EP1271614B1 - Lampe à halogénure métallique - Google Patents
Lampe à halogénure métallique Download PDFInfo
- Publication number
- EP1271614B1 EP1271614B1 EP02014260A EP02014260A EP1271614B1 EP 1271614 B1 EP1271614 B1 EP 1271614B1 EP 02014260 A EP02014260 A EP 02014260A EP 02014260 A EP02014260 A EP 02014260A EP 1271614 B1 EP1271614 B1 EP 1271614B1
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- EP
- European Patent Office
- Prior art keywords
- halide
- arc tube
- lamp
- iodide
- cerium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- -1 cerium halide Chemical class 0.000 claims description 58
- 229910001507 metal halide Inorganic materials 0.000 claims description 41
- 150000005309 metal halides Chemical class 0.000 claims description 41
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 229910052684 Cerium Inorganic materials 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 10
- 229910010293 ceramic material Inorganic materials 0.000 claims description 9
- 150000004820 halides Chemical class 0.000 claims description 9
- 229910052716 thallium Inorganic materials 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 6
- 229910052706 scandium Inorganic materials 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 229910052593 corundum Inorganic materials 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- 229910052691 Erbium Inorganic materials 0.000 claims description 2
- 229910052693 Europium Inorganic materials 0.000 claims description 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052765 Lutetium Inorganic materials 0.000 claims description 2
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052771 Terbium Inorganic materials 0.000 claims description 2
- 229910052775 Thulium Inorganic materials 0.000 claims description 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 2
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- FIXNOXLJNSSSLJ-UHFFFAOYSA-N ytterbium(III) oxide Inorganic materials O=[Yb]O[Yb]=O FIXNOXLJNSSSLJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 2
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 36
- ZEDZJUDTPVFRNB-UHFFFAOYSA-K cerium(3+);triiodide Chemical compound I[Ce](I)I ZEDZJUDTPVFRNB-UHFFFAOYSA-K 0.000 description 22
- 230000004907 flux Effects 0.000 description 22
- 230000032683 aging Effects 0.000 description 21
- HUIHCQPFSRNMNM-UHFFFAOYSA-K scandium(3+);triiodide Chemical compound [Sc+3].[I-].[I-].[I-] HUIHCQPFSRNMNM-UHFFFAOYSA-K 0.000 description 21
- 238000012423 maintenance Methods 0.000 description 18
- 229910008069 Cerium(III) iodide Inorganic materials 0.000 description 14
- 235000009518 sodium iodide Nutrition 0.000 description 12
- 238000009877 rendering Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 8
- 229910052721 tungsten Inorganic materials 0.000 description 8
- 239000010937 tungsten Substances 0.000 description 8
- GQKYKPLGNBXERW-UHFFFAOYSA-N 6-fluoro-1h-indazol-5-amine Chemical compound C1=C(F)C(N)=CC2=C1NN=C2 GQKYKPLGNBXERW-UHFFFAOYSA-N 0.000 description 6
- DPYXWFUVSMSNNV-UHFFFAOYSA-L europium(2+);diiodide Chemical compound [I-].[I-].[Eu+2] DPYXWFUVSMSNNV-UHFFFAOYSA-L 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229910052747 lanthanoid Inorganic materials 0.000 description 6
- 150000002602 lanthanoids Chemical class 0.000 description 6
- 238000010891 electric arc Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- 229910001511 metal iodide Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 3
- OKVQKDALNLHZLB-UHFFFAOYSA-K erbium(3+);triiodide Chemical compound I[Er](I)I OKVQKDALNLHZLB-UHFFFAOYSA-K 0.000 description 3
- IZZTUGMCLUGNPM-UHFFFAOYSA-K gadolinium(3+);triiodide Chemical compound I[Gd](I)I IZZTUGMCLUGNPM-UHFFFAOYSA-K 0.000 description 3
- KXCRAPCRWWGWIW-UHFFFAOYSA-K holmium(3+);triiodide Chemical compound I[Ho](I)I KXCRAPCRWWGWIW-UHFFFAOYSA-K 0.000 description 3
