EP1471180A2 - Silikonisierte Einlagestoffe, Verfahren zu deren Herstellung und deren Verwendung - Google Patents
Silikonisierte Einlagestoffe, Verfahren zu deren Herstellung und deren Verwendung Download PDFInfo
- Publication number
- EP1471180A2 EP1471180A2 EP04006891A EP04006891A EP1471180A2 EP 1471180 A2 EP1471180 A2 EP 1471180A2 EP 04006891 A EP04006891 A EP 04006891A EP 04006891 A EP04006891 A EP 04006891A EP 1471180 A2 EP1471180 A2 EP 1471180A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- textile
- fabric
- plasma discharge
- textile fabric
- interlining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
- D06M13/507—Organic silicon compounds without carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
Definitions
- the present invention relates to siliconized interlinings, in particular Nonwovens, with a permanent hydrophobization, their production and their use as inlays for textiles.
- WO-A-01 / 40,359 describes the treatment of an organic polymeric material, a substrate containing a polymer being treated with a plasma to which an organosilicon additive has been added. This creates a coating of SiO x groups on the surface of the substrate.
- WO-A-02 / 28,548 describes a method and an apparatus for Create a coating. This creates a finely divided layer-forming Material injected into an atmospheric plasma and strikes on the treating substrate surface. The procedure is suitable especially for the production of organic silicon coatings. As Suitable substrates are also textile fabrics, such as nonwovens, mentioned.
- the material of the Adhesive layer in addition to the connections with the textile also through the insert forming material flows and its properties disadvantageously changed.
- the present Invention textile fabrics are provided which are a combination of Soft feel, smoothness, shine, fullness and elasticity while being excellent Have permanence, which only have small amounts of silicone and which in can be manufactured in a simple and environmentally friendly manner.
- the Interlining materials according to the invention indicate at significantly lower proportions Silicone compared to conventional, wet-chemically manufactured interlinings comparable or even improved properties.
- Another object of the present invention is to provide of textile fabrics that are suitable as textile inserts and a have certain hydrophobicity.
- Another object of the present invention is to provide of hot-glue inserts, in which the hot-glue material at the Exposure to heat glued to the outer fabric.
- Another object of the present invention is to provide of hot-glue interlinings, which after bonding with a textile a have excellent separating power.
- Another object of the present invention is to provide a solvent-free process for the production of siliconized and glued interlinings.
- the present invention relates to interlinings comprising a siliconized Fibrous textile fabric that rests on at least one Surface at least at spatially separate locations thermally softenable adhesive material, the fibers with a Layer of silicon-containing material up to 40 nm thick, preferably from 1 to 10 nm thick.
- the layer of silicon-containing material can be applied by plasma treatment the interlinings are applied, the plasma a) being an organosilicon Material and / or a silane is added in finely divided form or b) the plasma-treated textile fabric is exposed to organic silicon material and / or a silane or c) the Textile fabrics before plasma treatment with a silicon organic material and / or a silane is impregnated.
- Examples of application processes are screen printing processes.
- the textiles required for the production of the interlinings according to the invention Flat structures can be made using all surface-forming techniques getting produced. Examples include weaving, laying, knitting, knitting or wet or dry nonwoven manufacturing processes.
- the textiles used in the interlinings according to the invention Flat structures can be applied in any known manner be produced by a wet or dry route.
- the fleeces can for example spunbond process, carding process, meltblowing process, Wet fleece process, electrostatic spinning or aerodynamic Nonwoven manufacturing processes are used.
- the interlinings according to the invention contain fibers from thread-forming Polymers and are preferably solidified.
- the interlinings according to the invention can be made from any fiber type different diameter ranges exist. Typical fiber diameter range from 0.01 to 200 ⁇ m, preferably 0.05 to 50 ⁇ m.
- these interlinings can consist of staple fibers or contain them.
- heterofil fibers or mixtures of various types can also be used Fiber types are used.
- the textile fabrics according to the invention typically have a weight per unit area of 0.05 to 500 g / m 2 .
- Nonwovens with a low basis weight of 5 to 150 g / m 2 are particularly preferably used.
- polymers are polyesters, especially polyethylene terephthalate, Polybutylene terephthalate or copolymers containing polyethylene terephthalate units or polybutylene terephthalate units, polyamides, in particular from aliphatic diamines and dicarboxylic acids, from alphatic aminocarboxylic acids or polyamides derived from aliphatic lactams, or aramids, that is, polyamides derived from aromatic diamines and dicarboxylic acid, Polyvinyl alcohol, viscose or mixtures of two or more of these Polymers.
