EP1973440B1 - Fermeture ignifugée - Google Patents

Fermeture ignifugée Download PDF

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Publication number
EP1973440B1
EP1973440B1 EP20060829189 EP06829189A EP1973440B1 EP 1973440 B1 EP1973440 B1 EP 1973440B1 EP 20060829189 EP20060829189 EP 20060829189 EP 06829189 A EP06829189 A EP 06829189A EP 1973440 B1 EP1973440 B1 EP 1973440B1
Authority
EP
European Patent Office
Prior art keywords
closure
flame
backing fabric
support layer
closure according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP20060829189
Other languages
German (de)
English (en)
Other versions
EP1973440A2 (fr
Inventor
Konstantinos Poulakis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gottlieb Binder GmbH and Co KG
Original Assignee
Gottlieb Binder GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE200610002339 external-priority patent/DE102006002339A1/de
Application filed by Gottlieb Binder GmbH and Co KG filed Critical Gottlieb Binder GmbH and Co KG
Priority to EP11000250.8A priority Critical patent/EP2301373B1/fr
Priority to EP20110001356 priority patent/EP2322049A3/fr
Priority to PL06829189T priority patent/PL1973440T3/pl
Publication of EP1973440A2 publication Critical patent/EP1973440A2/fr
Application granted granted Critical
Publication of EP1973440B1 publication Critical patent/EP1973440B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069Details
    • A44B18/0092Details flame retardant
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0023Woven or knitted fasteners
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069Details
    • A44B18/0073Attaching means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24008Structurally defined web or sheet [e.g., overall dimension, etc.] including fastener for attaching to external surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24008Structurally defined web or sheet [e.g., overall dimension, etc.] including fastener for attaching to external surface
    • Y10T428/24017Hook or barb
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3976Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]

