EP0461758A2 - Compositions and flooring materials using them - Google Patents
Compositions and flooring materials using them Download PDFInfo
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- EP0461758A2 EP0461758A2 EP91304220A EP91304220A EP0461758A2 EP 0461758 A2 EP0461758 A2 EP 0461758A2 EP 91304220 A EP91304220 A EP 91304220A EP 91304220 A EP91304220 A EP 91304220A EP 0461758 A2 EP0461758 A2 EP 0461758A2
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
- D06N7/0052—Compounding ingredients, e.g. rigid elements
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
Definitions
- the present invention relates to a flooring felt composition useful as a backing for linoleum or floor tile and containing a binder which is a latex copolymer made from a vinyl substituted aromatic monomer such as styrene, a conjugated diene monomer such as butadiene, a small amount of an unsaturated carboxylic acid such as itaconic acid, and a small amount of a functional crosslinking agent such as hydroxyethylacrylate.
- a binder which is a latex copolymer made from a vinyl substituted aromatic monomer such as styrene, a conjugated diene monomer such as butadiene, a small amount of an unsaturated carboxylic acid such as itaconic acid, and a small amount of a functional crosslinking agent such as hydroxyethylacrylate.
- Flooring felts have long been known to the art. However, a persistent problem is that they tend to be degraded by heat in drying ovens during the application and curing of a top coat to form a commercial floor covering.
- compositions useful for new flooring materials and preferably flooring felts of improved heat resistance.
- Flooring felts of the present invention generally contain a major amount of a generally water-insoluble filler, a styrene-butadiene type latex copolymer, various fibers, and antioxidants and have good heat resistance. More specifically, a flooring felt composition comprises approximately 100 parts by weight of one or more fillers, from about 5 to about 25 parts by weight of one or more different types of fiber, up to about 3 parts by weight of an antioxidant, and from about 5 to about 25 parts by weight of a latex copolymer, said latex copolymer made by polymerizing a monomer mixture containing (a) from about 20 to about 70 parts by weight of a vinyl substituted aromatic monomer having from 8 to 15 carbon atoms, (b) from about 30 to about 70 percent by weight of a conjugated diene having from 4 to about 12 carbon atoms, (c) up to about 5 percent by weight of an unsaturated carboxylic acid, and (d) up to about 5 percent by weight of a functional crosslinking agent other than said unsaturated
- the latex copolymer which acts as a binder in a flooring felt composition is made from a vinyl substituted aromatic monomer, a conjugated diene, an unsaturated carboxylic acid, and a functional cross-linking agent other than the carboxylic acid.
- the vinyl substituted aromatic monomer may contain from 8 to about 15 carbon atoms, desirably from 8 to about 12 carbon atoms, with styrene being preferred.
- Examples of such monomers include alpha-methylstyrene, 3-methylstyrene vinyltoluene, propylstyrene, butylstyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, and the like.
- the amount of the vinyl substituted aromatic monomer is generally from about 20 to about 70 percent by weight with from about 40 to about 60 percent by weight being preferred, based upon the total weight of the latex copolymer-forming monomers.
- the conjugated diene monomer utilized in forming the styrene-butadiene type copolymer is a conjugated diene having from 4 to 12 carbon atoms, desirably from about 4 to 8 carbon atoms, with butadiene being preferred.
- specific conjugated dienes include butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 2-methyl-1,3-pentadiene, 3,4-dimethyl-1,3-hexadiene, 4,5-diethyl-1,3-octadiene, hexadiene, and the like.
- the amount of the conjugated diene monomer is generally from about 30 to about 70 percent by weight and preferably from about 40 to about 60 percent by weight based upon the total weight of all the monomers forming the latex copolymer binder.
- the unsaturated carboxylic acid is a polycarboxylic acid such as a dicarboxylic acid.
- Unsaturated carboxylic acids may be utilized which have a total of from about 4 to about 10 carbon atoms, and about 2 carboxyl groups, and generally one point of unsaturation.
- monocarboxylic acids such as acrylic acid as well as methacrylic acid and various derivatives thereof not be utilized, inasmuch as they tend to yield poor results with regard to heat resistant properties of the flooring felt composition.
- the latex monomer forming composition is free from acrylic acid, and the like.
- suitable unsaturated acids include fumaric acid, itaconic acid, and derivatives thereof, as well as mixtures thereof, with fumaric and itaconic acid being preferred.
- the amount of the unsaturated acid is generally up to about 5 percent by weight and preferably from about 1 to about 3 percent by weight based upon the total weight of the latex copolymer-forming monomers.
- the functional crosslinking monomers are monomers other than the unsaturated acids which serve to form crosslinks with entities such as fibers, fillers, other latex polymer particles, and the like.
- Examples of functional crosslinking agents or monomers include acrylamide, methacrylamide, and N-methylolacrylamide, hydroxyethylacrylate, glycidylmethacrylate, and the like, as well as mixtures thereof.
- the amount of the various functional crosslinking agents utilized is up to 5 percent by weight, desirably from about 1 to about 4 percent by weight, and preferably from about 2 to about 3 percent by weight based upon the total weight of the latex copolymer-forming monomers.
- the above-noted monomers forming the latex copolymer which serves as a binder may be polymerized in a conventional manner as is well known to the art and to the literature.
- polymerization is generally conducted in water in the presence of surfactants, chain transfer agents, various free radical initiators, various chelating agents, various shortstop compounds, electrolytes, and the like.
- surfactants they can be cationic, anionic, or mixtures thereof with nonionics.
