EP0199729A1 - Wiederverwendbare verschlüsse und deren herstellung sowie diese verwendende verpackungen - Google Patents

Wiederverwendbare verschlüsse und deren herstellung sowie diese verwendende verpackungen

Info

Publication number
EP0199729A1
EP0199729A1 EP85900940A EP85900940A EP0199729A1 EP 0199729 A1 EP0199729 A1 EP 0199729A1 EP 85900940 A EP85900940 A EP 85900940A EP 85900940 A EP85900940 A EP 85900940A EP 0199729 A1 EP0199729 A1 EP 0199729A1
Authority
EP
European Patent Office
Prior art keywords
closure
ears
leg portions
hinge line
locking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85900940A
Other languages
English (en)
French (fr)
Inventor
Christine C. Brown
Dennis G. Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP0199729A1 publication Critical patent/EP0199729A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00Details of, or accessories for, sacks or bags
    • B65D33/16End- or aperture-closing arrangements or devices
    • B65D33/1658Elements for flattening or folding the mouth portion
    • B65D33/1675Hinged clips
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/80Packaging reuse or recycling, e.g. of multilayer packaging

Definitions

  • the present invention relates to reusable closures suitable for sealing bags or other open ⁇ ings, for holding sheets of pliable material to ⁇ gether, and for other such purposes.
  • the invention further relates to methods of manufacturing such closures, and to packaging systems using such clo- sures.
  • a further secondary object of this invention is to provide reusable closures which can be easily used in a packaging and storage system when a plurality of different types of merchandise must be stored in a series of sealed bags, and identified easily such as by color coding.
  • a further object is to provide closures which can be used to seal large pieces of covering mater- ials together, such as plastic sheets, to protect large objects from moisture and dirt.
  • an elongate closure is provided of the type comprising a member molded from plastics material such that a reduced thickness continuous live hinge line is formed along its length, with leg portions defined on opposite sides of the live hinge line whi-ch are movable towards and away from each other about the live hinge line.
  • Each leg portion has an upstanding ear extending along its length, and the areas join- ing the leg portions and ears are rounded.
  • the ears have interengageable locking portions at their free edges which are adapted to releasably snap into locking engagement when the legs are urged together into an A-shaped locking position.
  • One of the lock- ing portions has a slanted flat face and the other locking portion has a rounded face positioned so as to initially engage the slanted flat face when the leg portions are urged towards each other and to slide over the flat face into the locking position.
  • the plastics material is one that has "memory". In other words, the material is such that the ears and locking portions repeatedly return to their initial shape and orientation after locking and releasing actions. The material must therefore not be too flexible, but on the other hand must not be too hard so that there is an increased risk of the locking portions or ears snapping or tearing.
  • One suitable plastics material for this purpose is a copoly er of more than 85 percent polypropylene and the rest polyethylene.
  • Another suitable mater ⁇ ial is a mixture of more than 85 percent copolymer and the rest rubber.
  • the copolymer used contains 1 to 2 percent polyethylene and 99 to 98 percent polypropylene.
  • the copolymer is preferably mixed with an anti-static material so that the closure is anti-static.
  • the closure can be designed with suitable di - ensions for sealing bags of any size, thickness, or material, or for larger scale uses in sealing cover sheets protecting objects from the environment, such as construction areas, aeroplanes, missiles, or vehicles of any type.
  • a suitable length of reusable closure can be used to seal overlapping edges of cover sheets together.
  • 'It may also be used as a holder for sheets of any pliable material such as mylar or poly-plastics sheets.
  • One such use would be to provide a shroud to protect a rocket or jet engine during the manufacturing pro ⁇ cess to form an environmentally controlled shelter.
  • the closure permits convenient cover ⁇ ing of test equipment, air systems, and other equip ⁇ ment in a clean room environment.
  • the ears are arranged to curve arcuately towards each other in the released posi ⁇ tion of the closure. This reduces the stresses on the ears during repeated locking and releasing actions, and produces a closure with a longer effec- tive lifetime, typically several thousand repeated lockings and releases.
  • the closure may be provided with suitable hanger means for hanging the closure and a sealed bag on a suitable support (e.g., a hook, wire or bar).
  • a suitable support e.g., a hook, wire or bar.
  • a plurality of bags sealed with the closures can be hung in easily accessible and visible positions. This is useful whenever storage space is limited, such as in camping or travelling. It is also useful in industrial or commercial store rooms, when large quantities of merchandise must be stored in an easily accessible fashion.
