color brilliance or especially strong and / or particularly luminous colors on the hair could be achieved
  • the present invention therefore provides hair colorants creams for coloring keratin-containing fibers, in particular human hair, containing at least one coloring component and additionally at least one amphiphilic polymer and emulsifiers in an amount of less than 10% by weight.
  • hair coloration creams are to be understood as meaning emulsions and dispersions which, because of their ingredients, are suitable for coloring keratinic fibers.
  • the emulsion may be both an O / W emulsion and a W / O emulsion, where O
  • the dispersion is preferably a dispersion of fatty alcohols in an aqueous phase
  • the hair colorants according to the invention and in particular the G7W emulsions according to the invention, preferably have a high viscosity at low shear rate and a low viscosity at high shear rate, so that the consumer is provided with a rich product which can be distributed well at the same time is in this case a viscosity of 200-15000 Pa s, in particular of 500-10,000 Pa s, at a shear rate of 0.1 Hz (25 0 C, 1 bar) and from 0.1-10 Pa s, particularly preferably from 0, 5 - 2.0 Pa s, at a shear rate of 100 Hz (25 ° C, 1 bar) (determined by the following methods Rmg-Tensio-Meter (Fa Lauda) and drop-shape analysis (Fa Kruss))
  • emulsifiers are generally conventionally used short-chain surfactants, emulsifiers and coemulsifiers with the exception of silicone-containing surfactants and emulsifiers.
  • Short-chain surfactants, emulsifiers and coemulsifiers are understood as meaning, in particular, non-silicone-containing surfactants, emulsifiers and coemulsifiers having a molecular weight less than or equal to 1000 g / mol, in particular less than or equal to 3000 g / mol, preferably less than or equal to 5000 g / mol
  • compositions according to the invention are present in an amount of less than 10% by weight, more preferably less than 9, 8, 7 or 6% by weight, especially in an amount of less than 5, 4, 3 or 2% by weight. and in particular in an amount of less than 1, 0.5, 0.2 or 0.1% by weight
  • the composition contains no emulsifiers having a molecular weight of less than or equal to 5000 g / mol and is to be regarded as emulsifier-free according to the definition of the Deutschen für Dermopharmazie
  • composition according to the invention show a better behavior with regard to the problems skin irritation (skin irritation), skin redness or dry skin than the preparations conventionally used and that preferably these problems can be completely avoided
  • compositions according to the invention are high stability of the compositions against phase separation in different storage conditions, a good skin feel, which is due in particular to the good spreadability, the good sliding behavior, lack of stickiness, the absence of residues and the good pull-in behavior, as well as good application properties such lack of whitening effect (when triturated, there is no transient whitening due to foaming)
  • the preparation may optionally take place in the cold-cold process, which on the one hand represents a very energy-saving and thus cost-effective and environmentally friendly method of production and further allows the incorporation and stabilization of heat-sensitive active ingredients
  • the hair colorant cream is an agent which contains at least one fatty alcohol in addition to the amphiphilic polymer, water, surfactant and coloring components.
  • This embodiment preferably contains conventional surfactant in an amount of up to 8% by weight. in particular in an amount of 2-8% by weight.
  • the fatty alcohol is preferably present in an amount of up to 30% by weight, more preferably in an amount of 5-20% by weight
  • the hair coloration cream is an O / W emulsion which, in addition to the amphiphilic polymer, water and coloring components, contains at least one oil component and at least one thickener.
  • conventional surfactants are preferably present in an amount of less than 5% by weight, more preferably less than 3% by weight, especially less than 1% by weight, in this embodiment, the oil component is preferably present in an amount of up to 30% by weight, more preferably in an amount of 1 -20% by weight, contained
  • amphiphilic polymer according to the invention is preferably a hydrophobically modified polysaccharide or a hydrophilically modified silicone
  • the basic skeleton of the hydrophobically modified polysaccharide is preferably a water-soluble polysaccharide and / or its ether with short-chain alcohols.
  • the water-soluble polysaccharide can have any desired structure. For example, it can be linear, branched, comb-like and / or star-shaped, but with linear polysaccharides are preferred
  • the basic skeleton of the hydrophobically modified polysaccharide can also be a copolymer or a block copolymer of different monosaccharide units and / or monosaccharide units linked together in different ways
  • Polysaccharide basic skeletons which can be used according to the invention are selected, for example, from the group consisting of polyglucose, in particular cellulose, amylose, amylopectin or dextrins, and polyfructose and hydroxyalkyl-modified derivatives of these compounds
  • Particularly preferred polysaccharide basic skeletons according to the invention are hydroxyethylcellulose and linear polyfructose, in particular inuhn
  • the polysaccharide in particular the Inuhn, in a preferred embodiment comprises on average from 3 to 100, more preferably from 5 to 75, especially from 10 to 40, Monosacchand units
  • the hydrophobic modification is preferably achieved by C 3 . 22- Alkyl groups, in particular by C ⁇ - 20- alkyl groups, particularly preferably by C 10 -i 6 -alkyl groups
  • the alkyl groups can be linear or branched, saturated or unsaturated, but are preferably linear and unsaturated
  • the hydrophobic groups are preferably via an alkyl Etherbmdung or via an alkyl
  • the hydrophobic groups can also be attached via a linker to the Polysaccha ⁇ d basic skeleton be bound, for example via a polyether linker, in particular a Polyethylenglykol- Lmker
  • the degree of modification of the hydrophobically modified polysaccharide ie the quotient of the number of modifying groups and the number of monomer units, is preferably from 0.1 to 2.0, particularly preferably from 0.2 to 1.0, in particular 0.4 to 0.8
  • hydrophobic groups as well as regardless of the Polysaccha ⁇ d-backbone may also optionally be mono- or polysubstituted, in particular by radicals selected from halogen, insbsondere fluorine, chlorine or bromine, hydroxy, alkoxy, in particular C 1 ⁇ -alkoxy, amino, Alkylammo, in particular d- 6 -Alkylam ⁇ no, aryl, especially C 6 .io aryl, arylalkyl, in particular C ⁇ -io-aryl-Cv ⁇ -alkyl, carboxy, carboxy ester, in particular carboxy-C ⁇ -alkyl, and cycloaliphatic radicals
  • Hydrophobically modified polysaccharides used according to the invention are surface-active and significantly reduce the interfacial tension of water to air and water to oil.
  • Hydrophobically modified polysaccharides which are preferably used according to the invention are disclosed in EP 964054 A1 and in Biomacromolecules (2001, Volume 2, S 1256-1259).
  • Hydrophobically modified polysaccharides which are particularly preferably used according to the invention are Polysaccha ⁇ d-N-alkylurethanes from Orafti, in particular lauryl carbamate (Inutec SP-1, Fa Orafti), and hydrophobically modified hydroxyethyl cellulose from Hercules, in particular cetyl hydroxyethyl cellulose (Natrosol Plus CS 330, Polysurf , Fa Hercules)
  • hydrophilic-modified silicones or Sihkon-based nonionic emulsifiers are understood as meaning polyorganosiloxanes having hydrophilic substituents which increase the water-permeability or interfacial activity of the silicones.
  • the hydrophilically modified silicones reduce the stickiness and leave a fresh feeling on the skin.
  • hydrophilic-modified silicones those which are at least preferred in an amount of 0.5 wt - loose% at 20 0 C in water
  • hydrophilic substituents include hydroxy, hydroxyalkyl, polyalkylene glycol side chains, in particular polyethylene glycol or polyethylene glycol / polypropylene glycol side chains, and ethoxylated esters side chains
  • the hydrophilic substituent may in this case be selected from hydroxyalkyl groups, from polyether groups, in particular polyethylene glycol and polypropylene glycol groups, as well as polyethylene glycol / polypropylene glycol mixed or block copolymer groups, and alkyl polyether groups
  • the polysiloxane can also carry various hydrophilic substituents, in particular of the abovementioned types.
  • the hydrophilic substituent can in this case have an alkyl group, in particular a C 1-6 -alkyl group, especially via an ethylene or propylene group Be bound S ⁇ -atom
  • polyether group is preferably a polyoxyethylene (CI_ 4) alkylene group, wherein the polyoxy (C 1-4) alkylene is preferably selected from polyoxyethylene, polyoxypropylene and copolymers thereof, wherein the However, block copolymers may be preferred.