- NZOCXFRGADJTKP-UHFFFAOYSA-K lutetium(3+);triiodide Chemical compound I[Lu](I)I NZOCXFRGADJTKP-UHFFFAOYSA-K 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- OJXRJPFRTRETRN-UHFFFAOYSA-K terbium(iii) iodide Chemical compound I[Tb](I)I OJXRJPFRTRETRN-UHFFFAOYSA-K 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CMJCEVKJYRZMIA-UHFFFAOYSA-M thallium(i) iodide Chemical compound [Tl]I CMJCEVKJYRZMIA-UHFFFAOYSA-M 0.000 description 3
- LZOMHYVAEHYDST-UHFFFAOYSA-K thulium(3+);triiodide Chemical compound I[Tm](I)I LZOMHYVAEHYDST-UHFFFAOYSA-K 0.000 description 3
- XQKBFQXWZCFNFF-UHFFFAOYSA-K triiodosamarium Chemical compound I[Sm](I)I XQKBFQXWZCFNFF-UHFFFAOYSA-K 0.000 description 3
- LSSJSIMBIIVSTN-UHFFFAOYSA-K ytterbium(3+);triiodide Chemical compound I[Yb](I)I LSSJSIMBIIVSTN-UHFFFAOYSA-K 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000011195 cermet Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- RMUKCGUDVKEQPL-UHFFFAOYSA-K triiodoindigane Chemical compound I[In](I)I RMUKCGUDVKEQPL-UHFFFAOYSA-K 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ALGSDDPUNYQIGI-UHFFFAOYSA-J sodium cerium(3+) tetraiodide Chemical class [I-].[Na+].[Ce+3].[I-].[I-].[I-] ALGSDDPUNYQIGI-UHFFFAOYSA-J 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/12—Selection of substances for gas fillings; Specified operating pressure or temperature
- H01J61/125—Selection of substances for gas fillings; Specified operating pressure or temperature having an halogenide as principal component
Definitions
- the present invention relates to an arc tube used for a metal halide lamp.
- Metal halide lamps using ceramic arc tubes have been used widely for indoor lighting in stores and shops because such metal halide lamps have higher luminous efficiency, higher color rendering and longer service lives when compared to metal halide lamps using quartz arc tubes.
- FIGs. 5 and 6 show respectively a metal halide lamp using a conventional ceramic arc tube.
- An arc tube 28 comprises an arc tube container 29 composed of a discharge arc tube portion 30 of a polycrystalline alumina ceramic material and a pair of thin tube portions (31,32) sintered at the both ends of the discharge arc tube portion 30.
- a pair of tungsten coil electrodes (33,34) are arranged at the both ends of the arc tube 28.
- Feeding portions (35,36) of niobium or conductive cermet are adhered hermetically to the thin tube portions (31,32) by means of frit 37, and the tungsten electrodes (33,34) are connected to the respective feeding portions (35,36).
- a luminescent material 38 comprising a metal halide, mercury as a buffer gas, and a start-aiding rare gas such as argon are filled in the arc tube 28.
- the arc tube 28 composing a lamp 39 is disposed inside an outer bulb 40 of either quartz or hard glass, and a base 41 is attached to the outer bulb 40.
- About 50 kPa of a nitrogen-based gas is filled in the outer bulb 40.
- the lamp 39 is turned on by means of a copper-iron inductance ballast or an electron ballast with a built-in starter.
- references such as JP-57(1982)-92747 A and USP 5973453 describe the use of cerium iodide in combination with sodium iodide for a luminescent material applicable for a typical metal halide lamp for indoor/outdoor use.
- the luminescent material of cerium iodide can provide improved luminous efficiency since many of the emission spectra of cerium are distributed in a region with a higher relative luminosity factor regarding human eyes.
- USP 5973453 and Tokuhyo-2000-501563 (published Japanese translation of PCT international publication for patent application) describe a suitable NaI/CeI 3 molar composition ratio in a range from 3 to 25 (corresponding to a CeI 3 composition ratio from 12.2 wt% to 53.7 wt%), which is suitable for obtaining white light source color.
- a conventional metal halide lamp filled with a luminescent material of cerium iodide and sodium iodide has a problem of a drastic change in the lamp color temperature as well as a remarkable lowering in the flux maintenance factor over the lighting time.
