EP1029742A1 - Schallisolierendes Polyurethan Schaum Formteil mit geringer Wasser und Ölabsorption - Google Patents

Schallisolierendes Polyurethan Schaum Formteil mit geringer Wasser und Ölabsorption Download PDF

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Publication number
EP1029742A1
EP1029742A1 EP20000101572 EP00101572A EP1029742A1 EP 1029742 A1 EP1029742 A1 EP 1029742A1 EP 20000101572 EP20000101572 EP 20000101572 EP 00101572 A EP00101572 A EP 00101572A EP 1029742 A1 EP1029742 A1 EP 1029742A1
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EP
European Patent Office
Prior art keywords
polyurethane foam
noise insulating
insulating member
fluorine
noise
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20000101572
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English (en)
French (fr)
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EP1029742B1 (de
Inventor
Shinsuke c/o Tokai Rubber Industries Ltd Osanai
Kiyomi c/o Tokai Rubber Industries Ltd Nishida
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Sumitomo Riko Co Ltd
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Sumitomo Riko Co Ltd
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Publication of EP1029742A1 publication Critical patent/EP1029742A1/de
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0019—Use of organic additives halogenated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/08—Insulating elements, e.g. for sound insulation
    • B60R13/0838—Insulating elements, e.g. for sound insulation for engine compartments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/08—Insulating elements, e.g. for sound insulation
    • B60R13/0861—Insulating elements, e.g. for sound insulation for covering undersurfaces of vehicles, e.g. wheel houses
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00—Component parts, details or accessories, not otherwise provided for
    • F02B77/11—Thermal or acoustic insulation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B77/00—Component parts, details or accessories, not otherwise provided for
    • F02B77/11—Thermal or acoustic insulation
    • F02B77/13—Acoustic insulation
    • G—PHYSICS
    • G10—MUSICAL INSTRUMENTS; ACOUSTICS
    • G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162—Selection of materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/05—Open cells, i.e. more than 50% of the pores are open
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Definitions

  • the present invention relates in general to a noise insulating member having a low degree of water absorbency and a low degree of oil absorbency. More particularly, the invention is concerned with a noise insulating material which is made of a polyurethane foam having a low degree of water absorbency and a low degree of oil absorbency, so as to be suitable for forming a noise insulating member for use in an automotive vehicle or a hydro-bike.
  • noise insulating member in an automotive vehicle, for reducing undesirable transmission of noise into the passenger compartment or to the outside of the vehicle.
  • an engine topcover 2 for example, an engine topcover 2, an engine sidecover 4, an oilpan cover 6, an engine undercover 8 and other noise insulating covers are provided around the engine, i.e., a generator of a noise, as shown in Fig. 1, in the interest of reducing radiation of the noise from the engine.
  • Each of these noise insulating covers consists of a metallic plate or other rigid member, and a rubber or urethane foam or other foam body which is fixed to the rigid member.
  • a spacer 10 formed of a rubber or urethane foam or other foam body is positioned in a space between the engine and accessories such as a fuel injection pump, which are located adjacent to the engine, in the interest of minimizing generation of standing wave in the space.
  • a hood silencer 12 an intake pipe silencer (not shown), a dashboard silencer (not shown) and other noise insulating covers or members which are formed of respective foam bodies.
  • the above-described noise insulating members provided in an automotive vehicle are likely to be exposed to water or raindrop, in some cases, for example, where the vehicle runs in a rain, or where the vehicle is washed or cleaned with water in a periodic inspection or on other occasion.
  • the foam body used to constitute each of these noise insulating members is required to have a high degree of water repellency or a low degree of water absorbency, so that the water or raindrop is not absorbed into the foam body even where the noise insulating member is exposed to the water or raindrop.
  • each of the noise insulating members 2, 4, 6, 8, 10, 12, which are located around the engine needs to be constituted by the foam body having a high degree of oil repellency or a low degree of oil absorbency as well as a high degree of water repellency or a low degree of water absorbency, since these members 2, 4, 6, 8, 10, 12 are possibly exposed to an engine oil or other lubricant which has leaked from the engine. It is important to note that the noise insulating member may become inflammable if the member contains the oil absorbed therein.
  • a reference numeral 14 in Fig. 2 designates such a noise insulating member, by way of example, which is provided for the above purpose.
  • this noise insulating member 14 needs to have not only a high degree of water repellency but also a high degree of oil repellency, because the hydro-bike runs on water, and the noise insulating member 14 is positioned near the engine.
  • the noise insulating member for use in an automotive vehicle or a hydro-bike is constituted by a rubber foam as the foam body.