  • the number of oxyalkylene units is preferably from 4 to 100. Particular preference is given to embodiments with 4 to 50 oxyethylene units and / or with 4 to 50 oxypropylene units, especially with 4 to 50 oxyethylene units, followed by 4 to 20 oxypropylene units join
  • the terminal hydroxy group of the polyoxyalkylenes pointing the way from the polysiloxane backbone is free.
  • it may be an ether bond to an alkanol, in particular to a d 1 -alkanol, preferably a d 6 -alkanol or a C 16 . 20 alkanol, particularly preferably methanol or ethanol, form
  • ⁇ - carboxylic acid preferably to a C 12-20 carboxylic acid, more preferably to acetic acid, propanoic acid, butanoic acid, oleic acid, linoleic acid, linolenic acid, palmitic acid or palmitoleic acid
  • the terminal S ⁇ atoms of the polysiloxanes may also optionally carry previously mentioned hydrophilic substituents bound in the aforementioned manner.
  • only the terminal S ⁇ atoms of the polysiloxane backbone carry hydrophilic substituents, so that a block-like arrangement of hydrophilic substituents and polysiloxane
  • the hydrophilic substituents are not located at the terminal S ⁇ atoms of the polysiloxane backbone, but only at the S ⁇ atoms in the interior of the polysiloxane backbone such that there is a grafted array of hydrophilic substituents and polysiloxane backbone
  • the invention relates to polymeric molecules comprising units of the formula -S ⁇ (R 1 ) (R 2 ) (O) - and units of the formula -S ⁇ (R 3 ) ([X] m - [Y] n- [B ] 0 - [Z] pH) (O) -, where
  • R 1 , R 2 and R 3 independently of one another are C 1-12 -alkyl, in particular C 1. 6- alkyl, particularly preferably methyl,
  • X is d-e-alkylene, in particular ethylene or propylene,
  • Y is (C 1 -C 4 ) -oxyalkylene, in particular oxyethylene and / or oxypropylene, in which a mixed or block-like arrangement may be present,
  • Z is C 1-24 alkylene, preferably Ci. 2 2 o-alkylene, more preferably C 16 . 18 is alkylene, m is 0 or 1, preferably 1, n is 4 to 100, more preferably 4 to 50, o is 0 or 1, p is 0 or 1
  • All hydrocarbon radicals of the polysiloxanes according to the invention may optionally also be mono- or polysubstituted, in particular by radicals selected from halogen, in particular fluorine, chlorine or bromine, hydroxyl, alkoxy, in particular C 1-6 -alkoxy, amino, alkylamino, especially d- ⁇ - Alkylamino, dialkylammo, especially di-Ci. 6 -alkylamino, aryl, in particular C 6 -io-aryl, arylalkyl, in particular C 6 -io-aryl-C 1-6 -alkyl and cycloahphatic radicals
  • n 5 to 60
  • o and p 0
  • the ratio between alkyleneoxy units and S ⁇ atoms is preferably between 11 and 10.
  • the molecular weight of the hydrophilically modified silicones is preferably between 200 and 10000 g / mol, more preferably between 300 and 5000 g / mol
  • the number of S ⁇ atoms with hydrophilic groups to the total number of S ⁇ atoms, also called modification degree according to the invention, is preferably between 5 and 30%, particularly preferably between 10 and 20%.
  • a 0.2% aqueous solution of the hydrophilic ⁇ ge modifed silicone has a surface tension of not more than 40 mN / m at 25 0 C, particularly preferably less than or equal to 35 mN / m
  • suitable examples are hydrophilically modified silicone copolyols, especially dimethicone copolyols, for example, from Wacker-Chemie under the name Belsil ® DMC 6031 (PEG / PPG-25/25 dimethicone), Belsil ® DMC 6032, Belsil ® DMC 6038 (B ⁇ s PEG-15 methyl ether Dimethicone) or Belsil DMC 3071 ® VP (Cetyl PEG / PPG-15/15 butyl ether Dimethicone), from Dow Corning under the designation DC 193, DC 5324 or DC 5329 Oeweils PEG-12 dimethicone), DC 2501 (BIS-PEG-18 methyl ether dimethyl silane) or DC Q2-5220 (PEG / PPG-17/18 dimethicone), from Degussa / Goldschmidt under the name Abil EM 90 (Cetyl PEG / PPG-10/1 dimethicone), Abil
  • compositions preferred according to the invention are characterized in that they contain at least one hydrophilically modified silicone having an HLB value of greater than 7, particularly preferably having an HLB value of 8-17 and exceptionally preferably having an HLB value of 10 to 15 it is when the total content of hydrophilically modified silicone comprises substances having an HLB value of greater than 7, more preferably having an HLB value of 8-17, and most preferably having an HLB value of 10-15
  • amphiphilic polymer and in particular the hydrophobically modified polysaccharide and / or the hydrophilically modified silicone, is preferably present in the compositions according to the invention in an amount of from 0.01 to 10% by weight, in particular from 0.1 to 3% by weight, based on the weight of the ready-to-use colorant oil component
  • the oil component may in particular be a non-polar or polar liquid oil, which may be natural or synthetic.
  • the oil component may in particular be selected from
  • Tnglyceridole in particular sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojobaol, orange oil, wheat germ oil, peach kernel oil and the liquid parts of coconut oil
  • suitable Tnglyceridole such as the liquid portions of beef tallow and synthetic Tnglyceridole
  • liquid paraffin oils eg isohexadecane and isoeicosane
  • isoparaffinols eg isohexadecane and isoeicosane
  • hydrogenated polyalkenes in particular poly-1-decenes (commercially available as Nexbase 2004, 2006 or 2008 FG (Fortum, Belgium)
  • synthetic hydrocarbons eg B 1, 3 -D ⁇ - (2-ethyl-hexyl) - cyclohexane (Cetiol® S)
  • volatile and non-volatile Sihconolen which cychsch such as decamethylcyclopentasiloxane and Dodecamethylcyclohexasiloxan, or may be linear, for example, linear dimethylpolysiloxane, commercially available z under the designation Dow Corning ® 190, 200, 244, 245, 344, 345 or 350 and Baysilon ® 350 M
  • D ⁇ -n-alkyl ethers having a total of 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as D ⁇ -n-octyl ether (commercially available as Cetiol® OE), D ⁇ -n-decyl ether, D ⁇ -n nonyl ether, di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl -n-undecyl ether and di-tert-butyl ether, D ⁇ - ⁇ so-pentyl ether, D ⁇ -3-ethyldecyl ether, tert-butyl-n-ocy
  • Esterols are understood as meaning esters of C 6 -C 30 -, in particular C 6 -C 22 -fatty acids, with C 2 -C 30 -, in particular C 2 -C 24 -fatty alcohols, examples of fatty acid proportions used in the esters Caprylic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myrolidic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petrose acid, linoleic acid, linolenic acid, elaeo-stearic acid, arachidic acid, gadoleic acid, Behenic acids and erucic acids and their technical mixtures, which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxo synthesis
  • Dicarboxylic acid esters such as di-n-butyl adipate, di (2-ethylhexyl) adipate, di (2-ethylhexyl) succinate and diisotrdecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol diisotecdecanoate, propylene glycol d ⁇ (2-ethylhexanoate), propylene glycol dinostearate, Propylene glycol dipelargonate, butanediol dinearostearate, neopentyl glycol dicaprylate,
  • the polar oil component can furthermore be selected from branched alkanols, for example Guerbet alcohols with a single branching on the carbon atom 2, such as 2-hexyldecanol, 2-octyldodecanol, isotidecanol and isohexadecanol, from alkanediols, for example those from epoxyalkanes having 12-24 C Atoms by ring opening with vicinal diols available from water, from ether alcohols, for example the monoalkyl ethers of glycene, of ethylene glycol, of 1,2-propylene glycol or of 1,2-butanediol, of dialkyl ethers having in each case 12-24 carbon atoms, for example Alkyl methyl ethers or di-n-alkyl ethers each having a total of 12-24 carbon atoms, in particular di-n-octyl ether (Cet ⁇ ol ® OE ex Cognis
  • o-alkanols such as butanol and Glyce ⁇ n, eg PPG-3 Mynstylether (Witconol APM ®), PPG-14 butyl ether (Ucon Fluid ® AP) PPG-15 stearyl ether (Arlamol ® E), PPG-9-butyl ether (Breox B25 ®) and PPG-10-Butand ⁇ ol (Macol ® 57)
  • the oil component is used in the inventive compositions, if present, preferably in an amount of up to 30% by weight, more preferably in an amount of 1-20% by weight
  • Saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with 6 to 30, preferably 10 to 22 and very particularly preferably 12 to 22 carbon atoms can be used as fatty alcohols.
