EP1625254B1 - Utilisation d'alcools polyvinyliques a fonction silane dans des apprets pour papiers et feuilles de separation - Google Patents
Utilisation d'alcools polyvinyliques a fonction silane dans des apprets pour papiers et feuilles de separation Download PDFInfo
- Publication number
- EP1625254B1 EP1625254B1 EP04732604A EP04732604A EP1625254B1 EP 1625254 B1 EP1625254 B1 EP 1625254B1 EP 04732604 A EP04732604 A EP 04732604A EP 04732604 A EP04732604 A EP 04732604A EP 1625254 B1 EP1625254 B1 EP 1625254B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- silane
- carbon atoms
- group
- alkoxy
- silanes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 26
- 235000019422 polyvinyl alcohol Nutrition 0.000 title claims description 25
- 230000037452 priming Effects 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 27
- 229910000077 silane Inorganic materials 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 23
- -1 methoxy, ethoxy, methoxyethylene ethoxyethylene, methoxypropylene glycol ether Chemical compound 0.000 claims description 21
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 150000004756 silanes Chemical class 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 230000007062 hydrolysis Effects 0.000 claims description 7
- 238000006460 hydrolysis reaction Methods 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000003926 acrylamides Chemical class 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- BVCLXNHIJBDDTH-UHFFFAOYSA-N but-1-en-2-yl acetate Chemical compound CCC(=C)OC(C)=O BVCLXNHIJBDDTH-UHFFFAOYSA-N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- FMCKIFRVQWUXOM-UHFFFAOYSA-N pent-1-en-2-yl acetate Chemical compound CCCC(=C)OC(C)=O FMCKIFRVQWUXOM-UHFFFAOYSA-N 0.000 claims description 2
- 238000010526 radical polymerization reaction Methods 0.000 claims description 2
- 150000003377 silicon compounds Chemical class 0.000 claims description 2
- NVNRCMRKQVEOMZ-UHFFFAOYSA-N 1-ethoxypropane-1,2-diol Chemical compound CCOC(O)C(C)O NVNRCMRKQVEOMZ-UHFFFAOYSA-N 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000004447 silicone coating Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CVZIDTRJINIGGZ-UHFFFAOYSA-N 2-methoxypropan-2-yloxysilane Chemical compound COC(C)(C)O[SiH3] CVZIDTRJINIGGZ-UHFFFAOYSA-N 0.000 description 2
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 description 2
- DMZPTAFGSRVFIA-UHFFFAOYSA-N 3-[tris(2-methoxyethoxy)silyl]propyl 2-methylprop-2-enoate Chemical compound COCCO[Si](OCCOC)(OCCOC)CCCOC(=O)C(C)=C DMZPTAFGSRVFIA-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 description 2
- ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 description 2
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- XFOBMOZBCGIRDL-UHFFFAOYSA-N n-[[dimethoxy(propyl)silyl]oxymethyl]prop-2-enamide Chemical class CCC[Si](OC)(OC)OCNC(=O)C=C XFOBMOZBCGIRDL-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 2
- UOKUUKOEIMCYAI-UHFFFAOYSA-N trimethoxysilylmethyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C(C)=C UOKUUKOEIMCYAI-UHFFFAOYSA-N 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- IDXCKOANSQIPGX-UHFFFAOYSA-N (acetyloxy-ethenyl-methylsilyl) acetate Chemical compound CC(=O)O[Si](C)(C=C)OC(C)=O IDXCKOANSQIPGX-UHFFFAOYSA-N 0.000 description 1