Definitions

  • the invention relates to a flame-retardant closure having at least one closure part with at least one planar base fabric of warp threads and weft threads and with functional threads projecting on the front side of the base fabric, which at least partially penetrate the base fabric and form the closure elements, the base fabric being of non-flame retardant type and on its back at least partially a carrier layer having a flame retardant medium and / or having an active quenching medium.
  • Such a closure is for example made EP 1 486 606 A1 known.
  • the known closure is a textile product made of, containing and / or coated with flame retardant material.
  • the flame-retardant material contains a synthetic resin and an inorganic flame retardant dispersed in the synthetic resin.
  • In the base fabric filaments are embedded, which can form connecting hooks and connection loops of a hook and loop fastener.
  • the closure is provided over its entire surface with the carrier layer.
  • Woven adhesive closure parts whose warp, weft and functional threads may consist of textile fibers, but also of plastic or metal fibers, are freely available on the market in a large number of embodiments.
  • the functional threads form in the base fabric of warp and weft threads loop-shaped hooking elements, if they are formed from multifilament yarns. If the functional threads are formed from monofilament threads and provided that the loops closed to this effect are cut or thermally separated from one another, closure hooks which can be brought into engagement with a correspondingly formed fleece loop material of the other closure part of said fastening system are formed.
  • the pertinent closures are characterized by recurring possible opening and closing operations.
  • the EP-A-1 275 381 to coat an adhesive closure part with closure elements with a flame-retardant medium on the surface side and / or to introduce a pertinent flame-retardant medium into the closure itself.
  • a coating method a dipping method is proposed by way of example, wherein substances and substance groups are proposed as flame-retardant media, such as phosphorus, graphite, nitrogen and antimony compounds, and aluminum derivatives and hydrates.
  • the use of organic phosphorus substances is described, and for better attachment of the flame-retardant medium to the closure material, the use of a binder, for example in the form of vinyl acetate is proposed.
  • the known closure may be completely surrounded on its upper side by the flame-retardant medium or at least partially even consists of the flame-retardant medium itself, the pertinent measures are not sufficient to meet today's increased flame retardance guidelines.
  • a flame retardant fastener that is part of a releasable engagement system is adapted to a second fastener having a carrier layer of a flame-retardant polymer material, are introduced into the U-shaped brackets, the legs of which form handle portions which form at the free end and the support layer above each a closure head.
  • the thus formed closure elements as mushrooms are firmly anchored at the foot over the staple cross bar in the carrier layer and attaching the fastener to foreign parts such as vehicle components or the like is a non-flame retardant, pressure-sensitive adhesive which is applied to a support surface, the top of the support layer with the projecting mounting heads facing away from as part of the fastener.
  • the non-flame retardant, pressure-sensitive adhesive is a foam layer of a pressure-sensitive acrylic foam adhesive, adhesive constructed to this effect in the example WO-A-2005/017060 are described in more detail.
  • the pertinent solution already forms a very good-looking flame-retardant closure;
  • the known solution may be expensive to implement, especially as regards the introduction of the U-shaped fasteners in the carrier layer.
  • the present invention seeks to further improve the known solutions to the effect that a flame-retardant closure is realized, which also meets increased requirements for flame retardancy and beyond that is cost-effectively feasible.
  • This object is achieved by a flame-retardant closure having the features of patent claim 1 in its entirety.
  • the flame-retardant closure according to the invention is characterized in that the base fabric has a finish, which thus ensures the fixation of the base fabric with the individual threads.
  • the carrier layer has a connection component or a connecting part on its side facing away from the base fabric.
  • the pertinent connecting part may be formed as woven or non-woven material and allows a good connection of the closure to foreign parts such as upholstery fabrics or upholstery foam parts.
  • a conventional closure element is accordingly used, as shown by way of example in US Pat DE-B-102 40 986 the applicant is disclosed.
  • the pertinent Standard closure member is constructed of conventional plastic materials, such as polypropylene or polyamide material, which are more sensitive to heat.
  • the mentioned product is an industrial standard product that is produced in very large quantities and is cost-effective and reliable.
  • the pertinent standard closure part is now connected to a special carrier layer which is either flame-retardant and / or preferably has an active quenching substance.
  • the carrier medium to be attached rearward can be selected from its volume such that sufficient flame retardancy or extinguishing safety is ensured and yet in confined spaces, the closure can be attached well, as is the case for example is when cover fabrics are to be established on upholstery materials of passenger seats or the like.
  • the thickness of the carrier layer with the respective medium can thus correspond to the overall height of the closure part consisting of base fabric and closure elements, but also amount to a multiple thereof.
  • the carrier layer is connected to the base fabric by means of an adhesive layer.
  • the Fig. 1 shows a detail of a plan view of a sheet-like adhesive closure part, which can be arbitrarily extended within the image plane in both the one and in the other image direction, and the geometric dimensions of the fabric are dependent on the specifications of the weaving device on which the adhesive closure member is made.