  • Decanol, octanol, octenol, dodecenol, for example, can be used in the context of the invention.
  • Fatty alcohols are used in the compositions according to the invention, if present, preferably in an amount of up to 30% by weight, more preferably in an amount of 5-20% by weight
  • Cellulosic ethers such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose, as well as gelatin, vegetable gums such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum or locust bean gum, as well as thickening polymers based on can be used as thickeners of polyacrylates that may be if desired, crosslinked, or based on polyacrylamides or sulfonsaure phenomenon Georgian polyacrylates, z B Sepigel ® 305 or Simulgel ® EC continue natural inorganic thickeners, for example, and synthetic clays and phyllosilicates, for example bentonite, Hecto ⁇ t, Montmo ⁇ llomt or Laponite ® , as well as fully synthetic hydrocolloids such as polyvinyl alcohol, and also Ca, Mg or Zn Se ⁇ fen of fatty acids As a thickener preferably polys
  • the thickener is preferably used in the compositions according to the invention in an amount of up to 5% by weight, more preferably in an amount of 0.1-2.5% by weight
  • the coloring component is preferably selected
  • developer components are usually primary aromatic amines with a further, in the para or ortho position, free or substituted hydroxy or amino, Diaminopy ⁇ dinderivate, heterozykhsche hydrazones, 4-Am ⁇ nopyrazolder ⁇ vate and 2,4,5,6-tetraaminopyrimidine and its derivatives used
  • G 1 represents a hydrogen atom, a C 1 - to C 4 alkyl, C 1 - to C 4 - monohydroxyalkyl radical, a C 2 - to C 4 polyhydroxyalkyl radical, a (C 1 - to C 4 J-AIkOXy- ( C 1 - to C 4 ) -alkyl radical, a 4'-Aminophenylrest or a C 1 - to C 4 -alkyl radical which is substituted by a nitrogen-containing group, a phenyl or a 4'-Aminophenylrest, G 2 is a hydrogen atom a C 1 - to C 4 alkyl, C 1 - to C 4 - monohydroxyalkyl radical, a C 2 - to C 4 polyhydroxyalkyl radical, a (d- to C 4) alkoxy (C r to C 4) - alkyl radical or a C 1 - to C 4 -alkyl radical which is substituted by a nitrogen-containing
  • G 3 represents a hydrogen atom, a halogen atom such as a chlorine, bromine, iodine or fluorine atom, a C 1 - to C 4 -alkyl radical, a C 1 - to C 4 -monohydroxyalkyl radical, a C 2 - to C 4 - polyhydroxyalkyl radical, a C 1 - to C 4 -Hydroxyalkoxyrest, a C 1 - to C 4 - Acetylaminoalkoxyrest, a C 1 - to C 4 - Mesylaminoalkoxyrest or a C 1 - to C 4 - Carbamoylaminoalkoxyrest,
  • G 4 represents a hydrogen atom, a halogen atom or a C 1 - to C 4 -alkyl radical or, when G 3 and G 4 are ortho to one another, they may together form a bridging ⁇ , ⁇ -alkylenediooxy group, for example an ethylenedioxy group
  • C 1 - to C 4 - alkyl radicals are the methyl, ethyl, propyl, isopropyl and butyl ethyl and methyl are preferred alkyl groups
  • preferred C 1 - to C 4 -alkoxy are, for example, a methoxy - or an ethoxy group
  • a C 1 - to C 4 -hydroxyalkyl group a hydroxymethyl, a 2-hydroxyethyl, a 3-hydroxypropyl or a 4-hydroxybutyl group may be mentioned.
  • a 2-hydroxyethyl group is particularly preferably
  • a particularly Preferred C 2 - to C 4 -polyhydroxyalkyl group is the 1, 2-Dhydroxyethyl distrin
  • halogen atoms are according to the invention
  • F, Cl or Br atoms, Cl atoms are very particularly preferred according to the invention the other terms used are derived from the definitions given herein
  • nitrogen-containing groups of the formula (Ent1) are in particular the amino groups, C 1 - to C 4 - Monoalkylam ⁇ no phenomenon, C 1 - to C 4 - Dialkylammo phenomenon, C 1 - to C 4 -Tr ⁇ alkylammon ⁇ um phenomenon, C 1 - to C 4 - Monohydroxyalkylamino tendency, and ammonium Imidazolmium
  • Particularly preferred p-phenylenediamines of the formula (Ent1) are selected from p-phenylenediamine, p-Toluylend ⁇ am ⁇ n, 2-chloro-p
  • Very particularly preferred p-phenylenediamine derivatives of the formula (Ent1) according to the invention are p-phenylenediamine, p-toluenediamine, 2- ( ⁇ -hydroxyethyl) -p-phenylenediamine, 2- ( ⁇ , ⁇ -dihydroxyethyl) -p-phenylenediamine and N, N -B ⁇ s- (ß-hydroxyethyl) -p-phenylend ⁇ am ⁇ n
  • developer component compounds which contain at least two aromatic nuclei which are substituted by amino and / or hydroxyl groups
  • binuclear developer components which can be used in the compositions according to the invention, mention may be made in particular of the compounds corresponding to the following formula (Ent2) and their physiologically compatible salts
  • Z 1 and Z 2 independently of one another represent a hydroxyl or NH 2 radical which is optionally substituted by a C 1 - to C 4 -alkyl radical, by a C 1 - to C 4 -hydroxyalkyl radical and / or by a bond Y. or which is optionally part of a bridging ring system, the bond Y is an alkylene group having 1 to 14 carbon atoms, such as a linear or branched alkylene chain or an alkylene interrupted or terminated by one or more nitrogen-containing groups and / or one or more heteroatoms such as oxygen, sulfur or nitrogen atoms and may optionally be substituted by one or more hydroxyl or C 1 to C 8 alkoxy radicals, or a direct bond,
  • G 5 and G 6 are each independently a hydrogen or halogen atom, a C 1 - to C 4 alkyl radical, a Ci to C 4 monohydroxyalkyl radical, a C 2 - to C 4 - polyhydroxyalkyl radical, a C 1 - to C 4 -Am ⁇ noalkylrest or a direct connection to the bridge Y,
  • G 7 , G 8 , G 9 , G 10 , G 11 and G 12 independently of one another represent a hydrogen atom, a direct bond to the bond Y or a C 1 - to C 4 -alkyl radical, with the provisos that the compounds of the formula (Ent2) contain only one bond Y per molecule and the compounds of the formula (Ent2) contain at least one amino group which carries at least one hydrogen atom
  • Preferred binuclear developer components of the formula (Ent2) are in particular N, N'-bis ( ⁇ -hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1, 3-d ⁇ am ⁇ no-propan-2-ol, N , N'-bis (.beta.-hydroxyethyl) -N, N'-bis (4'-aminophenyl) ethylend ⁇ am ⁇ n, N, N'-B ⁇ s- (4-arnnophenyl) tetramethylend ⁇ am ⁇ n, N, N'-B ⁇ s- ( ⁇ -hydroxyethyl) -N, N'-bis (4-aminophenyl) -tetramethylend ⁇ am ⁇ n, N, N'-bis (4-methyl-aminophenyl) - tetramethylenediamine, N, N'-D ⁇ ethyl-N, N'- bis (4'-amino-3'-methylphenyl)
  • Very particularly preferred binuclear developer components of the formula (Ent2) are N, N'-bis ( ⁇ -hydroxyethyl) -N, N'-bis (4'-aminophenyl) -1,3-d ⁇ am ⁇ no-propan-2-ol, Bis (2-hydroxy-5-aminophenyl) methane, 1, 3-bis (2,5-d ⁇ am ⁇ nophenoxy) propan-2-ol, N, N'-bis (4'-aminophenyl) -1, 4-diazacycloheptane and 1, 10-bis (2 ', 5'-d ⁇ am ⁇ nophenyl) -1,4,7,10-tetraoxadecan or one of its physiologically acceptable salts
  • a p-aminophenol derivative or one of its physiologically compatible salts as the developer component.