- Examples of specific surfactants include the various alkyl sulfates, the various alkyl sulfosuccinates, the various alkyl aryl sulfonates, the various alpha-olefin sulfonates, the various quaternary ammonium salt, the various amine salts, the various fatty or resin acid salts, nonyl or octyl phenol reaction products of ethylene oxide, and the like.
- the alkyl portion of the various surfactants generally has from 8 to 18 carbon atoms. Naturally, an amount of a surfactant is utilized to obtain an aqueous emulsion of the various monomers.
- such an amount is typically from about 0.5 to about 5 or 6 parts by weight for every 100 parts by weight of the monomers.
- Other surfactants can be utilized such as those set forth in McCutcheon's "Detergents and Emulsifiers,” such as the 1990 edition, published by McCutcheon's Division, Allured Publishing Corporation, Ridgewood, New Jersey, “Surface Active Agents,” Schwartz and Perry, Vol. I, Interscience Publishers, Inc., New York, 1958; "Surface Activity,” Moilliet, Collie and Black, D. Van Nostrand Company, Inc., New York, 1961; “Organic Chemistry,” Fieser and Fieser, D.C. Heath and Company, Boston, 1944; and "The Merck Index,” Seventh Edition, Merck & Co., Inc., Rahway, N.J., 1960, all of which are hereby fully incorporated by reference.
- the various chain extenders or molecular weight regulators can be conventional compounds as well as those known to the art and to the literature. Accordingly, compounds such as triphenyl methane, and carbon tetrachloride can be utilized. However, mercaptans such as the alkyl and/or aralkyl mercaptans having from 8 to about 18 carbon atoms and preferably from about 12 to about 14 carbon atoms are preferably utilized. The tertiary alkyl mercaptans having from 12 to 14 carbon atoms are highly preferred.
- Suitable mercaptans include n-octyl mercaptan, n-dodecyl mercaptan, t-octyl mercaptan, t-dodecyl mercaptan, p-tridecyl mercaptan, tetradecyl mercaptan, hexadecyl mercaptan, and the like, as well as mixtures thereof.
- the amount of the molecular weight modifiers is an effective amount to provide for the proper retention of the tensile strength of the copolymer, for example from about 0.1 to about 5.0 parts by weight and desirably from about 0.2 to about 1.0 parts by weight for every 100 parts by weight of the monomers.
- the free-radical initiators which are utilized to polymerize the various monomers are utilized in amounts sufficient to obtain a desired molecular weight.
- a suitable amount is generally from about 0.15 to about 2.0 with from about 0.25 to about 1.5 parts being preferred for every 100 parts by weight of the monomers.
- Conventional free-radical initiators can be utilized as well as those known to the art and to the literature. Specific examples include ammonium persulfate, potassium persulfate, or sodium persulfate, hydrogen peroxide, and the like.
- Other free-radical initiators can be utilized which decompose or become active at the temperature utilized during polymerization.
- Examples of other free-radical catalysts include cumene hydroperoxide, dibenzoyl peroxide, diacetyl peroxide, dodecanoyl peroxide, di-t-butyl peroxide, dilauroyl peroxide, bis(p-methoxy benzoyl) peroxide, t-butyl peroxy pivalate, dicumyl peroxide, isopropyl percarbonate, di-sec-butyl peroxidicarbonate, azobisdimethylvaleronitrile, 2,2'-azobisisobutyronitrile, 2,2'-azobis-2-methyl-butyronitrile, 2,2'-azobis (methylisobutyrate), and the like, and mixtures thereof.
- the various persulfates are generally preferred in the present techniques with the sodium salt thereof being highly preferred since it imparts better color to the resulting polymer when dried.
- Chelating agents can be utilized during polymerization to tie up various metal impurities as well as to achieve a uniform polymerization.
- the amounts of such chelating agents are generally small such as from about 0.01 to about 0.25 parts by weight for every 100 parts by weight of the monomers.
- suitable chelating agents include ethylene diamine tetraacetic acid, nitrilotriacetic acid, citric acid, and their ammonium, potassium, and sodium salts.
- shortstop compounds can also be utilized. Not only do the shortstop compounds terminate the polymerization in the reactor at desired conversion levels, but also prevent further polymerization, cross-linking, etc., during stripping, and the like.
- suitable shortstop agents include hydroquinone, sodium sulfide, hydroxyl ammonium acid sulfate, hydroxyl ammonium sulfate, sodium diethyl dithiocarbamate, diethylhydroxylamine, sodium dimethyl dithiocarbamate, potassium dimethyl dithiocarbamate, dimethylammonium dimethyldithiocarbamate, hydroxylamine sulfate plus sodiumhydrosulfite, and the like.
- the amount of shortstop utilized is from about 0.05 to about 0.25 parts by weight for every 100 parts by weight of said monomers.
- Polymerization of the various monomers is carried out at a temperature sufficient to activate the initiators and the double bonds of the monomers. However, extremely high temperatures are avoided since they cause a run-away reaction. Too low temperatures are not desired since they retard polymerization. Suitable polymerization temperatures are from about 2°C to about 90°C, desirably from about 35°C to about 80°C, and preferably from about 65°C to about 77°C. Polymerization time will naturally vary depending upon the type of monomers utilized, the type of initiator utilized, and the degree of polymerization desired. Hence, typical polymerization times can range from about 5 to about 35 hours. Polymerization is generally carried out to completion and conducted in an acidic medium when acidic monomers are utilized. Upon completion of the reaction or the desired degree of polymerization, optional bases can be added to neutralize the latex. Examples of such optional bases include NaOH, KOH, NH4OH, and the like.
