EP1152837A1 - Method for producing a coating of solvent-free adhesive systems on especially release-coated substrates - Google Patents
Method for producing a coating of solvent-free adhesive systems on especially release-coated substratesInfo
- Publication number
- EP1152837A1 EP1152837A1 EP00907535A EP00907535A EP1152837A1 EP 1152837 A1 EP1152837 A1 EP 1152837A1 EP 00907535 A EP00907535 A EP 00907535A EP 00907535 A EP00907535 A EP 00907535A EP 1152837 A1 EP1152837 A1 EP 1152837A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- roller
- pressure
- sensitive adhesive
- adhesive
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/10—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an adhesive surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
- B05C1/0813—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line characterised by means for supplying liquid or other fluent material to the roller
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
- B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
Definitions
- the invention is concerned with a method for producing a coating of solvent-free PSA systems on, in particular, release-coated substrates, the coating process running over a roller.
- the pre-metered adhesive film is reduced in thickness, so that thin pressure-sensitive adhesive layers can be transferred to substrates.
- a disadvantage of the known method is that pressure-sensitive layers from untreated smooth rollers can only be removed from substrates that are not coated with a release, or that the roller coated with the pressure-sensitive adhesive must have a release effect which can be produced via a fluorocarbon or tefion layer.
- This release layer subsides over the course of its lifetime and is sensitive to external influences such as wear, dirt and mechanical damage.
- release rollers made with fluorocarbon or Teflon coatings are not sufficiently releasable compared to acrylate hotmelt adhesives in the event of machine downtimes, so that a robust process without lengthy cleaning efforts of the coated roller combined with downtimes is not possible.
- the anilox roller coating method with pre-dosed hot melt adhesives is also known from the prior art.
- the disadvantage of the anilox roller method is that, depending on the type of hot melt adhesive, the structure of the anilox roller surface is drawn on the adhesive film when the adhesive layer is transferred to a substrate.
- Another disadvantage of the anilox roller coating process is that at higher coating speeds it is not possible to completely empty the anilox structures, and this can result in an uneven application of adhesive. Furthermore, it is also difficult to remove the adhesive film with release-coated substrates from structured roller surfaces.
- the object of the present invention is to provide a method for producing a solvent-free PSA coating, in particular on release-coated substrates, which avoids the disadvantages of the prior art.
- the invention describes a method for producing a coating of solvent-free PSA systems on, in particular, release-coated substrates, a fluid film being applied to a rotating roller by means of a fluid applicator, and the PSA system being applied to the fluid film in one or more layers by means of an adhesive applicator, so that the fluid film is located between the roller and the pressure-sensitive adhesive system, and the substrate is led to the roller, so that the pressure-sensitive adhesive system is transferred from the roller to the substrate (release-coated and non-release-coated).
- the substrate is brought in in particular via a second roller. Papers, foils, nonwovens and release-coated materials such as release papers, foils and the like are used as substrates.
- the second roller also referred to as the contact roller, is preferably provided with a rubber coating and is preferably pressed against the roller with a line pressure of 50 to 500 N / mm, in particular with 100 to 200 N / mm.
- the contact roller preferably has a Shore hardness (A) of 40-100, in particular a Shore hardness of 60-80 shore (A).
- the substrate is preferably fed to the roller in such a way that the speed of the roller surface matches that of the substrate.
- the substrate can also have a higher speed.
- the roller is a steel roller, a chrome-plated steel roller, a rubber roller or a silicone rubber roller and / or the roller is made of elastic material. Furthermore, the roller can be smooth or have a slightly structured surface.
- the smooth roller can preferably have a chrome layer.
- the chrome-plated steel roller can optionally have a highly polished surface with a roughness depth of R 2 ⁇ +/- 1 ⁇ m.
- the coating roller can, however, also be rubberized, preferably with a rubber hardness of 40 to 100 shore (A), in particular with a hardness of 60-80 shore (A).
- the roller cover can be made of EPDM, Viton or silicone rubber or other elastic materials.
- the roller can be tempered, preferably in a range from -10 ° C. to 200 ° C., very particularly preferably from 2 ° C. to 50 ° C.