  • closing parts which are used for later use are assembled in the manner of roll-bonded adhesive-fastening tapes (not shown).
  • the closure part consists of warp threads 10 and weft threads 12, which weaves in cross-arrangement with each other, the base fabric Form 14 for the adhesive closure part.
  • the base fabric 14 is provided with functional threads 16 in the form of pile threads forming another part of the base fabric.
  • the respective functional thread 16 then forms the individual closure elements 18 for the sheet-like adhesive closure part.
  • the respective weft threads 12 are arc-shaped in the manner of a sine or cosine wave, and at the intersections between warp threads 10 and weft threads 12, the warp threads 10 extend parallel to the production direction 20 and parallel to one another in a straight-line arrangement.
  • the weft threads 12 are arranged in an arcuate manner in the base fabric 14, wherein the respective weft thread 12 overlaps a warp thread 12 in an alternating sequence and engages under the row immediately following in series.
  • the advantages of a pertinent arcuate design are closer in the DE-B-102 40 986 the Applicant pointed out, so it will not be discussed in more detail here.
  • the functional thread 16 forms an overlying loop 22, wherein subsequently immediately a further loop 24 is formed, so that a type of V-binding is realized.
  • the functional thread 16 in W-shaped type or the like.
  • the said loops 22, 24 form the closure elements 18 and remain the loops 22, 24 closed as shown, thus forming a kind of Velcro-type fastener part, with hook or mushroom-like closure elements can engage in the pertinent loops 22, 24 so as to form a releasable adhesive closure as a closure or fastening system to get. But it is also possible to cut open the loops 22, 24, so that then a closure hook (not shown) is formed, which can be hooked with a corresponding nonwoven or Velcro material of another closure member not shown as the first closure part.
  • a single weft thread 12 may also consist of a weft pair or be multifilament.
  • This also applies to the warp threads 10, which according to the cross-sectional or elevational view of the Fig. 2 in each case overlap a pair of weft threads 12 of the second closure part in an alternating sequence in order subsequently to undertake an undercut of this weft thread pair 12.
  • the respective functional or pile thread 16 thereby engages with the omission of a respective pair of weft threads 12, the two successive weft pairs 12 in the row shown.
  • the thread systems may consist of textile fibers, but preferably they are formed from a plastic material, in particular nylon or polypropylene material. The pertinent choice of material already makes it clear that the basic fabric 14 easily flammable with the closure elements 18, that is just of non-flame retardant type.
  • the closure part is after the Fig. 1 provided in accordance with a carrier layer, which in the cross-sectional view of the Fig. 2 is shown.
  • the scale conditions are in the representation of the Fig. 2 not quite true, in order to clearly reproduce the layer structure to the viewer. It should also be stressed at this point that in the Fig. 1 shown construction of a closure part only represents a possible tissue forming form and that the flame-retardant closure with a variety of basic fabric structures for a closure part together with functional and pile threads would be feasible.
  • the embodiment according to the Figures 1 and 2 accordingly has more exemplary character.
  • a finish preferably polyurethane finish (PUR).
  • PUR polyurethane finish
  • the patter texture is common and is in the Fig. 2 accordingly not shown in detail.
  • an adhesive layer 30 is arranged, which need not be pressure-sensitive and preferably formed in the form of a reactive polyurethane adhesive itself need not be flame-retardant.
  • a carrier layer 32 is arranged, which preferably covers the entire substructure of the base fabric 14 and whose thickness or construction height, for example, the thickness or construction height of the base fabric 14 may substantially correspond.
  • an active extinguishing medium may preferably be provided an extinguishing gas such as nitrogen or else an extinguishing fluid such as water.
  • an extinguishing gas such as nitrogen or else an extinguishing fluid such as water.
  • an extinguishing gas such as nitrogen or else an extinguishing fluid such as water.
  • a nitrogen carrier in particular melamine comes into question and as an active extinguishing medium for the discharge of water aluminum trihydroxide (ATH), but also magnesium hydroxide (MDH).
  • ATH aluminum trihydroxide
  • MDH magnesium hydroxide
  • the carrier layer 32 additionally or alternatively includes nano-particles such as silicates or graphite, which likewise have very good extinguishing properties.
  • the carrier layer 32 consists of ammonium polyphosphates (APP), this can form an effective extinguishing foam under the influence of heat, which prevents the supply of air in the direction of the base fabric 14 with its closure elements 18 and thus suffocates a flame or a fire and effectively terminated ,
  • APP ammonium polyphosphates
  • the flame retardant medium used is halogen-free, antimony-free and free from formaldehyde. If, for special reasons, the closure part can still be made to ignite, further protective mechanisms would be conceivable, for example to replace part of the threads with carbon yarns or the like. Furthermore, as in the prior art ( EP-A-1 275 318 ) it is possible to provide the closure part or parts thereof like the closure elements with a flame retardant medium coating.
  • connection component 34 may be applied flat.
  • This may be in the form of a non-woven or woven material and is most preferably a polyester nonwoven. With the pertinent polyester nonwoven the connection of the overall closure system to other non-illustrated third-carrier components, for example in the form of a upholstery fabric or a cushioning material to a passenger seat is particularly favorable.

