EP1516042A1 - Schaumdesinfektionsmittel - Google Patents
SchaumdesinfektionsmittelInfo
- Publication number
- EP1516042A1 EP1516042A1 EP03738067A EP03738067A EP1516042A1 EP 1516042 A1 EP1516042 A1 EP 1516042A1 EP 03738067 A EP03738067 A EP 03738067A EP 03738067 A EP03738067 A EP 03738067A EP 1516042 A1 EP1516042 A1 EP 1516042A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- foam
- disinfectant according
- atoms
- antimicrobial agent
- total
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000645 desinfectant Substances 0.000 title claims abstract description 32
- 239000006260 foam Substances 0.000 title claims description 43
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000004599 antimicrobial Substances 0.000 claims abstract description 14
- 125000003277 amino group Chemical group 0.000 claims abstract description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 6
- 239000006265 aqueous foam Substances 0.000 claims abstract description 4
- 230000002195 synergetic effect Effects 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 9
- 238000004659 sterilization and disinfection Methods 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910014033 C-OH Inorganic materials 0.000 claims description 2
- 229910014570 C—OH Inorganic materials 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 235000013305 food Nutrition 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- 150000002306 glutamic acid derivatives Chemical class 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 abstract description 2
- 238000009472 formulation Methods 0.000 description 10
- 230000000845 anti-microbial effect Effects 0.000 description 7
- 230000006399 behavior Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000003641 microbiacidal effect Effects 0.000 description 5
- 229940124561 microbicide Drugs 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- -1 aliphatic diamines Chemical class 0.000 description 3
- 239000003139 biocide Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000012085 test solution Substances 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- MITNMQMWBBEWFQ-UHFFFAOYSA-N 1-(4-chlorophenyl)-1-(3,4-dichlorophenyl)urea Chemical compound C=1C=C(Cl)C(Cl)=CC=1N(C(=O)N)C1=CC=C(Cl)C=C1 MITNMQMWBBEWFQ-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 description 1
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 description 1
- TYBHZVUFOINFDV-UHFFFAOYSA-N 2-bromo-6-[(3-bromo-5-chloro-2-hydroxyphenyl)methyl]-4-chlorophenol Chemical compound OC1=C(Br)C=C(Cl)C=C1CC1=CC(Cl)=CC(Br)=C1O TYBHZVUFOINFDV-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000003937 benzamidines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 231100000824 inhalation exposure Toxicity 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 244000005706 microflora Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/528—Carboxylic amides (R1-CO-NR2R3), where at least one of the chains R1, R2 or R3 is interrupted by a functional group, e.g. a -NH-, -NR-, -CO-, or -CON- group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Definitions
- the present invention relates to aqueous foam disinfectants, comprising a surfactant capable of foam formation of nonionic and amphoteric surfactants and a synergistic disinfectant combination.
- the present invention contains a method for foam disinfection of surfaces with the aid of a foam-producing device and the use of the foam disinfectant according to the invention for the disinfection of surfaces.
- compositions which are applied to surfaces in the form of a foam has already been described in various documents.
- An example of this is the German application DE 20 01 317.
- the corresponding formulations contain anionic surfactants such as sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium salts of laurylsaccosinate and, in some instances, surfactants which further enhance the stability of the foam, such as lauryldiethanolamide.
- anionic surfactants such as sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium salts of laurylsaccosinate and, in some instances, surfactants which further enhance the stability of the foam, such as lauryldiethanolamide.
- foam-forming formulations when spraying, droplets of a size arise which, due to their dimension, can not be expected to produce any relevant inhalation exposure. This is particularly important in the use of microbicides or other formulation ingredients that have potentially irritating or corrosive properties.
- the surfactant systems commonly used are not equally effective in all formulations. reversible. In particular, when it comes to formulating formulations with aminic or cationic biocides, anionic surfactants are not benign because of possible precipitations.
- the present invention was primarily concerned with finding new combinations of foamable surfactant systems and amine biocides in combination with other antimicrobial agents.
- the present invention provides foam disinfectants comprising from 0.1 to 10% by weight of a surfactant system comprising nonionic and amphoteric surfactants capable of foaming in contact with amines, and a synergistic disinfectant combination consisting of an antimicrobial agent having amino groups and at least one other antimicrobial agent.
- foam disinfectants which, as a surfactant system, comprise nonionic surfactants selected from the groups of fatty alcohols. holethoxylates and alkylpolyglycosides, and amphoteric surfactants selected from the group of acetobetaines.
- the said surfactant system contains at least one surfactant each from the groups of fatty alcohol ethoxylates, alkylpolyglycosides and acetobetaines.
- the said surfactant groups of the fatty alcohol ethoxylates, alkyl polyglycosides and acetobetaines to each other in a weight-amount ratio of (5 to 7) to (2 to 4) to (0.5 to 1, 5).