  • the noise insulating member serves as the above-described spacer 10
  • the noise insulating member is required to simply reduce a resonance noise, and to have a high degree of heat resistance rather than a high degree of acoustic absorption coefficient.
  • the spacer 10 is constituted by a rubber foam having a closed-cell network which is made of CR, EPDM or other material, and in which there is a predominance of non-communicating cells.
  • the rubber foam made of EPDM suffers from a low degree of oil resistance.
  • the urethane foam (polyurethane foam) is also used as the foam body for giving the noise insulating member.
  • the urethane foam provides a soft foam body having a density of as small as 0.1g/cm 3 or so.
  • the urethane foam is advantageously used where the foam body is required to have a light weight.
  • it is proposed to cover the surface of the urethane foam body with a film or other coating, as disclosed in JP-A-08-40154. Further, it is proposed to use a foam body which is obtained by using as additives a hydrophobic polyol and an asphalt component, as disclosed in JP-B-57-22051 or JP-B-61-50965.
  • the above first object may be achieved according to a first aspect of the present invention, which provides a noise insulating member having a low degree of water absorbency and a low degree of oil absorbency.
  • the noise insulating member comprises a polyurethane foam obtained by reaction of an organic polyisocyanate component and a polyol component in the presence of a fluorine-based surfactant or fluorine-containing surfactant, and having a cellular network having cells and communication holes which communicate with the cells and which have respective diameters each of which is not larger than 60 ⁇ m, more preferably not larger than 20 ⁇ m.
  • the noise insulating member of the present invention is constituted by the polyurethane foam which includes the fluorine-containing surfactant in its resin structure.
  • the fluorine-containing surfactant advantageously provides the polyurethane foam with not only an excellent water repellency but also an excellent oil repellency.
  • the polyurethane foam has the cellular network in which the cells are held in communication with each other through the respective communication holes whose diameters are made small to increase the degree of mutual independency of the cells. This increased mutual independency of the cells contributes to improvements in the noise insulating properties of the polyurethane foam as well as in the water and oil repellency.
  • the polyurethane foam has a gas permeability which permits a rate of gas flow therethrough of not higher than 1000mL/min. It is noted that this rate of gas flow represents an amount per minute of the gas passing through an area of 900 ⁇ mm 2 (e.g. a circular area having a radius of 30mm) over a distance of 10mm in the foam body, when the pressure on one of opposite sides of the foam body which is exposed to a reduced pressure is reduced to be lower by 10mmH 2 O, than the pressure on the other side which is exposed to the atmospheric pressure.
  • this rate of gas flow represents an amount per minute of the gas passing through an area of 900 ⁇ mm 2 (e.g. a circular area having a radius of 30mm) over a distance of 10mm in the foam body, when the pressure on one of opposite sides of the foam body which is exposed to a reduced pressure is reduced to be lower by 10mmH 2 O, than the pressure on the other side which is exposed to the atmospheric pressure.
  • the fluorine-containing surfactant is added to the reaction system of the organic polyisocyanate component and the polyol component for forming the polyurethane foam, preferably, such that the amount of the fluorine-containing surfactant is 0.1-5.0 parts by weight per 100 parts by weight of a polyurethane resin which is produced as a result of the reaction of the organic polyisocyanate component and the polyol component.
  • the fluorine-containing surfactant added to the reaction system includes a fluoro-aliphatic group having 3-20 carbon atoms, more preferably a fluoro-aliphatic group having 6-12 carbon atoms, thereby further improving the water and oil repellency of the noise insulating member.
  • the fluorine-containing surfactant includes an organic group having a high degree of affinity with respect to a polyurethane resin which is produced as a result of the reaction of the organic polyisocyanate component and the polyol component, so that the fluorine-containing surfactant has an increased compatibilty with the polyurethane resin.
  • the increased compatibility of the fluorine-containing surfactant with the polyurethane resin effectively enables the fluorine-containing surfactant to provide the above-described advantages.
  • the fluorine-containing surfactant has an average molecular weight of 500-1,000,000.
  • a noise insulating member for use in an automotive vehicle comprising a polyurethane foam obtained by reaction of an organic polyisocyanate component and a polyol component in the presence of a fluorine-containing surfactant, and having a cellular network having cells and communication holes which communicate with the cells, wherein each of the communication holes has a diameter not larger than 60 ⁇ m, and gas permeability which permits a rate of gas flow therethrough of not higher than 1000mL/min.