Landscapes

  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Glass Compositions (AREA)
  • Adhesive Tapes (AREA)
  • Graft Or Block Polymers (AREA)
  • Laminated Bodies (AREA)

Claims (8)

  1. Fermeture ignifuge comprenant au moins une partie de fermeture ayant au moins un tissu (14) de base de forme plane en fils (10) de chaîne et en fils (12) de trame et ayant des fils (16) fonctionnels en saillie du côté face du tissu, traversant au moins en partie le tissu (14) de base et formant des éléments (18) de fermeture, le tissu (14) de base étant d'un type non ignifuge et ayant sur l'envers au moins en partie une couche (32) de support ayant un milieu inflammable difficilement et/ou un milieu actif d'extinction, caractérisée en ce que le tissu (14) de base a un apprêt et en ce que la couche (32) de support a un élément (34) de liaison sur la face éloignée du tissu (14) de base.
  2. Fermeture suivant la revendication 1, caractérisée en ce que la couche (32) de support est reliée au tissu (14) de base au moyen d'une couche (30) de colle.
  3. Fermeture suivant la revendication 1 ou 2, caractérisée en ce que le tissu (14) de base a un apprêt en polyuréthane.
  4. Fermeture suivant l'une des revendications 1 à 3, caractérisée en ce que l'élément (34) de liaison est un non-tissé en polyester.
  5. Fermeture suivant l'une des revendications 1 à 4, caractérisée en ce que la matière utilisée par la couche (32) de support est choisie dans les groupes de substances suivantes .
    - phosphate d'ammonium (PA),
    - polyphosphate d'ammonium (PPA),
    - trihydroxyde d'aluminium (THA),
    - hydroxyde de magnésium (DHM),
    - bis-diphénylphosphate de résorcinol (PDP),
    - phosphore rouge (PR),
    - phosphate de tri-n-butyle (PTB),
    - phosphate de tricrésyle (PTC),
    - phosphate de triphényle (PTP),
    - mélamine.
  6. Fermeture suivant l'une des revendications 1 à 5, caractérisée en ce que le milieu actif d'extinction contient un gaz d'extinction comme de l'azote ou un fluide d'extinction comme de l'eau.
  7. Fermeture suivant l'une des revendications 1 à 6, caractérisée en ce que la couche (32) de support contient des nanoparticules comme des silicates ou du graphite.
  8. Fermeture suivant l'une des revendications 1 à 7, caractérisée en ce que la couche (32) de support forme une mousse d'extinction sous l'influence de la chaleur.
EP20060829189 2006-01-18 2006-11-30 Fermeture ignifugée Active EP1973440B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP11000250.8A EP2301373B1 (fr) 2006-01-18 2006-11-30 Fixation ignifugée
EP20110001356 EP2322049A3 (fr) 2006-01-18 2006-11-30 Fermeture ignifugée
PL06829189T PL1973440T3 (pl) 2006-01-18 2006-11-30 Zapięcie hamujące rozwój płomienia

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE202006002409U DE202006002409U1 (de) 2006-01-18 2006-01-18 Flammhemmender Verschluß
DE200610002339 DE102006002339A1 (de) 2006-01-18 2006-01-18 Flammhemmender Verschluss
PCT/EP2006/011477 WO2007082570A2 (fr) 2006-01-18 2006-11-30 Obturateur ignifuge

Related Child Applications (3)

Application Number Title Priority Date Filing Date
EP11000250.8A Division EP2301373B1 (fr) 2006-01-18 2006-11-30 Fixation ignifugée
EP20110001356 Division EP2322049A3 (fr) 2006-01-18 2006-11-30 Fermeture ignifugée
EP11000250.8 Division-Into 2011-01-14

Publications (2)

Publication Number Publication Date
EP1973440A2 EP1973440A2 (fr) 2008-10-01
EP1973440B1 true EP1973440B1 (fr) 2011-03-09

Family

ID=36314388

Family Applications (3)

Application Number Title Priority Date Filing Date
EP20110001356 Withdrawn EP2322049A3 (fr) 2006-01-18 2006-11-30 Fermeture ignifugée
EP11000250.8A Active EP2301373B1 (fr) 2006-01-18 2006-11-30 Fixation ignifugée
EP20060829189 Active EP1973440B1 (fr) 2006-01-18 2006-11-30 Fermeture ignifugée

Family Applications Before (2)

Application Number Title Priority Date Filing Date
EP20110001356 Withdrawn EP2322049A3 (fr) 2006-01-18 2006-11-30 Fermeture ignifugée
EP11000250.8A Active EP2301373B1 (fr) 2006-01-18 2006-11-30 Fixation ignifugée

Country Status (7)

Country Link
US (1) US7670663B2 (fr)
EP (3) EP2322049A3 (fr)
AT (1) ATE500761T1 (fr)
DE (2) DE202006002409U1 (fr)
ES (1) ES2589783T3 (fr)
PL (2) PL2301373T3 (fr)
WO (1) WO2007082570A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013022112A1 (de) 2013-12-27 2015-07-02 Gottlieb Binder Gmbh & Co. Kg Schwer entflammbares Verschlussteil sowie schwer entflammbare Appretur oder Beschichtung

