EP1796620A1 - Lichtschutzemulsion mit hohem anteil an lichtschutzfilterpigmenten - Google Patents
Lichtschutzemulsion mit hohem anteil an lichtschutzfilterpigmentenInfo
- Publication number
- EP1796620A1 EP1796620A1 EP05789814A EP05789814A EP1796620A1 EP 1796620 A1 EP1796620 A1 EP 1796620A1 EP 05789814 A EP05789814 A EP 05789814A EP 05789814 A EP05789814 A EP 05789814A EP 1796620 A1 EP1796620 A1 EP 1796620A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pigments
- weight
- organic
- cosmetic
- sun protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/496—Triazoles or their condensed derivatives, e.g. benzotriazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4966—Triazines or their condensed derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
Definitions
- the present invention relates to a cosmetic sunscreen emulsion containing UV sunscreen filter pigments in a concentration of at least 20% by weight, based on the total weight of the preparation.
- UVA and UVB filters are summarized in most industrialized countries in the form of positive lists such as Appendix 7 of the German Cosmetics Regulation.
- a special form of UV sunscreen filter substances are the micropigments.
- the UV protection effect of the micropigments is based on the physical effects of reflection and light scattering.
- cosmetic preparations are used as micropigments almost exclusively inorganic micropigments of titanium dioxide, zinc oxide or mixed oxides with, for example, iron oxides.
- the advantages of micropigments as UV filter substance in cosmetic preparations are mainly due to the fact that the pigments, in contrast to dissolved or liquid, do not penetrate into the skin. The occurrence of allergic reactions is excluded.
- micropigments are difficult to incorporate stable in cosmetic preparations.
- concentrations concentration above 7% by weight, based on the total weight of the preparation
- they form pigment agglomerates which precipitate out of the preparation relatively quickly.
- the storage stability is therefore low.
- the object of the present invention to overcome the deficiencies of the prior art and to develop stable emulsions with a high content of micropigments as UV light protection filters.
- the formulations should also have a stable absorption spectrum with a balanced UV-A / UV-B absorption balance when applied to the skin over a prolonged period of use.
- the weight ratio of inorganic to organic UV photoprotective pigments is preferably from 3: 1 to 1: 3.
- the organic sunscreen filter pigments are selected from the group 2 J 2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1, 1 J 3 J 3-tetramethylbutyl) -phenol) J
- the micropigments according to the invention may advantageously be present in an aqueous dispersion.
- C8-C16 alkylpolyglucoside amphiphilic polymers, as described in EP 1093796 B1, can be advantageously used according to the invention as a dispersing aid.
- Advantageous embodiments of the present invention contain the organic sunscreen filter pigments in a concentration of 1 to 20% by weight, based on the total weight of the preparation.
- Preferred embodiments of the present invention contain the organic sunscreen filter pigments in a concentration of 2 to 15% by weight, based on the total weight of the preparation.
- Preferred inorganic pigments are metal oxides and / or other sparingly soluble or insoluble metal compounds in water, in particular oxides of titanium (TiO 2 ), zinc (ZnO), iron (eg Fe 2 O 3 ), zirconium (ZrO 2 ), Silicon (SiO 2 ), manganese (for example MnO), aluminum (Al 2 O 3 ), cerium (for example Ce 2 O 3 ), mixed oxides of the corresponding metals and mixtures of such oxides, and also the sulfate of barium (BaSO 4 ).
- the titanium dioxide pigments can be present both in the rutile and anatase crystal modifications and can advantageously be surface-treated ("coated") for the purposes of the present invention, with a hydrophilic, amphiphilic or hydrophobic character, for example, being preferred. be formed or should remain preserved character.
- This surface treatment may consist in providing the pigments with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer by processes known per se.
- the various surface coating can also contain water for the purposes of the present invention.
- Coated and uncoated titanium dioxides described in the present invention can also be used in the form of commercially available oily or aqueous predispersions. Dispersants and / or solubilizers may advantageously be added to these predispersions.
- the titanium dioxides according to the invention are distinguished by a primary particle size of between 10 nm and 200 nm, particle sizes of from 10 nm to 100 nm being preferred according to the invention.
- titanium dioxides are the MT-100 Z and MT-100 TV from Tayca Corporation, Eusolex T-2000 and Eusolex T-AVO from Merck and the titanium dioxide T 805 from Degussa and the iron / titanium mixed oxide titanium dioxide T817 from Degussa ,
- zinc oxides can also be used in the form of commercially available oily or aqueous predispersions.
