EP1358387A2 - Crosslinked cellulosic product formed by extrusion process - Google Patents
Crosslinked cellulosic product formed by extrusion processInfo
- Publication number
- EP1358387A2 EP1358387A2 EP01993208A EP01993208A EP1358387A2 EP 1358387 A2 EP1358387 A2 EP 1358387A2 EP 01993208 A EP01993208 A EP 01993208A EP 01993208 A EP01993208 A EP 01993208A EP 1358387 A2 EP1358387 A2 EP 1358387A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- sep
- composite
- fibers
- foam
- crosslinked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 142
- 238000001125 extrusion Methods 0.000 title claims description 34
- 230000008569 process Effects 0.000 title description 87
- 239000000835 fiber Substances 0.000 claims abstract description 302
- 239000000463 material Substances 0.000 claims abstract description 71
- 239000002250 absorbent Substances 0.000 claims abstract description 44
- 230000002745 absorbent Effects 0.000 claims abstract description 44
- 239000002131 composite material Substances 0.000 claims description 163
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 113
- 239000006260 foam Substances 0.000 claims description 91
- 239000004816 latex Substances 0.000 claims description 44
- 229920000126 latex Polymers 0.000 claims description 44
- 239000003431 cross linking reagent Substances 0.000 claims description 43
- 238000003795 desorption Methods 0.000 claims description 38
- 239000004094 surface-active agent Substances 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 34
- 239000003570 air Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 24
- 229920002125 Sokalan® Polymers 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 17
- 239000004584 polyacrylic acid Substances 0.000 claims description 17
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 5
- 238000011065 in-situ storage Methods 0.000 abstract description 32
- 239000007767 bonding agent Substances 0.000 abstract description 11
- 229910001868 water Inorganic materials 0.000 description 46
- 235000015165 citric acid Nutrition 0.000 description 41
- 239000011148 porous material Substances 0.000 description 41
- 238000004132 cross linking Methods 0.000 description 33
- 239000011230 binding agent Substances 0.000 description 25
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 24
- 235000011613 Pinus brutia Nutrition 0.000 description 24
- 241000018646 Pinus brutia Species 0.000 description 24
- 238000009826 distribution Methods 0.000 description 24
- 238000013461 design Methods 0.000 description 23
- 230000000694 effects Effects 0.000 description 22
- 239000002245 particle Substances 0.000 description 21
- -1 methylolated ureas Chemical class 0.000 description 15
- 229920003043 Cellulose fiber Polymers 0.000 description 12
- 235000005018 Pinus echinata Nutrition 0.000 description 12
- 241001236219 Pinus echinata Species 0.000 description 12
- 235000017339 Pinus palustris Nutrition 0.000 description 12
- 235000013877 carbamide Nutrition 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 238000007792 addition Methods 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 241000219492 Quercus Species 0.000 description 9
- 235000016976 Quercus macrolepis Nutrition 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229920001131 Pulp (paper) Polymers 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 238000005187 foaming Methods 0.000 description 8
- 230000001965 increasing effect Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000011162 core material Substances 0.000 description 7
- 239000000123 paper Substances 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 6
- 239000001913 cellulose Substances 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 229920000058 polyacrylate Polymers 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920002994 synthetic fiber Polymers 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000012209 synthetic fiber Substances 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 206010021639 Incontinence Diseases 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- 238000000280 densification Methods 0.000 description 4