  • the above-described noise insulating member may be advantageously used as a noise insulating cover provided in an engine room of an automotive vehicle so as to be positioned adjacent to or around an engine of the automotive vehicle, for reducing radiation of noise from the engine, or may be advantageously used as a spacer provided in an engine room of an automotive vehicle so as to be positioned in a space between an engine of the automotive vehicle and accessories which are located adjacent to the engine, for minimizing generation of standing wave in the space.
  • the above third object may be achieved according to a third aspect of the present invention, which provides a noise insulating member provided in a hull of a hydro-bike, for reducing radiation of noise from an engine of the hydro-bike.
  • the noise insulating member comprising a polyurethane foam obtained by reaction of an organic polyisocyanate component and a polyol component in the presence of a fluorine-containing surfactant, and having a cellular network having cells and communication holes which communicate with the cells, wherein each of the communication holes has a diameter not larger than 60 ⁇ m, and gas permeability which permits a rate of gas flow therethrough of not higher than 1000mL/min.
  • the noise insulating member of the present invention is constituted by a polyurethane foam which is obtained by reaction of an organic polyisocyanate component and a polyol component.
  • Either of the organic polyisocyanate component and the polyol component may be selected from any conventionally known materials.
  • the organic polyisocyanate component may be selected from among tolylene diisocyanate, phenylene diisocyanate, xylylene diisocyanate, diphenylmethane diisocyanate, triphenylmethane triisocyanate, polymethylene polyphenyl isocyanate and naphthalene diisocyanate, or their derivatives, such as prepolymer which is obtained by reaction of polyisocyanate with polyol or the like, and modified polyisocyanate or the like.
  • the polyol component which reacts with the organic polyisocyanate component so as to form the polyurethane, may be selected from among various known kinds of polyols such as polyhydric hydroxy compound, polyetherpolyols, polyesterpolyols, polymerpolyols, polyetherpolyamines, polyesterpolyamines, alkylenepolyols, urea-dispersed polyols, melamine-modified polyols, polycarbonatepolyols, acrylpolyols, polybutadienepolyols, phenol-modified polyols.
  • the polyol component may be a combination of these various kinds of polyols.
  • the desired noise insulating member is constituted by the polyurethane foam which is obtained as a result of a reacting/foaming (foaming/curing) operation in which the above-described organic polyisocyanate component and the above-described polyol component react with each other in the presence of a fluorine-based or fluorine-containing surfactant.
  • the fluorine-containing surfactant is introduced into the formed polyurethane resin (polyurethane foam) by the reacting/foaming operation in the presence of the fluorine-containing surfactant.
  • the polyurethane resin is given a foam structure in which the cells communicate with each other through the communication holes each having the diameter not larger than 60 ⁇ m.
  • the foam structure has gas permeability permitting a rate of gas flow therethrough of not higher than 1000mL/min.
  • This arrangement advantageously provides the noise insulating member with a sufficiently high degree of water repellency and a sufficiently high degree of oil repellency as well as excellent noise insulating properties.
  • the fluorine-containing surfactant provides the advantages as described above, includes a fluoro-aliphatic group in which hydrogen atoms of hydrophobic group of hydrocarbon-containing surfactant are entirely or partially substituted by fluorine atoms and which has preferably 3-20 carbon atoms, more preferably 6-12 carbon atoms.
  • the fluorine-containing surfactant having a perfluoroalkyl group is advantageously used.
  • the fluorine-containing surfactant has a high degree of affinity with respect to the polyurethane resin.
  • the fluorine-containing surfactant includes an organic group having a high degree of affinity with respect to the polyurethane resin.
  • Such an organic group may be selected from among a lower or higher alkyl group, an alkylidene group, an aryl group, an acyl group, a vinyl group, a vinylidene group, an ethylenic double bond, a hydroxy group, a carboxyl group, an amino group, an epoxy group, a halogen, a polydimethylsiloxane group, a mercapto group, a polyoxyalkylene group and other group.
  • the polyoxyalkylene group is the most preferable since it is advantageous that the organic group has a high degree of compatibility with the polyol component in the production of the polyurethane foam.
  • the fluorine-containing surfactant having the fluoro-aliphatic group and also the organic group having a high degree of affinity with respect to the polyurethane resin is advantageously used, as described above.
  • a fluorine-containing surfactant include a compound having, in each molecule thereof, the fluoro-aliphatic group and the organic group having a high degree of affinity with respect to the polyurethane resin, and a random, block or graft copolymer of unsaturated monomer including the fluoro-aliphatic group and an unsaturated monomer including the organic group having a high degree of affinity with respect to the polyurethane resin.