- Zinc oxide particles and predispersions of zinc oxide particles which are suitable according to the invention are distinguished by a primary particle size of ⁇ 300 nm and can be obtained from the following companies under the following trade names:
- the concentration of inorganic light protection pigments in the preparation is from 1 to 30% by weight and preferably from 2 to 15% by weight, based in each case on the total weight of the preparation.
- Advantageous further UV filter substances in the sense of the present invention are, for example, those mentioned below which may be present in the water phase and / or the oil phase.
- UV filter substances which are liquid at room temperature for the purposes of the present invention are homomenthyl salicylate (INCI: homosalates), 2-ethylhexyl 2-hydroxybenzoate (2-ethylhexyl salicylate, octyl salicylate, INCI: octyl salicylates), 2-ethylhexyl-2-cyano-3, 3-diphenyl acrylate (INCI: Octocrylene) and esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: octyl methoxycinnamate) and 4-methoxycinnamic acid isopentyl ester (isopentyl 4-methoxycinnamate, INCI: isoamyl p-methoxycinnamate), 3- (4- (2,2-bise
- UV-A filter substances for the purposes of the present invention are dibenzoyl methane derivatives, in particular 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS No. 70356-09-1), which has been sold by Givaudan under the trademark Parsol ® 1789 and sold by Merck under the trade name Eusolex® 9020.
- UV-A filter substances in the context of the present invention are hydroxybenzophenones, which are distinguished by the following structural formula:
- Cycloalkenyl wherein the substituents R 1 and R 2 together with the nitrogen atom to which they - R 1 and R 2 are independently hydrogen, Ci-C 2 -alkyl, C 3 -C 0 cycloalkyl or C 3 -C 0 are bonded, can form a 5- or 6-membered ring and R 3 is a C 1 -C 20 -alkyl radical.
- a particularly advantageous hydroxybenzophenone in the context of the present invention is 2- (4'-diethylamino-2 1 -hydroxybenzoyl) -benzoic acid hexyl ester (also: aminobenzophenone), which has the following structure:
- UV filter substances in the context of the present invention are sulfonated, water-soluble UV filters, such as. B .:
- Benzene-1,4-di (2-oxo-3-bomylidenemethyl-10-sulfonic acid) becomes.
- Benzene-1,4-di (2-oxo-3-bornylidenemethyl-10-sulfonic acid) has the INCI name Terephtalidene Dicampher sulfonic acid (CAS No. 90457-82-2) and is, for example, under the trade name
- UV filter substances for the purposes of the present invention are also so-called broadband filters, ie filter substances which absorb both UV-A and UV-B radiation.
- An advantageous broadband filter for the purposes of the present invention is also the 2,2'-methyl-bis- (6- (2H-benzotriazol-2-yl) -4- (1, 1 J 3 J 3-tetramethylbutyl) phenol ) J which is available under the trade name Tinosorb® M from CIBA-Chemikalien GmbH.
- Advantageous broadband filter for the purposes of the present invention is also the 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-i - [(trimethylsilyl) oxy] disiloxanyl] propyl] phenol (CAS No .: 155633-54-8) with the INCI name Drometrizole Trisiloxanes.
- the other UV filter substances can be oil-soluble or water-soluble.
- Advantageous oil-soluble filter substances are z. B .:
- 4-aminobenzoic acid derivatives preferably (2-ethylhexyl) 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
- Esters of benzalmalonic acid preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
- Dioctylbutylamidotriazone (INCI: diethylhexyl butamido triazone), which is available under the trade name UVASORB HEB from Sigma 3V;
- Esters of cinnamic acid preferably 4-methoxycinnamic acid (2-ethylhexyl) ester 1 4-methoxycinnamic acid isopentyl ester;
- UV filter substances are: Phenylene-1 J 4-bis (2-benzimidazyl) -3,3'-5 J 5'-tetrasulfonic acid bis-natrium salt (INCI: bisimidazylate, trade name: Neoheliopan AP),
- the oil phase of the preparations according to the invention is advantageously selected from the group of polar lipids having a polarity ⁇ 35 mN / m.
- Particularly advantageous lipids in the context of the present invention are all native lipids, such as. As olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, thistle oil, evening primrose oil, macadamia nut oil, corn oil, avocado oil and the like, and those listed below.
