EP1329993B1 - Manufacturing method for sliding contact for medium and high current - Google Patents
Manufacturing method for sliding contact for medium and high current Download PDFInfo
- Publication number
- EP1329993B1 EP1329993B1 EP02026559A EP02026559A EP1329993B1 EP 1329993 B1 EP1329993 B1 EP 1329993B1 EP 02026559 A EP02026559 A EP 02026559A EP 02026559 A EP02026559 A EP 02026559A EP 1329993 B1 EP1329993 B1 EP 1329993B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sliding contact
- copper
- zinc
- temperature
- sintering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 239000010949 copper Substances 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 12
- 239000000956 alloy Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052718 tin Inorganic materials 0.000 claims abstract description 7
- 239000011230 binding agent Substances 0.000 claims abstract description 5
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 5
- 239000010439 graphite Substances 0.000 claims abstract description 5
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 235000004416 zinc carbonate Nutrition 0.000 claims description 2
- 239000011667 zinc carbonate Substances 0.000 claims description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
- MQWLIFWNJWLDCI-UHFFFAOYSA-L zinc;carbonate;hydrate Chemical compound O.[Zn+2].[O-]C([O-])=O MQWLIFWNJWLDCI-UHFFFAOYSA-L 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 239000011135 tin Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R39/00—Rotary current collectors, distributors or interrupters
- H01R39/02—Details for dynamo electric machines
- H01R39/18—Contacts for co-operation with commutator or slip-ring, e.g. contact brush
- H01R39/20—Contacts for co-operation with commutator or slip-ring, e.g. contact brush characterised by the material thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R43/00—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
- H01R43/12—Manufacture of brushes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49009—Dynamoelectric machine
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49117—Conductor or circuit manufacturing
- Y10T29/49119—Brush
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/53—Means to assemble or disassemble
- Y10T29/5313—Means to assemble electrical device
- Y10T29/53143—Motor or generator
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12146—Nonmetal particles in a component
Definitions
- the invention relates to a method for producing a sliding contact piece for medium to high current densities according to the preamble of claim 1.
- the sliding contact pieces produced thereafter are in particular carbon brushes for electrical machines, in particular in motor vehicles, where high current densities occur, especially in starters.
- various metal powders such as copper and zinc, or copper and tin, or copper, zinc and tin, and the like, may be intimately mixed with coal, molded, and heated in an indifferent or, more preferably, reducing atmosphere alloy individual metal powder and form a homogeneous mass with the trapped carbon.
- the present invention has for its object to provide a method for the production of sliding contact pieces, which then contain no environmentally harmful additives lead or antimony and nevertheless have the favorable operating characteristics of Gleitturi foundeden with these environmentally harmful substances as possible in an increased extent.
- This object is achieved according to the principle that in the manufacturing process either in the premixing of a copper-free matrix or subsequently in the mixing of a copper-containing matrix as the main mixture as a substitute a basic carbonate of a metal from the group zinc.
- Tin, bismuth or their alloys is added, with basic zinc carbonate is particularly preferred according to claim 2, because it results in particularly favorable properties of the sliding contact piece, in particular the stability.
- the basic carbonates added in fine form promote the alloy formation in the sintering process following the preparation of the main mixture or in the temperature treatment, resulting in a particularly long service life of the sliding contact pieces.
- the addition of about 2 to 5 weight percent zinc hydroxide carbonate to about 30 to 70 weight percent copper matrix in the main mixture forms the above-mentioned advantageous brass islands in the subsequent temperature treatment.
- the sintering and heat treatment of the pressed sliding contact pieces is advantageously carried out with the steps according to claim 4, wherein in a first step the sliding contact pieces are sintered at a temperature in the range 150 to 250 ° C in nitrogen atmosphere, in a second step, the sintering is continued at elevated temperature of 300 to 450 ° C, in a third step, the sintering with the addition of hydrogen to the sintering atmosphere at a temperature over 450 ° C is continued and finally an alloy formation takes place time-dependent at a temperature above 300 ° C.