- the free radical polymerization can be carried out according to any conventional method including batch, incremental, or continuous.
- the water used during the polymerization should be free of deleterious material and hence is often distilled or ion exchanged water.
- the amount of water used is sufficient to enable the formation of an emulsion and to enable proper mixing of the various ingredients as well as to obtain the desired rate and degree of polymerization, heat transfer, and the like.
- the amount of copolymer or solids content can vary from about 10 percent to about 60 percent by weight and preferably from about 50 percent to about 55 percent by weight.
- polymerization is conducted in an inert atmosphere such as nitrogen, helium, argon, and the like, and hence it is carried out in a closed reactor.
- the reactor can be any conventional reactor and thus have suitable ports, agitation means, heating and cooling means, and the like.
- the reactors utilized are generally cleaned as by flushing with water between polymerization to remove traces of various initiators, shortstops, residues, surfactants, and the like.
- the latex copolymer is generally added to a slurry which contains appropriate amounts of fillers and fibers.
- the latex copolymer can also contain an optional antioxidant in generally small amounts.
- a slurry containing fibers is initially prepared.
- the various fibers are generally water insoluble and can be natural or synthetic.
- the fibers are typically water-dispersible and if not inherently so, dispersibility can be imparted thereto by providing a small amount of hydrophilic or ionic groups or charges on the fiber as known to the art.
- short fibers are preferred, that is fibers having a length generally less than 25mm (1") and preferably less than 13m (0.5").
- any type of fiber may be utilized known to the flooring felt composition art as well as to the literature and examples of specific fibers include polyester fiber, nylon fiber, polyethylene fiber, glass fiber, boron fiber, graphite fiber, carbon fiber, cellulose fiber as made from cotton, wood fiber as obtained from wood pulp, ceramic fiber, and the like.
- cellulose fibers which include fibers obtained from wood such as kraft fibers.
- the preparation of the fiber slurry generally involves soaking the various fibers in water and then agitating the same and applying mild heat so that the agitated slurry solution is at from about 20°C-55°C (about 70 to about 130°F).
- the amount of the fibers is based upon 100 parts by weight of the basic recipe (dry basis) which contains the various latex copolymers, the various fibers, the various fillers, as well as the optional antioxidants, and generally is from about 5 or 6 parts to about 25 parts by weight and preferably from about 7 parts to about 15 parts by weight (dry basis) based upon 100 parts by weight (dry basis) basic recipe.
- any type of filler can be utilized which is known to the flooring felt art as well as to the literature and such fillers generally have a small particle size.
- the amount of the various fillers is generally from about 30 to about 90 parts by weight, desirably from about 70 to about 90 parts by weight and preferably from about 80 to about 86 parts by weight based upon 100 parts by weight (dry basis) of the basic recipe, that is, the latex copolymer, the fibers, the fillers and the antioxidants.
- suitable fillers include various clays such as kaolin , calcium carbonate, magnesium carbonate, titanium dioxide, zinc oxide, magnesium oxide, silica, barium sulfate, calcium-based sulfate, diatomaceous earth, aluminum silicate, magnesium silicate, mica, barytes, perlite, feldspar, and the like. Clay and talc are generally preferred.
- the various fillers are generally added to the fiber slurry under high mixing or agitation and blended therewith.
- the amount of the latex copolymer on a dry basis is from about 5 or 6 to about 25 parts by weight, and preferably from about 8 to about 15 parts by weight based upon 100 parts by weight of the total basic recipe.
- Another basic component of the recipe is an optional but oftentimes desirable antioxidant.
- the amount of the antioxidant is generally small and typically up to about 2 or 3 parts by weight (dry basis) based upon 100 parts by weight (dry basis) of the basic recipe.
- any typically antioxidant well known to the flooring felt art as well as to the literature can be utilized such as various diphenyl amines, and the like, with specific commercial examples including Wingstay L, Santo white Crystals, or any other non-staining, non-discoloring antioxidant.
- aqueous slurry in addition to containing various fibers, various fillers, one or more latex copolymers, and the optional antioxidants, can also contain various additives such as bactericides and fungicides in effective amounts to achieve their purpose which is generally less than 0.1 parts by weight based upon 100 parts by weight (dry basis) of the basic flooring felt composition.
- a destabilizing agent or a flocculating agent is added to precipitate and agglomerate all of the components.
- Flocculating agents are known to the art and to the literature and specific examples include cationic polymers, alum, CaCl2, MgSO4, and the like.
- the amount of flocculating agent is an effective amount to generally precipitate typically all of the flooring felt composition and desirably an amount such that the supernatant is clear. Such amounts will vary from composition to composition, but can be readily determined and are known to those skilled in the art as well as to the literature.
- aqueous flooring felt composition After the aqueous flooring felt composition has been flocculated, it is generally applied to a fourdrinier wire having a fine sized screen thereon. Vacuum is applied to remove the existing water. Then the felt is dried in an oven.
- the flooring felt composition has been found to have unexpectedly improved high heat resistance.
- the above flooring felt had the following recipe.
- the latex was prepared as follows:
- the above latex copolymer was utilized as a binder in the above-noted preparation of a flooring felt composition.
- a hydroxy ethyl acrylate latex was made having the recipe set forth above and prepared in accordance with the above noted charge procedure.
- a flooring felt composition was then made in the exact manner as set forth hereinabove with regard to the furnish preparation, slurry preparation, etc. This flooring felt composition yielded a heat resistant value of 200 seconds.
- the flooring felt composition was made except that 1/2 part by weight of the styrene monomer was removed and 1/2 part by weight of an acrylic acid was substituted therefore. This composition yielded a heat resistant value of 104 seconds.
