EP0179775B1 - Materiau en ceramique leger pour construction, procede pour sa fabrication ainsi que son utilisation - Google Patents
Materiau en ceramique leger pour construction, procede pour sa fabrication ainsi que son utilisation Download PDFInfo
- Publication number
- EP0179775B1 EP0179775B1 EP85900974A EP85900974A EP0179775B1 EP 0179775 B1 EP0179775 B1 EP 0179775B1 EP 85900974 A EP85900974 A EP 85900974A EP 85900974 A EP85900974 A EP 85900974A EP 0179775 B1 EP0179775 B1 EP 0179775B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- clay
- weight
- process according
- temperature
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 8
- 239000000463 material Substances 0.000 title abstract description 14
- 238000004519 manufacturing process Methods 0.000 title description 11
- 239000004927 clay Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000006260 foam Substances 0.000 claims abstract description 11
- 239000004566 building material Substances 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 6
- 239000004568 cement Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 125000000129 anionic group Chemical group 0.000 claims abstract 2
- 229910052570 clay Inorganic materials 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 229910001868 water Inorganic materials 0.000 claims description 7
- 238000005187 foaming Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- 230000009974 thixotropic effect Effects 0.000 claims description 4
- 239000011449 brick Substances 0.000 claims description 3
- 239000011810 insulating material Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 229910021532 Calcite Inorganic materials 0.000 claims 1
- 239000006004 Quartz sand Substances 0.000 claims 1
- 239000003945 anionic surfactant Substances 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 claims 1
- 239000003245 coal Substances 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 abstract description 7
- 238000010304 firing Methods 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000010276 construction Methods 0.000 description 6
- 238000009413 insulation Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000004567 concrete Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229910052572 stoneware Inorganic materials 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004132 Calcium polyphosphate Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 235000019827 calcium polyphosphate Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- XJKVPKYVPCWHFO-UHFFFAOYSA-N silicon;hydrate Chemical compound O.[Si] XJKVPKYVPCWHFO-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
- C04B18/027—Lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00112—Mixtures characterised by specific pH values
Definitions
- the invention relates to a method for producing a porous light ceramic material for building purposes according to the introductory part of claim 1 and its use.
- porous lightweight materials such as are known for example from EP-A-0 007 585, have satisfactory strength and other properties important for construction purposes, such as low weight, but are too expensive to manufacture for numerous applications.
- a process of the type mentioned at the outset is known from US Pat. No. 4,424,280, in which a slip consisting of clay, foaming agent and other additives is foamed, dried and fired, the viscosity being controlled by the addition of methyl cellulose , however, the material that can be produced when used for construction purposes does not have fully satisfactory product properties, in particular with regard to porosity and mechanical stability.
- FR-A 2 190 753 a method for foaming an aqueous mixture of clay materials, binders and surfactants by means of compressed air in an open system, i.e. without pressure, is known, but the material that can be produced thereafter does not have satisfactory product properties with regard to heat and / or sound insulation and Has fire resistance.
- FR-A-2 088 455 in which an already prefabricated foam mixture is admixed to a clay mixture, satisfactory porosity, density and strength properties cannot be achieved either.
- the invention is therefore based on the object of developing the method mentioned at the outset such that a porous light ceramic material can be produced which can be used both as a light aggregate and for the production of moldings, bricks, in particular also for heat and / or sound insulation purposes and for refractory construction purposes suitable and with simple starting materials in an inexpensive process to lead to pressure-resistant, lightweight moldings, the products produced thereafter should have improved porosity and mechanical properties.
- the invention also relates to the use of the material produced by the process according to the invention in solid and / or granulate form as a heat and / or sound-insulating material for building purposes, but also as an additive for high-temperature building materials, such as furnace building materials, refractory building materials or the like.
- a hydraulic binder such as cement.