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008059512A1 (de) * 2008-11-28 2010-06-10 Nordenia Deutschland Gronau Gmbh Verbundstoffelement für einen Klettverschluss
DE102012009250B4 (de) * 2012-04-27 2016-05-25 Bauerfeind Ag Flexibles Verschlusselement, Verschluss bestehend aus zwei Verschlusselementen sowie Verwendung mindestens eines Verschlusselements
DE102013010085A1 (de) 2013-06-10 2014-12-11 Gottlieb Binder Gmbh & Co. Kg Flächenförmiges Haftverschlussteil und Reinigungssystem mit einem solchen flächenförmigen Haftverschlussteil
US10213634B1 (en) * 2015-05-20 2019-02-26 Donald J. Maldonado Fire barrier blanket
DE102017011244A1 (de) * 2017-12-06 2019-06-06 Gottlieb Binder Gmbh & Co. Kg Haftverschlusssystem
DE102022004262A1 (de) * 2022-11-18 2024-05-23 Gottlieb Binder Gmbh & Co. Kg Sensorvorrichtung

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DE3513325A1 (de) 1985-04-13 1986-10-16 Gottlieb Binder GmbH & Co, 7038 Holzgerlingen Haftverschluss
US4824709A (en) 1988-05-24 1989-04-25 Collins & Aikman Corporation Textile product with backcoating comprising smoke suppressant and/or flame retardant intumescent particles
US5656351A (en) 1996-01-16 1997-08-12 Velcro Industries B.V. Hook and loop fastener including an epoxy binder
US5691021A (en) 1996-02-28 1997-11-25 Minnesota Mining And Manufacturing Company Flame retardant fastener and method for making the same
US20020028240A1 (en) 2000-04-17 2002-03-07 Toyohiro Sawada Timed-release compression-coated solid composition for oral administration
EP1275318A1 (fr) 2001-07-13 2003-01-15 Ykk Europe Ltd. Element de fermeture, procédé de fabrication d'un élément de fermeture ignifuge et utilisation d'un agent ignifuge
US7011724B2 (en) 2001-11-15 2006-03-14 Interface, Inc. Textile products having flame retardant properties and methods of manufacture
TW200302894A (en) 2002-02-05 2003-08-16 Y K K Corp Flame-resistance molded article and fabric product
DE10240986B3 (de) 2002-09-05 2004-02-12 Gottlieb Binder Gmbh & Co Flächenförmiges Haftverschlußteil
US20040166282A1 (en) 2003-02-20 2004-08-26 Kingsford Howard A. Woven fastener products
JP4578074B2 (ja) 2003-08-08 2010-11-10 スリーエム イノベイティブ プロパティズ カンパニー 非ハロゲン系難燃性アクリル系粘着シート又はテープ
JP4354232B2 (ja) 2003-08-29 2009-10-28 Ykk株式会社 静音面ファスナー材

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013022112A1 (de) 2013-12-27 2015-07-02 Gottlieb Binder Gmbh & Co. Kg Schwer entflammbares Verschlussteil sowie schwer entflammbare Appretur oder Beschichtung
WO2015096877A1 (fr) 2013-12-27 2015-07-02 Gottlieb Binder Gmbh & Co. Kg Élément de fermeture difficilement inflammable et apprêt ou revêtement difficilement inflammable

Also Published As

Publication number Publication date
PL1973440T3 (pl) 2011-08-31
EP2301373A3 (fr) 2015-03-25
US7670663B2 (en) 2010-03-02
EP2322049A2 (fr) 2011-05-18
PL2301373T3 (pl) 2016-12-30
EP2322049A3 (fr) 2015-03-25
ATE500761T1 (de) 2011-03-15
EP2301373A2 (fr) 2011-03-30
EP2301373B1 (fr) 2016-06-08
DE202006002409U1 (de) 2006-04-20
WO2007082570A3 (fr) 2007-10-18
WO2007082570A2 (fr) 2007-07-26
DE502006009076D1 (de) 2011-04-21
US20090036013A1 (en) 2009-02-05
ES2589783T3 (es) 2016-11-16
EP1973440A2 (fr) 2008-10-01

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