EP1064698A2 - Verfahren zum herstellen eines formkörpers - Google Patents
Verfahren zum herstellen eines formkörpersInfo
- Publication number
- EP1064698A2 EP1064698A2 EP99910497A EP99910497A EP1064698A2 EP 1064698 A2 EP1064698 A2 EP 1064698A2 EP 99910497 A EP99910497 A EP 99910497A EP 99910497 A EP99910497 A EP 99910497A EP 1064698 A2 EP1064698 A2 EP 1064698A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- flexible carrier
- carrier sheet
- product
- shaped component
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
- B29C70/086—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
Definitions
- This invention relates to a method of making a shaped component from a substantially dry, resinated feedstock comprising a material selected from particles or fibres of a lignocellulosic material, particles of an exfoliated vermiculite and particles of an expanded perlite, which material has been resinated.
- Shaped components made from synthetic organic fibres in combination with lignocellulosic particles or fibres, formed as a non- woven or needle-punched blanket and subsequently pressed to form the required shape, are well known in the automotive components field.
- shaped components made from wood fibreboard softboard composites pressed between male and female shaped platens in a press under conditions of temperature and pressure, are also well known in the production of door skins.
- a method of making a shaped component from a substantially dry resinated feedstock comprising a material selected from the group consisting of particles or fibres of a lignocellulosic material, particles of an exfoliated vermiculite and particles of an expanded perlite, which material has been resinated with a thermosetting resin, which is optionally combined with a thermoplastic resin, or a precursor of either resin, the resin being in a latent conditions, i.e. the resin not being polymerised or set, and optionally a hydraulic binder, includes the steps of:
- step (ii) placing the product of step (i) between the platens of a press and subjecting the product of step (i) to suitable conditions of temperature and pressure to mould the product of step (i) into a desired shape and to cause the resin to polymerise or to set;
- step (iii) removing the product of step (ii) from the press
- step (iv) optionally removing the flexible carrier sheet from the product of step (iii) to give the shaped component.
- the flexible carrier sheet is adapted to be removed from the product of step (iii) to give the shaped component.
- the flexible carrier sheet should be made of a material that does not degrade during step (ii) of the method of the invention, i.e. a material that does not change phase from the solid to the liquid, that does not adhere to the platens during the pressing, and is removeable from the product of step (iii) in step (iv).
- the flexible carrier sheet is preferably a woven or non-woven fabric sheet, a woven metallic wire sheet, or a paper sheet.
- An example of a suitable material for the manufacture of a flexible carrier sheet is a non-woven polyester sheet with a melting point in excess of 190°C, preferably in excess of 200°C.
- the flexible carrier sheet may be impregnated or coated with a release substance which facilitates removal of the flexible carrier sheet from the product of step (iii) in step (iv).
- the flexible carrier sheet is adapted to form part of the shaped component, i.e. step (iv) falls away.
- the flexible carrier sheet should be made of a material that bonds to the substantially dry resinated feedstock during step (ii).
- the flexible carrier sheet may be a sheet of an inert fibrous material, e.g. glass fibre, impregnated or coated with a suitable thermosetting resin or a precursor thereof, the resin being in a latent condition, and being adapted to set at the temperature of step (ii) to bond the flexible carrier sheet to the substantially dry resinated feedstock in the formation of the shaped component.
- a suitable thermosetting resin or a precursor thereof the resin being in a latent condition, and being adapted to set at the temperature of step (ii) to bond the flexible carrier sheet to the substantially dry resinated feedstock in the formation of the shaped component.
- the flexible carrier sheet may also be a sheet of a woven or non-woven plastics material which melts at the temperature of step (ii) to bond to the substantially dry resinated feedstock in the formation of the shaped component.
- suitable plastics materials are polyethylene and polypropylene.
- the length and width of the flexible carrier sheet depends upon the shaped component being made.
- a flexible carrier sheet for the manufacture of a panel may be 2 440mm x 1 220m; a flexible carrier sheet for the manufacture of a roof tile may be 450mm x 350mm; while a flexible carrier sheet for the manufacture of roof sheeting may be up to 6m long.
