EP0877029A3 - Dérivé optiquement actif de phosphine ayant un groupe vinyle, polymer en dérivant et ses complexes avec des méteaux de transition - Google Patents
Dérivé optiquement actif de phosphine ayant un groupe vinyle, polymer en dérivant et ses complexes avec des méteaux de transition Download PDFInfo
- Publication number
- EP0877029A3 EP0877029A3 EP98301768A EP98301768A EP0877029A3 EP 0877029 A3 EP0877029 A3 EP 0877029A3 EP 98301768 A EP98301768 A EP 98301768A EP 98301768 A EP98301768 A EP 98301768A EP 0877029 A3 EP0877029 A3 EP 0877029A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- transition metal
- phosphine derivative
- polymer
- lower alkyl
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003003 phosphines Chemical class 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 3
- 229910052723 transition metal Inorganic materials 0.000 title abstract 2
- 150000003624 transition metals Chemical class 0.000 title abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7283897 | 1997-03-11 | ||
JP72838/97 | 1997-03-11 | ||
JP07283897A JP3892932B2 (ja) | 1997-03-11 | 1997-03-11 | ビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0877029A2 EP0877029A2 (fr) | 1998-11-11 |
EP0877029A3 true EP0877029A3 (fr) | 1999-08-25 |
EP0877029B1 EP0877029B1 (fr) | 2002-12-11 |
Family
ID=13500957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98301768A Expired - Lifetime EP0877029B1 (fr) | 1997-03-11 | 1998-03-10 | Dérivé optiquement actif de phosphine ayant un groupe vinyle, polymer en dérivant et ses complexes avec des méteaux de transition |
Country Status (4)
Country | Link |
---|---|
US (1) | US6022936A (fr) |
EP (1) | EP0877029B1 (fr) |
JP (1) | JP3892932B2 (fr) |
DE (1) | DE69810002T2 (fr) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3892931B2 (ja) | 1997-03-11 | 2007-03-14 | 高砂香料工業株式会社 | 2個のビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体 |
US6229052B1 (en) | 1998-05-29 | 2001-05-08 | E. I. Du Pont De Nemours And Company | Hydroformylation of olefins using supported bis(phosphorus) ligands |
JP4275795B2 (ja) * | 1999-03-30 | 2009-06-10 | 高砂香料工業株式会社 | ビニル基を有するホスフィン誘導体、それをモノマーとするポリマー及びそれらの遷移金属錯体 |
US6420611B1 (en) * | 1999-09-20 | 2002-07-16 | E. I. Du Pont De Nemours And Company | Composition comprising polymeric phosphite |
JP2001139691A (ja) * | 1999-11-16 | 2001-05-22 | Mitsubishi Chemicals Corp | 3価リン含有重合体触媒によるアルデヒド類の製造方法および新規なホスファイト含有重合体 |
FR2802121A1 (fr) * | 1999-12-14 | 2001-06-15 | Expansia Sa | Supports polymeriques organiques possedant des ligands mono- ou bi-dentates et leur utilisation en catalyse supportee |
DE10002975A1 (de) | 2000-01-24 | 2001-07-26 | Degussa | Verwendung von molekulargewichtsvergrößerten Katalysatoren in einem Verfahren zur asymmetrischen kontinuierlichen Hydrierung, neue molekulargewichtsvergrößerte Liganden und Katalysatoren |
DE10002976A1 (de) * | 2000-01-24 | 2001-07-26 | Degussa | Molekulargewichtsvergrößerte Liganden für asymmetrische homogen lösliche Hydrierkatalysatoren, Verfahren zu deren Herstellung und Verwendung |
JP4725760B2 (ja) * | 2000-03-13 | 2011-07-13 | 東ソー株式会社 | 光学活性リン酸エステル誘導体及びその用途 |
US6271193B1 (en) | 2000-10-11 | 2001-08-07 | International Flavors & Fragrances Inc. | Carbon containing functional group substituted 4,5,6,7-tetrahydro-polyalkylated-4-indanes, isomers thereof, processes for preparing same and uses thereof |
AU2002365409A1 (en) * | 2001-11-26 | 2003-06-10 | E. I. Du Pont De Nemours And Company | Supported bis(phosphorus)ligands and their use in the catalysis |
US6660876B2 (en) | 2001-11-26 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions |
US20050277799A1 (en) * | 2004-06-12 | 2005-12-15 | Ingrid Boehmer | CH activation/dehydrogenation of hydrocarbons |
US7923396B2 (en) * | 2004-06-12 | 2011-04-12 | Conocophillips Company | Hydrocarbon conversion |
JP2007302859A (ja) * | 2006-04-12 | 2007-11-22 | Hokko Chem Ind Co Ltd | p−ホスフィン基含有スチレン−スチレン系共重合体を配位子とする新規なポリマー担持遷移金属錯体及び該錯体からなる触媒 |