- the flooring felt composition was made except that 1.5 parts by weight of the styrene monomer was removed and 1.5 parts by weight of an acrylic acid was substituted therefore. This composition yielded a heat resistant value of 62 seconds.
- the flooring felt composition embodying the invention yielded an unexpectedly high good heat resistant value.
- very small amounts by weight of an acrylic acid were substituted in the latex copolymer recipe, a dramatic reduction in the heat resistant values were obtained.
- the heat resistance value is the number of seconds which the felt sample endures at 215°C (420°F) until an exotherm is noted i.e. the temperature rises above that level.
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Abstract
Description
- The present invention relates to a flooring felt composition useful as a backing for linoleum or floor tile and containing a binder which is a latex copolymer made from a vinyl substituted aromatic monomer such as styrene, a conjugated diene monomer such as butadiene, a small amount of an unsaturated carboxylic acid such as itaconic acid, and a small amount of a functional crosslinking agent such as hydroxyethylacrylate.
- Flooring felts have long been known to the art. However, a persistent problem is that they tend to be degraded by heat in drying ovens during the application and curing of a top coat to form a commercial floor covering.
- Various patents exists which relate to a terpolymer emulsion, U.S. Patent No. 4,128,520; a froth-aid, U.S. Patent No. 4,172,067; various latexes as set forth in U.S. Patent Nos. 4,217,395, 4,225,383, 4,331,738, 4,436,857, 4,438,232, 4,503,184, 4,567,099, 4,782,109, and 4,857,566; an emulsion such as set forth in U.S. Patent No. 4,602,059; and a dispersion such as set forth in U.S. Patent No. 4,661,557.
- Herein, we seek to provide compositions useful for new flooring materials, and preferably flooring felts of improved heat resistance.
- Flooring felts of the present invention generally contain a major amount of a generally water-insoluble filler, a styrene-butadiene type latex copolymer, various fibers, and antioxidants and have good heat resistance. More specifically, a flooring felt composition comprises approximately 100 parts by weight of one or more fillers, from about 5 to about 25 parts by weight of one or more different types of fiber, up to about 3 parts by weight of an antioxidant, and from about 5 to about 25 parts by weight of a latex copolymer, said latex copolymer made by polymerizing a monomer mixture containing (a) from about 20 to about 70 parts by weight of a vinyl substituted aromatic monomer having from 8 to 15 carbon atoms, (b) from about 30 to about 70 percent by weight of a conjugated diene having from 4 to about 12 carbon atoms, (c) up to about 5 percent by weight of an unsaturated carboxylic acid, and (d) up to about 5 percent by weight of a functional crosslinking agent other than said unsaturated carboxylic acid.
- The latex copolymer which acts as a binder in a flooring felt composition is made from a vinyl substituted aromatic monomer, a conjugated diene, an unsaturated carboxylic acid, and a functional cross-linking agent other than the carboxylic acid. Considering the vinyl substituted aromatic monomer, it may contain from 8 to about 15 carbon atoms, desirably from 8 to about 12 carbon atoms, with styrene being preferred. Examples of such monomers include alpha-methylstyrene, 3-methylstyrene vinyltoluene, propylstyrene, butylstyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, and the like. The amount of the vinyl substituted aromatic monomer is generally from about 20 to about 70 percent by weight with from about 40 to about 60 percent by weight being preferred, based upon the total weight of the latex copolymer-forming monomers.
- The conjugated diene monomer utilized in forming the styrene-butadiene type copolymer is a conjugated diene having from 4 to 12 carbon atoms, desirably from about 4 to 8 carbon atoms, with butadiene being preferred. Examples of specific conjugated dienes include butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 2-methyl-1,3-pentadiene, 3,4-dimethyl-1,3-hexadiene, 4,5-diethyl-1,3-octadiene, hexadiene, and the like. The amount of the conjugated diene monomer is generally from about 30 to about 70 percent by weight and preferably from about 40 to about 60 percent by weight based upon the total weight of all the monomers forming the latex copolymer binder.
- The unsaturated carboxylic acid is a polycarboxylic acid such as a dicarboxylic acid. Unsaturated carboxylic acids may be utilized which have a total of from about 4 to about 10 carbon atoms, and about 2 carboxyl groups, and generally one point of unsaturation. However, it is particularly preferable that monocarboxylic acids such as acrylic acid as well as methacrylic acid and various derivatives thereof not be utilized, inasmuch as they tend to yield poor results with regard to heat resistant properties of the flooring felt composition. Thus, the latex monomer forming composition is free from acrylic acid, and the like. Examples of suitable unsaturated acids include fumaric acid, itaconic acid, and derivatives thereof, as well as mixtures thereof, with fumaric and itaconic acid being preferred. The amount of the unsaturated acid is generally up to about 5 percent by weight and preferably from about 1 to about 3 percent by weight based upon the total weight of the latex copolymer-forming monomers.
- The functional crosslinking monomers are monomers other than the unsaturated acids which serve to form crosslinks with entities such as fibers, fillers, other latex polymer particles, and the like. Examples of functional crosslinking agents or monomers include acrylamide, methacrylamide, and N-methylolacrylamide, hydroxyethylacrylate, glycidylmethacrylate, and the like, as well as mixtures thereof. The amount of the various functional crosslinking agents utilized is up to 5 percent by weight, desirably from about 1 to about 4 percent by weight, and preferably from about 2 to about 3 percent by weight based upon the total weight of the latex copolymer-forming monomers.