- the sliding contact piece with its advantageous properties, in particular stability, produced by one of the inventive method is provided.
- the main mixture is added to the zinc carbonate in a very fine grain, which as a first step 5 ZnO 2 CO2 4 H2O shown.
- the third stage occurs: 5 ZNO.
- the sintering atmosphere is added molecular hydrogen at a temperature of at least 450 ° C to a final temperature of 600 ° C, wherein in a fourth stage, a decomposition of the zinc oxide to Zn entry.
- a decomposition of the zinc oxide to Zn entry is added to a brass alloy by the fusion, ie without melting phase.
- the addition of zinc oxide is possible if stages 2 and 3 are to be produced.
- the addition of zinc can be done if the stage 4 is to be generated.
- the addition of the basic zinc carbonate in a modification of the above example can also be carried out to a copper-free matrix in the premix, the same operations as described above, but without final alloying, are performed.
- the alloying is particularly advantageous for achieving the high durability of the sliding contact pieces as mentioned above. Otherwise, however, the desired, lead- and antimony-replacing effects of the additive can be achieved in all the states described above, including alloying.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Contacts (AREA)
- Motor Or Generator Current Collectors (AREA)
- Sliding-Contact Bearings (AREA)
- Manufacturing Of Electrical Connectors (AREA)
- Lubricants (AREA)
- Conductive Materials (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Herstellung eines Gleitkontaktstücks für mittlere bis hohe Stromdichten nach dem Oberbegriff Anspruchs 1.The invention relates to a method for producing a sliding contact piece for medium to high current densities according to the preamble of claim 1.
Die danach hergestellten Gleitkontaktstücke sind insbesondere Kohlebürsten für elektrische Maschinen, insbesondere in Kraftfahrzeugen, wobei hohe Stromdichten vor allem bei Startern auftreten.The sliding contact pieces produced thereafter are in particular carbon brushes for electrical machines, in particular in motor vehicles, where high current densities occur, especially in starters.
In dem Bestreben, derartigen Gleitkontaktstücken günstige Eigenschaften sowohl von reinen Kohlekontaktstücken als auch von Metallkontaktstücken mitzuteilen, wurden diese Werkstoffe bei der Herstellung seit langem kombiniert, wobei insbesondere eine innige Verbindung von Kohleteilen mit dem Metall angestrebt wurde (
Bei einem bekannten Verfahren zur Herstellung von Schleif- und Druckkontakten, die aus Metalllegierungen und Kohle bestehen, werden Mischungen von Metall und Kohle in der Weise hergestellt, dass die Mischungen mit einem Bindemittel, z.B. Teer, vermengt werden, alsdann gepresst, in Kohlepulver eingebettet und gebrannt werden (
Weiterhin gehört es zum Stand der Technik, Zusätze von Blei oder Antimon, den übliche Gleitkontaktstücke enthalten und die eine gute Putzwirkung, eine Kühlung des Gleitkontaktstücks im Betrieb und eine gute Gleitfähigkeit an einem Gegenkontaktstück ergeben, jedoch giftig bzw. umweltschädlich sind, zu vermeiden (
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, Verfahren zur Herstellung von Gleitkontaktstücken vorzuschlagen, welche danach keine umweltschädlichen Zusätze an Blei oder Antimon enthalten und gleichwohl die günstigen Betriebseigenschaften von Gleitkontaktstücken mit diesen umweltschädlichen Stoffen möglichst noch in gesteigertem Maße aufweisen.The present invention has for its object to provide a method for the production of sliding contact pieces, which then contain no environmentally harmful additives lead or antimony and nevertheless have the favorable operating characteristics of Gleitkontaktstücken with these environmentally harmful substances as possible in an increased extent.