JP4020155B2 (ja) * | 2006-07-31 | 2007-12-12 | 三菱化学株式会社 | 有機二リン基架橋型重合体 |
CN104667977B (zh) * | 2013-11-29 | 2017-09-29 | 中国科学院大连化学物理研究所 | 一种丙烯氢甲酰化制丁醛的催化剂体系及使用其的方法 |
CN104707663B (zh) * | 2013-12-11 | 2017-07-18 | 中国科学院大连化学物理研究所 | 一种有机配体聚合物载体及其制备方法 |
WO2015085504A1 (fr) * | 2013-12-11 | 2015-06-18 | 中国科学院大连化学物理研究所 | Procédé pour la production d'aldéhyde ayant un grand nombre d'atomes de carbone à l'aide d'une réaction d'hydroformylation d'oléfines |
CN104710289B (zh) * | 2013-12-11 | 2017-04-19 | 中国科学院大连化学物理研究所 | 一种采用固体多相催化剂的用于烯烃氢甲酰化反应的方法 |
CN104707660B (zh) * | 2013-12-11 | 2017-03-08 | 中国科学院大连化学物理研究所 | 一种用于烯烃氢甲酰化反应的固体多相催化剂及其制备方法和应用 |
CN106140302B (zh) * | 2015-04-03 | 2018-11-27 | 中国科学院大连化学物理研究所 | 一种含膦有机混聚物-金属多相催化剂及其方法和应用 |
CN106140301B (zh) * | 2015-04-03 | 2018-11-27 | 中国科学院大连化学物理研究所 | 含膦有机混聚物-金属多相催化剂及其制备方法和应用 |
CN106140303B (zh) * | 2015-04-03 | 2018-11-27 | 中国科学院大连化学物理研究所 | 一种含膦有机混聚物-金属多相催化剂及其制备和应用 |
CN116410390B (zh) * | 2021-12-31 | 2024-05-10 | 中国石油天然气股份有限公司 | 有机膦配体聚合物及二齿膦配体共聚物催化剂的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3847997A (en) * | 1969-06-12 | 1974-11-12 | Phillips Petroleum Co | Hydroformylation process and catalyst |
JPH0249009A (ja) * | 1988-05-21 | 1990-02-19 | Tokuyama Soda Co Ltd | 単量体組成物 |
EP0614903A2 (fr) * | 1993-03-12 | 1994-09-14 | Takasago International Corporation | Composés de phosphines, complexes contenant les composés de phosphines comme ligands, procédé pour préparer des aldéhides optiquement actifs en utilisant les composés de Phosphines ou les complexes, et dérivés de 4-(R)-1'-formylethyl azétidine-2-one |
EP0614901A1 (fr) * | 1993-03-12 | 1994-09-14 | Mitsubishi Gas Chemical Company, Inc. | Composé de phosphine et complexe métal de transition-phosphine contenant le même ligand |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5116882A (en) * | 1991-05-16 | 1992-05-26 | Arco Chemical Technology, L.P. | Process for making copolymers of vinyl aromatic monomers and vinyl phosphonic acid derivatives and foamed articles therefrom |
-
1997
- 1997-03-11 JP JP07283897A patent/JP3892932B2/ja not_active Expired - Fee Related
-
1998
- 1998-03-10 EP EP98301768A patent/EP0877029B1/fr not_active Expired - Lifetime
- 1998-03-10 DE DE69810002T patent/DE69810002T2/de not_active Expired - Fee Related
- 1998-03-11 US US09/038,131 patent/US6022936A/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3847997A (en) * | 1969-06-12 | 1974-11-12 | Phillips Petroleum Co | Hydroformylation process and catalyst |
JPH0249009A (ja) * | 1988-05-21 | 1990-02-19 | Tokuyama Soda Co Ltd | 単量体組成物 |
EP0614903A2 (fr) * | 1993-03-12 | 1994-09-14 | Takasago International Corporation | Composés de phosphines, complexes contenant les composés de phosphines comme ligands, procédé pour préparer des aldéhides optiquement actifs en utilisant les composés de Phosphines ou les complexes, et dérivés de 4-(R)-1'-formylethyl azétidine-2-one |
EP0614901A1 (fr) * | 1993-03-12 | 1994-09-14 | Mitsubishi Gas Chemical Company, Inc. | Composé de phosphine et complexe métal de transition-phosphine contenant le même ligand |
Non-Patent Citations (2)
Title |
---|
CHEMICAL ABSTRACTS, vol. 113, no. 12, 17 September 1990, Columbus, Ohio, US; abstract no. 098270, MATSUOKA S ET AL: "Monomer compositions and their use in manufacture of polymers with high refractive index" XP002107088 * |
NOZAKI K ET AL: "ASYMMETRIC HYDROFORMYLATION OF OLEFINS IN A HIGHLY CROSS-LINKED POLYMER MATRIX", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 120, no. 16, 29 April 1998 (1998-04-29), pages 4051/4052, XP000740765 * |
Also Published As
Publication number | Publication date |
---|---|
DE69810002D1 (de) | 2003-01-23 |
DE69810002T2 (de) | 2003-04-17 |
EP0877029A2 (fr) | 1998-11-11 |
US6022936A (en) | 2000-02-08 |
JPH10251283A (ja) | 1998-09-22 |
EP0877029B1 (fr) | 2002-12-11 |
JP3892932B2 (ja) | 2007-03-14 |
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