  • Particular preference is given to p-aminophenol derivatives of the formula (Ent3) in which
  • G 13 represents a hydrogen atom, a halogen atom, a C 1 to C 4 alkyl radical, a C 1 to C 4 monohydroxyalkyl radical, a C 2 to C 4 polyhydroxyalkyl radical, a (C 1 to C 4 ) alkoxy - (C r to C 4 ) -alkyl radical, a C 1 - to C 4 -Am ⁇ noalkylrest, a HyCIrOXy- (C 1 - to C 4 ) -alkylam ⁇ norest, a C 1 - to C 4 -hydroxyalkoxy, a C 1 - to C 4 -hydroxyalkyl- (C r b ⁇ s C 4 ) -am ⁇ noalkylrest or a (di-C 1 - to C 4 -A ⁇ yIaIDmO) - (C 1 - to C 4 ) -alkyl radical, and
  • G 14 represents a hydrogen or halogen atom, a C 1 - to C 4 alkyl, C 1 - to C 4 - monohydroxyalkyl radical, a C 2 - to C 4 polyhydroxyalkyl radical, a (C 1 - to C 4 -alkoxy ⁇ - (C 1 - to C 4 ) -alkyl radical, a C 1 - to C 4 -Am ⁇ noalkylrest or a C 1 - to C 4 -Cyanoalkylrest, G 15 is hydrogen, a C 1 - to C 4 -alkyl radical, a C 1 to C 4 monohydroxyalkyl, C 2 to C 4 polyhydroxyalkyl, phenyl or benzyl, and G 16 represents hydrogen or halogen atom, a C 1 - to C 4 alkyl, C 1 - to C 4 - monohydroxyalkyl radical, a C 2 - to C 4 polyhydroxyalkyl, phenyl or benzyl
  • Preferred p-aminophenols of the formula (Ent3) are, in particular, p-aminophenol, N-methyl-p-ammophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 2-hydroxymethylamino-4-aminophenol, 4 -Am ⁇ no-3-hydroxymethylphenol, 4-amino-2- (ß-hydroxyethoxy) phenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethyl-phenol, 4-amino -2- aminomethylphenol, 4-amino-2- ( ⁇ -hydroxyethyl-aminomethyl) -phenol, 4-amino-2- ( ⁇ , ß-d ⁇ hydroxyethyl) -phenol, 4-amino-2-fluorophenol, 4-amino-2 Chlorophenol, 4-amino-2,6-diklorophenol, 4-amino-2- (d ⁇ ethyl-am ⁇ nomethyl) -phenol and their physiological
  • Very particularly preferred compounds of the formula (Ent3) are p-aminophenol, 4-amino-3-methylphenol, 4-amino-2-aminomethylphenol, 4-amino-2- ( ⁇ , ⁇ -dihydroxyethyl) -phenol and 4-amino 2- (d ⁇ ethyl-am ⁇ nomethyl) -phenol
  • the developer component may be selected from o-aminophenol and its derivatives, such as, for example, 2-amino-4-methylphenol, 2-amino-5-methylphenol or 2-amino-4-chlorophenol
  • the developer component may be selected from heterocyclic developer components such as the pyridine, pynmidine, pyrazole, pyrazole pyrazidine derivatives and their physiologically-acceptable salts
  • Preferred pyridine derivatives are, in particular, the compounds described in the patents GB 1 026 978 and GB 1 153 196, such as 2,5-dimethylaminopyridine, 2- (4'-methoxyphenyl) amino-3-amino-pyridine, 2,3-D ⁇ am ⁇ no-6-methoxy-pyr ⁇ d ⁇ n, 2- (ß-methoxyethyl) am ⁇ no-3-amino-6-methoxy-pyndin and 3,4-D ⁇ am ⁇ no-pyr ⁇ d ⁇ n
  • Preferred pynmidine derivatives are, in particular, the compounds described in German Patent DE 2 359 399, Japanese Laid-Open Patent JP 02019576 A2 or in Offenlegungssch ⁇ ft WO 96/15765, such as 2,4,5,6-Tetraam ⁇ nopyr ⁇ m ⁇ d ⁇ n, 4-hydroxy 2,5,6-t ⁇ aminopy ⁇ midine, 2-hydroxy-4,5,6-tr ⁇ am ⁇ nopyr ⁇ m ⁇ d ⁇ n, 2-D ⁇ methylam ⁇ no-4,5,6-tr ⁇ am ⁇ nopy ⁇ m ⁇ d ⁇ n, 2,4-D ⁇ hydroxy-5,6-d ⁇ am ⁇ nopyr ⁇ m ⁇ d ⁇ n and 2,5,6- Tr ⁇ am ⁇ nopyr ⁇ m ⁇ d ⁇ n
  • Preferred pyrazole derivatives are, in particular, the compounds described in patents DE 3 843 892, DE 4 133 957 and patent applications WO 94/08969, WO 94/08970, EP-740 931 and DE 195 43 988, such as 4,5 Diamino-i-methylpyrazole, 4,5-diamino-1- ( ⁇ -hydroxyethyl) -pyrazole, 3,4-diamino-pyrazole, 4,5-diamino-1- (4'-chlorobenzyl) -pyrazole, 4,5- D ⁇ am ⁇ no- 1, 3-dimethylpyrazole, 4,5-D ⁇ am ⁇ no-3-methyl-1-phenylpyrazol, 4,5-D ⁇ am ⁇ no-1-methyl-3-phenylpyrazole, 4-Am ⁇ no-1, 3-dimethyl-5-hydraz ⁇ nopyrazol, 1-Benzyl-4,5-d ⁇ am ⁇ no-3-methylpyrazole, 4,5-D ⁇
  • Preferred pyrazolopynmidine derivatives are, in particular, the derivatives of the pyrazolo [1, 5-a] -pyrrolidine of the following formula (Ent4) and their tautomeric forms, provided that a tautomeric equilibrium exists
  • G 17, G 18, G 19 and G 20 represent a hydrogen atom, an independently d- to C 4 alkyl radical, an aryl radical, a C 1 - to C 4 -hydroxyalkyl group, a C 2 - to C 4 - Polyhydroxyalkylrest a (C 1 - to C 4 J-AIkOXy- (C 1 - to C 4 ) -alkyl radical, a C 1 - to C 4 - aminoalkyl radical which may optionally be protected by an acetyl-ureide or a sulfonyl radical , a (C 1 - to C 4 ) -Alkylam ⁇ no- (C r to C 4 ) alkyl, a 01 - [(C 1 - to C 4 ) alkyl] - (C r to C 4 ) -am ⁇ noalkylrest, wherein the dialkyl radicals optionally form a carbon cycle or a heterocycle with 5 or 6 chain
  • Group OH occupy positions (2,3), (5,6), (6,7), (3,5) or (3,7),
  • Coupler components preferred according to the invention are m-aminophenol and its derivatives such as, for example, 5-amino-2-methylphenol, N-cyclopentyl-3-aminophenol, 3-amino-2-chloro-6-methylphenol, 2-hydroxy-4-aminophenoxyethanol, 2 6-dimethyl-3-aminophenol, 3-trifluoroacetylamino-2-chloro-6-methylphenol, 5-amino-4-chloro-2-methylphenol, 5-amino-4-methoxy-2-methylphenol, 5- (2'-methyl) Hydroxyethyl) -amino-2-methylphenol, 3- (D ⁇ ethylam ⁇ no) -phenol, N-cyclopentyl-3-aminophenol, 1, 3-D ⁇ hydroxy-5- (methylamino) benzene, 3-Ethylam ⁇ no-4-methylphenol and 2.4 -D ⁇ chlor-3-aminophenol, o-aminophenol and its derivatives, m-D ⁇ am
  • Di- or Tnhydroxybenzolderivate such as resorcinol, resorcinol monomethyl ether, 2-Methylresorc ⁇ n, 5-Methylresorc ⁇ n, 2,5-D ⁇ methylresorc ⁇ n, 2-chlororesorcinol, 4-Chlorresorc ⁇ n, pyrogallol and 1, 2,4-Tr ⁇ hydroxybenzol, Pyridinde ⁇ vate such as 2,6-D ⁇ hydroxypy ⁇ d ⁇ n , 2-Amino-3-hydroxypyr ⁇ d ⁇ n, 2-Am ⁇ no-5-chloro-3-hydroxypyr ⁇ d ⁇ n, 3-Am ⁇ no-2-methylam ⁇ no-6-methoxypy ⁇ d ⁇ n, 2,6-D ⁇ hydroxy-3,4-dimethylpy ⁇ din, 2,6-D ⁇ hydroxy 4-methylpyr ⁇ d ⁇ n, 2,6-D ⁇ am ⁇ nopyr ⁇ d ⁇ n, 2,3-D ⁇ am ⁇ no-6-methoxypyndin and 3,5-D ⁇
  • Naphthalinde ⁇ vate such as 1-naphthol, 2-methyl-1-naphthol, 2-hydroxymethyl-1-naphthol, 2-hydroxyethyl-1-naphthol, 1, 5-D ⁇ hydroxynaphthal ⁇ n, 1, 6-D ⁇ hydroxynaphthal ⁇ n, 1, 7 Dihydroxynaphthahn, 1 , 8-dihydroxynaphthalene, 2,7-dihydroxynaphthalene and 2,3-dihydroxynaphthalene,
  • Morpholinde ⁇ vate such as 6-Hydroxybenzomorphol ⁇ n and 6-Am ⁇ no-benzomorphol ⁇ n
  • Chinoxalinde ⁇ vate such as 6-methyl-1, 2,3,4-tetrahydroch ⁇ noxal ⁇ n
  • Pyrazolde ⁇ vate such as 1-phenyl-3-methylpyrazol-5-one
  • Indolde ⁇ vate such as 4- Hydroxy ⁇ ndol, 6-Hydroxy ⁇ ndol and 7-Hydroxy ⁇ ndol
  • Pyrimidinde ⁇ vate such as 4,6-D ⁇ am ⁇ nopyr ⁇ m ⁇ d ⁇ n
  • 2- Amino-4-methylpyrrolidine 2-amino-4-hydroxy-6-methylpyrrolidine and 4,6-dihydroxy-2-methylpyrrolidine, or