- the material in the feedstock may optionally be chemically modified prior to resination, or may be impregnated with a mineral or vegetable oil prior to or during resination.
- the substantially dry resinated feedstock is prepared according to a method disclosed in any of South African Patents Nos. 95/9111, 95/9112, 97/5547 or 98/1160 or in either of South African Patent Applications Nos. 98/5133 or 98/5134.
- step (ii) suitable conditions of temperature are a temperature of from 130°C to 230°C inclusive, preferably a temperature of from 180°C to 220°C inclusive, and of pressure are a pressure of from 20 to 75 kg/cm 2 inclusive, preferably from 50 to 70kg/cm 2 inclusive.
- the method of the invention may include an additional step:
- a flexible carrier sheet for use in the method set out above.
- Figure 1 is a schematic view of an embodiment of the method of the invention.
- the crux of the invention is that a shaped component is made from a substantially dry resinated feedstock which is placed on a flexible carrier sheet prior to moulding between the platens of a press.
- the substantially dry resinated feedstock comprises a material selected from a group consisting of particles or fibres of a lignocellulosic material, particles of an exfoliated vermiculite, and particles of an expanded perlite, which material has been resinated with a thermosetting resin, optionally combined with a thermoplastic resin, or a precursor of either thereof, the resin being in a latent condition, i.e. the resin not being polymerised or set, and optionally a hydraulic binder.
- the substantially dry resinated feedstock may be produced by the method disclosed in South African Patent No. 95/9111 which is incorporated herein by reference. This method is a method of preparing particles of a lignocellulosic material for the manufacture of a finished product which includes the steps of:
- thermoplastic resin in dry powder form, so that after the application of the adhesion promoter, the thermoplastic resin adheres to the surfaces of the particles of lignocellulosic material, the thermoplastic resin having been surface modified by irradiation or by fluorination; and d) after step (a) or step (c), removing the solvent.
- thermoplastic resin may be replaced by or mixed with a thermosetting resin.
- the substantially dry, resinated feedstock may be produced by the method disclosed in South African Patent No. 95/9112 which is incorporated herein by reference.
- This method is a method of preparing particles of an exfoliated vermiculite for the manufacture of a finished product which includes the steps of:
- thermoplastic resin in dry powder form, so that after the application of the adhesion promoter, the thermoplastic resin adheres to the surfaces of the particles of vermiculite, the thermoplastic resin having been surface modified by irradiation or by fluorination; or (ii) including in the impregnating composition of step (a) an isocyanate thermosetting resin dissolved in a suitable compatible solvent; or (iii) applying to the particles a dry powder novolac thermosetting resin and if necessary a catalyst therefor so that after the application of the adhesion promoter, the dry powder novolac thermosetting resin adheres to the surfaces of the particles of vermiculite; and (d) if necessary after step (c), removing any solvent present.
- the substantially dry, resinated feedstock may be produced by the method disclosed in South African Patent No. 97/5547 which is incorporated herein by reference.
- This method is a method of making a material for subsequent formation into a composite product which method includes the steps of:
- impregnating particles of an exfoliated vermiculite with an impregnating composition comprising a first thermosetting resin, an extending liquid for the first thermosetting resin, if necessary a catalyst for the first thermosetting resin, and a colouring agent for the particles;
- step (3) (4) coating the particles of step (3) with a binder composition comprising a second thermosetting resin and if necessary a catalyst for the second thermosetting resin;
- the substantially dry, resinated feedstock may be produced by the method disclosed in South African Patent No. 98/1160 which is incorporated herein by reference.
- This method is a method of preparing a starting material for the subsequent manufacture of a finished product from a feedstock selected from the group consisting of a lignocellulosic material, exfoliated vermiculite, expanded perlite, and a mixture of two or three thereof, which method includes the steps of:
- feedstock in the form of substantially dry finely divided lignocellulosic fibres, or substantially dry finely divided exfoliated vermiculite particles, or substantially dry finely divided expanded perlite particles, or a mixture of two or three thereof;
- thermosetting resin in finely divided dry powder form
- the substantially dry, resinated feedstock may be produced by the method disclosed in South African Patent Applications Nos. 98/5133 and 98/5134.
