EP1527217B1 - Vorrichtung zum spinnen und aufwickeln - Google Patents

Vorrichtung zum spinnen und aufwickeln Download PDF

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Publication number
EP1527217B1
EP1527217B1 EP03784079A EP03784079A EP1527217B1 EP 1527217 B1 EP1527217 B1 EP 1527217B1 EP 03784079 A EP03784079 A EP 03784079A EP 03784079 A EP03784079 A EP 03784079A EP 1527217 B1 EP1527217 B1 EP 1527217B1
Authority
EP
European Patent Office
Prior art keywords
godet
winding
threads
spinning
withdrawal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03784079A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1527217A1 (de
Inventor
Michael SCHRÖTER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oerlikon Textile GmbH and Co KG
Original Assignee
Oerlikon Textile GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oerlikon Textile GmbH and Co KG filed Critical Oerlikon Textile GmbH and Co KG
Publication of EP1527217A1 publication Critical patent/EP1527217A1/de
Application granted granted Critical
Publication of EP1527217B1 publication Critical patent/EP1527217B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D13/00Complete machines for producing artificial threads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H54/00Winding, coiling, or depositing filamentary material
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D7/00Collecting the newly-spun products
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/017Filament stretching apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/217Spinnerette forming conjugate, composite or hollow filaments