  • Erfmdungsgeolin particularly preferred coupler components are 1-naphthol, 1, 5, 2,7- and 1, 7-Dihydroxynaphthalm, 3-Aminophenol, 5-Am ⁇ no-2-methylphenol, 2-Am ⁇ no-3-hydroxypyr ⁇ d ⁇ n, resorcinol, 4-Chlorresorc ⁇ n , 2-chloro-6-methyl-3-aminophenol, 2-Methylresorc ⁇ n, 5-Methylresorc ⁇ n, 2,5-D ⁇ methylresorc ⁇ n and 2,6-D ⁇ hydroxy-3,4-d ⁇ methylpyr ⁇ d ⁇ n and the physiologically acceptable salts of the aforementioned compounds
  • the agents according to the invention preferably contain the developer components in an amount of from 0.005 to 10% by weight, preferably from 0.1 to 5% by weight, in each case based on the total agent
  • the agents according to the invention preferably contain the coupler components in an amount of from 0.005 to 10% by weight, preferably from 0.1 to 5% by weight, in each case based on the total agent
  • the composition according to the invention can be used as a coloring component in the form of the oxo dye precursors at least one combination of at least one compound of the component
  • Compounds according to the invention having a reactive carbonyl group have at least one carbonyl group as the reactive group which reacts with the compounds of component 2 to form a chemical bond linking both components.
  • compounds according to the invention are also components 1 in which the reactive carbonyl group is denationalized or masked so that the reactivity of the carbon atom of the de ⁇ vatis elected or masked carbonyl group is always present over the component 2
  • These derivatives are preferably condensation compounds of reactive carbonyl compounds with a) amines and their derivatives to form Immen or Oximes as Condensation Compound b) Alcohols to Form Acetals or Ketals as Condensation Compound c) Water to Form Hydrates as Condensation Compound of Aldehydes
  • Component 1 is preferably selected from the group formed from acetophenone, propiophenone, 2-hydroxyacetophenone, 3-hydroxyacetophenone, 4-hydroxyacetophenone, 2-hydroxypropiophenone, 3-hydroxypropiophenone, 4-hydroxypropylphenone, 2-hydroxybutyrophenone, 3-hydroxybutyrophenone, 4-hydroxybutyrophenone, 2,4-dihydroxyacetophenone, 2,5-dihydroxyacetophenone, 2,6-dihydroxyacetophenone, 2,3,4-trihydroxyacetophenone, 3,4,5-trihydroxyacetophenone, 2,4,6-trihydroxyacetophenone, 2,4, 6-trimethoxyacetophenone, 3,4,5-trimethoxyacetophenone, 3,4,5-tri-methoxy-acetophenone-d-ethyl ketal, 4-hydroxy-3-methoxy-acetophenone, 3,5-dimethoxy-4-hydroxyacetophenone, 4-aminoacetophenone, Dimethylaminoacetophenone, 4-morph
  • CH acyl those compounds are generally considered which carry a hydrogen atom bound to an aliphatic carbon atom, whereby activation of the corresponding carbon-hydrogen bond is brought about by electron-withdrawing substituents.
  • the invention also includes enamels obtained by alkaline Treatment of quaternized N-heterocycles with a standing in conjugation to the quaternary nitrogen CH-acyclic alkyl group arise
  • the CH-ac ⁇ den compounds of component 2 are preferably selected from the group consisting of 1, 2,3,3-tetramethyl-3H- ⁇ ndol ⁇ um ⁇ od ⁇ d, 1, 2,3,3-tetramethyl-3H- ⁇ ndol ⁇ um-p-toluenesulfonate, 1, 2,3,3-tetramethyl-3H- ⁇ ndol ⁇ um-methanesulfonat, 1, 3,3-T ⁇ methyl-2-methylen ⁇ ndol ⁇ n (Fischer's base), 2,3-D ⁇ methyl-benzoth ⁇ azol ⁇ um ⁇ od ⁇ d, 2,3-D ⁇ methyl-benzoth ⁇ azol ⁇ um-p-toluenesulfonate Fonate, 2,3-dimethyl-naphtho [1,2-d] thiazolium p-toluenesulfonate, 3-ethyl-2-methyl-naphtho [1,2-d] thiazolium p-toluenesul
  • Preferred primary or secondary aromatic amines of component B are selected from N, N-dimethyl-p-phenylenediamine, N, N-dimethyl-p-phenylenediamine, N- (2-hydroxyethyl) -N-ethyl-p-phenylenediamine, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, N- (2-methoxyethyl) -p-phenylenediamine, 2,3-di-chloro-p-phenylenediamine, 2,4-di-chloro-p-phenylenediamine, 2,5- Di-chloro-p-phenylenediamine, 2-chloro-p-phenylenediamine, 2,5-dihydroxy-4-morpholinoaniline, 2-aminophenol, 3-aminophenol, 4-aminophenol, 2-aminomethyl-4-aminophenol, 2-hydroxymethyl 4-aminophenol, o-phenylened
  • R 7 is a hydroxy or an amino group, which is represented by Ci. 4 alkyl, C ⁇ hydroxyalkyl, C 1-4 alkoxy or may be substituted,
  • R 8, R 9, R 10, R 11 and R 12 atom independently represent a hydrogen, a hydroxy or an Ammoè, by Ci-C 4 alkyl, C 1 -C 4 hydroxyalkyl, C 1 - C 4 alkyl, C 1 -C 4 aminoalkyl or dC ⁇ alkoxy-CrC ⁇ alkyl groups may be substituted, and
  • P is a direct bond, a saturated or unsaturated, optionally substituted by hydroxy groups carbon chain having 1 to 4 carbon atoms, a carbonyl, sulfoxy, sulfonyl or imino group, an oxygen or sulfur atom, or a group having the formula V
  • Q signifies a direct bond, a CH 2 or CHOH group
  • Q 'and Q are each independently an oxygen atom, an NR 13 group wherein R 13 is a hydrogen atom alkyl group, a Ci -4 alkyl or a hydroxy-C M, where also the two groups together with the a Restmolekul 5-, 6- or 7-R ⁇ ng form, the group O- (CH 2 ) P -NH or NH- (CH 2 ) P -O, wherein p and p 'are 2 or 3, stand and
  • O is a number from 1 to 4,
  • the abovementioned compounds can be used both in free form and in the form of their physiologically compatible salts, in particular as salts of inorganic acids, such as hydrochloric or sulfuric acid
  • Suitable nitrogen-containing heterocyclic compounds are, for example, 2-aminopyridine, 3-aminopynidine, 4-aminopynidine, 2-amino-3-hydroxypyridine, 2,6-diamino-pyrimidine, 2,5-diamino-pyndin, 2- (aminoethylamino) -5-aminopynidine, 2,3-dimethylaminopyridine, 2-dimethylamino-5-aminoaminodine, 2-methylamino-3-amino-6-methoxy-pyridine, 2,3-dimethylamin-6-methoxy-pyrimidine, 2 , 6-dimethoxy-3,5-d ⁇ am ⁇ no-pyr ⁇ d ⁇ n, 2,4,5-T ⁇ N- (5-amino-2-pyridyl) -amine, N- [2- (4-aminophenyl) -aminoethyl] -N- (5-amino-2-pyridyl
  • Suitable aromatic hydroxy compounds are, for example, 2-methylresorcinol, 4-methylresorcinol, 5-methylresorcinol, 2,5-dimethylresorcinol, resorcinol, 3-methoxyphenol, pyrocatechol, hydroquinone, pyrogallol, phloroglucinol, hydroxyhydroquinone, 2-methoxyphenol, 3-methoxyphenol, 4- Methoxyphenol, 3-D ⁇ methylam ⁇ nophenol, 2- (2-hydroxyethyl) phenol, 3,4-Methylend ⁇ oxyphenol, 2,4-dihydroxybenzoic acid, 3,4-Dihydroxybenzoesaure, 2,4-D ⁇ hydroxy-phenylessigsaure, 3,4-dihydroxy-phenylacetic acid, gallic acid , 2,4,6-Tr ⁇ hydroxybenzoesaure, 2,4,6-T ⁇ hydroxyace- tophenone, 2-Chlorresorc ⁇ n, 4-Chlorresorc ⁇ n, 1-n
  • the compounds of component A and the compounds of component B are preferably used in the shading agents according to the invention in each case in an amount of 0.03 to 65 mmol, in particular from 1 to 40 mmol, based on 100 g of the total Nuancierstoffs, the molar ratio of the Compound of component A and the compound of component B may be in the range of 0.5 to 2.0, preferably equimolar amounts are used.
