EP1806429A1 - Appareil et procédé de pulverisation à froid avec écoulement gazeux module - Google Patents
Appareil et procédé de pulverisation à froid avec écoulement gazeux module Download PDFInfo
- Publication number
- EP1806429A1 EP1806429A1 EP06000403A EP06000403A EP1806429A1 EP 1806429 A1 EP1806429 A1 EP 1806429A1 EP 06000403 A EP06000403 A EP 06000403A EP 06000403 A EP06000403 A EP 06000403A EP 1806429 A1 EP1806429 A1 EP 1806429A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cold gas
- cold
- pressure
- particle stream
- nozzle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
- B05B1/02—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape
- B05B1/08—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape of pulsating nature, e.g. delivering liquid in successive separate quantities ; Fluidic oscillators
- B05B1/083—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape of pulsating nature, e.g. delivering liquid in successive separate quantities ; Fluidic oscillators the pulsating mechanism comprising movable parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/14—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
- B05B7/1481—Spray pistols or apparatus for discharging particulate material
- B05B7/1486—Spray pistols or apparatus for discharging particulate material for spraying particulate material in dry state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B7/00—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
- B05B7/16—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
- B05B7/1606—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air
- B05B7/1613—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed
- B05B7/162—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed and heat being transferred from the atomising fluid to the material to be sprayed
- B05B7/1626—Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed and heat being transferred from the atomising fluid to the material to be sprayed at the moment of mixing
Definitions
- the invention relates to a cold gas spraying plant and a cold gas spraying process.
- the US 6,124,563 and the US Pat. No. 6,630,207 describe pulsed thermal spray processes.
- the DE 103 19 481 A1 and the WO 2003/041868 A2 describe special spray nozzle designs for the cold gas spraying process.
- the object is achieved by a cold gas spraying system according to claim 1 and a cold gas spraying method according to claim 29.
- the powder for a coating 13 is passed through a nozzle 8 onto a substrate 10, for example a component (turbine blade 120, 130, (FIG. 9, 10), combustion chamber wall 155 (FIG. 11) or a housing part (FIG. 9) of a turbine 9), so that a coating 13 forms there
- the powder comes from a powder container 16, wherein the pressure required for the cold gas spraying is generated by a high pressure gas generator 22, so that a cold gas particle stream 7 is generated by the powder
- High-pressure gas is supplied as carrier gas in the nozzle 8.
- the high-pressure gas can optionally be heated by means of a heater 19.
- the heater 19 can be integrated in the high-pressure gas generator.
- Cold spraying means that temperatures up to a maximum of 80 ° C - 550 ° C, especially 400 ° C to 550 ° C are used.
- the substrate temperature is 80 ° C to 100 ° C.
- the speeds are at 300m / s to 2000m / s.
- FIG. 2 shows a cold gas spraying installation 1 according to the invention.
- the cold gas spraying installation 1 according to the invention has one or more influencing means 25, 26, 29, 32, 35, 36, which have at least one property of the cold gas particle flow 7 (e.g. As temperature T, pressure p, particle density p, particulate material M, speed v, ...) changeable change (modulated).
- This influencing of the properties of the cold gas particle stream 7 can take place periodically or aperiodically during a coating process.
- periodic changes in coating times may be followed by aperiodic changes or vice versa.
- Preferably, only a periodic change of the one or more properties takes place.
- the influencing means may be, for example, a pulse heating means 25 which alternately, preferably pulsatingly, heats the high-pressure gas of the high-pressure gas generator and thus leads to a modulation of the cold gas particle stream 7.
- the pulse heating means 25 may also be part of the heater 19.
- a valve 32 as an influencing means in particular a perforated disc (chopper) 32 may be mounted in front of the nozzle inlet opening 8 '. Since this interrupts the cold gas particle stream 7 periodically or aperiodically, a pulsating cold gas particle stream 7 is generated in the direction of the substrate 10, which causes locally different particle densities p in the beam direction.
- the valve 32 When the valve 32 is closed, the material accumulates in front of the nozzle 8 and it builds up a higher pressure, which relaxes after opening the valve again.
- a modulated cold gas particle stream 7 can also be produced by adding the powder from the powder container 16 in changeable amounts per unit time, preferably pulsatingly, to the high-pressure gas. This can be done for example by particular piezoelectric injectors 35 as influencing means.
- the cold gas particle stream 7 can be modulated by pressure generator 29 as an influencing means, preferably by piezoelectric pressure generator 29, which are arranged at the beginning of the Laval nozzle 8 or on the nozzle 8 and change the cross section of the Laval nozzle changeable.
- the nozzle 8 may comprise a piezoelectric material or an inner piezoelectric coating which expand or contract by applying a voltage and thus change the cross section of the cold gas particle stream 7 and hence the particle density p, the pressure p and the velocity of the cold gas particle stream 7 change.
- the cold gas particle stream 7 in the region of the nozzle 8 can be influenced by an acoustic wave coupling by means of a shaft coupler 26, in particular by an ultrasound generator, which rests on the nozzle 8. These prevent any adhesion of particles in the nozzle 8.
