EP1357081A1 - Maschine zum aseptischen Abfüllen - Google Patents
Maschine zum aseptischen Abfüllen Download PDFInfo
- Publication number
- EP1357081A1 EP1357081A1 EP02008930A EP02008930A EP1357081A1 EP 1357081 A1 EP1357081 A1 EP 1357081A1 EP 02008930 A EP02008930 A EP 02008930A EP 02008930 A EP02008930 A EP 02008930A EP 1357081 A1 EP1357081 A1 EP 1357081A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- room
- bottles
- machine
- sterile air
- dosing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C7/00—Concurrent cleaning, filling, and closing of bottles; Processes or devices for at least two of these operations
- B67C7/0073—Sterilising, aseptic filling and closing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C2003/228—Aseptic features
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/26—Filling-heads; Means for engaging filling-heads with bottle necks
- B67C2003/2688—Means for filling containers in defined atmospheric conditions
- B67C2003/2694—Means for filling containers in defined atmospheric conditions by enclosing a set of containers in a chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/26—Filling-heads; Means for engaging filling-heads with bottle necks
- B67C2003/2688—Means for filling containers in defined atmospheric conditions
- B67C2003/2697—Means for filling containers in defined atmospheric conditions by enclosing the container partly in a chamber
Definitions
- This invention introduces a new aseptic filling technology for plastic bottles made of PET, PE, PEHD, polypropylene or other hygienically compatible plastics, which is applied to aseptic product packing machines with a rotary or carousel-based concept.
- Aseptic product packing in plastic bottles is a fairly recent technology. It has developed in the last years especially for products like fruit juices, tea, soft drinks, milk and its byproducts, going hand in hand with companies offering their new technological solutions for this field and, of course, with the market's interest for them to be applied.
- This kind of packing is a complex technology, which implies several stages and depends on the type, shape and condition of the original bottle, as well as on the product itself. It requires interventions by machine operators to be reduced to the lowest possible degree and to be carried out under the safest conditions in order to preclude the possibility of contamination of the machine, in particular of its internal microclimate and, as a consequence, of the product.
- Bottles belonging to the first group can be produced aseptically (i.e. completely closed) or else not hermetically (their inner part is open to the surrounding air). PET bottles are produced from preforms that are open to the ambient air, and therefore they are always blown under non-sterile conditions. In both cases, the bottles can be either produced at the product packing factory or bought from a specialized producer, who will deliver them arranged on pallets or in bulk within proper containers. Regardless of their delivery format, however, all bottles destined to aseptic packing undergo one of two different procedures, depending on their production:
- Procedure no. 1 non-aseptically produced bottles (all bottles described under "b") and non-hermetic bottles (described under "a"):
- First solution The whole machine is positioned inside a cleanroom, where sterile air (filtered in Class 1000 or Class 100) flows into; a slight overpressure is to be found in this environment.
- sterile air filtered in Class 1000 or Class 100
- the machine operator is part of the microclimate and integrates the operational cycle of the machine.
- Second solution - Proper laminar flows are generated in order to protect each machine's section (mini-cleanrooms in each section) enclosed by an upper wall (purposely built to support the filters), a lower wall (machine base) and a rigid side wall (sheet steel and/or glass) or alternatively a flexible side wall (transparent plastic material for the food industry).
- the machine operator can intervene from outside, working on the machine through openings dislocated in strategically optimal positions in the side walls, his arms covered by long flexible gloves (“sleeves”): they are fixed to the openings and thus always inside the aseptic environment, therefore a part of the internal microclimate. Although they cannot be contaminated from outside, they restrict intervention possibilities for the machine operator.
- the most critical sections in the machine are the dosing and cap application sections, where both the bottle and the product are most exposed to possible environmental contamination.
- the sterilization section instead, the chemical agents' vapours protect the microclimate against bacteria possibly coming from outside.
- the first two sections are also more frequently subject to intervention by the machine operator, for instance in case of wrong measuring up of the product, loss of closures or aluminium caps, stuck bottles and caps and so on. A wrong intervention in this area determines severe problems and may make it necessary to carry out a new sanitization cycle of the whole machine.