  • the fluorine-containing surfactant has an average molecular weight of 500-1,000,000, preferably 900-500,000. If the average molecular weight were smaller than 500, it would be difficult for the fluorine-containing surfactant to exhibit a sufficiently high modifying effect. If the average molecular weight were larger than 1,000,000, the compatibility of the fluorine-containing surfactant with respect to the polyurethane resin would be undesirably reduced.
  • the fluorine-containing surfactant is included in or added to the reaction system of the organic polyisocyanate component and the polyol component, for forming the polyurethane foam such that the amount of the fluorine-containing surfactant is 0.1-5.0 parts by weight per 100 parts by weight of polyurethane resin which is produced as a result of the reaction of the organic polyisocyanate component and the polyol component. If the added amount of the fluorine-containing surfactant were smaller than 0.1 part by weight, the polyurethane resin (foam) would not likely to be satisfactorily modified. If the added amount of the fluorine-containing surfactant were larger than 5.0 parts by weight, the polyurethane foam would not likely to be satisfactorily obtained due to possible destruction of the cells or other problems.
  • a suitable amount of water is used as a foaming agent for foaming the polyurethane (resin) which is formed by the reaction of the organic polyisocyanate component and the polyol component in the presence of the fluorine-containing surfactant.
  • the water reactions with the organic polyisocyanate component to form a carbonic acid gas, for thereby exhibiting a foaming effect.
  • the water is used in an amount of 1.0-6.0 parts by weight, preferably 2.0-5.0 parts by weight, per 100 parts by weight of the polyol component. If the amount of water to be used were smaller than 1.0 parts by weight, the obtained polyurethane foam would not be foamed to a satisfactory extent, and accordingly tends to increase its density. If the amount of water to be used were larger than 6.0 parts by weight, the foaming or expansion ratio would not be increased with an increase of the amount of water. In this case, the obtained foam body suffers from a lowered quality such as irregularity of voids or cells.
  • suitable additives known in the art such as a catalyst, a cross-linking agent, a foaming agent, a foam stabilizer, a flame retardant, a viscosity-reducing agent, a stabilizer, a filler and a coloring agent may be added to the respective reaction mixtures.
  • amine urethane catalysts such as triethylene diamine and dimethylethanolamine or organometallic urethane catalysts such as tin laurate and tin octanoate are used.
  • flon, methylene chloride and CO 2 gas may be used as the foaming agent in addition to, or in place of the water, for instance.
  • foam stabilizer include "SRX-274C” available from TORAY DOW CORNING CORPORATION, Japan "L-5390" available from NIPPON UNICAR COMPANY LIMITED, Japan, and "B-4113" available from GOLDSCHMIDT, Germany.
  • the cross-linking agent triethanolamine or diethanolamine is generally used.
  • the suitable amount of the fluorine-containing surfactant is first added to the polyol component, and the respective suitable amounts of the water as the foaming agent, the catalyst, the cross-linking agent, the foam stabilizer and other processing aid are then mixed with the suitable amount of the polyol component so as to provide a resin premixture (premixture polyol).
  • the suitable organic polyisocyanate is added for reaction, to thereby provide the desired polyurethane foam.
  • the resin premixture and the organic polyisocyanate component are mixed together by using a known urethane foaming device such that the mixture has an isocyanate index in the range of 60-110, preferably in the range of 70-100.
  • the mixture is poured into a suitable mold, for reaction and foaming, whereby the polyurethane foam having a desired shape is obtained.
  • the communication holes for communication of the cells with each other have respective diameters each of which is not larger than 60 ⁇ m, preferably not larger than 20 ⁇ m, and the polyurethane foam has a gas permeability which permits a rate of gas flow therethrough of not higher than 1000mL/min, preferably not higher than 500mL/min, so that the polyurethane foam is provided with a sufficiently high degree of water repellency and a sufficiently high degree of oil repellency as well as excellent noise insulating properties.
  • the polyurethane foam satisfactorily serves as a noise insulating member.
  • the presence of the suitable fluorine-containing surfactant in the reaction system of the organic polyisocyanate component and the polyol component for forming the desired polyurethane foam is effective to obtain the foam structure in which the communication holes communicating with the cells have remarkably reduced diameters, without considerably increasing or reducing the foaming or expansion ratio.
  • the communication holes having the reduced diameters permit the air and the gas generated in the foaming process to pass therethrough, but do not permit a droplet of water or oil to pass therethrough due to its surface tension, thereby contributing to the reduction of the oil absorbency and the water absorbency.
  • the reduction of the diameters of the communication holes increases reflections of incident or incoming acoustic wave in each cell, whereby the noise is more effectively damped, resulting in a remarkable improvement in the noise insulating properties of the noise insulating member.