- 229920002401 polyacrylamide Polymers 0.000 description 4
- 239000013055 pulp slurry Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 229920000247 superabsorbent polymer Polymers 0.000 description 4
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 3
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 239000000017 hydrogel Substances 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 150000003672 ureas Chemical class 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LGJMYGMNWHYGCB-UHFFFAOYSA-N 4,5-dihydroxy-1,3-dimethylimidazolidin-2-one Chemical compound CN1C(O)C(O)N(C)C1=O LGJMYGMNWHYGCB-UHFFFAOYSA-N 0.000 description 2
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920013683 Celanese Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001444 polymaleic acid Polymers 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- CEGRHPCDLKAHJD-UHFFFAOYSA-N 1,1,1-propanetricarboxylic acid Chemical compound CCC(C(O)=O)(C(O)=O)C(O)=O CEGRHPCDLKAHJD-UHFFFAOYSA-N 0.000 description 1
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 1
- YORGLSZZMFADAJ-UHFFFAOYSA-N 1,3-dihydroxy-1,3-dimethylurea Chemical compound CN(O)C(=O)N(C)O YORGLSZZMFADAJ-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- ZMGMDXCADSRNCX-UHFFFAOYSA-N 5,6-dihydroxy-1,3-diazepan-2-one Chemical class OC1CNC(=O)NCC1O ZMGMDXCADSRNCX-UHFFFAOYSA-N 0.000 description 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical group FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920002785 Croscarmellose sodium Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- MIGNWTQKRPNYLP-UHFFFAOYSA-N but-2-ene-2,3-diol urea Chemical compound NC(=O)N.OC(=C(C)O)C MIGNWTQKRPNYLP-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- HXDRSFFFXJISME-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O HXDRSFFFXJISME-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- VSEAAEQOQBMPQF-UHFFFAOYSA-N morpholin-3-one Chemical compound O=C1COCCN1 VSEAAEQOQBMPQF-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007652 sheet-forming process Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
- D21H11/20—Chemically or biochemically modified fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/002—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines by using a foamed suspension
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21J—FIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
- D21J3/00—Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Nonwoven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US24852000P | 2000-11-14 | 2000-11-14 | |
US248520P | 2000-11-14 | ||
PCT/US2001/045791 WO2002055774A2 (en) | 2000-11-14 | 2001-11-14 | Crosslinked cellulosic product formed by extrusion process |
Publications (1)
Publication Number | Publication Date |
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EP1358387A2 true EP1358387A2 (en) | 2003-11-05 |
Family
ID=22939511
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01993208A Withdrawn EP1358387A2 (en) | 2000-11-14 | 2001-11-14 | Crosslinked cellulosic product formed by extrusion process |
Country Status (10)
Country | Link |
---|---|
US (1) | US20020088581A1 (ja) |
EP (1) | EP1358387A2 (ja) |
JP (1) | JP2004523669A (ja) |
CN (1) | CN1474895A (ja) |
AU (1) | AU2002245063A1 (ja) |
BR (1) | BR0115337A (ja) |
CA (1) | CA2427910A1 (ja) |
MX (1) | MXPA03004204A (ja) |
NO (1) | NO20032128L (ja) |
WO (1) | WO2002055774A2 (ja) |
Families Citing this family (20)
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JP3558638B2 (ja) * | 1994-03-25 | 2004-08-25 | ウェヤーハウザー・カンパニー | 嵩高いセルロース繊維を用いているマルチプライセルロース製品 |