- This invention aims at creating a protection room for the dosing and cap application area that facilitates interventions by the machine operator, ensuring highest sterility and aseptic conditions at the same time, and reducing the need for intervention from outside - but above all also making it possible to clean and sterilize the machine in its dosing and cap application sections with chemical cleaning and sterilization solutions every time that the machine is to be prepared for production.
- the filling and closing room is regularly sterilized by means of traditional methods every time that the cleaning and sterilization phases of the main dosing unit and of the dosing nozzles are started. This ensures that the most critical environment is completely sanitized at every production start.
- this invention enables the operator to have direct access to stuck bottles through passages purposely planned in the room: wearing only a protective glove, he will be able to extract the bottle/cap without contaminating the environment.
- a third benefit given by this invention is the stationary part of the room, that makes it possible to create a safe and rigid connection between the room and the sterile air generation system, as well as the cleaning solution infeed and recovery systems. This concept makes the room independent of the other sections of the machine as a whole.
- the invention is the special configuration of the enclosing room containing the dosing and cap application sections, wich can be applied to any machine with a rotary or carousel-based concept for bottling products destined to the food industry and/or to the chemical and pharmaceutical industry. It is made of two sections and a series of accessories: the room contains two smaller rooms, the first protecting the filling and cap application area, the second enclosing the bottle's body. This concept may include two additional rooms to enable sterile air to be taken in.
- the upper room (C1) is absolutely essential, the lower room (C2) and the other rooms (C3) are useful but not strictly necessary, as the internal microclimate is maintained by the internal room with proper overpressure.
- This invention aims at obtaining an easier and safer process of aseptic filling for plastic bottles, regardless of their specific material, without using standard traditional cleanrooms or else laminar flows, but by making use of a room enclosing the critical area and consisting of two sections; both sections are purposely developed in order to best serve their functional purpose, minimizing the sterile room's volume, that is to say reducing it to the critical area comprising the bottle's neck and the lower part of the nozzles and of the closer.
- This is certainly an innovative solution: besides the advantages presented above, this invention also makes it possible to intervene directly on all mechanical parts of the machine without altering the microclimate in the filling area; thanks to this solution, any intervention becomes simpler and safer.
- sterile air is no more top-down distributed only through the filters, but it is now fed through apposite pipes and circuits, resulting in a better flow distribution and a more accurate control of the positive pressure, and offering better guarantees in terms of functionality.
Landscapes
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
- Auxiliary Devices For And Details Of Packaging Control (AREA)
- Basic Packing Technique (AREA)