Definitions

  • the invention relates to a device for spinning and winding a plurality of synthetic threads according to the preamble of claim 1.
  • Such apparatuses for spinning and winding a plurality of synthetic yarns including a spinneret having a plurality of spinnerets, at least one take-off godet, and a reel-up having a plurality of winding locations are well known.
  • a polymer melt is distributed to a plurality of spinnerets by means of a melt generator at the spinning device.
  • the polymer melt is extruded under pressure in each case into strand-like filament bundles, which are brought together after cooling to form a thread.
  • the threads, or the filament bundles are preferably withdrawn together by a Abzugsgalette of the spinnerets and guided to the winding points of the take-up.
  • the threads are guided within the device according to the versions of the individual devices with different distances from each other.
  • a further object of the invention is to provide a device which is as compact and user-friendly as possible for producing a multiplicity of threads.
  • the device according to the invention is particularly characterized in that the merging and spreading of the threads takes place in differently oriented planes.
  • the spreading and distribution of the yarn sheet to the individual winding positions of the take-up device is carried out to a substantial extent in an approximately horizontally oriented distribution level.
  • the depth of the device for guiding the threads is included.
  • the spinning device and the withdrawal godet is aligned transversely to the longitudinal axis of the take-up device and arranged on an end face of the take-up device.
  • the withdrawal godet is thus located directly next to the winding points in the winding machine.
  • the threads can thus be advantageous first in a vertical spinning plane from the spinning device lead to the Abzugsgalette, to be then guided at the transverse to the spinning plane distribution plane to the winding points of the take-up.
  • the withdrawal godet is associated with the outlet of a chute of the spinning device and the Abzugsgalette and the outlet of the chute on the operating side of the invention in a particularly advantageous embodiment of the invention Winding arranged within reach of an operator.
  • the outlet of the chute is preferably arranged at a distance to a Aufstellt the take-up, which is less than 250 cm. Thus, all can be arranged below the chute Facilities for guiding and treating the threads such as preparation device, thread monitor operated by a person.
  • the device of the invention is particularly suitable because a plurality of distributor rolls are arranged between the take-off godet and the winding points of the take-up device, by which the threads running from the take-off godet are separated for entry into the winding positions ,
  • the threads can after expiration of the withdrawal godet lead to several, in pairs or individually by the distributed in the direction of the longitudinal axis of the take-up arranged distribution roller.
  • Each winding position of the take-up device are each assigned a distributor roll. After expiration of the threads of the withdrawal godet thus takes place according to the arrangement of the winding stations separated division of the threads.
  • the distributor rollers are preferably arranged directly upstream of a head thread guide of the winding position, so that each thread undergoes a deflection of the take-off godet and a deflection on the Verteilrolle in the leadership of the winding point associated spinneret.
  • the wrapping ratios of each of the filaments are substantially the same so that there are no significant differences in yarn tension resulting from the distribution on the wrapping locations.
  • a second galette is assigned, particularly suitable.
  • the threads are thus guided before distribution to the winding points in several wraps on the Abzugsgalette and the second godet before they are forwarded by the Abzugsgalette directly to the winding stations.
  • a heat treatment, a stretching or a swirling of the threads before entry into the winding stations can be realized in a simple manner.
  • the second galette can also be advantageously formed by a driven overflow roller, so that the Abzugsgalette can muster higher withdrawal forces with an overrun by multiple looped threadline.
  • the facilities provided below the spinning device, in particular the withdrawal godet, are advantageously held directly on a frame part of the take-up device.
  • the device is thus composed essentially of the components of the spinning device, which are held on a carrier forming a floor, and the components of the take-up device, which are held by a machine frame arranged on the Aufstellplattfonn.
  • the drive and control electronics of all the machine frame of the take-up arranged components advantageously combine to form a unit.
  • the unit is preferably associated with a control panel through which the operator can operate each of the controllable units.
  • a first embodiment of the device according to the invention is shown in several views.
  • the device is in a side view
  • in Fig. 2 in a front view
  • in Fig. 3 shown in a plan view.
  • the following description applies, insofar as no explicit reference is made to one of the figures, for all figures.
  • the device according to the invention consists of a spinning device 1 and a winding device 10, wherein in the transition between the spinning device 1 and the winding device 10, a withdrawal godet 8 is arranged.
  • the spinning device 1 contains a heated spinning beam 2, which is connected via a melt feed 3 with a melt source, not shown here, for example, an extruder.
  • a plurality of spinning devices can be assigned to a common melt source.
  • the spinning beam 2 has on a bottom side a plurality of spinnerets 4.1, 4.2, 4.3 and 4.4.
  • the arrangement of the spinnerets and the number of spinnerets is exemplary. Thus, a plurality of spinnerets can also be arranged in several rows or in a circle.
  • Each of the spinnerets 4.1 to 4.4 has a multiplicity of nozzle bores in order to extrude in each case one filament bundle of a multi-filament thread 9.1 to 9.4 from a polymer melt supplied via the melt feed.
  • a cooling shaft 5 is provided below the spinning beam 2, through which the filament bundles are guided for the purpose of cooling.