  • closures may be provided as a storage system in a plurality of different colors..
  • such closures could be used in a continuous track or conveyor type inventory control . system, such as the conveyor type systems typically encountered at clothes cleaning establishments.
  • Different color closures may be used to color code different elec ⁇ tronic components, and then hung in easily visible positions so that items can be retrieved when neces ⁇ sary.
  • the closures can be labelled and relabelled for inventory control by writing on the outer faces of the leg portions.
  • the closure of this invention can be made in one piece by extrusion or injection molding.
  • a method of making such a closure comprises the steps of: mixing a. copolymer of polypropylene and polyethylene with an anti-static material, heating and melting the mixture; extruding the melted mixture through a die to form the closure shape of a substantially flat elongate part with a reduced thickness line extend- ing . along its length to form a live hinge line and upstanding interengageable locking portions extend ⁇ ing along its length of closure to its setting point by passing it through after forming means and into a cooling bath; and cutting the closure to the desired size.
  • the closure is urged into its A-shaped locking • position before cutting it to size. This gives a longer life to the live hinge since it is flexed before the molecular structure sets in. It is also easier to pack and ship the closures in their closed position.
  • the length of closure may be passed through a second cooling bath before being cut to size.
  • the length of closure may be passed with its locking portions upwards in the first cooling bath, and then be twisted so that the locking portions face downwards in the second cooling bath.
  • the closure may alternatively be formed by injection molding.
  • the- copolymer is mixed with anti-static material, melted, and injected into a mold ' having an internal shape to form the closure.
  • the mixture is directed to flow trans- versely across the live hinge, rather than along the live hinge axis. The mixture is then cooled to its setting point and the formed closure ejected from the mold.
  • closure of this invention may be manufactured within fairly close tolerances. It may be used in a storage system, and has a relatively long lifetime over repeated uses ' .
  • Figure 1 shows a perspective view of a reusable closure according to the invention in its closed or locking position
  • Figure 2 is an end view of the closure of Figure 1 in its released position, on an enlarged scale
  • Figure 3 shows an end view of the closure of Figure 2 in its closed position sealing the open end of a bag and also showing a hanger tab;
  • Figure 4 shows a perspective view of a modi ⁇ fied closure according to the invention.
  • Figure 5 is a flow chart showing schematically a method of making closures according to the inven ⁇ tion.
  • FIG. 6 is a flow chart showing schematically an alternative method of making closures according to the invention. Description of the Preferred Embodiment
  • Figures 1 to 3 show a reusable closure 1 according to a preferred embodiment of the present invention.
  • the closure 1 comprises a one-piece elongate member molded from a plastic material.
  • the member is formed with a reduced thickness live hinge line
  • leg por ⁇ tions 3 and 4 are movable towards and away from each other about the live hinge line 2 between the A-shaped locking position shown in Figures 1 and 7. and the released position shown in Figure 2.
  • Each leg portion 3, 4 has an upstanding ear 5,
  • each ear joins its respective leg portion are rounded to reduce the risk of the ears snapping or tearing off.
  • the rounding in these areas reduces the stresses during locking and releasing actions. Furthermore, such rounding adds to the strength, as opposed to sharp corners.
  • the lip 7 has a rounded face
  • the open end 13 is first posi ⁇ tioned between the ears 5 and 6 with the closure in a released position. Depending on the desired use, the open end 13 can be folded over before being positioned to ensure an even tighter seal.
  • the leg portions 3 and 4 are then urged towards each other into a A-shape.
  • the rounded face 11 of the lip 7 will engage the slanted flat face 12 of the lip 8 through the . bag material, and will slide over this face 12 to snap into the locking position shown in Figu e 3.
  • the open end 13 of the bag is then clamped firmly between the ears 5 and ⁇ .
  • the slanted flat face provides a sliding surface to aid in the locking action.
  • the leg portions 3 and 4 are urged apart until the locking portions snap out of engagement.
  • the leg portions 3 and 4 can be urged apart- by gripping the ends thereof and pulling them apart.
  • closure 1 may be pro ⁇ vided with a bag already attached.
  • the open end of the bag is attached or bonded along one side to the inside edge of leg 3 imme ⁇ diately above ear 5.