- VJVKOUFFNJZOTN-UHFFFAOYSA-N (prop-2-enoylamino)-propylazanium;chloride Chemical compound [Cl-].CCC[NH2+]NC(=O)C=C VJVKOUFFNJZOTN-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- QJJDJWUCRAPCOL-UHFFFAOYSA-N 1-ethenoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOC=C QJJDJWUCRAPCOL-UHFFFAOYSA-N 0.000 description 1
- BDHGFCVQWMDIQX-UHFFFAOYSA-N 1-ethenyl-2-methylimidazole Chemical compound CC1=NC=CN1C=C BDHGFCVQWMDIQX-UHFFFAOYSA-N 0.000 description 1
- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- KNJOXNMRJUPXJT-UHFFFAOYSA-N 12,12-dimethoxydodecoxy(ethenyl)silane Chemical compound COC(OC)CCCCCCCCCCCO[SiH2]C=C KNJOXNMRJUPXJT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- PGYJSURPYAAOMM-UHFFFAOYSA-N 2-ethenoxy-2-methylpropane Chemical compound CC(C)(C)OC=C PGYJSURPYAAOMM-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
- VWXVZIJRYUTYJM-UHFFFAOYSA-N 2-methylpropyl-(prop-2-enoylamino)azanium chloride Chemical compound [Cl-].CC(C)C[NH2+]NC(=O)C=C VWXVZIJRYUTYJM-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical class CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- HMBNQNDUEFFFNZ-UHFFFAOYSA-N 4-ethenoxybutan-1-ol Chemical compound OCCCCOC=C HMBNQNDUEFFFNZ-UHFFFAOYSA-N 0.000 description 1
- SJIBSEBLLOLBMW-UHFFFAOYSA-N 8,8-dimethoxyoctoxy(ethenyl)silane Chemical compound COC(OC)CCCCCCCO[SiH2]C=C SJIBSEBLLOLBMW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- IGRURXZWJCSNKU-UHFFFAOYSA-N Isopropenylacetic acid Chemical compound CC(=C)CC(O)=O IGRURXZWJCSNKU-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- JSROXOGQSYYVMK-UHFFFAOYSA-N N-[3-[tris(2-methoxyethoxy)silyl]propyl]prop-2-enamide Chemical class C(C=C)(=O)NCCC[Si](OCCOC)(OCCOC)OCCOC JSROXOGQSYYVMK-UHFFFAOYSA-N 0.000 description 1
- 229920003082 Povidone K 90 Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- MOOIXEMFUKBQLJ-UHFFFAOYSA-N [1-(ethenoxymethyl)cyclohexyl]methanol Chemical compound C=COCC1(CO)CCCCC1 MOOIXEMFUKBQLJ-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- XRLWQTOZMISADO-UHFFFAOYSA-N [diacetyloxy(prop-2-enyl)silyl] acetate Chemical compound CC(=O)O[Si](CC=C)(OC(C)=O)OC(C)=O XRLWQTOZMISADO-UHFFFAOYSA-N 0.000 description 1
- VRUNESGBWOQYBK-UHFFFAOYSA-N [diacetyloxy(propyl)silyl] 2-(prop-2-enoylamino)acetate Chemical class CCC[Si](OC(C)=O)(OC(C)=O)OC(=O)CNC(=O)C=C VRUNESGBWOQYBK-UHFFFAOYSA-N 0.000 description 1
- KTVHXOHGRUQTPX-UHFFFAOYSA-N [ethenyl(dimethyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(C)C=C KTVHXOHGRUQTPX-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- YLJJAVFOBDSYAN-UHFFFAOYSA-N dichloro-ethenyl-methylsilane Chemical compound C[Si](Cl)(Cl)C=C YLJJAVFOBDSYAN-UHFFFAOYSA-N 0.000 description 1
- OTFXLPHXAADAKO-UHFFFAOYSA-N didodecoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCCCCCCCC)OCCCCCCCCCCCC OTFXLPHXAADAKO-UHFFFAOYSA-N 0.000 description 1
- WNQVUWLKSJJSFK-UHFFFAOYSA-N dihexoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCC)OCCCCCC WNQVUWLKSJJSFK-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- QMUOYZCDQUNRJS-UHFFFAOYSA-N dioctoxy(prop-2-enoxy)silane Chemical compound C(=C)CO[SiH](OCCCCCCCC)OCCCCCCCC QMUOYZCDQUNRJS-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- MLVRYXJUYPBRSQ-UHFFFAOYSA-N ethenyl(trihexoxy)silane Chemical compound CCCCCCO[Si](OCCCCCC)(OCCCCCC)C=C MLVRYXJUYPBRSQ-UHFFFAOYSA-N 0.000 description 1