- the high pressure gas can be controlled by a high pressure valve 36 as an influencing means.
- the high-pressure valve 36 is integrated, for example, in the high-pressure gas generator or along a line 37, which leads the gas from the high-pressure gas generator 22 to the powder.
- the influencing means 25, 26, 29, 32, 35, 36 can be used singly, paired or multiple and used.
- the material M is supplied by the or the powder injectors 35 pulse-like the cold gas particle stream 7 and the velocity v of the cold gas particle stream 7 is modulated.
- the influencing means 25, 32, 35, 36 can either be arranged only in front of the nozzle inlet opening 8 '(FIG. 7) or can be arranged only after the nozzle inlet opening 8' (FIG. 8).
- the diameter ⁇ , the temperature T and / or the pressure p can be varied changeably to influence the cold gas particle stream 7.
- the nozzle 8 can be heated to produce a constant temperature T of the cold gas particle stream 7 or to change the temperature T of the cold gas particle stream 7 changeable.
- the entire cold gas spraying system 1 can be arranged in a vacuum chamber (not shown).
- Cold spraying means that temperatures up to a maximum of 80 ° C - 550 ° C, especially 400 ° C to 550 ° C are used.
- the substrate temperature is 80 ° C to 100 ° C.
- the speeds are from 300m / s to 2000m / s, especially up to 900m / s.
- the properties of the cold gas particle stream 7 can be changed individually or together in a coating process, in particular if the change acts in the same direction, ie temperature increase and pressure increase.
- the pulsed injection of powder particles may preferably be effected by a piezoelectric powder injector 35.
- Particularly grain sizes smaller than 1 ⁇ m, preferably less than 500 nm (nanoparticles) may be sprayed with the modulated cold gas particle streams. 7
- powder injectors 35 with different powder materials M can be used to achieve graded or multiple coatings.
- metals, metal alloys, semimetals and compounds thereof as well as semiconductors, high-temperature superconductors, magnetic materials, glasses and / or ceramics can be sprayed.
- FIG. 6 shows two powder containers 16, 16 'containing different materials for the particles.
- the materials of the powder containers 16, 16 ' can be added simultaneously or only one powder container 16, 16' is active.
- the particles have different particle sizes, it makes sense to change the velocity v of the cold gas particle stream, thus z. B. the same pulse at smaller, ie lighter particles is achieved.
- two gas heaters and or two high-pressure gas generators can be used.
- FIG. 9 shows by way of example a gas turbine 100 in a longitudinal partial section.
- the gas turbine 100 has inside a rotatably mounted about a rotation axis 102 rotor 103 with a shaft 101, which is also referred to as a turbine runner.
- a compressor 105 for example, a toroidal combustion chamber 110, in particular annular combustion chamber, with a plurality of coaxially arranged burners 107, a turbine 108 and the exhaust housing 109th
- the annular combustion chamber 110 communicates with an annular annular hot gas channel 111, for example.
- Each turbine stage 112 is formed, for example, from two blade rings.
- a row 125 formed of rotor blades 120 follows.
- the guide vanes 130 are fastened to an inner housing 138 of a stator 143, whereas the moving blades 120 of a row 125 are attached to the rotor 103 by means of a turbine disk 133, for example. Coupled to the rotor 103 is a generator or work machine (not shown).
- air 105 is sucked in and compressed by the compressor 105 through the intake housing 104.
- the compressed air provided at the turbine-side end of the compressor 105 is supplied to the burners 107 where it is mixed with a fuel.
- the mixture is then burned to form the working fluid 113 in the combustion chamber 110.
- the working medium 113 flows along the hot gas channel 111 past the guide vanes 130 and the rotor blades 120.
- the working medium 113 expands in a pulse-transmitting manner, so that the rotor blades 120 drive the rotor 103 and drive the machine coupled to it.
- the components exposed to the hot working medium 113 are subject to thermal loads during operation of the gas turbine 100.
- the guide vanes 130 and rotor blades 120 of the first turbine stage 112, viewed in the flow direction of the working medium 113, are subjected to the greatest thermal stress in addition to the heat shield elements lining the annular combustion chamber 110. To withstand the prevailing temperatures, they can be cooled by means of a coolant.
- substrates of the components can have a directional structure, ie they are monocrystalline (SX structure) or have only longitudinal grains (DS structure).
- SX structure monocrystalline
- DS structure only longitudinal grains
- As a material for the components, in particular for the turbine blade 120, 130 and components of the combustion chamber 110 are For example, iron, nickel or cobalt-based superalloys used.
- Such superalloys are for example from EP 1 204 776 B1 .
- EP 1 306 454 .
- the vane 130 has a guide vane foot (not shown here) facing the inner housing 138 of the turbine 108 and a vane head opposite the vane foot.
- the vane head faces the rotor 103 and fixed to a mounting ring 140 of the stator 143.