  • the closure may be used for sealing bags of any material, for example plastics, mylar, paper, cloth, and so on. It may be provided in any desired length, and may be designed with proportions suit ⁇ able -for holding or sealing any thickness of pli ⁇ able material. It may also be used, for example, to hold together overlapping edges of cover sheets, such as mylar or the like, used to protect construc ⁇ tion site areas, vehicles, large items during trans ⁇ portation, and so on.
  • Figure 4 shows a modification in which the closure is provided with a hanger tab 15 having an opening 16 for hanging the closure on a suitable support.
  • Any size hook may be utilized in the opening 16, which allows the closure to be adapted for uses where it needs to hang.
  • a hookshaped hanger may alternatively be provided.
  • the hanger tab allows bags sealed by the closure to be easily and accessibly stored. This is useful both in stor ⁇ age areas where a large number of different articles or components must be stored, and also in cases where storage space is limited, for example when camping, when travelling in boats, planes or cars, or in other domestic uses.
  • a simple storage system can be provided when such closures are supplied in a variety of dif ⁇ ferent colors. Different color closures can be used for color coding different inventory components or types of merchandise, and bags sealed by the clo ⁇ sures can be hung in easily accessible and visible positions for ready location and retrieval when needed. This is especially useful in a continuous track type inventory retrieval system.
  • the leg portions 3 and 4 of the closure have substantially flat- portions on their outer surfaces where information 17 can be stamped, imprinted, or written by hand.
  • a closure can be written on to identify articles stored in a bag sealed by the closure, and the writing can be wiped off or erased and -replaced if the closure is subsequently used to seal a bag containing different articles. Iii addi ⁇ tion, one may also affix identifying labels to the flat portions.
  • the relative proportions and * orientations of the leg portions 3 and 4, ears 5 and 6 and locking lips 7 and 8 are arranged to provide a good locking action and to reduce the risk of tearing or breaking of the closure under repeated locking actions.
  • the ' locking action also provides a tight enough seal to permit storing liquids without leakage at the seal. This is especially useful in many , medical related uses, such as storing and freezing plasma, blood, medications, and the like.
  • the actual dimensions used will depend on the application for which the closure is to be used, i.e. smaller scale for sealing bags of relatively thin mil material, larger scale for sealing thicker mil material bags or holding several sheets of material.
  • the leg portion 4 is wider than the leg portion 3 since its ear 6 must engage beneath the ear 5 in the locking position.
  • the leg portions 3 and 4 are of varying thickness. They are of in ⁇ creased, thickness in the areas 18, 19 adjacent the ears 5 and 6, to reduce stresses in these areas, and of reduced thickness at their outer edges 20, 21 and adjacent the live hinge line 2, where the stresses are less, in order to save material.
  • the leg portions are of taper ⁇ ing thickness between the ears and the live hinge line.
  • the ears 5 and 6 are positioned about two thirds of the way between the live hinge line 2 and the outer edge 20, 21 of their respective leg portions 3 and 4. Thus ear 5 is closer to the live hinge line than ear 6. The relative positioning of the ears depends on the thickness of the material to be held between them.
  • the ears curve arcuately towards each other at angles less than 90° to the leg portions. This also helps to reduce stress, particularly in large scale uses.
  • the radius of curvature of the ear 5 is slightly less than that of the ear 6.
  • the thickness of the ears is about the same as that of the leg portions in the areas 18 and 19.
  • each lip 7 and 8 and the adjacent leg portion 3 and 4 is about 35 percent of the width of the respective leg portion 3, 4.
  • the ear 6 is slightly longer and slightly thicker than the ear 5.
  • the lips 7 and 8 are approximately twice as thick as the ears 5 and 6.
  • the lip 7 has rounded locking face 11, and the lip 8 has rounded or arcuate faces 22 separated by the slanted flat face 12 which aids in the locking action.
  • the faces 22 have about the same radius of curvature as the face
  • legs are tapered toward the live hinge line, as shown in Figure 2.
  • Thickness along live hinge line 0.020 inches; Distance between live hinge line and ear 5 * 0.495 inches; Distance between live hinge line and ear 6 » 0.640 inches.
  • a desirable material for such a closure is a copolymer of between 85 and 99 percent polypropylene and between 15 and 1 per ⁇ cent polythethylene.
  • the copolymer used may be 1 to 2 percent polyethylene and 99 to 98 percent polypropylene. This provides a closure with more memory and thus an improved and long lasting locking action.
  • Another embodiment utilizes rubber material which increases resiliency, and elasticity.
  • Mixing rubber in the proportions of 15 to 5 percent rubber and the remainder as a copolymer is a suitable mixture. Preferred ranges include 15 to 5 percent rubber and 85 to 95 percent polypropylene. Another mixture would be approximately 15 to 5 percent rubber, 83 to 93 percent polypropylene, and approx- imatley 2 percent polyethylene, respectively.