Diese Aufgabe wird erfindungsgemäß nach dem Prinzip gelöst, daß bei dem Herstellungsverfahren entweder bei dem Vormischen einer kupferfreien Matrix oder anschließend bei dem Mischen einer kupferhaltigen Matrix als Hauptmischung als Ersatzstoff ein basisches Carbonat eines Metalls aus der Gruppe Zink. Zinn, Wismut oder deren Legierungen zugesetzt wird, wobei basisches Zinkcarbonat nach Anspruch 2 besonders bevorzugt ist, weil sich daraus besonders günstige Eigenschaften des Gleitkontaktstücks, insbesondere der Standfestigkeit ergeben. Die in feiner Form zugesetzten basischen Carbonate fördern die Legierungsbildung bei dem sich an die Herstellung der Hauptmischung anschließenden Sinterungsprozess bzw. bei der Temperaturbehandlung mit dem Ergebnis einer besonders langen Einsatzdauer der Gleitkontaktstücke.This object is achieved according to the principle that in the manufacturing process either in the premixing of a copper-free matrix or subsequently in the mixing of a copper-containing matrix as the main mixture as a substitute a basic carbonate of a metal from the group zinc. Tin, bismuth or their alloys is added, with basic zinc carbonate is particularly preferred according to claim 2, because it results in particularly favorable properties of the sliding contact piece, in particular the stability. The basic carbonates added in fine form promote the alloy formation in the sintering process following the preparation of the main mixture or in the temperature treatment, resulting in a particularly long service life of the sliding contact pieces.
Im einzelnen werden gemäß Anspruch 3 durch die Zugabe von ca. 2 bis 5 Gewichtsprozenten Zinkhydroxidcarbonat zu ca. 30 bis 70 Gewichtsprozenten Kupfermatrix in der Hauptmischung die weiter oben genannten vorteilhaften Messinginseln bei der anschließenden Temperaturbehandlung gebildet.Specifically, according to claim 3, the addition of about 2 to 5 weight percent zinc hydroxide carbonate to about 30 to 70 weight percent copper matrix in the main mixture forms the above-mentioned advantageous brass islands in the subsequent temperature treatment.
Zur Legierungsbildung mit dem in Form des basischen Carbonats zugesetzten Ersatzstoff erfolgt die Sinterung und Temperaturbehandlung der gepressten Gleitkontaktstücke vorteilhaft mit den Schritten gemäß Anspruch 4, wobei in einem ersten Schritt die Gleitkontaktstücke bei einer Temperatur in dem Bereich 150 bis 250 °C in Stickstoffatmosphäre gesintert werden, in einem zweiten Schritt die Sinterung weiter bei erhöhter Temperatur von 300 bis 450 °C fortgesetzt wird, in einem dritten Schritt die Sinterung unter Zugabe von Wasserstoff zur Sinteratmosphäre bei einer Temperatur über 450 °C fortgesetzt wird und schließlich eine Legierungsbildung zeitabhängig bei einer Temperatur über 300 °C erfolgt.For alloy formation with the substitute added in the form of the basic carbonate, the sintering and heat treatment of the pressed sliding contact pieces is advantageously carried out with the steps according to claim 4, wherein in a first step the sliding contact pieces are sintered at a temperature in the range 150 to 250 ° C in nitrogen atmosphere, in a second step, the sintering is continued at elevated temperature of 300 to 450 ° C, in a third step, the sintering with the addition of hydrogen to the sintering atmosphere at a temperature over 450 ° C is continued and finally an alloy formation takes place time-dependent at a temperature above 300 ° C.
Gemäß Anspruch 5 ist das Gleitkontaktstück mit seinen vorteilhaften Eigenschaften, insbesondere Standfestigkeit, nach einem der erfindungsgemäßen Verfahren hergestellt.According to claim 5, the sliding contact piece with its advantageous properties, in particular stability, produced by one of the inventive method.