  • the actual shading agent is prepared by separate storage of components A and B immediately prior to application by mixing
  • oxidation dye precursor of the developer type such indoles and Indohne having at least one hydroxy or amino group, preferably as a substituent on the six-membered ring
  • these groups can carry further substituents, eg in the form of an etherification or esterification of the hydroxy group or a Alkylation of the Amino Group
  • the colorants contain at least one indole and / or indole indenate
  • Particularly suitable precursors of natural-analogous hair dyes are derivatives of 5,6-dihydroxyindoline of the formula (VIa)
  • R 1 is hydrogen, a C ⁇ C ⁇ alkyl group or a CrC ⁇ hydroxy-alkyl group
  • R 2 is hydrogen or a -COOH group, wherein the -COOH group may also be present as a salt with a physiologically compatible cation
  • R 3 is hydrogen or a C 1 -C 4 alkyl group
  • R 4 is hydrogen, a C 1 -C 4 -alkyl group or a group -CO-R 6 , in which R 6 is a C r C 4 -alkyl group, and R 5 is one of the groups mentioned under R 4 , as well as physiologically acceptable salts of these compounds with an organic or inorganic acid
  • Particularly preferred derivatives of Indohns are 5,6-D ⁇ hydroxy ⁇ ndol ⁇ n, N-methyl-5,6-dihydroxyindohn, N-ethyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n, N-propyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n, N-butyl-5,6 -d ⁇ hydroxy ⁇ ndol ⁇ n, 5,6-D ⁇ hydroxy ⁇ ndol ⁇ n-2-carboxylic acid and the 6-Hydroxy ⁇ ndol ⁇ n, the 6-Am ⁇ no ⁇ ndol ⁇ n and the 4-Am ⁇ no ⁇ ndol ⁇ n
  • N-methyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n N-ethyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n, N-propyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n, N-butyl-5,6-d ⁇ hydroxy ⁇ ndol ⁇ n and in particular the 5, 6-D ⁇ hydroxy ⁇ ndol ⁇ n
  • R 1 represents hydrogen, a CrC ⁇ alkyl group or a hydroxyalkyl group dC t,
  • R 2 is hydrogen or a -COOH group, wherein the -COOH group may also be present as a salt with a physiologically compatible cation,
  • R 3 is hydrogen or a dC t -alkyl group
  • R 4 is hydrogen, a C 1 -C 4 alkyl group or a group -CO-R 6 , in which R 6 is a C 1 -C 4 alkyl group, and
  • R 5 is one of the groups mentioned under R 4 , and physiologically contractual salts of these compounds with an organic or inorganic acid
  • Particularly preferred derivatives of indole are 5,6-D ⁇ hydroxy ⁇ ndol, N-methyl-5,6-d ⁇ hydroxy ⁇ ndol, N-ethyl-5,6-d ⁇ hydroxy ⁇ ndol, N-propyl-5,6-d ⁇ hydroxy ⁇ ndol, N-butyl-5,6- D ⁇ hydroxy ⁇ ndol, 5,6- D ⁇ hydroxy ⁇ ndol-2-carboxylic acid, 6-Hydroxy ⁇ ndol, 6-Am ⁇ no ⁇ ndol and 4-Am ⁇ no ⁇ ndol
  • Preferred substantive dyes which are used as colorant component in the compositions according to the invention are nitrophenylenediamines, nitroaminophenols, azo dyes, anthraquinones or indophenols.
  • Preferred substantive dyes are those under the international designations or trade names HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow Acid Yellow 1, Acid Yellow 23, Acid Yellow 36, HC Orange 1, Disperse Orange 3, Acid Orange 7, HC Red 1, HC Red 3, HC Red 10, HC Red 11, HC Red 13, Acid Red 33, Acid Red 52, HC Red BN, Pigment Red 57 1, HC Blue 2, HC Blue 12, Disperse Blue 3, Acid Blue 7, Acid Green 50, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Acid Violet 43, Disperse Black 9, Acid Black 1, and Acid Black 52 known compounds and 1, 4-D ⁇ am ⁇ no-2-nitrobenzene, 2-Am ⁇ no-4-n ⁇ trophenol, 1, 4-B ⁇ s- (ß-hydroxyethyl ) Amino-2-
  • compositions according to the invention may contain a cationic substantive dye. Particular preference is given to this
  • aromatic systems substituted with a quaternary nitrogen group such as Basic Yellow 57, Basic Red 76, Basic Blue 99, Basic Brown 16 and Basic Brown 17, as well as
  • Preferred cationic substantive dyes of group (c) are in particular the following compounds
  • the compounds of the formulas (DZ1), (DZ3) and (DZ5) which are also known by the names Basic Yellow 87, Basic Orange 31 and Basic Red 51, are very particularly preferred cationic substantive dyes of the group (c)
  • the cationic direct dyes which are sold under the trademark Ananor ®, are accordance with the invention likewise very particularly preferred cationic direct dyes
  • compositions according to the invention preferably contain the substantive dyes in an amount of from 0.01 to 20% by weight, based on the ready-to-use agent
  • preparations according to the invention may also contain naturally occurring dyes such as those found in henna red, henna neutral, henna black, chamomile blood, sandalwood, black tea, buckthorn bark, sage, sawnwood, madder root, catechu, sedre and alkana root
  • the oxidation dye precursors or the substantive dyes each represent uniform compounds Rather, in the inventive Compositions, due to the production process for the individual dyes, may be contained in minor amounts of other components, as far as they do not adversely affect the color result or for other reasons, eg toxicological, must be excluded
  • the agent according to the invention contains oxidation dye precursors or in particular precursors of a nature-analogous dye based on indole or indone
  • the actual oxidative dyeing of the fibers can in principle be carried out with atmospheric oxygen.
  • an additional chemical oxidizing agent is used Coloring with the coloring components of a whitening effect on human hair is desired, an additional chemical oxidizing agent is generally used
  • a chemical oxidizing agent are persulfates, Chlonte and in particular hydrogen peroxide or its addition products of urea, melamine and sodium borate in question
  • compositions according to the invention contain at least one additional chemical oxidizing agent, preferably in an amount of from 0.5 to 12.0% by weight, in particular from 6 to 12% by weight, based in each case on the weight of the ready-to-use agent
  • a further embodiment of the agent according to the invention is a colorant for keratin-containing fibers, in particular human hair, which is mixed immediately before use of two components, wherein the first component comprises an agent comprising in a carrier at least one developer component and optionally at least one
  • the second component is an oxidizing agent composition containing at least one chemical oxidizing agent, in particular hydrogen peroxide, and at least one of the two components contains at least one amphiphilic polymer
  • the agent of the invention can also be applied to the hair together with an oxidation activator which activates the oxidation of the oxidation dye precursors by the oxidant.