  • Other suitable materials which exhibit improved elastic qualities, yet retain the other repeatability ⁇ hara- cteristics include using 100 percent K-styrine.
  • the copolymer is preferably mixed with an anti-static material to prevent build-up of static charges when the closure is used to seal plastic bags.
  • the anti-static material is suitably a mono or diglyceride emulsifier, such as gyceryl mono- stearate. The mixture may contain up to 5 percent by weight of the anti-static material.
  • an ultra violet inhibitor may be added to the mixture to preserve the material and protect it from sunlight.
  • suitable dye materials may be polyethylene or polypropylene, and the mixture suitable contains 1 percent by weight of coloring agent.
  • Closures of this type can be used in many areas for sealing bags or holding sheets of material together. They can be used for packaging, storage, and/or transportation of a large variety of merchandise, large or small scale, with suitable choice of closure dimensions. This would include shrouding of many aerospace parts. They are suit- able for home, industrial or commercial use, and can provide a system of packaging a large variety of different components, e.g. electrical compon ⁇ ents, for storage and easy retrieval. The closures have been carefully designed with relative propor- tions and suitable materials such that they can be reused many times and still retain their locking capabilities.
  • Figure 5 shows a method of manufacturing lengths of the- closure of Figures 1 to 4 by an extrusion process.
  • anti-static material which may be in powder or flake form (typically Emery #6003, Atumal 84 powder Atumal 84K large flake, or Atmos #150 fine powder).
  • the powder form has been preferred as it mixes more easily with the material. Any desired coloring agent or ultraviolet inhibitor is also mixed in at this stage, unless it is pre- ixed.
  • the mixture is then introduced to a machine 30, where it is heated to its melting point of about 380°F.
  • the melted material is extruded through a tool die 31 which has a shape slightly larger to allow for shrinkage and corresponding to the desired shape of the closure in its flat config- uration shown in Figure 2.
  • the tool die is larger because when the material is being extruded, it is pulled and stretched to the proper size as it passes into the after-forming mechanism.
  • the extruded length of closure 32 is then passed through a first after-forming die 33, typi ⁇ cally in the form of a plate, with its ears' upper ⁇ most.
  • the after forming die is positioned in a first cooling bath 34.
  • the length of closure is com ⁇ pletely submerged in water in the cooling bath, and is passed along a further after-forming device 33 in the open water bath which ensures that the ears and locking portions maintain their correct orien ⁇ tations relative to the leg portions. This is done to help relieve the lengthwise bow in the material.
  • the length of closure is then twisted around in the next stage 35 so that the ears face down ⁇ wards. This is done to further relieve any bow.
  • the length of closure then passes through a suitable cutting device where it is cut to the desired closure lengths 38. It is desirable to close, or snap-lock, the length of closure before cutting to size since this has been found to produce a longer lasting live hinge.
  • the cut lengths of closure will also be- ready for packaging and shipping, since they must be packaged in the locked position. Essentially, when the closure is urged into its A-shape immediately after the extrusion process, the molecular structure along the live hinge line will not yet have set in. If it is closed for at least 48 hours before the first use, a substantially stronger live hinge and better lock is provided.
  • the closure may be reheated before being cut
  • ⁇ to size and it may also be heated in the stage 35 before it is passed into the second water bath 36.
  • the cooling baths 34 and 36 are open, moving water baths.
  • the second water bath 36 is included, in the process for final cooling and has the advantage of producing closer tolerances.
  • the length of closure may be extruded with a projecting length of hanger tab.
  • excess material on either side is shaved off to form a hanger tab 15 as shown in Figure 4, and the hole or opening 16 is punched out.
  • a further step in the process may be provided for stamping or imprinting a name or other infor a- tion on an outer face of the closure.
  • a wheel having raised figures may be used to stamp a name repeatedly onto formed lengths of closure immediately subsequent to after-forming step.
  • the material should be heat treated, such as by exposure to open flame, prior thereto.
  • a heat stamp may be used.
  • the steps are simi ⁇ lar, in that they include a machine 30, a tool die 31, and closure 32 extruded to the desired shape. Extended length of closure 32 passes into a first after-forming die plate 33A. This die is the exact size of the final extruded closure.
  • the closure 32 next passes into a cold die 33B prefer ⁇ ably one to two feet long, in lieu of the after-forming device 33 and the open water bath 35 of Fig ⁇ ure 5.