Im nachfolgenden wird als bevorzugtes Beispiel des erfindungsgemäßen Verfahrens die Zugabe von basischem Zinkcarbonat zu einer Hauptmischung mit Kupferanteilen in der Matrix dargestellt.In the following, as a preferred example of the process according to the invention, the addition of basic zinc carbonate to a main mixture with copper contents in the matrix is shown.
Der Hauptmischung wird das Zinkcarbonat in einer sehr feinen Körnung zugemischt, welches als erste Stufe
5 ZnO 2 CO2 4 H2O
dargestellt.The main mixture is added to the zinc carbonate in a very fine grain, which as a first step
5 ZnO 2 CO2 4 H2O
shown.
Nach Verpressung des Gleitkontaktstücks erfolgt bei dessen Sinterung in Stickstoffatmosphäre und in einem Temperaturbereich von 150 bis 250 °C, insbesondere 180 °C, als erstes eine Umwandlung zu einer zweiten Stufe
2 ZN CO3 3 ZNO.
After pressing the Gleitkontaktstücks takes place when sintered in a nitrogen atmosphere and in a temperature range of 150 to 250 ° C, in particular 180 ° C, first to a conversion to a second stage
2 ZN CO3 3 ZNO.
Bei weiterer Temperaturerhöhung in dem Bereich von 300 bis 450 °C tritt die dritte Stufe ein:
5 ZNO.
Upon further temperature increase in the range of 300 to 450 ° C, the third stage occurs:
5 ZNO.
Anschließend wird der Sinteratmosphäre molekularer Wasserstoff bei einer Temperatur von mindestens 450 °C bis zu einer Endtemperatur von 600 °C beigegeben, wobei in einer vierten Stufe eine Zersetzung des Zinkoxids zu
Zn
eintritt. Danach bildet sich abhängig von Zeit und Temperatur ab 300 °C aus dem Zink mit dem Kupferanteil eine Messinglegierung durch die Fusion, d.h. ohne Schmelzphase.Subsequently, the sintering atmosphere is added molecular hydrogen at a temperature of at least 450 ° C to a final temperature of 600 ° C, wherein in a fourth stage, a decomposition of the zinc oxide to
Zn
entry. Thereafter, depending on time and temperature from 300 ° C from the zinc with the copper content forms a brass alloy by the fusion, ie without melting phase.
In einer Variante ist der Zusatz von Zinkoxid möglich, wenn die Stufen 2 und 3 erzeugt werden sollen.In one variant, the addition of zinc oxide is possible if stages 2 and 3 are to be produced.
Als weitere Variante kann auch der Zusatz von Zink erfolgen, wenn die Stufe 4 erzeugt werden soll.As a further variant, the addition of zinc can be done if the stage 4 is to be generated.
Grundsätzlich kann die Zugabe des basischen Zinkcarbonats in Abwandlung des obigen Beispiels auch zu einer kupferfreien Matrix in der Vormischung erfolgen, wobei die gleichen Vorgänge wie oben beschrieben, jedoch ohne abschließende Legierungsbildung, durchlaufen werden. Die Legierungsbildung ist allerdings zum Erzielen der hohen Standfestigkeit der Gleitkontaktstücke, wie oben erwähnt, besonders vorteilhaft. Im übrigen können jedoch die angestrebten, blei- und antimonersetzenden Wirkungen des Zusatzstoffes in allen oben beschriebenen Zuständen einschließlich einer Legierungsbildung erreicht werden.In principle, the addition of the basic zinc carbonate in a modification of the above example can also be carried out to a copper-free matrix in the premix, the same operations as described above, but without final alloying, are performed. However, the alloying is particularly advantageous for achieving the high durability of the sliding contact pieces as mentioned above. Otherwise, however, the desired, lead- and antimony-replacing effects of the additive can be achieved in all the states described above, including alloying.