- the foam disinfectant of the present invention preferably contains an antimicrobial agent having amino groups in an amount of 0.001 to 10% by weight in total, based on the whole agent.
- said antimicrobial agent having amino groups is selected from alkylamines of the formula (I) and / or (II)
- R 1 is -NH- (CH 2 ) 3 NH 2 (I), R 1 is -N - [(CH 2 ) 3 NH 2 ] 2 (H),
- R 1 is an alkyl radical having 8 to 18 C atoms, preferably 12 to 14 C atoms, and / or active compounds which are obtained by reacting a propylenediamine of the formula (I),
- R 1 is -NH- (CH 2 ) 3 NH 2 (I),
- R 2 is -O-CO- (CH 2 ) 2 -CH (NH 2 ) -COOH (III) in which R 2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, and optionally reaction of the product thus obtained with ethylene oxide and / or propylene oxide and optionally further reaction with organic or inorganic acids are obtainable.
- amine-containing microbicides are not easily used.
- the foam disinfectant according to the invention with at least one further antimicrobial active ingredient, preferably selected from the group of monohydric low molecular weight alcohols according to formula (IV),
- R is -C-OH (IV)
- R 3 , R 4 and R 5 independently of one another comprise H atoms or alkyl radicals having in each case 1 to 3 C atoms, the total number of C atoms being not greater than 6, combined.
- the object is achieved particularly well if the foam disinfectant according to the invention contains an alcohol selected from ethanol, 1-propanol and 2-propanol or mixtures thereof, wherein the total content of alcohols, based on the total agent, preferably in total 20 to 50 wt .-% constitutes, particularly preferably 20 to 40 wt .-%.
- the desired foaming and foam stability are particularly pronounced when ethanol and / or i-propanol are present in the foam disinfectant.
- the foam disinfectant according to the invention as antimicrobial active ingredient next to or instead of said alcohol, another antimicrobial component selected from the groups of alcohols not falling under formula (IV), the antimicrobial acids, carboxylic acid esters, acid amides, phenols, Phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1, 2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carbamate, iodine, iodophores, in particular undecylenic acid, citric acid, 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlor
- the foam disinfectant according to the invention contains, based on the total agent,
- Another object of the present invention is a method for foam disinfection of surfaces, in which a foam disinfectant according to the invention is applied with the aid of a foam-generating device, such as a foam spray bottle on said surfaces in the form of a foam, wherein the foam, if desired after sufficient exposure time by rinsing with Water or wiping with textile fabric is removed again.
- a foam-generating device such as a foam spray bottle
- an object of the present invention is the use of the foam disinfectant according to the invention for the disinfection of surfaces.
- the use according to the invention has proved to be particularly useful in the disinfection of surfaces in the medical field, in the food-producing and / or processing industry, in the hotel industry, in public buildings and institutions.
- test solutions E1 to E4 according to the invention and the comparative solutions V1 to V4 according to Table 1 were prepared.
- the bactericidal effectiveness tests were carried out in a quantitative suspension test according to the guidelines of the German Society for Hygiene and Microbiology against the test bacterium Staphylococcus aureus with the undiluted mixtures E1 and E2. The results are summarized in Table 2. It turns out that some of the above mixtures have an excellent effect already after 0.5 minutes (E2) and in particular after 3 minutes.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10228656 | 2002-06-27 | ||
DE10228656A DE10228656A1 (de) | 2002-06-27 | 2002-06-27 | Schaumdesinfektionsmittel |
PCT/EP2003/006498 WO2004003126A1 (de) | 2002-06-27 | 2003-06-20 | Schaumdesinfektionsmittel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1516042A1 true EP1516042A1 (de) | 2005-03-23 |
EP1516042B1 EP1516042B1 (de) | 2006-10-25 |
Family
ID=29761458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03738067A Expired - Lifetime EP1516042B1 (de) | 2002-06-27 | 2003-06-20 | Schaumdesinfektionsmittel |
Country Status (6)
Country | Link |
---|---|
US (1) | US8097265B2 (de) |
EP (1) | EP1516042B1 (de) |