  • the cold die 33B is the exact size and form needed, as is the after-forming die 33A.
  • the closure stays the same shape as it cools for the length of the cold die.
  • the die preferably has holes located in it to permit a vacuum for retaining the closure, and channels for circulating cooling water or air within the die. Alternatively, the entire cold die is submerged in water. This cold die step forms a crust or skin on the closure so the closure accurately retains, its shape. By using such a long cold die, no other after-forming, or twisting, of the closure is required.
  • stage 39A ma y be included, as shown in Figure 6, for imprinting or stamping identifying information on the closure.
  • the closure'-' may alternatively be formed by injection molding, when the molten mixture des- cribed above is injected into a mold instead of being extruded through a die.
  • the mold is prefer ⁇ ably a slide mold if there is a tab or need not be if there is no tab,, since the shape of the lips on the ears would make removal of the upper half of a normal mold impractical.
  • the mixture is directed to flow transversely across the live hinge, rather than along the live hinge axis. This results in a stronger hinge than by extension.
  • This mixture is then cooled to its setting point and the formed closure is ejected from the mold. Closing the closure afterwards give longer life to the live hinge.
  • a higher proportion of anti-static material may be used when the closure is formed by injection molding. In the extrusion process too much of this material creates a surge problem.
  • a hanger tab as shown in Figure 4 may be formed integrally with the closure in an injection molding process.
  • a copolymer of high impact polypropylene #PP1454A (typically 95-99 percent polypropylene and 1-5 percent polyethylene) was used. This material is made by El Paso Gas and has a melt flow of 4.0 mils and a Rockwell hardness of R55 Virgin material (no re-grind) was used.
  • the range of useful melt flows for the above- described processes is from 2 to 6 mils, with a higher melt flow being necessary for the injection molding process where the melted material must be injected at a much faster rate. Injection molding gives tolerances in the closure dimensions up to thousandths of an inch.
  • a name plate may be provided in the mold itself, so that the closures are formed with a name stamped on the outer face of one or both legs.
  • the name plate is preferably replaceable so that other names or words can be formed on the closures when desired.
  • the closure formed as described above by extru ⁇ sion or injection molding will maintain its anti ⁇ static properties throughout its lifetime, unlike closures which simply are dipped in anti-static material or have a spray-on anti-static coating.
  • the anti-static material becomes part of the mole ⁇ cular structure and is found to migrate to the sur ⁇ face of the closure during use. The anti-static material always replenishes itself when the surface area becomes depleted, so a long lasting anti ⁇ static effect is achieved.
  • the methods described above overcome many of the problems inherent in making closures of the type described.
  • the snap lock closures must be formed within close tolerances if an effective lock is to be achieved, and the choice of materials is critical to provide the right degree of memory while not making the closure either too brittle or too soft to withstand long-term use.
  • a long last ⁇ ing and repeatedly usable snap lock closure is provided, which can be designed to have anti-static properties which are maintained over the whole life ⁇ time of the closure.
  • a process for making such a closure within close tolerances is also provided.
  • another aspect of the invention pro ⁇ vides a method of packaging a variety of merchan ⁇ dise, such as foodstuffs, electronic components, aerospace products, ' entire homes, machinery, medical supplies, or any articles to be stored either domestically or industrially.
  • This closure is also easily adapted for use in environmentally controlled areas, as in space travel, where it is necessary to provide protection against cosmic dust such as during repair of orbiting satellites in which plastic material sheets, e.g. Mylar, can be sealed around a capsule, or used to form a closed shelter with the sheets to provide a sealed work area.
  • plastic material sheets e.g. Mylar
  • the closures may be attached to bags for storing merchandise, and hanger tabs are provided on the closures for hanging up the sealed merchandise in an easily visible and accessible position. Also, the closures can be of assistance in the medical field for freezing sterilized medical instruments and medications in moisture and air-tight containers.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Package Frames And Binding Bands (AREA)
EP85900940A 1984-10-31 1984-10-31 Wiederverwendbare verschlüsse und deren herstellung sowie diese verwendende verpackungen Withdrawn EP0199729A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1984/001779 WO1986002618A1 (en) 1984-10-31 1984-10-31 Reusable closures and their manufacture, and packaging systems using such closures