Claims (5)
- Manufacturing method for sliding contact for medium and high current densities, wherein graphite is hot-preblended with a plastic binder, the preblend so obtained is subsequently cold-blended with copper, the bulk blend so produced is then pressed to obtain a sliding contact piece which is finally sintered,
characterized in
that when preblending said graphite and said plastic binder or when blending said preblend so obtained with the copper, a basic carbonate of a metal from the group consisting of zinc, tin, bismuth or the alloys thereof is added. - Method according to claim 1
characterized by
zinc carbonate as the basic carbonate. - Method according to claim 2,
characterized in
that about 2 to 5 per cent by weight of zinc hydroxide carbonate is added to about 30 to 70 per cent by weight of copper matrix in the bulk blend. - Method according to one of the foregoing claims,
characterized in
that, in a first step, said sliding contacts are sintered within the temperature range of from 150 to 250°C in nitrogen atmosphere, that, in a second step, sintering is continued at an increased temperature of from 300 to 450°C, that, in a third step, sintering is continued while adding hydrogen to the sintering atmosphere at a temperature above 450°C up to a final temperature of 600°C, and finally, as a fourth step, time-dependently at a temperature above 300°C, an alloy formation is obtained. - Sliding contact for medium and high current densities on copper or carbon base, respectively, with an addition of a metal,
characterized in
that it has been produced in accordance with a method according to at least one of claims 1 to 4.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10201923 | 2002-01-19 | ||
DE10201923A DE10201923B4 (en) | 2002-01-19 | 2002-01-19 | Method for producing a sliding contact piece for medium to high current densities |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1329993A2 EP1329993A2 (en) | 2003-07-23 |
EP1329993A3 EP1329993A3 (en) | 2005-12-21 |
EP1329993B1 true EP1329993B1 (en) | 2008-01-02 |
Family
ID=7712536
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02026559A Expired - Lifetime EP1329993B1 (en) | 2002-01-19 | 2002-11-28 | Manufacturing method for sliding contact for medium and high current |
Country Status (5)
Country | Link |
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US (2) | US7449144B2 (en) |
EP (1) | EP1329993B1 (en) |
JP (1) | JP4073319B2 (en) |
AT (1) | ATE382969T1 (en) |
DE (2) | DE10201923B4 (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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FR2865858B1 (en) * | 2004-02-04 | 2016-10-07 | Carbone Lorraine Applications Electriques | BROOMS FOR ELECTRIC MOTORS OPERATING AT HIGH TEMPERATURE |
JP2008118831A (en) | 2006-11-08 | 2008-05-22 | Mabuchi Motor Co Ltd | Metal graphite brush |
PL223163B1 (en) | 2012-10-04 | 2016-10-31 | Gdański Univ Medyczny | New probes for detecting bacteria of the genus Acinetobacter baumannii, oligonucleotide primers, a method and kit for the analysis of medical and environmental samples |
CN103972758A (en) * | 2014-03-05 | 2014-08-06 | 台州昊泽碳制品有限公司 | Low-noise motor and electric brush combination |
RU2602569C1 (en) * | 2015-04-23 | 2016-11-20 | федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ" (НИУ)") | Method of producing electric carbon articles |
RU2613245C1 (en) * | 2015-10-27 | 2017-03-15 | федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет" (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ" (НИУ)") | Method of producing graphite fiber articles |
DE102015222200B3 (en) * | 2015-11-11 | 2017-05-04 | Schunk Gerhard Carbon Technology GmbH | sliding contact |
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DE289101C (en) * | ||||