- hydrocarbons in particular paraffin oil and further hydrogenated poly olefins such as hydrogenated polyisobutenes, squalane and squalene are to be used advantageously in the context of the present invention.
- the oil phase of the preparations according to the present invention may optionally be advantageous, although it is not mandatory, if the oil phase of the preparations according to the present invention also contains non-polar lipids.
- the aqueous phase of the preparations according to the invention may advantageously comprise customary cosmetic adjuvants, for example alcohols, in particular those of low C number, preferably ethanol and / or isopropanol, diols or polyols of low C number and their ethers, preferably propylene glycol, glycerol, ethylene glycol, Propanediol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, polymers, foam stabilizers, electrolytes, self-tanning agents, and in particular one or more thickeners, which are advantageously chosen can be selected from the group silicon dioxide, aluminum silicates,
- the cosmetic preparations according to the invention can be composed as usual. Particularly advantageous in the context of the present invention are preparations for the care of the skin: they can be used for cosmetic sunscreen, for cleaning or care of the skin and / or hair and as a make-up product in decorative cosmetics. A further advantageous embodiment of the present invention is Af ter-Sun products.
- the cosmetic preparations according to the invention are applied to the skin and / or the hair in a sufficient amount in the manner customary for cosmetics.
- the cosmetic preparations according to the invention may contain cosmetic adjuvants, such as are commonly used in such preparations, for.
- Advantageous preservatives for the purposes of the present invention are, for example, formaldehyde releasers (such as, for example, DMDM hydantoin, which is available under the trade name Glydant TM from Lonza), iodopropyl butylcarbamates (for example those sold under the trade names Glycacil-L, Glycacil -S. From the company.
- formaldehyde releasers such as, for example, DMDM hydantoin, which is available under the trade name Glydant TM from Lonza
- iodopropyl butylcarbamates for example those sold under the trade names Glycacil-L, Glycacil -S. From the company.
- the preserving system also advantageously also includes preserving aids, such as, for example, ethylhexylglycerol, glycine soya, etc.
- Advantageous complexing agents for the purposes of the present invention are, for example, EDTA, [S, S] -ethylenediamine disuccinate (EDDS), which is obtainable, for example, under the trade name Octaquest from the company Octel, pentasodium ethylenediamine tetramethylenephosphonate, which, for example, B. under the trade name Dequest 2046 from the company.
- Monsanto is available and / or iminodisuccinic, which among other things from the company.
- Bayer AG under the trade name Iminodisuccinat VP OC 370 (about 30% solution) and Baypure CX 100 is permanently available.
- Particularly advantageous preparations are also obtained when antioxidants are used as additives or active substances.
- the preparations advantageously contain one or more antioxidants. All antioxidants which are suitable or customary for cosmetic applications can be used as inexpensive but nevertheless optional antioxidants.
- water-soluble Antioxi ⁇ dantien can be used, such as vitamins, eg. As ascorbic acid and its derivatives.
- antioxidants are vitamin E and its derivatives as well as vitamin A and its derivatives.
- the amount of antioxidants (one or more compounds) in the preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20% by weight, in particular from 0.1 to 10% by weight, based on the total weight of the preparation.
- vitamin E and / or its derivatives are the antioxidant (s), it is advantageous to choose their respective concentrations from the range from 0.001 to 10% by weight, based on the total weight of the formulation.
- vitamin A or vitamin A derivatives, or carotenes or derivatives thereof are the antioxidant (s), it is advantageous if their respective concentrations are in the range from 0.001 to 10% by weight, based on the total weight of the formulation choose.
- the cosmetic preparations according to the present invention contain cosmetic active ingredients, preferred active substances being antioxidants which can protect the skin against oxidative stress.
- active ingredients in the context of the present invention are natural active substances and / or their derivatives, such as.
- 1, 16-dicarboxylic acid dioic acid, CAS number 20701-68-2, provisional INCI name octadecenedioic acid
- licochalcone A 1, 16-dicarboxylic acid (dioic acid, CAS number 20701-68-2, provisional INCI name octadecenedioic acid) and / or licochalcone A.
- Licochalcone can also be used advantageously as a constituent of herbal extracts, in particular of aqueous radix Glycyrrhizae inflatae.
- the cosmetic preparations contain 0.001 to 10% by weight, in particular 0.05 to 5% by weight, very particularly 0.01 to 2% by weight of an extract of Radix Glycyrrhizae inflatae, in each case on the total weight of the preparation.