- FIG. 10 shows a perspective view of a moving blade 120 or guide blade 130 of a turbomachine that extends along a longitudinal axis 121.
- the turbomachine may be a gas turbine of an aircraft or a power plant for power generation, a steam turbine or a compressor.
- the blade 120, 130 has along the longitudinal axis 121 consecutively a fastening region 400, a blade platform 403 adjacent thereto and an airfoil 406 and a blade tip 415.
- the blade 130 may have at its blade tip 415 another platform (not shown).
- a blade root 183 is formed, which serves for attachment of the blades 120, 130 to a shaft or a disc (not shown).
- the blade root 183 is designed, for example, as a hammer head. Other designs as Christmas tree or Schwalbenschwanzfuß are possible.
- the blade 120, 130 has a leading edge 409 and a trailing edge 412 for a medium flowing past the airfoil 406.
- blades 120, 130 for example, solid metallic materials, in particular superalloys, are used in all regions 400, 403, 406 of the blade 120, 130.
- Such superalloys are for example from EP 1 204 776 B1 .
- EP 1 306 454 .
- the blade 120, 130 can be made by a casting process, also by directional solidification, by a forging process, by a milling process or combinations thereof.
- the term generally refers to directionally solidified microstructures, which means both single crystals that have no grain boundaries or at most small angle grain boundaries, and stem crystal structures that have probably longitudinal grain boundaries but no transverse grain boundaries. These second-mentioned crystalline structures are also known as directionally solidified structures. Such methods are known from U.S. Patent 6,024,792 and the EP 0 892 090 A1 known; these writings are part of the revelation regarding the solidification process.
- the blades 120, 130 may have coatings against corrosion or oxidation, e.g. M is at least one element of the group iron (Fe), cobalt (Co), nickel (Ni), X is an active element and stands for yttrium (Y) and / or silicon and / or at least one element of the rare ones Earth, or hafnium (Hf)).
- M is at least one element of the group iron (Fe), cobalt (Co), nickel (Ni)
- X is an active element and stands for yttrium (Y) and / or silicon and / or at least one element of the rare ones Earth, or hafnium (Hf)).
- Such alloys are known from the EP 0 486 489 B1 .
- the density is preferably 95% of the theoretical density.
- thermal barrier coating which is preferably the outermost layer, and consists for example of ZrO 2 , Y 2 O 3 -ZrO 2 , ie it is not, partially or completely stabilized by yttria and / or calcium oxide and / or magnesium oxide.
- the thermal barrier coating covers the entire MCrA1X layer.
- suitable coating processes such as electron beam evaporation (EB-PVD)
- stalk-shaped grains are produced in the thermal barrier coating.
- Other coating methods are conceivable, for example atmospheric plasma spraying (APS), LPPS, VPS or CVD.
- the thermal barrier coating may have porous, micro- or macro-cracked grains for better thermal shock resistance.
- the thermal barrier coating is therefore preferably more porous than the MCrAlX layer.
- the blade 120, 130 may be hollow or solid. If the blade 120, 130 is to be cooled, it is hollow and may still film cooling holes 418 (indicated by dashed lines) on.
- FIG. 11 shows a combustion chamber 110 of the gas turbine 100.
- the combustion chamber 110 is designed, for example, as a so-called annular combustion chamber, in which a multiplicity of burners 107 arranged circumferentially about a rotation axis 102 open into a common combustion chamber space 154, which produce flames 156.
- the combustion chamber 110 is configured in its entirety as an annular structure, which is positioned around the axis of rotation 102 around.
- the combustion chamber 110 is designed for a comparatively high temperature of the working medium M of about 1000 ° C to 1600 ° C.
- the combustion chamber wall 153 is provided on its side facing the working medium M side with an inner lining formed from heat shield elements 155.
- the heat shield elements 155 are then, for example, hollow and possibly still have cooling holes (not shown) which open into the combustion chamber space 154.
- Each heat shield element 155 made of an alloy is working medium side with a particularly heat-resistant protective layer (MCrA1X layer and / or ceramic coating) or is made of high temperature resistant material (solid ceramic stones).
- M is at least one element of the group iron (Fe), cobalt (Co), nickel (Ni), X is an active element and stands for yttrium (Y) and / or silicon and / or at least one element of the rare earths, or hafnium (Hf).
- MCrA1X means: M is at least one element of the group iron (Fe), cobalt (Co), nickel (Ni), X is an active element and stands for yttrium (Y) and / or silicon and / or at least one element of the rare earths, or hafnium (Hf).
- Such alloys are known from the EP 0 486 489 B1 .
- EP 0 412 397 B1 or EP 1 306 454 A1
- a ceramic thermal barrier coating consists for example of ZrO 2 , Y 2 O 3 -ZrO 2 , ie it is not, partially or completely stabilized by yttria and / or calcium oxide and / or magnesium oxide.
- suitable coating processes such as electron beam evaporation (EB-PVD)
- stalk-shaped grains are produced in the thermal barrier coating.