DE154287C (en) * | ||||
DE182445C (en) * | 1905-10-01 | 1907-02-04 | Geb Siemens & Co | Process for making sliding and pressure contacts made of metal alloys and carbon. |
US1067003A (en) * | 1909-08-16 | 1913-07-08 | Nat Carbon Co | Process of making electrical conductors. |
CH82327A (en) * | 1919-01-28 | 1919-09-16 | Siemens & Co Geb | Process for making sliding and pressure contacts made of metal and carbon |
US2252277A (en) * | 1939-04-20 | 1941-08-12 | James R Tate | Molded porous electrical brush and the like |
DE845977C (en) * | 1942-11-13 | 1952-08-07 | Lorraine Carbone | Process for the production of brushes for electrical machines |
US2411060A (en) * | 1943-05-13 | 1946-11-12 | Gen Electric | Contact element |
US2581301A (en) * | 1948-07-20 | 1952-01-01 | Saywell Associates | Antifriction composition |
US3067319A (en) * | 1959-11-10 | 1962-12-04 | Air Reduction | Metal-graphite brush with welded shunt |
DE1273054B (en) * | 1963-05-01 | 1968-07-18 | Morganite Carbon Ltd | Contact brushes for electrical machines and their manufacturing process |
JPS556695B2 (en) * | 1974-12-28 | 1980-02-19 | ||
GB1568403A (en) * | 1976-03-20 | 1980-05-29 | Lucas Industries Ltd | Method of producing a sintered composition |
JPS5514513A (en) * | 1978-07-14 | 1980-02-01 | Sony Corp | Recording and reproducing unit for digital signal |
US5227689A (en) * | 1989-08-11 | 1993-07-13 | Mabuchi Motor Co., Ltd. | Metal-filled graphite for miniature motors and method of making same |
DE4024021A1 (en) * | 1990-07-28 | 1992-01-30 | Ringsdorff Werke Gmbh | Sliding electrically- and heat-conducting article contg. carbon - esp. for transferring electric current with body of filled temp.-resistant conductive synthetic resin bonded to 2nd body |
ATE123360T1 (en) * | 1991-07-22 | 1995-06-15 | Carbone Ag | SLIDING CONTACT PIECE FOR HIGH CURRENT DENSITIES. |
DE4343736A1 (en) * | 1993-12-21 | 1995-06-22 | Mando Machine Co Ltd | Copper graphite brush prodn, useful in small motor for small car |
EP0769562A4 (en) * | 1994-04-28 | 1997-08-06 | Nippon Steel Corp | High-strength self-lubricating composite material for high-temperature use and process for producing the same |
US6222298B1 (en) * | 1997-06-08 | 2001-04-24 | Mitsuba Corporation | Carbon commutator and method for producing the same |
US6132487A (en) * | 1998-11-11 | 2000-10-17 | Nikko Materials Company, Limited | Mixed powder for powder metallurgy, sintered compact of powder metallurgy, and methods for the manufacturing thereof |
AUPP773998A0 (en) * | 1998-12-16 | 1999-01-21 | Public Transport Corporation of Victoria | Low resistivity materials with improved wear performance for electrical current transfer and methods for preparing same |
-
2002
- 2002-01-19 DE DE10201923A patent/DE10201923B4/en not_active Expired - Fee Related
- 2002-11-28 DE DE50211452T patent/DE50211452D1/en not_active Expired - Lifetime
- 2002-11-28 AT AT02026559T patent/ATE382969T1/en active
- 2002-11-28 EP EP02026559A patent/EP1329993B1/en not_active Expired - Lifetime
-
2003
- 2003-01-17 US US10/346,824 patent/US7449144B2/en not_active Expired - Fee Related
- 2003-01-17 JP JP2003009275A patent/JP4073319B2/en not_active Expired - Fee Related
-
2008
- 2008-09-18 US US12/284,081 patent/US20090029184A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
DE10201923B4 (en) | 2006-05-24 |
US20030135993A1 (en) | 2003-07-24 |
ATE382969T1 (en) | 2008-01-15 |
US7449144B2 (en) | 2008-11-11 |
DE50211452D1 (en) | 2008-02-14 |
US20090029184A1 (en) | 2009-01-29 |
DE10201923A1 (en) | 2003-08-07 |
EP1329993A2 (en) | 2003-07-23 |
JP2003272795A (en) | 2003-09-26 |
JP4073319B2 (en) | 2008-04-09 |
EP1329993A3 (en) | 2005-12-21 |
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