- Simple clay and marl can be used as clay, but also Westerwald stoneware clay, porcelain stoneware clay, kaolin, montmorillonite or concrete. It is particularly economical that in the process according to the invention, after drying, unsatisfactory moldings or - in the case of granule production - fine clay foam granulate particles which are eliminated in the screening process can be returned directly to the starting mixture without further treatment, since they are only dried and not are burned and are therefore still fully reactive.
- the process according to the invention usually proceeds in such a way that clay is mixed with water and plasticizer with the addition of surfactant to form a low-water, thixotropic suspension. Then the foaming takes place in a dispersion system with the addition of compressed air.
- Conventional dispersing systems such as those sold under the trade name “Hansa Mixer” by the company Hansawerke Lürman, Scdazzling & Co., Bremen, can be used, which add defined amounts of compressed air under pressure (1 to 10 bar).
- the dispersion system has a further fine metering pump, by means of which liquid can be added before and, if necessary, during the foaming process.
- a substance which counteracts the liquefaction action of the liquefying agent is advantageously used, for example dilute hydrochloric acid, which makes it possible to produce highly viscous, thixotropic, inherently stable foam suspensions.
- the inherently stable, thixotropic foam suspension is then dried, the water vapor being able to escape unhindered through the pores due to the high inherent porosity of the material. It is particularly beneficial if the starting material mixture has a relatively low water content.
- the dried material is usually placed in strands of about 1 cm in diameter, it being possible, for example, to work at temperatures of 200 ° C. with drying times of no more than 5 minutes. This dried mate rial is crushed into granules before firing.
- the amount of the other additives for example in the production of refractory building materials, is set appropriately, that is to say the addition of alumina, magnesite, quartz and the like, as required by the respective application in this case.
- the invention is based on the surprising finding that it is possible to produce a product with properties of the type specified above which are significantly improved over the prior art by foaming in a closed system under pressure by means of a defined compressed air supply, which results in the desirable porosity and mechanical properties Properties.
- a process similar to that according to the invention, directed to the production of a porous adsorbing material, is the subject of EP-B-0 182 793 of the same priority.
- the drawing which consists of a single figure, shows a flow diagram of the method according to the invention.
- Such plates or shaped stones can be used as a replacement for glass fiber wool, asbestos fibers or rock wool or rigid foam based on polystyrene for thermal insulation as an insulating material, but also as cladding panels and for light partition walls if a low density is required due to the inadequate resilience of the substrate.
- a liquefier for example, water glass, calcium polyphosphate, sodium polyphosphate, phosphoric acid, chlorides or sulfates can be used in the process according to the invention.
- Cement can preferably be added as the hydraulic binder in order to achieve a higher raw strength.