- suitable coating methods are conceivable, for example atmospheric plasma spraying (APS), LPPS, VPS or CVD.
- the thermal barrier coating may have porous, micro- or macro-cracked grains for better thermal shock resistance.
- Refurbishment means that turbine blades 120, 130, heat shield elements 155 may need to be deprotected (e.g., by sandblasting) after use. This is followed by removal of the corrosion and / or oxidation layers or products. Optionally, cracks in the turbine blade 120, 130 or the heat shield element 155 are also repaired. This is followed by a re-coating of the turbine blades 120, 130, heat shield elements 155 and a renewed use of the turbine blades 120, 130 or the heat shield elements 155.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Nozzles (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT06000403T ATE400674T1 (de) | 2006-01-10 | 2006-01-10 | Kaltspritzanlage und kaltspritzverfahren mit moduliertem gasstrom |
EP06000403A EP1806429B1 (fr) | 2006-01-10 | 2006-01-10 | Appareil et procédé de pulverisation à froid avec écoulement gazeux module |
DE502006001063T DE502006001063D1 (de) | 2006-01-10 | 2006-01-10 | Kaltspritzanlage und Kaltspritzverfahren mit moduliertem Gasstrom |
RU2007100423/05A RU2426602C2 (ru) | 2006-01-10 | 2007-01-09 | Установка для холодного газового распыления и способ холодного газового распыления с модулированным газовым потоком |
US11/651,730 US7631816B2 (en) | 2006-01-10 | 2007-01-10 | Cold spraying installation and cold spraying process with modulated gas stream |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06000403A EP1806429B1 (fr) | 2006-01-10 | 2006-01-10 | Appareil et procédé de pulverisation à froid avec écoulement gazeux module |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1806429A1 true EP1806429A1 (fr) | 2007-07-11 |
EP1806429B1 EP1806429B1 (fr) | 2008-07-09 |
Family
ID=36032100
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06000403A Not-in-force EP1806429B1 (fr) | 2006-01-10 | 2006-01-10 | Appareil et procédé de pulverisation à froid avec écoulement gazeux module |
Country Status (5)
Country | Link |
---|---|
US (1) | US7631816B2 (fr) |
EP (1) | EP1806429B1 (fr) |
AT (1) | ATE400674T1 (fr) |
DE (1) | DE502006001063D1 (fr) |
RU (1) | RU2426602C2 (fr) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010003396A1 (fr) * | 2008-07-05 | 2010-01-14 | Mtu Aero Engines Gmbh | Procédé et dispositif de pulvérisation gazeuse à froid |
DE102008057159A1 (de) | 2008-11-13 | 2010-05-20 | Mtu Aero Engines Gmbh | Gasturbine |
WO2010054643A1 (fr) | 2008-11-13 | 2010-05-20 | Mtu Aero Engines Gmbh | Procédé de réparation du composant d'une turbine à gaz |
WO2011036045A1 (fr) * | 2009-09-25 | 2011-03-31 | Siemens Aktiengesellschaft | Aube pour une utilisation dans des flux diphasiques et procédé de production d'une telle aube |
WO2011057612A1 (fr) * | 2009-11-12 | 2011-05-19 | Mtu Aero Engines Gmbh | Procédé et dispositif de revêtement d'élément |
US8268237B2 (en) | 2009-01-08 | 2012-09-18 | General Electric Company | Method of coating with cryo-milled nano-grained particles |
EP2564980A3 (fr) * | 2011-08-29 | 2013-09-04 | General Electric Company | Système à l'état solide et procédé de réparation de pièces forgées |
US8544769B2 (en) | 2011-07-26 | 2013-10-01 | General Electric Company | Multi-nozzle spray gun |
CN103521404A (zh) * | 2013-10-25 | 2014-01-22 | 中国船舶重工集团公司第七二五研究所 | 一种便携式低压冷喷涂装置 |
EP2298962B1 (fr) * | 2009-07-17 | 2014-06-04 | MTU Aero Engines GmbH | Pulverisation à froid de revêtements contenant des oxydes |
WO2019180190A1 (fr) * | 2018-03-22 | 2019-09-26 | Reinhold Riemensperger | Dispositif de transport et de dosage de poudre, dispositif de fabrication d'une structure en couches sur une surface d'un élément de construction, élément chauffant plat et procédé de fabrication d'un élément chauffant plat |
EP3789516A1 (fr) * | 2019-09-09 | 2021-03-10 | Siemens Aktiengesellschaft | Installation de pulvérisation par gaz froid à rayon de particules réglable |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006117144A1 (fr) * | 2005-05-05 | 2006-11-09 | H.C. Starck Gmbh | Procede de revetement d'une surface de substrat et produit muni du revetement |
WO2008031185A1 (fr) * | 2006-09-13 | 2008-03-20 | Doben Limited | Ensemble tuyère pour système de pulvérisation dynamique à gaz froid |
US20080078268A1 (en) | 2006-10-03 | 2008-04-03 | H.C. Starck Inc. | Process for preparing metal powders having low oxygen content, powders so-produced and uses thereof |
