EP0241848B1 - Phosphor und fluoreszente, denselben verwendende Lampe - Google Patents

Phosphor und fluoreszente, denselben verwendende Lampe Download PDF

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Publication number
EP0241848B1
EP0241848B1 EP87105145A EP87105145A EP0241848B1 EP 0241848 B1 EP0241848 B1 EP 0241848B1 EP 87105145 A EP87105145 A EP 87105145A EP 87105145 A EP87105145 A EP 87105145A EP 0241848 B1 EP0241848 B1 EP 0241848B1
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Prior art keywords
phosphor
fluorescent lamp
weight
lamp
emission
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Expired - Lifetime
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EP87105145A
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English (en)
French (fr)
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EP0241848A2 (de
EP0241848A3 (en
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Masahiko C/O Patent Division Yamakawa
Kenji c/o Patent Division Terashima
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Toshiba Corp
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Toshiba Corp
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Priority claimed from JP8618386A external-priority patent/JPH0745656B2/ja
Priority claimed from JP61207672A external-priority patent/JPS6363783A/ja
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Publication of EP0241848A3 publication Critical patent/EP0241848A3/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/7734—Aluminates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H01J61/02—Details
    • H01J61/38—Devices for influencing the colour or wavelength of the light
    • H01J61/42—Devices for influencing the colour or wavelength of the light by transforming the wavelength of the light by luminescence
    • H01J61/44—Devices characterised by the luminescent material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7715—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing cerium
    • C09K11/7716—Chalcogenides
    • C09K11/7718—Chalcogenides with alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7715—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing cerium
    • C09K11/7721—Aluminates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7715—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing cerium
    • C09K11/77212—Silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/7729—Chalcogenides
    • C09K11/7731—Chalcogenides with alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/77342—Silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
    • C09K11/77344—Aluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7743—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing terbium
    • C09K11/7744—Chalcogenides
    • C09K11/7746—Chalcogenides with alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7743—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing terbium
    • C09K11/7749—Aluminates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7743—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing terbium
    • C09K11/77492—Silicates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7783—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
    • C09K11/7784—Chalcogenides
    • C09K11/7787—Oxides