- Formation And Processing Of Food Products (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT02008930T ATE289278T1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen abfüllen |
DE60222588T DE60222588T2 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
EP02008930A EP1357081B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
ES02008930T ES2233737T3 (es) | 2002-04-22 | 2002-04-22 | Maquina para llenado en condiciones asepticas. |
ES04005910T ES2289376T3 (es) | 2002-04-22 | 2002-04-22 | Maquina para llenado en condiciones asepticas. |
AT04005910T ATE373621T1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen abfüllen |
DE60202995T DE60202995T2 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
EP04005910A EP1468959B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02008930A EP1357081B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04005910A Division EP1468959B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1357081A1 true EP1357081A1 (de) | 2003-10-29 |
EP1357081B1 EP1357081B1 (de) | 2005-02-16 |
Family
ID=28685869
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04005910A Expired - Lifetime EP1468959B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
EP02008930A Expired - Lifetime EP1357081B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04005910A Expired - Lifetime EP1468959B1 (de) | 2002-04-22 | 2002-04-22 | Maschine zum aseptischen Abfüllen |
Country Status (4)
Country | Link |
---|---|
EP (2) | EP1468959B1 (de) |
AT (2) | ATE289278T1 (de) |
DE (2) | DE60222588T2 (de) |
ES (2) | ES2289376T3 (de) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10326618A1 (de) * | 2003-06-13 | 2005-01-05 | Khs Maschinen- Und Anlagenbau Ag, Patentabteilung | Behälterbehandlungsmaschine |
WO2005056465A1 (de) * | 2003-12-11 | 2005-06-23 | Poepplau Jens H | Behälterbehandlungsvorrichtung mit gasvorhang |
EP1369379B1 (de) * | 2002-06-07 | 2006-10-25 | Shikoku Kakoki Co., Ltd. | Rotierende aseptische Füllvorrichtung |
WO2010000431A1 (de) | 2008-06-30 | 2010-01-07 | Khs Ag | Füllsystem |
CN102408088A (zh) * | 2011-11-08 | 2012-04-11 | 金坛市新鑫包装机械有限公司 | 液体灌装机的多头同步充填装置 |
CN102717932A (zh) * | 2010-12-16 | 2012-10-10 | 克朗斯股份有限公司 | 容器灭菌设备 |
CN104370257A (zh) * | 2014-10-29 | 2015-02-25 | 广州达意隆包装机械股份有限公司 | 封闭式灌装机 |
US8985990B2 (en) | 2008-08-18 | 2015-03-24 | Krones Ag | Apparatus for shaping plastic preforms, comprising a sterile chamber |
WO2016108124A1 (en) | 2014-12-30 | 2016-07-07 | Gea Procomac S.P.A. | Process station for a parison or a container made of thermoplastic material, apparatus for processing parisons or containers, production and packaging line for producing and packaging the containers and method for producing and packaging containers |
WO2016108125A1 (en) | 2014-12-30 | 2016-07-07 | Gea Procomac S.P.A. | Apparatus and method for filling containers |
WO2020025224A1 (en) | 2018-07-31 | 2020-02-06 | Gea Procomac S.P.A. | Apparatus and process for decontaminating the mouth of a parison or container in thermoplastic material |
WO2021018541A1 (de) * | 2019-07-26 | 2021-02-04 | Khs Gmbh | Behandlungsvorrichtung und verfahren zur behandlung von behältern und/oder vorformlingen unter aseptischen bedingungen |
JP2021509878A (ja) * | 2017-12-18 | 2021-04-08 | エス.アイ.ピー.エイ.ソシエタ’インダストリアリザッジオーネ プロゲッタジオーネ エ オートマジオーネ ソシエタ ペル アチオニ | 熱可塑性素材の容器を製造するシステム及び方法 |
CN116553463A (zh) * | 2023-06-30 | 2023-08-08 | 中科圣杰(深圳)科技集团有限公司 | 一种无菌灌装隔离*** |
CN117342075A (zh) * | 2023-12-06 | 2024-01-05 | 正当年医药科技(广州)有限公司 | 一种高效同步智能灌装灭菌包装设备及工艺 |