- This method is a method of preparing lignocellulosic particles or exfoliated vermiculite particles, which method includes the steps of:
- thermosetting resin (ii) a liquid thermosetting resin and, if necessary, a catalyst therefor; in the form of a dispersion of a liquid resin in the mineral oil; to give the starting material.
- the method preferably includes a step, before step (a) or after step (a), of applying to the lignocellulosic particles or to the exfolitated vermiculite particles a thermosetting resin in finely divided dry powder form and, if necessary, a catalyst therefor, so that the thermosetting resin in finely divided dry powder form adheres to the surfaces of the lignocellulosic particles or exfoliated vermiculite particles.
- the feedstock must be substantially dry before being placed on the flexible carrier sheet.
- any excess solvent or volatiles or the like must be removed prior to the method of the invention.
- feedstocks as described above may be used on their own or in a blend of two or more thereof.
- a preferred resin for use in the method of the invention is, for example, a novolac resin, or a blend of an MDI and a novolac resin, or a blend of a thermoplastic polymer and a novolac resin.
- step (i) of the method of the invention the substantially dry feedstock 10 is passed from a hopper 12 on to a flexible carrier sheet 14 to form a layer 16.
- the flexible carrier sheet is made of a material which does not degrade during the pressing step, when it is intended that the flexible carrier sheet be removed from the product of step (iii) to give the shaped component.
- suitable flexible carrier sheets are, for example, sheets of a woven or a non-woven fabric, a sheet of a metallic wire, or a paper sheet.
- the sheet must be flexible so that it can conform to any shape from the flat to a shaped profile, with a minimum amount of disturbance of the feedstock.
- the material from which the flexible carrier sheet is made should have the attributes that it does not adhere to the platens of the press, preferably it does not change its phase from the solid to the liquid during the pressing step, it should be removable from the finished product after pressing, optionally it should be suitable for reuse, it should be relatively inexpensive, and it should be sufficiently soft so as not to damage the platens of the press.
- the flexible carrier sheet should be such that it may be left as an integral part of the shaped component produced, by bonding or adhering to it reliably.
- suitable flexible carrier sheets are those of lignocellulosic origin such as cotton, linen or hessian which may optionally have been modified by the methods described in South African Patent Application No. 98/5132, i.e. impregnation with a mineral oil and a liquid thermosetting resin, in which case they become an integral part of the shaped component produced and serve also to reinforce it. Alternatively they may be treated with a release agent to make them removable for re-use.
- flexible carrier sheet materials are woven, or non-woven materials manufactured from synthetic fibres such as acrylics, polyesters, polyethylenes, polypropylenes, acrylonitriles and the like, either with melting points typical of those at which the component is pressed, in which case they become a part of the shaped component by being melted into the feedstock, or alternatively having a higher melt temperature than that used in forming the shaped component in which case they are removable, preferably for re-use.
- materials suitable for the flexible carrier sheet are the inorganic fibres such as glass or ceramic, impregnated with a suitable thermosetting resin.
- a suitable flexible carrier sheet is a non-woven sheet manufactured from a synthetic fibre which has a melting point higher than the temperature required for the polymerisation of the resin in the feedstock.
- a specific example is a polyester fibre with a melting point in excess of
- a typical press temperature is in the range of 140 to 180°C, and thus it can be seen that such a polyester fibre will not degrade at the pressing temperature.
- the flexible carrier sheet may be coated or impregnated with a release substance that facilitates easy release of the flexible carrier sheet from the formed article.
- a suitable release substance are a fluorine- based compound such as Scotch Guard by 3M or Teflon by DuPont, or alternatively a cashew nut oil or derivative thereof, or further alternatively a silicone based-product.