- the pressure-sensitive adhesive system is placed on the roller in particular with the aid of a mono- or multi-channel nozzle or a slot nozzle.
- the roller loaded with fluid is preferably coated without contact with the adhesive film emerging from the nozzle.
- the distance from the nozzle to the roller can preferably be 0 to 60 mm, in particular 1 to 10 mm.
- the fluid applicator should also be temperature-controllable in order to bring agents contained in the adhesive formulation that are insensitive to the adhesive formulation to temperatures with the desired fluid properties.
- the fluid can be wiped or applied, but it is also possible for the fluid to be brought onto the roller without contact, for example by spraying.
- the pressure-sensitive adhesive film is crosslinked before the transfer to the substrate, in particular by means of electron beams, UV rays or a combination of the two methods.
- Typical radiation devices which are used in the embodiment of the method according to the invention are linear cathode systems, scanner systems or multi-longitudinal cathode systems, provided that the accelerator is an electron beam.
- the acceleration voltages are in the range between 40 kV and 350 kV, preferably 80 kV to 300 kV.
- the dose rates range between 5 to 150 kGy, in particular 20 to 90 kGy.
- two medium pressure mercury lamps with an output of 120 W / cm or one medium pressure mercury lamp with an output of 240 W / cm can be used as UV crosslinking systems.
- 10 to 300 mJ / cm 2 are preferably set as doses.
- the PSA film can be crosslinked thermally via the roller temperature of the coated roller, and the thermal crosslinking can also be used in addition.
- the fluid film is preferably water and / or distilled water, optionally with additives such as alcohol, wetting agents and / or agents that are insensitive to adhesive formulations such as plasticizers or liquid anti-aging agents.
- additives such as alcohol, wetting agents and / or agents that are insensitive to adhesive formulations such as plasticizers or liquid anti-aging agents.
- the surface tension of the fluid should be less than the surface tension of the roller to be wetted.
- Acrylic, natural rubber, synthetic rubber or EVA adhesives are used in particular as the pressure-sensitive adhesive system.
- the acrylate hotmelts can furthermore be mixed with one or more additives such as anti-aging agents, crosslinking agents, light stabilizers, anti-ozone agents, fatty acids, resins, plasticizers and accelerators.
- additives such as anti-aging agents, crosslinking agents, light stabilizers, anti-ozone agents, fatty acids, resins, plasticizers and accelerators.
- fillers such as fibers, carbon black, zinc oxide, solid microbeads, silica, silicates and chalk, it also being possible to add non-blocking isocyanates.
- rubbers can be added to improve the processability, thermoplastic elastomers in a weight fraction of 10 to 50 wt .-%, based on the total elastomer fraction.
- SIS styrene-isoprene-styrene
- SBS styrene-butadiene-styrene
- All of the previously known adhesive resins described in the literature can be used as the tackifying resins to be added. Representative are the rosins, their disproportionated, hydrogenated, polymerized, esterified derivatives and salts, the aliphatic and aromatic hydrocarbon resins, terpene resins and terpene-phenolic resins. Any combination of these and other resins can be used to adjust the properties of the resulting adhesive as desired. Attention is drawn to the presentation of the state of knowledge in the "Handbook of Pressure Sensitive Adhesive Technology" by Donatas Satas (van Nostrand, 1989).
- plasticizing substances known from adhesive tape technology can also be used as plasticizers to be added. These include, among others the paraffinic and naphthenic oils, (functionalized) oligomers such as oligobutadienes, isoprene, liquid nitrile rubbers, liquid terpene resins, vegetable and animal oils and fats, phthalates, functionalized acrylates.
- paraffinic and naphthenic oils such as oligobutadienes, isoprene, liquid nitrile rubbers, liquid terpene resins, vegetable and animal oils and fats, phthalates, functionalized acrylates.
- the nozzle (1) coats the hotmelt adhesive (11) on a roller (3), which can be designed as a smooth roller or a structured roller.
- a roller (3) which can be designed as a smooth roller or a structured roller.
- slot nozzles or multi-channel nozzles with, for example, three or more individual layers can also be used.