US20080145688A1 (en) | 2006-12-13 | 2008-06-19 | H.C. Starck Inc. | Method of joining tantalum clade steel structures |
US8197894B2 (en) | 2007-05-04 | 2012-06-12 | H.C. Starck Gmbh | Methods of forming sputtering targets |
DE102008006112A1 (de) * | 2008-01-25 | 2009-07-30 | BSH Bosch und Siemens Hausgeräte GmbH | Heizeinrichtung für ein Hausgerät zur Pflege von Wäschestücken und Verfahren zum Betreiben einer derartigen Heizeinrichtung |
US8246903B2 (en) | 2008-09-09 | 2012-08-21 | H.C. Starck Inc. | Dynamic dehydriding of refractory metal powders |
DE102008058141A1 (de) * | 2008-11-20 | 2010-05-27 | Mtu Aero Engines Gmbh | Verfahren zum Herstellen einer Schaufel für einen Rotor einer Strömungsmaschine |
DE102008058142A1 (de) * | 2008-11-20 | 2010-05-27 | Mtu Aero Engines Gmbh | Verfahren zum Herstellen und/oder Reparieren eines Rotors einer Strömungsmaschine und Rotor hierzu |
US20100170937A1 (en) * | 2009-01-07 | 2010-07-08 | General Electric Company | System and Method of Joining Metallic Parts Using Cold Spray Technique |
DE102009009474B4 (de) * | 2009-02-19 | 2014-10-30 | Sulzer Metco Ag | Gasspritzanlage und Verfahren zum Gasspritzen |
DE102009048659B3 (de) * | 2009-09-29 | 2011-04-28 | Siemens Aktiengesellschaft | Transformatorkern |
JP5712054B2 (ja) * | 2011-05-31 | 2015-05-07 | 日本発條株式会社 | シャフト付きヒータユニットおよびシャフト付きヒータユニットの製造方法 |
US8734896B2 (en) | 2011-09-29 | 2014-05-27 | H.C. Starck Inc. | Methods of manufacturing high-strength large-area sputtering targets |
US9335296B2 (en) | 2012-10-10 | 2016-05-10 | Westinghouse Electric Company Llc | Systems and methods for steam generator tube analysis for detection of tube degradation |
US10441962B2 (en) | 2012-10-29 | 2019-10-15 | South Dakota Board Of Regents | Cold spray device and system |
US10099322B2 (en) * | 2012-10-29 | 2018-10-16 | South Dakota Board Of Regents | Methods for cold spray repair |
JP6122666B2 (ja) * | 2013-03-07 | 2017-04-26 | 東京エレクトロン株式会社 | ホッパー及び溶射装置 |
JP6885865B2 (ja) | 2014-04-25 | 2021-06-16 | サウス ダコタ ボード オブ リージェンツ | 大容量電極 |
JP6488559B2 (ja) * | 2014-05-30 | 2019-03-27 | 東洋製罐グループホールディングス株式会社 | 紙成形体 |
CN106414252B (zh) * | 2014-05-30 | 2019-01-25 | 东洋制罐集团控股株式会社 | 纸成型体及局部区域被覆方法和被覆装置 |
US10315218B2 (en) | 2017-07-06 | 2019-06-11 | General Electric Company | Method for repairing turbine component by application of thick cold spray coating |
JP6967954B2 (ja) * | 2017-12-05 | 2021-11-17 | 東京エレクトロン株式会社 | 排気装置、処理装置及び排気方法 |
US10468674B2 (en) | 2018-01-09 | 2019-11-05 | South Dakota Board Of Regents | Layered high capacity electrodes |
US11935662B2 (en) | 2019-07-02 | 2024-03-19 | Westinghouse Electric Company Llc | Elongate SiC fuel elements |
CA3151605C (fr) | 2019-09-19 | 2023-04-11 | Westinghouse Electric Company Llc | Appareil pour effectuer un test d'adherence in situ de depots de pulverisation a froid et procede d'utilisation |
CA3169861A1 (fr) * | 2020-02-04 | 2021-08-12 | 1188511 Canada Ltd. | Realisation d'actions sur une piece a l'aide de forces electromagnetiques |
Citations (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4142089A (en) * | 1977-03-22 | 1979-02-27 | Canadian Patents And Development Limited | Pulsed coaxial thermal plasma sprayer |
US5302414A (en) | 1990-05-19 | 1994-04-12 | Anatoly Nikiforovich Papyrin | Gas-dynamic spraying method for applying a coating |
EP0486489B1 (fr) | 1989-08-10 | 1994-11-02 | Siemens Aktiengesellschaft | Revetement anticorrosion resistant aux temperatures elevees, notamment pour elements de turbines a gaz |
EP0412397B1 (fr) | 1989-08-10 | 1998-03-25 | Siemens Aktiengesellschaft | Revêtement protecteur contenant du rhénium possédant une résistance plus grande à la corrosion et l'oxydation |
EP0892090A1 (fr) | 1997-02-24 | 1999-01-20 | Sulzer Innotec Ag | Procédé de fabrication de structure smonocristallines |
EP0786017B1 (fr) | 1994-10-14 | 1999-03-24 | Siemens Aktiengesellschaft | Couche de protection de pieces contre la corrosion, l'oxydation et les contraintes thermiques excessives, et son procede de production |
WO1999067435A1 (fr) | 1998-06-23 | 1999-12-29 | Siemens Aktiengesellschaft | Alliage a solidification directionnelle a resistance transversale a la rupture amelioree |
US6024792A (en) | 1997-02-24 | 2000-02-15 | Sulzer Innotec Ag | Method for producing monocrystalline structures |
WO2000044949A1 (fr) | 1999-01-28 | 2000-08-03 | Siemens Aktiengesellschaft | Superalliage a base de nickel presentant une bonne usinabilite |