  • a cooling air flow is preferably generated in the cooling shaft 5 by an injection 6.
  • a preparation device 20 and a plurality of yarn guides 21 are arranged to bring together the filament bundles to the respective threads 9.1 to 9.4.
  • the cooling shaft 5 is immediately followed by a chute 7 and a withdrawal godet 8 at.
  • the threads 9.1 to 9.4 are withdrawn substantially in a spinning plane of the spinnerets 4.1 to 4.4.
  • the threads 9.1 to 9.4 are brought together by the yarn guide 21 on the outlet side of the cooling shaft 5 and the yarn guide strip 23.1 of a conditional by the spinning division yarn spacing to a smaller treatment distance.
  • the threads 9.1 to 9.4 are then guided with the treatment distance from each other on the circumference of the withdrawal godet 8.
  • a yarn collecting device 22 is provided, through which the yarn sheet is guided at a suction in a suction.
  • the thread-collecting device 22 has a movable guide means and a suction in order to be able to insulate the threads 9.1 to 9.4 when the thread breaks.
  • Such a thread-collecting device is known from EP 1 049 821 A1 known.
  • a winding device 10 is arranged below the spinning device 1, wherein the winding device 10 is aligned with its longitudinal axis transverse to the spinning plane of the yarn sheet of the threads 9.1 to 9.4.
  • the spinning device 1 and the withdrawal godet 8 are located transversely to the longitudinal axis of the take-up device 10 in the region of an end face 29 of the take-up device 10.
  • the thread sequence of the withdrawal godet 8 is preferably below an upper edge of the machine frame of the take-up device 10. In order to enable encapsulation of the take-up device, let the take-off godet be arranged completely below the upper edge of the take-up device.
  • the winding device 10 has distributed on its longitudinal axis a plurality of winding points 11.1 to 11.4. In each of the winding points 11.1 to 11.4 one of the threads 9.1 to 9.4 is wound to one of the coils 13.1 to 13.4, respectively.
  • the coils 13.1 to 13.4 are held for this purpose on a winding spindle 12.1.
  • the winding spindle 12.1 is driven in such a way that a uniform take-up speed for winding up the threads 9.1 to 9.4 is present.
  • the winding spindle 12.1 is rotatably mounted projecting parallel to the longitudinal axis on a spool revolver 15. At the spool revolver 15 a spaced second winding spindle 12.2 is arranged.
  • the bobbin revolver 15 is rotatably mounted in the machine frame 19, so that the winding spindle 12.1 and 12.2 can be alternately performed in a winding area and a change area.
  • the spool turret 15 is assigned a drive.
  • the winding spindle 12.1 or 12.2 cooperates with a pressure roller 14, which bears against the circumference of the coils 13.1 to 13.4 to be wound.
  • the pressure roller 14 is rotatably mounted, preferably on a movable support, which is for example pivotally connected to the machine frame 19.
  • a traversing device 16 is provided in each of the winding points 11.1 to 11.4, through which the thread is guided back and forth within a traverse stroke.
  • each of the winding stations 11.1 to 11.4 respectively a head thread guide 17.1 to 17.4 and a freely rotatable distributor roller 18.1 to 18.4 upstream.
  • the distributor rollers 18.1 to 18.4 are preferably formed by a respective smooth roller, which on a Axle is freely rotatably mounted.
  • the withdrawal godet 8 is arranged on the frame part 19.2. In order to distribute the threads 9.1 to 9.4 guided on the circumference of the withdrawal godet 8, the withdrawal godet 8 is followed by a yarn guide strip 23.2, by means of which the yarns are removed from the withdrawal godet 8 in parallel operation.
  • the threads 9.1 to 9.4 are guided via the distributor rollers 18.1 to 18.4 to the winding points 11.1 to 11.4.
  • the thread 9.1 runs after the departure of the godet 8 via the distributor roller 18.1 in the winding position 11.1.
  • the leadership of the threads 9.2, 9.3 and 9.4 is carried out according to the succession of the winding points 11.2, 11.3 and 11.4 arranged distribution rollers 18.2, 18.3 and 18.4.
  • the end face 29 of the take-up device 10 is at the same time the operating side of the take-up device.
  • a control panel 30 is disposed above the freely projecting winding spindles 12.1 and 12.2. Via the control panel 30, all controllable actuators and functional sequences of the take-up device 10 as well as the take-off godet 8 can be operated by an operator.
  • the devices in the region of the front side 29 of the take-up device 10, which are arranged below the chute 7 of the spinning device 1 can be operated by one person.
  • the outlet of the chute 7 is preferably arranged at a height above an installation platform 24, which lies below 250 cm. The decisive for the operation of the facilities below the spinning device 1 height is in the Fig.
  • the height of the spinning device which is marked with the letter S, represents the transition from a spinning distance to a treatment distance between the threads 9.1 to 9.4.
  • the height S is essentially determined by the permissible deflection angle of the threads. Here, an angle range of about 7 ° should be maintained as possible.
  • the overall height S is dependent on the number of parallel spun in the spinning device side by side threads and the arrangement of the spinnerets.
  • the spinnerets can be arranged single row or double row to each other. There is also the Possibility to place the spinnerets in a circular arrangement to obtain an advantageous melt distribution.
  • the threads are taken 9.1 to 9.4 after piecing and threading in the spinning device 1 at the outlet of the chute 7 by means of a suction gun by the operator.
  • a suction gun By manually guiding the suction gun, which discharges the threads continuously to a waste container, the threads are 9.1 to 9.4 successively created in the yarn guide the yarn guide 23.1, the yarn collecting device 22 and the Abzugsgalette 8 and the downstream yarn guide 23.2.
  • the distribution of the threads 9.1 to 9.4 takes place on the individual distributor rollers 18.1 to 18.4. This can be done by manual guidance or by auxiliary equipment such as from EP 0 886 623 A1 known, done.