  • gas permeability is interpreted to mean an amount of gas or air flow within a specimen (polyurethane foam) which is measured under a predetermined condition.
  • the measurement of the gas permeability is achieved by using a jig in the form of a plate having a cylindrical through-hole of a 60mm diameter formed in its central portion.
  • the polyurethane foam as the specimen having a plate shape of 75mm ⁇ 75mm ⁇ 10mm t is brought at one of its opposite surfaces in contact with the jig so that a portion of that surface is exposed to the atmosphere through the through-hole, while the other surface of the polyurethane foam is exposed to a reduced pressure generated by a vacuum pump.
  • the gas permeability is obtained by measuring the amount of air introduced into the vacuum pump, i.e., the amount of air passed through the polyurethane foam, by a suitable flow meter, when the pressure at the above-indicated other surface is reduced to be lower by 10mmH 2 O than the pressure at the above-described one surface.
  • the polyurethane foam obtained as described above is advantageously used as the noise insulating member of the present invention, which is characterized by its low degree of water absorbency and its low degree of oil absorbency.
  • the thus characterized noise insulating member is advantageously used in an automotive vehicle for serving as a noise insulating cover, such as an engine topcover 2, an engine sidecover 4, an oilpan cover 6, an engine undercover 8, a hood silencer 12 and a dashboard silencer (not shown), which are provided in an engine room of the vehicle, so as to be positioned around an engine of the vehicle, as shown in Fig.
  • the noise insulating member is advantageously used also in a hydro-bike, serving as a noise insulating member 14 which is provided in a hull of the hydro-bike, as shown in Fig. 2, for reducing radiation of a noise from the engine.
  • polyurethane foam bodies were prepared in the following procedure. That is, for preparing the polyurethane foam bodies, respective compounding agents A-D were first added to the polyol component in the form of "SUMIPHEN3063" (polyetherpolyol available from SUMITOMO BAYER URETHANE KABUSHIKI KAISHA, Japan, and having an OH value of 28 and a functionality of 3), in predetermined respective parts by weight per 100 parts by weight of the polyetherpolyol, as indicated in Tables 1 and 2. Then, 2.5 parts by weight of water as a foaming agent; 0.5 parts by weight of "KAOLIZER No.
  • SUMIPHEN3063 polyetherpolyol available from SUMITOMO BAYER URETHANE KABUSHIKI KAISHA, Japan, and having an OH value of 28 and a functionality of 3
  • the mixture was then poured into a suitable mold by using a low- or high-pressure casting device, and was foamed and cured at a temperature of 40-70°C for 10-30 minutes, to thereby provide each of the polyurethane foam bodies having respective characteristics as indicated in Tables 1 and 2.
  • the compounding agent A was "FX-3" which was a fluorine-containing surfactant available from DAINIPPON INK AND CHEMICALS, INCORPORATED, Japan, and formed of a fluorine-containing urethane oligomer.
  • the "FX-3” was a methylethylketone solution having a solid content of 60%, which includes a perfluoroalkyl group bond at each of opposite ends thereof
  • the compounding agent B was "MCF-310" which was a fluorine-containing surfactant available from DAINIPPON INK AND CHEMICALS, INCORPORATED and formed of a fluorine acryl oligomer.
  • the “MCF-310” was a methylethylketone/methylisobutylketone solution having a solid content of 30%, which includes a hydroxyl group.
  • the compounding agent C was "SERESTARL20R” which was a petroleum wax available from IPPOSHA YOSHI KABUSHIKI KAISHA, Japan.
  • the “SERESTARL20R” was a milky-white emulsion having a solid content of 40%.
  • the compounding agent D was "ELESTAN540" which was a fatty-acid-ester/silicon compound having a light yellow color.
  • the corresponding one of these compounding agents A, B, C and D was added to the reaction system for forming the desired polyurethane foam, with a predetermined value (phr) of parts by weight per 100 parts by weight of the polyurethane resin, as indicated in Tables 1 and 2.
  • Tables 1 and 2 indicate an open-cell ratio in each of the various types of polyurethane foam bodies (Examples of the present invention Nos. 1-5 and Comparative Examples Nos. 1-4), which ratio represents characteristics of the structure of the foam body, and a communicating hole diameter which is the diameter of each of the communication holes for mutual communication of the cells in each foam body.
  • the open-cell ratio was measured by using an air-comparative hydrometer "Type-1000" available from TOKYO SCIENCE INCORPORATED, Japan.
  • Tables 1 and 2 further indicate a gas permeability in each urethane foam body which represents a rate of gas flow through the foam body and which was measured as described above, and a contact angle of each urethane foam body.