- The above-noted monomers forming the latex copolymer which serves as a binder may be polymerized in a conventional manner as is well known to the art and to the literature. Thus, polymerization is generally conducted in water in the presence of surfactants, chain transfer agents, various free radical initiators, various chelating agents, various shortstop compounds, electrolytes, and the like. Considering the surfactants, they can be cationic, anionic, or mixtures thereof with nonionics. Examples of specific surfactants include the various alkyl sulfates, the various alkyl sulfosuccinates, the various alkyl aryl sulfonates, the various alpha-olefin sulfonates, the various quaternary ammonium salt, the various amine salts, the various fatty or resin acid salts, nonyl or octyl phenol reaction products of ethylene oxide, and the like. The alkyl portion of the various surfactants generally has from 8 to 18 carbon atoms. Naturally, an amount of a surfactant is utilized to obtain an aqueous emulsion of the various monomers. Generally, such an amount is typically from about 0.5 to about 5 or 6 parts by weight for every 100 parts by weight of the monomers. Other surfactants can be utilized such as those set forth in McCutcheon's "Detergents and Emulsifiers," such as the 1990 edition, published by McCutcheon's Division, Allured Publishing Corporation, Ridgewood, New Jersey, "Surface Active Agents," Schwartz and Perry, Vol. I, Interscience Publishers, Inc., New York, 1958; "Surface Activity," Moilliet, Collie and Black, D. Van Nostrand Company, Inc., New York, 1961; "Organic Chemistry," Fieser and Fieser, D.C. Heath and Company, Boston, 1944; and "The Merck Index," Seventh Edition, Merck & Co., Inc., Rahway, N.J., 1960, all of which are hereby fully incorporated by reference.
- The various chain extenders or molecular weight regulators can be conventional compounds as well as those known to the art and to the literature. Accordingly, compounds such as triphenyl methane, and carbon tetrachloride can be utilized. However, mercaptans such as the alkyl and/or aralkyl mercaptans having from 8 to about 18 carbon atoms and preferably from about 12 to about 14 carbon atoms are preferably utilized. The tertiary alkyl mercaptans having from 12 to 14 carbon atoms are highly preferred. Examples of suitable mercaptans include n-octyl mercaptan, n-dodecyl mercaptan, t-octyl mercaptan, t-dodecyl mercaptan, p-tridecyl mercaptan, tetradecyl mercaptan, hexadecyl mercaptan, and the like, as well as mixtures thereof. The amount of the molecular weight modifiers is an effective amount to provide for the proper retention of the tensile strength of the copolymer, for example from about 0.1 to about 5.0 parts by weight and desirably from about 0.2 to about 1.0 parts by weight for every 100 parts by weight of the monomers.
- The free-radical initiators which are utilized to polymerize the various monomers are utilized in amounts sufficient to obtain a desired molecular weight. A suitable amount is generally from about 0.15 to about 2.0 with from about 0.25 to about 1.5 parts being preferred for every 100 parts by weight of the monomers. Conventional free-radical initiators can be utilized as well as those known to the art and to the literature. Specific examples include ammonium persulfate, potassium persulfate, or sodium persulfate, hydrogen peroxide, and the like. Other free-radical initiators can be utilized which decompose or become active at the temperature utilized during polymerization. Examples of other free-radical catalysts include cumene hydroperoxide, dibenzoyl peroxide, diacetyl peroxide, dodecanoyl peroxide, di-t-butyl peroxide, dilauroyl peroxide, bis(p-methoxy benzoyl) peroxide, t-butyl peroxy pivalate, dicumyl peroxide, isopropyl percarbonate, di-sec-butyl peroxidicarbonate, azobisdimethylvaleronitrile, 2,2'-azobisisobutyronitrile, 2,2'-azobis-2-methyl-butyronitrile, 2,2'-azobis (methylisobutyrate), and the like, and mixtures thereof. The various persulfates are generally preferred in the present techniques with the sodium salt thereof being highly preferred since it imparts better color to the resulting polymer when dried.
- Chelating agents can be utilized during polymerization to tie up various metal impurities as well as to achieve a uniform polymerization. The amounts of such chelating agents are generally small such as from about 0.01 to about 0.25 parts by weight for every 100 parts by weight of the monomers. Examples of suitable chelating agents include ethylene diamine tetraacetic acid, nitrilotriacetic acid, citric acid, and their ammonium, potassium, and sodium salts.
- Various shortstop compounds can also be utilized. Not only do the shortstop compounds terminate the polymerization in the reactor at desired conversion levels, but also prevent further polymerization, cross-linking, etc., during stripping, and the like. Examples of suitable shortstop agents include hydroquinone, sodium sulfide, hydroxyl ammonium acid sulfate, hydroxyl ammonium sulfate, sodium diethyl dithiocarbamate, diethylhydroxylamine, sodium dimethyl dithiocarbamate, potassium dimethyl dithiocarbamate, dimethylammonium dimethyldithiocarbamate, hydroxylamine sulfate plus sodiumhydrosulfite, and the like. The amount of shortstop utilized is from about 0.05 to about 0.25 parts by weight for every 100 parts by weight of said monomers.
- Polymerization of the various monomers is carried out at a temperature sufficient to activate the initiators and the double bonds of the monomers. However, extremely high temperatures are avoided since they cause a run-away reaction. Too low temperatures are not desired since they retard polymerization. Suitable polymerization temperatures are from about 2°C to about 90°C, desirably from about 35°C to about 80°C, and preferably from about 65°C to about 77°C. Polymerization time will naturally vary depending upon the type of monomers utilized, the type of initiator utilized, and the degree of polymerization desired. Hence, typical polymerization times can range from about 5 to about 35 hours. Polymerization is generally carried out to completion and conducted in an acidic medium when acidic monomers are utilized. Upon completion of the reaction or the desired degree of polymerization, optional bases can be added to neutralize the latex. Examples of such optional bases include NaOH, KOH, NH₄OH, and the like.