- a metal halide lamp arc tube according to the present invention can be identical to that of a conventional technique, or a conventional metal halide lamp arc tube can be applied to the present invention.
- the present invention provides a material that is more reactive with a ceramic material than is a cerium halide in order to maintain a high flux maintenance factor while preventing a drastic change in the lamp color temperature.
- the reactive material is at least one halide of a rare earth element selected from the group consisting of scandium halide, gadolinium halide, terbium halide, dysprosium halide, holmium halide, erbium halide, thulium halide, ytterbium halide, lutetium halide, samarium halide, yttrium halide, and europium halide.
- a preferred halogen is either bromine (Br) or iodine (I).
- scandium halide (ScI 3 ) is particularly preferred.
- the filling amount of a halide of a rare earth element is in a range from 1.5 molar parts to 100 molar parts when a filling amount of the cerium halide is 100 molar parts. Accordingly, the oxide-based translucent ceramic material will react preferentially with a halide of a rare earth element other than cerium halide, and thus a reaction between the oxide-based translucent ceramic material and the cerium halide can be suppressed. This can suppress the decrease of cerium halide that serves for light emission, and also reduce changes in the lamp color temperature.
- thallium halide and indium halide also are filled in the arc tube.
- the metal halide lamp according to the present invention has a rated service life of at least 12000 hrs and a lamp efficiency of at least 117 lm/W in its initial state.
- 'initial state' denotes a condition at an aging time of 100 hrs.
- the present invention provides a metal halide lamp that can prevent lowering of flux maintenance factor and color temperature, and the metal halide lamp can be applied for general indoor and outdoor use.
- the metal halide lamp emitting white light is a high-wattage and long-life type, and it has high luminous efficiency, higher light color temperature and a higher general color rendering index.
- FIGs. 1 and 2 Embodiments of the present invention will be described below by referring to FIGs. 1 and 2.
- FIGs. 1 and 2 respectively show structures of an arc tube of a metal halide lamp having an alumina ceramic tube with 200 W, and an entire lamp including the arc tube.
- An arc tube 1 comprises an arc tube container 2 composed of a discharge arc tube portion 3 made of a polycrystalline alumina ceramic and a pair of thin tubes (4,5) sintered at the both ends of the discharge arc tube portion 3.
- the arc tube container 2 is not limited to the polycrystalline alumina ceramic but any oxide-based translucent ceramics can be used similarly.
- Al 2 O 3 (alumina), Y 3 Al 5 O 3 (YAG), BeO, MgO, Y 2 O 3 , Yb 2 O 3 , and ZrO 2 can be used.
- a pair of tungsten coil electrodes (6,7) are formed at the both ends of the arc tube 1, and the respective tungsten coil electrodes (6,7) comprise tungsten electrode rods (8,9) and tungsten coils (10,11).
- the electrodes are arranged with a distance of 18.0 mm.
- Feeding portions (12,13) of a conductive cermet are adhered hermetically to the thin tube portions (4,5) by means of frit 14.
- Each of the tungsten rods (8,9) is welded to one end of each of the feeding portions (12,13), while niobium outer leads (15,16) are welded to the other ends of the feeding portions (12,13) respectively.
- a cerium halide-based luminescent material 17, mercury as a buffer gas and a start-aiding rare gas containing an argon gas are filled in the arc tube 1.
- FIG. 2 is a general view of a lamp 18 comprising the arc tube 1.
- the arc tube 1 is arranged in the interior of an outer bulb 19 made of hard glass.
- a start-aiding conductor 20 made of a molybdenum wire is attached along the discharge arc tube portion 3 of the arc tube container 2.
- An inert gas such as a 50kP of a nitrogen gas is filled in the outer bulb 19.
- the interior of the outer bulb can be evacuated.
- Numeral 21 denotes a base.
- a lamp 18 comprising an arc tube 1 was prepared.
- the arc tube 1 was previously filled with 6 mg of a luminescent material 17 composed of 35 wt% (14 mol%) of CeI 3 , 60 wt% (83.5 mol%) of NaI, and 5 wt% (2.5 mol%) of ScI 3 .
- the flux maintenance factor of the lamp was improved drastically to 65% when the aging time was about 12000 hrs.