CN117774432A (zh) * | 2024-02-27 | 2024-03-29 | 南昌大学第一附属医院 | 一种细菌培养基挤出装置 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006007367B4 (de) * | 2006-02-17 | 2016-03-24 | Khs Gmbh | Anlage oder Vorrichtung zum Behandeln von Flaschen. |
DE102006053193A1 (de) * | 2006-11-09 | 2008-05-15 | Krones Ag | Vorrichtung und Verfahren zur Herstellung von Kunststoffbehältern |
DE102008026632A1 (de) * | 2008-06-04 | 2009-12-10 | Khs Ag | Verschließmaschine |
DE102009040924A1 (de) * | 2009-09-11 | 2011-03-24 | Khs Gmbh | Anlage zum sterilen Abfüllen von Produkten, insbesondere von Getränken in Flaschen oder dergleichen Behälter |
DE102012009206A1 (de) * | 2012-05-10 | 2013-11-14 | Khs Gmbh | Füllmaschine |
DE102015118671A1 (de) | 2015-10-30 | 2017-05-04 | Krones Ag | Vorrichtung zum Befüllen von Behältern mit einem Füllprodukt |
EP3757024A1 (de) * | 2019-06-25 | 2020-12-30 | Andreas Kunzmann | Anlage zum befüllen und verschliessen von dosen unter hygienischen bedingungen |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH101585A (fr) * | 1922-03-28 | 1923-10-16 | Jonas Nielsen Niels | Procédé pour la stérilisation et le remplissage de récipients avec des substances susceptibles de se gâter, et appareil pour sa mise en oeuvre. |
EP0405402A2 (de) * | 1989-06-26 | 1991-01-02 | Toyo Seikan Kaisha Limited | Maschine zum aseptischen Abfüllen |
EP0758624A1 (de) * | 1995-08-11 | 1997-02-19 | ROSSI & CATELLI S.P.A. | Anlage zum sterilen Füllen von Flaschen im Durchlaufverfahren |
US6026867A (en) * | 1997-07-24 | 2000-02-22 | Krones Ag Hermann Kronseder Maschinenfabrik | Rotary filling machine |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3500933B2 (ja) * | 1997-10-16 | 2004-02-23 | 東洋製罐株式会社 | 無菌充填系機械内の空調調整方法 |
-
2002
- 2002-04-22 AT AT02008930T patent/ATE289278T1/de not_active IP Right Cessation
- 2002-04-22 ES ES04005910T patent/ES2289376T3/es not_active Expired - Lifetime
- 2002-04-22 ES ES02008930T patent/ES2233737T3/es not_active Expired - Lifetime
- 2002-04-22 DE DE60222588T patent/DE60222588T2/de not_active Expired - Lifetime
- 2002-04-22 AT AT04005910T patent/ATE373621T1/de not_active IP Right Cessation
- 2002-04-22 EP EP04005910A patent/EP1468959B1/de not_active Expired - Lifetime
- 2002-04-22 EP EP02008930A patent/EP1357081B1/de not_active Expired - Lifetime
- 2002-04-22 DE DE60202995T patent/DE60202995T2/de not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH101585A (fr) * | 1922-03-28 | 1923-10-16 | Jonas Nielsen Niels | Procédé pour la stérilisation et le remplissage de récipients avec des substances susceptibles de se gâter, et appareil pour sa mise en oeuvre. |
EP0405402A2 (de) * | 1989-06-26 | 1991-01-02 | Toyo Seikan Kaisha Limited | Maschine zum aseptischen Abfüllen |
EP0758624A1 (de) * | 1995-08-11 | 1997-02-19 | ROSSI & CATELLI S.P.A. | Anlage zum sterilen Füllen von Flaschen im Durchlaufverfahren |
US6026867A (en) * | 1997-07-24 | 2000-02-22 | Krones Ag Hermann Kronseder Maschinenfabrik | Rotary filling machine |
Non-Patent Citations (1)
Title |
---|
"Product Brochure: 'Tetra Plast LFA-20'", DEUTSCHE MILCHWIRTSCHAFT, HILDESHEIM, DE, vol. 54, no. 17, 20 August 2003 (2003-08-20), DE, pages 1 - 2,712, XP002976631, ISSN: 0012-0480 |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1369379B1 (de) * | 2002-06-07 | 2006-10-25 | Shikoku Kakoki Co., Ltd. | Rotierende aseptische Füllvorrichtung |
DE10326618A1 (de) * | 2003-06-13 | 2005-01-05 | Khs Maschinen- Und Anlagenbau Ag, Patentabteilung | Behälterbehandlungsmaschine |