- The free radical polymerization can be carried out according to any conventional method including batch, incremental, or continuous. The water used during the polymerization should be free of deleterious material and hence is often distilled or ion exchanged water. The amount of water used is sufficient to enable the formation of an emulsion and to enable proper mixing of the various ingredients as well as to obtain the desired rate and degree of polymerization, heat transfer, and the like. Upon completion of polymerization, the amount of copolymer or solids content can vary from about 10 percent to about 60 percent by weight and preferably from about 50 percent to about 55 percent by weight.
- Desirably, polymerization is conducted in an inert atmosphere such as nitrogen, helium, argon, and the like, and hence it is carried out in a closed reactor. The reactor can be any conventional reactor and thus have suitable ports, agitation means, heating and cooling means, and the like. In accordance with conventional practice, the reactors utilized are generally cleaned as by flushing with water between polymerization to remove traces of various initiators, shortstops, residues, surfactants, and the like.
- Once the latex copolymer has been formed, it is generally added to a slurry which contains appropriate amounts of fillers and fibers. The latex copolymer can also contain an optional antioxidant in generally small amounts.
- In the preparation of a flooring felt composition , a slurry containing fibers is initially prepared. The various fibers are generally water insoluble and can be natural or synthetic. The fibers are typically water-dispersible and if not inherently so, dispersibility can be imparted thereto by providing a small amount of hydrophilic or ionic groups or charges on the fiber as known to the art. Generally, short fibers are preferred, that is fibers having a length generally less than 25mm (1") and preferably less than 13m (0.5"). Generally any type of fiber may be utilized known to the flooring felt composition art as well as to the literature and examples of specific fibers include polyester fiber, nylon fiber, polyethylene fiber, glass fiber, boron fiber, graphite fiber, carbon fiber, cellulose fiber as made from cotton, wood fiber as obtained from wood pulp, ceramic fiber, and the like. Especially preferred in the present invention are cellulose fibers which include fibers obtained from wood such as kraft fibers. The preparation of the fiber slurry generally involves soaking the various fibers in water and then agitating the same and applying mild heat so that the agitated slurry solution is at from about 20°C-55°C (about 70 to about 130°F). The amount of the fibers is based upon 100 parts by weight of the basic recipe (dry basis) which contains the various latex copolymers, the various fibers, the various fillers, as well as the optional antioxidants, and generally is from about 5 or 6 parts to about 25 parts by weight and preferably from about 7 parts to about 15 parts by weight (dry basis) based upon 100 parts by weight (dry basis) basic recipe.
- Generally, any type of filler can be utilized which is known to the flooring felt art as well as to the literature and such fillers generally have a small particle size. The amount of the various fillers is generally from about 30 to about 90 parts by weight, desirably from about 70 to about 90 parts by weight and preferably from about 80 to about 86 parts by weight based upon 100 parts by weight (dry basis) of the basic recipe, that is, the latex copolymer, the fibers, the fillers and the antioxidants. Examples of suitable fillers include various clays such as kaolin , calcium carbonate, magnesium carbonate, titanium dioxide, zinc oxide, magnesium oxide, silica, barium sulfate, calcium-based sulfate, diatomaceous earth, aluminum silicate, magnesium silicate, mica, barytes, perlite, feldspar, and the like. Clay and talc are generally preferred. The various fillers are generally added to the fiber slurry under high mixing or agitation and blended therewith.
- To the fiber-filler slurry is added the above described aqueous latex copolymer. The amount of the latex copolymer on a dry basis is from about 5 or 6 to about 25 parts by weight, and preferably from about 8 to about 15 parts by weight based upon 100 parts by weight of the total basic recipe.
- Another basic component of the recipe is an optional but oftentimes desirable antioxidant. The amount of the antioxidant is generally small and typically up to about 2 or 3 parts by weight (dry basis) based upon 100 parts by weight (dry basis) of the basic recipe. Generally any typically antioxidant well known to the flooring felt art as well as to the literature can be utilized such as various diphenyl amines, and the like, with specific commercial examples including Wingstay L, Santo white Crystals, or any other non-staining, non-discoloring antioxidant.
- The above-noted aqueous slurry, in addition to containing various fibers, various fillers, one or more latex copolymers, and the optional antioxidants, can also contain various additives such as bactericides and fungicides in effective amounts to achieve their purpose which is generally less than 0.1 parts by weight based upon 100 parts by weight (dry basis) of the basic flooring felt composition.
- After addition of the various additives to the agueous flooring felt slurry, a destabilizing agent or a flocculating agent is added to precipitate and agglomerate all of the components. Flocculating agents are known to the art and to the literature and specific examples include cationic polymers, alum, CaCl₂, MgSO₄, and the like. The amount of flocculating agent is an effective amount to generally precipitate typically all of the flooring felt composition and desirably an amount such that the supernatant is clear. Such amounts will vary from composition to composition, but can be readily determined and are known to those skilled in the art as well as to the literature.
- After the aqueous flooring felt composition has been flocculated, it is generally applied to a fourdrinier wire having a fine sized screen thereon. Vacuum is applied to remove the existing water. Then the felt is dried in an oven. The flooring felt composition has been found to have unexpectedly improved high heat resistance.
- The invention will be better understood by reference to the following examples.