- the roller (3) is designed as a chrome-plated steel roller with a highly polished surface, with a roughness depth R z ⁇ +/- 1 ⁇ m.
- the fluid film (21) is preferably applied to the roller (3) in a pre-metered manner by means of a roller applicator (2) designed according to the prior art.
- the roller (3) loaded with fluid (21) is coated with the adhesive film (11) emerging from the nozzle (1), preferably without contact.
- the distance between the nozzle (1) and the roller (3) is 5 mm.
- the adhesive film (11) floating on the roller (3) is then removed from the roller (3) with the aid of an application roller (6).
- the contact roller (6) is provided with a rubber coating and is pressed against the roller (3) with a line pressure of 150 N / mm.
- a release paper having release material is fed to the contact roller and the adhesive film (11) is thus transferred to the substrate (7).
- an acrylic hot melt adhesive as described in DE 39 42 232 or DE 43 13 008, was used at a temperature of 90 ° C with the help of a mono nozzle (manufacturer Breyer), working width 350 mm, coated on a smooth roller.
- the fluid wetting the smooth roller was water.
- the temperature of the smooth roller was 20 ° C.
- An adhesive film with a thickness of 20 g / m 2 was placed on the smooth roller and then removed from the roller with a corona-pretreated PET film (12 ⁇ m). The coating speed was 70 m / min. The uncovered adhesive side was then laminated with a release paper. The amount of fluid present on the uncovered adhesive side was so small that the subsequent lamination with release paper did not cause any damage to the free adhesive side.
- the composite produced in this way was coated a second time on the free film side and rolled up.
- the acrylate hotmelt adhesive mentioned in Example 1 was coated under the conditions mentioned in Example 1 in a layer thickness of 130 g / m 2 onto a smooth roller.
- the decreasing substrate in this case was a silicone release paper with a release value of 5 - 25 cN / cm.
- the fluid on the open adhesive side was dried by means of IR rays shortly before being rolled up.
- Example 4 The acrylate hotmelt adhesive mentioned in Example 1 was removed under the conditions mentioned in Example 2 in a layer thickness of 50 g / m 2 against a release-coated PETP film with a release value of 5-9 cN / cm and rolled up.
- Example 4
- a natural rubber hot melt adhesive was coated onto the smooth roller at a temperature of 120 ° C. using the nozzle.
- a water / alcohol mixture was used as the fluid.
- the transfer took place on a creped paper, which was equipped with an impregnation, a primer and a release in an upstream operation.
- a three-layer, self-adhesive product structure was extruded onto a smooth roller.
- the hotmelt adhesive the type described in Example 1 was extruded onto the top and bottom of a rubber-elastic middle layer support using the multi-channel die.
- This self-adhesive composite was placed on the smooth roller covered with water and transferred against a release paper with separation forces of 5 to 30 cN / cm and rolled up.
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19905935 | 1999-02-12 | ||
DE19905935A DE19905935A1 (en) | 1999-02-12 | 1999-02-12 | Process for producing a coating of solvent-free PSA systems, in particular on release-coated substrates |
PCT/EP2000/001062 WO2000047336A1 (en) | 1999-02-12 | 2000-02-10 | Method for producing a coating of solvent-free adhesive systems on especially release-coated substrates |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1152837A1 true EP1152837A1 (en) | 2001-11-14 |
EP1152837B1 EP1152837B1 (en) | 2005-01-05 |
Family
ID=7897330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00907535A Expired - Lifetime EP1152837B1 (en) | 1999-02-12 | 2000-02-10 | Method for producing a coating of solvent-free adhesive systems on especially release-coated substrates |