  • the distributor rollers 18.1 to 18.4 on a linear guide on which the distributor rollers can be guided for application in a contact position near the front side of the take-up device. To distribute the threads, the distributor rollers would then be brought into their respective operating position. After starting the winding device 10 and applying the threads 9.1 to 9.4 in the winding stations 11.1 to 11.4, the process is started.
  • the in the Fig. 1 to 3 The device shown is particularly suitable for producing preoriented threads to so-called POY yarns.
  • the L-shaped arrangement of the spinning device and the winding device to each other can be advantageous to perform the distribution of the threads after treatment to the take-up device in an aligned transversely to a vertical spinning plane inclined distribution plane.
  • a very low height can be realized.
  • the entire device extends only over two floors, wherein the take-up device is set up with all treatment facilities in the lowest floor and wherein the upper floor has the spinning device with the melt sources such as extruder.
  • a further embodiment of the device according to the invention is shown schematically in a front view.
  • the embodiment of the device according to the invention is substantially identical to the preceding embodiment, so that reference is made to the preceding description and at this point only the differences are shown.
  • the components of the same function have been given identical reference numerals.
  • the spinning device 1, the godet 8 and the take-up device 10 are set up in the L-shaped arrangement described above.
  • Fig. 4 in this case shows the operating side of the winding device 10, from which an operator carries out the application and threading of the threads 9.1 to 9.4.
  • the winding device 10 is substantially identical to the preceding embodiment, wherein on the machine frame 19 above the traversing device 16, an electronic unit 28 is arranged.
  • Such a structure of the winding machine 10 is for example from the EP 0 845 432 A1 known.
  • the frame part 19.1 is fixedly connected to the machine frame 19 of the take-up device 10.
  • the withdrawal godet 8 is rotatably supported.
  • the withdrawal godet 8 is driven by a godet drive 25.
  • the godet drive 25 is coupled to the electronics unit 28.
  • a distributor roll are arranged on the machine frame 19.1 per thread.
  • the arrangement of the distributor rollers corresponds to the embodiment previously shown so that in Fig. 4 only the first distributor roller 18.1 is shown.
  • the distributor roller 18.1 and all other distributor rollers not shown here are coupled to a roller drive 26.
  • the roller drive 26 By the roller drive 26, the associated distributor roller is driven at a predetermined peripheral speed.
  • the supply and the control of the roller drive 26 via the electronic unit 28. Der Roller drive 26 is thus coupled to the electronics unit 28.
  • the control of the withdrawal godet 8 and the distributor rollers 18.1 and the distributor rollers, not shown, can be performed by the operating panel 30.
  • FIG. 4 illustrated embodiment of the device according to the invention is thus characterized by a high degree of integration.
  • the device is thus formed essentially by the spinning device 1 and the winding device 10, wherein the winding device 10 includes all other means for treating the threads and electronically supplied.
  • the connection thus takes place in a simple manner directly via the electronic unit 28.
  • the distributor rollers can be driven individually by a respective roller drive or together by a common roller drive.
  • individual thread tension adjustments in particular equalization of the thread tensions for winding up the threads, can be set.
  • a differential speed acting between the take-off godet and the distributor rollers can advantageously be set for the treatment of the threads.
  • Fig. 5 a further embodiment of a device according to the invention is shown.
  • the exemplary embodiment is essentially identical to the previous exemplary embodiment Fig. 1 to 3 , In that regard, the previous description refers to the Fig. 1 to 3 Reference is made and only the differences explained here.
  • Fig. 5 the embodiment is shown in a side view.
  • the spinning device 1 is identical to the previous embodiment.
  • the winding device 10 only differences in the structure of the machine frame. So is on the machine frame 19.2 next to the Abzugsgalette 8 a second galette 31 arranged.
  • the withdrawal godet 8 and the second godet 31 are rotatably supported cantilevered on the machine frame 19.2, wherein each of the godets 8 and 31 are driven by a drive.
  • a Tangel sensible 27 is arranged, through which the repeatedly passed around the withdrawal godet 8 and the second godet 31 threads 9.1 to 9.4 are guided in a Umschlingungsast.
  • the distribution of the threads after the treatment and after expiration of the withdrawal godet 8 takes place in accordance with the preceding embodiments.
  • FIG. 5 illustrated embodiment of the device according to the invention thus differs in the treatment of the threads prior to winding.
  • the withdrawal godet 8 and / or the second godet 31 can be designed to be heatable. It is also possible to replace the second godet 31 by a non-driven freely rotatable overflow roller.
  • the treatment of the threads can be supplemented by other facilities not shown here, such as additional godets, heaters or turbulators.
  • FIGS. 1 to 5 shown embodiments of the device according to the invention are exemplary in the construction and choice of the individual processing units.
  • the device according to the invention is usually set up in a plurality to a complete system.
  • the inventive L-shaped arrangement of the device is particularly suitable to obtain a high integration.
  • the tops of the take-up devices can be walked on to form, for example, an operating path for the spinning device.
  • central cable guides for powering the device can be realized in a simple manner.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
EP03784079A 2002-08-06 2003-07-25 Vorrichtung zum spinnen und aufwickeln Expired - Lifetime EP1527217B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10235936 2002-08-06
DE10235936A DE10235936A1 (de) 2002-08-06 2002-08-06 Vorrichtung zum Spinnen und Aufwickeln
PCT/EP2003/008228 WO2004015173A1 (de) 2002-08-06 2003-07-25 Vorrichtung zum spinnen und aufwickeln