- the color temperature change during the aging was not more than -150 K, and this was better in comparison with a lamp that was not filled with ScI 3 .
- the flux and the luminous efficiency were 22800 lm and 117 lm/W respectively i.e., initial values thereof were kept substantially, while the light color temperature and the general color rendering index Ra were improved. That is, the light color temperature was as high as 4300 K at an initial stage, and the general color rendering index Ra exceeded a desired value of 65 and reached 70. The light source color also was improved.
- a lamp 18 comprising a conventional arc tube 1 was prepared.
- the lamp 18 was filled with 6 mg of a luminescent material 17 composed of cerium-sodium iodides (36 wt% (13.9 mol%) of CeI 3 + 64 wt% (86.1 mol%) of NaI).
- This NaI/CeI 3 composition ratio according to the conventional technique provides a white light source color in a range from about 3500 K to about 4000 K.
- the initial properties of the lamp were measured at an aging time of 100 hrs.
- the lamp flux was 23600 lm and the luminous efficiency was 118 lm/W (both are average values of four lamps).
- a desired value (117 ml/W) of luminous efficiency was obtained barely, though the general color rendering index was 60, i.e., lower than the desired value of 65.
- the flux maintenance factor dropped to 50% within the aging time of about 6800 hrs.
- a lifetime of a metal halide lamp is defined by an aging time at which a flux maintenance factor drops to 50%.
- the lamp light color was lowered gradually from the initial value of 4100 K to 3700 K during the service life of 5000 hrs.
- both the flux maintenance factor and the light color of the lamp 18 filled with (CeI 3 + NaI) dropped drastically. This is caused by a combination of two phenomena. First, cerium iodide in the tube reacts with the alumina ceramic (Al 2 O 3 ) of the arc tube and decreases. Secondly, since the discharge arc is focused and bent towards the arc tube wall, the temperature of the arc tube is raised locally to accelerate the reaction between the cerium iodide and the alumina ceramic. In other words, a ratio of CeI 3 that presents high luminous efficiency and high color temperature was decreased faster than NaI during the service life, and thus the flux and the light color were lowered.
- Example 1 An analysis of the Example 1 and Comparative Example shows that a basic measure for suppressing a reaction of cerium during a service life of the lamp is effective. That is, a lanthanoid-based metal halide is added to the interior of the arc tube so that the lanthanoid-based metal halide will react with the inner wall of the tube in an initial stage of lamp aging.
- This lanthanoid-based metal halide is required to have a smaller standard Gibbs energy in formation of an oxide than that of the cerium halide, so that the lanthanoid-based metal halide can react with alumina easily.
- Examples of effective lanthanoid-based metal halides include scandium iodide (ScI 3 ), gadolinium iodide (GdI 3 ), terbium iodide (TbI 3 ), dysprosium iodide (DyI 3 ), holmium iodide (HoI 3 ), erbium iodide (ErI 3 ), thulium iodide (TmI 3 ), ytterbium iodide (YbI 3 ), lutetium iodide (LuI 3 ), samarium iodide (SmI 3 ) (diatomic Sm), and europium iodide (EuI 3 ) (diatomic Eu). Scandium iodide is most favorable among these iodides.
- a lamp was prepared under the same condition of Example 1 except that the filling amount of scandium iodide was varied in a range from 0 to 200 molar parts with respect to 100 molar parts of CeI 3 , and the lamp was subjected to an aging test.
- the amount of the scandium iodide exceeded 100 molar parts, the tungsten electrodes (6,7) were deformed and worn and also the arc tube was blackened, and this caused lowering of the flux maintenance factor.
- the amount of the scandium iodide was less than 1.5 molar parts, no specific effects were expressed in suppressing a reaction between alumina and cerium halide.
- the test results show that a preferred range of the amount of scandium iodide is from 1.5 molar parts to 100 molar parts when CeI 3 is 100 molar parts.
- a small amount of aluminum was detected in the tube of a lamp in which at least 150 molar parts of ScI 3 had been filled.
- the aluminum is derived from aluminum iodide (AlI 3 ), which was formed by a reaction between scandium iodide and the alumina ceramic Al 2 O 3 .