US6124563A (en) | 1997-03-24 | 2000-09-26 | Utron Inc. | Pulsed electrothermal powder spray |
EP1132497A1 (fr) | 1998-11-05 | 2001-09-12 | Jury Veniaminovich Dikun | Procede de production d'un revetement se composant de materiaux en poudre et dispositif de mise en oeuvre de ce procede |
US6502767B2 (en) | 2000-05-03 | 2003-01-07 | Asb Industries | Advanced cold spray system |
EP1306454A1 (fr) | 2001-10-24 | 2003-05-02 | Siemens Aktiengesellschaft | Revêtement protecteur contenant du rhénium pour la protection d'un élément contre l'oxydation et la corrosion aux températures élevées |
WO2003041868A2 (fr) | 2001-05-29 | 2003-05-22 | Linde Aktiengesellschaft | Procede et dispositif de projection par gaz froid |
EP1319729A1 (fr) | 2001-12-13 | 2003-06-18 | Siemens Aktiengesellschaft | Pièce résistante à des températures élevées réalisé en superalliage polycristallin ou monocristallin à base de nickel |
US6630207B1 (en) | 2001-07-17 | 2003-10-07 | Science Applications International Corporation | Method and apparatus for low-pressure pulsed coating |
US20040037954A1 (en) | 2002-06-04 | 2004-02-26 | Linde Aktiengesellschaft | Process and device for cold gas spraying |
EP0924315B1 (fr) | 1997-12-18 | 2004-03-10 | Linde AG | Production de gaz chaud pour la pulvérisation thermique |
EP1204776B1 (fr) | 1999-07-29 | 2004-06-02 | Siemens Aktiengesellschaft | Piece resistant a des temperatures elevees et son procede de production |
DE10319481A1 (de) | 2003-04-30 | 2004-11-18 | Linde Ag | Lavaldüse für das thermische Spritzen und das kinetische Spritzen |
WO2005061116A1 (fr) * | 2003-12-24 | 2005-07-07 | Research Institute Of Industrial Science & Technology | Appareil de pulverisation de liquide refroidisseur presentant un dispositif de prechauffage de poudre |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070098912A1 (en) * | 2005-10-27 | 2007-05-03 | Honeywell International, Inc. | Method for producing functionally graded coatings using cold gas-dynamic spraying |
-
2006
- 2006-01-10 DE DE502006001063T patent/DE502006001063D1/de active Active
- 2006-01-10 EP EP06000403A patent/EP1806429B1/fr not_active Not-in-force
- 2006-01-10 AT AT06000403T patent/ATE400674T1/de not_active IP Right Cessation
-
2007
- 2007-01-09 RU RU2007100423/05A patent/RU2426602C2/ru not_active IP Right Cessation
- 2007-01-10 US US11/651,730 patent/US7631816B2/en not_active Expired - Fee Related
Patent Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4142089A (en) * | 1977-03-22 | 1979-02-27 | Canadian Patents And Development Limited | Pulsed coaxial thermal plasma sprayer |
EP0486489B1 (fr) | 1989-08-10 | 1994-11-02 | Siemens Aktiengesellschaft | Revetement anticorrosion resistant aux temperatures elevees, notamment pour elements de turbines a gaz |
EP0412397B1 (fr) | 1989-08-10 | 1998-03-25 | Siemens Aktiengesellschaft | Revêtement protecteur contenant du rhénium possédant une résistance plus grande à la corrosion et l'oxydation |
US5302414A (en) | 1990-05-19 | 1994-04-12 | Anatoly Nikiforovich Papyrin | Gas-dynamic spraying method for applying a coating |
US5302414B1 (en) | 1990-05-19 | 1997-02-25 | Anatoly N Papyrin | Gas-dynamic spraying method for applying a coating |
EP0786017B1 (fr) | 1994-10-14 | 1999-03-24 | Siemens Aktiengesellschaft | Couche de protection de pieces contre la corrosion, l'oxydation et les contraintes thermiques excessives, et son procede de production |
US6024792A (en) | 1997-02-24 | 2000-02-15 | Sulzer Innotec Ag | Method for producing monocrystalline structures |
EP0892090A1 (fr) | 1997-02-24 | 1999-01-20 | Sulzer Innotec Ag | Procédé de fabrication de structure smonocristallines |
US6124563A (en) | 1997-03-24 | 2000-09-26 | Utron Inc. | Pulsed electrothermal powder spray |
EP0924315B1 (fr) | 1997-12-18 | 2004-03-10 | Linde AG | Production de gaz chaud pour la pulvérisation thermique |
WO1999067435A1 (fr) | 1998-06-23 | 1999-12-29 | Siemens Aktiengesellschaft | Alliage a solidification directionnelle a resistance transversale a la rupture amelioree |
EP1132497A1 (fr) | 1998-11-05 | 2001-09-12 | Jury Veniaminovich Dikun | Procede de production d'un revetement se composant de materiaux en poudre et dispositif de mise en oeuvre de ce procede |
WO2000044949A1 (fr) | 1999-01-28 | 2000-08-03 | Siemens Aktiengesellschaft | Superalliage a base de nickel presentant une bonne usinabilite |
EP1204776B1 (fr) | 1999-07-29 | 2004-06-02 | Siemens Aktiengesellschaft | Piece resistant a des temperatures elevees et son procede de production |