- KPRMNZFLEVMTKA-UHFFFAOYSA-N ethenyl(trioctoxy)silane Chemical compound CCCCCCCCO[Si](OCCCCCCCC)(OCCCCCCCC)C=C KPRMNZFLEVMTKA-UHFFFAOYSA-N 0.000 description 1
- NNBRCHPBPDRPIT-UHFFFAOYSA-N ethenyl(tripropoxy)silane Chemical compound CCCO[Si](OCCC)(OCCC)C=C NNBRCHPBPDRPIT-UHFFFAOYSA-N 0.000 description 1
- QZOSZICRWGJQRX-UHFFFAOYSA-N ethenyl-dimethoxy-(2-methylpropyl)silane Chemical compound CO[Si](C=C)(OC)CC(C)C QZOSZICRWGJQRX-UHFFFAOYSA-N 0.000 description 1
- JEWCZPTVOYXPGG-UHFFFAOYSA-N ethenyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)C=C JEWCZPTVOYXPGG-UHFFFAOYSA-N 0.000 description 1
- NUFVQEIPPHHQCK-UHFFFAOYSA-N ethenyl-methoxy-dimethylsilane Chemical compound CO[Si](C)(C)C=C NUFVQEIPPHHQCK-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- PBZROIMXDZTJDF-UHFFFAOYSA-N hepta-1,6-dien-4-one Chemical compound C=CCC(=O)CC=C PBZROIMXDZTJDF-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- JUGMHUQFSYYJTB-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)prop-2-enamide Chemical class CCO[Si](OCC)(OCC)CCCNC(=O)C=C JUGMHUQFSYYJTB-UHFFFAOYSA-N 0.000 description 1
- YLVDOKXZTSRRFU-UHFFFAOYSA-N n-[(methoxy-methyl-propylsilyl)oxymethyl]prop-2-enamide Chemical class CCC[Si](C)(OC)OCNC(=O)C=C YLVDOKXZTSRRFU-UHFFFAOYSA-N 0.000 description 1
- BQHUUHKPGWUHNS-UHFFFAOYSA-N n-[[dimethoxy(2-methylpropyl)silyl]oxymethyl]prop-2-enamide Chemical class CC(C)C[Si](OC)(OC)OCNC(=O)C=C BQHUUHKPGWUHNS-UHFFFAOYSA-N 0.000 description 1
- RCIUBQSNTYGOMF-UHFFFAOYSA-N n-[[dimethoxy(methyl)silyl]oxymethyl]prop-2-enamide Chemical class CO[Si](C)(OC)OCNC(=O)C=C RCIUBQSNTYGOMF-UHFFFAOYSA-N 0.000 description 1
- LDMMQUPPWYNASL-UHFFFAOYSA-N n-[[dimethyl(propyl)silyl]oxymethyl]prop-2-enamide Chemical class CCC[Si](C)(C)OCNC(=O)C=C LDMMQUPPWYNASL-UHFFFAOYSA-N 0.000 description 1
- FHAUQKIQFCASKK-UHFFFAOYSA-N n-[[ethyl(dimethoxy)silyl]oxymethyl]prop-2-enamide Chemical class CC[Si](OC)(OC)OCNC(=O)C=C FHAUQKIQFCASKK-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- KHJNXCATZZIGAX-UHFFFAOYSA-N tert-butyl 2-ethyl-2-methylheptaneperoxoate Chemical compound CCCCCC(C)(CC)C(=O)OOC(C)(C)C KHJNXCATZZIGAX-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical class CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/001—Release paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/824—Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1452—Polymer derived only from ethylenically unsaturated monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1452—Polymer derived only from ethylenically unsaturated monomer
- Y10T428/1457—Silicon
Definitions
- the Höppler viscosity (according to DIN 53015 as 4% strength by weight aqueous solution) serves as a measure of the molecular weight and of the degree of polymerization of the partially or fully hydrolyzed, silanized Vinyl ester polymers, and is preferably from 2 to 50 mPas.
- Suitable vinyl esters are vinyl esters of unbranched or branched carboxylic acids having 1 to 18 carbon atoms.
- Preferred vinyl esters are vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, vinyl pivalate and vinyl esters of ⁇ -branched monocarboxylic acids having 5 to 13 carbon atoms, for example VeoVa9 R or VeoVa10 R (trade name of the company Shell). Particularly preferred is vinyl acetate.