EP1634996A1 (en) * | 2004-09-10 | 2006-03-15 | Chi-Yee Yeh | A method for producing paper pulp molded products of non-paper pulp natural fibers |
US8785714B2 (en) | 2011-02-28 | 2014-07-22 | Celanese International Corporation | Alkali neutralizing acquisition and distribution structures for use in personal care articles |
JP6397012B2 (ja) * | 2013-11-05 | 2018-09-26 | エフピーイノベイションズ | 超低密度繊維複合材料の生産方法 |
SE538770C2 (sv) * | 2014-05-08 | 2016-11-15 | Stora Enso Oyj | Förfarande för framställning av ett termoplastiskt fiberkompositmaterial och en väv |
US9458297B2 (en) * | 2014-06-30 | 2016-10-04 | Weyerhaeuser Nr Company | Modified fiber, methods, and systems |
US20160009050A1 (en) * | 2014-07-08 | 2016-01-14 | Gary M. Crowel | Concrete Curing Blanket |
SE539865C2 (en) * | 2014-10-03 | 2017-12-27 | Stora Enso Oyj | Method for producing a foam web involving electron beam radiation |
FI126474B (en) * | 2014-11-24 | 2016-12-30 | Paptic Oy | Fiber sheets and structures comprising fiber sheets |
SE1550985A1 (sv) * | 2015-07-07 | 2016-09-06 | Stora Enso Oyj | Shaped tray or plate of fibrous material and a method of manufacturing the same |
KR102196197B1 (ko) * | 2015-09-18 | 2020-12-29 | 오지 홀딩스 가부시키가이샤 | 적층체 |
WO2017079169A1 (en) | 2015-11-03 | 2017-05-11 | Kimberly-Clark Worldwide, Inc. | Paper tissue with high bulk and low lint |
US9926665B2 (en) | 2016-02-25 | 2018-03-27 | International Paper Company | Crosslinked cellulose as precursor in production of high-grade cellulose derivatives and related technology |
MX2019006196A (es) | 2016-12-22 | 2019-08-21 | Kimberly Clark Co | Proceso y sistema para reorientar fibras en proceso de formacion de espuma. |
US10751910B1 (en) * | 2017-11-29 | 2020-08-25 | Ramshorn Corporation | Concrete curing blanket |
WO2019108172A1 (en) | 2017-11-29 | 2019-06-06 | Kimberly-Clark Worldwide, Inc. | Fibrous sheet with improved properties |
SE541870C2 (en) * | 2017-12-21 | 2020-01-02 | Stora Enso Oyj | Improved process for manufacturing composite product |
BR112021001335B1 (pt) | 2018-07-25 | 2024-03-05 | Kimberly-Clark Worldwide, Inc | Método para fazer um substrato absorvente não tecido tridimensional (3d) |
US11352748B2 (en) | 2018-07-31 | 2022-06-07 | International Paper Company | Crosslinked pulps, cellulose ether products made therefrom; and related methods of making pulps and cellulose ether products |
EP3812419A1 (en) | 2019-10-23 | 2021-04-28 | Weidmann Holding AG | Microfibrillated cellulose-loaded foam, method of producing such foam and use of such a foam |
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-
2001
- 2001-11-14 JP JP2002556414A patent/JP2004523669A/ja active Pending
- 2001-11-14 AU AU2002245063A patent/AU2002245063A1/en not_active Abandoned
- 2001-11-14 EP EP01993208A patent/EP1358387A2/en not_active Withdrawn
- 2001-11-14 MX MXPA03004204A patent/MXPA03004204A/es not_active Application Discontinuation
- 2001-11-14 BR BR0115337-4A patent/BR0115337A/pt not_active IP Right Cessation
- 2001-11-14 US US10/002,844 patent/US20020088581A1/en not_active Abandoned
- 2001-11-14 CA CA002427910A patent/CA2427910A1/en not_active Abandoned
- 2001-11-14 CN CNA018188494A patent/CN1474895A/zh active Pending
- 2001-11-14 WO PCT/US2001/045791 patent/WO2002055774A2/en not_active Application Discontinuation
-
2003
- 2003-05-12 NO NO20032128A patent/NO20032128L/no unknown
Non-Patent Citations (1)
Title |
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See references of WO02055774A3 * |
Also Published As
Publication number | Publication date |
---|---|
WO2002055774A3 (en) | 2002-11-21 |
WO2002055774A2 (en) | 2002-07-18 |
BR0115337A (pt) | 2003-08-26 |
NO20032128D0 (no) | 2003-05-12 |
NO20032128L (no) | 2003-07-10 |
MXPA03004204A (es) | 2003-09-22 |
US20020088581A1 (en) | 2002-07-11 |
AU2002245063A1 (en) | 2002-07-24 |
CN1474895A (zh) | 2004-02-11 |
JP2004523669A (ja) | 2004-08-05 |
CA2427910A1 (en) | 2002-07-18 |
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