  • the polyurethane foam body is formed in a molding method in which a PP (polypropylene) plate is disposed on a cavity surface of a lower mold, so that the formed polyurethane foam body is provided with a skin layer which is not influenced by a mold releasing agent applied to the cavity surface.
  • the polyurethane foam body is partially submerged in water, and the angle between the surface of the water and the surface of the skin layer is measured as the contact angle.
  • the coefficient of water absorbency represents a change rate of weight of each polyurethane foam body having a rectangular shape with dimensions of 100mm ⁇ 100mm ⁇ 50mm t , where the polyurethane foam body was immersed in water at a room temperature for 24 hours. The change rate was obtained on the basis of the weight before the immersion and the weight after the immersion.
  • the water absorbency was evaluated in accordance with two methods A and B. In the evaluation method A, 3mL of an engine oil was first dropped onto the surface of the skin layer of each polyurethane foam body, and it was then checked as to whether the dropped oil remained on the surface or permeated into the skin layer at the times when one, two, three and four hours passed since the oil was dropped onto the surface.
  • the communication holes communicating with the cells have respective diameters each of which is not larger than 60 ⁇ m, and the gas permeability through the polyurethane foam is held not higher than 1000mL/min.
  • the fluorine-containing surfactant included in the resin structure of the polyurethane foam is effective to reduce both of the coefficient of water absorption and the oil absorbency thereby remarkably improving the water and oil repellency of the foam body, and also to increase the noise transmission loss thereby assuring the excellent noise insulating properties of the foam body.
  • the noise insulating member constructed according to the present invention has excellent water and oil repellency as well as excellent noise insulating properties.
  • the noise insulating member of the invention is advantageously used in an automotive vehicle, particularly, in the engine room of the vehicle, for reducing undesirable transmission of noise into the passenger compartment or to the outside of the vehicle.
  • the noise insulating member is also advantageously used in a hydro-bike.
  • the noise insulating member is characterized by including a polyurethane foam obtained by reaction of an organic polyisocyanate component and a polyol component in the presence of a fluorine-containing surfactant, and having a cellular network having cells and communication holes which communicate with said cells.
  • the communication holes have respective diameters each of which is not larger than 60 ⁇ m.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Multimedia (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
EP00101572A 1999-01-28 2000-01-27 Verwendung eines schallisolierenden Polyurethan-Schaum Formteils mit geringer Wasser und Ölabsorption Expired - Lifetime EP1029742B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2024899 1999-01-28
JP2024899A JP2000220467A (ja) 1999-01-28 1999-01-28 低吸水・低吸油性防音材

Publications (2)

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EP1029742A1 true EP1029742A1 (de) 2000-08-23
EP1029742B1 EP1029742B1 (de) 2002-11-13

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US (1) US6237717B1 (de)
EP (1) EP1029742B1 (de)
JP (1) JP2000220467A (de)
DE (1) DE60000749T2 (de)

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US6358890B1 (en) * 1998-08-24 2002-03-19 Namba Press Works Co., Ltd. Treating agent for preventing grating noise from generating between urethane foam and metal surface and method thereof
EP1215381A2 (de) * 2000-12-12 2002-06-19 Nichias Corporation Akustisch gedämpfer Deckel für Kraftwagen