- granules are expedient which can be obtained by the process according to the invention in that the dried moldings are passed through a crusher to a screening plant which retains a preferred particle size range and discards fines, which can then be returned to the mixer, as can be seen from the drawing.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85900974T ATE43826T1 (de) | 1984-04-19 | 1985-02-09 | Leichtkeramikmaterial fuer bauzwecke, verfahren zu seiner herstellung sowie seine verwendung. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3414967A DE3414967C2 (de) | 1984-04-19 | 1984-04-19 | Verfahren zum Herstellen eines Leichtkeramikmaterials für Bauzwecke und Verwendung dieses Materials |
DE3414967 | 1984-04-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0179775A1 EP0179775A1 (fr) | 1986-05-07 |
EP0179775B1 true EP0179775B1 (fr) | 1989-06-07 |
Family
ID=6234088
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85900974A Expired EP0179775B1 (fr) | 1984-04-19 | 1985-02-09 | Materiau en ceramique leger pour construction, procede pour sa fabrication ainsi que son utilisation |
Country Status (6)
Country | Link |
---|---|
US (2) | US4824811A (fr) |
EP (1) | EP0179775B1 (fr) |
JP (1) | JPS61501908A (fr) |
AU (1) | AU571654B2 (fr) |
DE (2) | DE3414967C2 (fr) |
WO (1) | WO1985004861A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4442810A1 (de) * | 1994-12-01 | 1996-06-05 | Cerasiv Gmbh | Granulat zur Herstellung hochporöser Formkörper |
Families Citing this family (74)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3744732A1 (de) * | 1987-02-19 | 1989-01-05 | Effem Gmbh | Pflanzensubstrat |
EP0288071B1 (fr) * | 1987-04-24 | 1992-07-08 | Arturo Broggini | Pierres artificielles et leur procédé de fabrication |
DE4011255C1 (fr) * | 1990-04-05 | 1991-06-20 | Effem Gmbh, 2810 Verden, De | |
DE4315088A1 (de) * | 1993-05-06 | 1994-11-10 | Wacker Chemie Gmbh | Verfahren zur Herstellung eines mikroporösen Körpers mit wärmedämmenden Eigenschaften |
US5852077A (en) * | 1995-01-03 | 1998-12-22 | Composite Industries Of America, Inc. | Lightweight, waterproof, insulating, cementitious compositions and methods for forming and using such compositions |
US5782970A (en) * | 1995-01-03 | 1998-07-21 | Composite Industries Of America, Inc. | Lightweight, waterproof, insulating, cementitious composition |
GB9519419D0 (en) * | 1995-09-22 | 1995-11-22 | Ecc Int Ltd | Particulate materials |
US6264734B1 (en) | 1997-03-20 | 2001-07-24 | Radva Corporation | Method for forming insulated products and building products formed in accordance therewith |
US5749960A (en) * | 1997-03-20 | 1998-05-12 | Radva Corporation | Formulation for producing heat insulating material and method for producing the same |
US7045476B1 (en) * | 2000-06-22 | 2006-05-16 | Thomas Joseph Lally | Aerated refractory, method for producing high-temperature structural members |
US20050084514A1 (en) * | 2000-11-06 | 2005-04-21 | Afmedica, Inc. | Combination drug therapy for reducing scar tissue formation |
DE10300043B4 (de) * | 2002-02-15 | 2011-12-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung geformter und gebrannter Bauelemente aus Schaumton |
RU2197423C1 (ru) * | 2002-02-19 | 2003-01-27 | Общество с ограниченной ответственностью "Ярси" | Способ получения алюмосиликатного пористого материала |
US6872677B2 (en) * | 2002-10-02 | 2005-03-29 | Oil Dri Corporation | Brick additives and methods for using same |
US20040217505A1 (en) * | 2003-04-30 | 2004-11-04 | Gurbaksh Singh | Apparatus and method for production of synthetic lightweight aggregate. |
KR100763751B1 (ko) | 2006-11-08 | 2007-10-04 | 이봉재 | 건축외장용 세라믹 박판 및 그 제조방법 |
DE102007027214A1 (de) * | 2007-06-13 | 2008-12-18 | Poegel, Hans Joachim, Dr. | Wärmedämmung |
PL2674409T3 (pl) | 2011-02-08 | 2020-04-30 | Ceilook, Sl | Kompozycja ceramiczna |
RU2481283C1 (ru) * | 2011-12-29 | 2013-05-10 | Юлия Алексеевна Щепочкина | Шихта для производства пористого заполнителя |