- R 1 has the meaning CH 2
- Examples of such (meth) acrylamido-alkylsilanes are: 3- (meth) acrylamido-propyltrimethoxysilanes, 3- (meth) acrylamidopropyltriethoxysilanes, 3- (meth) acrylamido-propyltri ( ⁇ -methoxyethoxy) silanes, 2- (meth) acrylamido-2 -methylpropyltrimethoxysilanes, 2- (meth) acrylamido-2-methylethyltrimethoxysilanes, N- (2- (meth) acrylamidoethyl) aminopropyltrimethoxysilanes, 3- (meth) acrylamido-propyltriacetoxysilanes, 2- (meth) acrylamido-ethyltrimethoxysilanes, 1- (meth ) acrylamido-methyltrimethoxysilanes, 3- (meth)
- silane-containing monomers are 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropylmethyldimethoxysilane, Vinyltrimethoxysilane, vinylmethyldimethoxysilane, vinyltriethoxysilane, vinylmethyldiethoxysilane, vinyltripropoxysilane, vinyltriisopropoxysilane, vinyltris (1-methoxy) isopropoxysilane, vinyltributoxysilane, vinyltriacetoxysilane, methacryloxymethyltrimethoxysilane, 3-methacryloxypropyltris (2-methoxyethoxy) silane, vinyltrichlorosilane, vinylmethyldichlorosilane, vinyltris (2-methoxyethoxy ) silane, trisacetoxyvinylsilane, Allylvinyltrimethoxysilan, allyltriacetoxysilane, vinyldimethylmethoxysilane, vinyldimethyle
- vinylcarbazole vinylidene cyanide
- vinyl esters acrylic anhydride, maleic anhydride, maleic and fumaric acid esters
- sulfonic acid-modified monomers such as 2-acrylamido-2-methylpropanesulfonic acid and their alkali metal salts
- cationic monomers such as trimethyl-3- (1- (meth) acrylamide 1,1-dimethylpropyl) ammonium chloride, trimethyl 3- (1- (meth) acrylamidopropyl) ammonium chloride, 1-vinyl-2-methylimidazole and their quaternized compounds.
- the reactor was heated to 51.5 ° C, after the reaction had stopped, it was gradually heated to 75 ° C. It was kept at this temperature for 2 hours, then cooled. The resulting polymer beads were filtered off with suction, washed well with water and dried.
- 90 g of polymer beads were dissolved in 810 g of methanol at 50 ° C.
- the solution was cooled to 30 ° C, covered with standing stirrer with 500 g of methanol and immediately mixed with methanolic NaOH (10 g of NaOH 46% strength in water dissolved in 90 g of methanol) and the stirrer turned on. The solution became increasingly cloudier.
- the stirrer was set to higher speed to crush the gel.
- Example 1 Vbsp. 1 Vbsp. 2 Example 1 Vbsp. 1 Vbsp. 2 storage time 0 0 0 7 d 7 d 7 d migration 1 1 4 1 5 5 Rub Off 1 1 4 1 5 6
- the test shows the superiority of the silane-containing polyvinyl alcohols used according to the invention after storage.
- the test shows that the silane-containing polyvinyl alcohols used according to the invention show no increase in viscosity on storage.
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Claims (7)
- Utilisation de poly(alcool vinylique)s à fonction silane dans des compositions d'apprêt pour papiers et films de séparation, contenant
au moins un poly(alcool vinylique) silané à base de copolymères d'esters vinyliques partiellement saponifiés ou totalement saponifiés ayant un degré d'hydrolyse de 75 à 100 % en moles, pouvant être obtenu par polymérisation radicalaire dea) un ou plusieurs esters vinyliques d'acides alkylcarboxyliques ramifiés ou non ramifiés ayant de 1 à 18 atomes de carbone, dont une proportion de 1 à 30 % en moles, par rapport au polymère total, consistent en un ou plusieurs esters 1-alkylvinyliques à radicaux alkyle ayant de 1 à 6 atomes de carbone et d'acides carboxyliques ayant de 1 à 6 atomes de carbone,b) 0,01 à 10 % en moles d'un ou plusieurs monomères silanés à insaturation éthylénique, ainsi qu'éventuellementc) d'autres comonomères copolymérisables avec ceux-ci,et saponification des polymères ainsi obtenus. - Utilisation selon la revendication 1, caractérisée en ce que le poly(alcool vinylique) silané est obtenu par copolymérisation avec de l'acétate de vinyle.
- Utilisation selon la revendication 1 ou 2, caractérisée en ce qu'un ou plusieurs esters 1-alkylvinyliques choisis dans le groupe comprenant l'acétate de 1-méthylvynyle, l'acétate de 1-éthylvynyle ainsi que l'acétate de 1-propylvinyle sont copolymérisés.