- Inventive formulations which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially ⁇ -glycosyl rutin), coenzyme Q10, vitamin E and / or derivatives and the like, are particularly advantageous for protection against aesthetically unattractive skin lesions, as z. Skin aging (such as dryness, roughness, dryness wrinkles, itching, decreased refatting (eg, after washing), visible vascular dilation (telangiectasia, cuperosis), slackness and wrinkle and wrinkle formation, localized hypersensitivity). , Hypo and false pigmentation (eg, age spots), increased susceptibility to mechanical stress (eg, cracking), and the like). Furthermore, they are advantageously suitable against the appearance of dry or rough skin.
- flavone glycosides especially ⁇ -glycosyl rutin
- coenzyme Q10 vitamin E and / or derivatives and the like
- the preparations according to the present invention can also advantageously contain self-tanning substances, for example dihydroxyacetone and / or melanin derivatives in concentrations of from 1% by weight to 8% by weight, based on the total weight of the preparation.
- self-tanning substances for example dihydroxyacetone and / or melanin derivatives in concentrations of from 1% by weight to 8% by weight, based on the total weight of the preparation.
- the preparations according to the present invention may also contain repellents for protection against mosquitoes, ticks and spiders and the like.
- repellents for protection against mosquitoes, ticks and spiders and the like.
- N N-diethyl-3-methylbenzamide (trade name: meta-delphene, "DEET"), dimethyl phthalate (trade name: palatinol M, DMP), 1-piperidinecarboxylic acid 2- (2-hydroxyethyl) -1-methylpropyl ester, and especially 3- (Nn-butyl-N-acetyl-amino) -propionic acid ethyl ester (available from Merck under the tradename Insekt Repellent® 3535.)
- the repellents can be used either individually or in combination.
- moisturizers for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, methylpropanediol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea.
- polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gellable polysaccharides.
- the cosmetic preparations according to the invention may also advantageously, although not necessarily, contain fillers which are e.g. B. further improve the sensory and cosmetic properties of the formulations and, for example, cause or enhance a velvety or silky feel on the skin.
- Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as, for example, tapioca starch, distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), pigments which have neither mainly UV filter nor coloring action (such as, for example, US Pat. B. boron nitride etc.) and / or Aerosils ® (CAS no.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Biophysics (AREA)
- Biotechnology (AREA)
- General Engineering & Computer Science (AREA)
- Medical Informatics (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Pharmacology & Pharmacy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200410047288 DE102004047288B4 (de) | 2004-09-27 | 2004-09-27 | Lichtschutzemulsion mit hohem Anteil an Lichtschutzfilterpigmenten |
PCT/EP2005/054780 WO2006035000A1 (de) | 2004-09-27 | 2005-09-23 | Lichtschutzemulsion mit hohem anteil an lichtschutzfilterpigmenten |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1796620A1 true EP1796620A1 (de) | 2007-06-20 |
Family
ID=35457740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05789814A Ceased EP1796620A1 (de) | 2004-09-27 | 2005-09-23 | Lichtschutzemulsion mit hohem anteil an lichtschutzfilterpigmenten |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1796620A1 (de) |
DE (1) | DE102004047288B4 (de) |
WO (1) | WO2006035000A1 (de) |
Families Citing this family (155)
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FR2918269B1 (fr) | 2007-07-06 | 2016-11-25 | Oreal | Composition de protection solaire contenant l'association d'un polymere semi-cristallin et de particules de latex creuses. |
FR2918561B1 (fr) | 2007-07-09 | 2009-10-09 | Oreal | Utilisation pour la coloration de la peau de l'acide dehydroascorbique ou des derives polymeres ; procedes de soin et/ou de maquillage. |