US6502767B2 (en) | 2000-05-03 | 2003-01-07 | Asb Industries | Advanced cold spray system |
WO2003041868A2 (fr) | 2001-05-29 | 2003-05-22 | Linde Aktiengesellschaft | Procede et dispositif de projection par gaz froid |
US6630207B1 (en) | 2001-07-17 | 2003-10-07 | Science Applications International Corporation | Method and apparatus for low-pressure pulsed coating |
EP1306454A1 (fr) | 2001-10-24 | 2003-05-02 | Siemens Aktiengesellschaft | Revêtement protecteur contenant du rhénium pour la protection d'un élément contre l'oxydation et la corrosion aux températures élevées |
EP1319729A1 (fr) | 2001-12-13 | 2003-06-18 | Siemens Aktiengesellschaft | Pièce résistante à des températures élevées réalisé en superalliage polycristallin ou monocristallin à base de nickel |
US20040037954A1 (en) | 2002-06-04 | 2004-02-26 | Linde Aktiengesellschaft | Process and device for cold gas spraying |
DE10319481A1 (de) | 2003-04-30 | 2004-11-18 | Linde Ag | Lavaldüse für das thermische Spritzen und das kinetische Spritzen |
WO2005061116A1 (fr) * | 2003-12-24 | 2005-07-07 | Research Institute Of Industrial Science & Technology | Appareil de pulverisation de liquide refroidisseur presentant un dispositif de prechauffage de poudre |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010003396A1 (fr) * | 2008-07-05 | 2010-01-14 | Mtu Aero Engines Gmbh | Procédé et dispositif de pulvérisation gazeuse à froid |
DE102008057159A1 (de) | 2008-11-13 | 2010-05-20 | Mtu Aero Engines Gmbh | Gasturbine |
WO2010054643A1 (fr) | 2008-11-13 | 2010-05-20 | Mtu Aero Engines Gmbh | Procédé de réparation du composant d'une turbine à gaz |
DE102008057162A1 (de) | 2008-11-13 | 2010-05-20 | Mtu Aero Engines Gmbh | Verfahren zur Reparatur des Bauteils einer Gasturbine |
US8268237B2 (en) | 2009-01-08 | 2012-09-18 | General Electric Company | Method of coating with cryo-milled nano-grained particles |
EP2298962B1 (fr) * | 2009-07-17 | 2014-06-04 | MTU Aero Engines GmbH | Pulverisation à froid de revêtements contenant des oxydes |
WO2011036045A1 (fr) * | 2009-09-25 | 2011-03-31 | Siemens Aktiengesellschaft | Aube pour une utilisation dans des flux diphasiques et procédé de production d'une telle aube |
WO2011057612A1 (fr) * | 2009-11-12 | 2011-05-19 | Mtu Aero Engines Gmbh | Procédé et dispositif de revêtement d'élément |
US9040116B2 (en) | 2009-11-12 | 2015-05-26 | Mtu Aero Engines Gmbh | Method and device for coating components |
US8544769B2 (en) | 2011-07-26 | 2013-10-01 | General Electric Company | Multi-nozzle spray gun |
EP2564980A3 (fr) * | 2011-08-29 | 2013-09-04 | General Electric Company | Système à l'état solide et procédé de réparation de pièces forgées |
CN103521404A (zh) * | 2013-10-25 | 2014-01-22 | 中国船舶重工集团公司第七二五研究所 | 一种便携式低压冷喷涂装置 |
CN103521404B (zh) * | 2013-10-25 | 2015-12-02 | 中国船舶重工集团公司第七二五研究所 | 一种便携式低压冷喷涂装置 |
WO2019180190A1 (fr) * | 2018-03-22 | 2019-09-26 | Reinhold Riemensperger | Dispositif de transport et de dosage de poudre, dispositif de fabrication d'une structure en couches sur une surface d'un élément de construction, élément chauffant plat et procédé de fabrication d'un élément chauffant plat |
EP3789516A1 (fr) * | 2019-09-09 | 2021-03-10 | Siemens Aktiengesellschaft | Installation de pulvérisation par gaz froid à rayon de particules réglable |
WO2021047855A1 (fr) * | 2019-09-09 | 2021-03-18 | Siemens Aktiengesellschaft | Système de pulvérisation de gaz froid ayant un jet de particules réglable |
CN114375350A (zh) * | 2019-09-09 | 2022-04-19 | 西门子股份公司 | 带有可调节粒子射束的冷气喷射设备 |
Also Published As
Publication number | Publication date |
---|---|
RU2426602C2 (ru) | 2011-08-20 |
EP1806429B1 (fr) | 2008-07-09 |
RU2007100423A (ru) | 2008-08-10 |
ATE400674T1 (de) | 2008-07-15 |
DE502006001063D1 (de) | 2008-08-21 |
US7631816B2 (en) | 2009-12-15 |
US20070187525A1 (en) | 2007-08-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1806429B1 (fr) | Appareil et procédé de pulverisation à froid avec écoulement gazeux module | |
EP1971443B1 (fr) | Ensemble de buses et procédé de projection par gaz froid | |
EP1845171B1 (fr) | Utilisation de poudres métalliques ayant des particles de taille diverse pour fabriquer un système de couches | |
EP2436798B1 (fr) | Matériel de masquage, couche de masquage et procédé de masquage d'un substrat | |
EP2143520A1 (fr) | Méthode de fabrication d'un trou | |
EP1974071B1 (fr) | Élément à disposer dans un canal d'écoulement d'une turbomachine et procédé de pulvérisation pour réaliser un revêtement | |