- Utilisation selon l'une quelconque des revendications 1 à 3, caractérisée en ce que le poly(alcool vinylique) silané est obtenu par copolymérisation d'un ou plusieurs monomères silanés à insaturation éthylénique choisis dans le groupe comprenant
des composés siliciés à insaturation éthylénique de formule générale (I) R1SiR2 0-2(OR3)1-3, R1 ayant la signification de CH2=CR4-(CH2)0-3 ou de CH2=CR4CO2(CH2)1-3, R2 représentant un radical alkyle en C1-C3, un radical alcoxy en C1-C3 ou un atome d'halogène, R3 étant un radical alkyle ramifié ou non ramifié, éventuellement substitué, ayant de 1 à 12 atomes de carbone, ou étant un radical acyle ayant de 2 à 12 atomes de carbone, R3 pouvant éventuellement être interrompu par un groupe éther, et R4 représentant H ou CH3, et des méthacrylamides contenant des groupes silane, de formule générale (II) CH2=CR5-CO-NR6-R7-SiR8 m-(R9)3-m, dans laquelle m = 0 à 2, R5 est soit H, soit un groupe méthyle, R6 est H ou un groupe alkyle ayant de 1 à 5 atomes de carbone, R7 est un groupe alkylène ayant de 1 à 5 atomes de carbone ou un groupe organique bivalent dans lequel la chaîne carbonée est interrompue par un atome d'oxygène ou d'azote, R8 est un groupe alkyle ayant de 1 à 5 atomes de carbone, R9 est un groupe alcoxy ayant de 1 à 40 atomes de carbone, qui peuvent être substitués par d'autres hétérocycles. - Utilisation selon la revendication 4, caractérisée en ce que le poly(alcool vinylique) silané est obtenu par copolymérisation d'un ou plusieurs monomères silanés à insaturation éthylénique, choisis dans le groupe comprenant des γ-acryl- ou γ-méthacryloxypropyltri(alcoxy)silanes, des α-méthacryloxyméthyltri(alcoxy)silanes, des γ-méthacryloxypropylméthyldi(alcoxy)silanes, des vinylalkyldi(alcoxy)silanes, des vinyltri(alcoxy)silanes, dans lesquels par exemple des radicaux méthoxy, éthoxy, méthoxyéthylène, éthoxyéthylène, méthoxypropylèneglycoléther ou éthoxypropylèneglycoléther peuvent être contenus en tant que groupes alcoxy.
- Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que 0,01 à 1,5 % en moles de monomères silanés à insaturation éthylénique sont copolymérisés.
- Utilisation selon l'une quelconque des revendications 1 à 6, dans des procédés pour le revêtement antiadhésif de papiers et films de séparation, dans lesquels, après application de l'apprêt, une couche de silicone est appliquée sur un support.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10323203A DE10323203A1 (de) | 2003-05-22 | 2003-05-22 | Verwendung von silanfunktionellen Polyvinylalkoholen in Grundierungsmitteln für Trennpapiere und -folien |
| PCT/EP2004/005153 WO2004104297A1 (fr) | 2003-05-22 | 2004-05-13 | Utilisation d'alcools polyvinyliques a fonction silane dans des apprets pour papiers et feuilles de separation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1625254A1 EP1625254A1 (fr) | 2006-02-15 |
| EP1625254B1 true EP1625254B1 (fr) | 2006-08-02 |
Family
ID=33461844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04732604A Expired - Lifetime EP1625254B1 (fr) | 2003-05-22 | 2004-05-13 | Utilisation d'alcools polyvinyliques a fonction silane dans des apprets pour papiers et feuilles de separation |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060204703A1 (fr) |
| EP (1) | EP1625254B1 (fr) |
| JP (1) | JP4377408B2 (fr) |
| CN (1) | CN100365208C (fr) |
| AT (1) | ATE335102T1 (fr) |
| DE (2) | DE10323203A1 (fr) |
| RU (1) | RU2329289C2 (fr) |
| WO (1) | WO2004104297A1 (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005000823A1 (de) * | 2005-01-05 | 2006-07-13 | Consortium für elektrochemische Industrie GmbH | Vernetzbare, silanmodifizierte Mischpolymerisate |