FR2918563B1 (fr) | 2007-07-12 | 2009-12-04 | Oreal | Composition photoprotectrice fluide aqueuse a base d'un polymere polyamide a terminaison amide tertiaire. |
DE102007038414A1 (de) | 2007-08-09 | 2009-02-12 | Beiersdorf Ag | Neue kosmetische Emulgatorkombination |
KR20100063096A (ko) * | 2007-08-30 | 2010-06-10 | 바스프 에스이 | 미용 조성물의 안정화 |
ES2929612T3 (es) * | 2007-12-14 | 2022-11-30 | Basf Se | Composiciones de pantalla solar que contienen pigmentos de color |
LT2092930T (lt) * | 2008-02-22 | 2017-04-10 | Stada Arzneimittel Ag | Apsauginis preparatas nuo saulės emulsijos aliejus/vandenyje pavidale, pasižymintis saulės blokavimo faktoriumi _> 50 |
DE102008021631A1 (de) † | 2008-04-25 | 2009-10-29 | Beiersdorf Ag | Lichtschutzfilterkombination mit 2,4,6-Tris-(biphenyl)-1,3,5-triazin |
FR2931064B1 (fr) | 2008-05-14 | 2010-08-13 | Oreal | Composition cosmetique contenant un derive de dibenzoylmethane et un derive de pyrrolidinone; procede de photostabilisation du derive de dibenzoylmethane |
DE102008028664A1 (de) | 2008-06-09 | 2009-12-10 | Beiersdorf Ag | Sonnenschutzmittel mit hohem UV-A-Schutz |
FR2933614B1 (fr) | 2008-07-10 | 2010-09-10 | Oreal | Kit de protection solaire. |
FR2936146B1 (fr) | 2008-09-24 | 2010-10-08 | Oreal | Utilisations de composes dithiolanes pour la photoprotection de la peau ; nouveaux composes dithiolanes ; compositions les contenant. |
FR2936706B1 (fr) | 2008-10-08 | 2010-12-17 | Oreal | Composition cosmetique contenant un derive de dibenzoylmethane et un compose dithiolane ; procede de photostabilisation du derive de dibenzoylmethane |
FR2939036B1 (fr) | 2008-12-01 | 2010-12-17 | Oreal | Procede de coloration artificielle de la peau utilisant un melange de carotenoide et de colorant vert lidophile ; nouveau melange de colorants lipophiles ; composition |
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FR2939315B1 (fr) | 2008-12-08 | 2011-01-21 | Oreal | Composition cosmetique contenant un derive de dibenzoylmethane et un compose ester de 2-pyrrolidinone 4-carboxy ; procede de photostabilisation du derive de dibenzoylmethane |
FR2940613B1 (fr) | 2008-12-30 | 2012-09-21 | Oreal | Association de monosaccharides avec des filtres solaires et son utilisation en cosmetique |
FR2947724B1 (fr) | 2009-07-10 | 2012-01-27 | Oreal | Materiau composite comprenant des filtres uv et des particules plasmoniques et utilisation en protection solaire |
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JP5792170B2 (ja) | 2009-08-28 | 2015-10-07 | ロレアル | 少なくとも1種の親油性2−ヒドロキシベンゾフェノン遮蔽剤及び少なくとも2つのアルキルアミノベンゾエート基で置換されているケイ素s−トリアジンを含む組成物 |
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EP2488148B1 (de) | 2009-10-12 | 2017-04-26 | L'Oréal | Verfahren zum schützen eines materials gegen uv-strahlung mittels photonenpartikel, zusammensetzungen |
WO2011045741A2 (en) | 2009-10-12 | 2011-04-21 | L'oreal | Photonic particles; compositions containing them; methods of photoprotecting various materials |
WO2011045746A2 (en) | 2009-10-12 | 2011-04-21 | L ' Oreal | A composition comprising a dispersion of photonic particles; methods of treating various materials |
JP2013508351A (ja) | 2009-10-22 | 2013-03-07 | ロレアル | 光防御組成物およびフィルム、ならびに製造方法 |
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WO2024124309A1 (en) | 2022-12-12 | 2024-06-20 | L'oreal | Cosmetic sunscreen composition and its use |
FR3143344A1 (fr) | 2022-12-16 | 2024-06-21 | L'oreal | Composition comprenant un filtre UV, un polymère lipophile convenablement sélectionné, et un carraghénane |
FR3143340A1 (fr) | 2022-12-20 | 2024-06-21 | L'oreal | Kit de soin anti-âge pour les matières kératiniques |
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ATE479419T1 (de) * | 2000-02-17 | 2010-09-15 | Basf Se | Wässrige dispersion wasserunlöslicher organischer uv-filtersubstanzen |
AU2003205656B2 (en) * | 2002-01-31 | 2007-09-06 | Ciba Specialty Chemicals Holding Inc. | Micropigment mixtures |
DE50307788D1 (de) * | 2003-05-22 | 2007-09-06 | Kemira Pigments Oy | Mischung aus titandioxid und methylen-bis-benzotriazolylphenol |
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DE102004047288B4 (de) | 2006-11-30 |
DE102004047288A1 (de) | 2006-04-13 |
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