EP1459939A1 (de) * 2003-03-20 2004-09-22 Intier Automotive Näher GmbH Schallreduktionssystem für Kraftfahrzeuge
EP1602675A1 (de) * 2003-02-17 2005-12-07 Nhk Spring Company Limited Polyurethan-weichschaumstoff
EP1695872A1 (de) * 2005-02-25 2006-08-30 Renault s.a.s. Mehrschichtige, schallisolierende Vorrichtung, die den Anforderungen des Fussgängeraufpralls genügt und für eine Motorraumkomponente geeignet ist
DE102005012138A1 (de) * 2004-03-17 2006-10-19 Tokai Rubber Industries, Ltd., Komaki Einen Kühler umgebendes thermisch isolierendes Dichtungsmaterial
EP1741583A1 (de) * 2005-07-08 2007-01-10 REHAU AG + Co Luftführungselement für Kraftfahrzeuge
US7196438B2 (en) 2005-05-12 2007-03-27 Emerson Electric Co. Resilient isolation members and related methods of reducing acoustic noise and/or structural vibration in an electric machine
FR2901209A1 (fr) * 2006-05-22 2007-11-23 Cera Ecran d'insonorisation sur moteur forme a base de materiau poreux
DE102006027230A1 (de) * 2006-06-09 2007-12-20 EFA -Entwicklungsgesellschaft für Akustik mbH Akustisch und thermisch wirkende Isolation
EP2811137A1 (de) * 2013-06-04 2014-12-10 Basf Se Thermische Isolation eines Verbrennungsmotors
WO2015055869A1 (es) * 2013-10-17 2015-04-23 Manprocar Vigo, S.L. Procedimiento para recubrir piezas de interior de vehículos automóviles
DE102014217501A1 (de) * 2014-09-02 2016-03-03 Ford Global Technologies, Llc Thermische Kapselung für einen Kraftfahrzeugantriebsstrang und Kraftfahrzeug
DE102015217100A1 (de) * 2015-09-07 2017-03-09 Röchling Automotive SE & Co. KG Kfz-Funktionskomponente mit durch adhäsiven Schaum aufgebrachter Isolationslage
EP1742201A4 (de) * 2004-04-30 2017-07-19 Kabushiki Kaisha Kobe Seiko Sho Poröse schallabsorptionsstruktur
CN109826785A (zh) * 2017-11-23 2019-05-31 上海新安汽车隔音毡有限公司 一种汽车发动机舱内燃油泵罩盖及其制作方法
WO2021004935A1 (fr) * 2019-07-11 2021-01-14 Treves Products, Services & Innovation Montage d'un écran de protection acoustique sur un moteur de véhicule automobile

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KR20070005620A (ko) * 2004-03-15 2007-01-10 다우 글로벌 테크놀로지스 인크. 팽창형 가요성 폴리우레탄을 기재에 접착시키는 방법
JP2005337097A (ja) * 2004-05-26 2005-12-08 Tokai Rubber Ind Ltd 防音カバー
DE102004039438A1 (de) * 2004-08-13 2006-02-23 Stankiewicz Gmbh Verfahren zum Herstellen eines Schallisolations-Formteils mit Masse und Feder
EP1659004B1 (de) * 2004-11-19 2012-02-01 Sumitomo Rubber Industries, Ltd. Einheit aus Reifen und Felge mit darin verwendetem Schallabsorber
JP4862189B2 (ja) * 2005-02-14 2012-01-25 日本発條株式会社 研磨パッド用クッション材
ATE427245T1 (de) * 2005-04-04 2009-04-15 Rieter Technologies Ag Hermetisches dunnes mehrschichtiges shallabsorbierendes element
DE102005023646A1 (de) * 2005-05-21 2006-11-23 Daimlerchrysler Ag Kraftfahrzeug mit Vorrichtung zur Verminderung der Schallabstrahlung
JP5105461B2 (ja) * 2006-02-20 2012-12-26 東洋ゴム工業株式会社 研磨パッド
JP2008069893A (ja) * 2006-09-14 2008-03-27 Honda Motor Co Ltd 防音構造
US7635048B2 (en) * 2006-10-19 2009-12-22 Caterpillar Inc. Sound suppression device for internal combustion engine system
DE102010031855A1 (de) * 2010-07-22 2012-01-26 J. Eberspächer GmbH & Co. KG Abgasanlage
JP6009193B2 (ja) * 2012-03-30 2016-10-19 株式会社荏原製作所 真空排気装置
JP6323303B2 (ja) * 2014-11-10 2018-05-16 株式会社デンソー 電子部品ユニット
CN108458467B (zh) * 2017-02-17 2020-11-10 S.I.Pan公司 分离器以及包括该分离器的***
KR101960823B1 (ko) * 2017-02-17 2019-03-22 주식회사 에스아이판 무향실용 흡음구조체 및 이를 포함하는 무향실
US10968874B2 (en) * 2019-05-14 2021-04-06 Ford Global Technologies, Llc Collapsible foam sleeve for engine air induction system
DE102019123201A1 (de) * 2019-08-29 2021-03-18 Elringklinger Ag Verfahren zum Entwickeln eines Abschirmteils hinsichtlich dessen akustischer Eigenschaften
WO2024024845A1 (ja) * 2022-07-27 2024-02-01 株式会社イノアックコーポレーション ポリウレタンフォーム