- polyesters especially polyethylene terephthalate, Polybutylene terephthalate or copolymers containing polyethylene terephthalate units or polybutylene terephthalate units
- polyamides in particular from aliphatic diamines and dicarboxylic acids, from alphatic aminocarboxylic acids or polyamides derived from aliphatic lactams, or aramids, that is,
- Interlinings according to the invention can be solidified in a manner known per se be, for example by mechanical or hydraulic needling, by Melting of binding fibers in the interlining material through thermal mechanical Solidify or by applying binders.
- the interlinings according to the invention are characterized by a Plasma treatment can be made.
- the Fibers of the interlining formed thin layers containing silicon on the one hand a blocking effect for the superficially applied adhesive cause and on the other hand the grip of the interlining as a result of improved Significantly improve fiber-to-fiber lubrication.
- the layer thicknesses are in the range specified above and can e.g. by means of Determine X-ray photoelectron spectroscopy. Doing so Layer thicknesses of up to 10 nm determine what the theoretical Depth of information corresponds to this surface analysis method. larger Layer thicknesses can be determined using AFM, ellipsometry or SEM.
- interlining materials according to the invention are also minor Shares, for example up to 10 vol.%, May have, as in the interior of the plasma-treated, siliconized textile fabrics, in which fibers occur without a silicon-containing layer. However, all fibers preferably have of the interlining according to the invention on silicon-containing layers.
- the method according to the invention is characterized by a low material and Energy consumption from and as a solvent-free process through a Protection of the environment.
- the interlinings have a silicon-containing layer which is covalently bonded to the fiber surface.
- the silicon-containing layer is additionally cross-linked. This increases the life of this layer.
- Alkylsilanes or alkoxysilanes are used to produce such flat structures: for example methylhydrogen silanes, tri- or tetraalkoxysilanes and triaminoalkylsilanes. Instead of this or in a mixture with it, silanes, for example SiH 4 or Si 2 H 6 , can also be used.
- thermoplastic polymers which at temperatures below the melting or Decomposition point of the fibers, which the interlining material and thus too form connecting textile, melt.
- adhesive materials are polyamides, polyesters, thermoplastic Polyurethanes, polyolefins, vinyl copolymers or mixtures of two or more of these polymers.
- the thermally softenable adhesive material can be siliconized on at least one Surface of the interlining can be applied in any shape, and for example in the form of a coating or in the form of dots or Lines or other geometric figures can be arranged.
- the thermally softenable adhesive material is in the form of a regular pattern applied on a surface.
- the former is particularly preferred.
- the plasma treatment is carried out by continuously guiding the textile Flat structure through the plasma discharge.
- Typical train speeds are 0.5 - 400 m / min.
- a wide variety of plasma treatments can be used. Examples of this are discharges under negative pressure, but especially with Atmospheric pressure.
- Plasmas under atmospheric pressure are preferred, in particular Glow discharges and discharges on electrodes with dielectric barriers (Barrier discharge).
- the treatment is preferably carried out in a non-oxidizing atmosphere with e.g. an inert gas, such as helium as an inert gas, at atmospheric pressure carried out. It can add reactive gases or additives in the Plasma may be included. Typical working pressures in plasma are 0.7 to 1.3 bar, preferably 0.9 to 1.1 bar.
- organosilicon compounds used are monomeric or to understand polymeric compounds, in addition to at least one Silicon atom at least one organic group, such as an alkyl, cycloalkyl, Aryl (including the heteroaryl) or aralkyl group. This can either be bound directly to the silicon atom or via a heteroatom, like the oxygen atom. Furthermore, the organic group can in turn be substituted, for example with halogen atoms or alkyl groups.
- silicon hydrides can also be used. This means compounds of the general formula Si n H 2n + 2, in which n is an integer of at least 1, for example 1 to 4. SiH 4 is preferred.
- Suitable organosilicon compounds are organosilanes or Organosiloxanes, such as alkyl or alkoxysilanes; or linear polyorganosiloxanes, such as poly-dialkyl siloxanes, e.g. Poly-dimethyl-siloxane or poly-dimethoxysiloxane; or cyclic polyorganosiloxanes, such as cyclic polydialkylsiloxanes, e.g. Octamethylcyclotetrasiloxane.
- the organosilane or organosiloxane have further atoms, such as hydrogen, Nitrogen and / or halogen atoms. These leftovers are right on the Silicon atom bound.