- a reaction formula is as follows. 2ScI 3 + Al 2 O 3 ⁇ Sc 2 O 3 + 2AlI 3
- the aluminum iodide is considered to cause the above-described wear of electrode and blackening of the arc tube.
- a metal halide lamp comprising an alumina ceramic tube can provide a rated service life of at least 12000 hrs and luminous efficiency of at least 117 lm/W, when 1.5-100 molar parts of scandium iodide (0.5-20 molar parts relative to the entire filling) with respect to 100 molar parts of CeI 3 in an alumina ceramic tube in which a luminescent material of cerium iodide and sodium iodide are filled.
- the light color and general color rendering index are also improved.
- Such a lamp can provide a high wattage, high luminous efficiency and a long service life in indoor and outdoor use.
- Similar lamps were prepared for examining the service life in aging, to which 2 to 200 molar parts of metal iodide other than scandium iodide was added.
- the metal iodide were gadolinium iodide (GdI 3 ), terbium iodide (TbI 3 ), dysprosium iodide (DyI 3 ), holmium iodide (HoI 3 ), erbium iodide (ErI 3 ), thulium iodide (TmI 3 ), ytterbium iodide (YbI 3 ), lutetium iodide (LuI 3 ), samarium iodide (SmI 3 ) (diatomic Sm), and europium iodide (EuI 3 ) (diatomic Eu).
- the result is shown as a line of Ce /lanthanoid-based iodide / Na
- the service life was improved as much as the case using scandium iodide, though the flux maintenance factor at an aging time of 12000 hrs was inferior to that of a lamp using scandium iodide.
- Example 3 addresses a method for improving a flux maintenance index by suppressing the focusing or bending of an arc discharge caused especially by the above-mentioned cerium halide luminescent material, and also for obtaining another essential object of improving the luminous efficiency. It was most effective when a combination of thallium halide (TlX) and indium halide InX was filled to serve as an additional luminescent material.
- TlX thallium halide
- InX indium halide
- a lamp 18 used for measurement of the initial properties and the change in the flux maintenance index in aging was prepared by adding TlI and InI in a composition range from 0 to 10 wt% to the above-described luminescent material (CeI 3 + NaI + ScI 3 ).
- the flux maintenance factor of the lamp 18 in aging was further improved, and a rated service life was improved, i.e., the flux maintenance factor was at least 60% at a time of 12000 hrs.
- the reason is as follows. Since the average excitation voltage Ve of thallium and indium is higher than ionization potential Vi (Ve > 0.585 Vi), the arc discharge was spread effectively, so that the local rise in temperature on the tube wall was suppressed. Relatively small amounts of TlI and InI (the total amount was 3.0 wt% or more) served to spread the arc discharge relatively remarkably, and the service life was as long as 12000 hrs.
- TlI indium iodide
- InI indium iodide
- FIG. 4 illustrates a preferred range of compositions of Example 3.
- a typical luminescent material 17 of the present invention contained 34 wt% (14.1 mol%) of CeI 3 + 55 wt% (79.0 mol%) of NaI + 5 wt% (2.5 mol%) of ScI 3 + 3.5 wt% (2.3 mol%) of TlI + 2.5 wt% (2.1 mol%) of InI.
- This luminescent material 17 was filled in a 200W type lamp 18.
- the lamp 18 showed excellent performance in indoor and outdoor use, i.e., for the initial properties, the flux was about 24100 lm and the luminous efficiency was 123.3 lm/W when a white light source color having a color temperature of 4340 K was used (all of the properties were taken as average values of four lamps) .
- Similar lamps were prepared for examining the service life properties in aging, to which metal iodides other than scandium iodide were added.
- the metal iodides were gadolinium iodide (GdI 3 ), terbium iodide (TbI 3 ), dysprosium iodide (DyI 3 ), holmium iodide (HoI 3 ), erbium iodide (ErI 3 ), thulium iodide (TmI 3 ), ytterbium iodide (YbI 3 ), lutetium iodide (LuI 3 ), samarium iodide (SmI 3 ) (diatomic Sm), and europium iodide (EuI 3 ) (diatomic Eu), to which TlI and InI were added further.