  • an oxidation activator which activates the oxidation of the oxidation dye precursors by the oxidant.
  • oxidizing agent as previously mentioned, atmospheric oxygen or additional chemical oxidants.
  • the oxidation activators are preferably selected from the group that is formed from carbonates, hydrogencarbonates, carbamates, carboxylic esters or their salts, aldehydes, in particular aliphatic aldehydes, 1, 3 Dihydroxyacetone, imidazole and its derivatives, alkali and ammomomer oxidisulfates, metal ions, iodides, quinones and enzymes
  • the oxidation activators are preferably present in amounts of from 0.01 to 5% by weight, based on the weight of the ready-to-use agent, in the agents according to the invention
  • Suitable metal ions are, for example, Zn 2+ , Cu 2+ , Fe 2+ , Fe 3+ , Mn 2+ , Mn 4+ , Li + , Mg 2+ , Ca 2+ and Al 3+ .
  • Zn 2+ is particularly suitable for this purpose, Cu 2+ and Mn 2+
  • the metal ions may in principle be used in the form of any physiologically compatible salt or complex compound.
  • Preferred salts are the acetates, sulfates, halides, lactates and tartrates accelerated as well as the color shade are specifically influenced
  • Suitable enzymes are, for example, peroxidases which can markedly increase the effect of small amounts of hydrogen peroxide.
  • Enzymes which directly oxidize the oxidation dye precursors with the aid of atmospheric oxygen, such as, for example, the laccases, or generate small amounts of hydrogen peroxide in situ and in this way are suitable biocatalytically activate the oxidation of the dye precursors
  • Particularly suitable catalysts for the oxidation of the dye precursors are the so-called 2-electron oxidoreductases in combination with the specific substrates, eg
  • Pyranose oxidase and, for example, D-glucose or galactose,
  • Lactate oxidase and lactic acid and their salts Lactate oxidase and lactic acid and their salts
  • the actual (oxidative) hair dye is expediently prepared immediately before use by mixing the oxidizing agent composition with the carrier of the coloring components, preferably in the weight ratio range of 1: 4 to 4: 1, in particular 1: 2 to 2: 1
  • the ready-to-use agent according to the invention should preferably have a pH in the range from pH 5 to pH 12, in particular from pH 7 to pH 11.
  • the use of the hair dye in a weakly alkaline medium in a pH range between pH 7 and pH is particularly preferred 9
  • the emulsifier which can be used according to the invention and which is contained in the compositions according to the invention preferably in an amount of less than 10% by weight, more preferably in an even smaller amount, as stated above, can in principle be selected from anionic, zwitterionic, ampholytic, nonionic and cationic surfactants
  • the surfactant is selected from anionic, zwitterionic and nonionic surfactants
  • anionic surfactants are in erfmdungsgespecializeden preparations all suitable for use on the human body anionic surfactants These are characterized by a wasserloshchpinde, anionic group such as a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 10 to 22 C-atoms
  • anionic group such as a carboxylate, sulfate, sulfonate or phosphate group
  • a lipophilic alkyl group with about 10 to 22 C-atoms
  • glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • anionic surfactants are, in each case in the form of the sodium, potassium and ammonium salts the mono-, di- and Tnalkanol- ammomumsalze with 2 or 3 C-atoms in the alkanol group, linear fatty acids with 10 to 22 carbon atoms (soaps),
  • Ethercarbon Acid the formula RO- (CH 2 -CH 2 O) x -CH 2 -COOH, in which R is a linear
  • Alkyl group having 10 to 22 C atoms and x 0 or 1 to 16,
  • Sulfosuccinic acid mono-alkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, linear alkanesulfonates having 12 to 18 C atoms, linear ⁇ -olefin sulfonates having 12 to 18 C atoms,
  • Alpha-sulfofatty acid methyl esters of fatty acids having 12 to 18 C atoms are examples of fatty acids having 12 to 18 C atoms.
  • Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH 2 -CH 2 O) x -SO 3 H, in which R is a preferably linear alkyl group having 10 to 18 C atoms and x 0 or 1 to 12,
  • esters of tartaric acid and citric acid with alcohols the addition products of about
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the Molecule and in particular salts of saturated and in particular unsaturated C 8 -C 22 - carboxylic acids, such as oleic acid, stearic acid, Isostea ⁇ nklare and palmitic acid
  • Nonionic surfactants contain, as hydrophilic group z B, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups.
  • Such compounds are, for example
  • Alkylphenols having 8 to 15 C atoms in the alkyl group having 8 to 15 C atoms in the alkyl group
  • Preferred nonionic surfactants are alkylpolyglycosides of the general formula R 1 O- (Z) x These compounds are characterized by the following parameters
  • the alkyl radical R 1 contains 6 to 22 carbon atoms and can be both linear and branched. Preferred are primary linear and methyl-branched aliphatic radicals in the 2-position. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myrylstyl, 1 -Cetyl and 1-stearyl Particularly preferred are 1-octyl, 1-decyl, 1-lauryl, 1-Myr ⁇ styl When using so-called "oxo-alcohols" as starting materials predominate compounds having an odd number of carbon atoms in the alkyl chain
  • the alkylpolyglycosides which can be used according to the invention can contain, for example, only a certain alkyl radical R 1.
  • these compounds are prepared starting from natural fats and oils or mineral oils.
  • the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular workup of these compounds
  • R 1 consists essentially of C 8 and C 10 alkyl groups, essentially of C 12 and C 14 alkyl groups, essentially of C 8 to C 16 alkyl groups or essentially of C 12 - to C 16 alkyl groups
  • sugar unit Z Any mono- or oligosaccharides can be used as sugar unit Z.
  • sugars having 5 or 6 carbon atoms and the corresponding oligosaccharides are used.
  • Such sugars are, for example, glucose, fructose, galactose, Arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose
  • Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose, glucose is particularly preferred
  • alkyl polyglycosides which can be used according to the invention contain on average from 1.1 to 5 sugar units. Alkyl polyglycosides having x values of from 1.1 to 1.6 are preferred. Very particular preference is given to alkyl glycosides in which x is from 1.1 to 1.4
  • the alkyl glycosides can also serve to improve the fixation of fragrance components on the hair.
  • the person skilled in the art is therefore preferred to this substance class as further in the event that an effect of the perfume on the hair beyond the duration of the hair treatment is desired.
  • alkoxylated homologs of said alkyl polyglycosides can also be used according to the invention. These homologs can contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit
  • zwitterionic surfactants can be used, in particular as cosurfactants.
  • Zwitterionic surfactants are surface-active compounds which have at least one quaternary ammonium group and at least one -COO H or -SO 3 H group.