WO2005056465A1 (de) * | 2003-12-11 | 2005-06-23 | Poepplau Jens H | Behälterbehandlungsvorrichtung mit gasvorhang |
US7357159B2 (en) | 2003-12-11 | 2008-04-15 | Popplau Jens H | Container treatment device with a gas curtain |
WO2010000431A1 (de) | 2008-06-30 | 2010-01-07 | Khs Ag | Füllsystem |
US11072106B2 (en) | 2008-08-18 | 2021-07-27 | Krones Ag | Method for shaping plastic preforms, comprising a sterile chamber |
US9505162B2 (en) | 2008-08-18 | 2016-11-29 | Krones, Ag | Apparatus for shaping plastic preforms, comprising a sterile chamber |
US10486357B2 (en) | 2008-08-18 | 2019-11-26 | Krones Ag | Apparatus for shaping plastic preforms, comprising a sterile chamber |
US8985990B2 (en) | 2008-08-18 | 2015-03-24 | Krones Ag | Apparatus for shaping plastic preforms, comprising a sterile chamber |
CN102717932A (zh) * | 2010-12-16 | 2012-10-10 | 克朗斯股份有限公司 | 容器灭菌设备 |
CN102717932B (zh) * | 2010-12-16 | 2016-02-03 | 克朗斯股份有限公司 | 容器灭菌设备 |
CN102408088B (zh) * | 2011-11-08 | 2016-05-11 | 金坛市新鑫包装机械有限公司 | 液体灌装机的多头同步充填装置 |
CN102408088A (zh) * | 2011-11-08 | 2012-04-11 | 金坛市新鑫包装机械有限公司 | 液体灌装机的多头同步充填装置 |
CN104370257A (zh) * | 2014-10-29 | 2015-02-25 | 广州达意隆包装机械股份有限公司 | 封闭式灌装机 |
WO2016108125A1 (en) | 2014-12-30 | 2016-07-07 | Gea Procomac S.P.A. | Apparatus and method for filling containers |
CN107001020B (zh) * | 2014-12-30 | 2019-03-01 | Gea普洛克玛柯股份公司 | 用于灌装容器的设备和方法 |
US10287152B2 (en) | 2014-12-30 | 2019-05-14 | Gea Procomac S.P.A. | Apparatus and method for filling containers |
CN107001020A (zh) * | 2014-12-30 | 2017-08-01 | Gea普洛克玛柯股份公司 | 用于灌装容器的设备和方法 |
US10800088B2 (en) | 2014-12-30 | 2020-10-13 | Gea Procomac S.P.A. | Process station for a parison or a container made of thermoplastic material, apparatus for processing parisons or containers, production and packaging line for producing and packaging the containers and method for producing and packaging containers |
WO2016108124A1 (en) | 2014-12-30 | 2016-07-07 | Gea Procomac S.P.A. | Process station for a parison or a container made of thermoplastic material, apparatus for processing parisons or containers, production and packaging line for producing and packaging the containers and method for producing and packaging containers |
JP2021509878A (ja) * | 2017-12-18 | 2021-04-08 | エス.アイ.ピー.エイ.ソシエタ’インダストリアリザッジオーネ プロゲッタジオーネ エ オートマジオーネ ソシエタ ペル アチオニ | 熱可塑性素材の容器を製造するシステム及び方法 |
WO2020025224A1 (en) | 2018-07-31 | 2020-02-06 | Gea Procomac S.P.A. | Apparatus and process for decontaminating the mouth of a parison or container in thermoplastic material |
WO2021018541A1 (de) * | 2019-07-26 | 2021-02-04 | Khs Gmbh | Behandlungsvorrichtung und verfahren zur behandlung von behältern und/oder vorformlingen unter aseptischen bedingungen |
CN116553463A (zh) * | 2023-06-30 | 2023-08-08 | 中科圣杰(深圳)科技集团有限公司 | 一种无菌灌装隔离*** |
CN117342075A (zh) * | 2023-12-06 | 2024-01-05 | 正当年医药科技(广州)有限公司 | 一种高效同步智能灌装灭菌包装设备及工艺 |
CN117342075B (zh) * | 2023-12-06 | 2024-02-13 | 正当年医药科技(广州)有限公司 | 一种高效同步智能灌装灭菌包装设备及工艺 |
CN117774432A (zh) * | 2024-02-27 | 2024-03-29 | 南昌大学第一附属医院 | 一种细菌培养基挤出装置 |
Also Published As
Publication number | Publication date |
---|---|
EP1468959B1 (de) | 2007-09-19 |
EP1357081B1 (de) | 2005-02-16 |
ATE373621T1 (de) | 2007-10-15 |
DE60202995T2 (de) | 2005-07-07 |
DE60222588D1 (de) | 2007-10-31 |
DE60202995D1 (de) | 2005-03-24 |
ES2233737T3 (es) | 2005-06-16 |
EP1468959A3 (de) | 2004-11-03 |
ES2289376T3 (es) | 2008-02-01 |
EP1468959A2 (de) | 2004-10-20 |
ATE289278T1 (de) | 2005-03-15 |
DE60222588T2 (de) | 2008-01-31 |
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