- a suitable flexible carrier sheet which is designed to form part of the shaped component is a 300g/m 2 chopped strand fibreglass mat, pre-impregnated either with a phenol formaldehyde resole resin which is acid catalysed, e.g. Blagden J 2818L and Phencat 10 respectively, in methanol, which methanol is removed before pressing, or an unsaturated polyester resin, e.g. Ultraset 997 by NCS of South Africa catalysed by a latent catalyst e.g. Triganox 29B50 by Akzo Chemie, in methylene chloride, which is removed before pressing.
- a phenol formaldehyde resole resin which is acid catalysed
- methanol which methanol is removed before pressing
- an unsaturated polyester resin e.g. Ultraset 997 by NCS of South Africa catalysed by a latent catalyst e.g. Triganox 29B50 by Akzo Chemie, in methylene chloride, which
- step (ii) of the method of the invention the product of step (i), i.e. the combination of the layer 16 of the feedstock and the flexible carrier sheet 14, is placed between a male platen 18 and a female platen 20 of a press. Then, the combination of flexible carrier sheet 14 and layer of feedstock 16 is subjected to suitable conditions of temperature and pressure, for example, a temperature of 130 to 230°C, and a pressure of from 20 to 75kg/cm 2 , to mould the product into a desired shape and to cause the resin to polymerise or set.
- suitable conditions of temperature and pressure for example, a temperature of 130 to 230°C, and a pressure of from 20 to 75kg/cm 2 , to mould the product into a desired shape and to cause the resin to polymerise or set.
- step (iii) of the method of the invention the product of step (ii) is removed from the platens 18, 20 of the press.
- step (iv) of the method of the invention optionally, the flexible carrier sheet 14 is removed from the product of step (ii) to give the shaped component.
- step (v) of the method of the invention optionally water is introduced into the shaped component to hydrate any hydraulic binder present.
- the method of the invention is of particular application in the production of shaped components such as automotive parts, e.g. door liners, fielded and planed door skins, corrugated roof sheeting, furniture parts and the like.
- a typical thickness of a shaped component made by the method of the invention is from 2mm to 12mm, more usually from 2,5mm to 8mm.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ZA9802191 | 1998-03-16 | ||
ZA982191 | 1998-03-16 | ||
PCT/GB1999/000792 WO1999048170A2 (en) | 1998-03-16 | 1999-03-16 | Method of making a shaped component |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1064698A2 true EP1064698A2 (de) | 2001-01-03 |
Family
ID=25586900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99910497A Withdrawn EP1064698A2 (de) | 1998-03-16 | 1999-03-16 | Verfahren zum herstellen eines formkörpers |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1064698A2 (de) |
AU (1) | AU744082B2 (de) |
CA (1) | CA2318209A1 (de) |
WO (1) | WO1999048170A2 (de) |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2520292B1 (fr) * | 1982-01-26 | 1986-09-12 | Isorel | Panneaux composites a base de fibres lignocellulosiques et de fibres de polyolefine, et leur procede de fabrication |
GB8516480D0 (en) * | 1985-06-28 | 1985-07-31 | Exxon Chemical Patents Inc | Weather resistant construction elements |
DE3841310C1 (de) * | 1988-12-08 | 1990-06-07 | Werzalit Ag + Co, 7141 Oberstenfeld, De |
-
1999
- 1999-03-16 CA CA002318209A patent/CA2318209A1/en not_active Abandoned
- 1999-03-16 WO PCT/GB1999/000792 patent/WO1999048170A2/en not_active Application Discontinuation
- 1999-03-16 AU AU29436/99A patent/AU744082B2/en not_active Ceased
- 1999-03-16 EP EP99910497A patent/EP1064698A2/de not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO9948170A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO1999048170A3 (en) | 1999-11-04 |
WO1999048170A2 (en) | 1999-09-23 |
CA2318209A1 (en) | 1999-09-23 |
AU744082B2 (en) | 2002-02-14 |
AU2943699A (en) | 1999-10-11 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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17P | Request for examination filed |
Effective date: 20000804 |
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AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): DE ES FR GB IT |
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17Q | First examination report despatched |
Effective date: 20020319 |
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GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20030227 |