  • Particularly suitable zwitterionic surfactants are so-called betaines such as the N-alkyl-N, N-d ⁇ methylammon ⁇ um-glyc ⁇ nate, for example, the cocoalkyl dimethylammonium glycinate, N-acyl-aminopropyl-N, N-d ⁇ methylammonamminc ⁇ nate, for example Kokosacylaminopropyl- dimethylammoniumglycinat, and 2-alkyl-3-carboxylmethyl 3-hydroxyethyl- ⁇ m ⁇ dazol ⁇ ne having in each case 8 to 18 C atoms in the alkyl or acyl group and Kokosacylaminoethylhydroxyethyl- carboxymethylglycinat
  • a preferred zwitterionic surfactant is known under the INCI name cocamidopropyl betaine fatty acid amide De ⁇ vat
  • ampholytic surfactants are surface-active compounds which, apart from a C 8 -C 18 -alkyl or acyl group in the molecule, have at least one free amino group and at least one --COOH- or -SO 3
  • suitable ampholytic surfactants are N-alkylglycene, N-alkylpropionic acids, N-alkylaminobutene acids, N-alkylmethylenediopropoxylic acids, N-hydroxyethyl-N-alkylaminopropylglycene, N-alkyltinoline, N-alkylarcosine , 2-Alkylam ⁇ noprop ⁇ onklaroy and Alkylaminoessigklaroy each having about 8 to 18 carbon atoms in the alkyl group
  • Particularly preferred ampholytic surfactants are the N-coco alkylammopropionate, Kokosacylaminoethylaminoprop
  • Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as Alkyltnmethylammoniumchloride, dialkyldimethylammonium chlorides and Trialkylmethylammoniumchlo ⁇ de, z B Cetyltrimethylammoniumchlo ⁇ d, Stearyltn- methyl ammonium chloride, Distearyldimethylammoniumchlo ⁇ d, Lauryldimethylammoniumchlo ⁇ d, lauryldimethylbenzylammonium chloride and T ⁇ cetylmethylammoniumchlorid, as well as those available under the INCI names Quatern ⁇ um-27 and Quatern ⁇ um-83 known Imidazohum Compounds
  • the long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms
  • esterquats are quaternized ester salts of fatty acids with ethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines such products are for example under the trademark Stepantex ®, Dehyquart ® and Armocare ® marketed products Armocare ® VGH-70, a N, N- B ⁇ s (2-Palm ⁇ toyloxyethyl) d ⁇ methylammon ⁇ umchlor ⁇ d, as well as Dehyquart ® F-75 and Dehyquart ® AU-35 are Examples of such esterquats
  • alkylamidoamines are usually natural by amidation or synthetic fatty acids and fatty acid cuts made with dialkylaminoamines erfmdungswash
  • Tegoamid ® S 18 commercially stearamidopropyl dimethylamine
  • cationic surfactants which can be used according to the invention are the quaternized protein hydrolysates
  • cationic silicone oils such as, for example, the commercially available products Q2-7224 (manufacturer Dow Corning, a stabilized tetramethylsilylamodimethicone), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, which is also referred to as amodimethicone), SM 2059 (manufacturer General Electric), SLM-55067 (manufacturer Wacker) and Ab ⁇ l ® Quat 3270 and 3272 (manufacturer Th Goldschmidt, d ⁇ -quatemare polydimethylsiloxanes, Quatern ⁇ um-80)
  • Q2-7224 manufactured Dow Corning, a stabilized tetramethylsilylamodimethicone
  • Dow Corning 929 emulsion containing a hydroxylamino-modified silicone, which is also referred to as amodimethicone
  • SM 2059 manufactured General Electric
  • SLM-55067 manufactured by SLM-55067 (
  • Em example of a suitable cationic surfactant quaternares sugar derivative is the commercially available product Glucquat ® 100 is, according to INCI nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride" OO
  • the compounds used as surfactant with alkyl groups may each be uniform substances. However, it is generally preferred to use native vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained
  • both products having a "normal" homolog distribution and those having a narrow homolog distribution can be used.
  • "Normal" homolog distribution means mixtures of homologs
  • narrow homolog distributions are obtained when, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alkoxides are used as catalysts. The use of products with narrow homolog distribution may be preferred
  • agents according to the invention may additionally contain all active ingredients, auxiliaries and additives known and commonly used in these fields.
  • These agents may in particular be selected from nonionic polymers, for example vinylpyrrolidone / vinyl acrylate copolymers,
  • dimethyldiallylammonium chloride polymers acrylamide-dimethyldiallyl-ammonium chlo ⁇ d copolymers, diethyl sulfate quaternized dimethylaminoethylmethacrylate-vinylpyrrolidone copolymers, vinylpyrrolidone-imidazolinium methochlo ⁇ d copolymers, and quaternized polyvinyl alcohol, zwitterionic and amphoteric polymers such as acrylamidopropyl-t-pyrrolidone methylammonium chloride / acrylate copolymers and octylacrylamide / methylmethacrylate / tert-
  • Butylaminoethyl methacrylate ⁇ -hydroxypropyl methacrylate copolymers anionic polymers such as polyacrylic acids, crosslinked polyacrylic acids,
  • Structurants such as maleic acid and lactic acid, hair conditioning compounds such as phospholipids, for example, soybean lecithin, E ⁇ Lec ⁇ t ⁇ n and Cephahne, Protein hydrolysates, in particular elastin, collagen, keratin, milk protein, soy protein and wheat protein hydrolysates, their condensation products with fatty acids and quaternized protein hydrolysates,
  • Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, Glyce ⁇ n and diethylene glycol, fiber structure-improving agents, especially mono-, di- and oligosaccharides such as glucose, galactose, fructose, fructose and lactose, quaternized amines such as methyl-1-alkylam ⁇ doethyl-2 -alkyl ⁇ m ⁇ dazol ⁇ n ⁇ um methosulfat defoamers such as silicones, dyes for staining the agent,
  • Antidandruff active ingredients such as Piroctone Olamine, Zinc Omadme and Climbazol, light stabilizers, in particular de ⁇ vatisator benzophenones, cinnamic acid derivatives and Tnazine, substances for adjusting the pH, such as customary acids, in particular pleasure acids and bases,
  • Active ingredients such as allantoin, pyrrolidonecarboxylic acids and their salts, and also bisabolol, vitamins, provitamins and vitamin precursors, in particular those of groups A, B 3 , B 5 , B 6 , C, E, F and H,
  • Plant extracts such as extracts of green tea, oak bark, stinging nettle, witch hazel, hops, chamomile, burdock root, horsetail, hawthorn, linden, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime, wheat, KIWI , Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, Hominy, Coltsfoot, Marshmallow, Meristem, Ginseng and Ginger root, Cholesterol,
  • Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers, fats and waxes such as spermaceti, beeswax, montan wax and paraffins, fatty acid alkanolamides,
  • Complexing agents such as EDTA, NTA, ß-Alan ⁇ nd ⁇ ess ⁇ gsaure and phosphonic acids, swelling and penetrating agents such Glyce ⁇ n, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidines, ureas and primary, secondary and tertiary phosphates, trubbing agents such as latex, styrene / PVP and styrene / acrylamide copolymers Pearlescing agents, such as ethylene glycol mono- and distearate, and PEG-3-dicstearate, pigments,
  • Stabilizers for hydrogen peroxide and other oxidizing agents propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air, antioxidants
  • the hair coloration cream according to the invention may be provided in a packaging unit (kit) in which it is packaged separately from optionally further components contained.
  • the kit may contain at least one likewise separately prepared oxidizing agent composition, especially if an (oxidative) colorant is present in the hair
  • the kit may additionally contain optional instructions for use, application aids, mixing vessels or protective gloves
  • a further subject of the present invention is a method for treating keratin-containing fibers, in which a hair coloration cream according to the invention, optionally after mixing with an oxidizing agent composition, is applied to the fibers and is unwound again after a contact time
  • the application temperatures can be in a range between 15 and 40 0 C
  • the hair dye is removed by unwinding of the hair to be dyed
  • the Nach Warren with a shampoo is omitted if a strong surfactant-containing carrier, eg a dyeing shampoo was used
  • a or B are mixed with a hydrogen peroxide solution, for example of the following composition
  • Stenol 16/18 is cetearyl alcohol
  • coconut oil C12-18 is fatty alcohols C12-18
  • SilSense SW-12 Noveon
  • KF-601 1 Tin-Etsu
  • a paint cream according to A or B and a developer according to C are mixed together when applied in the ratio 1 1
  • Example 3 Rheological properties of a hair coloration cream according to the invention in comparison to a surfactant-containing hair coloration cream
  • a hair coloration cream according to the invention has a markedly higher viscosity compared to a surfactant-containing hair coloring cream at a low shear rate and a significantly lower viscosity at a high shear rate. This provides the consumer with a richer product which can be distributed better at the same time

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Abstract

L'invention se rapporte à des crèmes de coloration capillaire comprenant des polymères amphiphiles et une faible quantité d'émulsifiant. Cette invention concerne également l'utilisation de ces crèmes de coloration capillaire pour colorer les cheveux.
EP07722776A 2006-02-07 2007-01-29 Creme de coloration capillaire a base de polymeres Ceased EP1986600A2 (fr)

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EP10171543A EP2332615A1 (fr) 2006-02-07 2007-01-29 Crème de coloration capillaire à base de polymères

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DE200610005450 DE102006005450A1 (de) 2006-02-07 2006-02-07 Haar-Colorationscreme auf Polymerbasis
PCT/EP2007/000731 WO2007090534A2 (fr) 2006-02-07 2007-01-29 Crème de coloration capillaire à base de polymères

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EP1986600A2 true EP1986600A2 (fr) 2008-11-05

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