Country Status (5)
Country | Link |
---|---|
US (1) | US6652908B1 (en) |
EP (1) | EP1152837B1 (en) |
DE (2) | DE19905935A1 (en) |
ES (1) | ES2233335T3 (en) |
WO (1) | WO2000047336A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1210183B2 (en) † | 1999-08-31 | 2007-10-31 | 3M Innovative Properties Company | Adhesive coating method and adhesive coated article |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10151286A1 (en) * | 2001-10-22 | 2003-04-30 | Tesa Ag | coating process |
DE10157883A1 (en) | 2001-11-26 | 2003-06-05 | Tesa Ag | coating process |
DE10157881A1 (en) | 2001-11-26 | 2003-06-05 | Tesa Ag | coating process |
DE10163545A1 (en) | 2001-12-21 | 2003-07-10 | Tesa Ag | Process for crosslinking and polymerizing sheet material by means of electron beams and / or UV rays |
DE10301837A1 (en) * | 2003-01-20 | 2004-07-29 | Beiersdorf Ag | Process for the production of plasters |
DE102004033516A1 (en) * | 2004-07-07 | 2006-02-02 | Beiersdorf Ag | Self-adhesive medical product comprises an adhesive layer with a gel value profile such that the degree of crosslinking is highest on the support side and lowest on the application side |
DE102005050104A1 (en) | 2005-10-18 | 2007-04-19 | Tesa Ag | Process for producing anisotropic pressure-sensitive adhesives |
DE102005054054A1 (en) * | 2005-11-10 | 2007-05-16 | Tesa Ag | Process for the preparation of PSAs of low anisotropy |
US7976741B2 (en) * | 2007-02-12 | 2011-07-12 | Ichia Technologies, Inc. | Method of manufacturing light guide plate of keypad |
US8455075B2 (en) * | 2010-10-11 | 2013-06-04 | Daejin Dsp Co., Ltd. | Decorative stainless steel rolled sheet with embossed pattern |
IT1402067B1 (en) * | 2010-10-18 | 2013-08-28 | Scm Group Spa | APPARATUS AND BONDING METHOD |
DE102015113161A1 (en) * | 2015-08-10 | 2017-02-16 | KROENERT GmbH & Co KG | Method and device for applying a medium to a substrate |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2213406B (en) * | 1987-12-08 | 1992-05-20 | Molins Plc | Coating apparatus and method |
FI885678A (en) | 1988-12-07 | 1990-06-08 | Keskuslaboratorio | PROCEDURE FOR THE PURPOSE OF APPROPRIATION WITH THE PAPER OF A POTENTIAL TV STEG. |
CA2110008A1 (en) | 1992-12-22 | 1994-06-23 | Ronald F. Sieloff | Method and apparatus for production of a hard coated substrate |
ATE149046T1 (en) | 1993-02-04 | 1997-03-15 | Voith Gmbh J M | DEVICE FOR APPLYING PAINT PAINT TO A FIBROUS WEB |
CA2122075A1 (en) | 1993-04-30 | 1994-10-31 | Glen H. Bayer, Jr. | Coating process and apparatus |
JP3499709B2 (en) * | 1997-05-15 | 2004-02-23 | 触媒化成工業株式会社 | Thin film forming method and thin film forming apparatus therefor |
DE19905934A1 (en) * | 1999-02-12 | 2000-08-17 | Beiersdorf Ag | Process for producing a coating of solvent-free PSA systems, in particular on release-coated substrates, in connection with crosslinking of the PSA system |
-
1999
- 1999-02-12 DE DE19905935A patent/DE19905935A1/en not_active Withdrawn
-
2000
- 2000-02-10 WO PCT/EP2000/001062 patent/WO2000047336A1/en active IP Right Grant
- 2000-02-10 DE DE50009159T patent/DE50009159D1/en not_active Expired - Lifetime
- 2000-02-10 US US09/937,742 patent/US6652908B1/en not_active Expired - Fee Related
- 2000-02-10 ES ES00907535T patent/ES2233335T3/en not_active Expired - Lifetime
- 2000-02-10 EP EP00907535A patent/EP1152837B1/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO0047336A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1210183B2 (en) † | 1999-08-31 | 2007-10-31 | 3M Innovative Properties Company | Adhesive coating method and adhesive coated article |
Also Published As
Publication number | Publication date |
---|---|
DE50009159D1 (en) | 2005-02-10 |
WO2000047336A1 (en) | 2000-08-17 |
DE19905935A1 (en) | 2000-08-17 |
US6652908B1 (en) | 2003-11-25 |
ES2233335T3 (en) | 2005-06-16 |
EP1152837B1 (en) | 2005-01-05 |
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