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EP3100993B1 (fr) | 2014-01-28 | 2020-01-08 | Ceilook, SL | Composition céramique à faible densité, utilisation du produit obtenu à partir de celle-ci |
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DE583301C (de) * | 1931-04-30 | 1933-09-01 | Aage Nielsen | Verfahren zur Herstellung von poroesen Tonwaren |
US1998686A (en) * | 1933-09-09 | 1935-04-23 | United States Gypsum Co | Process of producing cellular ceramic products |
FR825108A (fr) * | 1936-08-03 | 1938-02-24 | Brique poreuse en argile et son procédé de fabrication | |
FR832763A (fr) * | 1937-02-08 | 1938-10-03 | Procédé nouveau de fabrication de matières isolantes cuites à haute température | |
US2543987A (en) * | 1947-08-23 | 1951-03-06 | Stark Ceramics Inc | Method of producing porous, lightweight, burned argillaceous material |
FR2088455A1 (en) * | 1970-05-08 | 1972-01-07 | Krause Heinz | Porous granules and shaped articles from mineral powders |
DE2022419A1 (de) * | 1970-05-08 | 1971-11-25 | Krause Heinz Josef | Verfahren zur Herstellung von geblaehten,gebrannten Granulaten oder Formkoerpern aus staubfoermigen mineralischen Stoffen,insbesondere Gesteinsmehl,z.B.Tonstaub |
FR2190753A1 (en) * | 1972-06-27 | 1974-02-01 | Rouanet Henri | Porous aggregate from clay - by kneading clay with water and surfactant, blowing in air, drying, crushing and firing |
ZA742247B (en) * | 1974-04-08 | 1975-11-26 | Cullinan Holdings | Treatment of clays |
US4158685A (en) * | 1978-03-16 | 1979-06-19 | Kaiser Aluminum & Chemical Corporation | Foamed insulation refractory |
DE2902079B1 (de) * | 1979-01-19 | 1979-11-08 | Minora Forsch Entwicklung | Tierstreu |
JPS5650165A (en) * | 1979-09-28 | 1981-05-07 | Toyo Tire & Rubber Co | Manufacture of porous ceramic molded product |
US4395456A (en) * | 1980-01-10 | 1983-07-26 | Imperial Chemical Industries Limited | Inorganic foam |
US4318996A (en) * | 1980-04-21 | 1982-03-09 | Princeton Organics Incorporated | Lightweight ceramic composition |
US4356271A (en) * | 1980-05-27 | 1982-10-26 | Aluminum Company Of America | Noncollapsible ceramic foam |
US4341561A (en) * | 1981-04-22 | 1982-07-27 | The Babcock & Wilcox Company | Foamed insulating refractory |
CA1173463A (fr) * | 1981-05-27 | 1984-08-28 | Henri-Bernard Malric | Mousses ceramiques et procede de leur preparation |
DE3414965C2 (de) * | 1984-04-19 | 1986-06-19 | Effem Gmbh, 2810 Verden | Verfahren zum Herstellen von porösen Keramikkörpern zur Verwendung als Ad- bzw. Absorptionsmittel, insbesondere Tierstreu |
-
1984
- 1984-04-19 DE DE3414967A patent/DE3414967C2/de not_active Expired
-
1985
- 1985-02-09 DE DE8585900974T patent/DE3570861D1/de not_active Expired
- 1985-02-09 JP JP60500856A patent/JPS61501908A/ja active Granted
- 1985-02-09 AU AU39379/85A patent/AU571654B2/en not_active Ceased
- 1985-02-09 WO PCT/DE1985/000034 patent/WO1985004861A1/fr active IP Right Grant
- 1985-02-09 EP EP85900974A patent/EP0179775B1/fr not_active Expired
-
1987
- 1987-07-17 US US07/075,203 patent/US4824811A/en not_active Expired - Lifetime
-
1990
- 1990-02-01 US US07/474,639 patent/US5015606A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4442810A1 (de) * | 1994-12-01 | 1996-06-05 | Cerasiv Gmbh | Granulat zur Herstellung hochporöser Formkörper |
Also Published As
Publication number | Publication date |
---|---|
DE3570861D1 (en) | 1989-07-13 |
US5015606A (en) | 1991-05-14 |
DE3414967A1 (de) | 1985-11-07 |
JPH0543666B2 (fr) | 1993-07-02 |
WO1985004861A1 (fr) | 1985-11-07 |
AU571654B2 (en) | 1988-04-21 |
US4824811A (en) | 1989-04-25 |
AU3937985A (en) | 1985-11-15 |
JPS61501908A (ja) | 1986-09-04 |
DE3414967C2 (de) | 1986-06-05 |
EP0179775A1 (fr) | 1986-05-07 |
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