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Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6358890B1 (en) * 1998-08-24 2002-03-19 Namba Press Works Co., Ltd. Treating agent for preventing grating noise from generating between urethane foam and metal surface and method thereof
EP1215381A2 (de) * 2000-12-12 2002-06-19 Nichias Corporation Akustisch gedämpfer Deckel für Kraftwagen
EP1215381A3 (de) * 2000-12-12 2003-04-23 Nichias Corporation Akustisch gedämpfer Deckel für Kraftwagen
EP1602675A4 (de) * 2003-02-17 2007-08-22 Nhk Spring Co Ltd Polyurethan-weichschaumstoff
EP1602675A1 (de) * 2003-02-17 2005-12-07 Nhk Spring Company Limited Polyurethan-weichschaumstoff
EP1459939A1 (de) * 2003-03-20 2004-09-22 Intier Automotive Näher GmbH Schallreduktionssystem für Kraftfahrzeuge
DE102005012138A1 (de) * 2004-03-17 2006-10-19 Tokai Rubber Industries, Ltd., Komaki Einen Kühler umgebendes thermisch isolierendes Dichtungsmaterial
EP1742201A4 (de) * 2004-04-30 2017-07-19 Kabushiki Kaisha Kobe Seiko Sho Poröse schallabsorptionsstruktur
FR2882540A1 (fr) * 2005-02-25 2006-09-01 Renault Sas Dispositif insonorisant multicouche, respectant des contraintes de chocs pietons, pour composant situe dans le compartiment moteur d'un vehicule automobile
EP1695872A1 (de) * 2005-02-25 2006-08-30 Renault s.a.s. Mehrschichtige, schallisolierende Vorrichtung, die den Anforderungen des Fussgängeraufpralls genügt und für eine Motorraumkomponente geeignet ist
US7196438B2 (en) 2005-05-12 2007-03-27 Emerson Electric Co. Resilient isolation members and related methods of reducing acoustic noise and/or structural vibration in an electric machine
EP1741583A1 (de) * 2005-07-08 2007-01-10 REHAU AG + Co Luftführungselement für Kraftfahrzeuge
FR2901209A1 (fr) * 2006-05-22 2007-11-23 Cera Ecran d'insonorisation sur moteur forme a base de materiau poreux
US7954596B2 (en) 2006-06-09 2011-06-07 Entwicklungsgesellschaft Fur Akustik (Efa) Mit Beschrankter Haftung Acoustically and thermally acting insulation
DE102006027230A1 (de) * 2006-06-09 2007-12-20 EFA -Entwicklungsgesellschaft für Akustik mbH Akustisch und thermisch wirkende Isolation
EP2604476A1 (de) 2006-06-09 2013-06-19 HP Pelzer Holding GmbH Akustisch und thermisch wirkende Isolation
KR101446967B1 (ko) * 2006-06-09 2014-10-06 에이치피 펠저 홀딩 게엠베하 음향 및 열에 대한 효과적인 절연재
KR101446976B1 (ko) * 2006-06-09 2014-10-07 에이치피 펠저 홀딩 게엠베하 음향 및 열에 대한 효과적인 절연재
WO2007141193A3 (de) * 2006-06-09 2008-05-29 Entwicklungsgesellschaft Fuer Akustisch und thermisch wirkende isolation
WO2014195153A1 (de) * 2013-06-04 2014-12-11 Basf Se Thermische isolation eines verbrennungsmotors
EP2811137A1 (de) * 2013-06-04 2014-12-10 Basf Se Thermische Isolation eines Verbrennungsmotors
WO2015055869A1 (es) * 2013-10-17 2015-04-23 Manprocar Vigo, S.L. Procedimiento para recubrir piezas de interior de vehículos automóviles
DE102014217501A1 (de) * 2014-09-02 2016-03-03 Ford Global Technologies, Llc Thermische Kapselung für einen Kraftfahrzeugantriebsstrang und Kraftfahrzeug
DE102014217501B4 (de) 2014-09-02 2019-03-28 Ford Global Technologies, Llc Thermische Kapselung für einen Kraftfahrzeugantriebsstrang
DE102015217100A1 (de) * 2015-09-07 2017-03-09 Röchling Automotive SE & Co. KG Kfz-Funktionskomponente mit durch adhäsiven Schaum aufgebrachter Isolationslage
CN109826785A (zh) * 2017-11-23 2019-05-31 上海新安汽车隔音毡有限公司 一种汽车发动机舱内燃油泵罩盖及其制作方法
WO2021004935A1 (fr) * 2019-07-11 2021-01-14 Treves Products, Services & Innovation Montage d'un écran de protection acoustique sur un moteur de véhicule automobile
FR3098469A1 (fr) * 2019-07-11 2021-01-15 Treves Products, Services & Innovation Montage d’un écran de protection acoustique sur un moteur de véhicule automobile

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DE60000749T2 (de) 2003-04-24
DE60000749D1 (de) 2002-12-19
EP1029742B1 (de) 2002-11-13
US6237717B1 (en) 2001-05-29
JP2000220467A (ja) 2000-08-08

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