Definitions

  • the present invention relates to a blue-color light-emitting aluminate phosphor and a fluorescent lamp using the same.
  • a recent three-band type fluorescent lamp uses an aluminate phosphor as a blue-color light-emitting component.
  • a europium-activated aluminate phosphor [(Ba,Eu)Mg 2 AI 16 0 27] (Japanese Patent Publication (Kokoku) No. 52-22836) as a known blue phosphor is not satisfactory, since its emission intensity decreases during use.
  • Other europium-activated aluminate phosphors [(Ba,Eu)O•eAl 2 O 3 • fY 2 0 3] (Japanese Patent Disclosure (Kokai) No.
  • the emission colors of the respective phosphors of these types of fluorescent lamp differ greatly. when the emission outputs (emission intensities) of the respective phosphors decrease while the lamp is in use, color deviation occurs, degrading the color rendering properties.
  • Japanese Patent Disclosure (Kokai) No. 57-207678 discloses a fluorescent lamp having a combination of 3(M,Eu) 3 (PO 4 ) 2 •M'Cl 2 or k(M l-o Eu o O)•lP 2 O 5 mM'X 2' nB 2 0s as a blue phosphor, (Re l-p-q-r Tb p -CeqAsr) 2 03 ⁇ SiO 2 • ⁇ P 2 O 5 as a green phosphor, and (Y,E U ) 2 0 3 as a red phosphor.
  • This lamp however, color deviation occurs during use, due to a difference in the degradation rates of the respective phosphors, thus a decrease in the total luminous flux intensity of the lamp is large.
  • the present invention has been developed to solve the above problems, and has as its object to provide a blue-color light-emitting aluminate phosphor which has a high emission output and a low decrease in its emission intensity during use, and a fluorescent lamp using the same.
  • a satisfies O ⁇ a s 3.0 and that x satisfies 0.0006 s x ⁇ 0.0015.
  • Eu can be partially substituted by Mn.
  • the substitution ratio of Mn is twice or less than Eu in molar ratio.
  • coefficient z depends on the total amount of Eu and Mn.
  • the phosphor (Ba w Ca x Mg y Eu z )O•aAl 2 O 3 •bSiO 2 of the present invention can be synthesized as follows:
  • At least one member selected from the barium compound group consisting of barium oxide, barium hydroxide, barium carbonate, and so on can be used as a barium source; at least one member selected from the calcium compound group consisting of calcium oxide, calcium hydroxide, calcium carbonate and so on can be used as a calcium source; at least one member selected from the magnesium compound group consisting of magnesium oxide, magnesium hydroxide, magnesium carbonate, and so on can be used as a magnesium source; at least one member selected from the europium compound group consisting of europium oxide, europium fluoride, and so on can be used as a europium source; at least one member selected from an aluminum compound group consisting of aluminum oxide, aluminum hydroxide, and so on can be used as an aluminum source; and at least one member selected from the silicon compound group consisting of silicon dioxide and so on can be used as a silicon source.
  • Predetermined amounts of the above materials are weighed and mixed thoroughly.
  • the mixture is put in a refractory container and sintered in air at 1,200 to 1,600 ° C for 3 to 4 hours.
  • the obtained sintered product is pulverized and treated by washing with water and so on.
  • the powder obtained by pulverization is dried and put in the refractory container once again, and sintered in a reducing atmosphere at 1,400 to 1,600 ° C for 3 to 4 hours.
  • a blue-color light-emitting aluminate phosphor of the present invention can be obtained.
  • Fig. 1 shows a spectrum distribution of the blue-color light-emitting aluminate phosphor of the present invention. It can be seen from Fig. 1 that the phosphor of the present invention has an emission spectrum of a narrow wavelength range in the vicinity of 450 nm.
  • the fluorescent lamp according to the present invention is obtained by coating, on the inner surface of a glass bulb, a mixture of the blue phosphor (first phosphor); a second phosphor having an emission spectrum in a visible green color range and represented by a general formula Ln 2 O 3 •c(Mg l - u Ca u )O•d[(Al 2 O 3 ) l-v • (Si0 2 )v] (where Ln is at least one element selected from the group consisting of lanthanum, gadolinium, yttrium, cerium, and terbium, and 1.5 ⁇ c ⁇ 5.0, 2.5 ⁇ d s 14.0, 0.001 ⁇ u ⁇ 0.005, and 0.0002 ⁇ v ⁇ 0.0010); and a third phosphor having an emission spectrum in a visible red color range and represented by a general formula (Y l-t Eu t ) 2 O 3 (where 0.020 ⁇ t ⁇ 0.065).
  • the second phosphor is disclosed in Japanese Patent Application No. 61-120208 by the present inventors.
  • Fig. 1 shows the emission spectrum of the blue-color phosphor according to the present invention.
  • the above materials were mixed thoroughly.
  • the obtained mixture was sintered in air at 1.350 ° C for 4 hours.
  • the sintered product was pulverized and washed with water.
  • the powder obtained by pulverization was dried and sintered in a reducing atmosphere at 1.400°C for 4 hours. Finally, the sintered powder was pulverized, washed with water, and dried again to obtain a phosphor.
  • the composition of the obtained phosphor was (Ba 0.449 Ca 0.001 Mg 0.5 Eu 0.05 )0•2.5Al 2 O 3 •0.001SiO 2 .
  • the above materials were treated following the same procedures as in Example 1.
  • the composition of the obtained phosphor was (Ba 0.198 Ca 0.002 Mg 0.7 Eu 0.1 )O• 3.5Al 2 O 3 •0.002SiO 2 .
  • the above materials were treated following the same procedures as in Example 1.
  • the composition of the obtained phosphor was (Ba 0.2 Ca 0.0015 Mg 0.7385 Eu 0.06 )0• 2.0Al 2 O 3 •0.003SiO 2 .
  • Table 1 compares the emission intensities of the phosphors (Examples 1 to 3, Examples 4 to 16, in accordance with the same manufacturing method as in Examples 1 to 3) and conventional blue-color light-emitting aluminum phosphors (Controls 1 and 2), and their respective degradations. It can be seen from Table 1 that a phosphor of the present invention, represented by a general formula (Ba w Ca x MgyEu z )O ⁇ aAl 2 O 3 • bSi0 2 , has higher emission intensities immediately after excitation and after the lamp has been ON for 1,000 hours. It can also be seen that these high emission intensities can be obtained when 2.0 ⁇ a 9 3.0 or 0.0006 9 x ⁇ 0.0015.
  • the total luminous fluxes (emission outputs) after the lamp had been ON for 500 hours were 102% and 112% those of Control 3, respectively.
  • Example 17 has less color deviation and a smaller decrease in its emission output than the lamp according to Control 3.
  • Table 2 shows the results in this case.
  • the fluorescent lamps of the present invention are superior to that of Control 3, in that their color deviation and decrease in emission output are less.
  • Table 3 shows the emission outputs (total luminous fluxes) of fluorescent lamps, obtained by coating the blue, green, and red phosphors of Example 17 on the inner surfaces of different glass bulbs, immediately after manufacture (after the lamps had been ON for 0 hours) and after the lamps had been ON for 500 hours.
  • the rates of degradation in emission output of the respective phosphors of Example 17 are smaller than those of the respective phosphors used in the conventional fluorescent lamp (Control 4), and the rates of degradation in emission output of the respective colors are similar. This illustrates clearly that a decrease in total luminous flux and color deviation of a three-wavelength range fluorescent lamp are small, after the lamp has been is use.
  • Table 4 shows the results obtained when the respective phosphors of Table 3 were removed from the corresponding fluorescent lamps and the reflectances of the lamps were measured.
  • the phosphors of Example 17 have higher reflectances than those of Control 4. This is attributable to the following fact.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Luminescent Compositions (AREA)