Publications (1)

Publication Number Publication Date
EP0199729A1 true EP0199729A1 (de) 1986-11-05

Family

ID=22182317

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85900940A Withdrawn EP0199729A1 (de) 1984-10-31 1984-10-31 Wiederverwendbare verschlüsse und deren herstellung sowie diese verwendende verpackungen

Country Status (2)

Country Link
EP (1) EP0199729A1 (de)
WO (1) WO1986002618A1 (de)

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Publication number Priority date Publication date Assignee Title
DK153013C (da) * 1985-08-20 1988-10-31 Ice Pack Service Ag Lukkeklemme til poser
CH675869A5 (de) * 1988-08-30 1990-11-15 Arnold Zimmermann
US5152034A (en) * 1990-10-19 1992-10-06 Konings Frederikus J J Click-clip
DE19505359A1 (de) * 1995-02-17 1996-09-05 Poly Clip System Gmbh & Co Kg Verschluß-Clip
ES2523867T3 (es) 2010-04-09 2014-12-02 Poly-Clip System Gmbh & Co. Kg Presilla de cierre y matriz para cerrar dicha presilla
DE202011106293U1 (de) * 2011-09-30 2013-01-07 Poly-Clip System Gmbh & Co. Kg Verschlussclip mit mehreren Dornen

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US3223695A (en) * 1961-11-06 1965-12-14 Phillips Petroleum Co Monoolefin polymers destaticized with alkyl polyamines
US3354138A (en) * 1963-11-22 1967-11-21 Phillips Petroleum Co Production of antistatic polymers
US3425981A (en) * 1965-02-12 1969-02-04 Union Carbide Corp Olefin polymer compositions containing ethylene oxide polymers having a molecular weight of from 100,000 to 10 million
US3535746A (en) * 1966-11-07 1970-10-27 Stanley E Thomas Jr Reusable bag fastener
US3621539A (en) * 1970-02-27 1971-11-23 Variform Plastics Inc Bag sealer
US4001366A (en) * 1972-01-03 1977-01-04 Ingrip Fasteners Inc. Method for making self-gripping devices having integral trains of gripping elements
US3818553A (en) * 1973-08-17 1974-06-25 R Parmenter Bag closure
US3993726A (en) * 1974-01-16 1976-11-23 Hercules Incorporated Methods of making continuous length reinforced plastic articles
US4037295A (en) * 1976-02-09 1977-07-26 Rojahn Fred H Slide fastener stringer
DE2960381D1 (en) * 1978-03-15 1981-09-03 Ici Plc Antistatic films
US4329191A (en) * 1978-07-05 1982-05-11 Datafile Limited System for alphabetically labelling articles
IL62066A (en) * 1981-02-04 1984-10-31 Rami Bar Polymeric films for agricultural use
US4380103A (en) * 1981-07-21 1983-04-19 Mcgrath John E Balloon clip

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Title
See references of WO8602618A1 *

Also Published As

Publication number Publication date
WO1986002618A1 (en) 1986-05-09

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