-
- A. Place the following into a Williams stock breaker and disintegrator bucket and allow to soak for five minutes, then refine for 60 minutes (198 gms. bleached kraft, 7000 mls. deionized water).
- B. Pour the furnish into a 191 (5 gal) bucket and dilute to 18,750 mls. with deionized water. Pour into 571 (15 gal) bucket and add 18,750 of distilled water.
- 1. Check freeness:(0.528% furnish) 568 Ml. + 432 Ml. deionised water. Record freeness on work sheet (should be about 600 CSF).
- C. Agitate slurry and heat to 40°C (100°F).
-
- A. Dip out 2,500 mls. of the above slurry into a 3.91(1 gal) bucket. Begin agitating at 1,000 rpm with a high lift blade and add 12.0 gms. Narvon F-3 clay, 31.0 gms. Afton clay, 27.3 gms. Dicalite clay, 1.5 gms. OCF Glasfiber (grade 691-20-1/8).
- B. Slowly add 5.00 gm. (wet weight) of a 5.0% Kymene 557 (a polyacrylamide type polymer) solution to the slurry. Allow to mix about 60 seconds.
- C. Mix up the latex/anti-oxidant solution and dilute with 75 mls. of deionized water. Add to agitating slurry.
- 1. Latex/anti-oxidant solution
- a. Add 14.0 gms. of dry weight latex plus 2.25 pts. (on latex dry weight) of ANTI-OXIDANT (0.69 gms. Tiarco T-558, 42.5 percent fine grind Wingstay L dispersion. Adjust amount for other A-O dispersions).
- 1. Latex/anti-oxidant solution
- D. Wait 60 seconds. Start timer and add sufficient Betz 1260 (cationic) flocculent as a 0.25 percent solution to clear water. Record weight of flocculent used.
- 1. Agitate for 10 minutes, then add sufficient flocculent to clear slurry completely. Note amount, then agitate five more minutes and check freeness and make handsheets.
- Follow standard CSF freeness procedures using 75 ml of slurry and 925 ml of deionized water.
-
- A. Stretch a piece of cheesecloth over screen of 20 x 20 cm (8 x 8 inch) valley sheet forming mold.
- B. Close mold, add 1 liter of water to the mold.
- C. Add 850 mls. of the slurry to the mold, stir to disperse the fibers. Start timer and open drain valve on mold. Record time it takes for water to disappear from the surface of the sheet. Record this as the drain time in seconds.
- D. Pull vacuum on the mold for 30 seconds.
-
- A. Open drain box, place three 24 x 24 cm (9.5" x 9.5") blotters over sheet.
- B. Place a 20 x 20 cm (8" x 8") S.S. plate on blotters.
- C. Place roller in center of plate, roll back and forth five times, starting and ending in center. Remove plate and blotters.
- D. Lift sheet from screen by cheesecloth and place on fresh blotter with cheesecloth up. Remove cheesecloth.
-
- A. Place sheet on three blotters in center of press. Cover with release paper and press at approximately 13.7t (13.5 tons) for 60 seconds.
- Dry at 100°C (215°F) for ten minutes. Turn sheet over after five minutes.
- Obtain caliper, sheet weight, density, ambient tensile and percent elongation, 180°C (360°F) hot tensile and percent elongation, stiffness, split strength, plasticizer (pick-up, ambient tensile and elongation, 180°C (360°F) hot tensile and elongation), and 215°C (420°F) heat age.
-
-
- The above latex copolymer was utilized as a binder in the above-noted preparation of a flooring felt composition.
- A hydroxy ethyl acrylate latex was made having the recipe set forth above and prepared in accordance with the above noted charge procedure. A flooring felt composition was then made in the exact manner as set forth hereinabove with regard to the furnish preparation, slurry preparation, etc. This flooring felt composition yielded a heat resistant value of 200 seconds.
- In an exact identical manner as set forth in Example 1, the flooring felt composition was made except that 1/2 part by weight of the styrene monomer was removed and 1/2 part by weight of an acrylic acid was substituted therefore. This composition yielded a heat resistant value of 104 seconds.
- In an exact identical manner as set forth in Example 1, the flooring felt composition was made except that 1.5 parts by weight of the styrene monomer was removed and 1.5 parts by weight of an acrylic acid was substituted therefore. This composition yielded a heat resistant value of 62 seconds.
- As apparent from the above examples, the flooring felt composition embodying the invention yielded an unexpectedly high good heat resistant value. In contrast, when very small amounts by weight of an acrylic acid were substituted in the latex copolymer recipe, a dramatic reduction in the heat resistant values were obtained.
- In the above Examples, the heat resistance value is the number of seconds which the felt sample endures at 215°C (420°F) until an exotherm is noted i.e. the temperature rises above that level.
Claims (14)
- A flooring felt composition, comprising:
from about 30 to about 90 parts by weight of at least one filler,
from about 5 to about 25 parts by weight of at least one fiber material,
optionally, up to about 3 parts by weight of an antioxidant, and
from about 5 to about 25 parts by weight of a latex copolymer, said latex copolymer comprising residues of the following monomers:(a) from about 20 to about 70 percent by weight of a vinyl substituted aromatic monomer having from 8 to 15 carbon atoms,(b) from about 30 to about 70 percent by weight of a conjugated diene having from 4 to about 12 carbon atoms,(c) up to about 5 percent by weight of an unsaturated polycarboxylic acid, but being substantially free of any acrylic or methacrylic acid, and(d) up to about 5 percent by weight of a functional crosslinking agent other than said unsaturated carboxylic acid. - A composition according to claim 1 comprising 70 to 90 parts by weight of the filler.