- organosilicon compounds or silanes are used.
- Plasma discharge in a non-oxidizing atmosphere is preferred carried out.
- the interlinings according to the invention are reinforced with a textile outer fabric glued in a conventional manner.
- the invention relates to the use of plasma-treated siliconized textile fabrics as interlinings.
- a nonwoven fabric made from polyethylene terephthalate (“PET”) and polyamide fibers (“PA”) was exposed to an atmospheric pressure plasma functionalized. Helium was used as an inert gas and as a reactive substance Tetramethylcyclotetrasiloxane used. During the plasma treatment was worked in the absence of oxygen. The nonwoven samples showed excellent hydrophobic properties (water contact angle> 100 °). Then, on a siliconized side of the nonwoven fabric Adhesive dots applied from polyamide. It turned out that the siliconization prevented the glue dots spread on the surface of the material could flow through the nonwoven when heated. The quality of the bond after pressing with a cotton fabric in one Tear test assessed. The separation force was for the sample described above 8 N / 5cm. The assessment of the association was excellent.
- a nonwoven made of PET / PA fibers was made under the influence of a Functionalized atmospheric pressure plasma. There were helium as inert gas and Octamethylcyclotetrasiloxane used as a reactive substance. During the Plasma treatment was carried out in the absence of oxygen to achieve a Avoid oxidation of the reagent. The nonwoven samples show excellent grip properties. The separating force after bonding with Cotton fabric was 10.4 N / 5 cm. The practical assessment of the Verbund was also excellent.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Claims (12)
- Einlagestoff umfassend ein silikonisierte Fasern aufweisendes textiles Flächengebilde, der auf mindestens einer Oberfläche zumindest an örtlich getrennten Stellen eine Beschichtung aus thermisch erweichbarem Haftmaterial aufweist, wobei die Fasern mit einer Schicht aus siliziumhaltigem Material von bis zu 40 nm Dicke versehen sind.
- Einlagestoff nach Anspruch 1, dadurch gekennzeichnet, dass die Dicke der Schicht aus siliziumorganischem Material 1 bis 10 nm beträgt.
- Einlagestoff nach Anspruch 1, dadurch gekennzeichnet, dass das textile Flächengebilde ein Gewebe, Gestrick, Gelege, Gewirke oder insbesondere ein Vliesstoff ist.
- Einlagestoff nach Anspruch 1, dadurch gekennzeichnet, dass dieser Fasern enthält, die ausgewählt werden aus der Gruppe bestehend aus Polyamidfasern, Polyesterfasern, Aramidfasern, Polyvinylalkoholfasern, Viskosefasern oder Gemischen von zweien oder mehreren davon.
- Einlagestoff nach Anspruch 1, dadurch gekennzeichnet, dass das thermisch erweichbare Haftmaterial ausgewählt wird aus der Gruppe bestehend aus Polyestern, Polyamiden, thermoplastischen Polyurethanen, Polyolefinen, Vinylcopolymerisaten und Mischungen davon.
- Einlagestoff nach Anspruch 1, dadurch gekennzeichnet, dass das thermisch erweichbare Haftmaterial in der Form eines regelmäßigen Musters auf einer Oberfläche aufgetragen ist.
- Verfahren zur Herstellung eines Einlagestoffes nach Anspruch 1 umfassend die Schritte:a) Herstellung eines textilen Flächengebildes durch eine textile Flächenbildungstechnik in an sich bekannter Weise,b) Bereitstellen eines Raumbereiches, in dem eine Plasmaentladung brennt und in dem mindestens eine siliziumorganische Verbindung und/oder mindestens ein Silan in feinverteilter Form vorliegt,c) Transport des textilen Flächengebildes durch den Raumbereich, in dem die Plasmaentladung brennt, so dass das textile Flächengebilde der Plasmaentladung ausgesetzt wird, undd) Aufbringen eines thermisch erweichbaren Haftmaterials in vorbestimmten Bereichen mindestens einer Oberfläche des plasmabehandelten textilen Flächengebildes.