Publications (2)

Publication Number Publication Date
EP1527217A1 EP1527217A1 (de) 2005-05-04
EP1527217B1 true EP1527217B1 (de) 2008-09-03

Family

ID=30469476

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03784079A Expired - Lifetime EP1527217B1 (de) 2002-08-06 2003-07-25 Vorrichtung zum spinnen und aufwickeln

Country Status (10)

Country Link
US (1) US7322811B2 (ko)
EP (1) EP1527217B1 (ko)
JP (1) JP4204548B2 (ko)
KR (1) KR101004979B1 (ko)
CN (1) CN100347351C (ko)
AU (1) AU2003266247A1 (ko)
DE (2) DE10235936A1 (ko)
MX (1) MXPA05001020A (ko)
TW (1) TWI324644B (ko)
WO (1) WO2004015173A1 (ko)

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WO2006102932A1 (de) * 2005-03-26 2006-10-05 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum führen und fördern von zumindest einem faden
WO2007085274A1 (de) * 2006-01-26 2007-08-02 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum schmelzspinnen und aufwickeln von synthetischen fäden
WO2008055823A2 (en) * 2006-11-10 2008-05-15 Oerlikon Textile Gmbh & Co. Kg Process and device for melt-spinning and cooling synthetic filaments
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DE102009012001A1 (de) 2008-04-18 2009-10-22 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Abziehen und Aufwickeln einer Fadenschar
DE102009021131A1 (de) 2008-05-30 2009-12-03 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Schmelzspinnen und Aufwickeln einer Mehrzahl von Fäden sowie ein Verfahren zum Führen mehrerer Fäden beim Schmelzspinnen und Aufwickeln
JP5356778B2 (ja) * 2008-11-06 2013-12-04 Tmtマシナリー株式会社 紡糸巻取機
JP5107210B2 (ja) 2008-11-13 2012-12-26 Tmtマシナリー株式会社 紡糸巻取設備
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JP5711062B2 (ja) 2011-07-22 2015-04-30 Tmtマシナリー株式会社 紡糸巻取機
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CN102839436B (zh) * 2012-09-27 2015-06-10 北京中丽制机工程技术有限公司 长丝牵伸卷绕装置
DE102015002963A1 (de) 2015-03-07 2016-09-08 Oerlikon Textile Gmbh & Co. Kg Aufspulmaschine
US10801130B2 (en) * 2015-04-25 2020-10-13 Oerlikon Textile Gmbh & Co. Kg Process and device for the melt spinning and cooling of multifilament threads
WO2017162470A1 (de) 2016-03-24 2017-09-28 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum schmelzspinnen, abziehen und aufwickeln einer fadenschar
CN105714393A (zh) * 2016-04-01 2016-06-29 三河市浩运盛跃碳纳米科技有限公司 纤维预处理装置
DE102017010143A1 (de) * 2017-10-28 2019-05-02 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Abziehen und Aufwickeln mehrerer Fäden
US11918942B2 (en) 2017-10-31 2024-03-05 Schlumberger Technology Corporation In process screen parameter measurement and control
JP2021055235A (ja) * 2019-10-02 2021-04-08 Tmtマシナリー株式会社 紡糸生産設備
CN111410088A (zh) * 2020-05-25 2020-07-14 光山县群力化纤有限公司 一种纺丝机卷绕头
DE102022112853B3 (de) 2021-06-04 2022-10-27 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Aufwickeln einer Fadenschar
JP2023041473A (ja) * 2021-09-13 2023-03-24 Tmtマシナリー株式会社 紡糸生産設備

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JP2005534825A (ja) 2005-11-17
US20050129799A1 (en) 2005-06-16
CN100347351C (zh) 2007-11-07
TW200404107A (en) 2004-03-16
US7322811B2 (en) 2008-01-29
AU2003266247A1 (en) 2004-02-25
KR101004979B1 (ko) 2011-01-04
MXPA05001020A (es) 2005-11-23
DE10235936A1 (de) 2004-02-19
TWI324644B (en) 2010-05-11
DE50310439D1 (de) 2008-10-16
KR20050048591A (ko) 2005-05-24
CN1671894A (zh) 2005-09-21
JP4204548B2 (ja) 2009-01-07
EP1527217A1 (de) 2005-05-04
WO2004015173A1 (de) 2004-02-19

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