- the flux maintenance indices of the lamps were improved further, and the rated service lives were extended
- a metal halide lamp comprises an alumina ceramic tube filled with cerium iodide as a main luminescent material, and a rare earth metal iodide. It is most preferable that the rare earth metal iodide is scandium iodide in an amount defined in a range from 1.5 molar parts to 100 molar parts (0.5-20 molar % in the entire metal halides) when the cerium iodide was 100 molar parts.
- thallium iodide and indium iodide are filled in a composition range 1.0 ⁇ TlI wt% ⁇ 7.0 and also 0.6 ⁇ TlI wt% / InI wt% ⁇ 4.0, so that the lamp flux maintenance index can be improved further and the luminous efficiency is also improved.
- both the rated service life and the luminous efficiency exceed easily the respective desired values of 12000 hrs and 117 lm/W.
- a thus obtained alumina ceramic tube high-pressure discharge lamp for indoor and outdoor use is a high-wattage type and it has high luminous efficiency and a long service life.
Landscapes
- Discharge Lamp (AREA)
Claims (7)
- Lampe à halogénure métallique comprenant un tube à arc (1) comportant une enceinte (2) de tube à arc comme enveloppe, qui est constituée d'un matériau céramique translucide à base d'oxyde et qui comprend une partie (3) de tube à arc à décharge, le tube à arc étant rempli d'un halogénure de cérium comme matériau luminescent (17) et d'un halogénure de scandium, dans lequel le volume de remplissage en halogénure de scandium est dans la plage de 1,5 parties molaires à 100 parties molaires quand le volume de remplissage en halogénure de cérium est de 100 parties molaires,
ou au moins d'un autre halogénure d'un élément de terre rare qui est plus réactif avec le matériau céramique que ne l'est l'halogénure de cérium, dans lequel
le volume total de remplissage en autre(s) halogénure(s) d'au moins au autre élément de terre rare est dans la plage de 1,5 parties molaires à 100 parties molaires quand le volume de remplissage en halogénure de cérium est de 100 parties molaires, et dans lequel
de l'halogénure de thallium et de l'halogénure d'indium sont remplis dans le tube à arc,
le volume d'halogénure de thallium étant dans la plage de 1,0 % en poids à 7 % en poids par rapport à la totalité des halogénures métalliques, et le rapport du volume d'halogénure de thallium à l'halogénure d'indium rempli est dans la plage de 0,6 ≤ % de T1X en poids / % d'InX en poids ≤ 4,0, où X désigne l'halogène. - Lampe à halogénure métallique selon la revendication 1, dans laquelle l'au moins un halogénure d'un élément de terre rare est choisi dans le groupe constitué par l'halogénure de scandium, l'halogénure de gadolinium, l'halogénure de terbium, l'halogénure de dysprosium, l'halogénure d'holmium, l'halogénure d'erbium, l'halogénure de thulium, l'halogénure d'ytterbium, l'halogénure de lutécium, l'halogénure de samarium, l'halogénure d'yttrium et l'halogénure d'europium.
- Lampe à halogénure métallique selon la revendication 1 ou 2, dans laquelle le matériau céramique translucide à base d'oxyde est au moins une céramique choisie dans le groupe constitué par la céramique d'alumine polycristalline, l'Al2O3 (alumine), l'Y3Al6O3, le BeO, le MgO, l'Y2O3, l'Yb2O3 et le ZrO2.
- Lampe à halogénure métallique selon les revendications 1 à 3, dans laquelle l'halogénure de cérium l'halogénure de l'au moins un autre élément de terre rare comprennent l'iode comme halogène.
- Lampe à halogénure métallique selon les revendications 1 à 4, dans laquelle une ampoule extérieure en verre dur est formée à l'extérieur du tube à arc et remplie d'un gaz inerte.
- Lampe à halogénure métallique selon les revendications 1 à 5, dans laquelle un conducteur d'aide à l'amorçage est fixé le long de la partie de tube à arc à décharge de l'enceinte du tube a arc, et le conducteur d'aide à l'amorçage abaisse la tension d'amorçage de la lampe.