| DE102008000585A1 (de) * | 2008-03-10 | 2009-09-17 | Wacker Chemie Ag | Binderhaltige kolloidale wässrige Organopolysiloxandispersionen und deren Verwendung |
| FI123351B (fi) * | 2008-06-03 | 2013-03-15 | Upm Kymmene Corp | Irrokemateriaalikoostumus, pohjamateriaali ja menetelmä pohjamateriaalin valmistamiseksi, pintakäsittelyaine pohjamateriaalia varten sekä pintakäsittelyaineen käyttö |
| DE102009002130A1 (de) * | 2009-04-02 | 2010-10-14 | Wacker Chemie Ag | Membranen auf Basis von Polyvinylalkohol |
| FI20095392A0 (fi) | 2009-04-09 | 2009-04-09 | Upm Kymmene Corp | Menetelmä substraatin pinnan käsittelemiseksi |
| PL2440604T3 (pl) * | 2009-06-09 | 2017-09-29 | Tarkett G.D.L. S.A. | Powłoka powierzchni wielowarstwowej z warstwą barierową |
| BR112013008804A2 (pt) * | 2010-10-12 | 2016-06-28 | Tarkett Gld | processo para a produção de uma cobertura de superfície em pvc |
| DE102013107329A1 (de) | 2013-07-10 | 2015-01-15 | Kuraray Europe Gmbh | Imprägnierungsmaterialien für Release-Papiere |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3436252A (en) * | 1967-04-13 | 1969-04-01 | Stauffer Chemical Co | Paper release composition |
| DE76490T1 (de) * | 1981-10-05 | 1983-12-08 | Kuraray Co., Ltd., Kurashiki, Okayama | Mittel zur papierbeschichtung. |
| JPS58214596A (ja) * | 1982-06-01 | 1983-12-13 | 株式会社クラレ | 加工用原紙の製造方法 |
| NO157078C (no) * | 1985-08-22 | 1988-01-13 | Elkem As | Bakeovn for elektroder. |
| DE3622820A1 (de) * | 1986-07-08 | 1988-01-21 | Wacker Chemie Gmbh | Cobinder fuer streichmassen |
| ATE110131T1 (de) * | 1989-05-26 | 1994-09-15 | Kaemmerer Gmbh | Trennrohpapier, verfahren zu dessen herstellung und zur herstellung von silikontrennpapier. |
| US5358977A (en) * | 1990-10-23 | 1994-10-25 | Daubert Coated Products, Inc. | Stabilized paper substrate for release liners using aromatic and aliphatic primers, and novel primer coat |
| EP0799711B1 (fr) * | 1996-04-02 | 1999-07-28 | Kuraray Co., Ltd. | Agent pour le couchage du papier |
| DE19641064A1 (de) * | 1996-10-04 | 1998-04-09 | Wacker Chemie Gmbh | Modifizierte Polyvinylbutyrale mit niederer Lösungsviskosität |
| DE10035588A1 (de) * | 2000-07-21 | 2002-02-07 | Wacker Polymer Systems Gmbh | Verfahren zur Herstellung von zweiphasigen Polymerisaten in Form deren wässrigen Polymerdispersionen und in Wasser redispergierbaren Polymerpulver |
| DE10232666A1 (de) * | 2002-07-18 | 2004-02-05 | Wacker Polymer Systems Gmbh & Co. Kg | Silan-haltiger Polyvinylalkohol für Papierstreichmassen |
-
2003
- 2003-05-22 DE DE10323203A patent/DE10323203A1/de not_active Withdrawn
-
2004
- 2004-05-13 US US10/552,678 patent/US20060204703A1/en not_active Abandoned
- 2004-05-13 AT AT04732604T patent/ATE335102T1/de not_active IP Right Cessation
- 2004-05-13 DE DE502004001117T patent/DE502004001117D1/de not_active Expired - Fee Related
- 2004-05-13 EP EP04732604A patent/EP1625254B1/fr not_active Expired - Lifetime
- 2004-05-13 CN CNB2004800096530A patent/CN100365208C/zh not_active Expired - Fee Related
- 2004-05-13 WO PCT/EP2004/005153 patent/WO2004104297A1/fr active IP Right Grant
- 2004-05-13 RU RU2005139921/04A patent/RU2329289C2/ru active
- 2004-05-13 JP JP2006508176A patent/JP4377408B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE502004001117D1 (de) | 2006-09-14 |
| WO2004104297A1 (fr) | 2004-12-02 |
| EP1625254A1 (fr) | 2006-02-15 |
| ATE335102T1 (de) | 2006-08-15 |
| RU2005139921A (ru) | 2007-06-27 |
| JP4377408B2 (ja) | 2009-12-02 |
| DE10323203A1 (de) | 2004-12-23 |
| US20060204703A1 (en) | 2006-09-14 |
| CN1771367A (zh) | 2006-05-10 |
| JP2006526084A (ja) | 2006-11-16 |
| RU2329289C2 (ru) | 2008-07-20 |
| CN100365208C (zh) | 2008-01-30 |
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