AT (1) | ATE343626T1 (de) |
DE (2) | DE10228656A1 (de) |
PL (1) | PL203184B1 (de) |
WO (1) | WO2004003126A1 (de) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011016452A1 (de) * | 2011-04-08 | 2012-10-11 | Bode Chemie Gmbh | Desinfektionsmittel für Bildschirmoberflächen elektronischer Geräte |
US9920058B2 (en) | 2013-05-06 | 2018-03-20 | Georgia Tech Research Corporation | Molecules with potent DHFR binding affinity and antibacterial activity |
JP6109683B2 (ja) * | 2013-08-23 | 2017-04-05 | 日本曹達株式会社 | 泡状抗菌性組成物 |
DK3015538T3 (da) | 2014-11-03 | 2021-06-14 | Wet Wipe As | Desinfektions- og/eller rengøringsmiddel, anvendelse deraf og fremgangsmåde til desinfektion og/eller ren-gøring af overflader, værktøjer og/eller instrumenter |
FR3037597B1 (fr) * | 2015-06-16 | 2019-05-31 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Mousse aqueuse desinfectante, son procede de preparation et ses utilisations |
US10653658B2 (en) | 2015-08-11 | 2020-05-19 | Akeso Biomedical, Inc. | Biofilm inhibiting compositions enhancing weight gain in livestock |
EP3334439B1 (de) | 2015-08-11 | 2021-10-13 | Akeso Biomedical, Inc. | Antimikrobielle zubereitung und verwendungen davon |
EP3468555B1 (de) | 2016-06-14 | 2023-08-09 | Versitech Limited | Zusammensetzungen zur verwendung bei der behandlung von bakteriellen infektionen |
JP2020534271A (ja) * | 2017-09-15 | 2020-11-26 | ゴジョ・インダストリーズ・インコーポレイテッド | 抗菌組成物 |
WO2019215679A1 (en) | 2018-05-10 | 2019-11-14 | Protair-X Health Solutions, Inc. | Foam sanitizer composition |
EP4227393A1 (de) * | 2022-02-11 | 2023-08-16 | The Procter & Gamble Company | Reinigungsprodukt |
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DE2001317A1 (de) | 1970-01-13 | 1971-07-29 | Hans Schade | Mundpflegemittel |
CH675429A5 (de) | 1988-03-18 | 1990-09-28 | Lonza Ag | |
DE4007758A1 (de) * | 1990-03-12 | 1991-09-19 | Henkel Kgaa | Mittel und verfahren zur reinigung und desinfektion von gegenstaenden aus medizinischen einrichtungen in automatischen anlagen |
DE4234070A1 (de) * | 1992-10-09 | 1994-04-14 | Henkel Ecolab Gmbh & Co Ohg | Reinigendes Desinfektionsmittel |
US5635469A (en) * | 1993-06-10 | 1997-06-03 | The Procter & Gamble Company | Foaming cleansing products |
FR2708278B1 (fr) | 1993-06-28 | 1995-09-08 | Paragerm Snc | Composition nettoyante et désinfectante pour milieu hospitalier. |
US5576284A (en) * | 1994-09-26 | 1996-11-19 | Henkel Kommanditgesellschaft Auf Aktien | Disinfecting cleanser for hard surfaces |
EP2322137A1 (de) * | 1995-06-22 | 2011-05-18 | Minnesota Mining And Manufacturing Company | Stabile alkoholisch-wässrige Zusammensetzung |
DE19615286B4 (de) | 1996-04-18 | 2005-05-19 | Cognis Deutschland Gmbh & Co. Kg | Antimikrobielle Wirkstoffkonzentrate |
DE19652680A1 (de) | 1996-12-18 | 1998-06-25 | Clariant Gmbh | Mischungen von Alkoxylaten mit schaumdämpfender und desinfizierender Wirkung und deren Verwendung in Reinigungsmitteln |
CO5040174A1 (es) | 1997-12-12 | 2001-05-29 | Colgate Palmolive Co | Composiciones antimicrobianas para multiples propositos en microemulsion que contienen un tensioactivo cationico |
US6140289A (en) * | 2000-01-24 | 2000-10-31 | Colgate-Palmolive Company | Antimicrobial cleaning composition containing a cationic surfactant |
US20040200725A1 (en) * | 2003-04-09 | 2004-10-14 | Applied Materials Inc. | Application of antifoaming agent to reduce defects in a semiconductor electrochemical plating process |
-
2002
- 2002-06-27 DE DE10228656A patent/DE10228656A1/de not_active Withdrawn
-
2003
- 2003-06-20 DE DE50305504T patent/DE50305504D1/de not_active Expired - Lifetime
- 2003-06-20 US US10/518,784 patent/US8097265B2/en not_active Expired - Fee Related
- 2003-06-20 PL PL374357A patent/PL203184B1/pl unknown
- 2003-06-20 WO PCT/EP2003/006498 patent/WO2004003126A1/de active IP Right Grant
- 2003-06-20 AT AT03738067T patent/ATE343626T1/de not_active IP Right Cessation
- 2003-06-20 EP EP03738067A patent/EP1516042B1/de not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
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See references of WO2004003126A1 * |
Also Published As
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PL374357A1 (en) | 2005-10-17 |
US8097265B2 (en) | 2012-01-17 |
PL203184B1 (pl) | 2009-09-30 |
US20100111877A1 (en) | 2010-05-06 |
WO2004003126A1 (de) | 2004-01-08 |
DE50305504D1 (de) | 2006-12-07 |
DE10228656A1 (de) | 2004-01-22 |
ATE343626T1 (de) | 2006-11-15 |
EP1516042B1 (de) | 2006-10-25 |
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