- Lampe à halogénure métallique selon les revendications 1 à 6, dans laquelle la lampe à halogénure métallique a une durée de vie nominale d'utilisation d'au mois 12.000 heures et une efficacité lumineuse d'au moins 117 lm/W à l'état initial.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001195302 | 2001-06-27 | ||
JP2001195302 | 2001-06-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1271614A1 EP1271614A1 (fr) | 2003-01-02 |
EP1271614B1 true EP1271614B1 (fr) | 2005-09-21 |
Family
ID=19033304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02014260A Expired - Fee Related EP1271614B1 (fr) | 2001-06-27 | 2002-06-26 | Lampe à halogénure métallique |
Country Status (4)
Country | Link |
---|---|
US (1) | US7061182B2 (fr) |
EP (1) | EP1271614B1 (fr) |
CN (1) | CN100416746C (fr) |
DE (1) | DE60206215T2 (fr) |
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DE60206215T2 (de) | 2001-06-27 | 2006-05-04 | Matsushita Electric Industrial Co., Ltd., Kadoma | Metall-Halogen-Lampe |
JP2003016998A (ja) | 2001-06-28 | 2003-01-17 | Matsushita Electric Ind Co Ltd | メタルハライドランプ |
JP3990582B2 (ja) | 2001-06-29 | 2007-10-17 | 松下電器産業株式会社 | メタルハライドランプ |
JP4037142B2 (ja) * | 2002-03-27 | 2008-01-23 | 東芝ライテック株式会社 | メタルハライドランプおよび自動車用前照灯装置 |
DE10307067B8 (de) * | 2003-02-19 | 2005-01-13 | Sli Lichtsysteme Gmbh | Metallhalogendampflampe |
CN1802725B (zh) * | 2003-06-16 | 2010-07-14 | 松下电器产业株式会社 | 金属卤化物灯 |
US7268495B2 (en) * | 2005-01-21 | 2007-09-11 | General Electric Company | Ceramic metal halide lamp |
US7414368B2 (en) * | 2005-01-21 | 2008-08-19 | General Electric Company | Ceramic metal halide lamp with cerium-containing fill |
DE102005013003A1 (de) * | 2005-03-21 | 2006-09-28 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH | Metallhalogenidlampe |
CN101248512B (zh) * | 2005-03-31 | 2010-11-24 | 皇家飞利浦电子股份有限公司 | 高强度放电灯 |
US7245075B2 (en) * | 2005-04-11 | 2007-07-17 | Osram Sylvania Inc. | Dimmable metal halide HID lamp with good color consistency |
DE102006034833A1 (de) * | 2006-07-27 | 2008-01-31 | Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH | Hochdruckentladungslampe |
DE102008056173A1 (de) * | 2008-11-06 | 2010-05-12 | Osram Gesellschaft mit beschränkter Haftung | Hochdruckentladungslampe |
CN103400737B (zh) * | 2011-08-16 | 2015-10-14 | 国家电网公司 | 一种改良结构的真空间隙管 |
US20130127336A1 (en) * | 2011-11-17 | 2013-05-23 | General Electric Company | Influence of indium iodide on ceramic metal halide lamp performance |
JP5825130B2 (ja) * | 2012-02-08 | 2015-12-02 | 岩崎電気株式会社 | セラミックメタルハライドランプ |
CN104183466A (zh) * | 2013-05-28 | 2014-12-03 | 海洋王照明科技股份有限公司 | 陶瓷金卤灯 |
DE102016115523A1 (de) * | 2016-08-22 | 2018-02-22 | Osram Gmbh | Gasentladungslampe und Scheinwerfersystem mit Gasentladungslampe |
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2002
- 2002-06-26 DE DE60206215T patent/DE60206215T2/de not_active Expired - Lifetime
- 2002-06-26 EP EP02014260A patent/EP1271614B1/fr not_active Expired - Fee Related
- 2002-06-27 CN CNB021429049A patent/CN100416746C/zh not_active Expired - Fee Related
- 2002-06-27 US US10/185,930 patent/US7061182B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
US20030020408A1 (en) | 2003-01-30 |
US7061182B2 (en) | 2006-06-13 |
CN1407594A (zh) | 2003-04-02 |
EP1271614A1 (fr) | 2003-01-02 |
DE60206215D1 (de) | 2005-10-27 |
DE60206215T2 (de) | 2006-05-04 |
CN100416746C (zh) | 2008-09-03 |
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