Claims (3)

1. Leuchtstoff, gekennzeichnet durch die allgemeine Formel (BawCaxMgyEuz)O•aAl2O3•bSiO2, mit folgenden Beziehungen:
0,1 ≤ w ≤ 0,5,
0,0004 ≤ x ≤ 0,0020,
0,1 ≤ y ≤ 0,8,
0,03 ≤ z 0,10,
w + x + y + z = 1,
1,5 ≤ a ≤ 4,5 und
0,0005 ≤ b ≤ 0,0030.
2. Leuchtstoff nach Anspruch 1, dadurch gekennzeichnet, daß a der Beziehung 2,0 ≤ a ≤ 3,0 oder x der Beziehung 0,0006 ≤ x ≤ 0,0015 genügt.
3. Leuchtstofflampe mit einem Leuchtstoffilm auf einer Innenfläche eines Glaskolbens, dadurch gekennzeichnet, daß der Leuchtstoffilm einen ersten Leuchtstoff mit einem Emissionsspektrum in einem sichtbaren blauen Farbbereich, entsprechend der allgemeinen Formel (BawCaxMgyEuz)O•aAl2O3• bSi02, mit folgenden Beziehungen:
0,1 ≤ w ≤ 0,5,
0,0004 ≤ x ≤ 0,0020,
0,1 ≤ y ≤ 0,8,
0,03 ≤ z ≤ 0,10,
w + x + y + z = 1,
1,5 ≤ a ≤ 4,5 und
0,0005 ≤ b 0,0030;
einen zweiten Leuchtstoff mit einem Emissionsspektrum in einem sichtbaren Grünfarbenbereich, entsprechend der allgemeinen Formel Ln2O3•c(Mg-uCau)O•d[(Al2O3)1-v(SiO2)v], worin Ln für mindestens ein Element aus der Gruppe Lanthan, Gadolinium, Yttrium, Cer und Terbium steht und folgende Beziehungen gelten:
1,5 ≤ c ≤ 5,0,
2,5 ≤ d ≤ 14,0,
0,001 ≤ u ≤ 0,005 und
0,0002 ≤ v ≤ 0,0010; und
einen dritten Leuchtstoff mit einem Emissionsspektrum in einem sichtbaren roten Farbbereich entsprechend der allgemeinen Formel (Y1-tEUt)2O3, worin 0,020 ≤ t ≤ 0,065, enthält, worin der erste, zweite und dritte Leuchtstoff in bezug auf 100 Gew.-% des Gemischs in einer Menge von 0,2 bis 35 Gew.-%, 35 bis 60 Gew.-% bzw. 30 bis 60 Gew.-% vorhanden sind.
EP87105145A 1986-04-16 1987-04-07 Phosphor und fluoreszente, denselben verwendende Lampe Expired - Lifetime EP0241848B1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP8618386A JPH0745656B2 (ja) 1986-04-16 1986-04-16 蛍光体
JP86183/86 1986-04-16
JP207672/86 1986-09-05
JP61207672A JPS6363783A (ja) 1986-09-05 1986-09-05 蛍光ランプ

Publications (3)

Publication Number Publication Date
EP0241848A2 EP0241848A2 (de) 1987-10-21
EP0241848A3 EP0241848A3 (en) 1988-02-10
EP0241848B1 true EP0241848B1 (de) 1990-03-14