- Verfahren zur Herstellung eines Einlagestoffes nach Anspruch 1 umfassend die Schritte:a) Herstellung eines textilen Flächengebildes durch eine textile Flächenbildungstechnik in an sich bekannter Weise,a') Imprägnieren des textilen Flächengebildes mit mindestens einer siliziumorganischen Verbindung und/oder mit mindestens einem Silan,b) Bereitstellen eines Raumbereiches, in dem eine Plasmaentladung brennt und in dem gegebenenfalls mindestens eine siliziumorganische Verbindung und/oder mindestens ein Silan in feinverteilter Form vorliegt,c) Transport des textilen Flächengebildes durch den Raumbereich, in dem die Plasmaentladung brennt, so dass das textile Flächengebilde der Plasmaentladung ausgesetzt wird, undd) Aufbringen eines thermisch erweichbaren Haftmaterials in vorbestimmten Bereichen mindestens einer Oberfläche des plasmabehandelten textilen Flächengebildes.
- Verfahren zur Herstellung eines Einlagestoffes nach Anspruch 1 umfassend die Schritte:a) Herstellung eines textilen Flächengebildes durch eine textile Flächenbildungstechnik in an sich bekannter Weise,b) Bereitstellen eines Raumbereiches, in dem eine Plasmaentladung brennt und in dem gegebenenfalls mindestens eine siliziumorganische Verbindung und/oder mindestens ein Silan in feinverteilter Form vorliegt,c) Transport des textilen Flächengebildes durch den Raumbereich, in dem die Plasmaentladung brennt, so dass das textile Flächengebilde der Plasmaentladung ausgesetzt wird,c') Imprägnieren des plasmabehandelten textilen Flächengebildes mit mindestens einer siliziumorganischen Verbindung und/oder mit mindestens einem Silan, undd) Aufbringen eines thermisch erweichbaren Haftmaterials in vorbestimmten Bereichen mindestens einer Oberfläche des plasmabehandelten textilen Flächengebildes.
- Verfahren nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass die Plasmaentladung in Luft bei Drucken zwischen 0,7 und 1,3 bar durchgeführt wird.
- Verfahren nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass die Plasmaentladung in nicht-oxidierender Atmosphäre erfolgt, insbesondere unter Einsatz von Helium als Inertgas.
- Verwendung von plasmabehandelten silikonisierten textilen Flächengebilden als Einlagestoffe.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2003119058 DE10319058A1 (de) | 2003-04-25 | 2003-04-25 | Silikonisierte Einlagestoffe, Verfahren zu deren Herstellung und deren Verwendung |
DE10319058 | 2003-04-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1471180A2 true EP1471180A2 (de) | 2004-10-27 |
EP1471180A3 EP1471180A3 (de) | 2006-03-22 |
Family
ID=32946452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04006891A Withdrawn EP1471180A3 (de) | 2003-04-25 | 2004-03-23 | Silikonisierte Einlagestoffe, Verfahren zu deren Herstellung und deren Verwendung |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP1471180A3 (de) |
DE (1) | DE10319058A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008022682A1 (de) * | 2006-08-23 | 2008-02-28 | Carl Freudenberg Kg | Vliesstoffe mit positivem zeta-potenzial |
GB2461332A (en) * | 2008-06-23 | 2010-01-06 | Bondmor Ltd | A method of adhering an adhesive to a fabric piece |
CN109137476A (zh) * | 2018-09-11 | 2019-01-04 | 南通大学 | 一种基于TiO2纳米管的仿生超疏水棉织物的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001040359A1 (en) * | 1999-12-02 | 2001-06-07 | Dow Corning Limited | Surface treatment of an organic polymeric material |
WO2002028548A2 (en) * | 2000-10-04 | 2002-04-11 | Dow Corning Ireland Limited | Method and apparatus for forming a coating |
-
2003
- 2003-04-25 DE DE2003119058 patent/DE10319058A1/de not_active Ceased
-
2004
- 2004-03-23 EP EP04006891A patent/EP1471180A3/de not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001040359A1 (en) * | 1999-12-02 | 2001-06-07 | Dow Corning Limited | Surface treatment of an organic polymeric material |
WO2002028548A2 (en) * | 2000-10-04 | 2002-04-11 | Dow Corning Ireland Limited | Method and apparatus for forming a coating |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008022682A1 (de) * | 2006-08-23 | 2008-02-28 | Carl Freudenberg Kg | Vliesstoffe mit positivem zeta-potenzial |
GB2461332A (en) * | 2008-06-23 | 2010-01-06 | Bondmor Ltd | A method of adhering an adhesive to a fabric piece |
CN109137476A (zh) * | 2018-09-11 | 2019-01-04 | 南通大学 | 一种基于TiO2纳米管的仿生超疏水棉织物的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE10319058A1 (de) | 2004-12-02 |
EP1471180A3 (de) | 2006-03-22 |
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