WO2006061267A1 (fr) | Systeme stratifie, utilisation et procede de realisation d'un systeme stratifie | |
EP1952931A1 (fr) | Mechtrode ayant une alimentation en poudre et procédé d'utilisation de cette mechtrode | |
EP1816222A1 (fr) | Système de revêtements de couches métalliques protectrices à double couche | |
EP1816316B1 (fr) | Procédé de réparation de composants | |
EP1941965A1 (fr) | Réouverture de trous à l'aide de la thermographie et d'un composant | |
EP1839801A1 (fr) | Méthode de réparation pour la remise en état de pièces | |
EP2224039A1 (fr) | Revêtement doté d'un procédé de revêtement thermique et non thermique | |
EP1707651A1 (fr) | Système de revêtement et procédé de fabrication d'une système de revêtement | |
EP1666625A1 (fr) | Procédé de revêtement d'un composant a l'interieur d'un aparat | |
EP1681374B1 (fr) | Système de revêtement comprenant une couche barrière et procédé de fabrication | |
EP1806426A1 (fr) | Dispositf de fixation pour composants métalliques d'une turbine | |
EP2341165A1 (fr) | Élément de construction ceramique, massique ou revêmtement céramique ayant une haute porositée, leur utilisation et élément de construction comportant ladite revêtement | |
EP1586675B1 (fr) | Procédé de revêtement de l'intérieur d'un corps creux | |
EP1674193A1 (fr) | Procédé de fabrication d'un trou | |
EP1867749A1 (fr) | Procédé de revêtement d'un matériau à une pièce | |
EP1812186A2 (fr) | Procédé et pièce de coulée | |
EP1772533A1 (fr) | Appareil pour revêter des surfaces interieures, retort et methode pour l'application du tel revêtement | |
EP1932935A1 (fr) | Procédé de fabrication d'une aube de turbine avec une couche d'oxide, une aube de turbine et son utilisation, et procédé de fonctionnement d'une turbine | |
EP1818419A1 (fr) | Alliage, couche de protection et composant |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA HR MK YU |
|
17P | Request for examination filed |
Effective date: 20070720 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
AKX | Designation fees paid |
Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: SIEMENS SCHWEIZ AG Ref country code: CH Ref legal event code: EP |
|
REF | Corresponds to: |
Ref document number: 502006001063 Country of ref document: DE Date of ref document: 20080821 Kind code of ref document: P |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081109 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081009 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081020 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081209 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PCAR Free format text: SIEMENS SCHWEIZ AG;INTELLECTUAL PROPERTY FREILAGERSTRASSE 40;8047 ZUERICH (CH) |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
26N | No opposition filed |
Effective date: 20090414 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081009 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090131 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090110 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081010 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090110 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20090110 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080709 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20130318 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20130415 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20140103 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20140115 Year of fee payment: 9 Ref country code: IT Payment date: 20140130 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20140110 Year of fee payment: 9 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 502006001063 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 502006001063 Country of ref document: DE Effective date: 20140801 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140131 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140801 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140131 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20150801 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20150110 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150801 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150110 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20150930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150202 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150110 |