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EP87105145A Expired - Lifetime EP0241848B1 (de) 1986-04-16 1987-04-07 Phosphor und fluoreszente, denselben verwendende Lampe

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US (1) US4733126A (de)
EP (1) EP0241848B1 (de)
KR (1) KR900002447B1 (de)
DE (1) DE3761906D1 (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8700876A (nl) * 1987-04-14 1988-11-01 Philips Nv Luminescerend barium-hexa-aluminaat, luminescerend scherm voorzien van een dergelijk aluminaat en lagedrukkwikdampontladingslamp voorzien van een dergelijk scherm.
KR950701374A (ko) * 1993-02-26 1995-03-23 사토 후미오 형광체 및 그것을 사용한 형광램프
KR100432664B1 (ko) * 1996-10-23 2004-08-25 삼성에스디아이 주식회사 청색형광체
US6010644A (en) * 1997-05-09 2000-01-04 Kabushiki Kaisha Ohara Long-lasting phosphor
US5985174A (en) * 1997-09-22 1999-11-16 Samsung Display Devices Fluorescent material used in an active dynamic liquid crystal display device and method for manufacturing the same
US6117362A (en) * 1997-11-07 2000-09-12 University Of Georgia Research Foundation, Inc. Long-persistence blue phosphors
US6045721A (en) * 1997-12-23 2000-04-04 Patent-Treuhand-Gesellschaft Fur Elekrische Gluhlampen Mbh Barium magnesium aluminate phosphor
US6525460B1 (en) 2000-08-30 2003-02-25 General Electric Company Very high color rendition fluorescent lamps
US6452324B1 (en) 2000-08-30 2002-09-17 General Electric Company Fluorescent lamp for grocery lighting
US6953536B2 (en) 2003-02-25 2005-10-11 University Of Georgia Research Foundation, Inc. Long persistent phosphors and persistent energy transfer technique
CN1791702A (zh) * 2003-05-15 2006-06-21 奥斯兰姆施尔凡尼亚公司 通过化学气相沉积封装磷光体的方法
KR20060021308A (ko) * 2003-05-15 2006-03-07 오스람 실바니아 인코포레이티드 화학 증착에 의한 인광물질의 피막 방법
US7535176B2 (en) * 2003-05-15 2009-05-19 Osram Sylvania Inc. VUV-excited device with blue-emitting phosphor
WO2006111568A2 (en) * 2005-04-20 2006-10-26 Etech Ag Novel materials used for emitting light
CN103468256A (zh) * 2013-09-24 2013-12-25 中国科学院长春应用化学研究所 一种适用于紫外光和蓝光激发的白光led用荧光粉及其制备方法
CN108102648B (zh) * 2017-12-25 2020-03-10 广东工业大学 一种颜色可调的长余辉材料及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3577169A (en) * 1968-08-05 1971-05-04 Sylvania Electric Prod Coexisting crystalline solution phases activated by divalent europium
BE789747A (fr) * 1971-10-07 1973-04-05 Philips Nv Ecran luminescent
NL160869C (nl) * 1972-11-03 Philips Nv Luminescerend scherm, alsmede ontladingslamp en katho- de straalbuis, voorzien van een dergelijk scherm.
JPS5310568A (en) * 1976-07-15 1978-01-31 Iwasaki Electric Co Ltd Fluorescent lamp incorporating hig-pressure mercury vapor
NL179215C (nl) * 1977-01-19 1986-08-01 Philips Nv Luminescerend scherm, alsmede lagedrukkwikdampontladingslamp.
US4161457A (en) * 1977-03-15 1979-07-17 Dai Nippon Toryo Co., Ltd. Process for preparing a divalent europium activated alkaline earth metal aluminate phosphor
JPS54124581A (en) * 1978-03-20 1979-09-27 Matsushita Electronics Corp Fluorescent lamp
NL7903102A (nl) * 1979-04-20 1980-10-22 Philips Nv Luminescerende stof met aardalkalimetaalsilikaat- aluminaatgrondrooster.
NL8105739A (nl) * 1981-12-21 1983-07-18 Philips Nv Luminescerend scherm.

Also Published As

Publication number Publication date
DE3761906D1 (de) 1990-04-19
EP0241848A2 (de) 1987-10-21
US4733126A (en) 1988-03-22
KR870010606A (ko) 1987-11-30
KR900002447B1 (ko) 1990-04-14
EP0241848A3 (en) 1988-02-10

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