- A composition according to claim 1 or claim 2 in which the filler is clay or talc.
- A composition according to any one of claims 1 to 3 comprising 7 to 15 parts by weight of the fibre material.
- A composition according to any one of the preceding claims in which the fibre material is cellulosic.
- A composition according to any one of the preceding claims comprising 8 to 15 parts by weight of the latex copolymer.
- A composition according to any one of the preceding claims in which the monomers residual in the latex copolymer comprise 40 to 60% by weight of the vinyl substituted aromatic monomer and 40 to 60% by weight of the conjugated diene.
- A composition according to any one of the preceding claims in which the vinyl substituted aromatic monomer comprises styrene and the conjugated diene comprises butadiene.
- A composition according to any one of the preceding claims in which the monomers residual in the latex copolymer comprise 1 to 3% by weight of the unsaturated polycarboxylic acid and 1 to 4% by weight of the functional cross-linking agent.
- A composition according to any one of the preceding claims in which the unsaturated polycarboxylic acid comprises itaconic acid, fumaric acid, or a mixture of these.
- A composition according to any one of the preceding claims in which the functional cross-linking agent comprises acrylamide, methacrylamide, N-methylolacrylamide, hydroxyethylacrylate, and glycidylmethacrylate.
- A flooring felt obtainable by curing a composition according to any one of claims 1 to 11.
- A flooring material comprising a substrate of a flooring felt according to claim 12, and a top flooring material layer on said substrate.
- A method of making a flooring felt, comprising curing a composition according to any one of claims 1 to 11.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53940990A | 1990-06-13 | 1990-06-13 | |
US539409 | 1990-06-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0461758A2 true EP0461758A2 (en) | 1991-12-18 |
EP0461758A3 EP0461758A3 (en) | 1992-08-19 |
Family
ID=24151095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19910304220 Withdrawn EP0461758A3 (en) | 1990-06-13 | 1991-05-10 | Compositions and flooring materials using them |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0461758A3 (en) |
JP (1) | JPH0672363B2 (en) |
CA (1) | CA2031120A1 (en) |
MX (1) | MX173522B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7836648B2 (en) | 2002-05-03 | 2010-11-23 | Faus Group | Flooring system having complementary sub-panels |
US8209928B2 (en) | 1999-12-13 | 2012-07-03 | Faus Group | Embossed-in-registration flooring system |
US8875460B2 (en) | 1999-11-05 | 2014-11-04 | Faus Group, Inc. | Direct laminated floor |
CN111886265A (en) * | 2018-03-30 | 2020-11-03 | 日本A&L株式会社 | Process for producing conjugated diene copolymer latex |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8112958B2 (en) | 2002-05-03 | 2012-02-14 | Faus Group | Flooring system having complementary sub-panels |
US8181407B2 (en) | 2002-05-03 | 2012-05-22 | Faus Group | Flooring system having sub-panels |
US8201377B2 (en) | 2004-11-05 | 2012-06-19 | Faus Group, Inc. | Flooring system having multiple alignment points |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4225383A (en) * | 1978-02-02 | 1980-09-30 | The Dow Chemical Company | Highly filled sheets and method of preparation thereof |
US4810329A (en) * | 1987-09-08 | 1989-03-07 | The Dow Chemical Company | Composite flooring felt for vinyl flooring containing latexes and an activator |
EP0426280A1 (en) * | 1989-11-03 | 1991-05-08 | Gencorp Inc. | Paper mats |
-
1990
- 1990-11-29 CA CA 2031120 patent/CA2031120A1/en not_active Abandoned
- 1990-12-06 MX MX2362190A patent/MX173522B/en unknown
-
1991
- 1991-05-10 EP EP19910304220 patent/EP0461758A3/en not_active Withdrawn
- 1991-06-11 JP JP16521691A patent/JPH0672363B2/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4225383A (en) * | 1978-02-02 | 1980-09-30 | The Dow Chemical Company | Highly filled sheets and method of preparation thereof |
US4810329A (en) * | 1987-09-08 | 1989-03-07 | The Dow Chemical Company | Composite flooring felt for vinyl flooring containing latexes and an activator |
EP0426280A1 (en) * | 1989-11-03 | 1991-05-08 | Gencorp Inc. | Paper mats |
Non-Patent Citations (1)
Title |
---|
CHEMICAL ABSTRACTS, vol. 102, no. 6, 1984, Columbus, Ohio, US; abstract no. 46992C, 'BINDER FOR MANUFACTURING SHEETS' & JP-A-59126000 (JAPAN SYNTHETIC RUBBER) 20-7-84 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8875460B2 (en) | 1999-11-05 | 2014-11-04 | Faus Group, Inc. | Direct laminated floor |
US8209928B2 (en) | 1999-12-13 | 2012-07-03 | Faus Group | Embossed-in-registration flooring system |
US7836648B2 (en) | 2002-05-03 | 2010-11-23 | Faus Group | Flooring system having complementary sub-panels |
CN111886265A (en) * | 2018-03-30 | 2020-11-03 | 日本A&L株式会社 | Process for producing conjugated diene copolymer latex |
TWI726292B (en) * | 2018-03-30 | 2021-05-01 | 日商日本A&L股份有限公司 | Method for manufacturing conjugated diene copolymer latex |
Also Published As
Publication number | Publication date |
---|---|
MX173522B (en) | 1994-03-11 |
EP0461758A3 (en) | 1992-08-19 |
JPH0672363B2 (en) | 1994-09-14 |
JPH04228682A (en) | 1992-08-18 |
CA2031120A1 (en) | 1991-12-14 |
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